US20040137715A1 - Methods of manufacturing semiconductor devices - Google Patents
Methods of manufacturing semiconductor devices Download PDFInfo
- Publication number
- US20040137715A1 US20040137715A1 US10/744,717 US74471703A US2004137715A1 US 20040137715 A1 US20040137715 A1 US 20040137715A1 US 74471703 A US74471703 A US 74471703A US 2004137715 A1 US2004137715 A1 US 2004137715A1
- Authority
- US
- United States
- Prior art keywords
- copper
- depositing
- trench
- barrier layer
- copper line
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000034 method Methods 0.000 title claims abstract description 32
- 239000004065 semiconductor Substances 0.000 title claims abstract description 7
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229910052802 copper Inorganic materials 0.000 claims abstract description 26
- 239000010949 copper Substances 0.000 claims abstract description 26
- 230000004888 barrier function Effects 0.000 claims abstract description 18
- 239000002184 metal Substances 0.000 claims abstract description 7
- 229910052751 metal Inorganic materials 0.000 claims abstract description 7
- 238000001039 wet etching Methods 0.000 claims abstract description 5
- 230000009977 dual effect Effects 0.000 claims abstract description 3
- 238000000151 deposition Methods 0.000 claims abstract 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 238000005229 chemical vapour deposition Methods 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 2
- 238000009792 diffusion process Methods 0.000 claims description 2
- 238000009713 electroplating Methods 0.000 claims description 2
- 238000005498 polishing Methods 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 15
- 238000005530 etching Methods 0.000 description 4
- 239000011229 interlayer Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000000059 patterning Methods 0.000 description 1
- 238000007517 polishing process Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
- H01L21/76829—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing characterised by the formation of thin functional dielectric layers, e.g. dielectric etch-stop, barrier, capping or liner layers
- H01L21/76834—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing characterised by the formation of thin functional dielectric layers, e.g. dielectric etch-stop, barrier, capping or liner layers formation of thin insulating films on the sidewalls or on top of conductors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
- H01L21/76819—Smoothing of the dielectric
Definitions
- the present disclosure relates to semiconductor devices and, more particularly, to a methods of manufacturing semiconductor devices.
- a trench is formed in a substrate and a barrier metal layer is deposited on the overall surface of the substrate and the trench. Then, a copper layer is deposited over the barrier metal layer so that the trench is completely filled. A chemical mechanical polishing process is performed to flatten the copper layer. As a result, a copper interconnect is formed. Next, a barrier layer is formed over the copper interconnect.
- FIGS. 1 a through 1 f illustrate, in cross-sectional views, the results of process steps for fabricating a semiconductor device.
- ILD interlayer dielectric
- a trench 10 of a dual damascene structure is formed in an interlayer dielectric (ILD) through a predetermined patterning process so that a portion of a lower metal interconnect is exposed. Then, a barrier metal layer 12 to prevent diffusion of copper is deposited on the surface of the ILD including the trench 10 .
- ILD interlayer dielectric
- a copper layer 14 is deposited so that the trench 10 is completely filled with copper.
- the copper is deposited by means of at least one of electroplating and chemical vapor deposition (CVD).
- CVD chemical vapor deposition
- a planarization process is performed to flatten the copper layer.
- the planarization process may be, for example, a chemical mechanical polishing (CMP) process or an etch back process. As a result, a copper line 11 is formed.
- CMP chemical mechanical polishing
- an etching process such as wet etching is performed to remove some part of the copper line 11 in the trench 10 .
- the etching may be wet etching performed using an etching solution such as hydrochloric acid, dilute sulfuric acid, or aqueous ammonia, which have relatively low etching speeds.
- a barrier layer 16 is deposited on the etched copper line 11 .
- the barrier layer may be formed of SiN or SiC.
- a planarization process is performed to flatten the barrier layer.
- the planarization process may employ CMP or an etch back process.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
Abstract
Methods of manufacturing semiconductors are disclosed. One example method includes forming a trench through a dual damascene process, depositing a barrier metal layer on the overall surface, and depositing copper in the trench to form a copper line. The example method may also include performing a wet etching process to remove the top portion of the copper line, depositing a barrier layer on the etched copper line, and performing a planarization process to flatten the barrier layer.
Description
- The present disclosure relates to semiconductor devices and, more particularly, to a methods of manufacturing semiconductor devices.
- Generally, in a copper damascene process, a trench is formed in a substrate and a barrier metal layer is deposited on the overall surface of the substrate and the trench. Then, a copper layer is deposited over the barrier metal layer so that the trench is completely filled. A chemical mechanical polishing process is performed to flatten the copper layer. As a result, a copper interconnect is formed. Next, a barrier layer is formed over the copper interconnect.
- However, most barrier layers used as an etch-stop layer in a damascene process have high capacitance, thereby increasing the delay time of electrons. Such increase in the delay time of electrons makes it difficult to enhance processing speed of the device.
- FIGS. 1a through 1 f illustrate, in cross-sectional views, the results of process steps for fabricating a semiconductor device.
- Disclosed herein is an example semiconductor device manufacturing process that reduces capacitance of an interlayer dielectric (ILD), thereby reducing delay time of electron by forming a barrier layer only on a copper line, and, therefore, can enhance processing speed of a device produced by a copper damascene process.
- Referring to FIG. 1a, a
trench 10 of a dual damascene structure is formed in an interlayer dielectric (ILD) through a predetermined patterning process so that a portion of a lower metal interconnect is exposed. Then, abarrier metal layer 12 to prevent diffusion of copper is deposited on the surface of the ILD including thetrench 10. - Referring to FIG. 1b, a
copper layer 14 is deposited so that thetrench 10 is completely filled with copper. The copper is deposited by means of at least one of electroplating and chemical vapor deposition (CVD). Referring to FIG. 1c, a planarization process is performed to flatten the copper layer. The planarization process may be, for example, a chemical mechanical polishing (CMP) process or an etch back process. As a result, acopper line 11 is formed. - Referring to FIG. 1d, an etching process such as wet etching is performed to remove some part of the
copper line 11 in thetrench 10. In one example, the etching may be wet etching performed using an etching solution such as hydrochloric acid, dilute sulfuric acid, or aqueous ammonia, which have relatively low etching speeds. - Referring to FIG. 1e, a
barrier layer 16 is deposited on theetched copper line 11. The barrier layer may be formed of SiN or SiC. Referring to FIG. 1f, a planarization process is performed to flatten the barrier layer. The planarization process may employ CMP or an etch back process. - The foregoing describes how a barrier layer is formed only on the copper line using SiN or SiC to reduce capacitance of the ILD, thereby reducing delay time of electrons, which is proportional to resistance-capacitance (RC). Therefore, the disclosed techniques can increase processing speed of device.
- Although certain example methods are disclosed herein, the scope of coverage of this patent is not limited thereto. On the contrary, this patent covers every apparatus, method and article of manufacture fairly falling within the scope of the appended claims either literally or under the doctrine of equivalents.
Claims (4)
1. A method for manufacturing a semiconductor device comprising:
forming a trench through a dual damascene process;
depositing a barrier metal layer on an overall surface, the barrier metal layer preventing diffusion of copper;
depositing copper in the trench to form a copper line;
performing a wet etching process to remove a top portion of the copper line;
depositing a barrier layer on the etched copper line; and
performing a planarization process such as chemical mechanical polishing (CMP) or an etch back process to flatten the barrier layer.
2. A method as defined by claim 1 , wherein the barrier layer is formed of SiN or SiC.
3. A method as defined by claim 1 , wherein the copper is deposited by at least one of electroplating and chemical vapor deposition (CVD).
4. A method as defined by claim 1 , wherein the wet etching is performed using hydrochloric acid, dilute sulfuric acid, or aqueous ammonia.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/324,760 US7459394B2 (en) | 2002-12-30 | 2006-01-03 | Methods of manufacturing semiconductor devices |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020020087370A KR20040060563A (en) | 2002-12-30 | 2002-12-30 | Manufacture method and structure of semiconductor element |
KR10-2002-0087370 | 2002-12-30 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/324,760 Continuation US7459394B2 (en) | 2002-12-30 | 2006-01-03 | Methods of manufacturing semiconductor devices |
Publications (1)
Publication Number | Publication Date |
---|---|
US20040137715A1 true US20040137715A1 (en) | 2004-07-15 |
Family
ID=36757143
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/744,717 Abandoned US20040137715A1 (en) | 2002-12-30 | 2003-12-23 | Methods of manufacturing semiconductor devices |
US11/324,760 Active 2025-01-15 US7459394B2 (en) | 2002-12-30 | 2006-01-03 | Methods of manufacturing semiconductor devices |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/324,760 Active 2025-01-15 US7459394B2 (en) | 2002-12-30 | 2006-01-03 | Methods of manufacturing semiconductor devices |
Country Status (2)
Country | Link |
---|---|
US (2) | US20040137715A1 (en) |
KR (1) | KR20040060563A (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100752195B1 (en) * | 2006-09-08 | 2007-08-27 | 동부일렉트로닉스 주식회사 | Method of forming metal line in semiconductor device |
US9281239B2 (en) * | 2008-10-27 | 2016-03-08 | Nxp B.V. | Biocompatible electrodes and methods of manufacturing biocompatible electrodes |
CN105489549B (en) * | 2014-10-13 | 2018-11-16 | 中芯国际集成电路制造(上海)有限公司 | A kind of copper interconnection structure and its manufacturing method, electronic device |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5918149A (en) * | 1996-02-16 | 1999-06-29 | Advanced Micro Devices, Inc. | Deposition of a conductor in a via hole or trench |
US6110648A (en) * | 1998-09-17 | 2000-08-29 | Taiwan Semiconductor Manufacturing Company | Method of enclosing copper conductor in a dual damascene process |
US6156642A (en) * | 1999-03-23 | 2000-12-05 | United Microelectronics Corp. | Method of fabricating a dual damascene structure in an integrated circuit |
US6211085B1 (en) * | 1999-02-18 | 2001-04-03 | Taiwan Semiconductor Company | Method of preparing CU interconnect lines |
US6245669B1 (en) * | 1999-02-05 | 2001-06-12 | Taiwan Semiconductor Manufacturing Company | High selectivity Si-rich SiON etch-stop layer |
US6251786B1 (en) * | 1999-09-07 | 2001-06-26 | Chartered Semiconductor Manufacturing Ltd. | Method to create a copper dual damascene structure with less dishing and erosion |
US6274499B1 (en) * | 1999-11-19 | 2001-08-14 | Chartered Semiconductor Manufacturing Ltd. | Method to avoid copper contamination during copper etching and CMP |
US6403465B1 (en) * | 1999-12-28 | 2002-06-11 | Taiwan Semiconductor Manufacturing Company | Method to improve copper barrier properties |
US6670274B1 (en) * | 2002-10-01 | 2003-12-30 | Taiwan Semiconductor Manufacturing Company | Method of forming a copper damascene structure comprising a recessed copper-oxide-free initial copper structure |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6537913B2 (en) * | 2001-06-29 | 2003-03-25 | Intel Corporation | Method of making a semiconductor device with aluminum capped copper interconnect pads |
JP2003142579A (en) * | 2001-11-07 | 2003-05-16 | Hitachi Ltd | Semiconductor device and method for manufacturing the same |
-
2002
- 2002-12-30 KR KR1020020087370A patent/KR20040060563A/en not_active Application Discontinuation
-
2003
- 2003-12-23 US US10/744,717 patent/US20040137715A1/en not_active Abandoned
-
2006
- 2006-01-03 US US11/324,760 patent/US7459394B2/en active Active
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5918149A (en) * | 1996-02-16 | 1999-06-29 | Advanced Micro Devices, Inc. | Deposition of a conductor in a via hole or trench |
US6110648A (en) * | 1998-09-17 | 2000-08-29 | Taiwan Semiconductor Manufacturing Company | Method of enclosing copper conductor in a dual damascene process |
US6245669B1 (en) * | 1999-02-05 | 2001-06-12 | Taiwan Semiconductor Manufacturing Company | High selectivity Si-rich SiON etch-stop layer |
US6211085B1 (en) * | 1999-02-18 | 2001-04-03 | Taiwan Semiconductor Company | Method of preparing CU interconnect lines |
US6156642A (en) * | 1999-03-23 | 2000-12-05 | United Microelectronics Corp. | Method of fabricating a dual damascene structure in an integrated circuit |
US6251786B1 (en) * | 1999-09-07 | 2001-06-26 | Chartered Semiconductor Manufacturing Ltd. | Method to create a copper dual damascene structure with less dishing and erosion |
US6274499B1 (en) * | 1999-11-19 | 2001-08-14 | Chartered Semiconductor Manufacturing Ltd. | Method to avoid copper contamination during copper etching and CMP |
US6403465B1 (en) * | 1999-12-28 | 2002-06-11 | Taiwan Semiconductor Manufacturing Company | Method to improve copper barrier properties |
US6670274B1 (en) * | 2002-10-01 | 2003-12-30 | Taiwan Semiconductor Manufacturing Company | Method of forming a copper damascene structure comprising a recessed copper-oxide-free initial copper structure |
Also Published As
Publication number | Publication date |
---|---|
US7459394B2 (en) | 2008-12-02 |
KR20040060563A (en) | 2004-07-06 |
US20060172528A1 (en) | 2006-08-03 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6274497B1 (en) | Copper damascene manufacturing process | |
US6426289B1 (en) | Method of fabricating a barrier layer associated with a conductor layer in damascene structures | |
TWI821444B (en) | Method of forming self-aligned via | |
US8466055B2 (en) | Semiconductor device and method of manufacturing semiconductor device | |
US9824918B2 (en) | Method for electromigration and adhesion using two selective deposition | |
US20140225278A1 (en) | Interconnection structure for an integrated circuit | |
US7701004B2 (en) | Semiconductor device and method of manufacturing thereof | |
US20150325467A1 (en) | Methods for fabricating integrated circuits including barrier layers for interconnect structures | |
JP2007109894A (en) | Semiconductor device and its manufacturing method | |
US20050263892A1 (en) | Method of forming copper interconnection in semiconductor device and semiconductor device using the same | |
EP1330842B1 (en) | Low temperature hillock suppression method in integrated circuit interconnects | |
US9257329B2 (en) | Methods for fabricating integrated circuits including densifying interlevel dielectric layers | |
CN114743931A (en) | Method for manufacturing semiconductor integrated device | |
US7459394B2 (en) | Methods of manufacturing semiconductor devices | |
US8497208B2 (en) | Semiconductor device and method for manufacturing the same | |
US20130217225A1 (en) | Method for manufacturing semiconductor device | |
US7179734B2 (en) | Method for forming dual damascene pattern | |
US8704372B2 (en) | Integrated circuits and methods for processing integrated circuits with embedded features | |
US8587128B2 (en) | Damascene structure | |
US8084357B2 (en) | Method for manufacturing a dual damascene opening comprising a trench opening and a via opening | |
US20020081835A1 (en) | Method for fabricating a semiconductor device | |
US11658067B2 (en) | Semiconductor structure and formation method thereof | |
US7015149B2 (en) | Simplified dual damascene process | |
US20020072217A1 (en) | Method for improving contact reliability in semiconductor devices | |
KR100399909B1 (en) | Method of forming inter-metal dielectric in a semiconductor device |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: DONGBU ELECTRONICS CO., LTD., KOREA, REPUBLIC OF Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:LEE, KI MIN;REEL/FRAME:014941/0492 Effective date: 20031222 |
|
AS | Assignment |
Owner name: DONGBUANAM SEMICONDUCTOR, INC., KOREA, REPUBLIC OF Free format text: MERGER;ASSIGNOR:DONGBU SEMICONDUCTOR INC.;REEL/FRAME:016593/0667 Effective date: 20041221 |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |