US1697451A - Light-sensitive electric device - Google Patents
Light-sensitive electric device Download PDFInfo
- Publication number
- US1697451A US1697451A US276162A US27616228A US1697451A US 1697451 A US1697451 A US 1697451A US 276162 A US276162 A US 276162A US 27616228 A US27616228 A US 27616228A US 1697451 A US1697451 A US 1697451A
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- United States
- Prior art keywords
- light
- sensitive
- cell
- temperature
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000000463 material Substances 0.000 description 17
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 8
- 238000010276 construction Methods 0.000 description 8
- 239000010408 film Substances 0.000 description 8
- 229910052711 selenium Inorganic materials 0.000 description 8
- 239000011669 selenium Substances 0.000 description 8
- 239000010409 thin film Substances 0.000 description 7
- 239000012530 fluid Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- 230000001276 controlling effect Effects 0.000 description 4
- 239000004020 conductor Substances 0.000 description 3
- 230000003071 parasitic effect Effects 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/08—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof in which radiation controls flow of current through the device, e.g. photoresistors
Definitions
- This invention is for improvements in or relating to light-sensitive electric devices of the type in which light-sensitive materials such as selenium, thallium sulphide, carbon and so forth are used, these beingsubstances which chan e their electrical resistance when expose to radiant energy; the object of the invention is to provide a construction whereby the time-lag of the response of the device is reduced or eliminated, and in-some instances the device is rendered more sensitive.
- the invention accordingly comprises a light-sensitive cell wherein the light-sensitive substance is in the form of a thin film.
- the thin film aforesaid of the-light-sensitive substance may, according to another feature of this invention, be made so thin that it cannot support itself, and in this case the film is disposed on an insulating support which is itself of theminimum thickness necessary to provide the mechanical support'for the film.
- 80 the thin film may conveniently be'ohtained by sputtering it 'on the supporting element.
- the electrical resistance of selenium and other light-sensitive substances varies with its temperature, and the temperature coefficient itself varies, being positive over some ranges of temperature and negative over others: this variation is independent of the resistance variation due to the action of light,
- the present invention therefore 40 comprises further the combination with a light-sensitive cell, of means for controlling its temperature whereby it may be operated in circumstances in which the thermal effect is additive to the optical eflect when radiation falls on the cell, and the sensitivity is thereby considerably increased.
- This invention also comprises the combination with a light-sensitive cell, its circuits and amplifying devices, of means for controlling the temperature of some or all of these parts in order that parasitic currents in the conductors may beaminimized by maintaining them at a low temperature.
- This invention also comprises a construc- 56 tion of light-sensitive cell in which a sub- A Bnrrrsn COMPANY.
- stantially closedchamber has a light-sensitive substance dis in the form of a thin coating onits inner surface, and preferably extending all overthat surface: this chamber has an opening through which radlation can enter 1t to impinge on the lightsensitive substance and be entirely absorbed thereby.
- a light-sensitive cell may be constituted by a light-sensitive fluid or liquid in the form of a thin layer enclosed between two transparent plates or one opaque and.
- F1gure 1 is a perspective view showing a thin film of light-sensitive material mounted on a supporting element;
- Flgure 2 shows an alternative construction in which the light-sensitive element is self-supporting
- Figure 3 is a sectional view showing diagrammatically the ⁇ cell adapted for temperature control.
- FIGS 4 to 8 show diagrammatically various constructions of light-sensitive cell.
- a very thin sheet of mica or other insulating material 10' has a thin film of selenium sputtered on to it, for instance, by'means of an electric are, using the material selenium as one electrode. Electrical contacts are provided at the two ends of the strip in any convenient manner, as for example by spring clips 12.-
- the mica or other insulating support is made of the minimum thickness which will provide suflicient mechanical strength. and rigidity, and the film of selenium is so thin that it would not be mechanically self-supporting.
- a single large crystal of selenium may have conductors attached to its opposite ends 13, 14, and the intervening material is ground away as at'15 so as to, make it as thin as is consistent with the necessary 6 temperature.
- Figure 3 illustrates diagrammatically a light-sensitive j cell in which provision is made for regulating the temperature. It comprises a light-sensitive element 16 which may for example be similar to that illustrated in Figure 1, and it is enclosed in a double-walled chamberlT. A glass, quartz or other transparent window 18 is provided in this chamber to permit the entry of the radiant energy which is to act on the. lightsensitive material. The space between the double walls may be used for. circulating a cooling or heating fluid through pipe-connections 19, or alternatively or additionally a suitable resistance element 20 may be provided for electrically heating the vessel.
- This construction provides a device in which the temperature of the light-sensitive g element 16 can be positively controlled so that it is operated at the most advantageous When light or other radiant energy is to be measured by means of a selenium or similar light-sensitive cell, it is advantageous that the whole of the energy falling on the light-sensitive material should be absorbed thereby, and none lost by reflection or diffusion, as the sensitivity is thereby increased. 7
- the light-sensitive cell may be constructed as illustrated dia- 4 the whole of its interior with the light-sensigrammatically in Figure 4, in which a sub-' stantially closed chamber 21 is coated over tive material.
- a small opening 22 is provided to admit the radiation and with this arrangement it is ensured that all the energy entering the chamber is absorbed, because any energy reflected from the surface is subjected to repeated reflection until it is all absorbed.
- the current which is varied by the variation in resistance of the light-sensitive material, is arranged to traverse the whole of the material, the circuitbeing established by means of two leading-1n wires 23, 24 which -are connected to two points on the inner coating spaced apart, for example diametrically opposite one another.
- the chamber 25 maybe made of metal or other conducting material coated on its'inner surface with a layer 26 of light-sensitive material.
- The. aperture 27 by which the light enters the cell is closedby glass, quartz or other material transparent to the radiation which is-being used.
- the current 1s made to traverse the thickness of the layer or film 26 in a radial direction, one pole of the cell being constituted by the chamber 25 to which a connection 37 is made, and the other by a centrally-disposed nium is used as the end wall of a vessesl 30.
- One connection may be made directly to the outside surface of the plate 29, and the vessel is filled with a conducting liquid in which a terminal 31 constitutes the other pole of the cell.
- the walls of the vessel and the liquid are of course: such as to be transparent to the radiation-which is being used.
- the liquid on that side of the partition 32 whichis not exposed to the radiation may be any suitable conducting liquid, opaque to means 'for controlling their temperature during working in order that they may be caused to operate over a suitable temperature range is which the maximum sensitivity is obtained and parasitic currents are reduced.
- the whole or any desired part of the circuits associated with the cell are preferably also provided with means for maintaining them at a low temperature for the purpose of avoiding or minimizing parasitic currents.
- the temperature control of the whole apparatus may be effected in any desired manner, for example by enclosing the whole of the apparatus in a suitable chamber whereof the temperature can be controlled.
- a resistance unit variable by the action of light comprising an opaqueinsulating hollow body provided with an aperture therein for the passage of light, and having a thinfilm of light sensitive material. deposited on the interior thereof.
- a resistance unit variable by the action: of light comprising an opaque insulating hollow body provided with an a erture therein for the passage of light, and aving a thin film of light sensitive material deposited on the interior thereof, and means for controlling the temperature of said body.
- a resistance unit variable by the action of light comprising an opaque insulating hollow body provided with an aperture therein, and having 'a film of light sensitive material deposited on the interior thereof, a transparent member forming aclosure for said aperture for permitt-in passage of light to the interior of said body and for retaining conducting fluid therein, an electrode extending into said conducting fluid, and anelectrical connection to said light sensitive film.
- a resistance unit variable by the action of'light comprising an opaque insulating hollow body provided with an aperture therein, and having a film'of light sensitive material deposited on the interior thereof, a
- transparent member forming a closure for said aperture for permitting passage of light to the interior of said body and for retaining a conducting fluid therein, an electrode extending into said conducting fluid, a ter-- of light comprising an opaque hollow bodyof substantially spherical shape provided with'an aperture therein for the passage of light, and having a film of light-sensitive material deposited on the major portion of the interior thereof.
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- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Photometry And Measurement Of Optical Pulse Characteristics (AREA)
Description
Jan. 1, 1929. v
J. L. BAIRD LIGHT SENSITIVE ELECTRIC DEVICE Filed Ma 8, 1928 IIYYFITM I IS A w Patented Jan. ;1,- 1929.
UNITED STATES- PATENT oFFlCEa JOHN Loam BAIBD, or LONDON, ENGLAND,- assIeNon r 'rnmivrsroN Lnrrrnn, or
LONDON, ENG AND;
men'r-saNsrrrvn Application filed Kay 8, 1928, Serial No.
I This invention is for improvements in or relating to light-sensitive electric devices of the type in which light-sensitive materials such as selenium, thallium sulphide, carbon and so forth are used, these beingsubstances which chan e their electrical resistance when expose to radiant energy; the object of the invention is to provide a construction whereby the time-lag of the response of the device is reduced or eliminated, and in-some instances the device is rendered more sensitive.
The invention accordingly comprises a light-sensitive cell wherein the light-sensitive substance is in the form of a thin film.
which provides the maximum active area with the minimum weight and heat capacity, so that any response of the material due to change in temperature may, where suitable, be utilized in a'ddition'to the photoelectric effect. I
The thin film aforesaid of the-light-sensitive substance, may, according to another feature of this invention, be made so thin that it cannot support itself, and in this case the film is disposed on an insulating support which is itself of theminimum thickness necessary to provide the mechanical support'for the film. With this arrangement, 80 the thin film may conveniently be'ohtained by sputtering it 'on the supporting element. The electrical resistance of selenium and other light-sensitive substances varies with its temperature, and the temperature coefficient itself varies, being positive over some ranges of temperature and negative over others: this variation is independent of the resistance variation due to the action of light, The present invention therefore 40 comprises further the combination with a light-sensitive cell, of means for controlling its temperature whereby it may be operated in circumstances in which the thermal effect is additive to the optical eflect when radiation falls on the cell, and the sensitivity is thereby considerably increased. This invention also comprises the combination with a light-sensitive cell, its circuits and amplifying devices, of means for controlling the temperature of some or all of these parts in order that parasitic currents in the conductors may beaminimized by maintaining them at a low temperature.
This invention also comprises a construc- 56 tion of light-sensitive cell in which a sub- A Bnrrrsn COMPANY.
nnnc'rarc mivrcn.
278,162, t in Great-Britain-Iay 7, i927.-
stantially closedchamber has a light-sensitive substance dis in the form of a thin coating onits inner surface, and preferably extending all overthat surface: this chamber has an opening through which radlation can enter 1t to impinge on the lightsensitive substance and be entirely absorbed thereby. I y
According-to another feature of this invention a light-sensitive cell may be constituted by a light-sensitive fluid or liquid in the form of a thin layer enclosed between two transparent plates or one opaque and.
one transparent plate.
In the accompanying drawings, which illustrate this invention diagrammatically F1gure 1 is a perspective view showing a thin film of light-sensitive material mounted on a supporting element;
Flgure 2 shows an alternative construction in which the light-sensitive element is self-supporting;
Figure 3 is a sectional view showing diagrammatically the {cell adapted for temperature control; and
Figures 4 to 8 show diagrammatically various constructions of light-sensitive cell.
In the construction illustrated in" Figure 1, a very thin sheet of mica or other insulating material 10' has a thin film of selenium sputtered on to it, for instance, by'means of an electric are, using the material selenium as one electrode. Electrical contacts are provided at the two ends of the strip in any convenient manner, as for example by spring clips 12.- The mica or other insulating support is made of the minimum thickness which will provide suflicient mechanical strength. and rigidity, and the film of selenium is so thin that it would not be mechanically self-supporting.
In the construction illustrated in Figure 2, a single large crystal of selenium may have conductors attached to its opposite ends 13, 14, and the intervening material is ground away as at'15 so as to, make it as thin as is consistent with the necessary 6 temperature.
strip is but small, the heat-capacity of the terminals is not of such great importance.
Figure 3. illustrates diagrammatically a light-sensitive j cell in which provision is made for regulating the temperature. It comprises a light-sensitive element 16 which may for example be similar to that illustrated in Figure 1, and it is enclosed in a double-walled chamberlT. A glass, quartz or other transparent window 18 is provided in this chamber to permit the entry of the radiant energy which is to act on the. lightsensitive material. The space between the double walls may be used for. circulating a cooling or heating fluid through pipe-connections 19, or alternatively or additionally a suitable resistance element 20 may be provided for electrically heating the vessel. This construction provides a device in which the temperature of the light-sensitive g element 16 can be positively controlled so that it is operated at the most advantageous When light or other radiant energy is to be measured by means of a selenium or similar light-sensitive cell, it is advantageous that the whole of the energy falling on the light-sensitive material should be absorbed thereby, and none lost by reflection or diffusion, as the sensitivity is thereby increased. 7
With this object in view the light-sensitive cell may be constructed as illustrated dia- 4 the whole of its interior with the light-sensigrammatically in Figure 4, in which a sub-' stantially closed chamber 21 is coated over tive material. A small opening 22 is provided to admit the radiation and with this arrangement it is ensured that all the energy entering the chamber is absorbed, because any energy reflected from the surface is subjected to repeated reflection until it is all absorbed.
In this arrangement, the current, which is varied by the variation in resistance of the light-sensitive material, is arranged to traverse the whole of the material, the circuitbeing established by means of two leading- 1n wires 23, 24 which -are connected to two points on the inner coating spaced apart, for example diametrically opposite one another.
In the construction illustrated in Figure 5 the chamber 25 maybe made of metal or other conducting material coated on its'inner surface with a layer 26 of light-sensitive material. The. aperture 27 by which the light enters the cell is closedby glass, quartz or other material transparent to the radiation which is-being used. In this case the current 1s made to traverse the thickness of the layer or film 26 in a radial direction, one pole of the cell being constituted by the chamber 25 to which a connection 37 is made, and the other by a centrally-disposed nium is used as the end wall of a vessesl 30.
One connection may be made directly to the outside surface of the plate 29, and the vessel is filled with a conducting liquid in which a terminal 31 constitutes the other pole of the cell. The walls of the vessel and the liquid are of course: such as to be transparent to the radiation-which is being used. A modified construction of such a Cell'is illustrated in Figure 7, in which the selenium vplate32 constitutes a partition in a vessel separating two bodies of liquid which'constitute the electrodes of the cell. The liquid on that side of the partition 32 whichis not exposed to the radiationmay be any suitable conducting liquid, opaque to means 'for controlling their temperature during working in order that they may be caused to operate over a suitable temperature range is which the maximum sensitivity is obtained and parasitic currents are reduced. Also, the whole or any desired part of the circuits associated with the cell, such for example, as the amplifying devices are preferably also provided with means for maintaining them at a low temperature for the purpose of avoiding or minimizing parasitic currents. The temperature control of the whole apparatus may be effected in any desired manner, for example by enclosing the whole of the apparatus in a suitable chamber whereof the temperature can be controlled.
I claim 1. A resistance unit variable by the action of light, comprising an opaqueinsulating hollow body provided with an aperture therein for the passage of light, and having a thinfilm of light sensitive material. deposited on the interior thereof. f
A resistance unit variable by the action: of light, comprising an opaque insulating hollow body provided with an a erture therein for the passage of light, and aving a thin film of light sensitive material deposited on the interior thereof, and means for controlling the temperature of said body. 3. A resistance unit variable by the action of light, comprising an opaque insulating hollow body provided with an aperture therein, and having 'a film of light sensitive material deposited on the interior thereof, a transparent member forming aclosure for said aperture for permitt-in passage of light to the interior of said body and for retaining conducting fluid therein, an electrode extending into said conducting fluid, and anelectrical connection to said light sensitive film.
4. A resistance unit variable by the action of'light, comprising an opaque insulating hollow body provided with an aperture therein, and having a film'of light sensitive material deposited on the interior thereof, a
transparent member forming a closure for said aperture for permitting passage of light to the interior of said body and for retaining a conducting fluid therein, an electrode extending into said conducting fluid, a ter-- of light comprising an opaque hollow bodyof substantially spherical shape provided with'an aperture therein for the passage of light, and having a film of light-sensitive material deposited on the major portion of the interior thereof.
In testimony whereof I aflix mysignature.
' JOHN LOGIE BAIRD.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB653827X | 1927-05-07 | ||
GB1697451X | 1927-05-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
US1697451A true US1697451A (en) | 1929-01-01 |
Family
ID=59713397
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US276162A Expired - Lifetime US1697451A (en) | 1927-05-07 | 1928-05-08 | Light-sensitive electric device |
Country Status (2)
Country | Link |
---|---|
US (1) | US1697451A (en) |
FR (1) | FR653827A (en) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2426494A (en) * | 1943-12-20 | 1947-08-26 | Rca Corp | Heat detection device |
US2442396A (en) * | 1943-05-05 | 1948-06-01 | Mississippi Valley Res Lab Inc | Magneto-optic light rotator |
US2448517A (en) * | 1944-02-09 | 1948-09-07 | Univ Northwestern | Photocell |
US2572079A (en) * | 1947-03-13 | 1951-10-23 | Standard Telephones Cables Ltd | Radiation-sensitive cells and method of making same |
US2606215A (en) * | 1948-11-26 | 1952-08-05 | Weston Electrical Instr Corp | Encased and hermetically sealed photocell |
US2674677A (en) * | 1951-03-17 | 1954-04-06 | Comb Control Corp | Photoconductive cell |
US2779811A (en) * | 1952-04-21 | 1957-01-29 | Vitro Corp Of America | Photo-cell construction |
US2898525A (en) * | 1955-03-15 | 1959-08-04 | Gen Electric | Light responsive system |
US2918584A (en) * | 1955-10-20 | 1959-12-22 | Burroughs Corp | Light responsive electrical device |
US4313024A (en) * | 1977-04-05 | 1982-01-26 | Horne William E | Conversion of solar to electrical energy |
US6018124A (en) * | 1998-01-15 | 2000-01-25 | Lidow; Nicholai Hart | Selenium photo generator cell with fluid top electrode |
-
1928
- 1928-05-03 FR FR653827D patent/FR653827A/en not_active Expired
- 1928-05-08 US US276162A patent/US1697451A/en not_active Expired - Lifetime
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2442396A (en) * | 1943-05-05 | 1948-06-01 | Mississippi Valley Res Lab Inc | Magneto-optic light rotator |
US2426494A (en) * | 1943-12-20 | 1947-08-26 | Rca Corp | Heat detection device |
US2448517A (en) * | 1944-02-09 | 1948-09-07 | Univ Northwestern | Photocell |
US2572079A (en) * | 1947-03-13 | 1951-10-23 | Standard Telephones Cables Ltd | Radiation-sensitive cells and method of making same |
US2606215A (en) * | 1948-11-26 | 1952-08-05 | Weston Electrical Instr Corp | Encased and hermetically sealed photocell |
US2674677A (en) * | 1951-03-17 | 1954-04-06 | Comb Control Corp | Photoconductive cell |
US2779811A (en) * | 1952-04-21 | 1957-01-29 | Vitro Corp Of America | Photo-cell construction |
US2898525A (en) * | 1955-03-15 | 1959-08-04 | Gen Electric | Light responsive system |
US2918584A (en) * | 1955-10-20 | 1959-12-22 | Burroughs Corp | Light responsive electrical device |
US4313024A (en) * | 1977-04-05 | 1982-01-26 | Horne William E | Conversion of solar to electrical energy |
US6018124A (en) * | 1998-01-15 | 2000-01-25 | Lidow; Nicholai Hart | Selenium photo generator cell with fluid top electrode |
US6078007A (en) * | 1998-01-15 | 2000-06-20 | Lidow; Nicholai Hart | Selenium photo generator cell with fluid top electrode |
Also Published As
Publication number | Publication date |
---|---|
FR653827A (en) | 1929-03-28 |
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