US1845103A - Alloy - Google Patents

Alloy Download PDF

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Publication number
US1845103A
US1845103A US475396A US47539630A US1845103A US 1845103 A US1845103 A US 1845103A US 475396 A US475396 A US 475396A US 47539630 A US47539630 A US 47539630A US 1845103 A US1845103 A US 1845103A
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US
United States
Prior art keywords
alloy
aluminum
tin
zinc
antimony
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US475396A
Inventor
William A Schubert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HERMAN A SCHUBERT
Original Assignee
HERMAN A SCHUBERT
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HERMAN A SCHUBERT filed Critical HERMAN A SCHUBERT
Priority to US475396A priority Critical patent/US1845103A/en
Application granted granted Critical
Publication of US1845103A publication Critical patent/US1845103A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/26Selection of soldering or welding materials proper with the principal constituent melting at less than 400 degrees C
    • B23K35/262Sn as the principal constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C13/00Alloys based on tin

Definitions

  • My invention relates to alloys and particularly to a new alloy of the solder type.
  • solders of the ordinary type are not well adapted for the soldering of-aluminum
  • audit is also well known that such solders have substantially no period of plasticity between the liquid and solid state. That is, ordinary solders when heated, change very quickly from the solid. to the liquid condition, and vice versa, when cooled.
  • Another object is to provide an alloy of this type which can be used without any flux.
  • a further object is to provide an alloy which can be made plastic at comparatively low temperatures and which will not crack upon cooling.
  • my invention comprises the hereinafter described composition which includes, tin, zinc, antimony, lead and aluminum as alloying elements.
  • My alloy consists principally of zinc and tin, with from about 2.5% to about 12% antimony, lead and aluminum, in about the proportions by weight, hereinafter set forth.
  • the tin content may vary from about 75% to about 35%, andthe zinc content may vary from about 20% to it being understood that the tin is at the low limit of the range when the zinc is at the high limit, and vice versa.
  • the tin content is below about 35% and the zinc content above about 60%, the alloy becomes crystalline in character and does not spread or work well unless an extraordinary amount of heat is applied. Above tin and below about 20% zinc, the alloy lacks the desired period of plasticity Application filed August 14,1930. Serial No. 475,396.
  • the aluminum content may vary from about 0.5% to about 4%.
  • the alloy ens quickly, and lacks the desired plasticity.
  • the aluminum content runs below about 0.5%, the alloy likewise passes quickly from the solid to the liquid state, or vice versa, and lacks plasticity.
  • a very satisfactory composition contains about 2% of antimony, 2% of lead, about 1% aluminum, about 57% of tin, and about 38% of zinc.
  • the zinc and tin contents may be varied within the limits first given above. That is, 75% tin, and 20% zinc, with say 5% of the other elements, or 35% tin and 60% zinc with say 5% of the other elements, form desirable compositions.
  • the alloy hard- No flux is necessary in applying my alloy, and it is particularly adapted as afiller for cracks or holes because it may be placed, spread and smoothed for aconsiderable period before hardening. It adheres readily to aluminum without the use of any flux, and lugs have been soldered to aluminum castings, which could not be knocked off with a hammer, Without fracturing the casting.
  • An alloy containing as essential alloying'ingredients from 40 %ito 70% of tin, from %-to'55% of zinqmorethan 1% and less than 4% of antimony, more than 1 and less than 4% oflead, and more than 0.5% and lessthan 4% of aluminum.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electric Connection Of Electric Components To Printed Circuits (AREA)

Description

Patented Feb. 16, 1932 UNITED STATES PATENT OFFICE WILLIAM A. SCHUIBERT, OF IIROY, NEW YORK, ASSIGNOR 0E ONE-HALF TO HERMAN A.
SCHUBERT, OF TROY, NEW YORK ALLOY No Drawing.
My invention relates to alloys and particularly to a new alloy of the solder type.
It is well known that solders of the ordinary type are not well adapted for the soldering of-aluminum, audit is also well known that such solders have substantially no period of plasticity between the liquid and solid state. That is, ordinary solders when heated, change very quickly from the solid. to the liquid condition, and vice versa, when cooled.
One of the objects of my invention is to provide an alloy having a low melting point fairly comparable with that of ordinary half and half solder, but which will have a comparatively long period of plasticity intermediate the molten and solid states, and which will be of uniform consistency whereby it may readily be worked or shaped as may be desired. Another object is to provide a soldering alloy which is particularly adapted for aluminum, but which may be used with any material which can be tinned with ordinary half and half solder. An
other object is to provide an alloy of this type which can be used without any flux. A further object is to provide an alloy which can be made plastic at comparatively low temperatures and which will not crack upon cooling.
With these objects in view, my invention comprises the hereinafter described composition which includes, tin, zinc, antimony, lead and aluminum as alloying elements.
My alloy consists principally of zinc and tin, with from about 2.5% to about 12% antimony, lead and aluminum, in about the proportions by weight, hereinafter set forth.
The tin content may vary from about 75% to about 35%, andthe zinc content may vary from about 20% to it being understood that the tin is at the low limit of the range when the zinc is at the high limit, and vice versa. When the tin content is below about 35% and the zinc content above about 60%, the alloy becomes crystalline in character and does not spread or work well unless an extraordinary amount of heat is applied. Above tin and below about 20% zinc, the alloy lacks the desired period of plasticity Application filed August 14,1930. Serial No. 475,396.
betweenthe molten and solid condition, and it can not be built up.
The antimony content may vary from about 1% to about 4%. If antimony is incorporated above about 4%, the alloy becomes crystalline, is hard in spots, and lacks homogeneity. If less than about 1% of antimony is used, the alloy does not have the desired plastic stage between the molten and .solid condition, it liquifies rapidly, and cannot be built up.
Thelead content may vary from about 1% to about 4%, but if the content is over about 4%, the lead melts and bubbles out of the alloy bar before the other elements are melt.- ed. If the lead is below about 1%, the alloy is hard in spots and lacks homogeneity.
The aluminum content may vary from about 0.5% to about 4%.
ens quickly, and lacks the desired plasticity. On the other hand, if the aluminum content runs below about 0.5%, the alloy likewise passes quickly from the solid to the liquid state, or vice versa, and lacks plasticity.
A very satisfactory composition contains about 2% of antimony, 2% of lead, about 1% aluminum, about 57% of tin, and about 38% of zinc.
With about 2% of antimony, 2% of lead, and 1% of aluminum, or where the antimony, lead and aluminum are not all at the extreme range limits, the zinc and tin contents may be varied within the limits first given above. That is, 75% tin, and 20% zinc, with say 5% of the other elements, or 35% tin and 60% zinc with say 5% of the other elements, form desirable compositions.
If the aluminum P content runs above about 4%, the alloy hard- No flux is necessary in applying my alloy, and it is particularly adapted as afiller for cracks or holes because it may be placed, spread and smoothed for aconsiderable period before hardening. It adheres readily to aluminum without the use of any flux, and lugs have been soldered to aluminum castings, which could not be knocked off with a hammer, Without fracturing the casting.
I Small 'percentages of copper, and possibly other elements, may be added to'my alloy, but seem to have no effect, either desirable or undesirable on the composition. For example, the following analysis gives a very plastic composition having characteristics typical of my: alloy:
Per cent Sn 55.51 Zn 37.12 Sh 2.48 Gu 1.97 Pb 1.55 AL... 1.35
What "I c'laimis:
1. An alloy containing from35% to 75% of tin, from to 60% ofzinc, from 1% to 4%01 antimony, from 1% to 4%of-lead, and from 0.5% to 4% of aluminum.
2. An alloy containing as essential alloying'ingredients from 40 %ito 70% of tin, from %-to'55% of zinqmorethan 1% and less than 4% of antimony, more than 1 and less than 4% oflead, and more than 0.5% and lessthan 4% of aluminum.
'3. An alloy'eontainingas essential alloyin'g ingredients'from to 75% of tin, 'from 20% to of zinc, from 1.5% to3.5% of antimonyjfrorn 1.0% to 3.5% of lead, and from 0.-% to'3l5% of aluminum.
WILLIAM A. SCHUBERT.
US475396A 1930-08-14 1930-08-14 Alloy Expired - Lifetime US1845103A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2737712A (en) * 1952-07-23 1956-03-13 Fred E Larson Solder and process for making and using same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2737712A (en) * 1952-07-23 1956-03-13 Fred E Larson Solder and process for making and using same

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