US1435541A - Laundry preparation - Google Patents

Laundry preparation Download PDF

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Publication number
US1435541A
US1435541A US470282A US47028221A US1435541A US 1435541 A US1435541 A US 1435541A US 470282 A US470282 A US 470282A US 47028221 A US47028221 A US 47028221A US 1435541 A US1435541 A US 1435541A
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United States
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goods
oxalic acid
employed
acid
bath
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US470282A
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Phil L Mabrey
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Individual
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/10Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/265Carboxylic acids or salts thereof

Definitions

  • the acidic bath is utilized to remove stains and other discolorations from the goods and to thereby more efiiciently renovate the latter.
  • acetic and oxalic acids are commonly utilized in imparting the necessary degree of acidity'to thi latter bath, however, it has been observedthat the acetic acid alone does not have sufficient strength to remove fruit, iron. erspiration and other stains or discoloratlons from the goods, but can be merely employed for the purpose of counteracting the effects of the alkali, Oxalic acid, on the other hand by.
  • the-less has a distinctly detrimental effect upon the goods treatedtherewith, inasmuch as "*such goods, When' repeatedly subjected thereto and'within-"a' relatively short time becomes burned, because of the fact that the oxalic acid is very diflicult to remove from the goods, and by remaining therein causes their normal usefulness and life to be materially foreshortened.
  • the present invention therefore, consists wherein oxalic acidis'present, but in combined relationship with certain other materials, hereinafter specifically set forth, which serve to permit the ordinary beneficial results of said acid to be retained but, in addition, act to enable the said acid to be decomposed and used up entirely when employed in the presence of hot water, so that substantially none, or a negligible amount, of such acidwill remain in the fabric treated therewith, and to thereby avoid undue disintegration or premature destruction of said fa rics.
  • sofgium silico fluoride containing 58% uorine 59% Oxalic acid, powdered 25% Alum, powdered 8% Fine table salt 8% 'Thege materialsare assembled in bulk and are thoroughly mixed together, an efiicient mechanical mixture being obtained by means of revolving brushes, which serve to combine and 'intermingle all of the ingredients so that the same may be uniformly distributed throughout the bulk of the combined materials thus produced.
  • These .materials when combined and mixed produce a relatively fine powdered mass, which may be placed insuitable containers for commercial handling, the sodium silico acting to hold the fluorine and to prevent it from being wasted, by reason of its volatility when the containers are being moved about.
  • the substance or composition produced by combining the materials set forth is, whenactively used, adapted to'be placed in hot water of substantially 190 Fab in which the fabric is to be washed, ordlnarlly but substantially four ounces or even less of the composition being employed to approxi-' mately seventy-five pounds of goods to be washed thereby.
  • the sodium silico fluoride assists the oxalic acid in securing a whitening of the goods and removal of stains therefrom Without allowing the goods to be detrimentally effected by the acid.
  • the oxalic acid is broken up or decomposed and is used up entirely when employed in hot water, therefore, the same does not remain in the goods treated therewith after the washing process has been completed.
  • powdering the oxalic acid the same is enabled to dissolve and act, simultaneously With the fluorine, in
  • the alum also enables the setting of the blueing when the goods are subsequently treated to a separate blueinp bath, and to reduce the amount of the blueing; or other dye required in such latter bath.
  • the salt not only acts to decompose the oxalic acid but serves to accelerate the liberation of fluorine from the sodium silico fluoride.
  • the present invention provides a composition which will serve to enable commercial laundries to handlefabrics in such manner that while a thorough cleansing or renovation thereof will be effected, yet premature destruction of such fabrics, by reason of the chemicals in the various baths to which they are subjected will be overcome, and consequently the said fabrics may be treated repeatedly and successively to such washing treatments without becoming unduly worn or injured by said chemicals. Furthermore, in my preparation it will only be necessary to employ sub stantially four ounces thereof to seventyfive pounds of goods treated, whereas when oxalic acid is employed alone at least six ounces thereof is necessitated.
  • the present invention not only saves the fabric, but may also be employed more economically for producing similar results than can oxalic acid.
  • oxalic acid has been used as a part of previous washing compositions of this nature, but to the best of my knowledge oxalic acid has 'never been employed in such manner as to eliminate its injurious effects upon fabrics without minimizing its ordinary effectiveness and in the economical manner set forth. I therefore claim the material set forth in the formula above given. or their chemical equivalents, it being understood that the nomenclature applied to the several materials is of secondary importance, since vari' ous other chemical terms may be applied thereto Without deviation from the real materials specified.
  • a souring composition for laundries comprising an oxalic acid base, in combination with sodium silico fluoride and salt.
  • a laundry composition comprising sodium silico fluoride, in combination with ox.- alic acid, alum. and salt.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Description

Patented Nov. 14, 1922.
STA
31; NT 7 OFF rift IPA Parr. LQMABREY, or coLU'MBUsoHIo, r
LAUNDRY PREPARATION.
No Drawing.
To all whom it may concern:
Be it known that PHIL' L. MABREY, a citsubjected prior to their emerging in the acidic or souring bath; to remove stains and generally soften the goods, or fabrics, to
' prevent injurious effectsl' thereon by reason of the chemicals contained in the variousbaths to which-the goods are subjected, and
to render the said goods adaptable and capable of more readily receiving the intended effects of the subsequent blueing baths.
In steam laundries it is the common practice in thewashing of fabrics to place the latter,-after being initially washed by one or more soap baths,;in a bath containing an alkali, usually chlorate of lime, for the purpose of bleaching and whitening generally the goods or fabrics so treated. Following this the goods are placed in an acidic bath, commonly known as a sour for the purpose of neutralizing the effects of the chlorate of lime, in order that the goods will be rendered softer and free from the rough,
.coarse orharsh effects produced therein by the remainingpresence of the alkali. Also,-
the acidic bath is utilized to remove stains and other discolorations from the goods and to thereby more efiiciently renovate the latter. In carrying out this purpose, acetic and oxalic acids are commonly utilized in imparting the necessary degree of acidity'to thi latter bath, however, it has been observedthat the acetic acid alone does not have sufficient strength to remove fruit, iron. erspiration and other stains or discoloratlons from the goods, but can be merely employed for the purpose of counteracting the effects of the alkali, Oxalic acid, on the other hand by. reason of its greater relative strength or activity is not only'capable of neutralizing the effects of the lime but; also, effectively serves in removing thediscolora tions above noted and, therefore, laundries usually adopt the same for the purpose specified. However, the use, of oxalic acid while effective in the capacity stated never- Application filed May 12,1921. Serial No. 470,282.
the-less has a distinctly detrimental effect upon the goods treatedtherewith, inasmuch as "*such goods, When' repeatedly subjected thereto and'within-"a' relatively short time becomes burned, because of the fact that the oxalic acid is very diflicult to remove from the goods, and by remaining therein causes their normal usefulness and life to be materially foreshortened.
The present invention, therefore, consists wherein oxalic acidis'present, but in combined relationship with certain other materials, hereinafter specifically set forth, which serve to permit the ordinary beneficial results of said acid to be retained but, in addition, act to enable the said acid to be decomposed and used up entirely when employed in the presence of hot water, so that substantially none, or a negligible amount, of such acidwill remain in the fabric treated therewith, and to thereby avoid undue disintegration or premature destruction of said fa rics.
To this end, I employ the following ma- 'in the provision of a souring composition terials in substantially the proportions set I forth:
sofgium silico fluoride, containing 58% uorine 59% Oxalic acid, powdered 25% Alum, powdered 8% Fine table salt 8% 'Thege materialsare assembled in bulk and are thoroughly mixed together, an efiicient mechanical mixture being obtained by means of revolving brushes, which serve to combine and 'intermingle all of the ingredients so that the same may be uniformly distributed throughout the bulk of the combined materials thus produced. These .materials when combined and mixed produce a relatively fine powdered mass, which may be placed insuitable containers for commercial handling, the sodium silico acting to hold the fluorine and to prevent it from being wasted, by reason of its volatility when the containers are being moved about.
The substance or composition produced by combining the materials set forth is, whenactively used, adapted to'be placed in hot water of substantially 190 Fab in which the fabric is to be washed, ordlnarlly but substantially four ounces or even less of the composition being employed to approxi-' mately seventy-five pounds of goods to be washed thereby. When laced in the hot Water containing the goods the sodium silico fluoride assists the oxalic acid in securing a whitening of the goods and removal of stains therefrom Without allowing the goods to be detrimentally effected by the acid. Also, by the use of the salt, the oxalic acid is broken up or decomposed and is used up entirely when employed in hot water, therefore, the same does not remain in the goods treated therewith after the washing process has been completed. By powdering the oxalic acid the same is enabled to dissolve and act, simultaneously With the fluorine, in
order that complete activity of both acids may be obtained substantially simultaneously. The alum also enables the setting of the blueing when the goods are subsequently treated to a separate blueinp bath, and to reduce the amount of the blueing; or other dye required in such latter bath. The salt not only acts to decompose the oxalic acid but serves to accelerate the liberation of fluorine from the sodium silico fluoride.
In view of the foregoing description, it will be apparent that the present invention provides a composition which will serve to enable commercial laundries to handlefabrics in such manner that while a thorough cleansing or renovation thereof will be effected, yet premature destruction of such fabrics, by reason of the chemicals in the various baths to which they are subjected will be overcome, and consequently the said fabrics may be treated repeatedly and successively to such washing treatments without becoming unduly worn or injured by said chemicals. Furthermore, in my preparation it will only be necessary to employ sub stantially four ounces thereof to seventyfive pounds of goods treated, whereas when oxalic acid is employed alone at least six ounces thereof is necessitated. Therefore, the present invention not only saves the fabric, but may also be employed more economically for producing similar results than can oxalic acid. I of course realize that oxalic acid has been used as a part of previous washing compositions of this nature, but to the best of my knowledge oxalic acid has 'never been employed in such manner as to eliminate its injurious effects upon fabrics without minimizing its ordinary effectiveness and in the economical manner set forth. I therefore claim the material set forth in the formula above given. or their chemical equivalents, it being understood that the nomenclature applied to the several materials is of secondary importance, since vari' ous other chemical terms may be applied thereto Without deviation from the real materials specified.
What is claimed is:
1. A souring composition for laundries, comprising an oxalic acid base, in combination with sodium silico fluoride and salt.
2. A laundry composition comprising sodium silico fluoride, in combination with ox.- alic acid, alum. and salt.
In testimony whereof I affix my signature.
PHIL L. MABREY.
US470282A 1921-05-12 1921-05-12 Laundry preparation Expired - Lifetime US1435541A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE744307C (en) * 1938-12-03 1944-01-13 Dr Herbert Luckmann Process for cleaning and preserving stone walls, stone monuments, masonry and lime paints
US2853536A (en) * 1954-06-11 1958-09-23 Tudor Ab Accumulator cells
US2896242A (en) * 1956-05-11 1959-07-28 Personal Products Corp Cleaning and scouring pads
US3676353A (en) * 1971-02-16 1972-07-11 Basf Wyandotte Corp Nonflouride laundry sour containing fumaric acid

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE744307C (en) * 1938-12-03 1944-01-13 Dr Herbert Luckmann Process for cleaning and preserving stone walls, stone monuments, masonry and lime paints
US2853536A (en) * 1954-06-11 1958-09-23 Tudor Ab Accumulator cells
US2896242A (en) * 1956-05-11 1959-07-28 Personal Products Corp Cleaning and scouring pads
US3676353A (en) * 1971-02-16 1972-07-11 Basf Wyandotte Corp Nonflouride laundry sour containing fumaric acid

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