US1907890A - Annealing and coating a base with a metal - Google Patents

Annealing and coating a base with a metal Download PDF

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Publication number
US1907890A
US1907890A US198916A US19891627A US1907890A US 1907890 A US1907890 A US 1907890A US 198916 A US198916 A US 198916A US 19891627 A US19891627 A US 19891627A US 1907890 A US1907890 A US 1907890A
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Prior art keywords
bath
base
metal
coating
annealing
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Expired - Lifetime
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US198916A
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Abram P Steckel
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COLD METAL PROCESS CO
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COLD METAL PROCESS CO
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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/003—Apparatus
    • C23C2/0034—Details related to elements immersed in bath
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/003—Apparatus
    • C23C2/0034—Details related to elements immersed in bath
    • C23C2/00342—Moving elements, e.g. pumps or mixers
    • C23C2/00344—Means for moving substrates, e.g. immersed rollers or immersed bearings
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/003—Apparatus
    • C23C2/0035—Means for continuously moving substrate through, into or out of the bath
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/003—Apparatus
    • C23C2/0036—Crucibles

Definitions

  • This invention relates to annealing and coating a base with a metal, and is particularly useful for continuously annealing and coating a rolled strip with a metal, such as tin, in the continuous manufacture of tin plate, although the invention has many other applications.
  • I provide for annealing a base and coating it with a metal by subjecting the base to coat-.
  • lnglmetal which is at a temperature at least as lgh as the annealing temperature of the base and cooling the same to a lower tem-,
  • the process is preferably carried out by immersing the base in a bath of coating metal, a
  • Figure 1 is a vertical section through an apparatus emplo 'ng a relatively deep and narrow bath
  • Figure 2 is a similar view through an apparatus employing a relatively long and shalow bath.
  • FIG. 1 there is shown a relatively deep and narrow bath 2 provided with heatin means 3 at the bottom portion and almost filled with a molten coating metal 4, such as-tin.
  • the top of the bath is'divided into two parts by a division wall 5.
  • a suit able flux 6 isplaced on one side of the division wall and palm-oil 7 is provided on the other side.
  • the temperature of the portion is preferably maintained at about 450 F., while the bottom of the bath adja cent the heater is maintained at a temperature which is approximately the annealing temperature of the base, which in this case is rolled steel.
  • the boiling point of tin is perature.
  • Bafiles 8 are the bath there is provided the bath.
  • Strip material 10 is carriedto the coating bath and passes over a guide 11, then downwardl through the flux 6 andinto the molten tin. gpenings 12'are provided in'the bafiles 8 to permit the strip to pass downwardly to the bottom of the bath. At the bottom of a pulley 13 around which the strip turns and passes upwardly through openings 14 in the baflies; At the top 'of the bath the material passes through the palm oil 7 and between exit rolls 15 therein. It then passes over a guide 16 above the top of In operation the unannealed base metal 10 passes through the flux and travels downwardly to the bottom of the bath.
  • the conditions are ideal for coating of the metal and, in fact, a much better adherence of the coating metal to'the base may be expected than would be found in the ordinary tinning bath because of the fact that at the high temperature oh taining near the bottom of the bath an alloying, rather than a mere plating or coat- A in F: rei l is that the downwardly and upmil? each other, so that a heat transfer is set up which saves heat otherwise lost, and the desired gradient through the bath is more easily attai ed.
  • Figure 2 illustrates an embodiment of the moving portions of the base strip areadjacent without undue loss of invention wherein a relatively long and shallow bath is employed.
  • the coating metal 20 is contained in a tank 21 having a row of burners 22 therebeneath. Each burner is provided with a regulating valve 23 so that the desired heat condition along the bath may be maintained.
  • Cross walls 24 are provided adjacent each end of the bath so as to leave bath portions 25 for the reception of flux 26 and palm oil 27 at the entering and leaving ends respectively of the apparatus.
  • a metal base 28 passes over guides 29 which guide it downwardly through the flux into the bath of molten tin and then upwardly through the palm oil.
  • a hood 30 suspended from chains 31.
  • Conduits 32 are provided at either end of the hood 30. These conduits permit of supplying an inert gas, such as nitrogen, above the bath so as to prevent oxidation.
  • the ends of the hood 30 terminate adjacent the cross walls 24, and the small-space in between the hood and the cross walls and between the side walls'of the hood and the tank is filled wi th palm oil, as indicated at 33 so as to el-lmlnate any possibility of oxidation there.
  • the assage of the base through the bath will in uce a flow of tin from left to right in the bath as viewed in the drawing.
  • a byass 34 making connection with the bath adacent the ends of the hood 30 is provided so that the hot tin may flow from the bath at the right hand end back through the conduit to the left hand end of the bath.
  • a cooler 35 is provided for maintaining the tin at the proper temperature.
  • the method of annealing a. base and coating it with a metal which includes immersing the base in a coating metal bath, maintaining a portion of thebath at a temperature at least as high as the, annealing temperature of the base, cooling the entrance and exit portions of the bath below the annealing temperature to cool the base while it .is still immersed in the coating bath, and

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Strip Materials And Filament Materials (AREA)
  • Coating With Molten Metal (AREA)

Description

\ perature' in the v portion of which zone, whereit is annealed. The strip then out of .the bath.-
Patented May 9, 1933 ABRAI P. STECKEL, OF
YOUNGSTOWN,,OHIO, ASSIGNOR TO THE METAL PROCESS COMPANY, A CORPORATION OF OHIO ANNEALIHG- AND COATIN G A BASE WITH A IETAI) Application filed June 15,
This invention relates to annealing and coating a base with a metal, and is particularly useful for continuously annealing and coating a rolled strip with a metal, such as tin, in the continuous manufacture of tin plate, although the invention has many other applications. I
I provide for annealing a base and coating it with a metal by subjecting the base to coat-. lnglmetal which is at a temperature at least as lgh as the annealing temperature of the base and cooling the same to a lower tem-,
absence of oxygen. The process is preferably carried out by immersing the base in a bath of coating metal, a
is maintained at a temperature above the annealing temperature of the base, and while the base is still immersed in the bath, moving it to a portion of the bath which is at a temperature lower than the annealing point. The strip enters the cooler portion of the bath and passes to the hotter passes to a cooler portion of the bath, giving up the heat it has absorbed, and then passes In the accompanyin draw' illustratin two embodiments of the inve n t i on, g
Figure 1 is a vertical section through an apparatus emplo 'ng a relatively deep and narrow bath, an
Figure 2 is a similar view through an apparatus employing a relatively long and shalow bath.
Referring first to Figure 1 there is shown a relatively deep and narrow bath 2 provided with heatin means 3 at the bottom portion and almost filled with a molten coating metal 4, such as-tin. The top of the bath is'divided into two parts by a division wall 5. A suit able flux 6 isplaced on one side of the division wall and palm-oil 7 is provided on the other side.
The temperature of the portion is preferably maintained at about 450 F., while the bottom of the bath adja cent the heater is maintained at a temperature which is approximately the annealing temperature of the base, which in this case is rolled steel. The boiling point of tin is perature. Bafiles 8 are the bath there is provided the bath.
'1ng action, is obtained.
' desirable feature of the apparatus shown bath at the top 1927. Serial No. 198,916.
well above this temperature, so that it is entirel feasible to maintain the lower portion 0 the bath at above the annealing temprovided for impedlng circulation in the bath, thus permitting maintenance of a desired temperature gradient through the bath heat. A cooler 9 is used at the top of the bath to maintainthe desired temperature at that point. 7 1
Strip material 10 is carriedto the coating bath and passes over a guide 11, then downwardl through the flux 6 andinto the molten tin. gpenings 12'are provided in'the bafiles 8 to permit the strip to pass downwardly to the bottom of the bath. At the bottom of a pulley 13 around which the strip turns and passes upwardly through openings 14 in the baflies; At the top 'of the bath the material passes through the palm oil 7 and between exit rolls 15 therein. It then passes over a guide 16 above the top of In operation the unannealed base metal 10 passes through the flux and travels downwardly to the bottom of the bath. During such travel it absorbs heat from the-molten metal and finally reaches a temperature at the bottom of the bath which is above the annealingv oint of'the base. In passing upwardly t e metal is cooled in the absence of oxygen. It is rfectly annealed and no oportunit is, glven for a coating of scale to orm. n the contrary, the conditions are ideal for coating of the metal and, in fact, a much better adherence of the coating metal to'the base may be expected than would be found in the ordinary tinning bath because of the fact that at the high temperature oh taining near the bottom of the bath an alloying, rather than a mere plating or coat- A in F: rei l is that the downwardly and upmil? each other, so that a heat transfer is set up which saves heat otherwise lost, and the desired gradient through the bath is more easily attai ed.
Figure 2 illustrates an embodiment of the moving portions of the base strip areadjacent without undue loss of invention wherein a relatively long and shallow bath is employed. The coating metal 20 is contained in a tank 21 having a row of burners 22 therebeneath. Each burner is provided with a regulating valve 23 so that the desired heat condition along the bath may be maintained. Cross walls 24 are provided adjacent each end of the bath so as to leave bath portions 25 for the reception of flux 26 and palm oil 27 at the entering and leaving ends respectively of the apparatus. A metal base 28 passes over guides 29 which guide it downwardly through the flux into the bath of molten tin and then upwardly through the palm oil.
In order to prevent oxidation of the tin, it is covered by a hood 30 suspended from chains 31. Conduits 32 are provided at either end of the hood 30. These conduits permit of supplying an inert gas, such as nitrogen, above the bath so as to prevent oxidation. The ends of the hood 30 terminate adjacent the cross walls 24, and the small-space in between the hood and the cross walls and between the side walls'of the hood and the tank is filled wi th palm oil, as indicated at 33 so as to el-lmlnate any possibility of oxidation there.
' In operation only a relatively small num ber of the burners 22 will be.empl0yed after the apparatus. has once been brought up to the desired temperature. The burners will he so ad'usted that the central portion of the bath is ept hottest.
The assage of the base through the bath will in uce a flow of tin from left to right in the bath as viewed in the drawing. A byass 34 making connection with the bath adacent the ends of the hood 30 is provided so that the hot tin may flow from the bath at the right hand end back through the conduit to the left hand end of the bath. A cooler 35 is provided for maintaining the tin at the proper temperature.
While I have illustrated preferred embodiments of the invention, it will be understood that the invention is not thus limited, since it may be otherwise practiced or embodied within the scope of the following claims.
I claim: 1. The method of .annealing a base and coating it with a metal, which includes immersing the base in a bath of coating metal at an initial temperature below the annealing temperature of the base, subjecting the.
base while it is still immersed'in the bath to a temperature at least as high as the annealing temperature of .the base, and while the base is still immersed in the bath, cooling it below the annealing temperature.
2. The method of annealing a" base and coating it with a metal, which includes ima mersing the base in a bath of coatingmetal at an initial'temperature be1ow*thev-.annealing temperature of the base,'subjecting the r .is still immersed in the bath, and utilizing the heat given up during the cooling step to assist in heating other base materia 3. The method of annealing a baseand' coating it with a metal, which includes im- -mersing the base in a bath of coating metal,
maintaining one portion of the bath at a temperature at least as high as the annealing temperature of the base, trance and exit of the bath to a lower temperature.
4. The method of annealing a. base and coating it with a metal, which includes immersing the base in a coating metal bath, maintaining a portion of thebath at a temperature at least as high as the, annealing temperature of the base, cooling the entrance and exit portions of the bath below the annealing temperature to cool the base while it .is still immersed in the coating bath, and
withdrawing it whilethus cooled.
In testimony whereof and cooling the en- Ihave hereunto set
US198916A 1927-06-15 1927-06-15 Annealing and coating a base with a metal Expired - Lifetime US1907890A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2430475A (en) * 1942-04-15 1947-11-11 American Rolling Mill Co Process of hot coating metal strip
US3027268A (en) * 1960-01-29 1962-03-27 Herbert E Linden Method and apparatus for coating metals with molten aluminum
DE1189354B (en) * 1953-09-04 1965-03-18 Libbey Owens Ford Glass Co Method and device for coating with soldering metal and marking a strip of low-melting metal, in particular lead
US3479210A (en) * 1968-12-04 1969-11-18 Nat Steel Corp Method and apparatus for controlling coating metal temperature in a hot-dip coating bath
US3792520A (en) * 1971-11-03 1974-02-19 Rohm & Haas Novel, sulfide-resistant antistatic yarn
US3808033A (en) * 1970-01-27 1974-04-30 Nat Steel Corp Continuous metallic strip hot-dip metal coating apparatus

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2430475A (en) * 1942-04-15 1947-11-11 American Rolling Mill Co Process of hot coating metal strip
DE1189354B (en) * 1953-09-04 1965-03-18 Libbey Owens Ford Glass Co Method and device for coating with soldering metal and marking a strip of low-melting metal, in particular lead
US3027268A (en) * 1960-01-29 1962-03-27 Herbert E Linden Method and apparatus for coating metals with molten aluminum
US3479210A (en) * 1968-12-04 1969-11-18 Nat Steel Corp Method and apparatus for controlling coating metal temperature in a hot-dip coating bath
US3808033A (en) * 1970-01-27 1974-04-30 Nat Steel Corp Continuous metallic strip hot-dip metal coating apparatus
US3792520A (en) * 1971-11-03 1974-02-19 Rohm & Haas Novel, sulfide-resistant antistatic yarn

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