US1922308A - Process for improving vegetable textile materials - Google Patents
Process for improving vegetable textile materials Download PDFInfo
- Publication number
- US1922308A US1922308A US367152A US36715229A US1922308A US 1922308 A US1922308 A US 1922308A US 367152 A US367152 A US 367152A US 36715229 A US36715229 A US 36715229A US 1922308 A US1922308 A US 1922308A
- Authority
- US
- United States
- Prior art keywords
- strength
- sulphide
- per cent
- solution
- textile materials
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 title description 12
- 238000000034 method Methods 0.000 title description 11
- 235000013311 vegetables Nutrition 0.000 title description 6
- 239000004753 textile Substances 0.000 title description 5
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 10
- 239000003513 alkali Substances 0.000 description 8
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- 239000002657 fibrous material Substances 0.000 description 5
- 239000004744 fabric Substances 0.000 description 4
- 238000005517 mercerization Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- ZGHLCBJZQLNUAZ-UHFFFAOYSA-N sodium sulfide nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.[Na+].[Na+].[S-2] ZGHLCBJZQLNUAZ-UHFFFAOYSA-N 0.000 description 2
- 240000008564 Boehmeria nivea Species 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- DPLVEEXVKBWGHE-UHFFFAOYSA-N potassium sulfide Chemical compound [S-2].[K+].[K+] DPLVEEXVKBWGHE-UHFFFAOYSA-N 0.000 description 1
- -1 potassium sulphide Chemical compound 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000005418 vegetable material Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/53—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with hydrogen sulfide or its salts; with polysulfides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
Definitions
- This invention is based on the discovery that by mercerizing textile fibrous material by means of an alkali sulphide solution containing not less than 25 per cent. of alkali sulphide (calculated as NaiS), at a high temperature, the strength of the material both in the dry and in the wet condition is increased in a surprising degree, and the material acquires an excellent silky lustre which is appreciably superior to that obtainable by mercerization in known manner.
- alkali sulphide calculated as NaiS
- the treatment is preferably applied to the material in stretched condition; however, even when stretching is not applied, or is applied only in a slight degree, appreciable advantages are attained, the spun or woven material acquiring .a wool-like character and an increased strength.
- Example 1 --Cotton yarn is treated in the stretched condition for 5 minutes in a solution of crystallized sodium sulphide of 100 per cent. strength (prepared by melting the crystallized sulphide in its own water of crystallization) at a temperature of 115 C.; it is then passed through boiling water, acidified, washed and dried.
- crystallized sodium sulphide 100 per cent. strength (prepared by melting the crystallized sulphide in its own water of crystallization) at a temperature of 115 C.; it is then passed through boiling water, acidified, washed and dried.
- the yarn thus treated has a fine silky lustre and in comparison with untreated yarn its strength in the dry state has increased by 66 per cent. and in the wet state by 59.34 per cent.
- Example 2 A suitable cotton fabric is treated in stretched condition with a solution of crystallized sodium sulphide of 100 per cent. strength at 115 C. for to 5 minutes, after which it is passed through boiling water, acidified, washed and dried.
- Example 3 The procedure is as in Example 1 or Example 2, with the exception that the treatment is conducted at 100 C.
- Example 4 The procedure is as in Example 1 or Example 2, with the exception that there is used a solution of crystallized sodium sulphide of 84 per cent. strength (calculated as Na2S.9H2O) and the treatment is conducted at 100 C.
- Example 5 The procedure is as in Example 1 or Example 2, with the exception that there is used a solution of sodium sulphide of 58 per cent. strength (calculated as NazS) and the treatment is conducted at 100 C.
- Example 6 The procedure is as in any of the preceding examples, with the exception that stretching is not applied to the material, so that during the treatment with the hot sodium solution, the fabric is free to contract both in the longitudinal and in the transverse direction.
- any of the additional materials customary in the art of mercerization may be added to the sodium sulphide solutions therein prescribed.
- sodium sulphide an equivalent quantity of another alkali sulphide, such as potassium sulphide, may be used.
- alkali sulphide solution of any strength. from 25 per cent. (calulated as crystalline Na2S.9H2O) to solutions saturated at the temperature desired for the treatment may be used. And as to the temperatures, such of from 100 to 180 C. may be used, provided that, if high temperatures, for instance such exceeding 120 C. are used, the time of treatment is accordingly abbreviated.
- textile fibrous material as used in the specification and claims is intended to include wherever the context permits, all veg- .etable fibrous material, such as flax, linen, hemp, ramie, jute and particularly cotton, whether in the form of pure vegetable material, such as pure cotton fabric, or in the form of mixed material, and whether in the form of yarn in skeins or cops, or in the form of warps, or in the form of woven material.
- a method of treating vegetable fibrous materiel which comprises contacting the same with an alkali metal sulphide solution of not less than 25 per cent. strength at a temperature of not less than 100 C.
- a DI'OCGSSoWhlCh comprises treating vegetable fibrous material with a solution made by heating crystalline alkali metal sulphide at a temperature of approximately 115 C.
- a process which comprises treating vegetable fibrous material with an alkali sulphide solution of not less than 25 per cent. strength at a temperature of not less than 100 C.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Artificial Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT320062X | 1928-06-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1922308A true US1922308A (en) | 1933-08-15 |
Family
ID=3671542
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US367150A Expired - Lifetime US1989101A (en) | 1928-06-16 | 1929-05-29 | Process for improving artificial fibers or fabrics |
| US367152A Expired - Lifetime US1922308A (en) | 1928-06-16 | 1929-05-29 | Process for improving vegetable textile materials |
| US367154A Expired - Lifetime US1989100A (en) | 1928-06-16 | 1929-05-29 | Process for improving artificial fibrous material |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US367150A Expired - Lifetime US1989101A (en) | 1928-06-16 | 1929-05-29 | Process for improving artificial fibers or fabrics |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US367154A Expired - Lifetime US1989100A (en) | 1928-06-16 | 1929-05-29 | Process for improving artificial fibrous material |
Country Status (5)
| Country | Link |
|---|---|
| US (3) | US1989101A (ko) |
| BE (3) | BE361564A (ko) |
| DE (2) | DE701449C (ko) |
| FR (6) | FR676764A (ko) |
| NL (3) | NL31170C (ko) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2506043A (en) * | 1943-04-22 | 1950-05-02 | Cilander Ag | Process for obtaining transparent effects on regenerated cellulose fibers |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3124860A (en) * | 1964-03-17 | Textile process and product | ||
| DE753609C (de) * | 1941-09-25 | 1954-08-23 | Goldberger Sam | Verfahren zum Appretieren von Cellulosetextilgut mit Cellulosehydrat |
| BE461347A (ko) * | 1944-12-27 | |||
| US2497519A (en) * | 1946-12-04 | 1950-02-14 | Alrose Chemical Company | Art of stabilizing rayon type fabric |
| US2541457A (en) * | 1947-05-23 | 1951-02-13 | Alrose Chemical Company | Cellulosic textile shrinkage control and crease resistance with inhibited tenderizing action |
| US2512951A (en) * | 1947-06-16 | 1950-06-27 | Dixie Mercerizing Company | Mercerization |
| GB1230096A (ko) * | 1967-05-23 | 1971-04-28 |
-
0
- BE BE361531D patent/BE361531A/xx unknown
- NL NL29923D patent/NL29923C/xx active
- BE BE361532D patent/BE361532A/xx unknown
- NL NL28485D patent/NL28485C/xx active
- BE BE361564D patent/BE361564A/xx unknown
- NL NL31170D patent/NL31170C/xx active
-
1929
- 1929-05-29 US US367150A patent/US1989101A/en not_active Expired - Lifetime
- 1929-05-29 US US367152A patent/US1922308A/en not_active Expired - Lifetime
- 1929-05-29 US US367154A patent/US1989100A/en not_active Expired - Lifetime
- 1929-06-15 FR FR676764D patent/FR676764A/fr not_active Expired
- 1929-06-15 FR FR676766D patent/FR676766A/fr not_active Expired
- 1929-06-16 DE DE1929L0075420 patent/DE701449C/de not_active Expired
- 1929-06-17 FR FR676781D patent/FR676781A/fr not_active Expired
- 1929-06-17 FR FR676783D patent/FR676783A/fr not_active Expired
- 1929-06-17 FR FR676782D patent/FR676782A/fr not_active Expired
- 1929-06-17 FR FR679149D patent/FR679149A/fr not_active Expired
- 1929-06-18 DE DEL75436D patent/DE547204C/de not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2506043A (en) * | 1943-04-22 | 1950-05-02 | Cilander Ag | Process for obtaining transparent effects on regenerated cellulose fibers |
| US2506040A (en) * | 1943-04-22 | 1950-05-02 | Cilander Ag | Process for obtaining transparent effects on regenerated cellulose fibers |
| US2506042A (en) * | 1943-04-22 | 1950-05-02 | Cilander Ag | Process for obtaining transparent effects on regenerated cellulose fibers |
| US2506041A (en) * | 1943-04-22 | 1950-05-02 | Cilander Ag | Process for obtaining transparent effects on regenerated cellulose fibers |
Also Published As
| Publication number | Publication date |
|---|---|
| NL29923C (ko) | |
| NL31170C (ko) | |
| NL28485C (ko) | |
| FR676764A (fr) | 1930-02-27 |
| BE361532A (ko) | |
| DE547204C (de) | 1932-03-30 |
| DE701449C (de) | 1941-01-16 |
| US1989101A (en) | 1935-01-29 |
| FR676781A (fr) | 1930-02-27 |
| FR676782A (fr) | 1930-02-27 |
| BE361531A (ko) | |
| FR676783A (fr) | 1930-02-27 |
| FR676766A (fr) | 1930-02-27 |
| FR679149A (fr) | 1930-04-09 |
| BE361564A (ko) | |
| US1989100A (en) | 1935-01-29 |
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