US20040137715A1 - Methods of manufacturing semiconductor devices - Google Patents

Methods of manufacturing semiconductor devices Download PDF

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Publication number
US20040137715A1
US20040137715A1 US10/744,717 US74471703A US2004137715A1 US 20040137715 A1 US20040137715 A1 US 20040137715A1 US 74471703 A US74471703 A US 74471703A US 2004137715 A1 US2004137715 A1 US 2004137715A1
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United States
Prior art keywords
copper
depositing
trench
barrier layer
copper line
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/744,717
Inventor
Ki Min Lee
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DongbuAnam Semiconductor Inc
Original Assignee
Dongbu Electronics Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dongbu Electronics Co Ltd filed Critical Dongbu Electronics Co Ltd
Assigned to DONGBU ELECTRONICS CO., LTD. reassignment DONGBU ELECTRONICS CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: LEE, KI MIN
Publication of US20040137715A1 publication Critical patent/US20040137715A1/en
Assigned to DONGBUANAM SEMICONDUCTOR, INC. reassignment DONGBUANAM SEMICONDUCTOR, INC. MERGER (SEE DOCUMENT FOR DETAILS). Assignors: DONGBU SEMICONDUCTOR INC.
Priority to US11/324,760 priority Critical patent/US7459394B2/en
Abandoned legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76801Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
    • H01L21/76829Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing characterised by the formation of thin functional dielectric layers, e.g. dielectric etch-stop, barrier, capping or liner layers
    • H01L21/76834Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing characterised by the formation of thin functional dielectric layers, e.g. dielectric etch-stop, barrier, capping or liner layers formation of thin insulating films on the sidewalls or on top of conductors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76801Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
    • H01L21/76819Smoothing of the dielectric

Definitions

  • the present disclosure relates to semiconductor devices and, more particularly, to a methods of manufacturing semiconductor devices.
  • a trench is formed in a substrate and a barrier metal layer is deposited on the overall surface of the substrate and the trench. Then, a copper layer is deposited over the barrier metal layer so that the trench is completely filled. A chemical mechanical polishing process is performed to flatten the copper layer. As a result, a copper interconnect is formed. Next, a barrier layer is formed over the copper interconnect.
  • FIGS. 1 a through 1 f illustrate, in cross-sectional views, the results of process steps for fabricating a semiconductor device.
  • ILD interlayer dielectric
  • a trench 10 of a dual damascene structure is formed in an interlayer dielectric (ILD) through a predetermined patterning process so that a portion of a lower metal interconnect is exposed. Then, a barrier metal layer 12 to prevent diffusion of copper is deposited on the surface of the ILD including the trench 10 .
  • ILD interlayer dielectric
  • a copper layer 14 is deposited so that the trench 10 is completely filled with copper.
  • the copper is deposited by means of at least one of electroplating and chemical vapor deposition (CVD).
  • CVD chemical vapor deposition
  • a planarization process is performed to flatten the copper layer.
  • the planarization process may be, for example, a chemical mechanical polishing (CMP) process or an etch back process. As a result, a copper line 11 is formed.
  • CMP chemical mechanical polishing
  • an etching process such as wet etching is performed to remove some part of the copper line 11 in the trench 10 .
  • the etching may be wet etching performed using an etching solution such as hydrochloric acid, dilute sulfuric acid, or aqueous ammonia, which have relatively low etching speeds.
  • a barrier layer 16 is deposited on the etched copper line 11 .
  • the barrier layer may be formed of SiN or SiC.
  • a planarization process is performed to flatten the barrier layer.
  • the planarization process may employ CMP or an etch back process.

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)

Abstract

Methods of manufacturing semiconductors are disclosed. One example method includes forming a trench through a dual damascene process, depositing a barrier metal layer on the overall surface, and depositing copper in the trench to form a copper line. The example method may also include performing a wet etching process to remove the top portion of the copper line, depositing a barrier layer on the etched copper line, and performing a planarization process to flatten the barrier layer.

Description

    TECHNICAL FIELD
  • The present disclosure relates to semiconductor devices and, more particularly, to a methods of manufacturing semiconductor devices. [0001]
  • BACKGROUND
  • Generally, in a copper damascene process, a trench is formed in a substrate and a barrier metal layer is deposited on the overall surface of the substrate and the trench. Then, a copper layer is deposited over the barrier metal layer so that the trench is completely filled. A chemical mechanical polishing process is performed to flatten the copper layer. As a result, a copper interconnect is formed. Next, a barrier layer is formed over the copper interconnect. [0002]
  • However, most barrier layers used as an etch-stop layer in a damascene process have high capacitance, thereby increasing the delay time of electrons. Such increase in the delay time of electrons makes it difficult to enhance processing speed of the device.[0003]
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIGS. 1[0004] a through 1 f illustrate, in cross-sectional views, the results of process steps for fabricating a semiconductor device.
  • DETAILED DESCRIPTION
  • Disclosed herein is an example semiconductor device manufacturing process that reduces capacitance of an interlayer dielectric (ILD), thereby reducing delay time of electron by forming a barrier layer only on a copper line, and, therefore, can enhance processing speed of a device produced by a copper damascene process. [0005]
  • Referring to FIG. 1[0006] a, a trench 10 of a dual damascene structure is formed in an interlayer dielectric (ILD) through a predetermined patterning process so that a portion of a lower metal interconnect is exposed. Then, a barrier metal layer 12 to prevent diffusion of copper is deposited on the surface of the ILD including the trench 10.
  • Referring to FIG. 1[0007] b, a copper layer 14 is deposited so that the trench 10 is completely filled with copper. The copper is deposited by means of at least one of electroplating and chemical vapor deposition (CVD). Referring to FIG. 1c, a planarization process is performed to flatten the copper layer. The planarization process may be, for example, a chemical mechanical polishing (CMP) process or an etch back process. As a result, a copper line 11 is formed.
  • Referring to FIG. 1[0008] d, an etching process such as wet etching is performed to remove some part of the copper line 11 in the trench 10. In one example, the etching may be wet etching performed using an etching solution such as hydrochloric acid, dilute sulfuric acid, or aqueous ammonia, which have relatively low etching speeds.
  • Referring to FIG. 1[0009] e, a barrier layer 16 is deposited on the etched copper line 11. The barrier layer may be formed of SiN or SiC. Referring to FIG. 1f, a planarization process is performed to flatten the barrier layer. The planarization process may employ CMP or an etch back process.
  • The foregoing describes how a barrier layer is formed only on the copper line using SiN or SiC to reduce capacitance of the ILD, thereby reducing delay time of electrons, which is proportional to resistance-capacitance (RC). Therefore, the disclosed techniques can increase processing speed of device. [0010]
  • Although certain example methods are disclosed herein, the scope of coverage of this patent is not limited thereto. On the contrary, this patent covers every apparatus, method and article of manufacture fairly falling within the scope of the appended claims either literally or under the doctrine of equivalents. [0011]

Claims (4)

What is claimed is:
1. A method for manufacturing a semiconductor device comprising:
forming a trench through a dual damascene process;
depositing a barrier metal layer on an overall surface, the barrier metal layer preventing diffusion of copper;
depositing copper in the trench to form a copper line;
performing a wet etching process to remove a top portion of the copper line;
depositing a barrier layer on the etched copper line; and
performing a planarization process such as chemical mechanical polishing (CMP) or an etch back process to flatten the barrier layer.
2. A method as defined by claim 1, wherein the barrier layer is formed of SiN or SiC.
3. A method as defined by claim 1, wherein the copper is deposited by at least one of electroplating and chemical vapor deposition (CVD).
4. A method as defined by claim 1, wherein the wet etching is performed using hydrochloric acid, dilute sulfuric acid, or aqueous ammonia.
US10/744,717 2002-12-30 2003-12-23 Methods of manufacturing semiconductor devices Abandoned US20040137715A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US11/324,760 US7459394B2 (en) 2002-12-30 2006-01-03 Methods of manufacturing semiconductor devices

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020020087370A KR20040060563A (en) 2002-12-30 2002-12-30 Manufacture method and structure of semiconductor element
KR10-2002-0087370 2002-12-30

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100752195B1 (en) * 2006-09-08 2007-08-27 동부일렉트로닉스 주식회사 Method of forming metal line in semiconductor device
US9281239B2 (en) * 2008-10-27 2016-03-08 Nxp B.V. Biocompatible electrodes and methods of manufacturing biocompatible electrodes
CN105489549B (en) * 2014-10-13 2018-11-16 中芯国际集成电路制造(上海)有限公司 A kind of copper interconnection structure and its manufacturing method, electronic device

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5918149A (en) * 1996-02-16 1999-06-29 Advanced Micro Devices, Inc. Deposition of a conductor in a via hole or trench
US6110648A (en) * 1998-09-17 2000-08-29 Taiwan Semiconductor Manufacturing Company Method of enclosing copper conductor in a dual damascene process
US6156642A (en) * 1999-03-23 2000-12-05 United Microelectronics Corp. Method of fabricating a dual damascene structure in an integrated circuit
US6211085B1 (en) * 1999-02-18 2001-04-03 Taiwan Semiconductor Company Method of preparing CU interconnect lines
US6245669B1 (en) * 1999-02-05 2001-06-12 Taiwan Semiconductor Manufacturing Company High selectivity Si-rich SiON etch-stop layer
US6251786B1 (en) * 1999-09-07 2001-06-26 Chartered Semiconductor Manufacturing Ltd. Method to create a copper dual damascene structure with less dishing and erosion
US6274499B1 (en) * 1999-11-19 2001-08-14 Chartered Semiconductor Manufacturing Ltd. Method to avoid copper contamination during copper etching and CMP
US6403465B1 (en) * 1999-12-28 2002-06-11 Taiwan Semiconductor Manufacturing Company Method to improve copper barrier properties
US6670274B1 (en) * 2002-10-01 2003-12-30 Taiwan Semiconductor Manufacturing Company Method of forming a copper damascene structure comprising a recessed copper-oxide-free initial copper structure

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6537913B2 (en) * 2001-06-29 2003-03-25 Intel Corporation Method of making a semiconductor device with aluminum capped copper interconnect pads
JP2003142579A (en) * 2001-11-07 2003-05-16 Hitachi Ltd Semiconductor device and method for manufacturing the same

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5918149A (en) * 1996-02-16 1999-06-29 Advanced Micro Devices, Inc. Deposition of a conductor in a via hole or trench
US6110648A (en) * 1998-09-17 2000-08-29 Taiwan Semiconductor Manufacturing Company Method of enclosing copper conductor in a dual damascene process
US6245669B1 (en) * 1999-02-05 2001-06-12 Taiwan Semiconductor Manufacturing Company High selectivity Si-rich SiON etch-stop layer
US6211085B1 (en) * 1999-02-18 2001-04-03 Taiwan Semiconductor Company Method of preparing CU interconnect lines
US6156642A (en) * 1999-03-23 2000-12-05 United Microelectronics Corp. Method of fabricating a dual damascene structure in an integrated circuit
US6251786B1 (en) * 1999-09-07 2001-06-26 Chartered Semiconductor Manufacturing Ltd. Method to create a copper dual damascene structure with less dishing and erosion
US6274499B1 (en) * 1999-11-19 2001-08-14 Chartered Semiconductor Manufacturing Ltd. Method to avoid copper contamination during copper etching and CMP
US6403465B1 (en) * 1999-12-28 2002-06-11 Taiwan Semiconductor Manufacturing Company Method to improve copper barrier properties
US6670274B1 (en) * 2002-10-01 2003-12-30 Taiwan Semiconductor Manufacturing Company Method of forming a copper damascene structure comprising a recessed copper-oxide-free initial copper structure

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Publication number Publication date
US7459394B2 (en) 2008-12-02
KR20040060563A (en) 2004-07-06
US20060172528A1 (en) 2006-08-03

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AS Assignment

Owner name: DONGBU ELECTRONICS CO., LTD., KOREA, REPUBLIC OF

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:LEE, KI MIN;REEL/FRAME:014941/0492

Effective date: 20031222

AS Assignment

Owner name: DONGBUANAM SEMICONDUCTOR, INC., KOREA, REPUBLIC OF

Free format text: MERGER;ASSIGNOR:DONGBU SEMICONDUCTOR INC.;REEL/FRAME:016593/0667

Effective date: 20041221

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION