US11349143B2 - Fuel cell stack - Google Patents

Fuel cell stack Download PDF

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Publication number
US11349143B2
US11349143B2 US16/747,662 US202016747662A US11349143B2 US 11349143 B2 US11349143 B2 US 11349143B2 US 202016747662 A US202016747662 A US 202016747662A US 11349143 B2 US11349143 B2 US 11349143B2
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United States
Prior art keywords
support bar
power generation
fuel cell
pair
end plates
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US16/747,662
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US20200235418A1 (en
Inventor
Hideharu NAITO
Kosuke Takagi
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Honda Motor Co Ltd
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Honda Motor Co Ltd
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Assigned to HONDA MOTOR CO., LTD. reassignment HONDA MOTOR CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: NAITO, HIDEHARU, TAKAGI, KOSUKE
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465—Details of groupings of fuel cells
    • H01M8/247—Arrangements for tightening a stack, for accommodation of a stack in a tank or for assembling different tanks
    • H01M8/2475—Enclosures, casings or containers of fuel cell stacks
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0247—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the form
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0267—Collectors; Separators, e.g. bipolar separators; Interconnectors having heating or cooling means, e.g. heaters or coolant flow channels
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
    • H01M8/0273—Sealing or supporting means around electrodes, matrices or membranes with sealing or supporting means in the form of a frame
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2457—Grouping of fuel cells, e.g. stacking of fuel cells with both reactants being gaseous or vaporised
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465—Details of groupings of fuel cells
    • H01M8/247—Arrangements for tightening a stack, for accommodation of a stack in a tank or for assembling different tanks
    • H01M8/248—Means for compression of the fuel cell stacks
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
    • H01M2250/20—Fuel cells in motive systems, e.g. vehicle, ship, plane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T90/00—Enabling technologies or technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02T90/40—Application of hydrogen technology to transportation, e.g. using fuel cells

Definitions

  • the present invention relates to a fuel cell stack formed by stacking a plurality of power generation cells together.
  • the fuel cell stack includes a stack body formed by stacking a plurality of power generation cells together for performing power generation partially consuming a fuel gas and an oxygen-containing gas.
  • Each of the power generation cells includes a membrane electrode assembly (MEA) and a pair of separators sandwiching the MEA.
  • the MEA is formed by stacking an anode, an electrolyte membrane, and a cathode together.
  • the separators are bipolar plates.
  • the separator disclosed in Japanese Laid-Open Patent Publication No. 2016-143545 includes tabs which protrude outward, in its outer peripheral portion.
  • the tabs are accommodated in recesses of coupling members (support bars) extending between a pair of end plates.
  • the support bars are joined to of the end plates provided at both ends of the stack body in the stacking direction, respectively, to apply a tightening load to a plurality of power generation cells through the end plates.
  • the present invention has been made in relation to the technique of supporting the stack body formed by stacking the plurality of power generation cells as described above, and an object of the present invention is to provide a fuel cell stack in which it is possible to simplify the support bar to a greater extent.
  • a fuel cell stack includes a stack body including a plurality of power generation cells each having a tab, the tab protruding from an outer marginal portion of each of the power generation cells, a stack case containing the plurality of power generation cells that are stacked together in a stacking direction, and including a pair of end plates provided at both ends of the stack body in the stacking direction, a support bar extending inside the stack case in the stacking direction, and including a recess configured to accommodate the tab, the stack body being held between the pair of end plates in a manner that a tightening load is applied to the stack body, wherein one end of the support bar in the stacking direction is joined to one of the end plates, and another end of the support bar in the stacking direction is supported by another of the end plates.
  • one end of the support bar is joined to one of the end plates, and the other end of the support bar is supported by the end plate.
  • the support bar does not receive the tightening load to the plurality of power generation cells. That is, when the fuel cell stack receives a load, the support bar is engaged with the tabs of the power generation cells to have a dedicated function of suppressing lateral displacement of the separators of the power generation cells.
  • FIG. 1 is an exploded perspective view showing overall structure of a fuel cell stack according to an embodiment of the present invention
  • FIG. 2 is an exploded perspective view showing structure of a fuel cell stack
  • FIG. 3 is a cross sectional view showing the fuel cell stack in a state where the power generation cell and support bars are accommodated in a case body;
  • FIG. 4 is a cross sectional view taken along a line IV-IV in FIG. 3 ;
  • FIG. 5 is a cross sectional view enlarging a portion where one end of the support bar is joined.
  • FIG. 6 is a cross sectional view enlarging a portion where the other end of the support bar is supported.
  • a fuel cell stack 10 includes a plurality of power generation cells 12 as units of fuel cells.
  • the plurality of power generation cells 12 are stacked together in a horizontal direction indicated by an arrow A to form a stack body 14 .
  • the fuel cell stack 10 is mounted in a fuel cell automobile (not shown). It should be noted that, in the state where the stack body 14 is mounted in the fuel cell automobile, the plurality of power generation cells 12 may be stacked together in the gravity direction indicated by an arrow C.
  • the fuel cell stack 10 For the purpose of mounting the stack body 14 in the fuel cell automobile, the fuel cell stack 10 includes a stack case 16 containing the stack body 14 . Further, pipes, auxiliary devices (devices), etc. for a fuel cell system (not shown) including the fuel cell stack 10 are coupled to one end of the stack case 16 .
  • the stack case 16 includes a rectangular cylindrical case body 20 having a storage space 20 a , and a pair of end plates 24 a , 24 b for closing both ends of the case body 20 .
  • the case body 20 is in the form of a one-piece structural object including a ceiling plate, a pair of side plates, and a bottom plate that are formed integrally by extrusion, casting, etc.
  • Open sections 20 b are provided at both ends of the case body 20 in an axial direction indicated by the arrow A.
  • the open sections 20 b are connected to the storage space 20 a .
  • a plurality of body side screw holes 20 c are formed in both end surfaces of the case body 20 around the open sections 20 b .
  • the case body 20 may be formed by joining a ceiling plate, a pair of side plates, and a bottom plate as separate component parts, together.
  • a terminal plate 22 a is provided at one end of the plurality of power generation cells 12 in the stacking direction indicated by the arrow A.
  • An insulator 23 a is disposed outside the terminal plate 22 a .
  • a terminal plate 22 b is provided at the other end of the plurality of power generation cells 12 in the stacking direction.
  • An insulator 23 b is disposed outside the terminal plate 22 b.
  • an end plate 24 a is disposed at one end of the stack body 14 including the terminal plate 22 a and the insulator 23 a in the stacking direction.
  • An end plate 24 b is disposed at the other end of the stack body 14 including the terminal plate 22 b and the insulator 23 b in the stacking direction.
  • a plurality of fastening holes 25 are provided in each of the pair of end plates 24 a , 24 b .
  • the plurality of fastening holes 25 face the plurality of body side screw holes 20 c of the case body 20 .
  • bolts 26 are inserted through the fastening holes 25 , and screwed with the body side screw holes 20 c .
  • the end plates 24 a , 24 b are fixed to the case body 20 .
  • seal members 27 (see FIGS. 4 to 6 ) for preventing leakage of gases are disposed between the case body 20 and the end plates 24 a , 24 b.
  • the stack body 14 is held between the pair of end plates 24 a , 24 b such that a tightening load in the stacking direction indicated by the arrow A is applied from the case body 20 to the stack body 14 through the pair of end plates 24 a , 24 b .
  • adjustment of the tightening load is made by adjusting the thickness of the insulators 23 a , 23 b or determining the layout of shims.
  • the power generation cell 12 of the fuel cell stack 10 includes a resin frame equipped MEA 28 , and a pair of separators 32 , 34 sandwiching the resin frame equipped MEA 28 (hereinafter the two separators 32 , 34 , will also be referred to as “separators 30 ”, collectively).
  • the power generation cell 12 includes a first separator 32 disposed on one surface of the resin frame equipped MEA 28 , and a second separator 34 disposed on the other surface of the resin frame equipped MEA 28 .
  • the resin frame equipped MEA 28 of the power generation cell 12 includes a membrane electrode assembly 28 a (hereafter referred to as the “MEA 28 a ”) and a resin frame member 36 joined to an outer peripheral portion of the MEA 28 a , and provided around the outer peripheral portion of the MEA 28 a .
  • the MEA 28 a includes an electrolyte membrane 38 , a cathode 40 provided on one surface of the electrolyte membrane 38 , and an anode 42 provided on the other surface of the electrolyte membrane 38 .
  • the resin frame member 36 need not necessarily be provided for the MEA 28 a , and the electrolyte membrane 38 may protrude outward without using the resin frame member 36 .
  • a frame shaped film member may be used as the resin frame member 36 .
  • the electrolyte membrane 38 is a solid polymer electrolyte membrane (cation ion exchange membrane) which is a thin membrane of perfluorosulfonic acid containing water.
  • a fluorine based electrolyte may be used as the electrolyte membrane 38 .
  • an HC (hydrocarbon) based electrolyte may be used as the electrolyte membrane 38 .
  • each of the anode 42 and the cathode 40 includes a gas diffusion layer comprising a carbon paper, etc, and an electrode catalyst layer joined to the electrolyte membrane 38 .
  • the electrode catalyst layer is formed by paste containing porous carbon particles and ion exchange component deposited uniformly on the surface of the gas diffusion layer, and platinum alloy supported on the surfaces of the porous carbon particles.
  • the resin frame member 36 is provided around the MEA 28 a to facilitate cost reduction of the electrolyte membrane 38 , and suitably adjust the contact pressure between the MEA 28 a and the first and second separators 32 , 34 to achieve the desired sealing performance.
  • the resin frame member 36 is made of PPS (polyphenylene sulfide), PPA (polyphthalamide), PEN (polyethylene naphthalate), PES (polyethersulfone), LCP (liquid crystal polymer), PVDF (polyvinylidene fluoride), a silicone resin, a fluororesin, m-PPE (modified polyphenylene ether) resin, PET (polyethylene terephthalate), PBT (polybutylene terephthalate), or modified polyolefin.
  • PPS polyphenylene sulfide
  • PPA polyphthalamide
  • PEN polyethylene naphthalate
  • PES polyethersulfone
  • LCP liquid crystal polymer
  • PVDF poly
  • the first separator 32 includes an oxygen-containing gas flow field 44 on a surface 32 a facing the cathode 40 of the resin frame equipped MEA 28 , for allowing an oxygen-containing gas as one of reactant gases to flow along the oxygen-containing gas flow field 44 .
  • the oxygen-containing gas flow field 44 comprises straight flow grooves or wavy flow grooves formed between a plurality of ridges 44 a extending along the first separator 32 in the direction indicated by the arrow B.
  • the second separator 34 includes a fuel gas flow field 46 on its surface 34 a facing the anode 42 of the resin frame equipped MEA 28 , for allowing a fuel gas as the other of the reactant gases to flow along the fuel gas flow field 46 (in FIG. 2 , for convenience, the flow direction of the fuel gas is shown on the anode 42 of the MEA 28 a ).
  • the fuel gas flow field 46 includes a plurality of straight flow grooves or wavy flow grooves formed between a plurality of ridges 46 a extending along the second separator 34 in the direction indicated by the arrow B.
  • a coolant flow field 48 is provided between a surface 32 b of the first separator 32 and a surface 34 b of the second separator 34 , for allowing a coolant (e.g., water) to flow along the coolant flow field 48 .
  • a coolant e.g., water
  • the coolant flow field 48 is formed between the back surface of the oxygen-containing gas flow field 44 of the first separator 32 and the and the back surface of the fuel gas flow field 46 of the second separator 34 .
  • an oxygen-containing gas supply passage 50 a At one end of the first and second separator 32 , 34 , and the resin frame member 36 in the longitudinal direction (indicated by the arrow B), an oxygen-containing gas supply passage 50 a , a coolant supply passage 52 a , and a fuel gas discharge passage 54 b are provided, respectively.
  • the oxygen-containing gas supply passage 50 a , the coolant supply passage 52 a , and the fuel gas discharge passage 54 b extend through the first and second separators 32 , 34 and the resin frame member 36 in the stacking direction indicated by the arrow A.
  • the oxygen-containing gas supply passage 50 a , the coolant supply passage 52 a and the fuel gas discharge passage 54 b are arranged in the lateral direction indicated by the arrow C.
  • the oxygen-containing gas is supplied through the oxygen-containing gas supply passage 50 a to the oxygen-containing gas flow field 44 .
  • the coolant is supplied through the coolant supply passage 52 a to the coolant flow field 48 .
  • the fuel gas is discharged from the fuel gas flow field 46 through the fuel gas discharge passage 54 b.
  • a fuel gas supply passage 54 a At the other end of the first and second separators 32 , 34 and the resin frame member 36 in the longitudinal direction indicated by the arrow B, a fuel gas supply passage 54 a , a coolant discharge passage 52 b , and an oxygen-containing gas discharge passage 50 b are provided.
  • the fuel gas supply passage 54 a , the coolant discharge passage 52 b , and the oxygen-containing gas discharge passage 50 b extend through the first and second separators 32 , 34 and the resin frame member 36 in the stacking direction.
  • the fuel gas supply passage 54 a , the coolant discharge passage 52 b , and the oxygen-containing gas discharge passage 50 b are arranged in the lateral direction indicated by the arrow C.
  • the fuel gas is supplied to the fuel gas flow field 46 through the fuel gas supply passage 54 a .
  • the coolant is discharged from the coolant flow field 48 through the coolant discharge passage 52 b .
  • the oxygen-containing gas is discharged from the oxygen-containing gas flow field 44 through the oxygen-containing gas discharge passage 50 b.
  • the oxygen-containing gas supply passage 50 a , the oxygen-containing gas discharge passage 50 b , the fuel gas supply passage 54 a , the fuel gas discharge passage 54 b , the coolant supply passage 52 a , and the coolant discharge passage 52 b penetrate through the structure part (the terminal plate 22 a , the insulator 23 a , the end plate 24 a ) at one end of the stack body 14 in the stacking direction, and are connected to pipes (not shown) connected to the end plate 24 a .
  • the layout and the shape of the oxygen-containing gas supply passage 50 a , the oxygen-containing gas discharge passage 50 b , the fuel gas supply passage 54 a , the fuel gas discharge passage 54 b , the coolant supply passage 52 a , and the coolant discharge passage 52 b are not limited to the illustrated embodiment, and may be changed as necessary depending on the required specification of the fuel cell stack 10 .
  • a first bead 56 is formed on the surface 32 a of the first separator 32 by press forming.
  • the first bead 56 protrudes toward the resin frame equipped MEA 28 , and contacts the resin frame member 36 to form a seal (bead seal).
  • the first bead 56 is formed around the oxygen-containing gas flow field 44 , and surrounds the fuel gas supply passage 54 a , the fuel gas discharge passage 54 b , the coolant supply passage 52 a , and the coolant discharge passage 52 b , respectively, to prevent flow of the fuel gas and/or the coolant into the oxygen-containing gas flow field 44 .
  • a second bead 58 is formed on the surface 34 a of the second separator 34 by press forming.
  • the second bead 58 protrudes toward the resin frame equipped MEA 28 , and contacts the resin frame member 36 to form a seal (bead seal).
  • the second bead 58 is formed around the fuel gas flow field 46 , and surrounds the oxygen-containing gas supply passage 50 a , the oxygen-containing gas discharge passage 50 b , the coolant supply passage 52 a , and the coolant discharge passage 52 b , respectively, to prevent flow of the oxygen-containing gas and/or the coolant into the fuel gas flow field 46 .
  • Each of the separators 30 is an electrically conductive metal separator formed by press forming of, e.g., a steel plate, a stainless steel plate, an aluminum plate, a plated steel plate, or a metal thin plate having an anti-corrosive surface by surface treatment to have a corrugated shape in cross section.
  • a steel plate e.g., a steel plate, a stainless steel plate, an aluminum plate, a plated steel plate, or a metal thin plate having an anti-corrosive surface by surface treatment to have a corrugated shape in cross section.
  • carbon separators made of carbon material or mixed material of carbon and resin may be used as the separators 30 .
  • insulating resin material may be provided in outer marginal portions 33 , 35 of the first and second separators 32 , 34 .
  • the first separator 32 and the second separator 34 are joined together by a joining method such as welding, brazing, crimping, etc. to form a joint separator.
  • a joining method such as welding, brazing, crimping, etc.
  • the joint separators and the resin frame equipped MEAs 28 are stacked together alternately, to form structure of repeating the oxygen-containing gas flow field 44 between the first separator 32 and the resin frame equipped MEA 28 , the fuel gas flow field 46 between the resin frame equipped MEA 28 and the second separator 34 , and the coolant flow field 48 between the first separator 32 and the second separator 34 in this order.
  • a plurality of tabs (protrusion pieces) 60 are provided in the outer marginal portions 33 , 35 of the separators 30 (first and second separators 32 , 34 ) of the power generation cells 12 , respectively.
  • the plurality of tabs 60 are provided on the upper side and the lower side (long sides) of the first and second separators 32 , 34 .
  • the tab 60 on the upper side is provided at a position shifted toward one side from the center in the direction indicated by the arrow B
  • the tab 60 on the lower side is provided at a position shifted toward the other side from the center in the direction indicated by the arrow B. It should be noted that the positions of the tabs 60 in the outer marginal portions 33 , 35 are not limited specially.
  • Each of the tabs 60 includes a support 62 , a load receiver 64 , and a rib 65 .
  • the support 62 has a trapezoidal shape, and the support 62 is formed integrally with the outer marginal portion 33 , 35 of the separator 30 by press forming, in a manner to protrude outward from the outer marginal portion 33 , 35 in the direction indicated by the arrow C).
  • the rib 65 is formed in the support 62 .
  • the rib 65 is part of the separator 30 protruding in the stacking direction, and extending in the width direction of the support 62 (indicated by the arrow B).
  • the load receiver 64 is joined to the support 62 through a joint part 63 .
  • Each of both ends of the load receiver 64 in the width direction has a substantially triangular shape, and has a symmetrical shape about the central line in the width direction (indicated by the arrow B).
  • a positioning hole 66 is formed at the center of the load receiver 64 .
  • a rod (not shown) is inserted into the positioning hole 66 , for positioning the plurality of power generation cells 12 at the time of producing the fuel cell stack 10 .
  • the load receiver 64 comprises a metal thin plate, and the outer portion of the load receiver 64 and the inner circumferential portion of the positioning hole 66 are made of insulating resin material.
  • the resin material of the load receiver 64 has electrically insulating performance, the resin material is not limited specially.
  • polycarbonate, polyphenylene sulfide, polysulfone, fluororesin, or the same material as that used for the insulators 23 a , 23 b may be used.
  • the structure of the tab 60 is not limited specially.
  • the support 62 and the load receiver 64 may be formed integrally with each other.
  • the load receiver 64 may have any shape such as a rectangular shape, a trapezoidal shape, etc.
  • the load receiver 64 is joined to the support 62 by brazing, welding, etc.
  • the tabs 60 of the power generation cells 12 form a tab array 68 arranged on each of an upper surface and a lower surface of the stack body 14 .
  • the fuel cell stack 10 includes support bars 70 each having a recess 76 which can accommodate the tab array 68 (plurality of tabs 60 ).
  • the tabs 60 and the support bar 70 are engaged with each other to form structure of preventing lateral displacement of the separators 30 (first and second separators 32 , 34 ) of each of the power generation cells 12 .
  • the support bar 70 includes a proximal part 72 , and a pair of projections 74 protruding in the same direction from both ends of the proximal part 72 in the width direction. As shown in FIG. 1 , the entire length of the proximal part 72 and the pair of projections 74 is substantially the same as the length of the case body 20 in the direction indicated by the arrow A (stacking direction of the power generation cells 12 ).
  • the material of the support bar 70 is not limited especially as along as the support bar 70 has suitable rigidity which makes it possible to receive the load in the width direction of the tabs 60 . Metal material having rigidity which is lower than that of the conventional coupling member which applies the tightening load to the stack body 14 may be used.
  • metal material such as aluminum, iron may be used as material of the support bar 70 .
  • the support bar 70 may be made of insulating resin material, or formed by covering a metal body with an insulating resin member.
  • the tab 60 may be made of metal material.
  • the recess 76 surrounded by the proximal part 72 and the pair of projections 74 is provided in a part of the support bar 70 facing the stack body 14 .
  • the recess 76 is a laterally elongated groove having an R (rounded) shape at corners of the bottom in a cross sectional view.
  • the recess 76 is formed over the entire length in a direction in which the support bar 70 extends (indicated by the arrow A).
  • each of the tabs 60 is disposed in non-contact with the support bar 70 in the recess 76 . That is, the protruding end of the tab 60 in the direction indicated by the arrow C faces the bottom surface (proximal part 72 ) of the recess 76 through a clearance. Further, when no external load is applied to the fuel cell stack 10 , both sides of the tab 60 in the width direction face the pair of projections 74 of the recess 76 with a minute clearance.
  • the support bar 70 according to the embodiment of the present invention, one end 78 in the stacking direction of the stack body 14 is joined to the end plate 24 a , and another end 80 in the stacking direction of the stack body 14 is supported by the end plate 24 b .
  • the joining structure at the one end 78 of the support bar 70 , and the support structure at the other end 80 of the support bar 70 will be described in detail.
  • the support bar 70 provided under the stack body 14 will be taken as an example, it is a matter of course that the support bar 70 provided above the stack body 14 has the same structure.
  • the one end 78 of the support bar 70 is fastened to the end plate 24 a using a pair of hollow knock pins 82 and a pair of fastening bolts 84 .
  • a pair of joining holes 86 are formed in one end surface 78 a of the one end 78 , for insertion of the hollow knock pins 82 and the fastening bolts 84 into the pair of joining holes 86 .
  • a pair of holes 88 are formed in the end plate 24 a , for insertion of the hollow knock pins 82 and the fastening bolts 84 into the holes 88 .
  • the number of the hollow knock pins 82 and the number of the fastening bolts 84 used herein is not limited specially. Two or more hollow knock pins 82 and two or more fastening bolts 84 may be used. It is adequate that the joining holes 86 and the holes 88 are formed in correspondence with the number of the used hollow knock pins 82 and the number of the used fastening bolts 84 .
  • the hollow knock pin 82 has a cylindrical shape having an internal through hole 82 a .
  • the hollow knock pin 82 is disposed to be inserted into both of the joining hole 86 (knock pin area 86 b ) and the hole 88 (knock pin area 88 a ), and in the state where the support bar 70 and the end plate 24 a are joined together, the hollow knock pin 82 tightly contacts the joining hole 86 and the hole 88 .
  • the inner circumferential surface of the through hole 82 a of the hollow knock pin 82 is formed to have an inner diameter which allows a clearance to be formed between the inner circumferential surface of the hollow knock pin 82 and the outer circumferential surface of the fastening bolt 84 .
  • the fastening bolt 84 includes a male screw portion 84 a at its front end in the insertion direction, and a non-threaded smooth portion 84 b on the proximal end side of the male screw portion 84 a .
  • the length of the smooth portion 84 b is determined to have substantially the same as the length of the hollow knock pin 82 in the axial direction.
  • the proximal end side of the smooth portion 84 b is made up of a flange 84 c and a head 84 d of the fastening bolt 84 .
  • the flange 84 c protrudes outward in the radial direction beyond the outer shape of the hollow knock pin 82 .
  • the joining hole 86 of the support bar 70 includes a female screw area 86 a disposed on the deep side, capable of being screwed with the male screw portion 84 a of the fastening bolt 84 , and the knock pin area 86 b disposed on the one end surface 78 a side where the hollow knock pin 82 is disposed partially.
  • the diameter of the knock pin area 86 b is larger than the diameter of the female screw area 86 a . That is, the joining hole 86 includes a step in the axial direction.
  • the hole 88 of the end plate 24 a includes the knock pin area 88 a formed to have the same inner diameter as the knock pin area 86 b of the joining hole 86 , and a flange space 88 b where the flange 84 c of the fastening bolt 84 is disposed.
  • the diameter of the flange space 88 b is larger than the diameter of the knock pin area 88 a .
  • the hole 88 includes a stepped surface 88 c pressed by the flange 84 c .
  • the joining hole 86 need not necessarily include the flange space 88 b or the stepped surface 88 c , and may be made up of only the knock pin area 88 a , over the entire area in the thickness direction of the end plate 24 a.
  • the joining hole 86 and the hole 88 are holes having substantially the same shape as the outer shape formed by assembling the hollow knock pin 82 and the fastening bolt 84 together (state where the hollow knock pin 82 is positioned on the smooth portion 84 b of the fastening bolt 84 ). Therefore, the one end 78 of the support bar 70 is joined to the end plate 24 a without any clearance.
  • the other end 80 of the support bar 70 is supported by the end plate 24 b using a pair of solid pins 90 .
  • the “support(ing)” herein means that the support bar 70 is supported by the end plate 24 b through the pins 90 which are movable in the axial direction and immovable in the radial direction.
  • the support bar 70 can be in non-contact with the end plate 24 a .
  • a pair of first holes 92 are formed in another end surface 80 a of the other end 80 , for insertion of the pair of pins 90 into the first holes 92 .
  • a pair of second holes 94 are formed in the end plate 24 b , for insertion of the pair of pins 90 into the pair of second holes 94 .
  • the number of the pins 90 herein is not limited specially, as long as at least one pin 90 is used. It is adequate that the first holes 92 and the second holes 94 are formed depending on the number of used pins 90 .
  • the pins 90 may have a hollow shape.
  • the pin 90 has a circular column shape having a length in the axial direction which is shorter than the entire length of the fastening bolt 84 .
  • the outer diameter of the pin 90 is substantially the same as the outer diameter of the hollow knock pin 82 .
  • the inner diameter of the first hole 92 of the support bar 70 and the inner diameter of the second hole 94 of the end plate 24 b are formed such that the support bar 70 and the end plate 24 b tightly contact the outer circumferential surface of the pin 90 .
  • the depth (length in the axial direction) of the first hole 92 and the depth (length in the axial direction) of the second hole 94 are shorter than the length of the pin 90 in the axial direction.
  • the second hole 94 is formed such that the second hole 94 does not penetrate through the outer surface of the end plate 24 b.
  • the first hole 92 and the second hole 94 face each other to form a bag shape (closed space 96 ) into which the pin 90 can be inserted.
  • the length of the closed space 96 formed by combining the first hole 92 and the second hole 94 in the axial direction is longer than the length of the pin 90 in the axial direction. Therefore, in the state where the pin 90 is inserted into the closed space 96 , a clearance 98 is formed in the closed space.
  • the clearance 98 may not be present in the closed space 96 .
  • the second hole 94 may penetrate through the end plate 24 b . In this case, it is adequate that a member which closes the second hole 94 is fitted to the end plate 24 b .
  • a minute (of at least 10 ⁇ m) clearance 100 is formed between the end surface of the other end 80 and the end plate 24 b . That is, the support bar 70 is configured not to apply any tightening load to the stack body 14 .
  • the fuel cell stack 10 according to the embodiment of the present invention basically has the above structure. Next, operation of the fuel cell stack 10 will be described.
  • the case body 20 of the stack case 16 is formed by a production method such as extrusion, casting, etc. Thereafter, the body side screw hole 20 c , etc. for fixing the end plate 24 a and the end plate 24 b are formed in the one end surface and the other end surface of the case body 20 . Further, the end plates 24 a , 24 b , and the support bar 70 are formed by a suitable production method such as casting, forging, machining, etc.
  • the stack body 14 is formed by stacking the resin frame equipped MEA 28 , the joint separators (first and second separators 32 , 34 ) together, and stacking the terminal plates 22 a , 22 b , and the insulators 23 a , 23 b at both ends in the stacking direction. Further, in the state where the plurality of power generation cells 12 are stacked together, the tabs 60 form the tab array 68 . In the state where the tab array 68 is accommodated in the recess 76 , the support bar 70 and the stack body 14 are accommodated in the case body 20 .
  • Assembling of the support bar 70 to the stack case 16 and fixing of the pair of end plates 24 a , 24 b are performed at the same time. Specifically, at one end of the stack case 16 , while the end plate 24 a is fixed to the case body 20 , the one end 78 of the support bar 70 is joined to the end plate 24 a.
  • the hollow knock pins 82 are inserted to the joining holes 86 (knock pin areas 86 b ) of the support bar 70 .
  • One end of each of the pair of hollow knock pins 82 is inserted into the support bar 70 by substantially the half length in the axial direction, and the other end of each of the pair of hollow knock pins 82 is exposed from the support bar 70 .
  • the exposed portions of the pair of hollow knock pins 82 are fitted to the pair of holes 88 of the end plate 24 a . In this manner, the joining holes 86 and the holes 88 are positioned while aligned with each other.
  • the fastening bolts 84 are inserted from the outer surface of the end plate 24 a through the through holes 82 a of the hollow knock pins 82 into the deep side of the hollow knock pins 82 , and the male screw portions 84 a of the fastening bolts 84 are screwed into the female screw areas 86 a of the joining holes 86 .
  • the fastening bolts 84 are inserted through the end plate 24 a , and firmly fastened to the support bar 70 .
  • the end plate 24 b is fixed to the case body 20 , and the other end 80 of the support bar 70 is supported by the end plate 24 b .
  • the pins 90 are inserted into the pair of first holes 92 of the support bar 70 , respectively.
  • One end of each of the pair of pins 90 is inserted into the support bar 70 by substantially the half length in the axial direction, and the other end of each of the pair of pins 90 is exposed from the support bar 70 .
  • the pair of exposed pins 90 are fitted to the second holes 94 of the end plate 24 b . In this manner, the first holes 92 and the second holes 94 are positioned while aligned with each other.
  • the case body 20 and the end plate 24 b are fastened together using the bolts 26 .
  • the thickness of a shim (not shown) provided between the end plate 24 b and the insulator 23 b is adjusted in order to adjust the tightening load applied to the stack body 14 .
  • production of the stack case 16 containing the stack body 14 is finished.
  • the tab 60 of each of the power generation cells 12 is disposed in the recess 76 of the support bar 70 .
  • the tabs 60 are engaged with the recess 76 of the support bar 70 , lateral displacement of the power generation cells 12 is prevented.
  • an oxygen-containing gas is supplied to the oxygen-containing gas supply passage 50 a
  • a fuel gas is supplied to the fuel gas supply passage 54 a
  • a coolant is supplied to the coolant supply passage 52 a through pipes (not shown) coupled to the end plate 24 a to perform power generation.
  • the oxygen-containing gas is supplied from the oxygen-containing gas supply passage 50 a to the oxygen-containing gas flow field 44 of the first separator 32 .
  • the oxygen-containing gas flows along the oxygen-containing gas flow field 44 in the direction indicated by the arrow B, and the oxygen-containing gas is supplied to the cathode 40 of the MEA 28 a.
  • the fuel gas flows from the fuel gas supply passage 54 a into the fuel gas flow field 46 of the second separator 34 .
  • the fuel gas flows along the fuel gas flow field 46 in the direction indicated by the arrow B, and the fuel gas is supplied to the anode 42 of the MEA 28 a.
  • each of the MEAs 28 a power generation is performed by electrochemical reactions of the oxygen-containing gas supplied to the cathode 40 and the fuel gas supplied to the anode 42 .
  • the oxygen-containing gas supplied to the cathode 40 is partially consumed at the cathode 40 , and then, flows from the oxygen-containing gas flow field 44 to the oxygen-containing gas discharge passage 50 b .
  • the oxygen-containing gas is discharged along the oxygen-containing gas discharge passage 50 b .
  • the fuel gas supplied to the anode 42 is partially consumed at the anode 42 , and then, flows from the fuel gas flow field 46 to the fuel gas discharge passage 54 b .
  • the fuel gas is discharged along the fuel gas discharge passage 54 b.
  • the coolant supplied to the coolant supply passage 52 a flows into the coolant flow field 48 formed between the first separator 32 and the second separator 34 , and then, the coolant flows in the direction indicated by the arrow B. After the coolant cools the MEA 28 a , the coolant is discharged from the coolant discharge passage 52 b.
  • the hollow knock pins 82 and the pins 90 are present between border portions between the pair of end plates 24 a , 24 b and the support bar 70 .
  • the hollow knock pins 82 position the end plate 24 a and the support bar 70 in the radial direction.
  • the fastening bolts 84 are inserted into the hollow knock pins 82 to fasten the end plate 24 a and the support bar 70 together.
  • the pins 90 position the end plate 24 b and the support bar 70 in the radial direction, the pins 90 do not transmit the load in the axial direction of the end plate 24 b to the support bar 70 .
  • the fuel cell stack 10 is not limited to the above embodiment.
  • the case body 20 is not limited to the one-piece structure object including the ceiling plate, the pair of side plates, and the bottom plate that are formed integrally.
  • the case body 20 may be formed by joining a plurality of plates together (dividable structure).
  • the one end 78 of the support bar 70 is joined to the end plate 24 a , and the other end 80 of the support bar 70 is supported by the end plate 24 b .
  • the fuel cell stack 10 has structure where the support bar 70 does not apply the tightening load to the stack body 14 . That is, when the fuel cell stack 10 receives a load, the support bar 70 is engaged with the tabs 60 of the power generation cell 12 to have a dedicated function of suppressing lateral displacement of the separators 30 of the power generation cells 12 . Accordingly, the support bar 70 is simplified to a greater extent, and for example, it becomes possible to reduce the rigidity of the support bar 70 to achieve weight reduction.
  • the stack case 16 is formed by fastening the pair of end plates 24 a , 24 b to the rectangular cylindrical case body 20 containing the plurality of power generation cells 12 to apply the tightening load to the plurality of power generation cells 12 disposed between the pair of end plates 24 a , 24 b . Accordingly, the plurality of power generation cells 12 do not receive the tightening load by the support bar 70 , and the tightening load is applied stably to the plurality of power generation cells 12 from the case body 20 fastened by the pair of end plates 24 a , 24 b.
  • the one end 78 of the support bar 70 is joined to the end plate 24 a (one of the end plates 24 a , 24 b ) by the hollow knock pin 82 including the through hole 82 a penetrating through the hollow knock pin 82 in the axial direction, and the fastening bolt 84 penetrating through the through hole 82 a .
  • the structure of joining the end plate 24 a and the support bar 70 is simplified to a greater extent, and it is possible to reduce the number of component parts.
  • the other end 80 of the support bar 70 is supported by the other end plate 24 b (the other of the end plates 24 a , 24 b ) by the pin 90 inserted into both of the support bar 70 and the other end plate 24 b . Accordingly, the support structure of the end plate 24 b and the support bar 70 is simplified to a greater extent, and it is possible to reduce the number of component parts.
  • the support bar 70 includes the first hole 92 into which the pin 90 is inserted, the other end plate 24 b includes the second hole 94 into which the pin 90 is inserted, and the first hole 92 and the second hole 94 form the closed space 96 .
  • the structure it is possible to reliably prevent leakage of gases from the support structure of the end plate 24 b and the support bar 70 .
  • the support bar 70 is provided in each of the pair of opposing sides of the power generation cells 12 having the rectangular shape. In the structure, when the fuel cell stack 10 receives a load, the support bars 70 are brought into engagement with the tabs 60 of the pair of opposing sides of the power generation cells 12 . Therefore, it is possible to prevent lateral displacement of the separators 30 more reliably.
  • the clearance 100 is formed between the end surface of the other end of the support bar 70 and the end plate 24 b (the other of the end plates 24 a , 24 b ). Accordingly, in the fuel cell stack 10 , it is possible to more reliably realize structure where the tightening load is not applied to the stack body 14 through the end plates 24 a , 24 b and the support bar 70 . Accordingly, it is possible to facilitate size reduction of the support bar 70 .

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  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
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JP2019008992A JP6892460B2 (ja) 2019-01-23 2019-01-23 燃料電池スタック
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Publication number Priority date Publication date Assignee Title
CN114079073A (zh) * 2020-08-18 2022-02-22 未势能源科技有限公司 燃料电池
CN113707928B (zh) * 2021-08-10 2023-02-17 一汽解放汽车有限公司 电堆封装模块及燃料电池电堆装置

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102820494A (zh) * 2011-06-09 2012-12-12 索尼公司 电池模块、电子装置、电力存储系统及电力系统
US20150251560A1 (en) * 2014-03-06 2015-09-10 Honda Motor Co., Ltd. Mount structure for fuel cell stack
US20160226092A1 (en) 2015-02-02 2016-08-04 Honda Motor Co., Ltd. Fuel cell stack
JP2017016770A (ja) * 2015-06-29 2017-01-19 本田技研工業株式会社 燃料電池スタック及びその組み立て方法
US20170263968A1 (en) * 2016-03-08 2017-09-14 Honda Motor Co., Ltd. Fuel cell system
US20180366761A1 (en) 2017-06-15 2018-12-20 Honda Motor Co., Ltd. Fuel cell stack

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE602006002154D1 (de) * 2005-04-04 2008-09-25 Honda Motor Co Ltd Motorrad mit Brennstoffzelle
JP5430518B2 (ja) * 2010-08-13 2014-03-05 本田技研工業株式会社 燃料電池スタック
JP5409563B2 (ja) * 2010-09-09 2014-02-05 本田技研工業株式会社 燃料電池スタック
WO2013111669A1 (ja) * 2012-01-26 2013-08-01 本田技研工業株式会社 燃料電池車両
JP2013193724A (ja) * 2012-03-23 2013-09-30 Honda Motor Co Ltd 燃料電池システム
DE102012221407A1 (de) * 2012-11-22 2014-05-22 Elringklinger Ag Endplattenanordnung für eine elektrochemische Vorrichtung
GB2544790A (en) * 2015-11-27 2017-05-31 Intelligent Energy Ltd Connector system for a fuel cell stack
JP6450978B2 (ja) * 2015-12-25 2019-01-16 本田技研工業株式会社 燃料電池スタック
JP6682361B2 (ja) * 2016-05-31 2020-04-15 本田技研工業株式会社 燃料電池スタックの製造方法
JP6330198B2 (ja) * 2016-09-12 2018-05-30 本田技研工業株式会社 燃料電池スタックの製造方法

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102820494A (zh) * 2011-06-09 2012-12-12 索尼公司 电池模块、电子装置、电力存储系统及电力系统
US20150251560A1 (en) * 2014-03-06 2015-09-10 Honda Motor Co., Ltd. Mount structure for fuel cell stack
US20160226092A1 (en) 2015-02-02 2016-08-04 Honda Motor Co., Ltd. Fuel cell stack
JP2016143545A (ja) 2015-02-02 2016-08-08 本田技研工業株式会社 燃料電池スタック
JP2017016770A (ja) * 2015-06-29 2017-01-19 本田技研工業株式会社 燃料電池スタック及びその組み立て方法
US20170263968A1 (en) * 2016-03-08 2017-09-14 Honda Motor Co., Ltd. Fuel cell system
US20180366761A1 (en) 2017-06-15 2018-12-20 Honda Motor Co., Ltd. Fuel cell stack
JP2019003830A (ja) 2017-06-15 2019-01-10 本田技研工業株式会社 燃料電池スタック

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Japanese Office Action for Japanese Patent Application No. 2019-008992 dated Nov. 4, 2020.

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JP2020119720A (ja) 2020-08-06
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JP6892460B2 (ja) 2021-06-23
US20200235418A1 (en) 2020-07-23

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