US1557257A - Motor fuel - Google Patents

Motor fuel Download PDF

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Publication number
US1557257A
US1557257A US52688A US5268825A US1557257A US 1557257 A US1557257 A US 1557257A US 52688 A US52688 A US 52688A US 5268825 A US5268825 A US 5268825A US 1557257 A US1557257 A US 1557257A
Authority
US
United States
Prior art keywords
fuel
aniline
ether
motor fuel
gasoline
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US52688A
Inventor
Riboisiere Jean La
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to US52688A priority Critical patent/US1557257A/en
Application granted granted Critical
Publication of US1557257A publication Critical patent/US1557257A/en
Priority to FR620595D priority patent/FR620595A/en
Priority to GB20942/26A priority patent/GB257613A/en
Priority to DER68540D priority patent/DE486778C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1857—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/223—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond having at least one amino group bound to an aromatic carbon atom

Definitions

  • This invention relates to fuels, for in ternal combustion engines. More specifically my invention relates to the prevention of engine knock, and to the provision of a fuel which is economically efficient and will admirably remove that which is commonly formed by addlng to liquid hydrocarbons,
  • aniline or its derivatives and a blending agent, preferably ether.
  • a fuel has been found to possess remarkable anti-knock qualities.
  • my invention is directed to a motor fuel in which aniline itself is used or a derivative'thereof is employed, in conjunction with a blending agent.
  • the substituted anilines which have proven most satisfactory are alkyl and phenyl substituted anilines such as the ethyl anilines, the methyl anilines,-the diphenyl amines and derivatives thereof.
  • a blending agent such as other or acetone.
  • the most satisfactory means of measuring the anti-knock ualities of a motor fuel is the well known ,idgely bouncing pin apparatus, wherein the volume of gasgem erated in the apparatus is a measure of the detonation effect. The less the volume of gasgenerated, the greater the anti-knock effect of the fuel.
  • gasoline may be added to alter the B. t. u. value of the fuel.
  • the blending agent employed may be members of the class of others or ketone such as dimethyl ether, diethyl ether, etc, and the ketones may be dimethyl ketone, dlethyl 'ketoues, ethyl methyl, ketones or other members of this class.
  • a motor fuel comprising a hydrocar- 5 bon, aniline and an ether.
  • a motor fuel comprisin a hydrocarhon, aniline and ether, the latter two in quantity sufiicient to give to the motor fuel anti-knock characteristics comparable to a 50% benzol 50% gasoline mixture. 7
  • a motor fuel comprising benzol, aniline and ether.

Description

.ketones such as ether or acetone.
Patented Oct. 13, 1925.
UNITED STATES 3 V 1,557,257 PATENT OFFICE.
JEAN LA RIBOISIERE, OF WASHINGTON, DISTRICT OF COLUMBIA.
MOTOR FUEL.
No Drawing.
To all whom it may concern:
Be it known that I, JEAN LA Rlnorsinnn. a citizen of the Republic of France, residing at Washington, District of Columbia, have invented certain new and useful Improvements in Motor Fuels, of which the following is a specification.
This invention relates to fuels, for in ternal combustion engines. More specifically my invention relates to the prevention of engine knock, and to the provision of a fuel which is economically efficient and will admirably remove that which is commonly formed by addlng to liquid hydrocarbons,
aniline or its derivatives and a blending agent, preferably ether. Such a fuel has been found to possess remarkable anti-knock qualities. In its preferred form my invention is directed to a motor fuel in which aniline itself is used or a derivative'thereof is employed, in conjunction with a blending agent.
The substituted anilines which have proven most satisfactory are alkyl and phenyl substituted anilines such as the ethyl anilines, the methyl anilines,-the diphenyl amines and derivatives thereof. My experiments show that the'best anti-knoek motor fuel is obtained by using aniline mixed with a relatively small proportion of a blending agent such as other or acetone.
The most satisfactory means of measuring the anti-knock ualities of a motor fuel is the well known ,idgely bouncing pin apparatus, wherein the volume of gasgem erated in the apparatus is a measure of the detonation effect. The less the volume of gasgenerated, the greater the anti-knock effect of the fuel.
The following data using the fuel mix-- tures set forth were obtained by using the Midgely bouncing pin apparatus. The
Application filed August 26, 1925. Serial No. 52,688.
experiments upon which the following re sults are based were made on the same day .using the same apparatus on each mixture and the gasoline used in each mixture was of ldentlcal quality coming from a single container.
Fuel mixture used. Volume (0. 0.) generated. 1. Straight gasoline 2.9 2. Gasoline benzol 50% 0. 3. Straight gasoline plus 1% aniline 1.4 4. Straight gasoline plus 71 other- 2. 4 5. Straight gasoline plus 1% aniline and ether 0. 8 6. Straight gasoline plus 1 aniline and 70 other 0.55 7. Straight gasoline plus 2% aniline and other 0.35 8. Straight gasoline plus 3% aniline and 4% ether 0.25
In the above mixture, acetone may be substituted for the ether and similar results to those specified above will be obtained.
Upon reviewing the above data it will be seen that ether alone has practically no effect on the anti-knock qualities of the motor fuel. Aniline alone in small quantities has some effect on the anti-knock qualities of the fuel but in general the anti-- knock qualities of the fuel is unsatisfactory. It is only when the blending agent is used in conjunction with aniline or its de- :rivatives, that a real anti-knock effect is obtained. The fuel mixture 1%. 6 above gives an anti-knock value equivalent to a 50% gasoline and a 50% benzol mixture.
Instead of gasoline, hydrogenated hydrocarbons or hydrogenated naphthols and naphthenes may be employed. Benzols may also be employed. In a high compression motor having a comprtssion ratio in the neighborhood of one to twelve, and a compression in the neighborhood of 500 pounds a motor fuel composed of benzol with approximately 3% aniline and 1 to l of blending agent, such as ether, has proved.
peculiarly effective. To this mixture, gasoline may be added to alter the B. t. u. value of the fuel.
The blending agent employed may be members of the class of others or ketone such as dimethyl ether, diethyl ether, etc, and the ketones may be dimethyl ketone, dlethyl 'ketoues, ethyl methyl, ketones or other members of this class.
Ill)
The above disclosure is merely illustrative of my invention.
\Vhat I claim is:
1. A motor fuel comprising a hydrocar- 5 bon, aniline and an ether.
l ether.
4. A motor fuel comprisin a hydrocarhon, aniline and ether, the latter two in quantity sufiicient to give to the motor fuel anti-knock characteristics comparable to a 50% benzol 50% gasoline mixture. 7
5. A motor fuel comprising benzol, aniline and ether.
In testimony whereof I aflix my signature. 4
JEAN LA RIBOISIERE.
US52688A 1925-08-26 1925-08-26 Motor fuel Expired - Lifetime US1557257A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US52688A US1557257A (en) 1925-08-26 1925-08-26 Motor fuel
FR620595D FR620595A (en) 1925-08-26 1926-08-24 Fuel for engines
GB20942/26A GB257613A (en) 1925-08-26 1926-08-25 Improvements in and relating to motor fuels
DER68540D DE486778C (en) 1925-08-26 1926-08-27 Propellants for internal combustion engines

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US52688A US1557257A (en) 1925-08-26 1925-08-26 Motor fuel

Publications (1)

Publication Number Publication Date
US1557257A true US1557257A (en) 1925-10-13

Family

ID=21979255

Family Applications (1)

Application Number Title Priority Date Filing Date
US52688A Expired - Lifetime US1557257A (en) 1925-08-26 1925-08-26 Motor fuel

Country Status (4)

Country Link
US (1) US1557257A (en)
DE (1) DE486778C (en)
FR (1) FR620595A (en)
GB (1) GB257613A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3063933A (en) * 1959-05-05 1962-11-13 Union Oil Co Process for removing sulfur and nitrogen from a conversion feed stock with return ofnitrogen to conversion product
US3869262A (en) * 1971-05-05 1975-03-04 Oesterr Hiag Werke Ag Fuel and additive for the production thereof
US3976438A (en) * 1975-09-12 1976-08-24 Clifton McCleary, Jr. Gasoline additive and method for making same
US4131434A (en) * 1974-06-03 1978-12-26 Francisco Gonzalez Catalytic composition for internal combustion engines, furnaces and boilers
US4372753A (en) * 1980-04-23 1983-02-08 Source Technology, Inc. Liquid fuel for use in internal combustion engines
US5266080A (en) * 1989-10-11 1993-11-30 The Standard Oil Company Methanol fuel containing flame luminosity agent
US20070175088A1 (en) * 2006-01-30 2007-08-02 William Robert Selkirk Biodiesel fuel processing

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3063933A (en) * 1959-05-05 1962-11-13 Union Oil Co Process for removing sulfur and nitrogen from a conversion feed stock with return ofnitrogen to conversion product
US3869262A (en) * 1971-05-05 1975-03-04 Oesterr Hiag Werke Ag Fuel and additive for the production thereof
US4131434A (en) * 1974-06-03 1978-12-26 Francisco Gonzalez Catalytic composition for internal combustion engines, furnaces and boilers
US3976438A (en) * 1975-09-12 1976-08-24 Clifton McCleary, Jr. Gasoline additive and method for making same
US4372753A (en) * 1980-04-23 1983-02-08 Source Technology, Inc. Liquid fuel for use in internal combustion engines
US5266080A (en) * 1989-10-11 1993-11-30 The Standard Oil Company Methanol fuel containing flame luminosity agent
US20070175088A1 (en) * 2006-01-30 2007-08-02 William Robert Selkirk Biodiesel fuel processing

Also Published As

Publication number Publication date
FR620595A (en) 1927-04-25
DE486778C (en) 1929-11-28
GB257613A (en) 1927-05-19

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