US3086896A - Nitroguanidine propellant composition and process of preparation - Google Patents
Nitroguanidine propellant composition and process of preparation Download PDFInfo
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- US3086896A US3086896A US83849A US8384961A US3086896A US 3086896 A US3086896 A US 3086896A US 83849 A US83849 A US 83849A US 8384961 A US8384961 A US 8384961A US 3086896 A US3086896 A US 3086896A
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- nitroguanidine
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- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B21/00—Apparatus or methods for working-up explosives, e.g. forming, cutting, drying
- C06B21/0033—Shaping the mixture
- C06B21/0075—Shaping the mixture by extrusion
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B23/00—Compositions characterised by non-explosive or non-thermic constituents
- C06B23/006—Stabilisers (e.g. thermal stabilisers)
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B25/00—Compositions containing a nitrated organic compound
- C06B25/18—Compositions containing a nitrated organic compound the compound being nitrocellulose present as 10% or more by weight of the total composition
- C06B25/24—Compositions containing a nitrated organic compound the compound being nitrocellulose present as 10% or more by weight of the total composition with nitroglycerine
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B25/00—Compositions containing a nitrated organic compound
- C06B25/34—Compositions containing a nitrated organic compound the compound being a nitrated acyclic, alicyclic or heterocyclic amine
Definitions
- the present invention relates to a new product and process for producing a triple-base propellant, for use in guns, howitzers and like weapons.
- Triple-base propellants are composed of three major ingredients: nitroguanidine, nitrocellulose and nitroglycerine, These propellants have come into increasing use because of their high force values obtained at low flame temperatures. This results in reduced gun barrel erosion and, because of the low percentages of combustibles in muzzle gases relative flashlessness is obtained.
- the manufacturing time and cost of nitroguanidine-base propellants have proven to be considerably greater than those of either single or double-base artillery propellants. The primary reason for this is that a 4 /2 to 6-hour final mixing period is required to fully incorporate the nitroguanidine crystals into a uniform colloid, as compared to 1 hour for single-base, and a maximum of 2 hours for double-base propellants.
- nitroguanidine-base propellants can also be attributed to (a) the fact that they are more diflicult to ignite than any of the standard single or double-base formulations of equivalent energy level and (b) their poorer physical properties cause propellant-grain breakup in the gun.
- Another object of our invention is to provide a process for making triple-base propellants wherein the processing time and power expenditure during processing are greatly decreased.
- Still another object of our invention is to reduce or eliminate the high content of crystalline solids that are present due to the formation of double compounds.
- a further object of our invention is to provide a triplebase nitrogu-anidine propellant that is about fifty percent stronger in physical properties than other nitroguanidine propellants.
- triple-base propellant composition of our invention contains in addition to the three base propellants, nitroguanidine, nitrocellulose and nitroglycerine, a liquid dialkylphthalate that functions as a plasticizer and a diphenylamine that functions as a stabilizer.
- Any liquid dialkylphthalate plasticizer may be used in the triple-base composition.
- Some representative compounds of this series that are suitable are, dimethylphthalate, diethylphthalate, dipropylphthalate and other members of the dialkylphthalate series.
- the stabilizer In addition to the particular type plasticizer utilized, another critical component of the composition is the stabilizer.
- the stabilizer must not form double compounds with nitroguanidine.
- Stabilizers that have been found to be suitable for the composition are substituted diphenylamines. Of this series, optimum results are obtained with nitrodiphenylamine and other nitro-substituted diphenylamines.
- Another feature of this invention relates to the type of nitrocellulose that is used in the composition.
- the average degree of nitration of this nitrocellulose is about 12.6% $.10 (pyrocellulose), rather than the usual military blend of 13.15% nitrogen. It has been discovered that a more uniform mixture of ingredients is obtained when this nitrocellulose is used. Furthermore, this beneficial result, of uniformity of mixture of ingredients, is obtained at a much lower power expenditure, thus resulting in a considerable economic savings.
- the triple-base propellant found suitable for our composition contains from 50 to percent nitroguanidine having a specific surface of from about 9,000 to 22,000 sq. cm. per cc., preferably above about 12,000.
- the nitroguanidine is dispersed in 16 to 23 percent nitrocellulose, which is gelatinized by about 16 to 21 percent nitroglycerin, or other suitable liquid explosive nitric esters such as triethyleneglycol dinitrate, diethyleneglycol dinitrate and butanetriol trinitrate.
- the dialkylphthala'te plasticizer is present in the composition at a concentration of about 4.5 percent and the diphenylamine stabilizer is present in a concentration of about 1.5%.
- a process for carrying out our invention is as follows (percentages being by weight):
- a pre-mix was prepared in a Schrader bowl, or other like mixer, by adding about one-half amount, 27.3 percent, of nitroguanidine having a specific surface of 15,000 cm. 0111. and 20 percent nitrocellulose having a nitrogen content of 12.6%. These ingredients were mixed for about five minutes. Then 9 percent of nitroglycerin desensitized with acetone (NG/acetone 82/18) was added and the mixing was continued for an additional five minutes.
- This pre-mix was transferred to a sigma blade mixer and mixed for about five minutes before adding the remaining ingredients.
- the balance of the nitroguanidine, 27.4 percent and 0.3 percent cryolite were added to the mixer followed by the addition of 4.5 percent of dibutylphthalate and 1.5 percent of Z-nitrodiphenylamine dissolved in a solvent, such as 65 parts ethyl alcohol and 35 parts acetone.
- the total volatile solvent, which includes the acetone for desensitizing the nitroglycerin and the residual ethyl alcohol in the dehydrated nitrocellulose was about 14.5 percent based on the weight of all the ingredients of the composition.
- the mixing in the sigma blade mixer was continued for three hours from the time the final addition of nitroguanidine was made.
- the temperature in the sigma blade mixer was maintained between 80 F. and 105 F. Mixing the composition yielded a uniform, extrudable colloid.
- the colloid is then treated in the conventional manner to form shaped charges. That is the colloid is cooled, transferred to a press, blocked, screened, reblocked, extruded through dies of desired dimensions, cut to the desired length and dried.
- the following table discloses the preferred composition with thermochemical values and physical properties of the triple-base propellant.
- nitrocellulose was slurried in Water maintained at about 80 F. until all the fibers were well disbursed. This takes about ten minutes.
- the water to nitrocellulose ration was approximately 11 parts water to 1 part nitrocellulose, by weight.
- 19 parts nitroglycerin and 4.5 parts dibutylphthalate were added, as a mixture, to the slurry
- a water solution of 1.5 parts finely divided nitrodiphenylamine is added to the The slurry is then centrifuged whereby the water content was brought down to approximately 20 percent.
- This mixture was dried at about 120 F. with forced air to a moisture content of from about 4 to 6 percent.
- the impact-test for the composition was found to have a value of 3460 whereas for a conventional triple-base propellant the value was 1500.
- composition I a propellant identified as composition I
- composition I a propellant identified as composition I
- an extrudable propellant composition which comprises forming a mixture consisting essentially of, in proportions by weight, 50-65% nitroguanidine, in a state of comminution such that the particles have a surface of from 9,000-22,000 cm. /cm.
- a nitric acid ester of a polyhydric alcohol from the group consisting of diethylene glycol, triethylene glycol, glycerin and butanetriol
- the improvement which comprises stabilizing and increasing the dispersion of the said nitroguanidine and the said nitrocellulose in the said nitric acid ester by adding to the said mixture thereof a minor proportion of a dialkylphthalate, wherein the said alkyl groups contain from 16 carbon atoms, and a minor proportion of a nitrodiphenylamine and homogenizing the said mixture,
- dialkylphthalate is dibutylphthalate.
- dialkylphtha-late is added in the proportion of about 4.5% by weight of the total composition.
- the said alkyl groups contain from 1-6 carbon atoms
- dialkylphthalate is dibutylphthalate.
- composition as set forth in claim 7 wherein the nitrodiphenylamine is Z-nitrodiphenyla-mine.
Description
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3,086,896 NITROGUANIDINE PROE ELLANT (Zflh'iiUSlTlQN AND PRUCESS F PREPARATION Russell L. Trash, Morris Plains, NJL, Samuel Sage, Bronx,
N.Y., and Isidore G. Nadel, Little Falls, NJ assigners to the United States of America as represented by the Secretary of the Army N0 Drawing. Fiied Jan. 19, 1961, Ser. No. 83,849
11 Claims. (til. 19--92) (Granted under Title 35, US. Code (1952), see. 256) The invention described herein may be manufactured and used by or for the Government for governmental purposes without the payment to us of any royalty thereon.
The present invention relates to a new product and process for producing a triple-base propellant, for use in guns, howitzers and like weapons.
Triple-base propellants are composed of three major ingredients: nitroguanidine, nitrocellulose and nitroglycerine, These propellants have come into increasing use because of their high force values obtained at low flame temperatures. This results in reduced gun barrel erosion and, because of the low percentages of combustibles in muzzle gases relative flashlessness is obtained. However, the manufacturing time and cost of nitroguanidine-base propellants have proven to be considerably greater than those of either single or double-base artillery propellants. The primary reason for this is that a 4 /2 to 6-hour final mixing period is required to fully incorporate the nitroguanidine crystals into a uniform colloid, as compared to 1 hour for single-base, and a maximum of 2 hours for double-base propellants. It is believed, too, that despite the precaution of the extended mixing time a small percentage of the nitroguanidine crystals are not as uniformily incorporated throughout the propellant as desired. Therefore, erratic ballistics result when the finished product is fired in a weapon. The poorer ballistic uniformity of nitroguanidine-base propellants can also be attributed to (a) the fact that they are more diflicult to ignite than any of the standard single or double-base formulations of equivalent energy level and (b) their poorer physical properties cause propellant-grain breakup in the gun.
It is, therefore, a primary object of this invention to provide a new propellant composition having improved physical and ballistic properties.
Another object of our invention is to provide a process for making triple-base propellants wherein the processing time and power expenditure during processing are greatly decreased.
Still another object of our invention is to reduce or eliminate the high content of crystalline solids that are present due to the formation of double compounds.
A further object of our invention is to provide a triplebase nitrogu-anidine propellant that is about fifty percent stronger in physical properties than other nitroguanidine propellants.
These and other objects of the invention will become obvious to those skilled in the art as the invention is hereinafter particularly described.
It has been discovered that a new nitroguanidine tripleb-ase propellant is obtained having superior physical and ballistic properties and requiring fifty percent less final mixing time than those heretofore known when the following disclosed process and ingredients are used. The
triple-base propellant composition of our invention contains in addition to the three base propellants, nitroguanidine, nitrocellulose and nitroglycerine, a liquid dialkylphthalate that functions as a plasticizer and a diphenylamine that functions as a stabilizer.
Any liquid dialkylphthalate plasticizer may be used in the triple-base composition. Some representative compounds of this series that are suitable are, dimethylphthalate, diethylphthalate, dipropylphthalate and other members of the dialkylphthalate series.
In addition to the particular type plasticizer utilized, another critical component of the composition is the stabilizer. The stabilizer must not form double compounds with nitroguanidine. Stabilizers that have been found to be suitable for the composition are substituted diphenylamines. Of this series, optimum results are obtained with nitrodiphenylamine and other nitro-substituted diphenylamines.
Another feature of this invention relates to the type of nitrocellulose that is used in the composition. The average degree of nitration of this nitrocellulose is about 12.6% $.10 (pyrocellulose), rather than the usual military blend of 13.15% nitrogen. It has been discovered that a more uniform mixture of ingredients is obtained when this nitrocellulose is used. Furthermore, this beneficial result, of uniformity of mixture of ingredients, is obtained at a much lower power expenditure, thus resulting in a considerable economic savings.
The triple-base propellant found suitable for our composition contains from 50 to percent nitroguanidine having a specific surface of from about 9,000 to 22,000 sq. cm. per cc., preferably above about 12,000. The nitroguanidine is dispersed in 16 to 23 percent nitrocellulose, which is gelatinized by about 16 to 21 percent nitroglycerin, or other suitable liquid explosive nitric esters such as triethyleneglycol dinitrate, diethyleneglycol dinitrate and butanetriol trinitrate. The dialkylphthala'te plasticizer is present in the composition at a concentration of about 4.5 percent and the diphenylamine stabilizer is present in a concentration of about 1.5%.
A process for carrying out our invention is as follows (percentages being by weight):
A pre-mix was prepared in a Schrader bowl, or other like mixer, by adding about one-half amount, 27.3 percent, of nitroguanidine having a specific surface of 15,000 cm. 0111. and 20 percent nitrocellulose having a nitrogen content of 12.6%. These ingredients were mixed for about five minutes. Then 9 percent of nitroglycerin desensitized with acetone (NG/acetone 82/18) was added and the mixing was continued for an additional five minutes.
This pre-mix was transferred to a sigma blade mixer and mixed for about five minutes before adding the remaining ingredients. The balance of the nitroguanidine, 27.4 percent and 0.3 percent cryolite were added to the mixer followed by the addition of 4.5 percent of dibutylphthalate and 1.5 percent of Z-nitrodiphenylamine dissolved in a solvent, such as 65 parts ethyl alcohol and 35 parts acetone. The total volatile solvent, which includes the acetone for desensitizing the nitroglycerin and the residual ethyl alcohol in the dehydrated nitrocellulose was about 14.5 percent based on the weight of all the ingredients of the composition.
'and agitated for about ten minutes.
slurry and said slurry is mixed for ten minutes.
-is maintained between 80 F. and 105 F.
The mixing in the sigma blade mixer was continued for three hours from the time the final addition of nitroguanidine was made. The temperature in the sigma blade mixer was maintained between 80 F. and 105 F. Mixing the composition yielded a uniform, extrudable colloid.
The colloid is then treated in the conventional manner to form shaped charges. That is the colloid is cooled, transferred to a press, blocked, screened, reblocked, extruded through dies of desired dimensions, cut to the desired length and dried.
The following table discloses the preferred composition with thermochemical values and physical properties of the triple-base propellant.
Table I Composition:
Nitrocellulose (12.6% N) percent by weight 20.0 Nitroglycerin do 19.0 Nitroguanidine (15,000 cm. /cm. do 54.7 Dibutylphathalate do 4.5 2-nitrodiphenylamine do 1.5 Potassium aluminum fluoride (cryolite) do 0.3 Total volatiles do 0.3 Hygroscopicity 0.44 Specific gravity (15.5 C./155 C.) 1.65 Gravimetric density l-bs./ft. 56.0 Thermochemical values:
Flame temperature K 2599* Force a ft.-lbs./lb 334,000 Heat of explosion ca1./gm 807 Unoxidized carbon percent by weight 8.7 Combustibles do 49.8 Physical properties:
Compression test percent by weight..- 24.8 Side-impact test "inch-grams-.. 3460 An alternate process for preparing the above propellant composition is as follows:
20 parts nitrocellulose was slurried in Water maintained at about 80 F. until all the fibers were well disbursed. This takes about ten minutes. The water to nitrocellulose ration was approximately 11 parts water to 1 part nitrocellulose, by weight. 19 parts nitroglycerin and 4.5 parts dibutylphthalate were added, as a mixture, to the slurry A water solution of 1.5 parts finely divided nitrodiphenylamine is added to the The slurry is then centrifuged whereby the water content was brought down to approximately 20 percent. This mixture was dried at about 120 F. with forced air to a moisture content of from about 4 to 6 percent.
This above pre-mix was transferred to a sigma blade mixer, the solvent, a mixture of ethyl alcohol and acetone, was added followed by the addition of 54.7 parts of the composition nitroguanidine. Mixing of the composition is continued for about three hours and the temperature range The composition is now ready for extrusion.
Test have been made with a conventional triple-base propellant to show the differences in the physical strength between the present product and conventional triple-base propellants. The compression test value for the product of the instant invention as indicated in Table I above, is 24.8, whereas the ascertained value of the conventional product was 16.3. The flexibility of the propellant grains as measured by the standard compression test is 90% to 'low temperature brittleness and the elimination of grain breakup.
The impact-test for the composition was found to have a value of 3460 whereas for a conventional triple-base propellant the value was 1500.
The following table discloses a comparison of the results obtained firing our propellant, identified as composition I, and a conventional triple-base propellant.
Table II [Ballistic comparisons in mm. gun, M1 series. Shell: 90 mm. HE, M71] Muzzle Velocity Pressure Propel- Ammo lant Temp, Std. Max. Avg, Std. Max. F. Avg, Dcv., Disp., p.s.i./ Dev., Disp.
t./s. f./s. f./s. p.s.i./ p.s.i./
Composition L--- 70 2, 758 14. 4 52 374 9. 4 30 Conventi0na1 70 2, 740 24. 5 89 385 15.6 51 Composition 1.... 65 2, 708 15. 4 54 352 21. 6 76 Conventional 65 2, 630 27. 4 92 332 28. 7 65 Composition I- 2, 857 9.0 35 412 12. 9 46 Conventional 160 2, 820 17. 1 58 410 15.2 54
The superior physical properties of the propellant composition is clearly evidenced by these results set forth above.
We claim:
1. In the process of preparation of an extrudable propellant composition which comprises forming a mixture consisting essentially of, in proportions by weight, 50-65% nitroguanidine, in a state of comminution such that the particles have a surface of from 9,000-22,000 cm. /cm. 16-23% pyrocellulose, and 1621% of a nitric acid ester of a polyhydric alcohol from the group consisting of diethylene glycol, triethylene glycol, glycerin and butanetriol, the improvement which comprises stabilizing and increasing the dispersion of the said nitroguanidine and the said nitrocellulose in the said nitric acid ester by adding to the said mixture thereof a minor proportion of a dialkylphthalate, wherein the said alkyl groups contain from 16 carbon atoms, and a minor proportion of a nitrodiphenylamine and homogenizing the said mixture,
at an elevated temperature, until a homogeneous colloid is formed.
2. The process as fet forth in claim 1 wherein the dialkylphthalate is dibutylphthalate.
3. The process as set forth in claim 1 wherein the nitrodiphenylamine is 2-nitrodiphenylamine.
4. The process as set forth in claim 1 wherein the dialkylphtha-late is added in the proportion of about 4.5% by weight of the total composition.
5. The process as set forth in claim 1 wherein the diphenylamine is added in the proportion of about 1.5%
' by weight of the total composition.
-the said alkyl groups contain from 1-6 carbon atoms, and
a minor proportion of a nitrodiphenylamine.
8. The composition as set forth in claim 7 wherein the dialkylphthalate is dibutylphthalate.
9. The composition as set forth in claim 7 wherein the nitrodiphenylamine is Z-nitrodiphenyla-mine.
10. The composition as set forth in claim 7 wherein the 5 6 dialkylphthalate is present in the proportion of about References Cited in the file of this patent 4.5% by weight of the total composition. UNITED STATES PATENTS 11. The composition as set forth in claim 7 wherein the nitrodiphenylamine is present in the proportion of about gggi 3 et J 1.5% by weight of the total composition. 5 3 rmg une
Claims (1)
1. IN THE PROCESS OF PREPARATION OF AN EXTRUDABLE PROPELLANT COMPOSITION WHICH COMPRISES FORMING A MIXTURE CONSISTING ESSENTIALLY OF, IN PROPORTIONS BY WEIGHT, 50-65% NITROGUANIDINE, IN A STATE OF COMMINUTION SUCH THAT THE PARTICLES HAVE A SURFACE OF FROM 9,000-22,000 CM.2/CM.3, 16-23% PYROCELLULOSE, AND 16-21% OF A NITRIC ACID ESTER OF A POLYHYDRIC ALCOHOL FROM THE GROUP CONSISTING OF DIETHYLENE GLYCOL, TRIETHYLENE GLYCOL, GLYCERIN AND BUTANETRIOL, THE IMPROVEMENT WHICH COMPRISES STABILIZING AND INCREASING THE DISPERSION OF THE SAID NITROGUANIDINE AND THE SAID NITROCELLULOSE IN THE SAID NITRIC ACID ESTER BY ADDING TO THE SAID MIXTURE THEREOF A MINOR PROPORTION OF A DIALKYLPHTHALATE, WHEREIN THE SAID ALKYL GROUPS CONTAIN FROM 1-6 CARBON ATOMS, AND A MINOR PROPORTION OF A NITRODIPHENYLAMINE AND HOMOGENIZING THE SAID MIXTURE AT AN ELEVATED TEMPERATURE, UNTIL A HOMOGENEOUS COLLOID IS FORMED.
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US83849A US3086896A (en) | 1961-01-19 | 1961-01-19 | Nitroguanidine propellant composition and process of preparation |
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US83849A US3086896A (en) | 1961-01-19 | 1961-01-19 | Nitroguanidine propellant composition and process of preparation |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3447983A (en) * | 1967-07-31 | 1969-06-03 | Us Navy | Acetone treated nitrocellulose-based propellant and process |
US3715248A (en) * | 1970-12-15 | 1973-02-06 | Us Army | Castable metallic illuminant fuel containing nitrocellulose plasticized binder |
FR2221423A1 (en) * | 1973-01-05 | 1974-10-11 | Rockwell International Corp | Triaminoguanidine nitrate contg. propellant charge - with low flame temp. which prevents barrel erosion |
US3985594A (en) * | 1974-07-09 | 1976-10-12 | Ab Bofors | Method of reducing the muzzle flash when firing firearms loaded with powder, and powder flash-reducing agent intended for this purpose |
WO1990013528A2 (en) * | 1989-05-11 | 1990-11-15 | Wnc-Nitrochemie Gmbh | Process and device for producing a tribasic propellent powder |
US5468313A (en) * | 1994-11-29 | 1995-11-21 | Thiokol Corporation | Plastisol explosive |
JP2016003176A (en) * | 2014-06-19 | 2016-01-12 | 日油株式会社 | Triple-base propellant composition |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2027114A (en) * | 1932-03-12 | 1936-01-07 | Western Cartridge Co | Manufacture of smokeless powders |
US2557463A (en) * | 1946-09-14 | 1951-06-19 | Ici Ltd | Propellant composition and process of making same |
-
1961
- 1961-01-19 US US83849A patent/US3086896A/en not_active Expired - Lifetime
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2027114A (en) * | 1932-03-12 | 1936-01-07 | Western Cartridge Co | Manufacture of smokeless powders |
US2557463A (en) * | 1946-09-14 | 1951-06-19 | Ici Ltd | Propellant composition and process of making same |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3447983A (en) * | 1967-07-31 | 1969-06-03 | Us Navy | Acetone treated nitrocellulose-based propellant and process |
US3715248A (en) * | 1970-12-15 | 1973-02-06 | Us Army | Castable metallic illuminant fuel containing nitrocellulose plasticized binder |
FR2221423A1 (en) * | 1973-01-05 | 1974-10-11 | Rockwell International Corp | Triaminoguanidine nitrate contg. propellant charge - with low flame temp. which prevents barrel erosion |
US3985594A (en) * | 1974-07-09 | 1976-10-12 | Ab Bofors | Method of reducing the muzzle flash when firing firearms loaded with powder, and powder flash-reducing agent intended for this purpose |
WO1990013528A2 (en) * | 1989-05-11 | 1990-11-15 | Wnc-Nitrochemie Gmbh | Process and device for producing a tribasic propellent powder |
WO1990013528A3 (en) * | 1989-05-11 | 1990-12-27 | Nitrochemie Gmbh | Process and device for producing a tribasic propellent powder |
GR900100307A (en) * | 1989-05-11 | 1991-10-10 | Nitrochemie Gmbh | Method and arrangement for the fabrication of a powder propelling discharge |
US5468313A (en) * | 1994-11-29 | 1995-11-21 | Thiokol Corporation | Plastisol explosive |
JP2016003176A (en) * | 2014-06-19 | 2016-01-12 | 日油株式会社 | Triple-base propellant composition |
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