US1333465A - Manufacture of parchmentized paper, vulcanized fiber, and the like - Google Patents
Manufacture of parchmentized paper, vulcanized fiber, and the like Download PDFInfo
- Publication number
- US1333465A US1333465A US303185A US30318519A US1333465A US 1333465 A US1333465 A US 1333465A US 303185 A US303185 A US 303185A US 30318519 A US30318519 A US 30318519A US 1333465 A US1333465 A US 1333465A
- Authority
- US
- United States
- Prior art keywords
- paper
- thiocyanate
- solution
- manufacture
- thiocyanates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000835 fiber Substances 0.000 title description 7
- 238000004519 manufacturing process Methods 0.000 title description 6
- 239000000243 solution Substances 0.000 description 24
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 15
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 15
- 150000003567 thiocyanates Chemical class 0.000 description 12
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 229960000583 acetic acid Drugs 0.000 description 3
- 239000012224 working solution Substances 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- ALWXETURCOIGIZ-UHFFFAOYSA-N 1-nitropropylbenzene Chemical compound CCC([N+]([O-])=O)C1=CC=CC=C1 ALWXETURCOIGIZ-UHFFFAOYSA-N 0.000 description 1
- LJBWEZVYRBKOCI-UHFFFAOYSA-N 2,4,6-triaminoquinazoline Chemical compound N1=C(N)N=C(N)C2=CC(N)=CC=C21 LJBWEZVYRBKOCI-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- SXTGAOTXVOMSFW-UHFFFAOYSA-L magnesium;dithiocyanate Chemical compound [Mg+2].[S-]C#N.[S-]C#N SXTGAOTXVOMSFW-UHFFFAOYSA-L 0.000 description 1
- 231100000989 no adverse effect Toxicity 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/09—Sulfur-containing compounds
Definitions
- This invention has reference to the manufacture of parchmentized paper (so-called) vulcanized fiber and the like.
- thiocyanates of calcium, magnesium, strontium and lithium will by themselves give satisfactory results.
- satisfactory results may be obtained by employing two or more thiocyanates in conjunction, as e. g. by dissolving waterinsoluble or sparingly-soluble thiocyanates in solutions of readily water-soluble thiocyanates, or by partly replacing the solutlons of thiocyanates by solutions of other salts, e. 9. calcium chlorid, which do not adversely affect the action of the thiocyanate" or thiocyanates and which themselves may have no parchmentizing action upon paper. By the latter method, a considerable economy in thiocyanate can in some cases be effected.
- the thiocyanate s0 lutions operate best when they are of high concentration, but in-some cases the volume of thiocyanate solution necessary to conveniently treat the paper would, if highly concentrated, contain more thiocyanate than actually required to act upon the paper. In such cases, therefore, the thiocyanate or thiocyanates can be partly replaced in the working solution by a salt or salts having no adverse effect on the action of the thiocyanate or thiocyanates, without reducing the concentration of the latter in the working solution.
- the working solutions may be acidified (preferably with acetic acid) the effect of which is to increase the capacity of the solutions to parchmentlze paper and the rate of speed of the parchmentizing action, and also to prevent viscosity of the solutions.
- the solutions with which the paper is treated may be acidified by adding acetic acid thereto in the proportion of 4 parts by volume of glacial acetic acid to parts of solution.
- Vulcanized fiber or the like may be paper" is afterward washed and dried -in the usual way.
- parchnientizing paper which consists in treating the paper with a heated solution of a substantially water-insoluble thiocyanate in a solution of a substantially water-soluble thiocyanate.
Landscapes
- Paper (AREA)
Description
UNITED STATES PATENT OFFICE.
' AND HERBERT ERNEST WILLIAMS, OF MANCHESTER, ENGLAND, ASSIGNORS TO THE MANCHESTER OXIDE COMPANY, LIMITED, OF MANCHESTER, ENGLAND.
MANUFACTURE OF PARCI-IMENTIZED PAPER, VU'LCANIZED FIBER, AND THE LIKE.
No Drawing.
To all whom it may concern.
Be it known that we, ROBERT HENRY CLAYTON, JULIUs. HUEBNER, and HERBERT ERNEST WILLIAMS, subjects of the King of Great Britain and Ireland, and residents of Manchester, in the county of Lancaster, England; Cheadle Hulme, in the county of Chester, England; and Manchester, in the county of Lancaster, England,.respectively, have invented certain Improvements in or Relating to the Manufacture of Parchmentized Paper, Vulcanized Fiber, and the like, of which the following is a specification,
This invention has reference to the manufacture of parchmentized paper (so-called) vulcanized fiber and the like.
We have found that thiocyanates have a parchmentizing action upon paper. ,We have further found that some thiocyanates,
e. g. the thiocyanates of calcium, magnesium, strontium and lithium, will by themselves give satisfactory results. In other cases, satisfactory results may be obtained by employing two or more thiocyanates in conjunction, as e. g. by dissolving waterinsoluble or sparingly-soluble thiocyanates in solutions of readily water-soluble thiocyanates, or by partly replacing the solutlons of thiocyanates by solutions of other salts, e. 9. calcium chlorid, which do not adversely affect the action of the thiocyanate" or thiocyanates and which themselves may have no parchmentizing action upon paper. By the latter method, a considerable economy in thiocyanate can in some cases be effected. The thiocyanate s0 lutions operate best when they are of high concentration, but in-some cases the volume of thiocyanate solution necessary to conveniently treat the paper would, if highly concentrated, contain more thiocyanate than actually required to act upon the paper. In such cases, therefore, the thiocyanate or thiocyanates can be partly replaced in the working solution by a salt or salts having no adverse effect on the action of the thiocyanate or thiocyanates, without reducing the concentration of the latter in the working solution. It .will, of course, be understood that we may also partly replace the thiocyanate or thiocyanates or the solutions thereof by other salts or solutions of other salts which,=themselves, have a parchment- Specification of fLetters Patent.
Application filed June 10, 1919.
Patented Mar. 9, 1920.
Serial No. 303,185.
izing action upon paper. The working solutions may be acidified (preferably with acetic acid) the effect of which is to increase the capacity of the solutions to parchmentlze paper and the rate of speed of the parchmentizing action, and also to prevent viscosity of the solutions.
The following examples will serve to illus I trate the employment of thiocyanates for'the purpose referred to. I
Ewmmple I.
A solution of calcium thiocyanate, of such concentration as to boil at 157 C.
under atmospheric pressure, is heated to and maintained at 130 C. and unsized cotton or otherpaper is passed through the solution atsuch a speed that the paper is in contact with the solution for about 30 seconds. The paper is then washed and dried in the usualv way.
E'mtmtple Q.
. One part by weight of mercuric thiocyanate 1s dlssolved in a solution of two parts of magnesium thiocyanate and the resulting solution concentrated by evaporation until the boiling point rises to 145 C. under atmospheric pressure. The solution is then heated to 130 C. and maintained at this temperature while unsized cotton or other paper is passed therethrough at such a speed that, it is in contact with the solution for about 15 seconds. The paper is afterward washed and dried in the usual way.
Example 3.
passed through the solution so as to be in contact therewith for about 30 seconds.v
The
In the foregoing examples, the solutions with which the paper is treated may be acidified by adding acetic acid thereto in the proportion of 4 parts by volume of glacial acetic acid to parts of solution.
Vulcanized fiber or the like may be paper" is afterward washed and dried -in the usual way.
manufactured from paper treated as above described, in the same manner in which such fiber or the like is at present manufactured from paper treated with sulfuric acid or zinc chlorid.
lVhat we claim as our invention, and desire to secure by Letters Patent is 1. The process of parchinentizing paper. which consists in treating the paper with a heated thiocyanate solution,
2. The process of parchnientizing paper, which consists in treating the paper with a heated solution of a substantially water-insoluble thiocyanate in a solution of a substantially water-soluble thiocyanate.
3. The process of parchmentizing paper.
which consists in treating the paper with a heated solution of a thiocyanate and a salt which does not adversely affect the action of the thiocyanate and which may itself have no parchmentizing action upon paper.
at. The process of parchmentizing paper, which consists in treating the paper with a heated solution of an acidified thiocyanate solution.
5. The process of manufacturing (socalled) vulcanized fiber and the like,
which consists in treating paper with a heated thiocyanate solution and manufacturing the thus treated paper into vulcanized fiber orvthe like.
In Witness where-of we have hereunto set our hands.
ROBERT HENRY CLAYTON. JULIUS HUEBNER. HERBERT ERNEST VILLIAMS.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB10568/18A GB124979A (en) | 1918-06-27 | 1918-06-27 | Improvements in or relating to the Manufacture of Parchmentised Paper, "Vulcanised" Fibre and the like. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1333465A true US1333465A (en) | 1920-03-09 |
Family
ID=23170891
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US303185A Expired - Lifetime US1333465A (en) | 1918-06-27 | 1919-06-10 | Manufacture of parchmentized paper, vulcanized fiber, and the like |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US1333465A (en) |
| FR (1) | FR500504A (en) |
| GB (1) | GB124979A (en) |
| NL (1) | NL7580C (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2583548A (en) * | 1948-03-17 | 1952-01-29 | Vanderbilt Co R T | Production of pigmented cellulosic pulp |
| US2676885A (en) * | 1946-09-19 | 1954-04-27 | Syntics Ltd | Manufacture of articles such as boards and sheets from fibrous vegetable materials |
| US3268291A (en) * | 1962-09-14 | 1966-08-23 | Charles H Mack | Process for the production of permanent creases in cellulosic textiles utilizing inorganic salt solutions |
| US5096539A (en) * | 1989-07-24 | 1992-03-17 | The Board Of Regents Of The University Of Washington | Cell wall loading of never-dried pulp fibers |
-
0
- NL NL7580D patent/NL7580C/xx active
-
1918
- 1918-06-27 GB GB10568/18A patent/GB124979A/en not_active Expired
-
1919
- 1919-06-06 FR FR500504A patent/FR500504A/en not_active Expired
- 1919-06-10 US US303185A patent/US1333465A/en not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2676885A (en) * | 1946-09-19 | 1954-04-27 | Syntics Ltd | Manufacture of articles such as boards and sheets from fibrous vegetable materials |
| US2583548A (en) * | 1948-03-17 | 1952-01-29 | Vanderbilt Co R T | Production of pigmented cellulosic pulp |
| US3268291A (en) * | 1962-09-14 | 1966-08-23 | Charles H Mack | Process for the production of permanent creases in cellulosic textiles utilizing inorganic salt solutions |
| US5096539A (en) * | 1989-07-24 | 1992-03-17 | The Board Of Regents Of The University Of Washington | Cell wall loading of never-dried pulp fibers |
Also Published As
| Publication number | Publication date |
|---|---|
| GB124979A (en) | 1919-04-10 |
| FR500504A (en) | 1920-03-16 |
| NL7580C (en) |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2399156A (en) | Treatment of rubber | |
| GB350902A (en) | A process for improving artificial fibres made from viscose | |
| US1546211A (en) | Manufacture of products containing cellulose | |
| GB124979A (en) | Improvements in or relating to the Manufacture of Parchmentised Paper, "Vulcanised" Fibre and the like. | |
| US2528517A (en) | Impregnated protective charcoal and its manufacture | |
| GB496234A (en) | Process for improving artificial silk fabrics | |
| US1301652A (en) | Process of treating cellulose. | |
| US2002063A (en) | Manufacture of fibroin solutions | |
| GB692478A (en) | A process for the treatment of keratinous materials and production of articles from the treated materials | |
| US1972098A (en) | Cuprammonium process for dissolving cellulose | |
| US1726252A (en) | Complex compounds of aromatic paradiamines with sulphur dioxide and process of preparing same | |
| US1549886A (en) | Method of preparing sulphur in colloidal form | |
| US1897189A (en) | Preparation of vulcanizable latex | |
| US1755657A (en) | Caustic-soda solution of cellulose | |
| GB573471A (en) | Improvements in and relating to fire-retardant treatments for organic fibrous materials | |
| US1848553A (en) | oe berlin | |
| US955082A (en) | Cellulose formate. | |
| US1379699A (en) | Cellulose composition | |
| SU90542A1 (en) | The method of increasing the strength and water resistance of glass fabrics | |
| US2422078A (en) | Treatment of cellulosic fibres | |
| US1531143A (en) | Process for obtaining new effects on animal fibers | |
| US2120572A (en) | Process and product for obtaining rapid coagulation of rubber | |
| US2535103A (en) | Method for improving the strength of artificial insolubilized protein filaments | |
| GB187987A (en) | Improved manufacture of water resisting paper | |
| GB328627A (en) | Improvements in and relating to the manufacture of artificial silk and like products |