US20200003103A1 - Exhaust aftertreatment system for an engine - Google Patents

Exhaust aftertreatment system for an engine Download PDF

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Publication number
US20200003103A1
US20200003103A1 US16/022,085 US201816022085A US2020003103A1 US 20200003103 A1 US20200003103 A1 US 20200003103A1 US 201816022085 A US201816022085 A US 201816022085A US 2020003103 A1 US2020003103 A1 US 2020003103A1
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United States
Prior art keywords
exhaust
aftertreatment system
catalytic
catalytic module
exhaust aftertreatment
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US16/022,085
Inventor
Michael Bradford
Nagoor Mohamed
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Tenneco Automotive Operating Co Inc
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Tenneco Automotive Operating Co Inc
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Priority to US16/022,085 priority Critical patent/US20200003103A1/en
Assigned to TENNECO AUTOMOTIVE OPERATING COMPANY INC. reassignment TENNECO AUTOMOTIVE OPERATING COMPANY INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: BRADFORD, MICHAEL, MOHAMED, NAGOOR
Assigned to WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL TRUSTEE reassignment WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL TRUSTEE CONFIRMATORY GRANT OF SECURITY INTERESTS IN UNITED STATES PATENTS Assignors: BECK ARNLEY HOLDINGS LLC, CARTER AUTOMOTIVE COMPANY LLC, CLEVITE INDUSTRIES INC., FEDERAL-MOGUL CHASSIS LLC, FEDERAL-MOGUL FILTRATION LLC, FEDERAL-MOGUL FINANCING CORPORATION, FEDERAL-MOGUL IGNITION LLC, FEDERAL-MOGUL MOTORPARTS LLC, FEDERAL-MOGUL PISTON RINGS, LLC, FEDERAL-MOGUL POWERTRAIN IP LLC, FEDERAL-MOGUL POWERTRAIN LLC, FEDERAL-MOGUL PRODUCTS US LLC, FEDERAL-MOGUL SEVIERVILLE, LLC, FEDERAL-MOGUL VALVETRAIN INTERNATIONAL LLC, FEDERAL-MOGUL WORLD WIDE LLC, FELT PRODUCTS MFG. CO. LLC, F-M MOTORPARTS TSC LLC, F-M TSC REAL ESTATE HOLDINGS LLC, MUZZY-LYON AUTO PARTS LLC, TENNECO AUTOMOTIVE OPERATING COMPANY INC., TENNECO GLOBAL HOLDINGS INC., TENNECO INC., TENNECO INTERNATIONAL HOLDING CORP., THE PULLMAN COMPANY, TMC TEXAS INC.
Publication of US20200003103A1 publication Critical patent/US20200003103A1/en
Assigned to FEDERAL-MOGUL PISTON RINGS, LLC, FEDERAL-MOGUL FINANCING CORPORATION, CARTER AUTOMOTIVE COMPANY LLC, BECK ARNLEY HOLDINGS LLC, TMC TEXAS INC., FEDERAL-MOGUL POWERTRAIN IP LLC, TENNECO AUTOMOTIVE OPERATING COMPANY INC., FEDERAL-MOGUL VALVE TRAIN INTERNATIONAL LLC, TENNECO GLOBAL HOLDINGS INC., TENNECO INC., FEDERAL-MOGUL IGNITION LLC, CLEVITE INDUSTRIES INC., MUZZY-LYON AUTO PARTS LLC, FEDERAL-MOGUL FILTRATION LLC, FEDERAL-MOGUL WORLD WIDE LLC, FEDERAL-MOGUL PRODUCTS US LLC, FELT PRODUCTS MFG. CO. LLC, FEDERAL-MOGUL SEVIERVILLE, LLC, F-M TSC REAL ESTATE HOLDINGS LLC, F-M MOTORPARTS TSC LLC, FEDERAL-MOGUL POWERTRAIN LLC, THE PULLMAN COMPANY, FEDERAL-MOGUL MOTORPARTS LLC, TENNECO INTERNATIONAL HOLDING CORP., FEDERAL-MOGUL CHASSIS LLC reassignment FEDERAL-MOGUL PISTON RINGS, LLC RELEASE BY SECURED PARTY (SEE DOCUMENT FOR DETAILS). Assignors: WILMINGTON TRUST, NATIONAL ASSOCIATION
Abandoned legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/009Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
    • F01N13/0093Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series the purifying devices are of the same type
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/009Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
    • F01N13/0097Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series the purifying devices are arranged in a single housing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/101Three-way catalysts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F01N3/206Adding periodically or continuously substances to exhaust gases for promoting purification, e.g. catalytic material in liquid form, NOx reducing agents
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/30Arrangements for supply of additional air
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2470/00Structure or shape of gas passages, pipes or tubes
    • F01N2470/18Structure or shape of gas passages, pipes or tubes the axis of inlet or outlet tubes being other than the longitudinal axis of apparatus
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Definitions

  • the present disclosure relates to an exhaust aftertreatment system for an engine. More particularly, the present disclosure relates to an exhaust aftertreatment system for an engine that is configured to operate under a range of stoichiometric and sub-stoichiometric air-fuel ratios (0.92 ⁇ 1).
  • An aftertreatment system may be provided for reducing an amount of undesired emissions, for example, Carbon monoxide (CO), Nitric oxides (NOx), or excess Ammonia (NH3) that could be present in an exhaust of an internal combustion engine.
  • Use of the aftertreatment system can therefore help render the exhaust innocuous from one or more obnoxious constituents, that would otherwise negatively impact the atmosphere besides being detrimental to plant and animal life.
  • the aftertreatment system would be rendered bulky and consequently entail a large packaging space. This would also pose challenges during installation of the aftertreatment system when tight space constraints are encountered. Moreover, by positioning these catalysts one behind the other, it is also envisioned that the individual catalysts may suffer from successive drops in temperature as the gas is flown past each of these catalysts and consequently, one or more of these catalysts may require a longer time to ‘light-off’.
  • U.S. Pat. No. 6,837,336 (hereinafter referred to as ‘the '336 patent’) discloses an apparatus that includes a plurality of gas treating compartments. In each of these compartments, a tubular body member containing a treatment element may be present. Although not disclosed by the '336 patent, it can be believed that the tubular shape of the body members and the inter-relative positioning of these body members disclosed in the '336 patent could hold promise in overcoming the afore-mentioned drawbacks.
  • an exhaust aftertreatment system for an engine operating within a range of stoichiometric and sub-stoichiometric air-fuel ratios (0.92 ⁇ 1) includes an exhaust passageway, and a first catalytic module that has an inlet disposed in fluid communication with the exhaust passageway for receiving exhaust from the exhaust passageway.
  • the exhaust aftertreatment system also includes a first device for introducing an oxidant into the exhaust of the first catalytic module, and a second device for mixing the introduced oxidant with the exhaust of the first catalytic module.
  • the exhaust aftertreatment system also includes a second catalytic module concentric with the first catalytic module such that heat transfer is facilitated between the first and second catalytic modules while exhaust is prevented from flowing radially between the first and second catalytic modules, and a means for diverting the exhaust from an outlet of the first catalytic module to an inlet of the second catalytic module.
  • the inlet of the first catalytic module may be coupled to an outlet of a conduit defining the exhaust passageway.
  • the inlet of the first catalytic module is joined with the outlet of the conduit by an adhesive.
  • the inlet of the first catalytic module may be joined with the outlet of the conduit using a compressible fiber mat. Additionally, or optionally, a compression seal could be positioned between the inlet of the first catalytic module and the outlet of the conduit.
  • the inlet of the first catalytic module may be positioned proximal to an outlet of a conduit defining the exhaust passageway.
  • the inlet of the first catalytic module could be positioned within a range of 3 to 10 millimeters from the outlet of the conduit.
  • a diameter of the inlet of the first catalytic module could be equal to or greater than a diameter associated with the outlet of the conduit.
  • the first catalytic module may be formed from a first substrate and the second catalytic module may be formed from a second substrate.
  • an impermeable member could be positioned between the first and second substrates for preventing the exhaust from flowing radially between the first and second catalytic modules.
  • a co-efficient of thermal expansion associated with the impermeable member could be selected to lie within a predetermined range of, or be similar to, a co-efficient of thermal expansion associated with at least one of the first and second substrates.
  • the first and second catalytic modules may be formed from a monolithic substrate defining a plurality of channels therethrough.
  • the first and second catalytic modules may be separated by an impermeable zone defined in an annular region of the monolithic substrate.
  • the impermeable zone could be formed integrally with the monolithic substrate by rendering the annular region of the monolithic substrate between the first and second catalytic modules with zero porosity.
  • the impermeable zone may be formed by plugging ends of channels in the annular region of the monolithic substrate with an inert non-catalytic solid.
  • the impermeable zone could be defined by filling channels in the annular region of the monolithic substrate with an inert non-porous medium.
  • the exhaust aftertreatment system may include a housing.
  • the housing may have a first end and a second end that is distally located from the first end.
  • the first catalytic module could be positioned within the housing such that the inlet of the first catalytic module is disposed proximal to the first end of the housing.
  • the means for diverting the exhaust from the outlet of the first catalytic module to the inlet of the second catalytic module may be the second end of the housing.
  • the second device may be positioned at, or adjacent to the second end of the housing so that the exhaust is mixed with introduced oxidant prior to the oxidant enriched exhaust entering the second catalytic module.
  • FIG. 1 is a diagrammatic representation of an exemplary engine and an exhaust aftertreatment system for treating exhaust from the exemplary engine, in accordance with an embodiment of the present invention
  • FIG. 2 is a diagrammatic cross-sectional representation of the exhaust aftertreatment system taken along section A-A′′ of FIG. 1 , the cross-sectional representation showing a pair of concentrically arranged cylindrical catalytic modules in accordance with an embodiment of the present invention
  • FIG. 3 is a diagrammatic cross-sectional representation indicating a shape of the pair of catalytic modules that could be employed in the exhaust aftertreatment system of FIG. 1 , in accordance with an alternative embodiment of the present invention
  • FIG. 4 is a diagrammatic representation of the exemplary engine and the exhaust aftertreatment system, in accordance with another embodiment of the present invention.
  • FIG. 5 is a diagrammatic cross-sectional representation of the exhaust aftertreatment system taken along section B-B′ of FIG. 4 , the diagrammatic cross-sectional representation showing a monolithic substrate forming the pair of concentrically arranged catalytic modules, in accordance with an embodiment of the present invention
  • FIG. 6 is a diagrammatic cross-sectional representation of the monolithic substrate taken along section C-C′ of FIG. 4 , in accordance with an embodiment of the present invention
  • FIG. 7 is another diagrammatic cross-sectional representation taken along section B-B′ of FIG. 4 , the diagrammatic cross-sectional representation showing a monolithic substrate forming the pair of concentrically arranged catalytic modules, in accordance with an alternative embodiment of the present invention.
  • FIG. 8 is a diagrammatic cross-sectional representation of the monolithic substrate taken along section D-D′ of FIG. 7 , in accordance with an embodiment of the present invention.
  • This disclosure relates to an exhaust aftertreatment system for an engine. More particularly, the present disclosure relates to an exhaust aftertreatment system for an engine that is configured to operate under a range of stoichiometric and sub-stoichiometric air-fuel ratios (0.92 ⁇ 1).
  • an engine 102 is shown.
  • the engine 102 may be of any type.
  • the engine 102 may be used to drive a generator for power generation, or other mechanical assemblies such as a compressor.
  • the engine 102 may be employed in mobile machines such as, but not limited to, marine vessels, earth moving machines, passenger vehicles, or other types of mobile machine known to persons skilled in the art.
  • the engine 102 may be, for example, a spark-ignited (SI) engine, or a compression ignited (CI) engine.
  • the engine 102 may be a single cylinder engine, or a multi-cylinder engine.
  • fuel that would be associated with the engine 102 may include, but is not limited to, Gasoline (Petrol), Compressed Natural Gas (CNG), Autogas (Liquified Petroleum Gas (LPG)), methanol, ethanol, bioethanol, hydrogen, or other spark-ignited fuels known to persons skilled in the art.
  • a type of fuel may include, for example, diesel.
  • aspects of the present disclosure may be adapted to suit different engine and exhaust aftertreatment system configurations depending on specific requirements of an application.
  • aspects of the present disclosure are directed towards improving a conversion efficiency of an aftertreatment system that is provided for treating exhaust that is produced under stoichiometric and sub-stoichiometric engine operation i.e., where ⁇ is between 0.92 and 1 but not exceeding 1 .
  • the engine 102 is provided with an exhaust aftertreatment system 104 .
  • the exhaust aftertreatment system 104 includes a housing 106 having a first end 108 and a second end 110 that is distally located from the first end 108 .
  • the housing 106 may be configured such that various components of the exhaust aftertreatment system 104 can be secured by positioning such components within, or at least partly within the housing 106 .
  • the exhaust aftertreatment system 104 further includes an exhaust passageway 112 .
  • the exhaust passageway 112 is defined by a conduit 114 that may form part of the engine 102 , or the exhaust aftertreatment system 104 .
  • the exhaust aftertreatment system 104 also includes a first catalytic module 116 .
  • the first catalytic module 116 may be, for example, a three-way catalytic converter (TWC).
  • TWC three-way catalytic converter
  • the first catalytic module 116 is positioned within the housing 106 , and has an inlet 118 that, as shown in the illustrated embodiment of FIG. 1 , is positioned proximal to the first end 108 of the housing 106 .
  • the inlet 118 of the first catalytic module 116 is also disposed in fluid communication with the exhaust passageway 112 for receiving exhaust of the engine 102 from the exhaust passageway 112 . As shown in the illustrated embodiment of FIG. 1 , the inlet 118 of the first catalytic module 116 may be coupled to an outlet 120 of the conduit 114 that defines the exhaust passageway 112 . In one embodiment, the inlet 118 of the first catalytic module 116 may be joined with the outlet 120 of the conduit 114 by an adhesive.
  • the inlet 118 of the first catalytic module 116 may be joined with the outlet 120 of the conduit 114 using a compressible fiber mat 122 .
  • the compressible fiber mat 122 would be configured to allow an axial or radial inter-relative displacement of the first catalytic module 116 with the outlet 120 of the conduit 114 , for example, when shocks or vibrations are experienced by the first catalytic module 116 , or displacement of the first catalytic module 116 occurs under thermal expansion effects.
  • a compression seal 124 could be positioned between the outlet 120 of the conduit 114 and the inlet 118 of the first catalytic module 116 .
  • the compression seal 124 would be configured to prevent a loss of fluid communication between the outlet 120 of the conduit 114 and the inlet 118 of the first catalytic module 116 .
  • the exhaust aftertreatment system 104 also includes a first device 126 for introducing an oxidant 128 into the exhaust of the first catalytic module 116 .
  • the first device 126 may be a passively operational device, for example, an opening 130 that is in fluid communication with a portion of the housing 106 adjacent the second end 110 of the housing 106 as shown in the illustrated embodiment of FIG. 1 . This opening 130 could facilitate entry of the oxidant 128 , for example, ambient air into the housing 106 .
  • the first device 126 disclosed herein may alternatively include, one or more actively operated devices, such as, but not limited to, a powered aerator, or an oxidant injector in communication with a turbocharger outlet (not shown).
  • the exhaust aftertreatment system 104 also includes a second device 132 for mixing the introduced oxidant with the exhaust of the first catalytic module 116 .
  • the second device 132 may be a gas mixer, preferably, of a configuration that can be accommodated and secured within the housing 106 .
  • the exhaust aftertreatment system 104 includes the first device 126 and the second device 132 as separate devices for performing specific functions, it other embodiments of the present invention, it can be contemplated to incorporate a single device that provides the functionality disclosed in conjunction with respective ones of the first device 126 and second device 132 . Such modifications are to be understood as falling within the scope of the present invention.
  • the exhaust aftertreatment system 104 also includes a second catalytic module 134 .
  • the second catalytic module 134 may include one or more of, for example, a Diesel Oxidation Catalyst (DOC), an Ammonia Slip Catalyst (ASC), a Diesel Particulate Filter (DPF) or other types of catalysts known to persons skilled in the art.
  • DOC Diesel Oxidation Catalyst
  • ASC Ammonia Slip Catalyst
  • DPF Diesel Particulate Filter
  • the second catalytic module 134 is concentric with the first catalytic module 116 such that heat transfer is facilitated between the first and second catalytic modules 116 , 134 while exhaust is prevented from flowing radially between the first and second catalytic modules 116 , 134 .
  • the exhaust aftertreatment system 104 also includes a means 136 for diverting the exhaust from an outlet 138 of the first catalytic module 116 to an inlet 140 of the second catalytic module 134 .
  • the second end 110 of the housing 106 may be configured to embody the means 136 for diverting the exhaust from the outlet 138 of the first catalytic module 116 to the inlet 140 of the second catalytic module 134 .
  • actively operated devices such as, but not limited to, flow controllers, flow regulators, diverting structures may be to form the means 136 for diverting the exhaust from the outlet 138 of the first catalytic module 116 to the inlet 140 of the second catalytic module 134 .
  • the second device 132 may be positioned at, or adjacent to the second end 110 of the housing 106 so that the exhaust is mixed with introduced oxidant prior to the oxidant enriched exhaust entering the inlet 140 of the second catalytic module 134 .
  • the first catalytic module 116 may be formed from a first substrate 142 and the second catalytic module 134 may be formed from a second substrate 144 .
  • the exhaust aftertreatment device would also include an impermeable member 146 that could be positioned between the first and second substrates 142 , 144 for preventing the exhaust from flowing radially between the first and second catalytic modules 116 , 134 .
  • a cross-section, taken about section line A-A′ of FIG. 1 , of the first and second catalytic modules 116 , 134 is circular indicating that the first and second catalytic modules 116 , 134 are cylindrical in shape.
  • the circular cross-section of the first and second catalytic modules 116 , 134 is merely exemplary in nature and hence, non-limiting of the present invention. Rather, other shapes such as, but not limited to, square as shown in the diagrammatic sectional representation of FIG. 3 , oval, rectangular, reniform, or other shapes may be used to respective ones of the first and second catalytic modules 116 , 134 depending upon specific requirements of an aftertreatment application.
  • a type of material used to form the impermeable member 146 may be, preferably, non-catalytic in nature to respective ones of the reactions occurring in each of the first and second catalytic modules 116 , 134 .
  • the impermeable member 146 could be embodied as a can or a shell made from Stainless Steel (SS), or other suitable alloys of steel having a grade that would meet specific requirements of the aftertreatment application.
  • SS Stainless Steel
  • a co-efficient of thermal expansion associated with the impermeable member 146 could be selected to lie within a predetermined range, for example, within 10 percent tolerance, from a co-efficient of thermal expansion associated with at least one of the first and second substrates 142 , 144 . It is envisioned that with little or no difference between the co-efficient of thermal expansions of respective ones of the first substrate 142 , the second substrate 144 , and the impermeable member 146 , uniform expansion may be experienced to minimize a possibility of the exhaust aftertreatment system's structural integrity from being compromised, for example, by cracking under the effect of non-uniform expansion during operation.
  • the inlet 118 of the first catalytic module 116 may be positioned proximal to the outlet 120 of the conduit 114 i.e., without physical contact between the outlet 120 of the conduit 114 and the inlet 118 of the first catalytic module 116 .
  • the inlet 118 of the first catalytic module 116 could be positioned within a distance D of 3 to 10 millimeters from the outlet 120 of the conduit 114 , for example, at M millimeters from the outlet 120 of the conduit 114 .
  • a diameter d 1 of the inlet 118 of the first catalytic module 116 would be equal to or greater than a diameter d 2 associated with the outlet 120 of the conduit 114 i.e., d 1 ⁇ d 2 . This way, little or no exhaust from the exhaust passageway 112 would travel directly into an outlet 148 of the housing 106 by directing a majority of the exhaust from the exhaust passageway 112 to enter the inlet 118 of the first catalytic module 116 .
  • the first and second catalytic modules 116 , 134 may be formed from a monolithic substrate 402 .
  • the monolithic substrate 402 defines multiple channels 502 therethrough.
  • the first and second catalytic modules 116 , 134 may be separated by an impermeable zone 504 defined in an annular region 506 of the monolithic substrate 402 .
  • the impermeable zone 504 may be formed by plugging ends 510 of the channels 502 that are in the annular region 506 of the monolithic substrate 402 with an inert non-catalytic solid 508 .
  • the impermeable zone 504 could be defined by filling channels 502 in the annular region 506 of the monolithic substrate 402 with an inert non-porous medium 702 .
  • the impermeable zone 504 could be formed integrally with the monolithic substrate 402 during a manufacture of the monolithic substrate 402 by rendering the annular region 506 of the monolithic substrate 402 between the first and second catalytic modules 116 , 134 with zero porosity.
  • joinder references e.g., attached, joined, coupled, connected, and the like
  • joinder references are only used to aid the reader's understanding of the present disclosure, and may not create limitations, particularly as to the position, orientation, or use of the systems disclosed herein. Therefore, joinder references, if any, are to be construed broadly. Moreover, such joinder references do not necessarily infer that two elements are directly connected to each other.
  • fuel dithering describe an oscillation of an engine charge composition relating to different Lambda ( ⁇ i.e., normalized air-fuel ratio) values over time.
  • Fuel dithering when implemented, by dynamically operating engine fuel supply systems, can create consecutive patterns of rich/lean fueling conditions in the engine that, in turn, can lead to dynamically oscillating catalyst surface conditions in an exhaust aftertreatment system to achieve an optimum conversion efficiency.
  • aspects of the present disclosure have been discussed independent of such fuel dithering techniques. As aspects of the present disclosure are also directed at improving a conversion efficiency of an aftertreatment system, it will be appreciated that aspects of the present disclosure can be implemented to realize an improved conversion efficiency in conjunction with, or without the implementation of a fuel dithering technique.
  • manufacturers can render exhaust aftertreatment systems with a compact configuration and an improved conversion efficiency.
  • an axial length of the housing 106 may decrease, and this decrease in the axial length of the housing 106 may help render a compact configuration to the exhaust aftertreatment device 104 .
  • packaging requirements for the exhaust aftertreatment system 104 of the present invention may be minimized and the exhaust aftertreatment system 104 can be installed in locations that have tight space constraints.
  • the exhaust would be required to pass through the first catalytic module 116 , mix with the oxidant 128 , cause to be reversed in its direction of flow, and thereafter be treated as an oxidant enriched mixture at the second catalytic module 134 before exiting the housing 106 .
  • the first catalytic module 116 could abate most of the undesired constituents in the exhaust stream i.e., reduce Nitrogen oxides (NO x ) to Nitrogen (N 2 ), oxidize Carbon monoxide (CO) to Carbon dioxide (CO 2 ), and oxidize unburnt hydrocarbons (HC) to Carbon dioxide (CO 2 ) and water (H 2 O).
  • TWC three-way catalyst
  • a third device could also be provided with the exhaust aftertreatment system 104 of the present invention to dose a reductant, for example, Urea typically in the form of an aqueous Ammonia (NH 3 ) solution.
  • a reductant for example, Urea typically in the form of an aqueous Ammonia (NH 3 ) solution.
  • this Ammonia (NH 3 ), if present in excess quantities, and if traces of the undesired constituents (NO x , CO, and/or unburnt hydrocarbons) continue to remain, then by introducing the oxidant 128 , preferably, under pressure, and subsequently mixing the exhaust of the first catalytic module 116 with the oxidant 128 , a concomitant abatement of remnant Nitrogen oxides (NO), Carbon monoxide (CO), unburnt hydrocarbons (HC), and any excess Ammonia (NH 3 ) could be easily achieved.
  • a conversion efficiency of the aftertreatment system disclosed herein may be greater than that typically associated with use of previously known aftertreatment systems resulting in an improved abatement of the undesired emissions in the exhaust, and lesser detrimental effects to the atmosphere.

Abstract

An exhaust aftertreatment system for an engine operating within a range of stoichiometric and sub-stoichiometric air-fuel ratios (0.92<λ≤1) includes an exhaust passageway, and a first catalytic module that has an inlet disposed in fluid communication with the exhaust passageway for receiving exhaust from the exhaust passageway. The exhaust aftertreatment system also includes a first device for introducing an oxidant into the exhaust of the first catalytic module, and a second device for mixing the introduced oxidant with the exhaust of the first catalytic module. The exhaust aftertreatment system also includes a second catalytic module concentric with the first catalytic module such that heat transfer is facilitated between the first and second catalytic modules while exhaust is prevented from flowing radially between the first and second catalytic modules, and a means for diverting the exhaust from an outlet of the first catalytic module to an inlet of the second catalytic module.

Description

    TECHNICAL FIELD
  • The present disclosure relates to an exhaust aftertreatment system for an engine. More particularly, the present disclosure relates to an exhaust aftertreatment system for an engine that is configured to operate under a range of stoichiometric and sub-stoichiometric air-fuel ratios (0.92<λ≤1).
  • BACKGROUND
  • An aftertreatment system may be provided for reducing an amount of undesired emissions, for example, Carbon monoxide (CO), Nitric oxides (NOx), or excess Ammonia (NH3) that could be present in an exhaust of an internal combustion engine. Use of the aftertreatment system can therefore help render the exhaust innocuous from one or more obnoxious constituents, that would otherwise negatively impact the atmosphere besides being detrimental to plant and animal life.
  • However, many limitations in the performance of these aftertreatment systems may arise owing, at least in part, due to system design. In many cases, it has been seen that when two or more catalysts, for instance, a Three-Way Catalyst (TWC), a Diesel Oxidation Catalyst (DOC), and/or an Ammonia Slip Catalyst are to be included in an aftertreatment system, the catalysts received the exhaust serially, however these catalysts were typically positioned in line with one another, or stated differently, one behind the other.
  • With such inter-relative positioning of these catalysts, the aftertreatment system would be rendered bulky and consequently entail a large packaging space. This would also pose challenges during installation of the aftertreatment system when tight space constraints are encountered. Moreover, by positioning these catalysts one behind the other, it is also envisioned that the individual catalysts may suffer from successive drops in temperature as the gas is flown past each of these catalysts and consequently, one or more of these catalysts may require a longer time to ‘light-off’.
  • U.S. Pat. No. 6,837,336 (hereinafter referred to as ‘the '336 patent’) discloses an apparatus that includes a plurality of gas treating compartments. In each of these compartments, a tubular body member containing a treatment element may be present. Although not disclosed by the '336 patent, it can be believed that the tubular shape of the body members and the inter-relative positioning of these body members disclosed in the '336 patent could hold promise in overcoming the afore-mentioned drawbacks.
  • Nevertheless, ever stringent emission regulations have also been driving manufacturers of aftertreatment devices to continually direct their efforts towards improving a conversion efficiency of the aftertreatment devices. Hence, there is a need for an exhaust aftertreatment system that provides an improved conversion efficiency for reducing the negative impact that may be caused to the atmosphere, plant life, or animal life from combustion of fuels.
  • SUMMARY OF THE DISCLOSURE
  • In an embodiment of the present invention, an exhaust aftertreatment system for an engine operating within a range of stoichiometric and sub-stoichiometric air-fuel ratios (0.92<λ≤1) includes an exhaust passageway, and a first catalytic module that has an inlet disposed in fluid communication with the exhaust passageway for receiving exhaust from the exhaust passageway. The exhaust aftertreatment system also includes a first device for introducing an oxidant into the exhaust of the first catalytic module, and a second device for mixing the introduced oxidant with the exhaust of the first catalytic module. The exhaust aftertreatment system also includes a second catalytic module concentric with the first catalytic module such that heat transfer is facilitated between the first and second catalytic modules while exhaust is prevented from flowing radially between the first and second catalytic modules, and a means for diverting the exhaust from an outlet of the first catalytic module to an inlet of the second catalytic module.
  • In an embodiment of the present invention, the inlet of the first catalytic module may be coupled to an outlet of a conduit defining the exhaust passageway. In one embodiment, the inlet of the first catalytic module is joined with the outlet of the conduit by an adhesive. In an alternative embodiment of the present invention, the inlet of the first catalytic module may be joined with the outlet of the conduit using a compressible fiber mat. Additionally, or optionally, a compression seal could be positioned between the inlet of the first catalytic module and the outlet of the conduit.
  • In an embodiment of the present invention, the inlet of the first catalytic module may be positioned proximal to an outlet of a conduit defining the exhaust passageway. For instance, the inlet of the first catalytic module could be positioned within a range of 3 to 10 millimeters from the outlet of the conduit. Also, a diameter of the inlet of the first catalytic module could be equal to or greater than a diameter associated with the outlet of the conduit.
  • In an embodiment of the present invention, the first catalytic module may be formed from a first substrate and the second catalytic module may be formed from a second substrate. Further, an impermeable member could be positioned between the first and second substrates for preventing the exhaust from flowing radially between the first and second catalytic modules. Furthermore, a co-efficient of thermal expansion associated with the impermeable member could be selected to lie within a predetermined range of, or be similar to, a co-efficient of thermal expansion associated with at least one of the first and second substrates.
  • In an alternative embodiment of the present invention, the first and second catalytic modules may be formed from a monolithic substrate defining a plurality of channels therethrough. The first and second catalytic modules may be separated by an impermeable zone defined in an annular region of the monolithic substrate.
  • Further, in one embodiment of the present invention, the impermeable zone could be formed integrally with the monolithic substrate by rendering the annular region of the monolithic substrate between the first and second catalytic modules with zero porosity. In an alternative embodiment of the present invention, the impermeable zone may be formed by plugging ends of channels in the annular region of the monolithic substrate with an inert non-catalytic solid. In yet another alternative embodiment, the impermeable zone could be defined by filling channels in the annular region of the monolithic substrate with an inert non-porous medium.
  • In an embodiment of the present invention, the exhaust aftertreatment system may include a housing. The housing may have a first end and a second end that is distally located from the first end. The first catalytic module could be positioned within the housing such that the inlet of the first catalytic module is disposed proximal to the first end of the housing. In one further embodiment, the means for diverting the exhaust from the outlet of the first catalytic module to the inlet of the second catalytic module may be the second end of the housing. Also, the second device may be positioned at, or adjacent to the second end of the housing so that the exhaust is mixed with introduced oxidant prior to the oxidant enriched exhaust entering the second catalytic module.
  • Other features and aspects of this disclosure will be apparent from the following description and the accompanying drawings.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a diagrammatic representation of an exemplary engine and an exhaust aftertreatment system for treating exhaust from the exemplary engine, in accordance with an embodiment of the present invention;
  • FIG. 2 is a diagrammatic cross-sectional representation of the exhaust aftertreatment system taken along section A-A″ of FIG. 1, the cross-sectional representation showing a pair of concentrically arranged cylindrical catalytic modules in accordance with an embodiment of the present invention;
  • FIG. 3 is a diagrammatic cross-sectional representation indicating a shape of the pair of catalytic modules that could be employed in the exhaust aftertreatment system of FIG. 1, in accordance with an alternative embodiment of the present invention;
  • FIG. 4 is a diagrammatic representation of the exemplary engine and the exhaust aftertreatment system, in accordance with another embodiment of the present invention;
  • FIG. 5 is a diagrammatic cross-sectional representation of the exhaust aftertreatment system taken along section B-B′ of FIG. 4, the diagrammatic cross-sectional representation showing a monolithic substrate forming the pair of concentrically arranged catalytic modules, in accordance with an embodiment of the present invention;
  • FIG. 6 is a diagrammatic cross-sectional representation of the monolithic substrate taken along section C-C′ of FIG. 4, in accordance with an embodiment of the present invention;
  • FIG. 7 is another diagrammatic cross-sectional representation taken along section B-B′ of FIG. 4, the diagrammatic cross-sectional representation showing a monolithic substrate forming the pair of concentrically arranged catalytic modules, in accordance with an alternative embodiment of the present invention; and
  • FIG. 8 is a diagrammatic cross-sectional representation of the monolithic substrate taken along section D-D′ of FIG. 7, in accordance with an embodiment of the present invention.
  • DETAILED DESCRIPTION
  • Wherever possible, the same reference numbers will be used throughout the drawings to refer to same or like parts.
  • This disclosure relates to an exhaust aftertreatment system for an engine. More particularly, the present disclosure relates to an exhaust aftertreatment system for an engine that is configured to operate under a range of stoichiometric and sub-stoichiometric air-fuel ratios (0.92<λ≤1).
  • Referring to FIG. 1, an engine 102 is shown. The engine 102 may be of any type. In one embodiment, the engine 102 may be used to drive a generator for power generation, or other mechanical assemblies such as a compressor. In other embodiments, the engine 102 may be employed in mobile machines such as, but not limited to, marine vessels, earth moving machines, passenger vehicles, or other types of mobile machine known to persons skilled in the art.
  • The engine 102 may be, for example, a spark-ignited (SI) engine, or a compression ignited (CI) engine. The engine 102 may be a single cylinder engine, or a multi-cylinder engine. Where the engine 102 is of a spark-ignited type, fuel that would be associated with the engine 102 may include, but is not limited to, Gasoline (Petrol), Compressed Natural Gas (CNG), Autogas (Liquified Petroleum Gas (LPG)), methanol, ethanol, bioethanol, hydrogen, or other spark-ignited fuels known to persons skilled in the art. Where the engine 102 is of a compression ignited type, a type of fuel may include, for example, diesel.
  • Although some examples of engines may be disclosed herein, it may be noted that such examples are not limiting of a configuration, or a fuel-type associated therewith. Rather, it will be appreciated that aspects of the present disclosure may be adapted to suit different engine and exhaust aftertreatment system configurations depending on specific requirements of an application. In fact, aspects of the present disclosure are directed towards improving a conversion efficiency of an aftertreatment system that is provided for treating exhaust that is produced under stoichiometric and sub-stoichiometric engine operation i.e., where λ is between 0.92 and 1 but not exceeding 1.
  • As shown, the engine 102 is provided with an exhaust aftertreatment system 104. In the illustrated embodiment of FIG. 1, the exhaust aftertreatment system 104 includes a housing 106 having a first end 108 and a second end 110 that is distally located from the first end 108. The housing 106 may be configured such that various components of the exhaust aftertreatment system 104 can be secured by positioning such components within, or at least partly within the housing 106.
  • As shown, the exhaust aftertreatment system 104 further includes an exhaust passageway 112. The exhaust passageway 112 is defined by a conduit 114 that may form part of the engine 102, or the exhaust aftertreatment system 104. The exhaust aftertreatment system 104 also includes a first catalytic module 116. The first catalytic module 116 may be, for example, a three-way catalytic converter (TWC). The first catalytic module 116 is positioned within the housing 106, and has an inlet 118 that, as shown in the illustrated embodiment of FIG. 1, is positioned proximal to the first end 108 of the housing 106.
  • The inlet 118 of the first catalytic module 116 is also disposed in fluid communication with the exhaust passageway 112 for receiving exhaust of the engine 102 from the exhaust passageway 112. As shown in the illustrated embodiment of FIG. 1, the inlet 118 of the first catalytic module 116 may be coupled to an outlet 120 of the conduit 114 that defines the exhaust passageway 112. In one embodiment, the inlet 118 of the first catalytic module 116 may be joined with the outlet 120 of the conduit 114 by an adhesive.
  • As shown in the illustrated embodiment of FIG. 1, the inlet 118 of the first catalytic module 116 may be joined with the outlet 120 of the conduit 114 using a compressible fiber mat 122. The compressible fiber mat 122 would be configured to allow an axial or radial inter-relative displacement of the first catalytic module 116 with the outlet 120 of the conduit 114, for example, when shocks or vibrations are experienced by the first catalytic module 116, or displacement of the first catalytic module 116 occurs under thermal expansion effects.
  • Additionally, or optionally, a compression seal 124 could be positioned between the outlet 120 of the conduit 114 and the inlet 118 of the first catalytic module 116. The compression seal 124 would be configured to prevent a loss of fluid communication between the outlet 120 of the conduit 114 and the inlet 118 of the first catalytic module 116.
  • Further, as shown, the exhaust aftertreatment system 104 also includes a first device 126 for introducing an oxidant 128 into the exhaust of the first catalytic module 116. In certain embodiments, the first device 126 may be a passively operational device, for example, an opening 130 that is in fluid communication with a portion of the housing 106 adjacent the second end 110 of the housing 106 as shown in the illustrated embodiment of FIG. 1. This opening 130 could facilitate entry of the oxidant 128, for example, ambient air into the housing 106. In other embodiments, the first device 126 disclosed herein, may alternatively include, one or more actively operated devices, such as, but not limited to, a powered aerator, or an oxidant injector in communication with a turbocharger outlet (not shown).
  • Furthermore, the exhaust aftertreatment system 104 also includes a second device 132 for mixing the introduced oxidant with the exhaust of the first catalytic module 116. The second device 132 may be a gas mixer, preferably, of a configuration that can be accommodated and secured within the housing 106.
  • In embodiments herein, although it is disclosed that the exhaust aftertreatment system 104 includes the first device 126 and the second device 132 as separate devices for performing specific functions, it other embodiments of the present invention, it can be contemplated to incorporate a single device that provides the functionality disclosed in conjunction with respective ones of the first device 126 and second device 132. Such modifications are to be understood as falling within the scope of the present invention.
  • The exhaust aftertreatment system 104 also includes a second catalytic module 134. The second catalytic module 134 may include one or more of, for example, a Diesel Oxidation Catalyst (DOC), an Ammonia Slip Catalyst (ASC), a Diesel Particulate Filter (DPF) or other types of catalysts known to persons skilled in the art. The second catalytic module 134 is concentric with the first catalytic module 116 such that heat transfer is facilitated between the first and second catalytic modules 116, 134 while exhaust is prevented from flowing radially between the first and second catalytic modules 116, 134.
  • With continued reference to FIG. 1, the exhaust aftertreatment system 104 also includes a means 136 for diverting the exhaust from an outlet 138 of the first catalytic module 116 to an inlet 140 of the second catalytic module 134. In the illustrated embodiment of FIG. 1, the second end 110 of the housing 106 may be configured to embody the means 136 for diverting the exhaust from the outlet 138 of the first catalytic module 116 to the inlet 140 of the second catalytic module 134. However, in other embodiments, actively operated devices (not shown) such as, but not limited to, flow controllers, flow regulators, diverting structures may be to form the means 136 for diverting the exhaust from the outlet 138 of the first catalytic module 116 to the inlet 140 of the second catalytic module 134.
  • In a further embodiment, the second device 132 may be positioned at, or adjacent to the second end 110 of the housing 106 so that the exhaust is mixed with introduced oxidant prior to the oxidant enriched exhaust entering the inlet 140 of the second catalytic module 134.
  • In one embodiment as shown in FIG. 1 and as best seen in the views of FIGS. 2 and 3, the first catalytic module 116 may be formed from a first substrate 142 and the second catalytic module 134 may be formed from a second substrate 144. Moreover, in this embodiment, the exhaust aftertreatment device would also include an impermeable member 146 that could be positioned between the first and second substrates 142, 144 for preventing the exhaust from flowing radially between the first and second catalytic modules 116, 134.
  • In an embodiment as shown by way of the diagrammatic sectional representation in FIG. 2, a cross-section, taken about section line A-A′ of FIG. 1, of the first and second catalytic modules 116, 134 is circular indicating that the first and second catalytic modules 116, 134 are cylindrical in shape. However, it may be noted that the circular cross-section of the first and second catalytic modules 116, 134 is merely exemplary in nature and hence, non-limiting of the present invention. Rather, other shapes such as, but not limited to, square as shown in the diagrammatic sectional representation of FIG. 3, oval, rectangular, reniform, or other shapes may be used to respective ones of the first and second catalytic modules 116, 134 depending upon specific requirements of an aftertreatment application.
  • Also, it is hereby contemplated that a type of material used to form the impermeable member 146 may be, preferably, non-catalytic in nature to respective ones of the reactions occurring in each of the first and second catalytic modules 116, 134. In one example, the impermeable member 146 could be embodied as a can or a shell made from Stainless Steel (SS), or other suitable alloys of steel having a grade that would meet specific requirements of the aftertreatment application.
  • Furthermore, a co-efficient of thermal expansion associated with the impermeable member 146 could be selected to lie within a predetermined range, for example, within 10 percent tolerance, from a co-efficient of thermal expansion associated with at least one of the first and second substrates 142, 144. It is envisioned that with little or no difference between the co-efficient of thermal expansions of respective ones of the first substrate 142, the second substrate 144, and the impermeable member 146, uniform expansion may be experienced to minimize a possibility of the exhaust aftertreatment system's structural integrity from being compromised, for example, by cracking under the effect of non-uniform expansion during operation.
  • In another embodiment as shown in FIG. 4, the inlet 118 of the first catalytic module 116 may be positioned proximal to the outlet 120 of the conduit 114 i.e., without physical contact between the outlet 120 of the conduit 114 and the inlet 118 of the first catalytic module 116. In an embodiment, the inlet 118 of the first catalytic module 116 could be positioned within a distance D of 3 to 10 millimeters from the outlet 120 of the conduit 114, for example, at M millimeters from the outlet 120 of the conduit 114. Also, a diameter d1 of the inlet 118 of the first catalytic module 116 would be equal to or greater than a diameter d2 associated with the outlet 120 of the conduit 114 i.e., d1≥d2. This way, little or no exhaust from the exhaust passageway 112 would travel directly into an outlet 148 of the housing 106 by directing a majority of the exhaust from the exhaust passageway 112 to enter the inlet 118 of the first catalytic module 116.
  • In an alternative embodiment as shown in FIG. 4, the first and second catalytic modules 116, 134 may be formed from a monolithic substrate 402. As best shown in FIGS. 5-8, the monolithic substrate 402 defines multiple channels 502 therethrough. The first and second catalytic modules 116, 134 may be separated by an impermeable zone 504 defined in an annular region 506 of the monolithic substrate 402.
  • In one embodiment as shown in FIG. 5 and best seen in the diagrammatic sectional view of FIG. 6, the impermeable zone 504 may be formed by plugging ends 510 of the channels 502 that are in the annular region 506 of the monolithic substrate 402 with an inert non-catalytic solid 508. In another embodiment as shown in FIG. 7 and best seen in the diagrammatic sectional view of FIG. 8, the impermeable zone 504 could be defined by filling channels 502 in the annular region 506 of the monolithic substrate 402 with an inert non-porous medium 702. In an alternative embodiment of the present invention, the impermeable zone 504 could be formed integrally with the monolithic substrate 402 during a manufacture of the monolithic substrate 402 by rendering the annular region 506 of the monolithic substrate 402 between the first and second catalytic modules 116, 134 with zero porosity.
  • Various embodiments disclosed herein are to be taken in the illustrative and explanatory sense and should in no way be construed as limiting of the present disclosure. All joinder references (e.g., attached, joined, coupled, connected, and the like) are only used to aid the reader's understanding of the present disclosure, and may not create limitations, particularly as to the position, orientation, or use of the systems disclosed herein. Therefore, joinder references, if any, are to be construed broadly. Moreover, such joinder references do not necessarily infer that two elements are directly connected to each other.
  • Additionally, all numerical terms, such as, but not limited to, “first”, “second” or any other ordinary and/or numerical terms, should also be taken only as identifiers, to assist the reader's understanding of the various elements of the present disclosure, and may not create any limitations, particularly as to the order, or preference, of any element relative to, or over, another element.
  • It is to be understood that individual features shown or described for one embodiment may be combined with individual features shown or described for another embodiment. The above described implementation does not in any way limit the scope of the present disclosure. Therefore, it is to be understood although some features are shown or described to illustrate the use of the present disclosure in the context of functional devices, such features may be omitted without limiting the scope of the present disclosure as defined by the appended claims.
  • INDUSTRIAL APPLICABILITY
  • The terms ‘fuel dithering’, describe an oscillation of an engine charge composition relating to different Lambda (λ i.e., normalized air-fuel ratio) values over time. Fuel dithering, when implemented, by dynamically operating engine fuel supply systems, can create consecutive patterns of rich/lean fueling conditions in the engine that, in turn, can lead to dynamically oscillating catalyst surface conditions in an exhaust aftertreatment system to achieve an optimum conversion efficiency.
  • Although many fuel dithering techniques are known to persons skilled in the art, aspects of the present disclosure have been discussed independent of such fuel dithering techniques. As aspects of the present disclosure are also directed at improving a conversion efficiency of an aftertreatment system, it will be appreciated that aspects of the present disclosure can be implemented to realize an improved conversion efficiency in conjunction with, or without the implementation of a fuel dithering technique.
  • With use of embodiments disclosed herein, manufacturers can render exhaust aftertreatment systems with a compact configuration and an improved conversion efficiency. In embodiments herein, by positioning the first and second catalytic modules 116, 134 concentrically, an axial length of the housing 106 may decrease, and this decrease in the axial length of the housing 106 may help render a compact configuration to the exhaust aftertreatment device 104. As the compact configuration of the exhaust aftertreatment system 104 also serves to reduce an overall space claim, packaging requirements for the exhaust aftertreatment system 104 of the present invention may be minimized and the exhaust aftertreatment system 104 can be installed in locations that have tight space constraints.
  • Moreover, as the first and second catalytic modules 116, 134 are placed concentrically, the exhaust would be required to pass through the first catalytic module 116, mix with the oxidant 128, cause to be reversed in its direction of flow, and thereafter be treated as an oxidant enriched mixture at the second catalytic module 134 before exiting the housing 106. It may be noted that if the first catalytic module 116 embodies, for instance, a three-way catalyst (TWC), then the first catalytic module 116 could abate most of the undesired constituents in the exhaust stream i.e., reduce Nitrogen oxides (NOx) to Nitrogen (N2), oxidize Carbon monoxide (CO) to Carbon dioxide (CO2), and oxidize unburnt hydrocarbons (HC) to Carbon dioxide (CO2) and water (H2O).
  • Also, it is hereby contemplated that in some cases, a third device (not shown) could also be provided with the exhaust aftertreatment system 104 of the present invention to dose a reductant, for example, Urea typically in the form of an aqueous Ammonia (NH3) solution. It is hereby envisioned that this Ammonia (NH3), if present in excess quantities, and if traces of the undesired constituents (NOx, CO, and/or unburnt hydrocarbons) continue to remain, then by introducing the oxidant 128, preferably, under pressure, and subsequently mixing the exhaust of the first catalytic module 116 with the oxidant 128, a concomitant abatement of remnant Nitrogen oxides (NO), Carbon monoxide (CO), unburnt hydrocarbons (HC), and any excess Ammonia (NH3) could be easily achieved.
  • Moreover, it is hereby also envisioned that by reversing the flow of the oxidant enriched exhaust towards the second catalytic module 134, an increased amount of residence time would be available for the exhaust of the first catalytic module 116 in the housing of the exhaust aftertreatment system 104 so that the exhaust can be abated of its undesired constituents. Due to this, a reduction in the amount of the undesired constituents would be enhanced as compared to that accomplished with use of previously known aftertreatment systems. Therefore, with use of embodiments herein, a conversion efficiency of the aftertreatment system disclosed herein may be greater than that typically associated with use of previously known aftertreatment systems resulting in an improved abatement of the undesired emissions in the exhaust, and lesser detrimental effects to the atmosphere.
  • While aspects of the present disclosure have been particularly shown and described with reference to the embodiments above, it will be understood by those skilled in the art that various additional embodiments may be contemplated by the modification of the disclosed machines, systems, methods and processes without departing from the spirit and scope of what is disclosed. Such embodiments should be understood to fall within the scope of the present disclosure as determined based upon the claims and any equivalents thereof.

Claims (18)

1. An exhaust aftertreatment system for an engine operating within a range of stoichiometric and sub-stoichiometric air-fuel ratios (0.92<λ≤1), the exhaust aftertreatment system comprising:
an exhaust passageway;
a first catalytic module having an inlet disposed in fluid communication with the exhaust passageway for receiving exhaust from the exhaust passageway;
a first device for introducing an oxidant into the exhaust of the first catalytic module;
a second device for mixing the introduced oxidant with the exhaust of the first catalytic module;
a second catalytic module concentric with the first catalytic module such that heat transfer is facilitated between the first and second catalytic modules while exhaust is prevented from flowing radially between the first and second catalytic modules; and
a housing positioned between the first catalytic module and the second catalytic module for diverting the exhaust from an outlet of the first catalytic module to an inlet of the second catalytic module.
2. The exhaust aftertreatment system of claim 1, wherein the inlet of the first catalytic module is coupled to an outlet of a conduit defining the exhaust passageway.
3. The exhaust aftertreatment system of claim 2, wherein the inlet of the first catalytic module is joined with the outlet of the conduit by an adhesive.
4. The exhaust aftertreatment system of claim 2, wherein the inlet of the first catalytic module is joined with the outlet of the conduit using a compressible fiber mat.
5. The exhaust aftertreatment system of claim 2 further comprising a compression seal positioned between the inlet of the first catalytic module and the outlet of the conduit.
6. The exhaust aftertreatment system of claim 1, wherein the inlet of the first catalytic module is positioned proximal to an outlet of a conduit defining the exhaust passageway.
7. The exhaust aftertreatment system of claim 6, wherein the inlet of the first catalytic module is positioned within a range of 3 to 10 millimeters from the outlet of the conduit.
8. The exhaust aftertreatment system of claim 6, wherein a diameter of the inlet of the first catalytic module is one of: equal to and greater than a diameter associated with the outlet of the conduit.
9. The exhaust aftertreatment system of claim 1, wherein the first catalytic module is formed from a first substrate and the second catalytic module is formed from a second substrate.
10. The exhaust aftertreatment system of claim 9 further comprising an impermeable member between the first and second substrates for preventing the exhaust from flowing radially between the first and second catalytic modules.
11. The exhaust aftertreatment system of claim 10, wherein a co-efficient of thermal expansion associated with the impermeable member is within a predetermined range of, or similar to, a co-efficient of thermal expansion associated with at least one of the first and second substrates.
12. The exhaust aftertreatment system of claim 1, wherein the first and second catalytic modules are formed from a monolithic substrate defining a plurality of channels therethrough.
13. The exhaust aftertreatment system of claim 12, wherein the first and second catalytic modules are separated by an impermeable zone defined in an annular region of the monolithic substrate.
14. The exhaust aftertreatment system of claim 13, wherein the impermeable zone is formed integrally with the monolithic substrate by rendering the annular region of the monolithic substrate between the first and second catalytic modules with zero porosity.
15. The exhaust aftertreatment system of claim 13, wherein the impermeable zone is formed by plugging ends of channels in the annular region of the monolithic substrate with an inert non-catalytic solid.
16. The exhaust aftertreatment system of claim 13, wherein the impermeable zone is defined by filling channels in the annular region of the monolithic substrate with an inert non-porous medium.
17. The exhaust aftertreatment system of claim 1 wherein the housing has a first end and a second end distally located from the first end, such that the inlet of the first catalytic module is positioned proximal to the first end of the housing.
18. The exhaust aftertreatment system of claim 17, wherein the second device is positioned at, or adjacent to the second end of the housing so that the exhaust is mixed with introduced oxidant prior forming an oxidant enriched exhaust that enters the second catalytic module.
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US20220106899A1 (en) * 2019-06-26 2022-04-07 Vitesco Technologies GmbH Exhaust gas aftertreatment device

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US3701823A (en) * 1970-09-02 1972-10-31 Universal Oil Prod Co Method and means for two-stage catalytic treating of engine exhaust gases
US3910770A (en) * 1971-12-23 1975-10-07 Gulf Research Development Co Catalytic converter
US3960510A (en) * 1973-05-21 1976-06-01 W. R. Grace & Co. Honeycomb structure for countercurrent gas flow
US20070157598A1 (en) * 2005-08-22 2007-07-12 Gagov Atanas Plastic components formed from 3D blow molding

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Publication number Priority date Publication date Assignee Title
US3701823A (en) * 1970-09-02 1972-10-31 Universal Oil Prod Co Method and means for two-stage catalytic treating of engine exhaust gases
US3910770A (en) * 1971-12-23 1975-10-07 Gulf Research Development Co Catalytic converter
US3960510A (en) * 1973-05-21 1976-06-01 W. R. Grace & Co. Honeycomb structure for countercurrent gas flow
US20070157598A1 (en) * 2005-08-22 2007-07-12 Gagov Atanas Plastic components formed from 3D blow molding

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* Cited by examiner, † Cited by third party
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US20220106899A1 (en) * 2019-06-26 2022-04-07 Vitesco Technologies GmbH Exhaust gas aftertreatment device

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