US1870251A - Wetting and penetrating agents and process for preparing the same - Google Patents

Wetting and penetrating agents and process for preparing the same Download PDF

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Publication number
US1870251A
US1870251A US415789A US41578929A US1870251A US 1870251 A US1870251 A US 1870251A US 415789 A US415789 A US 415789A US 41578929 A US41578929 A US 41578929A US 1870251 A US1870251 A US 1870251A
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US
United States
Prior art keywords
wetting
terpineol
isopropylated
sulfonated
alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US415789A
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English (en)
Inventor
Clyde O Henke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR708177D priority Critical patent/FR708177A/fr
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Priority to US415789A priority patent/US1870251A/en
Priority to GB37016/30A priority patent/GB368351A/en
Application granted granted Critical
Publication of US1870251A publication Critical patent/US1870251A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00Sulfonic acids; Halides, esters, or anhydrides thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S516/00Colloid systems and wetting agents; subcombinations thereof; processes of
    • Y10S516/01Wetting, emulsifying, dispersing, or stabilizing agents
    • Y10S516/03Organic sulfoxy compound containing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S92/00Expansible chamber devices
    • Y10S92/01Bearing on piston or cylinder

Definitions

  • This invention relates to wetting and penetrating agents and to an improved process utilizing such agents for increasin the wetting and penetrating capacity 0 aqueous treating liquids employed in textile mdustries.
  • wetting agents have previously been proposed for increasing the efficiency of treating baths by employing a large class of reagents known as wetting agents.
  • wetting agents may be mentioned the sulfonic acids of alkylated polynuclearhydrocarbons, such as isopropyl-naphthalene sulfonic acid, diisobutyl-naphthalene sulfonic acid, and isopropyl-tetrahydro-naphthalene sulfonic acid.
  • wetting agents by sulfonating the products obtained by the pyrogenic decomposition of abietic acid containing material, these products being generically described as abietene sulfonic acids in U. S. Patent No. 1,853,352, issued April 12, 1932.
  • menthene alcohols while para-menthanol belongs to the class of menthane alcohols.
  • the terpene alcohols may be used in the technical y pure state, as for example, pure alpha terpineol, or they may be used in admixture withclosely related products.
  • the alpha terpineol may be used in the form of a liquid terpineol, the commercial product containing about 95% alpha terpineol.
  • These new treating agents may be used in the various wet treatment of textiles in acid,
  • Example 1 To parts ofwater are added 0.7 part of a mixture made from 50 parts of abietene sulfonic acid sodium salt, 35parts of liquid terpineol and 15 parts of water. 10 grams of cotton yarn are added to this bath and.
  • Example 1 except that, in preparing the wetting out mixture, instead of using 50. parts carbon and a terpene alcohol.
  • Example 4 An aqueous bath is made up of parts of water and 0.7 part of a mixture composed of 50 parts-of ahietene sulfonic acid, 35 parts of liquid terpincol and 15 parts or water. Wool is then treated in this bath for a few seconds in which time it will be thoroughly wetted.
  • Example 5 A dye bath is made up of Anthrene Violet BNX- (Color Index 1163) There is then added adequate of a mixture composed of 50 parts of abietene sulfonic acid sodium salt and 35 parts of liquid terpineol, 15 parts: of water to give a 1% solution. Cotton 1111- mersed in this bath is dyed in strong and even shades. A similar hath made up but omitting the wetting mixture gives weak and uneven dyeings.
  • terpene alcohol to wetting agent 7 0 1( )0
  • this ratio may be varied within wide ranges.
  • a ratio of 25:.100 is not too small and a ratio of 100: 100 is not too large. While the ratios within these limits give the most desirable results, noticeable improvement may also be obtained in the use of ratios outside said limits.
  • concentration of the entire mixture in the treatment bath is, in the most pre ferred practice, usually around 0.5 to 1%, the limits 0.1% to 5% are not extreme.
  • V 1 The processwhich comprises treating textile fibers with an aqueous solution of a 5 sulfonated polynuclear hydrocarbon of the type that are characterized by strong wetting properties and a terpene alcohol.
  • a wetting inixture comprising an isopropylated sulfonated polynuclear hydrocarbon and a terpene alcohol of the group consisting of alpha -terpineol and para-menthanol.
  • 'A a newcomposition of matter, a wetting mixture comprising an isopropylated sulfonated polynuclear hydrocarbon and alpha-terpineol.
  • v V V 11 As a new composition of matter, an aqueous treating bath containing a, sulfonated polynuclear hydrocarbon of the type that are characterized by strong wetting properties and a terpene alcohol.
  • an aqueous treating bath containing an alkylated sulfonated polynuclear hydrocarbon and a tcrpene alcohol.
  • an aqueous treating bath containing an isopropylated sulfonated polynuclear hydrocarbon and a terpene alcohol.
  • an aqueous treating bath containing an isopropylated sulfonated polynuclear hydrocarbon and a terpene alcohol of the group consisting of alpha-terpineol and para-menthanol.
  • aqueous treating bath containing a wetting mixture comprising an isopropylated sulfonated polynuclear hydrocarbon and alphaterpineol.
  • a wetting mixture comprising an isopropylated' sulfonated polynuclear hydrocarbon and a J menthane alcohol.
  • an aqueous treating bath containing an isopropylated sulfonated: polynuclear hydrocarbon and a menthene alcohol.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Coloring (AREA)
US415789A 1929-12-21 1929-12-21 Wetting and penetrating agents and process for preparing the same Expired - Lifetime US1870251A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
FR708177D FR708177A (sv) 1929-12-21
US415789A US1870251A (en) 1929-12-21 1929-12-21 Wetting and penetrating agents and process for preparing the same
GB37016/30A GB368351A (en) 1929-12-21 1930-12-08 Wetting and penetrating agents and process for utilizing the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US415789A US1870251A (en) 1929-12-21 1929-12-21 Wetting and penetrating agents and process for preparing the same

Publications (1)

Publication Number Publication Date
US1870251A true US1870251A (en) 1932-08-09

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Family Applications (1)

Application Number Title Priority Date Filing Date
US415789A Expired - Lifetime US1870251A (en) 1929-12-21 1929-12-21 Wetting and penetrating agents and process for preparing the same

Country Status (3)

Country Link
US (1) US1870251A (sv)
FR (1) FR708177A (sv)
GB (1) GB368351A (sv)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2915472A (en) * 1956-01-09 1959-12-01 Pressner Samuel Brightening compositions

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2915472A (en) * 1956-01-09 1959-12-01 Pressner Samuel Brightening compositions

Also Published As

Publication number Publication date
GB368351A (en) 1932-03-04
FR708177A (sv)

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