US121263A - Improvement in converting articles made of wrought-iron into steel - Google Patents

Improvement in converting articles made of wrought-iron into steel Download PDF

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US121263A
US121263A US121263DA US121263A US 121263 A US121263 A US 121263A US 121263D A US121263D A US 121263DA US 121263 A US121263 A US 121263A
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iron
steel
wrought
improvement
cast
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/28Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases more than one element being applied in one step
    • C23C8/30Carbo-nitriding
    • C23C8/32Carbo-nitriding of ferrous surfaces
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49716Converting

Definitions

  • my invention consists in manufacturing the articles to be treated under my process of and with wrought-iron first, and immersing them in a bath of molten cast-iron free from sulphur and phosphorus, and carburized to its utmost capacity.
  • the best for that purpose is spiegleisen, but in default thereof, such cast-iron may be made by melting good malleable iron or blister-steel in a cupola-furnace with charcoal, or the best anthracite coal, or bituminous coal, or coke, as fuel.
  • the articles are left in this bath a space of time which must vary with the degree of hardness desired to be imparted to the metal and with the size of the articles, and also according to the intention of converting the whole mass of the metal into steel, or simply of converting the surface so as to retain a core of malleable 11011.
  • This brasque is intended to supply to the bath dated November 28, 1871;; antedated November 13, 1871.
  • the converting-bath of cast-iron may also be covered during the operation with a glass or slag covering, so as to prevent the loss of carbon by contact with the gas of the furnace.
  • the time required for the degree of conversion sought for the converted articles are taken out or, still better, the castiron is tapped and run off, and the heat in the crucible or furnace increased so as to free the objects from any portion of cast-iron which might adhere to them, when it will be found that they are according as the operation has been conductedpartly or totally converted into steel, the quality of which will depend upon that of the iron used.
  • the cementation or conversion into steel of articles made of wrought-iron by immersing them in a bath of molten cast-iron after they have been partially worked into their respective shapes, whereby the heaviest parts of the work is accomplished upon wrought-iron and not upon steel, and the operation of welding steel to iron is dispensed with.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Furnace Housings, Linings, Walls, And Ceilings (AREA)

Description

PATENT OFFICE.
LOUIS LA BREOHE-VIGER,
OF MONTREAL, CANADA.
IMPROVEMENT IN CONVERTING ARTICLES MADE OF WROUGHHRUN INTO STEEL.
Specification forming part of Letters Patent No. 121,263,
To all whom it may concern:
Be it known that I, LoUIs LA BREoHE-VIGER, of Montreal, Province of Quebec, Dominion of Canada, have invented a new and useful improvement in the manufacture of axes, chisels, hammers, saws, angers, and of all other tools and instruments which are usually made of steel or of malleable iron, or partly of both, by welding, and also in the manufacture of rails, axles, and of all parts of machinery of any kind in which steel may be substituted for malleable iron, or may be usefully combined with malleable iron by Welding; and I declare that the following is a full and exact description thereof.
The nature of my invention consists in manufacturing the articles to be treated under my process of and with wrought-iron first, and immersing them in a bath of molten cast-iron free from sulphur and phosphorus, and carburized to its utmost capacity. The best for that purpose is spiegleisen, but in default thereof, such cast-iron may be made by melting good malleable iron or blister-steel in a cupola-furnace with charcoal, or the best anthracite coal, or bituminous coal, or coke, as fuel. The articles are left in this bath a space of time which must vary with the degree of hardness desired to be imparted to the metal and with the size of the articles, and also according to the intention of converting the whole mass of the metal into steel, or simply of converting the surface so as to retain a core of malleable 11011.
For small objects crucibles may be used, and for larger articles, or when large quantities are to be converted, reverberatory furnaces of all the descriptions now known may be employed.
After a number of operations the cast-iron bath would not be rich enough in carbon, and
consequently the heat required to maintain it in a molten condition would be too high, which circumstance might cause the fusion of the parts sufficiently carburized before the underlying layers had attained to the proper degree of conversion; but to obviate this difficulty and retain to the cast-iron the required fluidity compatible with the lowest degree of heat, I line the crucibles and the bottom of the furnaces, which I build with silicious sand, with a brasque of charcoalpowder or of plumbago, into which I may incorporate nitrogenous matters, such as cyanides or animal matter, as leather or horn pulverized.
This brasque is intended to supply to the bath dated November 28, 1871;; antedated November 13, 1871.
of cast-iron the carbon which may be abstracted from it by the metal during cementation, and also the nitrogen which may be useful to the metal; but it is not indispensable to the process, as the bath of cast-iron may be renewed after each operation by using fresh cast-iron, or by remelting the same in a cupola-furnace in contact With as pure fuel as possible, and running it directly from the cupola over the objects to be converted. The converting-bath of cast-iron may also be covered during the operation with a glass or slag covering, so as to prevent the loss of carbon by contact with the gas of the furnace. After remaining in the converting-bath the time required for the degree of conversion sought for the converted articles are taken out or, still better, the castiron is tapped and run off, and the heat in the crucible or furnace increased so as to free the objects from any portion of cast-iron which might adhere to them, when it will be found that they are according as the operation has been conductedpartly or totally converted into steel, the quality of which will depend upon that of the iron used.
I do not claim as my invention the principle of cementing malleable iron by immersion in molten cast-iron, as this was to a certain extent practiced anciently upon lumps of wrought-iron; but
I claim as my inventionl. The cementation or conversion into steel of articles made of wrought-iron by immersing them in a bath of molten cast-iron after they have been partially worked into their respective shapes, whereby the heaviest parts of the work is accomplished upon wrought-iron and not upon steel, and the operation of welding steel to iron is dispensed with.
2. The cementation or conversion into steel of articles made of wrought-iron by immersing them in a bath of cast-iron in fusion in such a way as to convert only the surface ofsuch articles to the required depth, leaving the interior in its original state of malleable iron, thereby producing articles externally as hard as those made of pure steel, with the toughness dependent on that part of their substance retaining the nature of malleable iron, and free from the inconvenience of imperfect welding.
3. The use of furnaces to effect such conversion on a large scale, as set forth.
4. The lining of crucibles or furnaces with a the cast-iron to said oupola-furnaee Whenever required, the whole as above described, and for the purposes set forth in the foregoing specification.
Montreal May 3, 1871.
LOUIS LA BREGHE-VIGER.
Witnesses L. LAFLAMME, M. A. ADAM.
US121263D Improvement in converting articles made of wrought-iron into steel Expired - Lifetime US121263A (en)

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