US1979943A - Lubricating grease - Google Patents
Lubricating grease Download PDFInfo
- Publication number
- US1979943A US1979943A US471427A US47142730A US1979943A US 1979943 A US1979943 A US 1979943A US 471427 A US471427 A US 471427A US 47142730 A US47142730 A US 47142730A US 1979943 A US1979943 A US 1979943A
- Authority
- US
- United States
- Prior art keywords
- rubber
- grease
- aluminum
- lubricating grease
- soap
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M131/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing halogen
- C10M131/08—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing halogen containing carbon, hydrogen, halogen and oxygen
- C10M131/12—Acids; Salts or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/20—Natural rubber; Natural resins
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/02—Groups 1 or 11
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/06—Groups 3 or 13
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/08—Groups 4 or 14
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/02—Bearings
Definitions
- This invention consists in a new lubricating grease adapted for use in conjunction with bearings carrying heavy loads and subjected to reciprocating forces or repeated shock, namely a lubricating grease compounded with aluminum soap and rubber.
- a stable gel structure is formed that is very resistant to separation usually produced by mechanical working or agitation.
- two samples of grease were compounded at 250 F., from aluminum stearate and 300 seconds Saybolt viscosity at 100 F., napthene base pale oil, one sample containing .5% by weight of rubber hydrocarbon.
- the product is a very stable one, being little affected by mechanical agitation, and consequently when compounded as a semi-fluid grease,
- This product is very adhesive to metallic surfaces, the addition of rubber considerably increasing this property in the grease.
- This adhesive property together with high ductility and its tenacious film-forming ability, all go to produce a very superior and emcient lubricant.
- Rubber for this process may be obtained and used in the form of pale crepe, smoked sheet, rubber latex or para rubber.
- the rubber hydrocarbon employed must first be dissolved in the mineral oil to be used and the two compounded in the usual manner with the aluminum soap.
- the process of dissolving the rubber is rather difiicult so it is preferred to use the rubber latex which is a milky liquid containing globules of rubber hydrocarbon dispersed in a watery medium.
- This process can be carried out at temperatures ranging from 150 to 250 F. for the usual mixture used. When, however, more than about 15% aluminum soap is used, or when the oil employed is of a parafline base these temperatures will range from 250 to 500 F. 35
- a substantially water free lubricating grease comprising mineral lubricating oil, aluminum soap of a higher fatty acid in a quantity suflicient togive the compound the consistency of a grease,
- a lubricating composition comprising as its active ingredients more than about 35% mineral oil, less than about 60% aluminum soap of a fatty acid and less than about 5% uncoagulated rubber from latex.
- a lubricating composition comprising as its active ingredients more than about mineral oil, less than about 15% aluminum soap of a fatty acid and less than 5% uncoagulated rubber from latex.
Description
Patented Nov. 6, 1934 UNITED STATES PATENT OFFICE by mesne assignments,
to Shell Development Company, San Francisco, Salli, a corporation of Delaware No Drawing. 'Application July 28, 1930,
Serial No. 471,427
6 Claims.
This invention consists in a new lubricating grease adapted for use in conjunction with bearings carrying heavy loads and subjected to reciprocating forces or repeated shock, namely a lubricating grease compounded with aluminum soap and rubber. v
The present practice in the commercial manufacture of consistent lubricating greases is to produce various mixtures and combinations of sodium, calcium, aluminum, zinc and lead salts of fatty acids with'hydrocarbon oils. -One of the greatest troubles experienced with such greases is their unstable character and the tendency of the metallic soap and oil phases to separate. In the grease of my new production this tendency is very materially decreased. My previous Patent 1,749,251 shows the particular process for the manufacture of an aluminum soap grease. My present process differs from this in that a small amount of rubber hydrocarbon is incorporated in the mixture, and the process can be carried out at temperatures materially, lower than 335 F. The addition of this rubber is directly responsible for the increased stability of the mixture and the reduction of the tendency ofoil separation. A stable gel structure is formed that is very resistant to separation usually produced by mechanical working or agitation. In order to show the improvement in stability due to the eifect of this material, two samples of grease were compounded at 250 F., from aluminum stearate and 300 seconds Saybolt viscosity at 100 F., napthene base pale oil, one sample containing .5% by weight of rubber hydrocarbon.
' Mixture I II Percent aluminum stearate.-." 9. 5 9. 5 Percent rubber hydrocarbonn O.- 0.5
4 0 Percent 300 pale oil 90. 5 90. 0
The A. S. T. M. penetration at 77 F. (original unworked consistency) was for I-278, for 11- 269. The A. S. T. M. penetration worked at 77 F. strokes in the worker) was for I-over 400, for 11-340. These tests show conclusively the increased stability due to rubber. For a complete description of the method of making this penetration test, reference should be made to Method 31.1 (A. S. T. M., D-2l'l-27T) page 45, U. S. Bureau of Mines Technical Paper 323B, No. 2d, edition of 1927.
The product is a very stable one, being little affected by mechanical agitation, and consequently when compounded as a semi-fluid grease,
is a superior lubricant for gears, wheels, ball and roller bearings. These greases show also very increased ductility, it being possible to draw out a small portion several centimeters before it breaks off. Such greases show a very tenacious and highly adsorbed lubrication film on metallic surfaces and are for this reason superior to mixtures-of soap and mineral oil alone.
This product is very adhesive to metallic surfaces, the addition of rubber considerably increasing this property in the grease. This adhesive property, together with high ductility and its tenacious film-forming ability, all go to produce a very superior and emcient lubricant.
Rubber for this process may be obtained and used in the form of pale crepe, smoked sheet, rubber latex or para rubber. The rubber hydrocarbon employed must first be dissolved in the mineral oil to be used and the two compounded in the usual manner with the aluminum soap. The process of dissolving the rubber is rather difiicult so it is preferred to use the rubber latex which is a milky liquid containing globules of rubber hydrocarbon dispersed in a watery medium.
This process can be carried out at temperatures ranging from 150 to 250 F. for the usual mixture used. When, however, more than about 15% aluminum soap is used, or when the oil employed is of a parafline base these temperatures will range from 250 to 500 F. 35
In theexample of a grease of my invention given above under mixture II, I have specified aluminum stearate. However, I donot limit myself to the use of the stearate alone as any aluminum soap of the higher fatty acids such as stearate, palmitate, or any mixtures of them can be employed. i
It is alsounderstood that the consistency of the product may be varied at will by changing the amounts of rubber hydrocarbon, aluminum soap and mineral oil. Very dense greases may be made containing as much as 60% aluminum soap and 5% rubber hydrocarbon. The invention is extended to include that class of lubricants termed .compounded oils or liquid greases. These are lubricating oils to which small quantities of the alkali or metal salts of the fatty acids have been added. These may contain 1% or even less of aluminum stearate and rubber combined.
I claim as my invention:
1. A substantially water free lubricating grease comprising mineral lubricating oil, aluminum soap of a higher fatty acid in a quantity suflicient togive the compound the consistency of a grease,
5. A lubricating composition comprising as its active ingredients more than about 35% mineral oil, less than about 60% aluminum soap of a fatty acid and less than about 5% uncoagulated rubber from latex.
6. A lubricating composition comprising as its active ingredients more than about mineral oil, less than about 15% aluminum soap of a fatty acid and less than 5% uncoagulated rubber from latex.
EDWIN N. KLEMGARD.
Lib
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US471427A US1979943A (en) | 1930-07-28 | 1930-07-28 | Lubricating grease |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US471427A US1979943A (en) | 1930-07-28 | 1930-07-28 | Lubricating grease |
Publications (1)
Publication Number | Publication Date |
---|---|
US1979943A true US1979943A (en) | 1934-11-06 |
Family
ID=23871591
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US471427A Expired - Lifetime US1979943A (en) | 1930-07-28 | 1930-07-28 | Lubricating grease |
Country Status (1)
Country | Link |
---|---|
US (1) | US1979943A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2732356A (en) * | 1952-02-11 | 1956-01-24 | Oil composition for air | |
US2801967A (en) * | 1955-09-12 | 1957-08-06 | Oil Base | Drilling fluid and method |
-
1930
- 1930-07-28 US US471427A patent/US1979943A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2732356A (en) * | 1952-02-11 | 1956-01-24 | Oil composition for air | |
US2801967A (en) * | 1955-09-12 | 1957-08-06 | Oil Base | Drilling fluid and method |
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