US20010018826A1 - Device for catalytic exhaust gas purification - Google Patents
Device for catalytic exhaust gas purification Download PDFInfo
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- US20010018826A1 US20010018826A1 US09/781,207 US78120701A US2001018826A1 US 20010018826 A1 US20010018826 A1 US 20010018826A1 US 78120701 A US78120701 A US 78120701A US 2001018826 A1 US2001018826 A1 US 2001018826A1
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- Prior art keywords
- exhaust gas
- space
- injection
- reagent
- exhaust
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
- F01N3/2066—Selective catalytic reduction [SCR]
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N1/00—Silencing apparatus characterised by method of silencing
- F01N1/24—Silencing apparatus characterised by method of silencing by using sound-absorbing materials
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2882—Catalytic reactors combined or associated with other devices, e.g. exhaust silencers or other exhaust purification devices
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2230/00—Combination of silencers and other devices
- F01N2230/04—Catalytic converters
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2240/00—Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being
- F01N2240/20—Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being a flow director or deflector
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2470/00—Structure or shape of gas passages, pipes or tubes
- F01N2470/02—Tubes being perforated
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2610/00—Adding substances to exhaust gases
- F01N2610/02—Adding substances to exhaust gases the substance being ammonia or urea
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Definitions
- the invention lies in the field of catalytic converters.
- the invention relates to a device for the catalytic removal of a pollutant from the exhaust gas of a combustion system, such as a fossil-fired power plant or an internal combustion engine.
- the combustion system has an exhaust-gas duct for carrying the exhaust gas and an injection device for introducing a reagent into the exhaust gas in an injection space of the exhaust-gas duct.
- a catalytic converter is installed in the exhaust-gas duct.
- the injection space and a mixing space are configured as a muffler.
- the mixing space is connected downstream if appropriate and is provided for the purpose of mixing the reagent with the exhaust gas.
- a catalytic removal device is disclosed, for example, in European Patent Application 0 779 415 A1.
- a combustion system of this kind can include a boiler system or a fossil-fired power plant, for example, or even an internal combustion engine.
- the prior art includes DeNOx catalysts for reducing the quantity of nitrogen oxides.
- Such catalysts convert the nitrogen oxides (NOx) contained in the exhaust gas by a reducing agent, generally ammonia or urea, into environmentally neutral nitrogen and water by the process known as selective catalytic reduction (SCR).
- SCR selective catalytic reduction
- the reducing agent is introduced into the exhaust gas ahead of the catalytic converter in the direction of flow of the exhaust gas.
- the reducing agent then enters the catalytic converter, as far as possible as a homogeneous mixture with the nitrogen oxides contained in the exhaust gas. It is also possible in this context for a number of catalytic converters to be disposed in series.
- the prior art For reducing the quantity of pollutants in the exhaust gas of an Otto engine, the prior art includes catalysts containing noble metals, for example, on which hydrocarbons and carbon monoxide together with nitrogen oxides are converted into carbon dioxide, nitrogen, and/or water.
- the above mentioned DeNOx catalyst can be used to remove nitrogen oxides from the exhaust gas of a diesel engine.
- urea is preferably used.
- the urea is injected into the flow of exhaust gas in a manner appropriate to the application. With such an electronically controlled diesel catalytic converter, it is possible to reduce considerably the level of nitrogen oxides in the exhaust gas of the diesel engine.
- An SCR device for the catalytic removal of NOx in the exhaust gas of a combustion system is first of all required to effect a significant and effective reduction in NOx emissions. It is also generally required to reduce sound emissions. The sound results from the operation of the combustion system and represents a problem for the environment. At the same time, there is a demand for minimizing the space required. To reduce sound emissions, provision has hitherto been made for the installation of a separate muffler in the exhaust-gas duct. The separate muffler made it possible to reduce sound emissions to below the permissible limits. However, there are noticeable disadvantages with the muffler solution, to wit, additional costs, an increased pressure drop, and a larger space requirement.
- the invention is based on the consideration that the objective can be achieved if different functions can be combined in an already existing component.
- a device for catalytic removal of a pollutant from an exhaust gas of a combustion system including an exhaust-gas duct for carrying exhaust gas, a reagent, a muffler having an injection space and a mixing space for mixing the reagent with the exhaust gas, an injection device for introducing the reagent into the exhaust gas in the injection space, at least one catalytic converter disposed in the exhaust-gas duct, and mixers disposed at least one of before and after the injection space with respect to a direction of flow of the exhaust gas, the mixers defining a distance therebetween, the distance matched to a frequency of sound to be damped in the exhaust gas.
- the combustion system is a fossil-fired power plant or an internal combustion engine.
- An advantage of such solution is that it is possible to construct an SCR catalytic converter system for the exhaust gas of a combustion system in a very compact and economical manner because the injection and mixing space are configured as a muffler.
- the injection space and/or the mixing space can then be lined with a perforated plate or a thin, flexible single- or double-layer plate.
- the injection space and/or the mixing space is/are preferably provided with a sound-deadening lining.
- the mixing space is disposed downstream of the injection space.
- the perforated plate, the flexible single-layer plate, and/or the flexible double-layer plate are backed with a sound-absorbing material selected from the group consisting of steel wool, ceramic wool, steel web, and fiber web.
- the exhaust gas duct has an inlet part and a 180° deflection for the exhaust gas, and the 180° deflection is disposed between the inlet part and the at least one catalytic converter, and including at least one of a reflection damper and a absorption damper disposed in a region of the 180° deflection.
- the injection space and the mixing space form a constructional or structural unit.
- the structural unit has an inflow side and an outflow side and at least one of the inflow side and the outflow side is a pipe resonator.
- the 180° deflection is disposed on the outflow side of the structural unit.
- the injection device has a nozzle and a jacketing tube in a region at the nozzle, and the jacketing tube is aligned in a direction of flow of the exhaust gas.
- FIG. 1 is a diagrammatic cross-sectional view of a vertical SCR system with a vertical injection and mixing space and 180° deflection of the exhaust gas according to the invention.
- FIG. 2 is a diagrammatic cross-sectional view of a tubular injection and mixing space with various refinements for sound deadening according to the invention.
- FIG. 1 there is shown exhaust gas A containing NOx, that is preliminarily deflected through 90° in the exhaust-gas duct 8 and passed from below into a structural unit 2 that, in turn, is provided with a sound-deadening lining 20 and a perforated plate 22 .
- An injection device 10 with a nozzle 12 leads into the injection space 4 .
- the injection device 10 is provided for introducing a reducing agent or reagent R into the exhaust gas A in the injection space 4 .
- the downstream mixing space 6 serves to mix the reagent R introduced with the exhaust gas A.
- Ammonia or urea can be used as a reagent R, for example.
- the reducing agent or reagent R can be injected in a pure form (liquid or gaseous) or in solution (e.g., with water or steam).
- the tubular structural unit 2 shown in FIG. 1, including the injection space 4 and the mixing space 6 is vertical.
- the exhaust gas A undergoes a 180° deflection in a deflection space 23 and, in the downstream space 14 or SCR reactor, enters two SCR catalytic converters 16 , 18 in series.
- the purified exhaust gas A′ leaves the device after a 90° deflection.
- Mixers 24 and 26 are disposed at the inlet and outlet of the structural unit 2 .
- baffles 28 are provided in the upper deflection space 23 .
- the abovementioned lining of the injection and mixing space 4 , 6 with the perforated plate 22 can be provided.
- the perforated plate 22 it is also possible to use a thin, flexible plate.
- the perforated plate 22 is backed with an absorbent material, such as steel wool, ceramic wool, steel web, or fiber web, as a lining 20 .
- the distance between the mixers 24 , 26 is matched to the sound frequency to be damped.
- reflection damping is provided at the 180° deflection of the exhaust gas A between the structural unit 2 and the SCR reactor 14 .
- the reflection damping is shown in the form of a sound-deadening lining 30 on the upper inner wall.
- the deflection does not necessarily have to be exactly 180°. Any deflection that allows reflection of the sound into upstream parts of the system can be employed. With appropriate lining of the deflection, upstream sound reflection is possible even with deflections of less than 90°.
- FIG. 2 illustrates a number of possibilities for the embodiment of the combined structural unit 2 containing the injection space 4 and the mixing space 6 .
- the features illustrated need not necessarily all be present at the same time.
- the inflow side and the outflow side of the structural unit 2 of FIG. 2 are constructed as pipe resonators 32 and 34 . They are tuned to the sound frequency to be damped.
- the structural unit 2 is provided with a sound-deadening lining 20 over the entire length of the tube. Its material and thickness are likewise matched to the sound frequency to be damped. In the region of the mixing space 6 there is a perforated plate 22 .
- the size of the holes and the length of the section incorporating the perforated plate 22 are matched to the sound frequency to be damped.
- the tube 38 can be two-layers with an air gap between the two layers.
- the distance between the two mixers 24 and 26 is matched to the sound frequency.
- Reference numeral 37 denotes a backing of the perforated plate 22 .
- the backing 37 is an abrasion-resistant material that is temperature-stable and does not allow any discharge through the perforated plate 22 .
- a jacketing tube 40 is provided in the region of the nozzle 12 .
- the tube 40 is thin-walled. It can also have a two-layer construction with an air gap between the layers.
- a holder 42 in the interior holds he jacketing tube 40 .
- the jacketing tube is aligned in the direction of flow of the exhaust gas A.
Abstract
A device for catalytic removal of a pollutant from an exhaust gas of a combustion system, particularly, a fossil-fired power plant or an internal combustion engine, includes an exhaust-gas duct for carrying exhaust gas, a reagent, a muffler having an injection space and a mixing space for mixing the reagent with the exhaust gas, an injection device for introducing the reagent into the exhaust gas in the injection space, at least one catalytic converter disposed in the exhaust-gas duct, and mixers disposed at least one of before and after the injection space with respect to a direction of flow of the exhaust gas. The mixers define a distance therebetween, and the distance is matched to a frequency of sound to be damped in the exhaust gas. According to the invention, the injection chamber and the downstream mixture chamber are embodied as a muffler in order to reduce the emissions of sound while enabling the production of a device having a compact structure.
Description
- This application is a continuation of copending International Application No. PCT/DE99/02350, filed Jul. 30, 1999, which designated the United States.
- 1. Field of the Invention
- The invention lies in the field of catalytic converters. The invention relates to a device for the catalytic removal of a pollutant from the exhaust gas of a combustion system, such as a fossil-fired power plant or an internal combustion engine. The combustion system has an exhaust-gas duct for carrying the exhaust gas and an injection device for introducing a reagent into the exhaust gas in an injection space of the exhaust-gas duct. A catalytic converter is installed in the exhaust-gas duct. The injection space and a mixing space are configured as a muffler. The mixing space is connected downstream if appropriate and is provided for the purpose of mixing the reagent with the exhaust gas.
- A catalytic removal device is disclosed, for example, in European Patent Application 0 779 415 A1.
- When a fossil fuel is burnt in a combustion system, considerable quantities of pollutants, such as nitrogen oxides (NOx), hydrocarbons, carbon monoxide, and oxides of sulfur, are formed. If the combustion temperatures are high enough, dioxins and furans are also formed. These pollutants can enter the environment through the exhaust gas from the combustion system. A combustion system of this kind can include a boiler system or a fossil-fired power plant, for example, or even an internal combustion engine.
- Due to strict legal requirements that limit emissions of the above mentioned pollutants, it is necessary to treat the exhaust gas from combustion systems for reducing the quantity of pollutants it contains. Many different catalytic converters have been developed for such a purpose. Thus, for example, the prior art includes DeNOx catalysts for reducing the quantity of nitrogen oxides. Such catalysts convert the nitrogen oxides (NOx) contained in the exhaust gas by a reducing agent, generally ammonia or urea, into environmentally neutral nitrogen and water by the process known as selective catalytic reduction (SCR). The reducing agent is introduced into the exhaust gas ahead of the catalytic converter in the direction of flow of the exhaust gas. The reducing agent then enters the catalytic converter, as far as possible as a homogeneous mixture with the nitrogen oxides contained in the exhaust gas. It is also possible in this context for a number of catalytic converters to be disposed in series.
- For reducing the quantity of pollutants in the exhaust gas of an Otto engine, the prior art includes catalysts containing noble metals, for example, on which hydrocarbons and carbon monoxide together with nitrogen oxides are converted into carbon dioxide, nitrogen, and/or water.
- The above mentioned DeNOx catalyst can be used to remove nitrogen oxides from the exhaust gas of a diesel engine. Here, urea is preferably used. The urea is injected into the flow of exhaust gas in a manner appropriate to the application. With such an electronically controlled diesel catalytic converter, it is possible to reduce considerably the level of nitrogen oxides in the exhaust gas of the diesel engine.
- An SCR device for the catalytic removal of NOx in the exhaust gas of a combustion system is first of all required to effect a significant and effective reduction in NOx emissions. It is also generally required to reduce sound emissions. The sound results from the operation of the combustion system and represents a problem for the environment. At the same time, there is a demand for minimizing the space required. To reduce sound emissions, provision has hitherto been made for the installation of a separate muffler in the exhaust-gas duct. The separate muffler made it possible to reduce sound emissions to below the permissible limits. However, there are noticeable disadvantages with the muffler solution, to wit, additional costs, an increased pressure drop, and a larger space requirement.
- It is accordingly an object of the invention to provide a device for catalytic exhaust-gas purification that overcomes the hereinafore-mentioned disadvantages of the heretofore-known devices of this general type and that requires no unnecessary space for a separate muffler and further reduces sound emissions.
- The invention is based on the consideration that the objective can be achieved if different functions can be combined in an already existing component.
- With the foregoing and other objects in view, there is provided, in accordance with the invention, a device for catalytic removal of a pollutant from an exhaust gas of a combustion system, including an exhaust-gas duct for carrying exhaust gas, a reagent, a muffler having an injection space and a mixing space for mixing the reagent with the exhaust gas, an injection device for introducing the reagent into the exhaust gas in the injection space, at least one catalytic converter disposed in the exhaust-gas duct, and mixers disposed at least one of before and after the injection space with respect to a direction of flow of the exhaust gas, the mixers defining a distance therebetween, the distance matched to a frequency of sound to be damped in the exhaust gas. Particularly, the combustion system is a fossil-fired power plant or an internal combustion engine.
- An advantage of such solution is that it is possible to construct an SCR catalytic converter system for the exhaust gas of a combustion system in a very compact and economical manner because the injection and mixing space are configured as a muffler. For noise damping, the injection space and/or the mixing space can then be lined with a perforated plate or a thin, flexible single- or double-layer plate. The injection space and/or the mixing space is/are preferably provided with a sound-deadening lining.
- In accordance with another feature of the invention, the mixing space is disposed downstream of the injection space.
- In accordance with an added feature of the invention, the perforated plate, the flexible single-layer plate, and/or the flexible double-layer plate are backed with a sound-absorbing material selected from the group consisting of steel wool, ceramic wool, steel web, and fiber web.
- In accordance with an additional feature of the invention, the exhaust gas duct has an inlet part and a 180° deflection for the exhaust gas, and the 180° deflection is disposed between the inlet part and the at least one catalytic converter, and including at least one of a reflection damper and a absorption damper disposed in a region of the 180° deflection.
- In accordance with yet another feature of the invention, the injection space and the mixing space form a constructional or structural unit.
- In accordance with yet a further feature of the invention, the structural unit has an inflow side and an outflow side and at least one of the inflow side and the outflow side is a pipe resonator.
- In accordance with yet an added feature of the invention, the 180° deflection is disposed on the outflow side of the structural unit.
- In accordance with a concomitant feature of the invention, the injection device has a nozzle and a jacketing tube in a region at the nozzle, and the jacketing tube is aligned in a direction of flow of the exhaust gas.
- Other features that are considered as characteristic for the invention are set forth in the appended claims.
- Although the invention is illustrated and described herein as embodied in a device for catalytic exhaust-gas purification, it is, nevertheless, not intended to be limited to the details shown because various modifications and structural changes may be made therein without departing from the spirit of the invention and within the scope and range of equivalents of the claims.
- The construction and method of operation of the invention, however, together with additional objects and advantages thereof, will be best understood from the following description of specific embodiments when read in connection with the accompanying drawings.
- FIG. 1 is a diagrammatic cross-sectional view of a vertical SCR system with a vertical injection and mixing space and 180° deflection of the exhaust gas according to the invention; and
- FIG. 2 is a diagrammatic cross-sectional view of a tubular injection and mixing space with various refinements for sound deadening according to the invention.
- In all the figures of the drawing, sub-features and integral parts that correspond to one another bear the same reference symbol in each case.
- Referring now to the figures of the drawings in detail and first, particularly to FIG. 1 thereof, there is shown exhaust gas A containing NOx, that is preliminarily deflected through 90° in the exhaust-gas duct8 and passed from below into a
structural unit 2 that, in turn, is provided with a sound-deadening lining 20 and aperforated plate 22. Aninjection device 10 with anozzle 12 leads into theinjection space 4. Theinjection device 10 is provided for introducing a reducing agent or reagent R into the exhaust gas A in theinjection space 4. Thedownstream mixing space 6 serves to mix the reagent R introduced with the exhaust gas A. Ammonia or urea can be used as a reagent R, for example. Generally speaking, the reducing agent or reagent R can be injected in a pure form (liquid or gaseous) or in solution (e.g., with water or steam). The tubularstructural unit 2 shown in FIG. 1, including theinjection space 4 and themixing space 6, is vertical. At the outlet of thestructural unit 2, the exhaust gas A undergoes a 180° deflection in adeflection space 23 and, in thedownstream space 14 or SCR reactor, enters two SCRcatalytic converters Mixers structural unit 2. To facilitate the 180° deflection, baffles 28 are provided in theupper deflection space 23. - In the embodiment of FIG. 1, a sound-deadening effect is achieved in various ways.
- First, the abovementioned lining of the injection and mixing
space perforated plate 22 can be provided. Instead of theperforated plate 22, it is also possible to use a thin, flexible plate. Theperforated plate 22 is backed with an absorbent material, such as steel wool, ceramic wool, steel web, or fiber web, as alining 20. - Second, reflection damping is provided between the
mixers mixers - Third, reflection damping is provided at the 180° deflection of the exhaust gas A between the
structural unit 2 and theSCR reactor 14. The reflection damping is shown in the form of a sound-deadeninglining 30 on the upper inner wall. - In the embodiment, further deflections are possible in the region of the injection and mixing
space - With regard to FIG. 1, the deflection does not necessarily have to be exactly 180°. Any deflection that allows reflection of the sound into upstream parts of the system can be employed. With appropriate lining of the deflection, upstream sound reflection is possible even with deflections of less than 90°.
- The embodiment of FIG. 2 illustrates a number of possibilities for the embodiment of the combined
structural unit 2 containing theinjection space 4 and the mixingspace 6. The features illustrated need not necessarily all be present at the same time. - The inflow side and the outflow side of the
structural unit 2 of FIG. 2 are constructed aspipe resonators structural unit 2 is provided with a sound-deadeninglining 20 over the entire length of the tube. Its material and thickness are likewise matched to the sound frequency to be damped. In the region of the mixingspace 6 there is aperforated plate 22. - Here, the size of the holes and the length of the section incorporating the
perforated plate 22 are matched to the sound frequency to be damped. Within thestructural unit 2 there is a thin-walledinner tube 38. Thetube 38 can be two-layers with an air gap between the two layers. Here, too, the distance between the twomixers -
Reference numeral 37 denotes a backing of theperforated plate 22. Thebacking 37 is an abrasion-resistant material that is temperature-stable and does not allow any discharge through theperforated plate 22. - In the embodiment in FIG. 2, a
jacketing tube 40 is provided in the region of thenozzle 12. Thetube 40 is thin-walled. It can also have a two-layer construction with an air gap between the layers. Aholder 42 in the interior holds he jacketingtube 40. The jacketing tube is aligned in the direction of flow of the exhaust gas A.
Claims (14)
1. A device for catalytic removal of a pollutant from an exhaust gas of a combustion system, comprising:
an exhaust-gas duct for carrying exhaust gas;
a reagent;
a muffler having an injection space and a mixing space for mixing said reagent with the exhaust gas;
an injection device for introducing said reagent into the exhaust gas in said injection space;
at least one catalytic converter disposed in said exhaust-gas duct; and
mixers disposed at least one of before and after said injection space with respect to a direction of flow of the exhaust gas, said mixers defining a distance therebetween, said distance matched to a frequency of sound to be damped in the exhaust gas.
2. The device according to , wherein said mixing space is disposed downstream of said injection space.
claim 1
3. The device according to , wherein at least one of said injection space and said mixing space is lined with at least one of a group consisting of a perforated plate, a thin, flexible single-layer plate, and a thin, flexible double-layer plate.
claim 1
4. The device according to , wherein said perforated plate is backed with a sound-absorbing material selected from the group consisting of steel wool, ceramic wool, steel web, and fiber web.
claim 3
5. The device according to , wherein said flexible single-layer plate is backed with a sound-absorbing material selected from the group consisting of steel wool, ceramic wool, steel web, and fiber web.
claim 3
6. The device according to , wherein said flexible double-layer plate is backed with a sound-absorbing material selected from the group consisting of steel wool, ceramic wool, steel web, and fiber web.
claim 3
7. The device according to , wherein said exhaust gas duct has an inlet part and a 180° deflection for the exhaust gas, and said 180° deflection is disposed between said inlet part and said at least one catalytic converter, and including at least one of a reflection damper and a absorption damper disposed in a region of said 180° deflection.
claim 1
8. The device according to , wherein said injection space and said mixing space form a structural unit.
claim 1
9. The device according to , wherein said structural unit has an inflow side and an outflow side and at least one of said inflow side and said outflow side is a pipe resonator.
claim 8
10. The device according to , wherein:
claim 1
said exhaust gas duct has an inlet part and a 180° deflection for the exhaust gas;
said 180° deflection is disposed between said inlet part and said at least one catalytic converter;
said injection space and said mixing space form a structural unit having an inflow side and an outflow side;
at least one of said inflow side and said outflow side is a pipe resonator; and
said 180° deflection is disposed on said outflow side of said structural unit.
11. The device according to , wherein at least one of said injection space and said mixing space has a sound-deadening lining.
claim 1
12. The device according to , wherein:
claim 1
said injection device has a nozzle and a jacketing tube in a region at said nozzle; and
said jacketing tube is aligned in a direction of flow of the exhaust gas.
13. A device for catalytic removal of a pollutant from an exhaust gas of a fossil-fired power plant, comprising:
an exhaust-gas duct for carrying exhaust gas;
a reagent;
a muffler having an injection space and a mixing space for mixing said reagent with the exhaust gas;
an injection device for introducing said reagent into the exhaust gas in said injection space;
at least one catalytic converter disposed in said exhaust-gas duct; and
mixers disposed at least one of before and after said injection space with respect to a direction of flow of the exhaust gas, said mixers defining a distance therebetween, said distance matched to a frequency of sound to be damped in the exhaust gas.
14. A device for catalytic removal of a pollutant from an exhaust gas of an internal combustion engine, comprising:
an exhaust-gas duct for carrying exhaust gas;
a reagent;
a muffler having an injection space and a mixing space for mixing said reagent with the exhaust gas;
an injection device for introducing said reagent into the exhaust gas in said injection space;
at least one catalytic converter disposed in said exhaust-gas duct; and
mixers disposed at least one of before and after said injection space with respect to a direction of flow of the exhaust gas, said mixers defining a distance therebetween, said distance matched to a frequency of sound to be damped in the exhaust gas.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19836355 | 1998-08-11 | ||
DE19836355 | 1998-08-11 | ||
DE19836355.9 | 1998-08-11 | ||
PCT/DE1999/002350 WO2000009869A1 (en) | 1998-08-11 | 1999-07-30 | Device for catalytic exhaust gas purification |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/DE1999/002350 Continuation WO2000009869A1 (en) | 1998-08-11 | 1999-07-30 | Device for catalytic exhaust gas purification |
Publications (2)
Publication Number | Publication Date |
---|---|
US20010018826A1 true US20010018826A1 (en) | 2001-09-06 |
US6442933B2 US6442933B2 (en) | 2002-09-03 |
Family
ID=7877192
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/781,207 Expired - Fee Related US6442933B2 (en) | 1998-08-11 | 2001-02-12 | Device for catalytic exhaust gas purification |
Country Status (9)
Country | Link |
---|---|
US (1) | US6442933B2 (en) |
EP (1) | EP1108122B1 (en) |
JP (1) | JP2002522703A (en) |
KR (1) | KR20010072389A (en) |
AT (1) | ATE214783T1 (en) |
DE (1) | DE59901031D1 (en) |
DK (1) | DK1108122T3 (en) |
ES (1) | ES2174642T3 (en) |
WO (1) | WO2000009869A1 (en) |
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-
1999
- 1999-07-30 EP EP99950473A patent/EP1108122B1/en not_active Expired - Lifetime
- 1999-07-30 ES ES99950473T patent/ES2174642T3/en not_active Expired - Lifetime
- 1999-07-30 DK DK99950473T patent/DK1108122T3/en active
- 1999-07-30 KR KR1020017001750A patent/KR20010072389A/en not_active Application Discontinuation
- 1999-07-30 DE DE59901031T patent/DE59901031D1/en not_active Expired - Fee Related
- 1999-07-30 JP JP2000565284A patent/JP2002522703A/en not_active Withdrawn
- 1999-07-30 WO PCT/DE1999/002350 patent/WO2000009869A1/en not_active Application Discontinuation
- 1999-07-30 AT AT99950473T patent/ATE214783T1/en not_active IP Right Cessation
-
2001
- 2001-02-12 US US09/781,207 patent/US6442933B2/en not_active Expired - Fee Related
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KR102395691B1 (en) | 2017-11-07 | 2022-05-09 | 바르실라 핀랜드 오이 | Exhaust gas silencers and exhaust systems for exhaust systems of internal combustion engines |
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US10316721B1 (en) | 2018-04-23 | 2019-06-11 | Faurecia Emissions Control Technologies, Usa, Llc | High efficiency mixer for vehicle exhaust system |
CN108981015A (en) * | 2018-06-26 | 2018-12-11 | 南京海洛阿姆生物科技有限公司 | Air cleaning unit and operating method with degerming deodorization functions |
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CN114673576A (en) * | 2022-04-30 | 2022-06-28 | 哈尔滨工程大学 | Exhaust purification and noise elimination integrated device of high-power diesel engine |
Also Published As
Publication number | Publication date |
---|---|
US6442933B2 (en) | 2002-09-03 |
WO2000009869A1 (en) | 2000-02-24 |
ATE214783T1 (en) | 2002-04-15 |
ES2174642T3 (en) | 2002-11-01 |
EP1108122B1 (en) | 2002-03-20 |
KR20010072389A (en) | 2001-07-31 |
DK1108122T3 (en) | 2002-07-08 |
DE59901031D1 (en) | 2002-04-25 |
JP2002522703A (en) | 2002-07-23 |
EP1108122A1 (en) | 2001-06-20 |
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