US1813247A - Detergent - Google Patents

Detergent Download PDF

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Publication number
US1813247A
US1813247A US41877A US4187725A US1813247A US 1813247 A US1813247 A US 1813247A US 41877 A US41877 A US 41877A US 4187725 A US4187725 A US 4187725A US 1813247 A US1813247 A US 1813247A
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US
United States
Prior art keywords
soap
water
soda ash
clay
detergent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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US41877A
Inventor
Merlub-Sobel Menahem
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Individual
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Individual
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Priority to US41877A priority Critical patent/US1813247A/en
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Publication of US1813247A publication Critical patent/US1813247A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/06Inorganic compounds
    • C11D9/08Water-soluble compounds
    • C11D9/10Salts
    • C11D9/12Carbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06Powder; Flakes; Free-flowing mixtures; Sheets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/06Inorganic compounds
    • C11D9/18Water-insoluble compounds

Definitions

  • soap powders consist escompounds I .sentially of a mixture of soap and soda ash, & I I I mixed hot with an amount of water too small g y m ni Z 3 90%) f to crystallize the s a t when quickly 5&2333152112:::::::::::::::::i a "a s (it Z 05 chilled, as by being poured on a cold surface, W-j- 0 (34% 4 m d rs powders; etc., these nugreat:
  • the objects provedwashmg powder is as follows: of the invention are the provision of a'soap Y (I) I I 5 powder having maximum bulk and enhanced f a brittle cake is produced which is afterwards ,1 ground to a powder and retains its powdery 6 P '-P TP Q are thosegwen 1 condition regardless of all ordinary atmos-v 111 theRaTentheSe$- a 1 3- pheric changesi
  • the amount of soap varies, 1 T 1 6 understood that the m 6o -the customary limits being between about li OfCOmPQSitiOR indicated 9 c a 10% and about 3Q% and such powder are not al be reachedatthe same time
  • P P P 1 g gs that ofthe water up to about 50% ,merals referring-t6 the content of anhydrous gr eat t a
  • powders having'a minimum nda a t latte! quantity vof soap are generally deficient in P t as the Proportlon of the t f'f crease In the case of a powder contaming g5 venti'on. to producefla composition of mm 0%.
  • pt l l X mum soap content whi h ha h a l sary a the concentrat on of active detergent 0w h r t f 1 'th is alreadyso high.
  • colloidal clay Of natural clays the material 40 known. as bentonite'is preferred, but arti P Stlda ash will take P Water from 86.
  • this 'colloidal clay exhibits two important features; first it greatly increases the bulk of the owder, second, it increases the detergent e ect of the same more than would an equal addition of .eithergsoap or soda ash. Accordingly the advantageous effects of this substance are most conspicuous in connection with those soap powders having minimum percentages of soap, owing to the fact that the increased bulkiness is most effective under these conditions, and also I owing to the fact that the feflfect of the clay is more apparent when the amount of soap is already small.
  • a detergent preparation consisting of a pulverized mixture containing approximately z-Soap 10% (anhydrous content), colloidal clay 2 (anhydrous, content), soda ash 45% (anhydrous content water 42
  • a detergent preparation consisting of a pulverized mixture containing approximately z-Soap 10% (anhydrous content), colloidal clay 2 (anhydrous, content), soda ash 45% (anhydrous content water 42

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Description

cleansing power joined with a less expensive j m a composition; Most soap powders consist escompounds I .sentially of a mixture of soap and soda ash, & I I I mixed hot with an amount of water too small g y m ni Z 3 90%) f to crystallize the s a t when quickly 5&2333152112::::::::::::::::::::::i a "a s (it Z 05 chilled, as by being poured on a cold surface, W-j- 0 (34% 4 m d rs powders; etc., these nugreat:
f cleansing power and it i an Qbject of j t' v much ,-larger proportion of the anhydrous soa. 4
is also a known fact d; a bulky Powder 1 tergent action ofthe soap, whlch under these 75 is not only more easil salable, but it exhibits I suprioncleansing e ect and is more easily My improved detergent consists of a pow-- ficial materials. such as kaolin can be eml a'tent ed' l llyi 193l- I i:UNITEDJ;STATES PATENT x p Imus-scam, or n aw 201m, N. Y. 1' o Io Drawing. Application filed July 8, 1925'. Serial No, 41 ,877. x
r t n v This inventiourelatesto detergents and sults with from about 2% to 2%% of the has specialreference to that class of detersame. The" general composition of'my "imgents known as soap powders. The objects provedwashmg powder is as follows: of the invention are the provision of a'soap Y (I) I I 5 powder having maximum bulk and enhanced f a brittle cake is produced which is afterwards ,1 ground to a powder and retains its powdery 6 P '-P TP Q are thosegwen 1 condition regardless of all ordinary atmos-v 111 theRaTentheSe$- a 1 3- pheric changesi The amount of soap varies, 1 T 1 6 understood that the m 6o -the customary limits being between about li OfCOmPQSitiOR indicated 9 c a 10% and about 3Q% and such powder are not al be reachedatthe same time For exordinarily classified in accordance with the amplei t 13 t P to ma tionof soda ash always at least as amount of soul contained be'n known as P P P 1 g gs that ofthe water up to about 50% ,merals referring-t6 the content of anhydrous gr eat t a h Of W ter. between soap-j, However, powders having'a minimum nda a t latte! quantity vof soap are generally deficient in P t as the Proportlon of the t f'f crease In the case of a powder contaming g5 venti'on. to producefla composition of mm 0%. pt l l X mum soap content whi h ha h a l sary a the concentrat on of active detergent 0w h r t f 1 'th is alreadyso high. At decreased soap'per- 9 8 O ore assocl y W1 a centa'g'es, however, the advantage of the clay is-augmented to supplement the reduced dcconditions iseven superior to an ual wei ht of soa as. well I as rendering t e pow er lighter-arid more fluify. ,Theamoun't of water must'be adjusted toboththe clay and the soda ash. It may not exceed the-capacity'of the so soda ash plus'the clay to absorb it and hold it in sensibly dry form and it must not-be present in toosmall a quantity to render the mix- :ture fluid while hot else manufacture is ima spread or disseminated as well as shown less HESS.
- dered mixture of soap, soda ash, water, and
colloidal clay. Of natural clays the material 40 known. as bentonite'is preferred, but arti P Stlda ash will take P Water from 86.
5 to 10 molecules of water depending upon the loyed if rendered colloidal ,in any of the p of manufacture although 5 111016011165 finownmodes." The amounts of such material (equlv cn to b t 0f the 0d1um carmay constitute from about to about, 20% bonate) is the practlcal maximum; while the of the composition I have had the best recolloidal clay will take up about its own 00 wei ht f'water. As a general practice the tota water should be about %-to 50% of y :the mixture. There is no close connectionbetween the amount of the soda ash and that much of it is used as will absorb whatever moisture the clay does not.
As examples of some other successful cornpositions falling within the general outline eretofore given:
' y p I. Percent Soap u 5 -Clay 1 Soda ash;.. .i- 40 0 Water 45 Soap '12 Clay 3 Soda ash 45 Wate-r Soap; 10
soda ash c 50 Water; I 39 (w a 1 Soa i' 85 Cla I Soda asht Water I 3 9 Soap.. 5% to'f 20%' Clay -%'to-;1O% Soda {toget1er malliing 100% and 1Lthe wa er ins cient to or sta 'ze Water the soda ash y i y (9) Soap v 57 to 10% "E er -"s a a? oge er ma ing 1 7 an te g z water at least not materially in V a r --excess ofthe soda ash t a 1 Soap 571m 207 Clay. 17 to 10% Soda ash 20% to W 2 t c (i) Soap 5% to 19% together making "127 to together making 100% and the v Soda ash amount of water at least-not 66 Water 7 substantiallyin excess of the ysodaash.
- signature.
'Whenemployed in admixture with soap and soda ash this 'colloidal clay exhibits two important features; first it greatly increases the bulk of the owder, second, it increases the detergent e ect of the same more than would an equal addition of .eithergsoap or soda ash. Accordingly the advantageous effects of this substance are most conspicuous in connection with those soap powders having minimum percentages of soap, owing to the fact that the increased bulkiness is most effective under these conditions, and also I owing to the fact that the feflfect of the clay is more apparent when the amount of soap is already small. This enables a package of given size to be made and sold more cheapl or a'given amount of cleansing effect to secured by smaller weight of material, or' a' larger quantity of thepowder to be furn ished for a given price, depending upon the choice of the manufacturer.
Having thus described my invention what I claim is:
A detergent preparation consisting of a pulverized mixture containing approximately z-Soap 10% (anhydrous content), colloidal clay 2 (anhydrous, content), soda ash 45% (anhydrous content water 42 In testimonywhereof hereunto aflixmy
US41877A 1925-07-06 1925-07-06 Detergent Expired - Lifetime US1813247A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4166039A (en) * 1973-10-15 1979-08-28 The Proctor & Gamble Company Detergent composition and process

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4166039A (en) * 1973-10-15 1979-08-28 The Proctor & Gamble Company Detergent composition and process

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