US12151A - Improvement in compositions for unhairing hides - Google Patents
Improvement in compositions for unhairing hides Download PDFInfo
- Publication number
- US12151A US12151A US12151DA US12151A US 12151 A US12151 A US 12151A US 12151D A US12151D A US 12151DA US 12151 A US12151 A US 12151A
- Authority
- US
- United States
- Prior art keywords
- soda
- improvement
- skin
- carbonate
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title 2
- 210000003491 Skin Anatomy 0.000 description 32
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate dianion Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 20
- PMZURENOXWZQFD-UHFFFAOYSA-L na2so4 Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 16
- 238000000034 method Methods 0.000 description 14
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 8
- VXMKYRQZQXVKGB-CWWHNZPOSA-N Tannin Chemical compound O([C@H]1[C@H]([C@@H]2OC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)O[C@H]([C@H]2O)O1)O)C(=O)C1=CC(O)=C(O)C(O)=C1 VXMKYRQZQXVKGB-CWWHNZPOSA-N 0.000 description 8
- 235000015450 Tilia cordata Nutrition 0.000 description 8
- 235000011941 Tilia x europaea Nutrition 0.000 description 8
- 239000004571 lime Substances 0.000 description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- 235000018553 tannin Nutrition 0.000 description 8
- 229920001864 tannin Polymers 0.000 description 8
- 239000001648 tannin Substances 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 6
- 239000011148 porous material Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- 235000017550 sodium carbonate Nutrition 0.000 description 4
- 241000272201 Columbiformes Species 0.000 description 2
- 210000003608 Feces Anatomy 0.000 description 2
- 241001137350 Fratercula Species 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 238000003287 bathing Methods 0.000 description 2
- 230000002951 depilatory Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000002515 guano Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 230000002522 swelling Effects 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C1/00—Chemical treatment prior to tanning
- C14C1/06—Facilitating unhairing, e.g. by painting, by liming
Definitions
- my invention consists in the employment of a solution of carbonate and sulphate of soda, into which the hide or skin is to be steeped, for the purpose of loosening its hair and preparing said hide or skin for the application of tannin to it.
- the hide or skin with the hair on is to be steeped for about two days in this solution.
- the hair may be removed from it by the usual process of beaming, the skin being left in a much better state for being tanned than when it is sweated or prepared with lime in the usual way.
- soda-ash and lime which of late has been the practice with some tanners in the preparation of skins for the reception of tannin, the skins have to be subjected to what is termed the drenching process in order to remove the lime.
- This drenching process con sists in immersing them in a solution of guano, pigeons or hens dung, and it is a very offensive and disagreeable mode of treatment.
- soda-ash and lime generally requires about three weeks soaking of a skin in order to properly prepare it. With my improved mode of treating the skin it is prepared for the beamster in about two days. By my improvement the drenching ofthe skins is entirely avoided. As soon as the hair has been removed, or the Skin hasbeen beamed, it should be rinsed in clear water. It is then ready to be tanned. When the hair is removed by the solution of the carbonate and sulphate of Soda, the hide is left in a puffed up state, and with its pores opened for the reception of the tanning material, into which it is next to be put.
- the hide After the hide has absorbed as much of the tanning-liquor as it apparently can, it may be removed from the tan-vat and rinsed in water, in order to remove the material that clogs the pores, as they will be found to be more or less clogged with foreign matter.
- the'skin When sufficiently rinsed the'skin may be again put into a solution of the depilatory salts or carbonate and sulphate of soda, which will have the effect of puffin g or swelling it and distending the pores. It may again be returned to the tanning-vat, where it will absorb more of the tanning-liquor. This process may be repeated until thehide is thoroughly tanned.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Description
UNITED STATES PATENT OFFICE.
ANDREW H. WARD, JR, or BOSTON, MASSAoHUSErrS, ASSIGNOR TO A. H. WARD, R, AND KIRK BOOTT.
IMPROVEMENT IN COMPOSITIONS FOR UNHAIRING HIDES.
Specification forming part of Letters Patent No. 12,151 dated January 2, 1855.
To all whom it may concern:
Be it known that 1, ANDREW H. WARD, J r., of Boston, in the county of Suffolk and State of Massachusetts, have invented a new and useful improvement in treating skins or hides, either previous to or during the process of tanning them and I do hereby declare that the sameis fully described and represented in the following specification.
The nature of my invention consists in the employment of a solution of carbonate and sulphate of soda, into which the hide or skin is to be steeped, for the purpose of loosening its hair and preparing said hide or skin for the application of tannin to it.
In carrying out my invention I make use of about two pounds of the carbonate of soda to one pound of the sulphate of soda, and fifteen gallons or one hundredand twenty pounds (avoidupois) of liquid or water, not confining myself strictly to such proportions, as the same may be somewhat varied and Still be productive of good results.
The hide or skin with the hair on is to be steeped for about two days in this solution. At the end of this time the hair may be removed from it by the usual process of beaming, the skin being left in a much better state for being tanned than when it is sweated or prepared with lime in the usual way.
In using soda-ash and lime, which of late has been the practice with some tanners in the preparation of skins for the reception of tannin, the skins have to be subjected to what is termed the drenching process in order to remove the lime. This drenching process con sists in immersing them in a solution of guano, pigeons or hens dung, and it is a very offensive and disagreeable mode of treatment.
The employment of soda-ash and lime generally requires about three weeks soaking of a skin in order to properly prepare it. With my improved mode of treating the skin it is prepared for the beamster in about two days. By my improvement the drenching ofthe skins is entirely avoided. As soon as the hair has been removed, or the Skin hasbeen beamed, it should be rinsed in clear water. It is then ready to be tanned. When the hair is removed by the solution of the carbonate and sulphate of Soda, the hide is left in a puffed up state, and with its pores opened for the reception of the tanning material, into which it is next to be put. After the hide has absorbed as much of the tanning-liquor as it apparently can, it may be removed from the tan-vat and rinsed in water, in order to remove the material that clogs the pores, as they will be found to be more or less clogged with foreign matter. When sufficiently rinsed the'skin may be again put into a solution of the depilatory salts or carbonate and sulphate of soda, which will have the effect of puffin g or swelling it and distending the pores. It may again be returned to the tanning-vat, where it will absorb more of the tanning-liquor. This process may be repeated until thehide is thoroughly tanned.
By the employment of the solution of carbonate and sulphate of soda for depilating a skin and preparing it for the reception of tannin it will be better tanned in eight days than in the great length of time (generally Several months) that is usually consumed by the ordinary process of liming, bathing, beaming, and tanning.
I have found that the use of carbonate of soda alone in depilating the hide is along and tedious operation, several weeks bein ,9; required to prepare the skin so that the hair maybe removed. By the addition of sulphate of Soda to the carbonate in Solution a wonderful acceleration of the process is effected.
I shall not pretend .to state the rationale of the action of the hydrated compound solution;
but as experience and observation have exhibited a result of great importance in the use of this compound solution in the manner as described, it is not necessary for me to go into chemical explanation of the manner in which the Solution of the carbonate and sulphate of Soda is made to operate so much more expeditiously on the skin than a solution of either the carbonate or sulphate alone.
The application'ofa compound solution of carbonate and sulphate of soda to hides and skins for the purpose of loosening their hair and preparing them for the reception of tannin.
In testimony whereof I have hereunto set my signature this 20th day of May, A. D. 1854.
ANDREW I-I. WARD, JR.
Publications (1)
Publication Number | Publication Date |
---|---|
US12151A true US12151A (en) | 1855-01-02 |
Family
ID=2072489
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12151D Expired - Lifetime US12151A (en) | Improvement in compositions for unhairing hides |
Country Status (1)
Country | Link |
---|---|
US (1) | US12151A (en) |
-
0
- US US12151D patent/US12151A/en not_active Expired - Lifetime
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