Classifications

• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
• • C—CHEMISTRY; METALLURGY
  • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
  • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
  • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
  • C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
• • C—CHEMISTRY; METALLURGY
  • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
  • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
  • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
  • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
  • C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
  • C04B41/48—Macromolecular compounds
  • C04B41/4857—Other macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
• • C—CHEMISTRY; METALLURGY
  • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
  • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
  • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
  • C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
  • C04B41/61—Coating or impregnation
  • C04B41/62—Coating or impregnation with organic materials
  • C04B41/63—Macromolecular compounds
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
  • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
  • C08F222/10—Esters
  • C08F222/12—Esters of phenols or saturated alcohols
  • C08F222/14—Esters having no free carboxylic acid groups, e.g. dialkyl maleates or fumarates
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
  • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
  • C09D5/002—Priming paints

Definitions

• the present invention relates to a curable resin composition. More specifically, the present invention relates to a composition comprising methylene malonate functional reactive resin, to its preparation methods, and to the use of the composition in the construction field.
• Construction coatings are widely used in applications including but not limited to flooring in industrial and commercial buildings, anchoring in tunnels and mines, consolidating rocks, slags and coals in tunnels and mines, and waterproofing in roof, basement, balconies, bridge, dams, river locks, dykes, marine cargo ports, docks, parking lots, pools, sewage, tunnels, mines as well as subway and railway tracks.
• Substrates for construction coating such as concrete or stone, normally have porous surfaces where the tiny holes preserve air and enable a permeability of moisture, certain chemicals and coats. Therefore, a primer is required before applying the next layer of coats and it is even more significant for thick coats like self-leveling.
• the primer is a thin layer of coating that well adheres to the porous surfaces and further penetrates the substrates to seal the surfaces of the substrates. The tiny holes are filled by the primer and the preserved air is released into the atmosphere. Thus, defects like bubbles or holes are avoided in coats and moreover, the primer forms a barrier between the substrates and moisture, certain chemicals as well as the coats.
• the substrates are protected by the primer since the moisture and certain chemicals cause deterioration. And in the other hand, the substrates hardly absorb the coats and hence no waste occurs.
• An object of this invention is to provide a composition which does not have the above deficiencies in the prior art.
• an object of this invention is to provide a novel composition, wherein the methylene malonate monomer and the polymer thereof are mixed in a certain ratio.
• Such composition can be anionic polymerized with intrinsically basic substrates, e.g. concrete and basic stone surface, and is excellent in curability and forms a cured product excellent in adhesion, acid/alkaline resistance, solvent resistance and the like.
• the resulting cured product is substantially a 100% solid compound with little volatile organic compounds (VOC).
• the curable resin composition of the present invention can be effectively used as coating in the construction applications, for example, for flooring, waterproofing, wall paint and underground construction applications.
• R 1 and R 2 are in each case independently selected from the group consisting of C1-C30-alkyl, C2-C30-alkenyl, C3-C30-cyclolalkyl, C2-C30-heterocyclyl, C2-C30-heterocyclyl-C1-C30-alkyl, C6-C30-aryl, C6-C30-aryl-C1-C30-alkyl, C2-C30-heteroaryl, C2-C30-heteroaryl-C1-C30-alkyl, C1-C30-alkoxy-C1-C30-alkyl, halo-C1-C30-alkyl, and halo-C3-C30-cyclolalkyl, each of which radicals is optionally substituted, the heteroatom being selected from N, O and S; (B) at least one methylene malonate polymer having formula (II):
• the acidic stabilizer (C) is in an amount of from 0.1 to 1000 ppm, preferably from 0.1 to 500 ppm and more preferably from 0.1 to 200 ppm, in each case based on the total weight of the monomer (A) and the polymer (B).
• composition is prepared by a process comprising steps of:
• composition according to present invention can be formulated without extra catalysts/initiators to be applied on concrete surface or stone surface, which can undergo fast curing.
• the cured products seal porous surface very well and their adhesion onto the surface is very good. They also show excellent mechanical performance and are resistant to solvents, acid, alkaline conditions.
• the invention relates to the use of the composition according to the invention as a coating material.
• the articles “a” and “an” refer to one or to more than one (i.e., to at least one) of the grammatical object of the article.
• an element means one element or more than one element.
• methylene malonate refers to a compound having the core formula —O—C(O)—C( ⁇ CH 2 )—C(O)—O—.
• two-component refers to a composition comprising two components, each of which may also be a mixture of several compounds. The two components can be blended together if needed. And the two components may also be two independent packages that can be mixed on the spot for applications.
• RH is equal to “Relative Humidity” and refers to the ratio of the partial vapor pressure of water to the saturated vapor pressure of water at a given temperature.
• the term “substantial absence” as in “substantial absence of the solvent” refers to a reaction mixture which comprises less than 1% by weight of the particular component as compared to the total reaction mixture. In certain embodiments, the “substantial absence” refers to less than 0.7%, less than 0.5%, less than 0.4%, less than 0.3%, less than 0.2% or less than 0.1% by weight of the particular component as compared to the total reaction mixture. In certain other embodiments, the “substantial absence” refers to less than 1.0%, less than 0.7%, less than 0.5%, less than 0.4%, less than 0.3%, less than 0.2% or less than 0.1% by volume of the particular component as compared to the total reaction mixture.
• the term “stabilized,” e.g., in the context of “stabilized” monomers of the invention or compositions comprising the same, refers to the tendency of the monomers of the invention (or their compositions) to substantially not polymerize with time, to substantially not harden, form a gel, thicken, or otherwise increase in viscosity with time, and/or to substantially show minimal loss in cure speed (i.e., cure speed is maintained) with time as compared to similar compositions that are not stabilized.
• shelf-life e.g., as in the context of the compositions of the invention having an improved “shelf-life,” refers to the compositions of the invention which are stabilized for a given period of time, e.g., 1 month, 6 months, or even 1 year or more.
• additives refers to additives included in a formulated system to enhance physical or chemical properties thereof and to provide a desired result.
• additives include, but are not limited to, dyes, pigments, toughening agents, impact modifiers, rheology modifiers, plasticizing agents, thixotropic agents, natural or synthetic rubbers, filler agents, reinforcing agents, thickening agents, opaciffers, inhibitors, fluorescence or other markers, thermal degradation reducers, thermal resistance conferring agents, surfactants, wetting agents, defoaming agents, dispersants, flow or slip aids, biocides, and stabilizers.
• base refers to a component having at least one electronegative group capable of initiating anionic polymerization.
• base precursor refers to a component that may be converted to a base upon being acted upon in some manner, e.g., application of heat, chemical reaction, or UV activation.
• base enhancer refers to an agent that is capable of acting in some manner to improve or enhance the basicity of an agent.
• halogen atom As used herein, the term “halogen atom”, “halogen”, “halo-” or “Hal-” is to be understood as meaning a fluorine, chlorine, bromine or iodine atom.
• alkyl is understood as meaning a radical of a saturated aliphatic hydrocarbon group and may be branched or unbranched, for example methyl, ethyl, propyl, butyl, isobutyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl or dodecyl, or an isomer thereof.
• alkenyl either on its own or else in combination with further terms, for example haloalkenyl, is understood as meaning a straight-chain or branched radical which has at least one double bond, for example vinyl, allyl, propenyl, butenyl, butadienyl, pentenyl, pentadienyl, hexenyl, or hexadienyl, or an isomer thereof.
• alkynyl either on its own or else in combination with further terms, for example haloalkynyl, is understood as meaning a straight-chain or branched radical which has at least one triple bond, for example ethynyl, propynyl, or propargyl, or an isomer thereof.
• cycloalkyl either on its own or else in combination with further terms, is understood as meaning a fused or non-fused, saturated, monocyclic or polycyclic hydrocarbon ring, for example cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, or cyclooctyl, or an isomer thereof.
• alkoxy is understood as meaning linear or branched, saturated, group having a formula —O-alkyl, in which the term “alkyl” is as defined above, for example methoxy, ethoxy, propoxy, butoxy, pentoxy, or hexoxy, or an isomer thereof.
• aryl either on its own or else in combination with further terms, for example arylalkyl, is understood to include fused or non-fused aryl, such as phenyl or naphthyl, wherein phenyl is optionally substituted by 1 to 5 groups, and naphtyl is optionally substituted by 1 to 7 groups.
• hetero- is understood as meaning a saturated or unsaturated radical which is interrupted by at least one heteroatom selected from the group consisting of oxygen (O), nitrogen (N), and sulphur (S).
• A- to B-hetero- for example “3- to 6-hetero-”, is understood as meaning a fused or non-fused, saturated or unsaturated monocyclic or polycyclic radical comprising, in addition to carbon atom, at least one heteroatom selected from the group consisting of oxygen (O), nitrogen (N), and sulphur (S), provided that the sum of the number of carbon atom and the number of heteroatom is within the range of A to B.
• the hetero groups according to this invention are preferably 5- to 30-hetero groups, most preferably 6- to 18-hetero groups, especially 6- to 12-hetero groups, and particularly 6- to 8-hetero groups.
• heterocyclyl is understood as including aliphatic or aromatic heterocyclyl, for example heterocyclylalkyl or heterocyclylalkenyl.
• substituted means that one or more hydrogens on the designated atom is replaced with a selection from the indicated group, provided that the designated atom's normal valency under the existing circumstances is not exceeded, and that the substitution results in a stable compound. Combinations of substituents and/or variables are permissible only if such combinations result in stable compounds.
• optionally substituted means optional substitution with the specified groups, radicals or moieties. Unless stated otherwise, optionally substituted radicals may be mono- or polysubstituted, where the substituents in the case of polysubstitution may be the same or different.
• halogen-substituted radicals for example haloalkyl
• haloalkyl are mono- or polyhalogenated, up to the maximum number of possible substituents.
• the halogen atoms can be identical or different.
• halogen is fluorine, chlorine, bromine or iodine.
• the groups with suffix “-ene” represent the groups have two covalent bond which could be linked to other radicals, for example —CH 2 CH(CH 3 )CH 2 — (isobutylene),
• the covalent bond may be located in ortho-, meta-, or para-position.
• radical definitions or elucidations given above in general terms or within areas of preference apply to the end products and correspondingly to the starting materials and intermediates. These radical definitions can be combined with one another as desired, i.e. including combinations between the general definition and/or the respective ranges of preference and/or the embodiments.
• the temperature refers to room temperature and the pressure refers to ambient pressure.
• the solvent refers to all organic and inorganic solvents known to the persons skilled in the art and does not include any type of monomer molecular.
• the invention provides a composition comprising,
• R 1 and R 2 are in each case independently selected from the group consisting of C1-C30-alkyl, C2-C30-alkenyl, C3-C30-cyclolalkyl, C2-C30-heterocyclyl, C2-C30-heterocyclyl-(C1-C30-alkyl), C6-C30-aryl, C6-C30-aryl-C1-C30-alkyl, C2-C30-heteroaryl, C2-C30-heteroaryl-C1-C30-alkyl, and C1-C30-alkoxy-C1-C30-alkyl, halo-C1-C30-alkyl, and halo-C3-C30-cyclolalkyl, each of which radicals is optionally substituted, the heteroatom being selected from N, O and S; (B) at least one methylene malonate polymer having formula (II)
• the acidic stabilizer (C) is in an amount of from 0.1 to 1000 ppm, preferably from 0.1 to 500 ppm and more preferably from 0.1 to 200 ppm, in each case based on the total weight of the monomer (A) and the polymer (B).
• R 1 and R 2 are in each case independently selected from the group consisting of C1-C10-alkyl, C2-C10-alkenyl, C3-C10-cyclolalkyl, C2-C10-hetercyclyl, C2-C10-hetercyclyl-C1-C10-alkyl, C3-C18-aryl, C3-C18-aryl-C1-C10-alkyl, C2-C10-heteroaryl, C2-C10-heteroaryl-C1-C10-alkyl, and C1-C10-alkoxy-C1-C10-alkyl, halo-C1-C10-alkyl, and halo-C3-C10-cyclolalkyl; each of which radicals is optionally substituted, the heteroatom being selected from N, O and S.
• R 1 and R 2 are in each case independently selected from the group consisting of C1-C6-alkyl, C2-C6-alkenyl, C3-C6-cyclolalkyl, C3-C6-hetercyclyl, C3-C6-hetercyclyl-C1-C6-alkyl, C6-C8-aryl, C6-C8-aryl-C1-C6-alkyl, C3-C6-heteroaryl, C3-C6-heteroaryl-C1-C6-alkyl, C1-C6-alkoxy-C1-C6-alkyl, halo-C1-C10-alkyl, and halo-C3-C10-cyclolalkyl; each of which radicals is optionally substituted, the heteroatom being selected from N, O and S;
• R 1 and R 2 are in each case independently selected from the group consisting of C1-C6-alkyl, for example methyl, ethyl, n- or isopropyl, n-, iso-, tert- or 2-butyl, pentyls such as n-pentyl and isopentyl, hexyls such as n-hexyl, isohexyl and 1,3-dimethylbutyl;
• R 1 and R 2 are in each case independently selected from the group consisting of C1-C6-alkyl, for example methyl, ethyl, n-propyl, n-butyl, n-pentyl, n-hexyl.
• R 3 and R 4 are in each case independently selected from the group consisting of C1-C10-alkyl, C2-C10-alkenyl, C3-C10-cyclolalkyl, C2-C10-hetercyclyl, C2-C10-hetercyclyl-C1-C10-alkyl, C3-C18-aryl, C3-C18-aryl-C1-C10-alkyl, C2-C10-heteroaryl, C2-C10-heteroaryl-C1-C10-alkyl, and C1-C10-alkoxy-C1-C10-alkyl, halo-C1-C10-alkyl, and halo-C3-C10-cyclolalkyl; each of which radicals are optionally substituted, the heteroatom being selected from N, O and S.
• R 3 and R 4 are in each case independently selected from the group consisting of C1-C6-alkyl, C2-C6-alkenyl, C3-C6-cyclolalkyl, C3-C6-hetercyclyl, C3-C6-hetercyclyl-C1-C6-alkyl, C6-C8-aryl, C6-C8-aryl-C1-C6-alkyl, C3-C6-heteroaryl, C3-C6-heteroaryl-C1-C6-alkyl, C1-C6-alkoxy-C1-C6-alkyl, halo-C1-C10-alkyl, and halo-C3-C10-cyclolalkyl; each of which radicals are optionally substituted, the heteroatom being selected from N, O and S.
• R 3 and R 4 are in each case independently selected from the group consisting of C1-C6-alkyl, for example methyl, ethyl, n- or isopropyl, n-, iso-, tert- or 2-butyl, pentyls such as n-pentyl and isopentyl, hexyls such as n-hexyl, isohexyl and 1,3-dimethylbutyl.
• C1-C6-alkyl for example methyl, ethyl, n- or isopropyl, n-, iso-, tert- or 2-butyl, pentyls such as n-pentyl and isopentyl, hexyls such as n-hexyl, isohexyl and 1,3-dimethylbutyl.
• R 3 and R 4 are in each case independently selected from the group consisting of C1-C6-alkyl, for example methyl, ethyl, n-propyl, n-butyl, n-pentyl, n-hexyl.
• R 1 , R 2 , R 3 and R 4 are the same.
• n is an integer from 1 to 15, more preferably from 1 to 10, much more preferably from 1 to 8, most preferably from 2 to 8 and especially from 3 to 6.
• the radicals are further substituted by substituents.
• substituents are selected from the group consisting of halogen, hydroxyl, nitro, cyano, C1-C10-alkyl, C2-C10-alkenyl, C2-C10-alkynyl, C1-C10-alkoxy, C3-C10-cyclolalkyl, C2-C10-hetercyclyl, C2-C10-hetercyclyl-C1-C10-alkyl, halo-C1-C10-alkyl, halo-C3-C10-cyclolalkyl, C3-C18-aryl, C3-C18-aryl-C1-C10-alkyl, C2-C10-heteroaryl, C3-C10-cyclolalkenyl, and C3-C10-cyclolalkynyl, the heteroatom being selected from N, O and S.
• the substituents are selected from the group consisting of halogen, hydroxyl, nitro, cyano, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C6-alkoxy, C3-C6-cyclolalkyl, C3-C6-hetercyclyl, C3-C6-hetercyclyl-C1-C6-alkyl, halo-C1-C6-alkyl, halo-C3-C6-cyclolalkyl, C6-C8-aryl, C6-C8-aryl-C1-C6-alkyl, C3-C6-heteroaryl, C3-C6-cyclolalkenyl, and C3-C6-cyclolalkynyl, the heteroatom being selected from N, O and S.
• compositions of the invention shall include one or more compounds to extend the shelf-life.
• the compositions are formulated such that the composition is stable for at least 6 months and preferably, is stable for at least one year.
• Said compounds comprise acidic stabilizer.
• the acidic stabilizer is preferably one or more selected from sulfuric acid (H 2 SO 4 ), trifluoromethane sulfonic acid (TFA), chlorodifluoro acid, maleic acid, methane sulfonic acid (MSA), p-toluenesulfonic acid (p-TSA), difluoro acetic acid, trichloroacetic acid, phosphoric acid, dichloroacetic acid.
• Such acidic stabilizers have a pKa value in the range of, for example, between about ⁇ 15 to about 5, or between about ⁇ 15 to about 3, or between about ⁇ 15 to about 1, or between about ⁇ 2 to about 2, or between about 2 to about 5, or between about 3 to about 5.
• the acidic stabilizer is in an amount of from 0.1 to 500 ppm, preferably from 0.1 to 300 ppm and more preferably from 0.1 to 200 ppm, based on the total weight of the component (A) and component (B).
• the composition is substantial absence of any solvent.
• the composition further comprises additives.
• the additive is at least one selected from plasticizers, thixotropic agents, adhesion promoters, antioxidants, light stabilizers, UV stabilizer, filler, cement, lime stone, surfactant, wetting agents, viscosity modifier, extenders, dispersants, anti-blocking agents, air release agents, anti-sagging agents, anti-setting agents, matting agents, flattening agents, waxes, anti-mar additives, anti-scratch additives, defoaming agent coloring agent, fiber, polymer powder, mesh, chip, hollow spheres and inert resins.
• the additives is at least one selected from plasticizers, thixotropic agents, adhesion promoters, antioxidants, light stabilizers, UV stabilizer, filler, surfactant, wetting agents, viscosity modifier, dispersants, air release agents, anti-sagging agents, anti-setting agents, defoaming agent, coloring agent, fiber, polymer powder, mesh, chip, hollow spheres and inert resins.
• the additive is at least selected from plasticizers, thixotropic agents, adhesion promoters, antioxidants, light stabilizers, UV stabilizer, filler, cement, lime stone, surfactant, wetting agents, viscosity modifier, dispersants, air release agents, anti-sagging agents, anti-setting agents, defoaming agent, coloring agent, fiber, polymer powder, mesh, chip, hollow spheres and inert resins
• composition according to the invention is obtained by a process comprising steps of mixing the monomer (A), the polymer (B) and the acidic stabilizer (C).
• the mixing used in the method is carried out by conventional means in the art in a unit suitable for mixing, for example, by stirring or agitating at a room temperature.
• the process for preparing the composition according to the invention comprises a) mixing the monomer (A) and the polymer (B) in amounts as described in the above; b) adding the acidic stabilizer (C) into the mixture obtained from step (a).
• the monomer (A) having formula (I) could be prepared by those skilled in the art by means of the following steps: (a) reacting a malonic acid ester with a source of formaldehyde, optionally in the presence of an acidic or basic alkali accelerator, and optionally in the presence of an acidic or non-acidic solvent, to form a reaction complex; (b) contacting the reaction complex or a portion thereof with an energy transfer means to produce a vapor phase comprising methylene malonates monomer; and (c) isolating the methylene malonates monomer from the vapor phase.
• the polymer (B) having formula (II) could be prepared by those skilled in the art by means of the following steps: An appropriate amount of starting material (e.g., DEMM) and an appropriate amount of OH-containing linking group (e.g., diol) are mixed and reacted in the presence of a catalyst (e.g., Novazym 435), and the resulting mixture is stirred and heated for a period of time at a certain temperature, while the alcohol generated was removed by evaporation. Subsequently, the reaction mixture is cooled and stabilized with a minor amount of acid stabilizer, and then filtered to obtain the crude residue, which is further purified on column chromatography to obtain the desired product.
• a catalyst e.g., Novazym 435
• the invention relates to the use of the composition according to the invention as a coating for flooring, waterproofing, wall paint and underground construction applications applied on alkali substrates.
• a mixture comprising monomer (A) and polymer (B), mixed with the acidic stabilizer (C) and additives such as filler and UV stabilizer, applied on the substrate and, after a while, to obtain a substantially 100% solid product.
• coating is carried out in a way known to those skilled in the art, for example by brushing, spraying, or roll coating. It is noted that the way of coating used in the present invention depends on the workability of the composition, particularly, long gel time is needed for roller coating, whereas short gel time is needed for spray coating.
• the alkali substrates comprise concrete, alkali stone, alkali mineral powder, metals.
• alkali stone include limestone, andesite, basalt etc.
• composition or the mixture is applied on wet substrates.
• the temperature for the use is from ⁇ 30° C. to 60° C., preferably from ⁇ 20° C. to 40° C.
• the relative humidity for the use is from 1% to 99%, preferably from 5% to 95%.
• the 1 st embodiment is a composition comprising
• R 1 and R 2 are in each case independently selected from the group consisting of C1-C30-alkyl, C2-C30-alkenyl and C3-C30-cyclolalkyl; (B) at least one methylene malonate polymer having formula (II):
• the 2 nd embodiment is a composition comprising
• R 1 and R 2 are in each case independently selected from the group consisting of C1-C30-alkyl, C2-C30-alkenyl and C3-C30-cyclolalkyl; (B) at least one methylene malonate polymer having formula (II):
• TFA trifluoromethane s
• the 3 rd embodiment is a composition comprising (A) at least one methylene malonate monomer having formula (I):
• R 1 and R 2 are in each case independently selected from the group consisting of C1-C30-alkyl, C2-C30-alkenyl and C3-C30-cyclolalkyl; (B) at least one methylene malonate polymer having formula (II):
• the 4 th embodiment is a composition comprising
• R 1 and R 2 are in each case independently selected from the group consisting of C1-C30-alkyl, C2-C30-alkenyl and C3-C30-cyclolalkyl; (B) at least one methylene malonate polymer having formula (II):
• the 5 th embodiment is a composition comprising
• R 1 and R 2 are in each case independently selected from the group consisting of C1-C30-alkyl, C2-C30-alkenyl and C3-C30-cyclolalkyl; (B) at least one methylene malonate polymer having formula (II):
• the 6 th embodiment is a composition comprising
• R 1 and R 2 are in each case independently selected from the group consisting of C1-C30-alkyl, C2-C30-alkenyl and C3-C30-cyclolalkyl; (B) at least one methylene malonate polymer having formula (II):
• the 7 th embodiment is a composition comprising
• R 1 and R 2 are in each case independently selected from the group consisting of C1-C30-alkyl, C2-C30-alkenyl and C3-C30-cyclolalkyl; (B) at least one methylene malonate polymer having formula (II):
• the 8 th embodiment is a composition comprising
• R 1 and R 2 are in each case independently selected from the group of C1-C30-alkyl; (B) at least one methylene malonate polymer having formula (II):
• the 9 th embodiment is a composition comprising
• R 1 and R 2 are in each case independently selected from the group consisting of C1-C30-alkyl, C2-C30-alkenyl, C3-C30-cycloalkyl, C6-C30-aryl, halo-C1-C30-alkyl; (B) at least one methylene malonate polymer having formula (II):
• the 10 th embodiment is a composition comprising
• R 1 and R 2 are in each case independently selected from the group consisting of C1-C30-alkyl, C2-C30-alkenyl, C3-C30-cycloalkyl, C6-C30-aryl, halo-C1-C30-alkyl; (B) at least one methylene malonate polymer having formula (II):
• the 11 th embodiment is a composition comprising
• R 1 and R 2 are in each case independently selected from the group of C1-C30-alkyl; (B) at least one methylene malonate polymer having formula (II):
• the 12 th embodiment is a composition comprising
• R 1 and R 2 are in each case independently selected from the group of C1-C30-alkyl; (B) at least one methylene malonate polymer having formula (II):
• the 13 th embodiment is a composition comprising
• R 1 and R 2 are in each case independently selected from the group of C1-C30-alkyl; (B) at least one methylene malonate polymer having formula (II):
• the 14 th embodiment is a composition comprising
• R 1 and R 2 are in each case independently selected from the group consisting of C1-C30-alkyl, C2-C30-alkenyl, C3-C30-cycloalkyl, C6-C30-aryl, halo-C1-C30-alkyl; (B) at least one methylene malonate polymer having formula (II):
• the 15 th embodiment is a composition comprising
• R 1 and R 2 are in each case independently selected from the group consisting of C1-C30-alkyl, C2-C30-alkenyl and C3-C30-cyclolalkyl; (B) at least one methylene malonate polymer having formula (II):
• the 16 th embodiment is a composition comprising
• R 1 and R 2 are in each case independently selected from the group consisting of C1-C30-alkyl, C2-C30-alkenyl and C3-C30-cyclolalkyl; (B) at least one methylene malonate polymer having formula (II):
• the 17 th embodiment is a mixture comprising the composition according to any one of embodiments 1-16, which further comprises one or more additives selected from the group consisting of plasticizers, thixotropic agents, adhesion promoters, antioxidants, light stabilizers, UV stabilizer, filler, cement, lime stone, surfactant, wetting agents, viscosity modifier, dispersants, air release agents, anti-sagging agents, anti-setting agents, defoaming agent, coloring agent, fiber, polymer powder, mesh, chip, hollow spheres and inert resins.
• additives selected from the group consisting of plasticizers, thixotropic agents, adhesion promoters, antioxidants, light stabilizers, UV stabilizer, filler, cement, lime stone, surfactant, wetting agents, viscosity modifier, dispersants, air release agents, anti-sagging agents, anti-setting agents, defoaming agent, coloring agent, fiber, polymer powder, mesh, chip, hollow spheres and inert resins.
• the 18 th embodiment is a mixture comprising the composition according to any one of embodiments 1-16, which further comprises one or more additives selected from the group consisting of plasticizers, thixotropic agents, surfactant, UV stabilizer, cement, lime stone and defoaming agent.
• the 19 th embodiment is a mixture comprising the composition according to any one of embodiments 1-16, which further comprises one or more additives selected from the group consisting of antioxidants, light stabilizers, UV stabilizers and fillers.
• the 20 th embodiment is a mixture comprising the composition according to any one of embodiments 1-16, which further comprises one or more additives selected from the group consisting of light stabilizers, pigments, air release agents and defoaming agent.
• the 21 st embodiment is a mixture comprising the composition according to any one of embodiments 1-16, which further comprises other additives selected from the group consisting of UV stabilizers pigments, air release agents and fillers.
• the 22 nd embodiment is a mixture comprising the composition according to any one of embodiments 1-16, which further comprises other additives selected from the group consisting of antioxidants, UV stabilizers, air release agents, defoaming agent and fillers.
• Diethyl malonate (DEM) and Dihexyl malonate (DHM) were purchased from Alfa Aesar.
• Paraformaldehyde, potassium acetate, copper (II) acetate, Novazym 435 as a catalyst were purchased from Acros Organics.
• Trifluoromethane sulfonic acid, 1,5-pentanediol, 2-methylpropane-1,3-diol, 1,4-phenylenedimethanol were purchased from Alfa Aesar.
• Routine one-dimensional NMR spectroscopy was performed on either a 400 MHz Varian® spectrometer or a 400 MHz Bruker® spectrometer. The samples were dissolved in deuterated solvents. Chemical shifts were recorded on the ppm scale and were referenced to the appropriate solvent signals, such as 2.49 ppm for DMSO-d6, 1.93 ppm for CD3CN, 3.30 ppm for CD3OD, 5.32 ppm for CD2012 and 7.26 ppm for CDCl3 for 1H spectra.
• GC-MS was obtained with a Hewlett Packard 5970 mass spectrometer equipped Hewlett Packard 5890 Gas Chromatograph with. The ion source was maintained at 270° C.
• thermos LTO-FT Low Temperature Oxidation-Fourier Transform
• a hybrid instrument consisting of a linear ion trap mass analyzer and Fourier transform ion cyclotron resonance mass analyzer.
• Gel time means the time from the start of the composition until becoming the state of viscous, and it indicates the workability of the composition; particularly, long gel time (for example 20-30 min) is needed for roller coating, whereas short gel time (for example 0.5-5 min) is needed for spray coating.
• Dry through Time means the time from the start of mixing component I and component II to the solid state of the mixture.
• Adhesive bonding is measured according to ASTM D7234-12.
• Solvent resistance is measured according to ASTM D1308-C2. The test period is ten days.
• the pull-off test is to measure the adhesion between coating and concrete. The failure occurs at either coating-substrate or coating-glue interface or glue-dolly interfaces. Failure at the concrete phase indicates the adhesion between coating and concrete substrate is very high.
• the preparation is carried out according to Example 1, except for using dihexyl malonate in step 2. This gives 227 g (yield of 80%, purity of 95%) pure monomer.
• the monomer was stabilized with 60 ppm of sulfuric acid.
• the preparation is carried out according to Example 1, except for using dicyclohexyl malonate in step 2. This gives 224 g (yield of 80%, purity of 95%) pure monomer.
• the monomer was stabilized with 60 ppm of sulfuric acid.
• the monomer (A) and polymer (B) as per table 1 were first placed in a polyethylene vessel with a magnetic stir bar. While stirring, without heating, at 900 rpm, the acidic stabilizer (C) was added into the vessel. The mixture is continuously stirred for an additional 5 minutes. This gives a ready-made composition.
• compositions Components Inventive composition Comparative composition No. 1 2 3 4 5 6 7
• A Monomer DEMM — — — 50 — 80 100 (% by weight) DHMM — 10 37 5 64 2 —
• B Polymer Polymer (B-1) 44 40 28 20 16 8 — (% by weight) Polymer (B-2) 56 50 35 25 20 10 —
• C acid stabilizer MSA 30 36 27 30 25.2 37 20 (ppm) H2SO4 10 — 9 — 8.4 — — TFA — 12 — 9 — 7 10
• inventive compositions 1 and 2 have excellent workability and controlled curing compared to the comparative compositions and epoxy/amine system.
• Example 1 It shows that the composition of Example 1 and Example 2 have good adhesive bonding with concrete.
• Example 1 and Example 2 both have good resistance against common solvents.
• the structures, materials, compositions, and methods described herein are intended to be representative examples of the invention, and it will be understood that the scope of the invention is not limited by the scope of the examples. Those skilled in the art will recognize that the invention is practiced with variations on the disclosed structures, materials, compositions, and methods, and such variations are regarded as within the ambit of the invention. Thus, it is intended that the present invention cover such modifications and variations as come within the scope of the appended claims and their equivalents.

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