USRE4434E - Improvement in the manufacture of iron and steel - Google Patents
Improvement in the manufacture of iron and steel Download PDFInfo
- Publication number
- USRE4434E USRE4434E US RE4434 E USRE4434 E US RE4434E
- Authority
- US
- United States
- Prior art keywords
- iron
- steel
- manufacture
- improvement
- oil
- Prior art date
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title description 108
- 229910052742 iron Inorganic materials 0.000 title description 54
- 229910000831 Steel Inorganic materials 0.000 title description 36
- 239000010959 steel Substances 0.000 title description 36
- 238000004519 manufacturing process Methods 0.000 title description 16
- 239000002184 metal Substances 0.000 description 16
- 229910052751 metal Inorganic materials 0.000 description 16
- 238000000034 method Methods 0.000 description 10
- 239000012535 impurity Substances 0.000 description 8
- 229940072033 potash Drugs 0.000 description 8
- 235000015320 potassium carbonate Nutrition 0.000 description 8
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 8
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 8
- XFXPMWWXUTWYJX-UHFFFAOYSA-N cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 6
- 238000000746 purification Methods 0.000 description 6
- 229910001018 Cast iron Inorganic materials 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N Calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- LWJROJCJINYWOX-UHFFFAOYSA-L Mercury(II) chloride Chemical compound Cl[Hg]Cl LWJROJCJINYWOX-UHFFFAOYSA-L 0.000 description 2
- RCTGMCJBQGBLKT-PAMTUDGESA-N Scarlet Red Chemical compound CC1=CC=CC=C1\N=N\C(C=C1C)=CC=C1\N=N\C1=C(O)C=CC2=CC=CC=C12 RCTGMCJBQGBLKT-PAMTUDGESA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Inorganic materials [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 235000010333 potassium nitrate Nutrition 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 229960005369 scarlet red Drugs 0.000 description 2
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 2
Definitions
- the combustion of this will cause an immediate flux of the molten mass, separating the carbon and impurities from the iron, leaving it pure decarbonized iron, and both malleable and ductile.
- the length of time required for the purification of the iron depends much upon the quality of the ore and the amount of impurities it contains, usually about four hours.
- the operator can judge when the iron is purified sufficiently for the purpose for which he wishes to apply it by the color of the blaze coming from the iron for when the iron is cleansed from all impurities the blaze becomes of a scarlet-red color and the iron becomes thicker in the furnace and requires greater heat to keep it fluid.
- the length of time required to convert such iron into steel depends much on the temper desired.
- a mild-tempered steel may be produced in this way in thirty minutes, and a very ,highlycarbonized steel in two hours. This steel being sufficiently carbonized, it is ready to be drawn olf and worked into bars or into any desired shape.
- This steel is admirably adapted for tools that are to be used where they are exposed to heat, friction, or heavy blows, for it is possessed of greater hardness and tenacity than other steel, and, therefore, has greater powers of resistance; and when used for edged tools its powers of resistance and durability are wonderful. Being of a closer grain, finer texture, and greater tenacity, it is of the utmost value for many purposes. I therefore propose to manufacture all such tools and other articles for which this metal is specially adapted directly from it, when the said treatment is completed, and before the metal has cooled, by casting in metal molds of special forms and shapes for the different tools, such as hammers of all kinds, pick-axes, drills, stone-picks, and the like.
Description
UNITED STATES PATENT OFFICE,
RICHARD YEILDING, OF DETROIT, MICHIGAN, ASSIGNOR TO FRANK W. ISHAM AN D ELIZABETH YEILDING.
IMPROVEMENT IN THE MANUFACTURE OF IRON AND STEEL.
Specification forming part of Letters Patent No. 83,119, dated October 13, 1868; reissue No. 4,434, dated June To all whom it may concern:
Be it known that I, RICHARD YEILDING, of the city of Detroit, in the county of Wayne and State of Michigan, have discovered a new and Improved Method of Fusing and Cleansing Metal from its Ore and all its Impurities, and of Manufacturing Pure Iron and Steel Direct from the ()re and Crude Metal Without Remelting; and I do hereby declare that the following is a full and exact description of my process.
The nature of my discovery consists in the use of chemicals and oil for the purpose of fusing, purifying, and decarbonizing the crude metal and making pure iron, and recarbonizing the iron again and making it steel.
To enable others skilled in the art of manufacturing iron and steel to use my discovery, I will proceed to explain the process.
To manufacture iron I place the ore or crude iron in a cupola or furnace, apply the fuel,(coke or charcoal,) and fuse the metal in the ordinary way and when brought to a molten state I take ten gallons of petroleum-oil, or any of its kindred fluids except the baser residuum, mix with it one pound of finely-powdered saltpeter and one pound of pulverized potash, mixed thoroughly with the oil, and inject it into the bottom of the molten iron, through a suitable aperture,by mechanical force or gravity. This is sufficient for the purification of about a ton of iron. This solution must be applied gradually and very slowly. The combustion of this will cause an immediate flux of the molten mass, separating the carbon and impurities from the iron, leaving it pure decarbonized iron, and both malleable and ductile. The length of time required for the purification of the iron depends much upon the quality of the ore and the amount of impurities it contains, usually about four hours. The operator can judge when the iron is purified sufficiently for the purpose for which he wishes to apply it by the color of the blaze coming from the iron for when the iron is cleansed from all impurities the blaze becomes of a scarlet-red color and the iron becomes thicker in the furnace and requires greater heat to keep it fluid. When it assumes this appearance it is pure decarbonized iron, and may be drawn off and run into ingots, or at once put into any desired shape by the application of the tilt-hammer or roller. If I now wish to convert this into carbonized steel, I continue the iron in its molten state, discontinue the use of the chemicals described above, and apply a solution of ten gal lons of oil and one pound of prussiate of potash, in the same manner as the first was applied, closing the top of the furnace so as to exclude the atmospheric air. The combustion of the oil and prussiate of potash will create a carbonic gas that will penetrate the entire mass of iron, replace the carbon that has been thrown out in the process of purification of the iron, and it is thus at once converted into steel. The length of time required to convert such iron into steel depends much on the temper desired. A mild-tempered steel may be produced in this way in thirty minutes, and a very ,highlycarbonized steel in two hours. This steel being sufficiently carbonized, it is ready to be drawn olf and worked into bars or into any desired shape.
If I wish to convert iron into steel that cannot be annealed by heat or friction, heat below that required to fuse it,) instead of using the prussiate of potash I use the oxide of copper, oxide of zinc, and corrosive sublimate, in the same manner as is described for the manufacture of carbonized steel. The time required for changing iron into this kind of steel need not exceed one hour; and this may be readily molded, like cast-iron, into any article that cast-iron may be molded. The proportion of these oxides is one pound of each to ten gallons of oil. They should all be finely pulverized and mixed with the oil.
This steel is admirably adapted for tools that are to be used where they are exposed to heat, friction, or heavy blows, for it is possessed of greater hardness and tenacity than other steel, and, therefore, has greater powers of resistance; and when used for edged tools its powers of resistance and durability are wonderful. Being of a closer grain, finer texture, and greater tenacity, it is of the utmost value for many purposes. I therefore propose to manufacture all such tools and other articles for which this metal is specially adapted directly from it, when the said treatment is completed, and before the metal has cooled, by casting in metal molds of special forms and shapes for the different tools, such as hammers of all kinds, pick-axes, drills, stone-picks, and the like.
Having thus described my invention, 1 claim as new and desire to secure by Letters Patent- 1. The process herein described of fusing and refining metal and decarbonizing iron.
2. The process herein described for converting iron into carbonized steel.
3. The converting of iron into unannealable steel, by the use of the foregoing articles, in the manner and for the purposes herein set forth, and the general combination of the principles and the use of the articles, combined and separately, and the use of the oil alone, in the manner and for the purposes set forth in the foregoing specifications.
4. The manufacture of unannealable-steel
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