US1483519A - Souring composition and method - Google Patents
Souring composition and method Download PDFInfo
- Publication number
- US1483519A US1483519A US568650A US56865022A US1483519A US 1483519 A US1483519 A US 1483519A US 568650 A US568650 A US 568650A US 56865022 A US56865022 A US 56865022A US 1483519 A US1483519 A US 1483519A
- Authority
- US
- United States
- Prior art keywords
- sour
- souring
- fluorine
- goods
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title description 8
- 238000000034 method Methods 0.000 title description 6
- 239000000463 material Substances 0.000 description 19
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 11
- 239000002253 acid Substances 0.000 description 11
- 229910052731 fluorine Inorganic materials 0.000 description 11
- 239000011737 fluorine Substances 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 10
- 239000004753 textile Substances 0.000 description 9
- 238000004061 bleaching Methods 0.000 description 7
- 230000001066 destructive effect Effects 0.000 description 6
- 239000007844 bleaching agent Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000003638 chemical reducing agent Substances 0.000 description 4
- 238000004900 laundering Methods 0.000 description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical class Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 235000011167 hydrochloric acid Nutrition 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- BFXAWOHHDUIALU-UHFFFAOYSA-M sodium;hydron;difluoride Chemical compound F.[F-].[Na+] BFXAWOHHDUIALU-UHFFFAOYSA-M 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/30—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using reducing agents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/20—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which contain halogen
- D06L4/22—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which contain halogen using inorganic agents
- D06L4/23—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which contain halogen using inorganic agents using hypohalogenites
Definitions
- the laundry sour which ll propose using comprises a compound of fluorine havin an l acid reaction in combination with a re ucing agent or other material adapted to neutralize the destructive efiect lOf chlorine, hypochlorous acid and other products or the acid decomposition of by ochlorites I from the bleach which was used in a'previous stage.
- a re ucing agent or other material adapted to neutralize the destructive efiect lOf chlorine, hypochlorous acid and other products or the acid decomposition of by ochlorites I from the bleach which was used in a'previous stage.
- One example of such an improved sour is a mixture of sodium acid fluoride and sodium sulfite; another is sodium silicofluoride and sodium bisulfite.
- any alkali which is present either free or in combination with the oxycelluloses is neutralized and the goods are thereby whitened. Certain stains are removed by reduction and decolorizing of them.
- Any insoluble lime magnesia soaps which may remain on or in the goods are so modified as to be rendered soluble in alkaline solution. By this souring opera tion the goods are put in the best shape for the bluing operation which follows and which is succeeded by the final rinsing in clear water.
- a sour of the same character is found very advantageous; that is, a sour composed of an acid compound of fluorine with a reducing agent as' above described.
- the acid compound of fluorine combines with any alkali present, to remove stains andwhiten the material and also to remove any lime salts caused by the water or by the materials used.
- Sul: phuric and hydrochloric acids have been largely used for this purpose, but any-traces thereof left in the goods will rot the latter, whereas the acid compounds of fluorine will not do so.
- the method which consists in subjecting the goods to a sour after bleaching, said sour containing an acid compound of fluorine and an agent adapted to neutralize the destructive eifect of the bleach.
- a souring composition for treating textile materials comprising an acid compound of fluorine and a neutralizing agent opposed to the destructive action of bleaches.
- a souring composition for treating textile materials after bleaching comprising an acid compound of fluorine and a reducing agent.
- a souring composition for treating textile materials including a chlorine-neutralizing agent.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
la souring operations.
Patented Feb. 12, 1924.
UNITED STATES PATENT orrica.
ROBERT PHAIR, OF ALLENDALE, NEW JERSEY, ASSIGNOR, BY MESNE ASSIGN- MENTS, TO H. KOHNSTAMM & (10., 1110., .A CORYORATION OF NEW YORK.
SOUBING COMPOSITION AND METHOD.
Ho Drawing. Original application filed July 18, 1921, Serial no. 485,642. Divided and this application filed J'une 15, 1922. Serial No. 568,650.
To all whomit may concern:
Be it known that I ROBERT A. PHAIR, a citizen of the United states, residing in A1- lendale, New Jersey, have invented certain is new and usefuhlmprovements in Souring Compositions and Methods, of which the following is aspecification.
In my application No. 485,642, filed July 18, 1921, l have described certain improveto merits in the materials and steps used in laundry work and in the analogous treatment of textile materials. The present application is a division thereof, directed particularly to the materials and steps used in After the usual laundering operations it is customary to bleach the goods and then to rinse them so as to remove the bleaching material. But there is generally a residue of the bleaching material and certain products of the bleac ing operation, which cannot be removed by rinsing, and the goods should be treated to a subsequent souring operation. My invention contemplates an improvement on such souring operations by adding to the usual laundry sour or to any suitable laundry sour a chlorine-neutralizing agent.
The laundry sour which ll propose using comprises a compound of fluorine havin an l acid reaction in combination with a re ucing agent or other material adapted to neutralize the destructive efiect lOf chlorine, hypochlorous acid and other products or the acid decomposition of by ochlorites I from the bleach which was used in a'previous stage. One example of such an improved sour is a mixture of sodium acid fluoride and sodium sulfite; another is sodium silicofluoride and sodium bisulfite.
The advantages which this sour possesses over others previousl used are several. Even if it is not thoroug ly rinsed out in the next operation, it is'not destructive of the oods. The decomposition products of the ypochlorites used in the bleaching operation have an intense destructive action, and such (products are entirely removed or neutralize by .this sour. Any of the bleach in more or less loose combination with-stains in the fabric, and which would ordinaril cause holes therein in time, is neutralize Thus the color of print goods for example,
' and also the fabric are saved from such de-,
structive efi'ects. Also any alkali which is present either free or in combination with the oxycelluloses is neutralized and the goods are thereby whitened. Certain stains are removed by reduction and decolorizing of them. Any insoluble lime magnesia soaps which may remain on or in the goods are so modified as to be rendered soluble in alkaline solution. By this souring opera tion the goods are put in the best shape for the bluing operation which follows and which is succeeded by the final rinsing in clear water.
In the treatment of textile materials, and particularly vegetable fibers, to remove the fats, waxes and other dirt prior to bleaching, mercerizing or dyeing, a sour of the same character is found very advantageous; that is, a sour composed of an acid compound of fluorine with a reducing agent as' above described. The acid compound of fluorine combines with any alkali present, to remove stains andwhiten the material and also to remove any lime salts caused by the water or by the materials used. Sul: phuric and hydrochloric acids have been largely used for this purpose, but any-traces thereof left in the goods will rot the latter, whereas the acid compounds of fluorine will not do so. Also a very much smaller quantity of the latter may be used because of the comparative sluggishness of sulphuric and hydrochloric acids; in fact about onefifteenth as much of the acid compound of fluorine will do the same amount of work. This use of an acid com ound of fluorine in the treatment of texti e materials after a boiling out of the unbleached vegetable fi-' hers is believed to be new combination with the reducing agent.
Though I have described with cat par-- ticularity of detail certain embo iments of my invention, yet it is not to be understood therefrom that the invention is restricted to the particular steps and materials described. Various modifications thereof may be made by those skilled in the art without departing from the invention as defined in the following claims.
What I claim is- 1. In launderin or treating textile materials the metho which consists in subjecting the goods after the bleaching, to
either alone or in treatment with a composition which sours and neutralizes the destructive efi'ect of the bleach.
2. In the laundering or treating of textile materials the method which consists in subjecting the goods to a sour after bleaching, said sour containing an acid compound of fluorine and an agent adapted to neutralize the destructive eifect of the bleach.
3.. In the laundering or treating of textile materials the method which consists in sub'ecting the goods to a sour containing an aci compound of fluorine with a: reducing agent.
4. In the treating of textile materials to remove fats, Waxes or other dirt, the method which includes boiling out the fibers and then subjecting the material to a sour containing an acid compound of fluorine.
5. A souring composition for treating textile materials comprising an acid compound of fluorine and a neutralizing agent opposed to the destructive action of bleaches.
6. A souring composition for treating textile materials after bleaching comprising an acid compound of fluorine and a reducing agent. I
7. A souring composition for treating textile materials including a chlorine-neutralizing agent.
In Witness whereof, I have hereunto signed my name.
ROBERT A. PHAIR.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US568650A US1483519A (en) | 1921-07-18 | 1922-06-15 | Souring composition and method |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US485642A US1435332A (en) | 1921-07-18 | 1921-07-18 | Laundering method and material |
| US568650A US1483519A (en) | 1921-07-18 | 1922-06-15 | Souring composition and method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1483519A true US1483519A (en) | 1924-02-12 |
Family
ID=27048430
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US568650A Expired - Lifetime US1483519A (en) | 1921-07-18 | 1922-06-15 | Souring composition and method |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1483519A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2521328A (en) * | 1948-10-14 | 1950-09-05 | Alrose Chemical Company | Stabilizing cellulosic textile materials against shrinkage employing glyoxal and a metal silicofluoride as a catalyst |
-
1922
- 1922-06-15 US US568650A patent/US1483519A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2521328A (en) * | 1948-10-14 | 1950-09-05 | Alrose Chemical Company | Stabilizing cellulosic textile materials against shrinkage employing glyoxal and a metal silicofluoride as a catalyst |
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