US1774180A - Stable mixture of petroleum hydrocarbons and alcohols - Google Patents
Stable mixture of petroleum hydrocarbons and alcohols Download PDFInfo
- Publication number
- US1774180A US1774180A US566881A US56688122A US1774180A US 1774180 A US1774180 A US 1774180A US 566881 A US566881 A US 566881A US 56688122 A US56688122 A US 56688122A US 1774180 A US1774180 A US 1774180A
- Authority
- US
- United States
- Prior art keywords
- alcohol
- alcohols
- composition
- petroleum hydrocarbons
- gasoline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title description 17
- 229930195733 hydrocarbon Natural products 0.000 title description 10
- 150000002430 hydrocarbons Chemical class 0.000 title description 10
- 239000003208 petroleum Substances 0.000 title description 7
- 150000001298 alcohols Chemical class 0.000 title description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 25
- 235000019441 ethanol Nutrition 0.000 description 17
- 150000003333 secondary alcohols Chemical class 0.000 description 14
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 9
- 150000003138 primary alcohols Chemical class 0.000 description 8
- 239000007788 liquid Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 5
- 238000009835 boiling Methods 0.000 description 4
- 239000003209 petroleum derivative Substances 0.000 description 4
- -1 amyl alcohols Chemical group 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 235000001018 Hibiscus sabdariffa Nutrition 0.000 description 1
- 240000004153 Hibiscus sabdariffa Species 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005237 degreasing agent Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5004—Organic solvents
- C11D7/5022—Organic solvents containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/24—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/261—Alcohols; Phenols
Definitions
- Patented Aug. 26, 1930 UNITED STATES "PATENQT OFFICE MATTHEW D. MANN, JR., OF ROSELLE, JERSEY.
- My invention relates to a composition of matter, and more particularly a composition of liquid character. Specifically my invention relates to stable mixtures of petroleum hydrocarbons and a secondary alcohol with or without a primary alcohol as desired, the mixtures being obtained Without the addition of any blending means other than that supplied by the secondary alcohol itself.
- hydrocarbons for some uses are susceptible of modification and improvement by admixture of other components.
- secondary alcohols are exceptionally valuable as modifying a ents.
- These alcohols hitherto very little noWn as to characteristics, when properly employed with liquid hydrocarbons found in petroleum, afford a range of new and useful solvents, paint and varnish thinners, cleaning and degreasing agents, motor fuels, etc. v
- the secondary alcohols may be employed, depending upon the boiling point limitations and particular use in view, and similarly with the petroleum hydrocarbons.
- the lower secondary alcohols should preferably be especially dehydrated; in the case of secondary butyl and secondary amyl alcohols this maybe simply accomplished b mixing the alcohol with a hydrocarbon, suc as gasoline, and allowing a layer separation to occur, and
- the secondary butyl alcohol substantially free from water preliminarily if desired or a mixture of secondary alcohols in which secondary butyl is a large component, is mixed with the petroleum hydro'carbons of desired boiling point, but ordinarily preferably between 110 and 450" F. This forms a homogeneous composition in various proportions useful for many purposes. Although miscible in wide proportions, usually from about 5 to of the secondary alcohol is most advantageous. While various petroleum hydrocarbons may be employed, I prefer gasoline on account of its general availability and cheapness. If desired, primary alcohols, especially ethyl alcohol, can be incorporated in addition, the
- a convenient and very generally useful formula for instance, comprises commercial gasoline secondary butyl alcohol 5%, and ethyl alcohol (of 95% concentration) 15%. This composition will remain homogeneous down to 10 C. or less.
- the secondary butyl alcohol notonly forms withgasoline hydrocarbons, mixtures which are stable without a blending agent, but when in further combination with a diflicultly blendable primary alcohol such as ethyl alcohol, the secondary alcohol acts as a stabilizer or blending agent therefor.
- a composition of matter comprising gasoline ethyl alcohol 15% and secondary butyl alcohol 5%.
- composition of matter comprising 80% gasoline, 15% ethyl alcohol, and 5% secondary butyl alcohol containing not more than 5% water.
- composition of matter consisting of a I gasoline, secondary butyl alcohol and ethyl alcohol.
- composition of matter comprising a gasoline, a primary alcohol, and a secondary alcohol in amount sufi'icient to prevent separation of the primary alcohol at temperatures above 10 C.
- a composition of matter consisting of a liquid petroleum hydrocarbon boiling below 450 F., a secondary alcohol and ethyl alcohol.
- composition of matter consisting of a liquid petroleum hydrocarbon, boiling below 450 F., secondary butyl alcohol and (ethyl alcohol.
- composition of matter consisting of a liquid petroleum hydrocarbon, ethyl alcohol, and secondary butyl alcohol in amount sufiicient to prevent separation of ethyl alcohol at temperatures above 10 C.
- composition of matter comprising a liquid petroleum hydrocarbon, a primary alcohol, and a secondary alcohol operating as the sole blending agent for said primary alcohol and hydrocarbon.
Description
Patented Aug. 26, 1930 UNITED STATES "PATENQT OFFICE MATTHEW D. MANN, JR., OF ROSELLE, JERSEY.
'No Drawing.
My invention relates to a composition of matter, and more particularly a composition of liquid character. Specifically my invention relates to stable mixtures of petroleum hydrocarbons and a secondary alcohol with or without a primary alcohol as desired, the mixtures being obtained Without the addition of any blending means other than that supplied by the secondary alcohol itself. The
10 invention will be fully understood from the following description.
The properties or action of hydrocarbons for some uses are susceptible of modification and improvement by admixture of other components. In particular I have found that secondary alcohols are exceptionally valuable as modifying a ents. These alcohols, hitherto very little noWn as to characteristics, when properly employed with liquid hydrocarbons found in petroleum, afford a range of new and useful solvents, paint and varnish thinners, cleaning and degreasing agents, motor fuels, etc. v
Various of the secondary alcohols (singly. or mixed) may be employed, depending upon the boiling point limitations and particular use in view, and similarly with the petroleum hydrocarbons. For some. combinations the lower secondary alcohols should preferably be especially dehydrated; in the case of secondary butyl and secondary amyl alcohols this maybe simply accomplished b mixing the alcohol with a hydrocarbon, suc as gasoline, and allowing a layer separation to occur, and
then drawing ofl? the alcohol and gasoline from the aqueous layer; but even this is unnecessary with the higher members. The extent to which the dehydration of the alcohol is carried either by the method as outlined'or by any other desirable process depends upon the use to be made of the products. For. most purposes, especially in the case of the lower secondary alcoholssuch as isopropyl and secondary butyl alcohols, a dehydration sufficient to produce a 95-98% alcohol is sufficient, but in some cases the dehydration should be carried out to produce a substantially anhydrous alcohol. I I As an example, I may refer to secondary butyl alcohol and petroleum hydrocarbons of Application filed June 8, 1922. Serial No. 566,881:
the gasoline range. The secondary butyl alcohol, substantially free from water preliminarily if desired or a mixture of secondary alcohols in which secondary butyl is a large component, is mixed with the petroleum hydro'carbons of desired boiling point, but ordinarily preferably between 110 and 450" F. This forms a homogeneous composition in various proportions useful for many purposes. Although miscible in wide proportions, usually from about 5 to of the secondary alcohol is most advantageous. While various petroleum hydrocarbons may be employed, I prefer gasoline on account of its general availability and cheapness. If desired, primary alcohols, especially ethyl alcohol, can be incorporated in addition, the
amounts, as with the case of the secondary alcohols, varying within wide limits depending upon the particular use in view. An 'especial utility enters here from the fact that relatively small proportions of the secondary alcohols suffice for enabling the addition of considerable quantities of undehydrated primary alcohols, even over quite a range oftemperature, and the proportion of the sec ondary alcohol can be closely gaged as required with this in view. A convenient and very generally useful formula, for instance, comprises commercial gasoline secondary butyl alcohol 5%, and ethyl alcohol (of 95% concentration) 15%. This composition will remain homogeneous down to 10 C. or less. As thus seen, the secondary butyl alcohol notonly forms withgasoline hydrocarbons, mixtures which are stable without a blending agent, but when in further combination with a diflicultly blendable primary alcohol such as ethyl alcohol, the secondary alcohol acts as a stabilizer or blending agent therefor.
While in describing my invention I have referred to specific details,'it will be under stood that these are illustrative and in no sense limitative: 'On the contrary the invention is to be regarded as limited only as defined in the following claims, in which it is my intention to claim all inherent novelty as broadly as the prior art permits.
What I claim is:
1. A composition of matter comprising gasoline ethyl alcohol 15% and secondary butyl alcohol 5%. a
2. A composition of matter comprising 80% gasoline, 15% ethyl alcohol, and 5% secondary butyl alcohol containing not more than 5% water.
3. A composition of matter consisting of a I gasoline, secondary butyl alcohol and ethyl alcohol.
4. A composition of matter comprising a gasoline, a primary alcohol, and a secondary alcohol in amount sufi'icient to prevent separation of the primary alcohol at temperatures above 10 C.
5. A composition of matter consisting of a liquid petroleum hydrocarbon boiling below 450 F., a secondary alcohol and ethyl alcohol.
6. A composition of matter consisting of a liquid petroleum hydrocarbon, boiling below 450 F., secondary butyl alcohol and (ethyl alcohol.
7. A composition of matter consisting of a liquid petroleum hydrocarbon, ethyl alcohol, and secondary butyl alcohol in amount sufiicient to prevent separation of ethyl alcohol at temperatures above 10 C.
8. A composition of matter comprising a liquid petroleum hydrocarbon, a primary alcohol, and a secondary alcohol operating as the sole blending agent for said primary alcohol and hydrocarbon. I
' MATTHEW D. MANN,'JR(
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US566881A US1774180A (en) | 1922-06-08 | 1922-06-08 | Stable mixture of petroleum hydrocarbons and alcohols |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US566881A US1774180A (en) | 1922-06-08 | 1922-06-08 | Stable mixture of petroleum hydrocarbons and alcohols |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1774180A true US1774180A (en) | 1930-08-26 |
Family
ID=24264789
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US566881A Expired - Lifetime US1774180A (en) | 1922-06-08 | 1922-06-08 | Stable mixture of petroleum hydrocarbons and alcohols |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1774180A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3330165A1 (en) * | 1983-08-20 | 1985-03-07 | Union Rheinische Braunkohlen Kraftstoff AG, 5000 Köln | ENGINE FUEL |
| US4541836A (en) * | 1982-12-09 | 1985-09-17 | Union Carbide Corporation | Fuel compositions |
| EP0537736A2 (en) * | 1991-10-16 | 1993-04-21 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Detergent for resin-molding mold |
| WO1999035215A2 (en) * | 1998-01-12 | 1999-07-15 | Deborah Wenzel | An additive composition also used as a fuel composition comprising water soluble alcohols |
| US20120144902A1 (en) * | 2010-06-16 | 2012-06-14 | Butamax(Tm) Advanced Biofuels Llc | Oxygenated butanol gasoline composition having good driveability performance |
| US20120151996A1 (en) * | 2010-06-16 | 2012-06-21 | Butamax(Tm) Advanced Biofuels Llc | Oxygenated butanol gasoline composition having good driveability performance |
| US20150322363A1 (en) * | 2001-04-18 | 2015-11-12 | Standard Alcohol Company Of America, Inc | Higher mixed alcohol fuels for internal combustion engines, furnaces, boilers, kilns and gasifiers |
-
1922
- 1922-06-08 US US566881A patent/US1774180A/en not_active Expired - Lifetime
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4541836A (en) * | 1982-12-09 | 1985-09-17 | Union Carbide Corporation | Fuel compositions |
| DE3330165A1 (en) * | 1983-08-20 | 1985-03-07 | Union Rheinische Braunkohlen Kraftstoff AG, 5000 Köln | ENGINE FUEL |
| EP0537736A2 (en) * | 1991-10-16 | 1993-04-21 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Detergent for resin-molding mold |
| EP0537736A3 (en) * | 1991-10-16 | 1993-09-22 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Detergent for resin-molding mold |
| WO1999035215A2 (en) * | 1998-01-12 | 1999-07-15 | Deborah Wenzel | An additive composition also used as a fuel composition comprising water soluble alcohols |
| WO1999035215A3 (en) * | 1998-01-12 | 1999-10-28 | Deborah Wenzel | An additive composition also used as a fuel composition comprising water soluble alcohols |
| US20150322363A1 (en) * | 2001-04-18 | 2015-11-12 | Standard Alcohol Company Of America, Inc | Higher mixed alcohol fuels for internal combustion engines, furnaces, boilers, kilns and gasifiers |
| US20120144902A1 (en) * | 2010-06-16 | 2012-06-14 | Butamax(Tm) Advanced Biofuels Llc | Oxygenated butanol gasoline composition having good driveability performance |
| US8870983B2 (en) * | 2010-06-16 | 2014-10-28 | Butamax Advanced Biofuels Llc | Oxygenated butanol gasoline composition having good driveability performance |
| US8876924B2 (en) * | 2010-06-16 | 2014-11-04 | Butamax Advanced Biofuels Llc | Oxygenated butanol gasoline composition having good driveability performance |
| US20120151996A1 (en) * | 2010-06-16 | 2012-06-21 | Butamax(Tm) Advanced Biofuels Llc | Oxygenated butanol gasoline composition having good driveability performance |
| US9388353B2 (en) | 2010-06-16 | 2016-07-12 | Butamax Advanced Biofuels Llc | Oxygenated butanol gasoline composition having good driveability performance |
| US9873845B2 (en) | 2010-06-16 | 2018-01-23 | Butamax Advanced Biofuels Llc | Oxygenated butanol gasoline composition having good driveability performance |
| US10301563B2 (en) | 2010-06-16 | 2019-05-28 | Butamax Advanced Biofuels Llc | Oxygenated butanol gasoline composition having good driveability performance |
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