US1374A - Improvement in the process of protecting iron from oxidation - Google Patents

Improvement in the process of protecting iron from oxidation Download PDF

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Publication number
US1374A
US1374A US1374DA US1374A US 1374 A US1374 A US 1374A US 1374D A US1374D A US 1374DA US 1374 A US1374 A US 1374A
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Prior art keywords
iron
improvement
oxidation
zinc
tin
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/06Zinc or cadmium or alloys based thereon

Definitions

  • the plates or sheets of iron preserve their malleability unimpaired, and may be bent and otherwise worked as easily as before they had received such coating-a result which appears to be due to theinterposition of the coatingof tin between the zinc and the iron, by which interposition the chemical combination of the iron and zinc is prevented.
  • plates of metal of a larger size than that of sheets of tin-plate we take that material as it comes from the manufactories, and have then only to give to it a coating of zinc, to receive which it does not require any particular. preparation.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Description

UNITED STATES PATENT OFFICE.
PALMER SUMNER AND PETER NAYLOR, OF NEW YORK, N. Y.
IMPROVEMENT IN THE PROCESS OF PROTECTING lRON FROM OXIDATION.
Specification forming part of Letters Patent 'No. [,374, dated October 18, 1839.
To all whom it may concern:
Be it known that we, PALMER SUMNER and PETER NAYLOR, of the city of New York, in the State of New York, have invented an improvement in the process, method, or methods by which various articles of iron or steel may be preserved from oxidation or rusting by the galvanic action produced by zinc, (for which process Lei tcrs Patentwere granted to M. Sorel on the 7th day of December, 1837 and we do hereby declare that the following is a full and exact description of our improvement.
We, the said PALMER SUMNER and PETER NAYLOR, having become proprietors, by assignment, of a right to use the said process, have, in carrying the same into practical op eration, found the malleability of sheet-ironis much impaired by giving thereto a coating of zinc in the manner directed in the specification of the Letters Patent of said M. Sore], and that in consequence of this diminished malleability such prepared sheet-iron is unsuited in many cases to be applied to the purpose of covering the roofs of houses, or to be otherwise used where it is required to be grooved, seamed, or in any way suddenly bent; and our improvement consists in a process by which this difficulty is obviated, while the zinc is at the same time so applied as, by its galvanic action on the iron, to protect it from oxidation.
. We take sheets of iron and cover them with tin or with an alloy of tin and lead, adopting in this process the mode or modes followed in the well-known manufacture of sheets or plates of iron into tin-plate After having completed this operation we submit the sheets or plates so prepared to a like process, with the substitution of zinc for tin or an alloy of tin, the mode of performing which process is fully set forth in the Letters Patent granted to said M. Sore], and does not dider from the ordinary process known under the name of tinning. When thus treated the plates or sheets of iron preserve their malleability unimpaired, and may be bent and otherwise worked as easily as before they had received such coating-a result which appears to be due to theinterposition of the coatingof tin between the zinc and the iron, by which interposition the chemical combination of the iron and zinc is prevented. Where it is not necessary to use plates of metal of a larger size than that of sheets of tin-plate we take that material as it comes from the manufactories, and have then only to give to it a coating of zinc, to receive which it does not require any particular. preparation.
In the Letters Patent granted to M. Sorel it is proposed sometimes to add a coating of tin over that of the zine for the purpose of giving to the article made a bright appearance, and as an improvement also in culinary vessels; but our process is the reverse of this, and the end attained by us altogether different from that above proposed, and at the same time our process produces a new and useful result.
What we claim, therefore, as our invention, and as an improvement on the process of ill. Sorel, is-
1. The preserving the mallcability ofsheetiron while it is protected from oxidation by the galvanic action between it and zinc, in the manner herein set forth-namely, by first tinning said iron in the ordinary way and afterward by giving thereto a coating of zinc above the tin.
2. The protection of iron and manufactures of iron generally from rust by the same process.
PALMER SUMNER. PETER NAYLOR.
Witnesses:
K. S. VAN VooEHis, GEo. STEVENs.
US1374D Improvement in the process of protecting iron from oxidation Expired - Lifetime US1374A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2557764A (en) * 1947-03-06 1951-06-19 Henry A Roemer Method of coating strip steel with a protective metal coating
US4482377A (en) * 1983-04-15 1984-11-13 Chempro Corporation Separation of zinc from a zinc-copper alloy
US20100127232A1 (en) * 2004-12-02 2010-05-27 Koninklijke Philips Electronics N.V. Non-volatile memory

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2557764A (en) * 1947-03-06 1951-06-19 Henry A Roemer Method of coating strip steel with a protective metal coating
US4482377A (en) * 1983-04-15 1984-11-13 Chempro Corporation Separation of zinc from a zinc-copper alloy
US20100127232A1 (en) * 2004-12-02 2010-05-27 Koninklijke Philips Electronics N.V. Non-volatile memory

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