US1464012A - Propellant explosive - Google Patents
Propellant explosive Download PDFInfo
- Publication number
- US1464012A US1464012A US460438A US46043821A US1464012A US 1464012 A US1464012 A US 1464012A US 460438 A US460438 A US 460438A US 46043821 A US46043821 A US 46043821A US 1464012 A US1464012 A US 1464012A
- Authority
- US
- United States
- Prior art keywords
- powder
- nitrocellulose
- black powder
- mixture
- black
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B25/00—Compositions containing a nitrated organic compound
- C06B25/18—Compositions containing a nitrated organic compound the compound being nitrocellulose present as 10% or more by weight of the total composition
Definitions
- This invention relates to an improved propellant explosive, in powder form, designed for use in ammunition of various kinds.
- the improved propellant explosive of the present invention is composed of an intimate mixture or blend of nitrocellulose and ordinary black powder, with the nitrocellulose present in preponderating proportion, and the black powder present in sufliclent amount, e. g., from 5% to 35% by weight of the mixture, to aid in the combustion of the nitrocellulose, so that the composite roduct has improved properties, as a propel ant explosive, hereinafter more fullyset forth.
- the invention also includes an improved method or methods of producing the composite propellant explosive in powder form.
- the new propellant explosive of the present invention can be made by intimately mixing and blending the nitrocellulose and bl? k powder and granulating the m1xture or blend by any suitable method of granulation.
- the nitrocellulose and the black powder may thus be mixed in the desired proportion, and the mixture rumbled in a rumbling barrel and the granulation formed colloid the nitrocellulose, for example, by.
- the black powder dope should be thoroughly incorporated in a wheel mill in much the same manner as for the manufacture of ordinary black powder.
- the nitrocellulose colloid and the black powder paste may be mixed, for example, in the manner commonly used for the manufacture of smokeless powder.
- the mixture may be subjected to granulation by any suit able method. The mixture may thus be pressed, granulated and dried in much the same manner as that employed for making smokeless powder.
- the resulting product will contain the nitrocellulose and the black powder blended together in the form of an intimate mixture or blend.
- the product will be of a composite character, with the nitrocellulose present in preponderating proportion, and with the black powder present in relatively small proportion, that is, from 5 to 35% by weight of the mixture.
- the black powder may be of the ordinary composition, i. e., made of sulfur, carbon and saltpetre in the usual proportions.
- Other oxidizing ingredients besides otassium nitrate can, however, be used in t e formation of the black powder, such as barium nitrate, sodium nitrate, etc.
- the new propellant explosive of the present invention possesses various advanta es which distinguish it from black 'p'owler alone and from smokeless powder, as well,
- the black powder serves as an aid to the combustion of lhe smokeless powder or nitrocellulose in a produced when the powder is fired, the remainder of the composition being converted into a liquid or fused state by the h gh temperature.
- the new explosive presents the further advantage that the ignition of the nitrocellulose is considerably accelerated by the presence of the black powder in the small proportions used, so that the black powder serves as an aid to the combustion of the smokeless powder.
- the process is advantageously modified by the water employed.
- the water When the powder is pressed, the water is forced toward the surface of the grain and acts as a lubricant, making a. very free-flowing and smooth colloid.
- the water has the further advantage of making the mixture difficult to ignite during the mixing and granulating operations, thus increasing the safety of these operations.
- smokeless powder as commonly manufactured, if a free flame is applied, the ether and alcohol ignite, and, as the ether and alcohol leave the grain, the nitrocellulose ignites and a very rapid burning 'is produced.
- black powder a free flame produces a flash. With the com position of the present invention, only the grains affected by the flame will burn; and
- the water used in the composition has the further advantage of partly pre cipitating the nitrocellulose, thus making the powder grain more or less bulky. This is advantageous in that more perfect ignition is reduced.
- the granulation can be controlled at all times, and a definite and uniform granulation ob tained which will adapt the powder to fit the particular kind of ammunition for which it is to be fired.
- the granulation can be brought about and regulated by forcing through a die, etc, in much the same manner as smokeless powder, for use in small ammunition or in guns of large calibre, etc.
- the method of producing a propellant explosive which comprises forming an intimate mixture of black powder with nitrocellulose, the'latter being present in preponderating proportion, which consists in first forming a nitro-cellulose colloid which is then mixed with ablack powder paste containing water, forcing the mixture through a die and cutting the resultin product into granules 3.
- the method of producing a propellant explosive which comprises forming an intimate mixture of nitro-cellulose colloid with a black powder paste containing water and alcohol, forcing the through a die, and cutting the resulting product into granules.
- the method of preduoing a propellantexplosive which comprises forming an intimate mixture of intro-cellulose colloid with a. black powder paste containing substantially 50% water and 5072- alcohol, forcing the resulting mixture through 2-. die, and cutting the resulting product into granules.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Glanulating (AREA)
- Jellies, Jams, And Syrups (AREA)
- Cosmetics (AREA)
Description
Patented Aug. 7, 1923.
U ST
PTENT OFFICE.
ARTHUR SAMUEL ONEIL AND RAYMOND ROYAL EVANS, 0F SPRINGFIELD, ILLINOIS, ASSIGNORS, BY MESNE ASSIGNMENTS, TO WESTERN CARTRIDGE COMPANY, A.
CORPORATION OF DELAWARE.
PROPELLANT EXPLOSIVE.
No drawing.
To all whom it may concern:
Be it known that we, ARTHUR S. ONEIL and Rxnioxo ROYAL Evans, citizens of the United States, residing at Springfield, in the county of Sangamon, State of Illinois, have invented certain new and useful improvements in ropellant Explosives; and we do hereby declare the following to be a full, clear, and exact description of the invention, such as will enable others skilled in the art to. which it appertains to make and use the same.
This invention relates to an improved propellant explosive, in powder form, designed for use in ammunition of various kinds.
The improved propellant explosive of the present invention is composed of an intimate mixture or blend of nitrocellulose and ordinary black powder, with the nitrocellulose present in preponderating proportion, and the black powder present in sufliclent amount, e. g., from 5% to 35% by weight of the mixture, to aid in the combustion of the nitrocellulose, so that the composite roduct has improved properties, as a propel ant explosive, hereinafter more fullyset forth.
The invention also includes an improved method or methods of producing the composite propellant explosive in powder form.
The new propellant explosive of the present invention can be made by intimately mixing and blending the nitrocellulose and bl? k powder and granulating the m1xture or blend by any suitable method of granulation. The nitrocellulose and the black powder may thus be mixed in the desired proportion, and the mixture rumbled in a rumbling barrel and the granulation formed colloid the nitrocellulose, for example, by.
introducing the nitrocellulose into a regular powder mixer, together with the proper amount of solvent, such as ether andalcohol; and to bring about the intermixture of'the resulting colloid with an aqueous aste con-- taining the black powder, and ma e, for ex- Appllcation filed April 11 1921. Serial No. 460,438.
ample, by mixing the black powder dope, as it comes from the wheel mill, into a paste with alcohol and 50% water. The black powder dope, before it is mixed into the paste, should be thoroughly incorporated in a wheel mill in much the same manner as for the manufacture of ordinary black powder. The nitrocellulose colloid and the black powder paste may be mixed, for example, in the manner commonly used for the manufacture of smokeless powder. The mixture may be subjected to granulation by any suit able method. The mixture may thus be pressed, granulated and dried in much the same manner as that employed for making smokeless powder. I
The resulting product will contain the nitrocellulose and the black powder blended together in the form of an intimate mixture or blend. The product will be of a composite character, with the nitrocellulose present in preponderating proportion, and with the black powder present in relatively small proportion, that is, from 5 to 35% by weight of the mixture. The black powder may be of the ordinary composition, i. e., made of sulfur, carbon and saltpetre in the usual proportions. Other oxidizing ingredients besides otassium nitrate can, however, be used in t e formation of the black powder, such as barium nitrate, sodium nitrate, etc.
The new propellant explosive of the present invention possesses various advanta es which distinguish it from black 'p'owler alone and from smokeless powder, as well,
as from mixtures heretofore proposed containing a preponderating proportion of black powder (e. g., around 80%) anda small proportion of nitrocellulose (e. g., around 20%). When a small amount of nitrocellulose is used with a. large amount of black powder, the resulting mixture partakes of the nature of black powder, while the nitrocellulose serves to stick the particles of black powder together and to give a cleaner combustion; whereas the-new explosive of the present invention presents the advantage, among others, that the black powder serves as an aid to the combustion of lhe smokeless powder or nitrocellulose in a produced when the powder is fired, the remainder of the composition being converted into a liquid or fused state by the h gh temperature. In the case of smokeless powder, a large gas volume is obtained from the smokeless powder supplemented by that from the black powder, while the black powder will give a considerable quantity of substances in a liquid or fused state at a high temperature, and these substances will serve to maintain and equalize the teniperature of the gases produced by the ignition, thus materially airlin in the work done upon the projectile. Tn consequence, rela tively high velocities can be obtained with relatively low pressures.
The new explosive presents the further advantage that the ignition of the nitrocellulose is considerably accelerated by the presence of the black powder in the small proportions used, so that the black powder serves as an aid to the combustion of the smokeless powder. 1
When the new propellant explosive. is made by compounding nitrocellulose in the form of a solution or colloid, with an aqueous paste of black powder, in the manner above described, the process is advantageously modified by the water employed. When the powder is pressed, the water is forced toward the surface of the grain and acts as a lubricant, making a. very free-flowing and smooth colloid. The water has the further advantage of making the mixture difficult to ignite during the mixing and granulating operations, thus increasing the safety of these operations. With smokeless powder as commonly manufactured, if a free flame is applied, the ether and alcohol ignite, and, as the ether and alcohol leave the grain, the nitrocellulose ignites and a very rapid burning 'is produced. With black powder, a free flame produces a flash. With the com position of the present invention, only the grains affected by the flame will burn; and
the remainder of the powder is unaffected by the fire. The water used in the composition has the further advantage of partly pre cipitating the nitrocellulose, thus making the powder grain more or less bulky. This is advantageous in that more perfect ignition is reduced.
y granulating the powder, i. e., by forcing the mixture through a dieand cutting into a uniform and regular granulation, the granulation can be controlled at all times, and a definite and uniform granulation ob tained which will adapt the powder to fit the particular kind of ammunition for which it is to be fired. The granulation can be brought about and regulated by forcing through a die, etc, in much the same manner as smokeless powder, for use in small ammunition or in guns of large calibre, etc.
We claim: 1. The method of producing a propellant explosive in powder form containing black powder and nitrocellulose, the nitro-cellulose being present in preponderating proportion, which consists in first colloiding the nitro-cellulose, then. inter-mixing this colloid with an aqueous paste containing black pow der, forcing the mixture of intro-cellulose,
colloid and aqueous black powder through a die to form regular granulations and finally cutting the resulting products into granules.
2. The method of producing a propellant explosive which comprises forming an intimate mixture of black powder with nitrocellulose, the'latter being present in preponderating proportion, which consists in first forming a nitro-cellulose colloid which is then mixed with ablack powder paste containing water, forcing the mixture through a die and cutting the resultin product into granules 3. The method of producing a propellant explosive which comprises forming an intimate mixture of nitro-cellulose colloid with a black powder paste containing water and alcohol, forcing the through a die, and cutting the resulting product into granules. 3
4. The method of preduoing a propellantexplosive which comprises forming an intimate mixture of intro-cellulose colloid with a. black powder paste containing substantially 50% water and 5072- alcohol, forcing the resulting mixture through 2-. die, and cutting the resulting product into granules.
In testimony whereof we aflix our signatures. 7
ARTHUR SAIWEUEL ONETL. RAYIV'ZOND ROYAL EVAN-5.
resulting mixture
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US460438A US1464012A (en) | 1921-04-11 | 1921-04-11 | Propellant explosive |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US460438A US1464012A (en) | 1921-04-11 | 1921-04-11 | Propellant explosive |
Publications (1)
Publication Number | Publication Date |
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US1464012A true US1464012A (en) | 1923-08-07 |
Family
ID=23828701
Family Applications (1)
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US460438A Expired - Lifetime US1464012A (en) | 1921-04-11 | 1921-04-11 | Propellant explosive |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0608505A1 (en) * | 1993-01-23 | 1994-08-03 | TEMIC Bayern-Chemie Airbag GmbH | Gas generator for an airbag with an auto-ignition agent |
-
1921
- 1921-04-11 US US460438A patent/US1464012A/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0608505A1 (en) * | 1993-01-23 | 1994-08-03 | TEMIC Bayern-Chemie Airbag GmbH | Gas generator for an airbag with an auto-ignition agent |
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