US20010053572A1 - Semiconductor device having opening and method of fabricating the same - Google Patents

Semiconductor device having opening and method of fabricating the same Download PDF

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Publication number
US20010053572A1
US20010053572A1 US09/788,673 US78867301A US2001053572A1 US 20010053572 A1 US20010053572 A1 US 20010053572A1 US 78867301 A US78867301 A US 78867301A US 2001053572 A1 US2001053572 A1 US 2001053572A1
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insulator film
conductive part
etching
semiconductor device
film
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US09/788,673
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Yoshinari Ichihashi
Takashi Goto
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Sanyo Electric Co Ltd
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Sanyo Electric Co Ltd
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Assigned to SANYO ELECTRIC CO., LTD. reassignment SANYO ELECTRIC CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: GOTO, TAKASHI, ICHIHASHI, YOSHINARI
Publication of US20010053572A1 publication Critical patent/US20010053572A1/en
Priority to US10/624,540 priority Critical patent/US7052989B2/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • H01L21/283Deposition of conductive or insulating materials for electrodes conducting electric current
    • H01L21/285Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation
    • H01L21/28506Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers
    • H01L21/28512Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising elements of Group IV of the Periodic System
    • H01L21/28518Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising elements of Group IV of the Periodic System the conductive layers comprising silicides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
    • H01L21/3105After-treatment
    • H01L21/311Etching the insulating layers by chemical or physical means
    • H01L21/31105Etching inorganic layers
    • H01L21/31111Etching inorganic layers by chemical means
    • H01L21/31116Etching inorganic layers by chemical means by dry-etching
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76801Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
    • H01L21/76802Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing by forming openings in dielectrics
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76801Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
    • H01L21/76802Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing by forming openings in dielectrics
    • H01L21/76805Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing by forming openings in dielectrics the opening being a via or contact hole penetrating the underlying conductor
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76801Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
    • H01L21/76829Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing characterised by the formation of thin functional dielectric layers, e.g. dielectric etch-stop, barrier, capping or liner layers
    • H01L21/76834Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing characterised by the formation of thin functional dielectric layers, e.g. dielectric etch-stop, barrier, capping or liner layers formation of thin insulating films on the sidewalls or on top of conductors

Definitions

  • the present invention relates to a semiconductor device and a method of fabricating the same, and more particularly, it relates to a semiconductor device having an opening and a method of fabricating the same.
  • each of gate, source and drain electrodes itself has high wiring resistance and high parasitic resistance.
  • spacers of silicon SiO 2
  • a metal is deposited on the overall surface of the element and thereafter heat-treated for silicifying the surfaces of the gate, source and drain electrodes in a self-aligned manner. Then, the remaining unreacted metal part is removed.
  • the salicide structure is formed.
  • the contact hole is required to have a high aspect ratio.
  • etching with CHF 3 gas or CF 4 gas through a low-concentration plasma device it is difficult to suppress a microloading effect (irregular etching) as the aspect ratio of the contact hole is increased.
  • the microloading effect irregular etching
  • FIG. 7 is a sectional view for illustrating the problem caused when forming contact holes by conventional etching with CHF 3 gas or CF 4 gas through a high-concentration plasma device.
  • an element isolation film 112 is formed on a prescribed region of the surface of a semiconductor substrate 101 in a conventional semiconductor device.
  • a source electrode 102 and a drain electrode 103 serving as impurity active regions are formed on an active region (element forming region) enclosed with the element isolation film 112 at a prescribed interval to hold a channel region 104 therebetween.
  • a gate electrode 106 is formed on the channel region 104 through a gate insulator film 105 .
  • Salicide layers 102 s , 103 s and 106 s are formed on the surfaces of the source electrode 102 , the drain electrode 103 and the gate electrode 106 respectively. Further, an interlayer isolation film 109 of silicon oxide (SiO 2 ) is formed to cover the overall surface. The interlayer isolation film 109 is formed with contact holes 110 reaching the source electrode 102 , the drain electrode 103 and the gate electrode 106 respectively.
  • the contact holes 110 are formed in the interlayer isolation film 109 by etching with CHF 3 gas or CF 4 gas through a high-concentration plasma device in order to suppress a microloading effect (irregular etching) in this structure, the surfaces of the electrodes 102 , 103 and 106 having the salicide structure are also etched. This is because it is difficult to set the concentration of CF 2 or CF 3 , which is a polymer precursor in the plasma of the etching gas, to a value capable of ensuring a high etching selection ratio of the base salicide layers 102 s , 103 s and 106 s , as hereinabove described.
  • An object of the present invention is to provide a semiconductor device capable of compatibly suppressing a microloading effect (irregular etching) and over-etching in formation of a fine contact hole requiring a high aspect ratio.
  • Another object of the present invention is to provide a semiconductor device capable of automatically reducing an etching rate before an opening reaches a lower conductive part.
  • Still another object of the present invention is to provide a method of fabricating a semiconductor device capable of compatibly suppressing a microloading effect (irregular etching) and over-etching.
  • a semiconductor device comprises a first conductive part, an insulator film having an opening formed on the first conductive part and a second conductive part electrically connected to the first conductive part through the opening, and the insulator film includes an upper insulator film and a lower insulator film, stacked/formed at least around a connection part between the first conductive part and the second conductive part, consisting of different materials.
  • the upper insulator film and the lower insulator film consisting of different materials are stacked/formed at least around the connection part between the first conductive part and the second conductive part, so that the etching rate is automatically reduced when etching for forming the opening reaches the lower insulator film from the upper insulator film if the lower insulator film is prepared from a material having a higher etching selection ratio than the upper insulator film, for example.
  • the first conductive part can be prevented from over-etching. Consequently, a semiconductor device capable of compatibly suppressing the microloading effect and over-etching in formation of a fine contact hole requiring a high aspect ratio can be provided.
  • the lower insulator film preferably contains a material having a higher etching selection ratio than the upper insulator film.
  • the etching rate can be readily automatically reduced when etching for forming the opening reaches the lower insulator film from the upper insulator film.
  • the etching rate is automatically reduced when the etching reaches the lower insulator film from the upper insulator film for the following reason: It is well known that anisotropy of etching for vertically forming an opening in an insulator film is improved by performing the etching with formation of a side wall protective film on the inner peripheral surface of the opening.
  • This side wall protective film is formed by an etched member, a polymerization film from the etching gas component or a reaction product thereof adhering to the inner peripheral surface of the opening.
  • the side wall protective film has an effect of hindering transverse progress of the etching.
  • the lower insulator film having a high etching selection ratio is provided under the upper insulator film through the aforementioned property, whereby the first conductive part can be prevented from over-etching also when etching is performed through a high-concentration plasma device with which a high etching selection ratio of the first conductive part is hard to attain for suppressing the microloading effect (irregular etching).
  • the first conductive part preferably contains a material having a higher etching selection ratio than the lower insulator film.
  • the first conductive part can be more effectively prevented from over-etching.
  • the first conductive part may include a silicified element electrode
  • the lower insulator film may include a silicon nitride film
  • the upper insulator film may include a silicon oxide film.
  • the element electrode may include a silicified gate electrode, a silicified source electrode and a silicified drain electrode.
  • the silicon nitride film is formed to be in contact with areas of the surfaces of the silicified electrodes except those exposed in the opening.
  • the etching rate is further reduced by the surfaces of the silicified electrodes immediately after being reduced by the silicon nitride film. Therefore, the surfaces of the silicified electrodes can be more effectively prevented from over-etching.
  • the lower insulator film may include an SOG film.
  • a method of fabricating a semiconductor device comprises steps of forming an insulator film including a multilayer film of an upper insulator film and a lower insulator film having a higher etching selection ratio than the upper insulator film on a first conductive part, etching the insulator film thereby forming an opening reaching the first conductive part, and forming a second conductive part connected with the first conductive part through the opening.
  • the insulator film including the multilayer film of the upper insulator film and the lower insulator film having a higher etching selection ratio than the upper insulator film is etched for forming the opening reaching the first conductive part, so that the etching rate is automatically reduced when etching for forming the opening reaches the lower insulator film from the upper insulator film.
  • the first conductive part can be prevented from over-etching. Consequently, the microloading effect and over-etching can be compatibly suppressed in formation of a fine contact hole requiring a high aspect ratio.
  • the first conductive part preferably contains a material having a higher etching selection ratio than the lower insulator film.
  • the first conductive part can be more effectively prevented from over-etching.
  • the method of fabricating a semiconductor device may preferably further comprise a step of silicifying the first conductive part in advance of the step of forming the insulator film.
  • the silicified surface has a higher etching selection ratio than the lower insulator film, whereby the first conductive part can be more effectively prevented from over-etching.
  • the first conductive part may include a gate electrode, a source electrode and a drain electrode
  • the step of silicifying the first conductive part may include a step of silicifying the surfaces of the gate electrode, the source electrode and the drain electrode.
  • the silicified surfaces of the gate, source and drain electrodes of the semiconductor device can be more effectively prevented from over-etching in etching for forming the opening.
  • the lower insulator film preferably includes a silicon nitride film
  • the upper insulator film preferably includes a silicon oxide film
  • the step of forming the opening preferably includes a step of forming the opening by etching the upper insulator film and the lower insulator film by dry etching with gas having a composition of C x H y F z .
  • the gas consisting of C x H y F z preferably includes gas consisting of C 4 H 8 .
  • the silicon nitride film forming the lower insulator film is preferably formed to be in contact with the surface of the first conductive part.
  • the surface of the first conductive part is exposed immediately after the etching rate is reduced by the silicon nitride film in etching for forming the opening, whereby the surface of the first conductive part can be prevented from over-etching.
  • the step of forming the opening is preferably carried out by dry etching through a high-concentration plasma device.
  • the lower insulator film may include an SOG film.
  • FIG. 1 is a sectional view showing the structure of a semiconductor device according to an embodiment of the present invention.
  • FIGS. 2 to 4 are sectional views for illustrating a fabrication process for the semiconductor device according to the embodiment shown in FIG. 1;
  • FIG. 5 is a graph showing results of element analysis of substances deposited on salicide layers after formation of contact holes in the semiconductor device according to the embodiment provided with a silicon nitride film;
  • FIG. 6 is a graph showing results of element analysis of substances deposited on salicide layers after formation of contact holes in a conventional semiconductor device provided with no silicon nitride film.
  • FIG. 7 is a sectional view for illustrating a problem in a conventional semiconductor device.
  • FIG. 1 shows an embodiment of the inventive semiconductor device, which is applied to a MOS transistor.
  • an element isolation film 12 is formed on a prescribed region of the surface of a semiconductor substrate 1 of silicon.
  • a source electrode 2 and a drain electrode 3 serving as impurity active regions are formed on an active region (element forming region) enclosed with the element isolation film 12 at a prescribed interval to hold a channel region 4 therebetween.
  • a gate electrode 6 is formed on the channel region 4 through a gate insulator film 5 .
  • Salicide layers 6 s , 2 s and 3 s are formed on the surfaces of the gate electrode 6 , the source electrode 2 and the drain electrode 3 in thicknesses of at least 5 nm respectively.
  • Spacers 7 of silicon oxide (SiO 2 ) are formed on the side surfaces of the gate electrode 6 .
  • a silicon nitride film (SiN) 8 is formed in a thickness of at least 5 nm, to cover the spacers 7 .
  • the silicon nitride film 8 is formed to cover the overall surface except regions formed with contact holes 10 . More specifically, the silicon nitride film 8 is also formed on regions of the surfaces of the salicide layers 6 s , 2 s and 3 s except those exposed through the contact holes 10 .
  • an interlayer isolation film 9 of silicon oxide (SiO 2 ) is formed in a thickness of at least 10 nm to cover the overall surface.
  • the contact holes 10 reaching the surfaces of the gate electrode 6 , the source electrode 2 and the drain electrode 3 respectively are formed in the interlayer isolation film 9 .
  • Wires 11 are connected to the gate electrode 6 , the source electrode 2 and the drain electrode 3 having a salicide structure through the contact holes 10 respectively.
  • the aforementioned spacers 7 of silicon oxide (SiO 2 ) are provided for bringing only the upper surface of the gate electrode 6 and only necessary regions of the source electrode 2 and the drain electrode 3 into salicide states. Further, the salicide layers 2 s , 3 s and 6 s are formed on the surfaces of the source electrode 2 , the drain electrode 3 and the gate electrode 6 as reaction films of titanium (Ti) respectively. Connection resistance can be remarkably reduced by connecting the wires 11 with the source electrode 2 , the drain electrode 3 and the gate electrode 6 through the salicide layers 2 s , 3 s and 6 s.
  • the silicon nitride film 8 has a function of inhibiting the salicide layers 2 s , 3 s and 6 s from over-etching when forming the contact holes 10 .
  • FIG. 1 A method of fabricating the semiconductor device according to the embodiment shown in FIG. 1 is now described with reference to FIGS. 2 to 4 .
  • the element isolation film 12 is formed on the prescribed region of the semiconductor substrate 1 , as shown in FIG. 2.
  • the source electrode 2 and the drain electrode 3 are formed on the active region (element forming region) enclosed with the element isolation film 12 at a prescribed interval to hold the channel region 4 therebetween.
  • the gate electrode 6 is formed on the channel region 4 through the gate insulator film 5 .
  • the gate electrode 6 , the source electrode 2 and the drain electrode 3 form the MOS transistor.
  • the spacers 7 of silicon oxide (SiO 2 ) are formed on the side surfaces of the gate electrode 6 .
  • a titanium (Ti) film is formed by sputtering in a thickness of about 50 nm, for example, from above the semiconductor substrate 1 .
  • This titanium film is heated in a stream of N 2 to about 800° C., thereby selectively silicifying the surfaces of the gate electrode 6 , the source electrode 2 and the drain electrode 3 .
  • the salicide layers 6 s , 2 s and 3 s having thicknesses of at least 5 nm are formed in a self-aligned manner.
  • the semiconductor substrate 1 is cooled and thereafter unreacted Ti is removed with an aqueous solution of NH 4 OH/H 2 O 2 O 2 .
  • the silicon nitride film 8 is formed in a thickness of at least 5 nm to cover the overall surface.
  • This silicon nitride film 8 is formed by LPCVD (low-pressure CVD) under the following conditions:
  • the flow rate of each of the aforementioned material gas and ammonia is expressed in a volume (cubic meters) per unit time (seconds) in terms of a standard state.
  • the interlayer isolation film 9 of silicon oxide is formed on the upper surface of the silicon nitride film 8 in a thickness of at least 10 nm, as shown in FIG. 3.
  • the interlayer isolation film 9 is flattened and thereafter resist patterns 20 for forming the contact holes 10 are formed on prescribed regions of the upper surface of the interlayer isolation film 9 .
  • the interlayer isolation film 9 is dry-etched through the resist patterns 20 serving as masks, thereby forming the contact holes 10 as shown in FIG. 4.
  • the dry etching for forming the contact holes 10 is performed through a high-concentration plasma device under the following conditions:
  • Etching gas C 4 F 8 /O 2 /Ar
  • the silicon nitride film 8 having a higher etching selection ratio than the interlayer isolation film 9 reduces the etching rate.
  • the salicide layers 6 s , 2 s and 3 s having a higher etching selection ratio than the silicon nitride film 8 further reduce the etching rate.
  • the surfaces of the salicide layers 6 s , 2 s and 3 s can be effectively inhibited from over-etching in the etching for forming the contact holes 10 . This point is now described in detail.
  • the high-concentration plasma device is employed mainly with etching gas of C 4 F 8 , as hereinabove described.
  • ionized etching gas receives downward force from an electric field perpendicularly applied to the semiconductor substrate 1 .
  • the ionized gas collides with the interlayer isolation film 9 , thereby scattering silicon oxide forming the interlayer isolation film 9 outward as gas layers.
  • the contact holes 10 are defined.
  • the etching gas and a C—F based polymer formed in the process of reaction between the etching gas and silicon oxide adhere to the inner peripheral surfaces of the contact holes 10 formed in the interlayer isolation film 9 .
  • the adhering polymer defines side wall protective films. These side wall protective films inhibit the interlayer isolation film 9 from horizontal etching.
  • the surfaces of the salicide layers 2 s , 3 s and 6 s are covered with the silicon nitride film 8 after formation thereof, thereby attaining an effect similar to the aforementioned side wall protection effect on the upper surfaces of the salicide layers 2 s , 3 s and 6 s .
  • the silicon nitride film 8 having a higher selection ratio than silicon oxide forming the interlayer isolation film 9 is formed under the interlayer isolation film 9 when etching the interlayer isolation film 9 mainly with C 4 F 8 gas, thereby prompting deposition of the C—F based polymer on the upper surface of the silicon nitride film 8 .
  • the etching rate is automatically reduced when the etching gas reaches the silicon nitride film 8 , with no control related to the etching rate or the like.
  • the salicide layers 2 s , 3 s and 6 s have a higher etching selection ratio than the silicon nitride film 8 , and hence reduction of the etching rate more remarkably appears on the salicide layers 2 s , 3 s and 6 s .
  • deposition of the C—F based polymer on the upper surfaces of the salicide layers 2 s , 3 s and 6 s is prompted.
  • the salicide layers 2 s , 3 s and 6 s can be more effectively prevented from over-etching. Consequently, the contact holes 10 can be formed without passing through the salicide layers 2 s , 3 s and 6 s by over-etching.
  • the resist patterns 20 are removed. Finally, the wires 11 are formed in the contact holes 10 as shown in FIG. 1, thereby completing the semiconductor device according to this embodiment.
  • FIGS. 5 and 6 Substances deposited on the salicide layers 2 s , 3 s and 6 s after formation of the contact holes 10 are now described with reference to FIGS. 5 and 6.
  • the horizontal axis shows chemical bond energy of each substance
  • the vertical axis shows the ratio (count) of the chemical bond energy.
  • element analysis inclusive of the chemical composition is enabled by independently counting the ratio of the substance corresponding to each chemical bond energy.
  • broken lines show theoretical values, and solid lines show actually measured values.
  • FIG. 5 shows results of element analysis of substances deposited on the salicide layers 2 s , 3 s and 6 s after formation of the contact holes 10 in the semiconductor device according to this embodiment provided with the silicon nitride film 8 .
  • FIG. 6 shows results of element analysis of substances deposited on salicide layers after formation of contact holes in a conventional semiconductor device provided with no silicon nitride film 8 . It is understood from FIGS. 5 and 6 that a large quantity of C—F based polymer is deposited on the salicide layers 2 s , 3 s and 6 s when performing etching with provision of the silicon nitride film 8 , as compared with the case of performing etching with no provision of the silicon nitride film 8 . Therefore, it is understood possible to effectively reduce the etching rate on the salicide layers 2 s , 3 s and 6 s.
  • the substances deposited on the salicide layers 2 s , 3 s and 6 s are removed.
  • the substances deposited on the salicide layers 2 s , 3 s and 6 s are removed by oxygen plasma treatment, for example.
  • This oxygen plasma treatment is performed under conditions of a reaction chamber pressure of 10 mT, microwave power (2.45 GHz) of 1500 W, a substrate bias of 400 W and an O 2 flow rate of 100 sccm.
  • the substances deposited on the salicide layers 2 s , 3 s and 6 s may alternatively be removed by ashing such as ozone ashing or down-flow ashing.
  • etching can be stopped in the salicide layers 2 s , 3 s and 6 s without extremely reducing the etching rate when forming the contact holes 10 , by providing the silicon nitride film 8 having a higher etching selection ratio than the interlayer isolation film 9 of silicon oxide on the salicide layers 2 s , 3 s and 6 s .
  • the contact holes 10 can be formed without passing through the salicide layers 2 s , 3 s and 6 s.
  • the etching can be readily performed with high precision by employing the silicon nitride film 8 generally employed as an insulator film as a film having a higher etching selection ratio than the interlayer isolation film 9 .
  • the aforementioned salicide layers 2 s , 3 s and 6 s may alternatively be formed by a method other than that described with reference to the aforementioned embodiment. Further, the aforementioned film forming method, thicknesses and etching conditions are properly changeable.
  • the silicon nitride film 8 is employed as the film having a higher selection ratio than the interlayer isolation film 9 in the aforementioned embodiment, the present invention is not restricted to this but another film such as an SOG film, for example, may be employed.
  • the etching gas for etching the contact holes 10 is mainly composed of C 4 F 8 in the aforementioned embodiment, the present invention is not restricted to this but another etching gas may be employed.
  • the etching gas may be mainly composed of arbitrary gas having a composition expressed as C x H y F z .
  • the interlayer isolation film 9 is etched with the gas mainly composed of C 4 F 8 through the high-concentration plasma device in the aforementioned embodiment, the present invention is not restricted to this but another etching may be employed.
  • the interlayer isolation film 9 may be etched by any method so far as a film having a higher selection ratio than the interlayer isolation film 9 with respect to the employed etching gas is formed between the interlayer isolation film 9 and the silicide films thereby inhibiting the silicide films from over-etching due to an effect similar to the side wall protection effect.
  • the gate electrode 6 , the source electrode 2 and the drain electrode 3 may not necessarily have a silicide structure.
  • the present invention is not restricted to this but is also applicable to a structure of connecting wires with each other through contact holes.
  • lower wires can be inhibited from over-etching when forming the contact holes in an interlayer isolation film by forming a film having a higher selection ratio than the interlayer isolation film between the interlayer isolation film and the lower wires.
  • the electrodes or the wires located under the contact holes may not necessarily have a higher etching selection ratio than the film formed on the surfaces thereof.
  • the semiconductor substrate 1 consists of silicon in the aforementioned embodiment, the present invention is not restricted to this but the semiconductor substrate may consist of a silicon-germanium alloy, silicon carbide, germanium, cadmium selenide, cadmium sulfide or gallium arsenide.

Abstract

A semiconductor device capable of compatibly suppressing a microloading effect (irregular etching) and over-etching also in formation of a fine contact hole requiring a high aspect ratio is obtained. This semiconductor device comprises a first conductive part, an insulator film having an opening formed on the first conductive part and a second conductive part electrically connected with the first conductive part through the opening. The insulator film includes an upper insulator film and a lower insulator film, stacked/formed at least around a connection part between the first conductive part and the second conductive part, consisting of different materials. Thus, when employing a material having a higher etching selection ratio than the upper insulator film for the lower insulator film, the first conductive part is prevented from over-etching also when etching is performed through a high-concentration plasma device with which a high etching selection ratio of the first conductive part is hard to attain for suppressing a microloading effect (irregular etching).

Description

    BACKGROUND OF THE INVENTION
  • 1. Field of the Invention [0001]
  • The present invention relates to a semiconductor device and a method of fabricating the same, and more particularly, it relates to a semiconductor device having an opening and a method of fabricating the same. [0002]
  • 2. Description of the Prior Art [0003]
  • Following recent improvement of the degree of integration of semiconductor devices, refinement of semiconductor elements loaded on semiconductor devices gets more and more important. Such refinement of the semiconductor elements results in a new problem of electric resistance of each element electrode and dispersion of the resistance. In a MOS transistor, for example, each of gate, source and drain electrodes itself has high wiring resistance and high parasitic resistance. Following the aforementioned refinement, unignorable wiring delay and conductance deterioration result from the electric resistance of each electrode. [0004]
  • In general, therefore, a technique of bringing the surfaces of gate, source and drain electrodes into a suicide structure obtained by combining the electrode material (silicon) with a metal element thereby reducing wiring delay and conductance deterioration is put into practice. Further, the so-called salicide (self-aligned silicide) structure selectively forming silicide layers on the surfaces of the gate, source and drain electrodes in a self-aligned manner is also frequently employed in recent years. [0005]
  • In a general fabrication process for the salicide structure, spacers of silicon (SiO[0006] 2) are first formed on the side surfaces of the gate electrode of polycrystalline silicon. Thereafter a metal is deposited on the overall surface of the element and thereafter heat-treated for silicifying the surfaces of the gate, source and drain electrodes in a self-aligned manner. Then, the remaining unreacted metal part is removed. Thus, the salicide structure is formed.
  • The aforementioned problem of electric resistance can be avoided by employing the salicide structure. When a contact hole (opening) is formed in an interlayer isolation film for connecting each electrode of the aforementioned salicide structure with a wire, however, the following problem arises: [0007]
  • Following the aforementioned refinement of the element, the contact hole is required to have a high aspect ratio. In generally employed etching with CHF[0008] 3 gas or CF4 gas through a low-concentration plasma device, however, it is difficult to suppress a microloading effect (irregular etching) as the aspect ratio of the contact hole is increased. In etching with CHF3 gas or CF4 gas through a high-concentration plasma device, on the other hand, the microloading effect (irregular etching) can be suppressed.
  • In the etching through a high-concentration plasma device, however, it is difficult to set the concentration of CF[0009] 2 or CF3, which is a polymer precursor in the plasma of the etching gas, to a value capable of ensuring a high etching selection ratio of the base salicide structure. Therefore, the surfaces of the electrodes of the salicide structure are disadvantageously scraped off by the etching.
  • FIG. 7 is a sectional view for illustrating the problem caused when forming contact holes by conventional etching with CHF[0010] 3 gas or CF4 gas through a high-concentration plasma device. Referring to FIG. 7, an element isolation film 112 is formed on a prescribed region of the surface of a semiconductor substrate 101 in a conventional semiconductor device. A source electrode 102 and a drain electrode 103 serving as impurity active regions are formed on an active region (element forming region) enclosed with the element isolation film 112 at a prescribed interval to hold a channel region 104 therebetween. A gate electrode 106 is formed on the channel region 104 through a gate insulator film 105. Salicide layers 102 s, 103 s and 106 s are formed on the surfaces of the source electrode 102, the drain electrode 103 and the gate electrode 106 respectively. Further, an interlayer isolation film 109 of silicon oxide (SiO2) is formed to cover the overall surface. The interlayer isolation film 109 is formed with contact holes 110 reaching the source electrode 102, the drain electrode 103 and the gate electrode 106 respectively.
  • When the [0011] contact holes 110 are formed in the interlayer isolation film 109 by etching with CHF3 gas or CF4 gas through a high-concentration plasma device in order to suppress a microloading effect (irregular etching) in this structure, the surfaces of the electrodes 102, 103 and 106 having the salicide structure are also etched. This is because it is difficult to set the concentration of CF2 or CF3, which is a polymer precursor in the plasma of the etching gas, to a value capable of ensuring a high etching selection ratio of the base salicide layers 102 s, 103 s and 106 s, as hereinabove described.
  • As described above, it is generally difficult to compatibly suppress the microloading effect (irregular etching) and over-etching in formation of the [0012] contact holes 110 requiring a high aspect ratio. This problem is not restricted to the case of forming contact holes on a salicide structure but similarly arises also in formation of contact holes provided in an insulator film for attaining electrical contact between a lower conductive part and an upper conductive part.
  • SUMMARY OF THE INVENTION
  • An object of the present invention is to provide a semiconductor device capable of compatibly suppressing a microloading effect (irregular etching) and over-etching in formation of a fine contact hole requiring a high aspect ratio. [0013]
  • Another object of the present invention is to provide a semiconductor device capable of automatically reducing an etching rate before an opening reaches a lower conductive part. [0014]
  • Still another object of the present invention is to provide a method of fabricating a semiconductor device capable of compatibly suppressing a microloading effect (irregular etching) and over-etching. [0015]
  • A semiconductor device according to an aspect of the present invention comprises a first conductive part, an insulator film having an opening formed on the first conductive part and a second conductive part electrically connected to the first conductive part through the opening, and the insulator film includes an upper insulator film and a lower insulator film, stacked/formed at least around a connection part between the first conductive part and the second conductive part, consisting of different materials. [0016]
  • In the semiconductor device according to the aforementioned aspect, the upper insulator film and the lower insulator film consisting of different materials are stacked/formed at least around the connection part between the first conductive part and the second conductive part, so that the etching rate is automatically reduced when etching for forming the opening reaches the lower insulator film from the upper insulator film if the lower insulator film is prepared from a material having a higher etching selection ratio than the upper insulator film, for example. Thus, also when employing etching through a high-concentration plasma device with which a high etching selection ratio of the first conductive part is hard to attain for suppressing a microloading effect (irregular etching), the first conductive part can be prevented from over-etching. Consequently, a semiconductor device capable of compatibly suppressing the microloading effect and over-etching in formation of a fine contact hole requiring a high aspect ratio can be provided. [0017]
  • In the semiconductor device according to the aforementioned aspect, the lower insulator film preferably contains a material having a higher etching selection ratio than the upper insulator film. Thus, the etching rate can be readily automatically reduced when etching for forming the opening reaches the lower insulator film from the upper insulator film. [0018]
  • The etching rate is automatically reduced when the etching reaches the lower insulator film from the upper insulator film for the following reason: It is well known that anisotropy of etching for vertically forming an opening in an insulator film is improved by performing the etching with formation of a side wall protective film on the inner peripheral surface of the opening. This side wall protective film is formed by an etched member, a polymerization film from the etching gas component or a reaction product thereof adhering to the inner peripheral surface of the opening. The side wall protective film has an effect of hindering transverse progress of the etching. It has been confirmed that an effect similar to this side wall protection effect is attained also when vertically progressing etching reaches a member (having a high selection ratio) harder to etch than the insulator film to be etched. In other words, a film similar to the aforementioned side wall protective film tends to be formed also on the upper surface of the lower insulator film having a high etching selection ratio. According to the present invention, the lower insulator film having a high etching selection ratio is provided under the upper insulator film through the aforementioned property, whereby the first conductive part can be prevented from over-etching also when etching is performed through a high-concentration plasma device with which a high etching selection ratio of the first conductive part is hard to attain for suppressing the microloading effect (irregular etching). [0019]
  • In this case, the first conductive part preferably contains a material having a higher etching selection ratio than the lower insulator film. Thus, the first conductive part can be more effectively prevented from over-etching. In this case, the first conductive part may include a silicified element electrode, the lower insulator film may include a silicon nitride film, and the upper insulator film may include a silicon oxide film. Further, the element electrode may include a silicified gate electrode, a silicified source electrode and a silicified drain electrode. [0020]
  • In the aforementioned case, the silicon nitride film is formed to be in contact with areas of the surfaces of the silicified electrodes except those exposed in the opening. Thus, the etching rate is further reduced by the surfaces of the silicified electrodes immediately after being reduced by the silicon nitride film. Therefore, the surfaces of the silicified electrodes can be more effectively prevented from over-etching. In the aforementioned case, the lower insulator film may include an SOG film. [0021]
  • A method of fabricating a semiconductor device according to another aspect of the present invention comprises steps of forming an insulator film including a multilayer film of an upper insulator film and a lower insulator film having a higher etching selection ratio than the upper insulator film on a first conductive part, etching the insulator film thereby forming an opening reaching the first conductive part, and forming a second conductive part connected with the first conductive part through the opening. [0022]
  • In the method of fabricating a semiconductor device according to the aforementioned aspect, the insulator film including the multilayer film of the upper insulator film and the lower insulator film having a higher etching selection ratio than the upper insulator film is etched for forming the opening reaching the first conductive part, so that the etching rate is automatically reduced when etching for forming the opening reaches the lower insulator film from the upper insulator film. Thus, also when employing etching through a high-concentration plasma device with which a high etching selection ratio of the first conductive part is hard to attain for suppressing a microloading effect (irregular etching), the first conductive part can be prevented from over-etching. Consequently, the microloading effect and over-etching can be compatibly suppressed in formation of a fine contact hole requiring a high aspect ratio. [0023]
  • In the method of fabricating a semiconductor device according to the aforementioned aspect, the first conductive part preferably contains a material having a higher etching selection ratio than the lower insulator film. Thus, the first conductive part can be more effectively prevented from over-etching. [0024]
  • The method of fabricating a semiconductor device according to the aforementioned aspect may preferably further comprise a step of silicifying the first conductive part in advance of the step of forming the insulator film. Thus, the silicified surface has a higher etching selection ratio than the lower insulator film, whereby the first conductive part can be more effectively prevented from over-etching. In this case, the first conductive part may include a gate electrode, a source electrode and a drain electrode, and the step of silicifying the first conductive part may include a step of silicifying the surfaces of the gate electrode, the source electrode and the drain electrode. Thus, the silicified surfaces of the gate, source and drain electrodes of the semiconductor device can be more effectively prevented from over-etching in etching for forming the opening. [0025]
  • In the method of fabricating a semiconductor device according to the aforementioned aspect, the lower insulator film preferably includes a silicon nitride film, the upper insulator film preferably includes a silicon oxide film, and the step of forming the opening preferably includes a step of forming the opening by etching the upper insulator film and the lower insulator film by dry etching with gas having a composition of C[0026] xHyFz. In this case, the gas consisting of CxHyFz preferably includes gas consisting of C4H8.
  • In this case, further, the silicon nitride film forming the lower insulator film is preferably formed to be in contact with the surface of the first conductive part. Thus, the surface of the first conductive part is exposed immediately after the etching rate is reduced by the silicon nitride film in etching for forming the opening, whereby the surface of the first conductive part can be prevented from over-etching. [0027]
  • In the method of fabricating a semiconductor device according to the aforementioned aspect, the step of forming the opening is preferably carried out by dry etching through a high-concentration plasma device. Further, the lower insulator film may include an SOG film. [0028]
  • The foregoing and other objects, features, aspects and advantages of the present invention will become more apparent from the following detailed description of the present invention when taken in conjunction with the accompanying drawings.[0029]
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a sectional view showing the structure of a semiconductor device according to an embodiment of the present invention; [0030]
  • FIGS. [0031] 2 to 4 are sectional views for illustrating a fabrication process for the semiconductor device according to the embodiment shown in FIG. 1;
  • FIG. 5 is a graph showing results of element analysis of substances deposited on salicide layers after formation of contact holes in the semiconductor device according to the embodiment provided with a silicon nitride film; [0032]
  • FIG. 6 is a graph showing results of element analysis of substances deposited on salicide layers after formation of contact holes in a conventional semiconductor device provided with no silicon nitride film; and [0033]
  • FIG. 7 is a sectional view for illustrating a problem in a conventional semiconductor device. [0034]
  • DESCRIPTION OF THE PREFERRED EMBODIMENTS
  • An embodiment of the present invention is now described with reference to the drawings. [0035]
  • FIG. 1 shows an embodiment of the inventive semiconductor device, which is applied to a MOS transistor. In the MOS transistor according to this embodiment, an [0036] element isolation film 12 is formed on a prescribed region of the surface of a semiconductor substrate 1 of silicon. A source electrode 2 and a drain electrode 3 serving as impurity active regions are formed on an active region (element forming region) enclosed with the element isolation film 12 at a prescribed interval to hold a channel region 4 therebetween. A gate electrode 6 is formed on the channel region 4 through a gate insulator film 5.
  • Salicide layers [0037] 6 s, 2 s and 3 s are formed on the surfaces of the gate electrode 6, the source electrode 2 and the drain electrode 3 in thicknesses of at least 5 nm respectively. Spacers 7 of silicon oxide (SiO2) are formed on the side surfaces of the gate electrode 6. A silicon nitride film (SiN) 8 is formed in a thickness of at least 5 nm, to cover the spacers 7. The silicon nitride film 8 is formed to cover the overall surface except regions formed with contact holes 10. More specifically, the silicon nitride film 8 is also formed on regions of the surfaces of the salicide layers 6 s, 2 s and 3 s except those exposed through the contact holes 10.
  • On the [0038] silicon nitride film 8, an interlayer isolation film 9 of silicon oxide (SiO2) is formed in a thickness of at least 10 nm to cover the overall surface. The contact holes 10 reaching the surfaces of the gate electrode 6, the source electrode 2 and the drain electrode 3 respectively are formed in the interlayer isolation film 9. Wires 11 are connected to the gate electrode 6, the source electrode 2 and the drain electrode 3 having a salicide structure through the contact holes 10 respectively.
  • The [0039] aforementioned spacers 7 of silicon oxide (SiO2) are provided for bringing only the upper surface of the gate electrode 6 and only necessary regions of the source electrode 2 and the drain electrode 3 into salicide states. Further, the salicide layers 2 s, 3 s and 6 s are formed on the surfaces of the source electrode 2, the drain electrode 3 and the gate electrode 6 as reaction films of titanium (Ti) respectively. Connection resistance can be remarkably reduced by connecting the wires 11 with the source electrode 2, the drain electrode 3 and the gate electrode 6 through the salicide layers 2 s, 3 s and 6 s.
  • The [0040] silicon nitride film 8 has a function of inhibiting the salicide layers 2 s, 3 s and 6 s from over-etching when forming the contact holes 10.
  • A method of fabricating the semiconductor device according to the embodiment shown in FIG. 1 is now described with reference to FIGS. [0041] 2 to 4.
  • First, the [0042] element isolation film 12 is formed on the prescribed region of the semiconductor substrate 1, as shown in FIG. 2. The source electrode 2 and the drain electrode 3 are formed on the active region (element forming region) enclosed with the element isolation film 12 at a prescribed interval to hold the channel region 4 therebetween. The gate electrode 6 is formed on the channel region 4 through the gate insulator film 5. The gate electrode 6, the source electrode 2 and the drain electrode 3 form the MOS transistor. Thereafter the spacers 7 of silicon oxide (SiO2) are formed on the side surfaces of the gate electrode 6.
  • Thereafter a titanium (Ti) film is formed by sputtering in a thickness of about 50 nm, for example, from above the [0043] semiconductor substrate 1. This titanium film is heated in a stream of N2 to about 800° C., thereby selectively silicifying the surfaces of the gate electrode 6, the source electrode 2 and the drain electrode 3. Thus, the salicide layers 6 s, 2 s and 3 s having thicknesses of at least 5 nm are formed in a self-aligned manner. The semiconductor substrate 1 is cooled and thereafter unreacted Ti is removed with an aqueous solution of NH4OH/H2O2O2.
  • Then, the [0044] silicon nitride film 8 is formed in a thickness of at least 5 nm to cover the overall surface. This silicon nitride film 8 is formed by LPCVD (low-pressure CVD) under the following conditions:
  • Material gas: 5×10[0045] −7 m3/s of dichlorosilane
  • 4.1×10[0046] −6 m3/s of ammonia
  • Pressure: 26.6 Pa [0047]
  • Temperature: 750° C. [0048]
  • The flow rate of each of the aforementioned material gas and ammonia is expressed in a volume (cubic meters) per unit time (seconds) in terms of a standard state. [0049]
  • Then, the [0050] interlayer isolation film 9 of silicon oxide is formed on the upper surface of the silicon nitride film 8 in a thickness of at least 10 nm, as shown in FIG. 3. The interlayer isolation film 9 is flattened and thereafter resist patterns 20 for forming the contact holes 10 are formed on prescribed regions of the upper surface of the interlayer isolation film 9. The interlayer isolation film 9 is dry-etched through the resist patterns 20 serving as masks, thereby forming the contact holes 10 as shown in FIG. 4. The dry etching for forming the contact holes 10 is performed through a high-concentration plasma device under the following conditions:
  • Etching gas: C[0051] 4F8/O2/Ar
  • Pressure: 9.3×10[0052] −1 Pa
  • Microwave: 1.5 kW [0053]
  • RF: 400 W [0054]
  • When the aforementioned etching for forming the contact holes [0055] 10 reaches the silicon nitride film 8 from the interlayer isolation film 9, the silicon nitride film 8 having a higher etching selection ratio than the interlayer isolation film 9 reduces the etching rate. Further, the salicide layers 6 s, 2 s and 3 s having a higher etching selection ratio than the silicon nitride film 8 further reduce the etching rate. Thus, the surfaces of the salicide layers 6 s, 2 s and 3 s can be effectively inhibited from over-etching in the etching for forming the contact holes 10. This point is now described in detail.
  • For the dry etching for forming the contact holes [0056] 10 in this embodiment, the high-concentration plasma device is employed mainly with etching gas of C4F8, as hereinabove described. In the etching through the high-concentration plasma device, ionized etching gas receives downward force from an electric field perpendicularly applied to the semiconductor substrate 1. The ionized gas collides with the interlayer isolation film 9, thereby scattering silicon oxide forming the interlayer isolation film 9 outward as gas layers. Thus, the contact holes 10 are defined.
  • At this time, the etching gas and a C—F based polymer formed in the process of reaction between the etching gas and silicon oxide adhere to the inner peripheral surfaces of the contact holes [0057] 10 formed in the interlayer isolation film 9. The adhering polymer defines side wall protective films. These side wall protective films inhibit the interlayer isolation film 9 from horizontal etching.
  • When carrying out the aforementioned dry etching for forming the contact holes [0058] 10 with CHF3 gas or CF4 gas through a low-concentration plasma device, it is difficult to suppress a microloading effect (irregular etching) as the aspect ratio of the contact holes 10 is increased. According to this embodiment, therefore, the etching is carried out through the high-concentration plasma device.
  • In the etching with CHF[0059] 3 gas or CF4 gas through a high-concentration plasma device, however, it is difficult to ensure high selection ratios of the base salicide layers 2 s, 3 s and 6 s, which in turn are disadvantageously over-etched in general.
  • According to this embodiment, therefore, the surfaces of the salicide layers [0060] 2 s, 3 s and 6 s are covered with the silicon nitride film 8 after formation thereof, thereby attaining an effect similar to the aforementioned side wall protection effect on the upper surfaces of the salicide layers 2 s, 3 s and 6 s. In other words, the silicon nitride film 8 having a higher selection ratio than silicon oxide forming the interlayer isolation film 9 is formed under the interlayer isolation film 9 when etching the interlayer isolation film 9 mainly with C4F8 gas, thereby prompting deposition of the C—F based polymer on the upper surface of the silicon nitride film 8. Thus, the etching rate is automatically reduced when the etching gas reaches the silicon nitride film 8, with no control related to the etching rate or the like.
  • The salicide layers [0061] 2 s, 3 s and 6 s have a higher etching selection ratio than the silicon nitride film 8, and hence reduction of the etching rate more remarkably appears on the salicide layers 2 s, 3 s and 6 s. In other words, deposition of the C—F based polymer on the upper surfaces of the salicide layers 2 s, 3 s and 6 s is prompted. Thus, the salicide layers 2 s, 3 s and 6 s can be more effectively prevented from over-etching. Consequently, the contact holes 10 can be formed without passing through the salicide layers 2 s, 3 s and 6 s by over-etching.
  • After forming the contact holes [0062] 10 in the aforementioned manner, the resist patterns 20 are removed. Finally, the wires 11 are formed in the contact holes 10 as shown in FIG. 1, thereby completing the semiconductor device according to this embodiment.
  • Substances deposited on the salicide layers [0063] 2 s, 3 s and 6 s after formation of the contact holes 10 are now described with reference to FIGS. 5 and 6. Referring to each of FIGS. 5 and 6, the horizontal axis shows chemical bond energy of each substance, and the vertical axis shows the ratio (count) of the chemical bond energy. In each graph, element analysis inclusive of the chemical composition is enabled by independently counting the ratio of the substance corresponding to each chemical bond energy. Referring to FIGS. 5 and 6, broken lines show theoretical values, and solid lines show actually measured values.
  • FIG. 5 shows results of element analysis of substances deposited on the salicide layers [0064] 2 s, 3 s and 6 s after formation of the contact holes 10 in the semiconductor device according to this embodiment provided with the silicon nitride film 8. FIG. 6 shows results of element analysis of substances deposited on salicide layers after formation of contact holes in a conventional semiconductor device provided with no silicon nitride film 8. It is understood from FIGS. 5 and 6 that a large quantity of C—F based polymer is deposited on the salicide layers 2 s, 3 s and 6 s when performing etching with provision of the silicon nitride film 8, as compared with the case of performing etching with no provision of the silicon nitride film 8. Therefore, it is understood possible to effectively reduce the etching rate on the salicide layers 2 s, 3 s and 6 s.
  • When forming the [0065] wires 11 through the contact holes 10, the substances deposited on the salicide layers 2 s, 3 s and 6 s are removed. The substances deposited on the salicide layers 2 s, 3 s and 6 s are removed by oxygen plasma treatment, for example. This oxygen plasma treatment is performed under conditions of a reaction chamber pressure of 10 mT, microwave power (2.45 GHz) of 1500 W, a substrate bias of 400 W and an O2 flow rate of 100 sccm. The substances deposited on the salicide layers 2 s, 3 s and 6 s may alternatively be removed by ashing such as ozone ashing or down-flow ashing.
  • In the fabrication method according to this embodiment, as hereinabove described, etching can be stopped in the salicide layers [0066] 2 s, 3 s and 6 s without extremely reducing the etching rate when forming the contact holes 10, by providing the silicon nitride film 8 having a higher etching selection ratio than the interlayer isolation film 9 of silicon oxide on the salicide layers 2 s, 3 s and 6 s. Thus, the contact holes 10 can be formed without passing through the salicide layers 2 s, 3 s and 6 s.
  • Further, the etching can be readily performed with high precision by employing the [0067] silicon nitride film 8 generally employed as an insulator film as a film having a higher etching selection ratio than the interlayer isolation film 9.
  • Although the present invention has been described and illustrated in detail, it is clearly understood that the same is by way of illustration and example only and is not to be taken by way of limitation, the spirit and scope of the present invention being limited only by the terms of the appended claims. [0068]
  • For example, the aforementioned salicide layers [0069] 2 s, 3 s and 6 s may alternatively be formed by a method other than that described with reference to the aforementioned embodiment. Further, the aforementioned film forming method, thicknesses and etching conditions are properly changeable.
  • While the [0070] silicon nitride film 8 is employed as the film having a higher selection ratio than the interlayer isolation film 9 in the aforementioned embodiment, the present invention is not restricted to this but another film such as an SOG film, for example, may be employed.
  • While the etching gas for etching the contact holes [0071] 10 is mainly composed of C4F8 in the aforementioned embodiment, the present invention is not restricted to this but another etching gas may be employed. For example, the etching gas may be mainly composed of arbitrary gas having a composition expressed as CxHyFz.
  • While the [0072] interlayer isolation film 9 is etched with the gas mainly composed of C4F8 through the high-concentration plasma device in the aforementioned embodiment, the present invention is not restricted to this but another etching may be employed. In other words, the interlayer isolation film 9 may be etched by any method so far as a film having a higher selection ratio than the interlayer isolation film 9 with respect to the employed etching gas is formed between the interlayer isolation film 9 and the silicide films thereby inhibiting the silicide films from over-etching due to an effect similar to the side wall protection effect.
  • The [0073] gate electrode 6, the source electrode 2 and the drain electrode 3 may not necessarily have a silicide structure.
  • While the [0074] electrodes 2, 3 and 6 and the wires 11 are connected with each other through the contact holes 10 in the aforementioned embodiment, the present invention is not restricted to this but is also applicable to a structure of connecting wires with each other through contact holes. In this case, lower wires can be inhibited from over-etching when forming the contact holes in an interlayer isolation film by forming a film having a higher selection ratio than the interlayer isolation film between the interlayer isolation film and the lower wires.
  • The electrodes or the wires located under the contact holes may not necessarily have a higher etching selection ratio than the film formed on the surfaces thereof. [0075]
  • While the [0076] semiconductor substrate 1 consists of silicon in the aforementioned embodiment, the present invention is not restricted to this but the semiconductor substrate may consist of a silicon-germanium alloy, silicon carbide, germanium, cadmium selenide, cadmium sulfide or gallium arsenide.

Claims (16)

What is claimed is:
1. A semiconductor device comprising:
a first conductive part;
an insulator film having an opening formed on said first conductive part; and
a second conductive part electrically connected to said first conductive part through said opening, wherein
said insulator film includes an upper insulator film and a lower insulator film, stacked/formed at least around a connection part between said first conductive part and said second conductive part, consisting of different materials.
2. The semiconductor device according to
claim 1
, wherein
said lower insulator film contains a material having a higher etching selection ratio than said upper insulator film.
3. The semiconductor device according to
claim 2
, wherein
said first conductive part contains a material having a higher etching selection ratio than said lower insulator film.
4. The semiconductor device according to
claim 3
, wherein
said first conductive part includes a silicified element electrode,
said lower insulator film includes a silicon nitride film, and
said upper insulator film includes a silicon oxide film.
5. The semiconductor device according to
claim 4
, wherein
said element electrode includes a silicified gate electrode, a silicified source electrode and a silicified drain electrode.
6. The semiconductor device according to
claim 4
, wherein
said silicon nitride film is formed to be in contact with areas of the surfaces of said silicified electrodes except those exposed in said opening.
7. The semiconductor device according to
claim 2
, wherein
said lower insulator film includes an SOG film.
8. A method of fabricating a semiconductor device, comprising steps of:
forming an insulator film including a multilayer film of an upper insulator film and a lower insulator film having a higher etching selection ratio than said upper insulator film on a first conductive part;
etching said insulator film thereby forming an opening reaching said first conductive part; and
forming a second conductive part connected with said first conductive part through said opening.
9. The method of fabricating a semiconductor device according to
claim 8
, wherein
said first conductive part contains a material having a higher etching selection ratio than said lower insulator film.
10. The method of fabricating a semiconductor device according to
claim 8
, further comprising a step of silicifying said first conductive part in advance of said step of forming said insulator film.
11. The method of fabricating a semiconductor device according to
claim 10
, wherein
said first conductive part includes a gate electrode, a source electrode and a drain electrode, and
said step of silicifying said first conductive part includes a step of silicifying the surfaces of said gate electrode, said source electrode and said drain electrode.
12. The method of fabricating a semiconductor device according to
claim 8
, wherein
said lower insulator film includes a silicon nitride film,
said upper insulator film includes a silicon oxide film, and
said step of forming said opening includes a step of forming said opening by etching said upper insulator film and said lower insulator film by dry etching with gas having a composition of CxHyFz.
13. The method of fabricating a semiconductor device according to
claim 12
, wherein
said gas consisting of CxHyFz includes gas consisting of C4H8.
14. The method of fabricating a semiconductor device according to
claim 12
, wherein
said silicon nitride film forming said lower insulator film is formed to be in contact with the surface of said first conductive part.
15. The method of fabricating a semiconductor device according to
claim 8
, wherein
said step of forming said opening is carried out by dry etching through a high-concentration plasma device.
16. The method of fabricating a semiconductor device according to
claim 8
, wherein
said lower insulator film includes an SOG film.
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US20210217798A1 (en) * 2020-01-15 2021-07-15 United Microelectronics Corp. Semiconductor image sensor device and fabrication method thereof
US11538844B2 (en) * 2020-01-15 2022-12-27 United Microelectronics Corp. Semiconductor image sensor device and fabrication method thereof
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