US1716797A - Method of producing colored smoke clouds - Google Patents

Method of producing colored smoke clouds Download PDF

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Publication number
US1716797A
US1716797A US704081A US70408124A US1716797A US 1716797 A US1716797 A US 1716797A US 704081 A US704081 A US 704081A US 70408124 A US70408124 A US 70408124A US 1716797 A US1716797 A US 1716797A
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Prior art keywords
smoke
producing
colored smoke
clouds
primary
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US704081A
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Savage John Clifford
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    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06DMEANS FOR GENERATING SMOKE OR MIST; GAS-ATTACK COMPOSITIONS; GENERATION OF GAS FOR BLASTING OR PROPULSION (CHEMICAL PART)
    • C06D3/00Generation of smoke or mist (chemical part)

Definitions

  • This invention relates to the formation of colored smoke for signalling, advertising, smoke screen or other work, and has particular but not exclusive reference to the forn ing of clouds or trails of colored smoke from aircraft.
  • My invention comprises a new method of producing colored smoke, and in one phase thereof provides a smoke producing mixture or mixtures which may be non-inflammable or non-toxic.
  • mixtures for the production of colored smoke have depended for their ability to function on the inclusion in their composition of certain chemicals which react with sufficient heat to insure vaporization of the coloring medium, and usually there is actual combustion of one or more of the ingredients for the generation of heat.
  • the heat necessary to vaporize the compound is provided from external and not from internal sources and the compound employed by me does not necessarily include among its constituents material or materials, such as lactose and potassium chlorate, which are expressly included in the usual compound to provide a heat producing reaction.
  • the aim of my invention is to prevent any part of the coloring medium being combusted and I therefore employ a mixture, the
  • This mixture when introduced into the exhaust of a gasoline engine, is vaporized and, when ejected into the air, condenses to form a red smoke.
  • the coloring agent is the aniline dye, and the mineral oil acts as a vehicle and a base smoke, which base smoke is colored by the exceedingly fine particles of the condensed coloring material.
  • WVhile my invention finds its most ready application in connection with the exhaust of an internal combustion engine, its method of operation is not limited to this. I may for example, employ a stream of steam, superheated if necessary, and directly or indirectly into contact with my compound, to provide sufficient heat to effect the necessary vaporization thereof or any other method, the essential factor being that no (or a negligible amount of) combustion shall take place and that the hot gases or vapors shall be sufficient temperature to effect the requisite vaporization.
  • one phase of my invention aims at the prevention of wastage of coloring ma terial by completely avoiding combustion
  • primary/secondary coloration medium I mean a coloration medium producing one of the primary colors of the spectrum, or a shade, to wit a secondary color, as for example purple.
  • the method of producing colored smoke clouds or trails which consists in vaporizing a primary/secondary coloration medium in the absence of combustion and producing a base smoke neutral thereto, and ejecting the two in conjunction into the atmosphere.
  • the method of producing primary/ secondary colored smoke clouds or trails which consists in vaporizing a material which, when condensed, forms a white smoke, vaporizing a primary/secondary coloration medium in the absence of combustion and coloring the base smoke by condensation of the coloration medium vapor.
  • the method of producing primary/secondary colored smoke clouds or trails which consists in mixing oil and a vaporizable coloration medium to form a body which will flow, flowing said body into a chamber subjected to heat wherein the body is vaporized, and ejecting the vapor into the atmosphere.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Botany (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • Aerodynamic Tests, Hydrodynamic Tests, Wind Tunnels, And Water Tanks (AREA)

Description

eirsaoz OR STATES PATENT OFFICE.
JOHN CLIFFORD SAVAGE, OF NEW YORK, N. Y.
METHOD OF PRODUCING No Drawing. Application filed April 3,
This invention relates to the formation of colored smoke for signalling, advertising, smoke screen or other work, and has particular but not exclusive reference to the forn ing of clouds or trails of colored smoke from aircraft.
My invention comprises a new method of producing colored smoke, and in one phase thereof provides a smoke producing mixture or mixtures which may be non-inflammable or non-toxic.
Heretofore, mixtures for the production of colored smoke have depended for their ability to function on the inclusion in their composition of certain chemicals which react with sufficient heat to insure vaporization of the coloring medium, and usually there is actual combustion of one or more of the ingredients for the generation of heat.
In my method the heat necessary to vaporize the compound is provided from external and not from internal sources and the compound employed by me does not necessarily include among its constituents material or materials, such as lactose and potassium chlorate, which are expressly included in the usual compound to provide a heat producing reaction.
I have discovered that all systems of colored smoke production depending upon combustion of one or more ingredients lose in efficiency, for the reason that in every case a certain proportion of the coloring medium is burnt, with consequently a very considerable loss in color value.
The aim of my invention is to prevent any part of the coloring medium being combusted and I therefore employ a mixture, the
pgnstituentsoi which danot react in the COLORED SMOKE cLoU ns.
1924. Serial No. 704,081.
ample of my colored smoke producing mixture is as follows Orange oil soluble aniline dye 10 pounds.
Light mineral lubricating oil 1 gallon. Tetrachlorethane or carbon tetrachloride 1 pint.
This mixture, when introduced into the exhaust of a gasoline engine, is vaporized and, when ejected into the air, condenses to form a red smoke. In practice I have run a pipe from the exhaust manifold of an aeroplane to the rear of the fuselage and have fed the smoke producing mixture into said pipe at a point approximately four feet from the manifold. The coloring agent is the aniline dye, and the mineral oil acts as a vehicle and a base smoke, which base smoke is colored by the exceedingly fine particles of the condensed coloring material.
WVhile my invention finds its most ready application in connection with the exhaust of an internal combustion engine, its method of operation is not limited to this. I may for example, employ a stream of steam, superheated if necessary, and directly or indirectly into contact with my compound, to provide sufficient heat to effect the necessary vaporization thereof or any other method, the essential factor being that no (or a negligible amount of) combustion shall take place and that the hot gases or vapors shall be sufficient temperature to effect the requisite vaporization.
Although one phase of my invention aims at the prevention of wastage of coloring ma terial by completely avoiding combustion, I am aware that in cases where my type of mixture is introduced into the exhaust gases of a gasoline motor, and in cases where such motor is running on an imperfectly carbureted mixture, there may be some free oxygen, carbon monoxide or other combustion supportlng material present in the exhaust gases and consequently some degree of c0mbustion, but such accidental occurrences do not upset the principle of my invention.
To produce a green smoke I employ a mixture of orange oil soluble aniline dye and synthetic indigo blended in suitable proportions to secure the requisite shade of green, the other ingredients remaining the same. Black or dark-grey smokes can be secured by the inclusion of anthracene in the mixture in place of the aniline, or purple smokes by the inclusion of iodine.
In the attached claims by primary/secondary coloration medium I mean a coloration medium producing one of the primary colors of the spectrum, or a shade, to wit a secondary color, as for example purple.
Having described my invention what I claim and desire to secure by Letters Patent is as follows':-
1. The method of producing colored smoke clouds or trails, which consists in vaporizing a primary/secondary coloration medium in the absence of combustion and producing a base smoke neutral thereto, and ejecting the two in conjunction into the atmosphere.
. 2. The method of producing colored smoke clouds or trails, which consists in vaporizing a material which, when condensed, forms a white smoke, and coloring the base smoke by mixing the same wlth a primary/secondary coloration medium in the absence of combustion. V
3. The method of producing primary/ secondary colored smoke clouds or trails, which consists in vaporizing a material which, when condensed, forms a white smoke, vaporizing a primary/secondary coloration medium in the absence of combustion and coloring the base smoke by condensation of the coloration medium vapor.
4. The method of producing primary/secondary colored smoke clouds or trails which consists in subjecting oil and a vaporizable coloration medium to heat whereby the said substances are conjointly vaporized, and ejecting the vapors thus formed into the atmosphere.
5. The method of producing primary/secondary colored smoke clouds or trails which consists in mixing oil and a vaporizable coloration medium to form a body which will flow, flowing said body into a chamber subjected to heat wherein the body is vaporized, and ejecting the vapor into the atmosphere.
6. The method of producing primary/ secondary colored smoke clouds or trails, which consists in vaporizing an oil by sub- "jecting the same to heat, vaporizing a primary/secondary coloration medium, and simultaneously ejecting the said vapors into the atmosphere.
In testimony whereof, I have signed my name to this specification.
JOHN C. SAVAGE
US704081A 1924-04-03 1924-04-03 Method of producing colored smoke clouds Expired - Lifetime US1716797A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0558964A1 (en) * 1992-02-12 1993-09-08 Orient Chemical Industries, Ltd. Colored smoking oil
US5407774A (en) * 1992-07-15 1995-04-18 Orient Chemical Industries, Ltd. Charge control agent and positively chargeable toner for developing electrostatic images
RU2462442C1 (en) * 2011-02-07 2012-09-27 Открытое акционерное общество "Чебоксарское производственное объединение им. В.И. Чапаева" Pyrotechnic smoke-producing composition
RU2570462C1 (en) * 2014-07-07 2015-12-10 Акционерное общество "Чебоксарское производственное объединение имени В.И. Чапаева" Pyrotechnical composition of orange smoke

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0558964A1 (en) * 1992-02-12 1993-09-08 Orient Chemical Industries, Ltd. Colored smoking oil
US5407774A (en) * 1992-07-15 1995-04-18 Orient Chemical Industries, Ltd. Charge control agent and positively chargeable toner for developing electrostatic images
RU2462442C1 (en) * 2011-02-07 2012-09-27 Открытое акционерное общество "Чебоксарское производственное объединение им. В.И. Чапаева" Pyrotechnic smoke-producing composition
RU2570462C1 (en) * 2014-07-07 2015-12-10 Акционерное общество "Чебоксарское производственное объединение имени В.И. Чапаева" Pyrotechnical composition of orange smoke

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