US1757838A - Liquid fuel - Google Patents

Liquid fuel Download PDF

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Publication number
US1757838A
US1757838A US714810A US71481024A US1757838A US 1757838 A US1757838 A US 1757838A US 714810 A US714810 A US 714810A US 71481024 A US71481024 A US 71481024A US 1757838 A US1757838 A US 1757838A
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United States
Prior art keywords
gasoline
lead
mixture
alcohol
liquid fuel
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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US714810A
Inventor
Carl O Johns
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Standard Oil Development Co
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Standard Oil Development Co
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Publication date
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Priority to US714810A priority Critical patent/US1757838A/en
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Publication of US1757838A publication Critical patent/US1757838A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/023Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for spark ignition

Definitions

  • This invention relates to motor fuels, and particularly motor fuels which it is desired shall be operable under relatively high "en'- this condition it has been proposed to add to such fuels a metallo-alkyl compound, particularly lead tetraethyl. While effective in reducing the knocking propensities of the fuel, objection is made in some instances to the presence of as much lead as is involved In accordance with the present-invention.
  • the amount of lead or other metallo-alkyl compound necessary to accomplish the desired object can be minimized, it being found that in adding lead tetraethyl to gasoline for instance, the knocking propensity of the gasoline is reduced not in direct proportion with increasing increments of added lead tetraethyl but the first cubic centimeter of lead compound for instance per gallon of gasoline is the most effective While the result of additional increments of the anti-knock agent is successively less.
  • a motor fuel which comprises a mixture of about 95% of gasoline and 5% of ethyl alcohol, and lead tetraethyl in the amount of about 1 cc. per gallon of the mixture.
  • a motor fuel which comprises a mixture of 90-97% of gasoline and 23-10% of an alcohol with a boiling point within the gas-- oline range, and lead tetraethyl in the amount of 12 cc. per gallon of the mixture.
  • a motor fuel which comprises a mixture of gasoline with not to exceed 10% of an I alcohol with a boiling point within the gasoline range, and lead" tetraethyl in amount not to exceed 2 cc. per gallon of the mixture.
  • a motor fuel which comprises a mixture of petroleum hydrocarbons with a relatively small proportion of analcohol'boiling with in the range of said petroleum hydrocarbons, and lead tetraethyl inamount not to exceed 1 2 cc. per gallon of the mixture. g a 5.
  • a motor fuel which comprises petroleum hydrocarbons, an alcohol boiling within the range of said hydrocarbons in relatively small proportion, knock agent.
  • an alcohol as for example ethyl alcohol, methyl alcohol, or
  • alcohol may be added in amount of 13-10% position comprises a mixtureof about 9 5% v of gasoline and 5% of ethyl alcohol, and-1V cc.,of lead tetraethyl per gallon-of the mixture'.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Output Control And Ontrol Of Special Type Engine (AREA)

Description

. in the amount of agent required.
Patented Ma 6, 1930 UNITED. STATES CARL o. JOHNS, or ELIZABETH, NEW JERSEY, nssr'enon TO STANDARD OIL DEVELOP- PATENT OFFICE KENT COMPANY, A CORPORATION OF DELAWARE I LIQUID FUEL No Drawing.
This invention relates to motor fuels, and particularly motor fuels which it is desired shall be operable under relatively high "en'- this condition it has been proposed to add to such fuels a metallo-alkyl compound, particularly lead tetraethyl. While effective in reducing the knocking propensities of the fuel, objection is made in some instances to the presence of as much lead as is involved In accordance with the present-invention. the amount of lead or other metallo-alkyl compound necessary to accomplish the desired object can be minimized, it being found that in adding lead tetraethyl to gasoline for instance, the knocking propensity of the gasoline is reduced not in direct proportion with increasing increments of added lead tetraethyl but the first cubic centimeter of lead compound for instance per gallon of gasoline is the most effective While the result of additional increments of the anti-knock agent is successively less. In preparing a motor fuel, I employ a small amount of lead tetraethyl sufiicient in quantity to produce the first and greatest efiect but instead of addin further increments of lead tetraethyl to equal the total'proportion of the agent heretofore customarily used, I further modify the petroleum hydrocarbons-by the addition Application filed May 21,
1924. Serial No. 714,810.
.the quantity'of anti-knock agent needed in a gasoline to produce afuel that may be used without detonation in internal combustion engines having relatively high compressions.
.I claim: I
1. A motor fuel which comprises a mixture of about 95% of gasoline and 5% of ethyl alcohol, and lead tetraethyl in the amount of about 1 cc. per gallon of the mixture. 2. A motor fuel which comprises a mixture of 90-97% of gasoline and 23-10% of an alcohol with a boiling point within the gas-- oline range, and lead tetraethyl in the amount of 12 cc. per gallon of the mixture. 3. A motor fuel which comprises a mixture of gasoline with not to exceed 10% of an I alcohol with a boiling point within the gasoline range, and lead" tetraethyl in amount not to exceed 2 cc. per gallon of the mixture.
4. A motor fuel which comprises a mixture of petroleum hydrocarbons with a relatively small proportion of analcohol'boiling with in the range of said petroleum hydrocarbons, and lead tetraethyl inamount not to exceed 1 2 cc. per gallon of the mixture. g a 5. A motor fuel which comprises petroleum hydrocarbons, an alcohol boiling within the range of said hydrocarbons in relatively small proportion, knock agent.
4 CARL O. JOHNS.
of a small proportion ,of an alcohol; as for example ethyl alcohol, methyl alcohol, or
isopropyl alcohol or mixtures thereof. The
alcohol may be added in amount of 13-10% position comprises a mixtureof about 9 5% v of gasoline and 5% of ethyl alcohol, and-1V cc.,of lead tetraethyl per gallon-of the mixture'. By using-my preferred type of modified fuel, I am able to materially decrease and a metallo-alkyl anti- A iou
US714810A 1924-05-21 1924-05-21 Liquid fuel Expired - Lifetime US1757838A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US714810A US1757838A (en) 1924-05-21 1924-05-21 Liquid fuel

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US714810A US1757838A (en) 1924-05-21 1924-05-21 Liquid fuel

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US1757838A true US1757838A (en) 1930-05-06

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2897067A (en) * 1954-11-26 1959-07-28 Exxon Research Engineering Co Alcohol-containing gasoline composition
US3030195A (en) * 1959-01-20 1962-04-17 Sun Oil Co Motor fuels
US3901664A (en) * 1971-06-25 1975-08-26 Chevron Res Motor fuel
US3988122A (en) * 1971-06-25 1976-10-26 Chevron Research Company Motor fuel composition
US4154580A (en) * 1974-03-22 1979-05-15 Mobil Oil Corporation Method for producing a stabilized gasoline-alcohol fuel
FR2752583A1 (en) * 1996-08-22 1998-02-27 Rouquette Jean Marie High performance fuel for four=stroke petrol engines

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2897067A (en) * 1954-11-26 1959-07-28 Exxon Research Engineering Co Alcohol-containing gasoline composition
US3030195A (en) * 1959-01-20 1962-04-17 Sun Oil Co Motor fuels
US3901664A (en) * 1971-06-25 1975-08-26 Chevron Res Motor fuel
US3988122A (en) * 1971-06-25 1976-10-26 Chevron Research Company Motor fuel composition
US4154580A (en) * 1974-03-22 1979-05-15 Mobil Oil Corporation Method for producing a stabilized gasoline-alcohol fuel
FR2752583A1 (en) * 1996-08-22 1998-02-27 Rouquette Jean Marie High performance fuel for four=stroke petrol engines

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