US1852231A - Hair dressing - Google Patents
Hair dressing Download PDFInfo
- Publication number
- US1852231A US1852231A US485829A US48582930A US1852231A US 1852231 A US1852231 A US 1852231A US 485829 A US485829 A US 485829A US 48582930 A US48582930 A US 48582930A US 1852231 A US1852231 A US 1852231A
- Authority
- US
- United States
- Prior art keywords
- hair
- hair dressing
- phosphates
- oil
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 description 16
- 229910019142 PO4 Inorganic materials 0.000 description 14
- 235000021317 phosphate Nutrition 0.000 description 14
- 239000000463 material Substances 0.000 description 10
- 239000003921 oil Substances 0.000 description 7
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 235000019198 oils Nutrition 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 5
- 239000010452 phosphate Substances 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 235000019441 ethanol Nutrition 0.000 description 4
- 239000010775 animal oil Substances 0.000 description 3
- 239000004305 biphenyl Substances 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 239000008158 vegetable oil Substances 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- 241000208152 Geranium Species 0.000 description 2
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 2
- 235000019804 chlorophyll Nutrition 0.000 description 2
- 229930002875 chlorophyll Natural products 0.000 description 2
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 231100000344 non-irritating Toxicity 0.000 description 2
- 239000004006 olive oil Substances 0.000 description 2
- 235000008390 olive oil Nutrition 0.000 description 2
- 235000019271 petrolatum Nutrition 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- MIDXCONKKJTLDX-UHFFFAOYSA-N 3,5-dimethylcyclopentane-1,2-dione Chemical compound CC1CC(C)C(=O)C1=O MIDXCONKKJTLDX-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 235000019489 Almond oil Nutrition 0.000 description 1
- 235000019737 Animal fat Nutrition 0.000 description 1
- 241000416162 Astragalus gummifer Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 244000028419 Styrax benzoin Species 0.000 description 1
- 235000000126 Styrax benzoin Nutrition 0.000 description 1
- 235000008411 Sumatra benzointree Nutrition 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000008168 almond oil Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229960002130 benzoin Drugs 0.000 description 1
- 235000013736 caramel Nutrition 0.000 description 1
- 239000004106 carminic acid Substances 0.000 description 1
- 235000012730 carminic acid Nutrition 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000001926 citrus aurantium l. subsp. bergamia wright et arn. oil Substances 0.000 description 1
- 229940080423 cochineal Drugs 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 235000019717 geranium oil Nutrition 0.000 description 1
- 239000010648 geranium oil Substances 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 235000021384 green leafy vegetables Nutrition 0.000 description 1
- 235000019382 gum benzoic Nutrition 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 235000019719 rose oil Nutrition 0.000 description 1
- 239000010666 rose oil Substances 0.000 description 1
- 150000003870 salicylic acids Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 229940098465 tincture Drugs 0.000 description 1
- 235000010487 tragacanth Nutrition 0.000 description 1
- 239000000196 tragacanth Substances 0.000 description 1
- 229940116362 tragacanth Drugs 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/55—Phosphorus compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
Definitions
- the subject matter of the present invention is concerned with cosmetics, and more particularly with such a material that is suitable for a hair dressing.
- materials of the type in question have consisted usually of a wax or gum, such as beeswax, gum arabic, gum resin, tragacanth, etc., dissolved in ethyl alcohol and mixed with an oil such as a petroleum jelly, glycerine, olive oil or an animal fat, and made to a consistency suitable for a paste or thick liquid.
- a wax or gum such as beeswax, gum arabic, gum resin, tragacanth, etc.
- an oil such as a petroleum jelly, glycerine, olive oil or an animal fat
- These compositions usually also contain small quantities of dye and perfume to impart a desired color and odor thereto, and sufficient be-nzoic, boric, or salicylic acids to prevent rancidity or equivalent decomposition therein when plant or animal products are used.
- the purpose of such hair dressing is to keep the hair in a satisfactory condition, easy to keep combed and smooth in appearance. Frequently, however, the hair thus treated becomes matted, greasy. or otherwise
- tri-aryl phosphates such as 'gphenyl-bi-diphenyh. cresyl-diphenyL, tri-cresyl-, phenyl-dicresyl-, etc, phosphates, to be suitable and effective materials for hair dressing compositions, many'of such phosphates being heavy. almost colorless, viscous liquids.
- a suitable vessel in the usual manner with a quantity of an-oil, such as olive oil, for instance, which serves to moisten and oil the hair and scalp, and also to be beneficial in producing other favorable results with the phosphate employed.
- the phosphate-oil mixture may noW be diluted with or dissolved in alcohol to a desired consistency and, if desired, a small quantity of dyeing material and perfume added.
- the hair dressing composition thus prepared is practically greaseless and may be applied in the usual way, the hair treated maintaining a comb for a lon er time and presenting a smooth and attractlve appearance.
- Emamp le I Phenyl bi-diphenyl (monophenyl bi-orthodiphenyl) phosphate 40 grams Castor oil 25 grams Ethyl alcohol (20 percentwa-ter) perfumed with geranium 1 litre Chlorophyll solution 5 cc.
- Example II Phenyl bi-diphenyl (monophenyl bi-orthodiphenyl) phosphate 40 grams
- liquid organic phosphates were used.
- Many of the compounds coming within the scope of my invention, however, are crystalline salts when pure, but become heavy viscous oils when mixed with other phosphates or even when various impurities are present.
- the usual method for making such phosphates which consists of reacting a phenolic compoundnarily is a crystalline material, is mixed with the other constituents ofrthe' hair dressing composition, such mixture remains practically liquid after the dissolving solvent has been substantially removed therefrom.
- the constituents adapted to be used in conjunction with the materials forming the subject matter of my hair dressing composi- I 1 tion may be much varied. Petroleum jellies or oils may be desirable because of their stability and relative cheapness, but the results obtained thereby are mostly inferior to those obtained by vegetable and animal oils, the
- Perfumes such as rose, geranium, or almond oil in small quantities, are suitable to add to cover the natural tint of the oils or greases of the composition and to impart thereto the odor desired.
- My hair dressing compositions as obtained in the above examples are practically colorless, light to heavy viscous liquids,.which may be conveniently colored by adding thereto small amounts of such coloring materials, for instance, as solutions or extracts of caramel for yellows or browns, cochineal for reds. chlorophyll or bergamot oil for greens, indigo for blues, etc.
- numerous other combinations of materials embodying my invention may be made.
- 'My invention briefly, consists then in a new composition of matter comprising an organic phosphate and suitablefor use as a hair dressing material, thereby providing a composition that is effective, substantially non-irritating, non-poisonous, and which may be conveniently and economically compounded and used.
- a hair dressin composition comprising a tri-aryl phosp ate.
- a hair dressing composition compris 2 in% phenyl bi-diphenyl phosphate.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Cosmetics (AREA)
Description
Patented Apr. 5, W32
UNITED STATES PATENT OFFICE FIRED BRYNER, F MIDLAND, MICHIGAN, ASSIGNOR TO THE DOW CHEMICAL COMPANY, MIDLAND, MICHIGAN, A. CORPORATION OF MICHIGAN HAIR DRESSING No Drawing. Application filed October 1,
The subject matter of the present invention is concerned with cosmetics, and more particularly with such a material that is suitable for a hair dressing.
In the past, materials of the type in question have consisted usually of a wax or gum, such as beeswax, gum arabic, gum resin, tragacanth, etc., dissolved in ethyl alcohol and mixed with an oil such as a petroleum jelly, glycerine, olive oil or an animal fat, and made to a consistency suitable for a paste or thick liquid. These compositions usually also contain small quantities of dye and perfume to impart a desired color and odor thereto, and sufficient be-nzoic, boric, or salicylic acids to prevent rancidity or equivalent decomposition therein when plant or animal products are used. The purpose of such hair dressing is to keep the hair in a satisfactory condition, easy to keep combed and smooth in appearance. Frequently, however, the hair thus treated becomes matted, greasy. or otherwise unattractive due to the crystallization of the constituents thereof when the alcohol solvent evaporates, and for other reasons.
I have found tri-aryl phosphates, such as 'gphenyl-bi-diphenyh. cresyl-diphenyL, tri-cresyl-, phenyl-dicresyl-, etc, phosphates, to be suitable and effective materials for hair dressing compositions, many'of such phosphates being heavy. almost colorless, viscous liquids.
I have also found the substances in question to be practically non-irritating, non-poisonous, and largely tasteless and odorless, and such phosphates to possess germicidal action in sufiicient amount largely to prevent decomposition or other similar action in the composition wherein employed. My invention,then, consists of the features hereinafter fully described and particularly pointed out in the claims, the following description setting forth in detail several approved combinations of ingredients embodying my invention, such disclosed means constituting, however, but several of various ways in which the principle of the invention may be used.
Inproceeding according to my invention. I preferably employ a liquid phosphate as previously indicated and mix the same'in a 1930'. Serial No. 485,829.
suitable vessel in the usual manner with a quantity of an-oil, such as olive oil, for instance, which serves to moisten and oil the hair and scalp, and also to be beneficial in producing other favorable results with the phosphate employed. The phosphate-oil mixture may noW be diluted with or dissolved in alcohol to a desired consistency and, if desired, a small quantity of dyeing material and perfume added. The hair dressing composition thus prepared is practically greaseless and may be applied in the usual way, the hair treated maintaining a comb for a lon er time and presenting a smooth and attractlve appearance.
The following examples set forth several preferred compositions illustrating my invention; it is understood, however,"that such examples do not thus limit my invention.
Emamp le I Phenyl bi-diphenyl (monophenyl bi-orthodiphenyl) phosphate 40 grams Castor oil 25 grams Ethyl alcohol (20 percentwa-ter) perfumed with geranium 1 litre Chlorophyll solution 5 cc.
Example II Phenyl bi-diphenyl (monophenyl bi-orthodiphenyl) phosphate 40 grams In the foregoing examples liquid organic phosphates were used. Many of the compounds ,coming within the scope of my invention, however, are crystalline salts when pure, but become heavy viscous oils when mixed with other phosphates or even when various impurities are present. In the usual method for making such phosphates, which consists of reacting a phenolic compoundnarily is a crystalline material, is mixed with the other constituents ofrthe' hair dressing composition, such mixture remains practically liquid after the dissolving solvent has been substantially removed therefrom.
The constituents adapted to be used in conjunction with the materials forming the subject matter of my hair dressing composi- I 1 tion may be much varied. Petroleum jellies or oils may be desirable because of their stability and relative cheapness, but the results obtained thereby are mostly inferior to those obtained by vegetable and animal oils, the
latter of which, in combination with the phosphates enumerated previously, appear to possess certain hair stimulating and other valuable properties which are practically absent when the petroleum product is similarly used. Although glycerine has been used with/or in place of the vegetable or animal oils, yet it is known to dry up and injure the hair, and therefore the same is preferably not incorporated in my hair dressing composition. Preservatives are necessary when vegetable and animal oils are specified, but when these materials are used with the tri-aryl phosphates, for. instance, the free phenol content of the latter is usually suflicient to make other preservatives unnecessary. When preservatives are indicated, however, boric and salicyclic acids and tincture of benzoin are found adaptable. Perfumes such as rose, geranium, or almond oil in small quantities, are suitable to add to cover the natural tint of the oils or greases of the composition and to impart thereto the odor desired. My hair dressing compositions as obtained in the above examples are practically colorless, light to heavy viscous liquids,.which may be conveniently colored by adding thereto small amounts of such coloring materials, for instance, as solutions or extracts of caramel for yellows or browns, cochineal for reds. chlorophyll or bergamot oil for greens, indigo for blues, etc. Obviously, numerous other combinations of materials embodying my invention may be made.
'My invention, briefly, consists then in a new composition of matter comprising an organic phosphate and suitablefor use as a hair dressing material, thereby providing a composition that is effective, substantially non-irritating, non-poisonous, and which may be conveniently and economically compounded and used.
Other modes of applying the principleof my invention may be employed instead of those explained, change being made as regards the materials employed, provided the ingredients stated by any of the following claims or the equivalent of such stated ingredients be employed.
I therefore particularly point out and distinctly claim as my invention 1. A hair dressin composition comprising a tri-aryl phosp ate.
. A hair dressing composition compris 2 in% phenyl bi-diphenyl phosphate.
FRED BRYNER.
igned by me this 26 day of September,
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US485829A US1852231A (en) | 1930-10-01 | 1930-10-01 | Hair dressing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US485829A US1852231A (en) | 1930-10-01 | 1930-10-01 | Hair dressing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1852231A true US1852231A (en) | 1932-04-05 |
Family
ID=23929598
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US485829A Expired - Lifetime US1852231A (en) | 1930-10-01 | 1930-10-01 | Hair dressing |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1852231A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2622596A (en) * | 1951-03-12 | 1952-12-23 | Freed Irving | Medical appliance |
| US3145104A (en) * | 1959-08-07 | 1964-08-18 | Gisela K Oster | Photographic processes comprising cross-linking of thiol polymers |
| US4002734A (en) * | 1973-10-29 | 1977-01-11 | Pickford Melcina H | Hair grooming composition |
| US20070189998A1 (en) * | 2006-02-13 | 2007-08-16 | Eastman Kodak Company | Oil-in-oil emulsions |
| EP1495749B1 (en) * | 2003-07-07 | 2014-03-26 | Beiersdorf AG | Fixing cosmetic composition allowing multiple reshaping of the hair |
-
1930
- 1930-10-01 US US485829A patent/US1852231A/en not_active Expired - Lifetime
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2622596A (en) * | 1951-03-12 | 1952-12-23 | Freed Irving | Medical appliance |
| US3145104A (en) * | 1959-08-07 | 1964-08-18 | Gisela K Oster | Photographic processes comprising cross-linking of thiol polymers |
| US4002734A (en) * | 1973-10-29 | 1977-01-11 | Pickford Melcina H | Hair grooming composition |
| EP1495749B1 (en) * | 2003-07-07 | 2014-03-26 | Beiersdorf AG | Fixing cosmetic composition allowing multiple reshaping of the hair |
| US20070189998A1 (en) * | 2006-02-13 | 2007-08-16 | Eastman Kodak Company | Oil-in-oil emulsions |
| US8329761B2 (en) * | 2006-02-13 | 2012-12-11 | Eastman Kodak Company | Oil-in-oil emulsions |
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