US1730009A - Process of making paper and product thereof - Google Patents
Process of making paper and product thereof Download PDFInfo
- Publication number
- US1730009A US1730009A US178503A US17850327A US1730009A US 1730009 A US1730009 A US 1730009A US 178503 A US178503 A US 178503A US 17850327 A US17850327 A US 17850327A US 1730009 A US1730009 A US 1730009A
- Authority
- US
- United States
- Prior art keywords
- paper
- kelp
- product
- algulose
- fibre pulp
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 15
- 241000512259 Ascophyllum nodosum Species 0.000 description 41
- 239000000835 fiber Substances 0.000 description 29
- 235000010443 alginic acid Nutrition 0.000 description 20
- 229920000615 alginic acid Polymers 0.000 description 20
- 239000000783 alginic acid Substances 0.000 description 16
- 229960001126 alginic acid Drugs 0.000 description 16
- 150000004781 alginic acids Chemical class 0.000 description 16
- 239000000463 material Substances 0.000 description 10
- 229920001971 elastomer Polymers 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 8
- 239000011686 zinc sulphate Substances 0.000 description 8
- 235000009529 zinc sulphate Nutrition 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000003513 alkali Substances 0.000 description 5
- 239000000945 filler Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 241001466453 Laminaria Species 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 2
- 239000001639 calcium acetate Substances 0.000 description 2
- 229960005147 calcium acetate Drugs 0.000 description 2
- 235000011092 calcium acetate Nutrition 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- WQZGKKKJIJFFOK-CBPJZXOFSA-N D-Gulose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@H](O)[C@H]1O WQZGKKKJIJFFOK-CBPJZXOFSA-N 0.000 description 1
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052500 inorganic mineral Chemical class 0.000 description 1
- 239000002198 insoluble material Substances 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000004571 lime Chemical class 0.000 description 1
- 239000011707 mineral Chemical class 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/30—Alginic acid or alginates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S524/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S524/925—Natural rubber compositions having nonreactive materials, i.e. NRM, other than: carbon, silicon dioxide, glass titanium dioxide, water, hydrocarbon or halohydrocarbon
Definitions
- My invention relates particularly to an improved process of making paper and other fibrous products and similar materials, as Well as the product thereof which is more resistant to electricity, heat, cold, oils and moisture than paper products heretofore made.
- the object of my invention is to provide a process of the above character,'and product thereof having the above characteristics, and in which the dielectric is very much higher than in the case of previous paper or fibrous products.
- Previously attempts have been made to secure somewhat similar properties by applying a coating in the form of a varnish to the paper but the product so produced becomes stifi' and brittle and loses its natural flexibility and resilience.
- the product made in accordance with my invention has the above desired improved characteristics and at the same time substantially retains the natural flexibility of the fibres.
- Example 1 may take 1 1b., that is to say 454 grams, of cotton rag fibre which has been thoroughly pulped, and add thereto 22 grams of kelp, that is to say, preferably Laminaria containing both the algin compounds and the algulose reduced to an aqueous solution by the incorporation with the kelp of 2 grams of sodium hydroxide dissolved in 25 cc. of Water. These materials are thoroughly mixed together in a pulp beater so as to produce a homogeneous mass. I then add 16 grams of zinc sulphate dissolved in 200 cc. of water and run the beater until the zinc has become thoroughly distributed through the same. The zinc sulphate acts as a precipitant.
- the web of paper is now gilt through a supercalender and the paper 'shed in the usual way in the manufacture of paper.
- the precipitated algin and algulose is compressed into a film through and around the cotton fibres without afiecting the natural flexibility of the fibrous sheet, while the resistance of the product to electricity, heat, cold, oils, moisture, etc., is greatly increased.
- the dielectric of the product is about 450 bolts per mill. thickness, that is to say at least 40% hi her than in the case of paper Without the ad ition of the kelp.
- zinc sulphate I may use other metallic salts, lime or mineral acids as a precipitaut.
- Example 2 In this example of my invention I take 1 1b., that is 454 grams, of cotton rag fibre which has been thoroughly pulped, and add thereto 13 grams of kelp preferably Laminaria containing both the algin compounds and algulose reduce to an aqueous solution by the addition thereto of 1 gram of sodium hydroxide dissolved in 25 cc. of water. To the kelp solution I add 5 grams of raw rubber in the form of latex before the solution is added to the pulp. I thereupon incorporate the resultant solution with the pulp in a pulp heater and then add 18 to 20 grams of calcium acetate dissolved in 200 cc. of water and run the beater until perfect distribution has been obtained to form a homogeneous mass.
- the calcium acetate acts as a precipitant.
- the product is then washed and run onto a screen of a paper making machine to make a web which is drieduntil there is only 5% of moisture left. Then the web is passed through a supercalender with hot rolls to finish the paper as above, in the previous example, in accordance with the usual steps followed in the manufacture of paper.
- the temperature of the hot rolls should be about 240 F.
- I may use, instead of the'rubber, any other binding material including waxes such as beeswax, resins such as rosin, bituminous substances such as asphalt, and I may use as a filler an inert insoluble material in order to obtain the product desired for the several uses to which it may be applied.
- any of these binding material and fillers in the first example of my invention above referredto, or, in fact, in any form of my invention, when desired.
- I may use any of the precipitants as referred to in the first example.
- any other kind of fibre pulp may be used, such as wood pulp, etc.
- algulose and rubber are algulose and rubber, and then forming the same into a paper web.
- the process of making fibrous products which comprises incorporating together fibrous material, a kelp product formed from alginic acid and alkulose, a filler and rubber, and then forming the same into a coherent mass.
- a paper containing a fibre pulp, a kelp product-formed from kel including its alginic acid and algulose, w 'ch has been solubilized with an alkali and rendered insoluble with a precipitant, and a binding material.
- a paper containin a fibre pulp, a kelp product formed from ke including its alginic acid and algulose, w 'ch has been solubilized with an alkali and rendered insoluble glilth a precipitant, abinding material and a 20.
- a fibrous material containing fibre a kelp product formedfrom kelp including its alginic acid and algulose which has been solubilized and then rendered insoluble with a precipitant, and rubber.
Landscapes
- Paper (AREA)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US178503A US1730009A (en) | 1927-03-25 | 1927-03-25 | Process of making paper and product thereof |
GB15287/27A GB287538A (enrdf_load_stackoverflow) | 1927-03-25 | 1927-06-08 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US178503A US1730009A (en) | 1927-03-25 | 1927-03-25 | Process of making paper and product thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
US1730009A true US1730009A (en) | 1929-10-01 |
Family
ID=22652784
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US178503A Expired - Lifetime US1730009A (en) | 1927-03-25 | 1927-03-25 | Process of making paper and product thereof |
Country Status (2)
Country | Link |
---|---|
US (1) | US1730009A (enrdf_load_stackoverflow) |
GB (1) | GB287538A (enrdf_load_stackoverflow) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE845748C (de) * | 1950-03-07 | 1952-08-04 | Zschimmer & Schwarz | Verfahren zur Behandlung von Papierstoff und Papierabwasser |
US2639989A (en) * | 1946-04-25 | 1953-05-26 | United States Gypsum Co | Treatment of cellulosic pulps |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2772970A (en) * | 1952-04-04 | 1956-12-04 | Armstrong Cork Co | Method of making fibrous sheet material containing a synthetic rubber binder |
-
1927
- 1927-03-25 US US178503A patent/US1730009A/en not_active Expired - Lifetime
- 1927-06-08 GB GB15287/27A patent/GB287538A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2639989A (en) * | 1946-04-25 | 1953-05-26 | United States Gypsum Co | Treatment of cellulosic pulps |
DE845748C (de) * | 1950-03-07 | 1952-08-04 | Zschimmer & Schwarz | Verfahren zur Behandlung von Papierstoff und Papierabwasser |
Also Published As
Publication number | Publication date |
---|---|
GB287538A (enrdf_load_stackoverflow) | 1928-07-12 |
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