US1593296A - Process for the production of moistness-resisting papers - Google Patents
Process for the production of moistness-resisting papers Download PDFInfo
- Publication number
- US1593296A US1593296A US596140A US59614022A US1593296A US 1593296 A US1593296 A US 1593296A US 596140 A US596140 A US 596140A US 59614022 A US59614022 A US 59614022A US 1593296 A US1593296 A US 1593296A
- Authority
- US
- United States
- Prior art keywords
- paper
- substances
- drying
- formaldehyde
- temperatures
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 29
- 230000008569 process Effects 0.000 title description 26
- 238000004519 manufacturing process Methods 0.000 title description 18
- 239000000123 paper Substances 0.000 description 120
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 39
- 239000000126 substance Substances 0.000 description 34
- 238000001035 drying Methods 0.000 description 31
- 239000000243 solution Substances 0.000 description 24
- 230000002378 acidificating effect Effects 0.000 description 19
- 238000010438 heat treatment Methods 0.000 description 18
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 13
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 description 8
- 238000005470 impregnation Methods 0.000 description 8
- 239000002253 acid Substances 0.000 description 7
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 6
- 239000001164 aluminium sulphate Substances 0.000 description 6
- 235000011128 aluminium sulphate Nutrition 0.000 description 6
- 239000000084 colloidal system Substances 0.000 description 6
- 239000003292 glue Substances 0.000 description 6
- 238000004040 coloring Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 238000004026 adhesive bonding Methods 0.000 description 4
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 3
- 230000002421 anti-septic effect Effects 0.000 description 3
- 239000001110 calcium chloride Substances 0.000 description 3
- 229910001628 calcium chloride Inorganic materials 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000010426 asphalt Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 239000005018 casein Substances 0.000 description 2
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 2
- 235000021240 caseins Nutrition 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 230000000249 desinfective effect Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000009877 rendering Methods 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 1
- 241000543381 Cliftonia monophylla Species 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000011088 parchment paper Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000011295 pitch Substances 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/22—Proteins
Definitions
- nnus'r runs or HANAU, GERMANY.
- the duration of the subsequent heating which depends on the quality and on the of the paper, can vary within very wide limits. ltcan be many hours but under certain conditions 'a short subsequent heating of for instance hours, 4 hours duration can give good results.
- the properties of the papers to be produced can be improved by the additional use of colloid bodies such as casein, animal glue and the like, which under the given conditions become hard and insoluble.
- the incorporation of the colloid bodies can precede the treatment of the paper with acid substances and formaldehyde, for instance by addition of casein or animal glue to the pulp. It is however possible also to add these colloid bodies in such a manner that papers which have absorbing capability are impregnated with a solution which contains for instance animal glue besides the acid substances and formaldehyde.
- a magnesium chloride and calcium chloride has proved to be advisable as the solutions of these salts are. capable. even in the presence of formaldehyde, of dissolving comparatively great quantities of animal glue.
- any of the well known moist-devices and eventually several of the same together, can be used.
- salts are used for renllti ' sprinkled l nder certain dering impermeable of meaeee
- the constituents of the solution could be applied separately, one surface of the paper sheet could for instance be painted with a concentrated mixture of dissolvents and a diluting substance for instance could be used for painting the other surface. conditions the impregnating with heated solutions or mixtures of solutions has proved to be advantageous.
- the working method composed of three operations: impregnation, drying and subsequent heating, can be considerably simplilied by executing the impregnation directly -with the drying process for instance in using an impregnating press in such a manner that the paper is conducted through a heat- :ihle dipping device whereupon it is immediately submitted to pressure and conducted over the drying cylinders.
- this working method also the constituents of the impregnating liquid can be applied separately for instance in such a manner thatthe paper is first impregnated with hot salt solution, and pressed whereupon shortly before it gets upon the drying cylinder, formaldehyde is applied to the paper, for instance by sprinding, by conducting the paper over *ollers with formaldehyde or in any other convenient manner, the formaldehyde being preferably applied uponthe surface of the paper which comes in contact with the drying cylinder, wherefrom results, that the formaldehyde, evaporated by the heat, is driven by diffusion at a uniformly distributed state into the paper sheet.
- the Working with impregnating presses has proved to be advantageous in cases in which the renthe paper has been combined with the colouring of the same.
- the process is adopted, amongst other uses, also for the rendering moist proof of spun papers designed to be used for the'production of paper threads, paper fabrics or the like.
- Spun paper rendered moist proof according to this process can be worked directly into impermeable paper threads, fabrics or the like. It is however advisable to insert the impermeating css for manufacturing the paper thread. This can be done in such a manner that for instance the paper in strips, which is spun to threads by simple twisting Whilst being moistened, is impregnated instead. of with water with a solution which according to the invention is designed for rendering the paper moist proof, the paper threads being then dried. and subsequently heated.
- the impermeable paper produced according to the invention can further be refined and improved by being heated in a known manner with varnish, asphaltum, pitch. tar or the like. In the coatings thus applied, threads, light fabrics or the like could be embedded.
- A. process for the production of moistness resisting paper consisting in impregnating the paper with solutions having acidic properties, in drying the impregnated paper at temperatures below 100 C. and in subjecting the dried'paper to a subsequent heating at temperatures from about 60 C. to about 100 C. j
- a process for the production of moistness resisting paper consisting in impregnating the paper with solutions having acidic in drying the impregnated paper at ten'iperatures below 100 C. and in submitting the dried paper to a subsequentheating at temperatures to about 100 C.
- a process for the production of moistness resisting paper consisting in impregnating the paper with a solution of aluminum suiphate as a solution having acidic properties and with formaldehyde, in drying the impregnated paper at temperatures below 100 C. and in subjecting the dried paper to a subsequent heating at temperatures approximately between 6 0 C. and 100 C.
- a process for the production of moistness resisting paper consisting in impregnating the paper with not more than 1% alumiformaldehyde, in drying the impregnatedpaper at temperaand in subjecting the dried paper to a subsequent heating at temperatures from about 60 C. to about 100 C;
- a process for the production of moistness resisting paper consisting in impregnating the paper with not more than 1% aluminum sulphate and with more than 4% formaldehyde, in drying the impregnated paper at temperatures below 100 C. and in subjecting the dried paper to a subsequent heating at temperatures from about. 00 C. to about 100 C.
- A' process tor the production of moistness resisting paper consisting in impregnat ing the paper with substances having acidic properties and with antiseptic substances of which one is formaldehyde, in drying the impregnated paper at temperatures below 100 C. and in subjecting the dried paper to a subsequent heating at temperatures from about C. to about 100 0.
- a process for the production of moistness resisting paper consisting in iu'ipregnating the paper with substances having acidic properties and at the same time are adapted formaldehyde, in drying the impregnated paper at temperatures below 100 C. and in subjecting the dried paper to a subsequent heating at temperatures from about 00 C. to about 100 C.
- a process for the production of moistness resisting paper consisting in impregnating the paper with substances having acidic properties, with antiseptic substances of which one is formaldehyde and with organic colloids, in dryingthe impregnated paper at temperatures below 100 C. and in subjecting the dried paper to a subsequent heating at temperatures from about (30 C. to about 100 C.
- a process for the production of moistness resisting paper consisting in impregnating the. paper with substances having acidic properties and at the same time are adapted to render the paper supple, with formaldehyde, and with organic colloid substances, in drying the impregnated paper at temperatures below 100 C. and in subjecting the dried paper to a subsequent heating at temperatures from about 00 C. to about 100 C.
- a process for the production of moistness resisting paper consisting in impregnating the paper with substances having acidic. properties and with formaldehyde, in such a manner that solutions for higher concentrations are used at degrees of impregnation which amount to less than 10% ot' the weight of the paper pulp, in drying the impregnated paper at temperatures below 100 C. and in subjecting the dried paper to a subsequent heating at temperatures from about 60 C. to about 100 C.
Landscapes
- Paper (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| YU33726X | 1921-10-29 | ||
| YU33726X | 1922-08-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1593296A true US1593296A (en) | 1926-07-20 |
Family
ID=27130847
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US596140A Expired - Lifetime US1593296A (en) | 1921-10-29 | 1922-10-21 | Process for the production of moistness-resisting papers |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US1593296A (da) |
| AT (1) | AT100719B (da) |
| DE (1) | DE415557C (da) |
| DK (1) | DK33726C (da) |
| GB (2) | GB187987A (da) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2767178A (en) * | 1952-01-14 | 1956-10-16 | Dearborn Chemicals Co | Method for the preparation of nitrites of organic amines |
| US3265463A (en) * | 1961-11-17 | 1966-08-09 | Burlington Industries Inc | Continuous method of imparting wet and dry crease resistance to cellulosic materials through reaction with formaldehyde |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2498207A (en) * | 1945-09-06 | 1950-02-21 | Champion Paper & Fibre Company | Paper coating composition and coated paper |
-
1922
- 1922-10-14 DE DEF52744D patent/DE415557C/de not_active Expired
- 1922-10-16 AT AT100719D patent/AT100719B/de active
- 1922-10-21 US US596140A patent/US1593296A/en not_active Expired - Lifetime
- 1922-10-23 DK DK33726D patent/DK33726C/da active
- 1922-10-28 GB GB29491/22A patent/GB187987A/en not_active Expired
-
1923
- 1923-08-09 GB GB20321/23A patent/GB202314A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2767178A (en) * | 1952-01-14 | 1956-10-16 | Dearborn Chemicals Co | Method for the preparation of nitrites of organic amines |
| US3265463A (en) * | 1961-11-17 | 1966-08-09 | Burlington Industries Inc | Continuous method of imparting wet and dry crease resistance to cellulosic materials through reaction with formaldehyde |
Also Published As
| Publication number | Publication date |
|---|---|
| DE415557C (de) | 1925-06-29 |
| AT100719B (de) | 1925-08-10 |
| GB202314A (en) | 1924-06-19 |
| GB187987A (en) | 1924-01-28 |
| DK33726C (da) | 1924-10-06 |
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