US1096822A - Process of coating webs of paper with leaf metal. - Google Patents

Process of coating webs of paper with leaf metal. Download PDF

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US1096822A
US1096822A US1913779095A US1096822A US 1096822 A US1096822 A US 1096822A US 1913779095 A US1913779095 A US 1913779095A US 1096822 A US1096822 A US 1096822A
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web
leaf
metal
paper
webs
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Emil Brandt
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    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/02Apparatus or processes for manufacturing printed circuits in which the conductive material is applied to the surface of the insulating support and is thereafter removed from such areas of the surface which are not intended for current conducting or shielding
    • H05K3/022Processes for manufacturing precursors of printed circuits, i.e. copper-clad substrates
    • H05K3/025Processes for manufacturing precursors of printed circuits, i.e. copper-clad substrates by transfer of thin metal foil formed on a temporary carrier, e.g. peel-apart copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17Dry transfer
    • B44C1/1712Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
    • B44C1/1729Hot stamping techniques
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31678Of metal
    • Y10T428/31703Next to cellulosic

Definitions

  • the adhesive used 'must be one which dries quickly, and one which is notI soluble in water, as the eoated paper is used for cigarette ti s. This necessitates the use of resinous a hesives and the like, and with these the eoated paper cannot be given a high polish, because the adhesive is melted by the heat produced by the operation of polishing.
  • a web of cigarette paper receives pieces of leaf metal at intervals from a traveling carrier, which takes a separate path after applyiug the leaf metal, no regulation of pressure being effected or attempted.
  • a traveling carrier which takes a separate path after applyiug the leaf metal, no regulation of pressure being effected or attempted.
  • the object of the present invention is to enable wide and narrow webs of paper to be eoated over their entire surface with leaf metal which 'is applied with regulatable pressure, and to which a high polish can be given if desired.
  • the web to be eoated with leaf metal, and a traveling web carrying the leaf metal are brought to- Speoificaton of Letters Patent.
  • the amount of pressure applicd may be regulated by regulating the period during which the two webs are subjected to the pressure. If the adhesive used is one which dries slowly and is soluble in water, a high polish can be applied to the eoated paper, because such adhesives do not become soft in the course of the polishing process. The leaf metal can be very tirmly attached, and the adhesive is not liable to penetrate through such small holes as sometimes occur in leaf metal.
  • a plurality of leaf metal feed rolls may be used side by side, or one behind the other, each having a separate pressure roll, the several pressure rolls being arranged at the periphery of a larger roll for the web to be eoated.
  • Several strips of leaf metal can thus be placed side by side on a web, slightly overlapping each other to obviate gaps.
  • Figure l is a diagram' illustrating one method of carrying the process into effect.
  • Fg. 2 is a sectional diagram, illustrating an'- other mode of operation, and Fig. 3 is a similar view, illustrating a third mode of operation;
  • Fig. 4 is a mutilated plan view of the leaf metal rolls and webs shown in Fig. 3
  • Fig. 5 is a section of the webs on the line A--B of Fig. 4.
  • Fig. 6 is a sectional diagram illustrating another mode of operation, Fig. 7 being a mutilated plan view of the leaf metal rolls and webs, Fig. 8 a section of the webs on the line C-D of Fig. 7, and Fig. 9 a olan view of one of the webs.
  • the web b thus coated may be fedV to a drying apparatus and thereuponl either wound onto a roller, cut into sheets or otherwise treated, while the web e having transferred the leaf metal, is wound up on the roller b.
  • the adhesive is preferably applied to the Web b beforehand, the web then being dried and rolled.
  • the prepared web, with the dried adhesive thereon, is subsequently, before being coated with metal leaf, unrolled and passed through water, and then rolled up again while wet, so that the adhesive be-A comes active and is distributed in the form of an even film by the pressure applied in rolling.
  • the web itself becomes uniformly saturated with moisture from both sides, so that when used after a few hours it travels smoothly, without creasing, over the roller c.
  • the above described mode of operation requires uniform saturation of the web b with water, in order to obtain Smooth and uniform coating of leaf metal.
  • the quantity of adhesive applied is so regulated that the coated paper has the requisite fiexibility when subsequently passing through the polishing machine.
  • the 'adhesive alone will sutice to completely saturate the paper with mosture.
  • the described saturating process may also be used indepcndently of the above described process of producing metal coated aper.
  • the leaf' metal is not in the form of a continuous strip but consists of a number of leaves arranged one behind the other on the paper backing, or carrier, it may occur that individual leaves become detached from the backing'while passing over the roller, and may slide forward and vbecome crumpled between the rollers, in which condition it is then applied to the paper strip to be coated, a portion of the latter remaining bare.
  • the leaf' metal is not in the form of a continuous strip but consists of a number of leaves arranged one behind the other on the paper backing, or carrier, it may occur that individual leaves become detached from the backing'while passing over the roller, and may slide forward and vbecome crumpled between the rollers, in which condition it is then applied to the paper strip to be coated, a portion of the latter remaining bare.
  • the lweb coated with the adhesive may be drawn with its coated side facing inward over a convexcurved surface, the web or webs carrying the metal leaf being causcd to travel between the said convex surface and the adhesive web, so that theleaf metal is pressed by the stretched webs against the ad esive surface.
  • This arrangement not only obviates 'the above mentioneddisad- Vantage but renders the use of toothed gearing and other transmission gear unnecessary.
  • the movement of all the rollers and the control of this movement are effected solely by the pull of the web of paper coated with the metal leaf.
  • the convex surface is preferably formed by a plurality 'of rollers arranged in' a curve, this Varrangement being better than a single large roller, inasmuch as it prevents the occurrence of creases even when coating wide webs.
  • An arrangement working on this principle is shown diagrammatically in Fig. 2, in which al designates the paper roll, and bl the web drawn therefrom to be coated with leaf metal fl drawn from a roll dl together with a carrier web el of paper or the like.
  • i is a fixed or rotating roller, on the periphery k of which the web of paper bl is brou ht into contact with the leaf metal.
  • the roll al is preferably provided withv a suitable brake device in order to keep the paper and leaf metal webs at the proper tension when passing around the roller h is the roll on which the carrier webel is rewound.
  • the operation is as follows: The draw-ofi' roller Z is rotated and by adhesion moves the Vwet, adhesive web bl, pulling the said web off its roll al.
  • the latter pulls the web el with the leaf metal fl off the roll all at the same ⁇ speed as that at which it travels itself. While the webs are travelingover surface le intimate, smooth and uniform connection of metal with paper -is effected.
  • the blank web el leaves the coated web at n and is wound on the roll k for subsequent use, and the metal coated web is dried by any known drying apparatus, androlled up for further treatment' or use.
  • the web el prevents the metal leaf which it carries from being damaged by thel surface k and also enables very thin and wet paper to be coated, as it takes part of the tension.
  • carrier webs (24, with are of the same width as drawn from rolls dz, da, with leaf metal fz, f3 thereon, the two rolls forming each pair lying coaxially side by side, and the rolls da* being set back, so that the webs can bc made to overlap, as shown at o in Figs. 4 and 5.
  • the carrier webs with the leaf metal meet at m2 the adhesive paper web bz drawn from the roll az, and then travel under the web b2 over the surface 702 of the roller iz, and thence to the roller lz.
  • the carrier web se arates from the coated paper web 62.
  • the curved path k* for a plurality of fixed or rotatable rollers q arranged in an are.
  • the web of paper b* to be coated with metal leaf travels from a roll a* to mi, and then over the rollers g to a roller 14.
  • the several carrier webs travel side by side, their edges practically meeting, and the strips of metal leaf f* are of the same width as the carriers et
  • the strips of metal leaf f5 on the carrier 65 are, however, wider than the said carriers, so that these strips overlap the strips f4, as shown in Figs. 7 and 8.
  • lVhile wound on the rolls (ZE the strips f5 are covered by protective strips 66, which the strips of leaf metal f5 and lie between the latter and the carrier webs 65.
  • the strips e which serve only for protection during packing, transport, Storage etc., are wound up separately, as at h6 and leave the leaf metal exposed for transfer to the web 64.
  • roller l* there is pressure roll fr, weighted or acted on by Springs, so that it bears on the carrier webs.
  • the carthe webs is formed by rier webs e4, 65 are wound up separately to form a roll hi, and the coated web b* continues its travel in another direction.
  • suitable means such as the take-up roller h illustrated in Figs. 1 and 2, is provided to wind up the carrier web after the metal leaf has been transferred to the adhesive web.
  • the carrier web after removal of the metal leaf therefrom is caused to travel in one direc- ⁇ tion by the roller h, while the adhesive web provided with the leaf is caused by manual or mechanical means to travel in a different direction, thus causing the carrier web to separate from the coated web.
  • the herein described rocess of applying metal leaf to a web, w ich process consists in simultaneously passing an adhesive web and a plurality of carriers each provided with metal leaf thereon, while in contact with each ⁇ other about a platen surface, exerting pressure against saidl surface through tensioning of said carriers and said web whereby aicontinuing surface pressure is exerted upon said web and said carriers to insure application of saidl metal leaf from all of said carriers to said web, and finally separating said carriers and said web after such pressure has ceased.

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Replacement Of Web Rolls (AREA)

Description

B. BRANDT.
roonss oF coATING wBBs oF PAPER WITH LBAF METAL.
AYPLIOATION I'ILED JULY 15, 1913.
Patented May 19, 1914.
2 SHEETB-SHEBT 2.
UNITED STATES PATENT OFFICE.
EMIL BRANDT, OF MUN'ICH, GERMANY.
PROCESS OF COATING WEBS OF PAPER WITH LEAF METAL.
To all whom 'it may concern:
Be it known that I, EMIL BRANDT, citizen of Germany, residing at Munich, Bavaria, Germany, have invented certain new and useful Improvements in the Process of Coating 'Webs of Paper with Leaf Metal; and I do hereby declare the following to be a full, clear, and exact description of lthe invention, such as will enable others skilled in the. art, to which it appertains to make and use the same. 4
One known method of coating a strip of paper with leaf metal consists in winding the paper, with an adhesve substance thereon, together with a strip carrying thev leaf metal, the leaf being pressed between the two strips by the tension applied in winding them. WVith this process it is only possible to feed the metal'leaf from one roll, because if several feed rolls were placed side by side, in order to coat a wider strip or web of paper, creases would be too liable to be formed in the course of transferring the several strips of leaf metal to the strip of paper to be coated. Moreover, as the leaf is gener-l ally subjected to the action of a blower while being applied to the strip to be eoated, the
is liable to shift the strips at the sides thereof. The adhesive used 'must be one which dries quickly, and one which is notI soluble in water, as the eoated paper is used for cigarette ti s. This necessitates the use of resinous a hesives and the like, and with these the eoated paper cannot be given a high polish, because the adhesive is melted by the heat produced by the operation of polishing.
In another known process, a web of cigarette paper receives pieces of leaf metal at intervals from a traveling carrier, which takes a separate path after applyiug the leaf metal, no regulation of pressure being effected or attempted. With this process, only portions of the surface of the paper are eoated with leaf metal, so that it is not in the full sense a process of producing metal-` coated paper.
The object of the present invention is to enable wide and narrow webs of paper to be eoated over their entire surface with leaf metal which 'is applied with regulatable pressure, and to which a high polish can be given if desired. To this end the web to be eoated with leaf metal, and a traveling web carrying the leaf metal, are brought to- Speoificaton of Letters Patent.
Application med July 15, 1913,
air current acting o-n one strip of leaf metal' Patented May 19, 1914.
serial No. 779,095.
gether under ressure, as for example between two ro lers, the pressure being removed after the transfer of the leaf to the firstmentioned web, and thel two webs then continuing their travel in separate paths. The amount of pressure applicd may be regulated by regulating the period during which the two webs are subjected to the pressure. If the adhesive used is one which dries slowly and is soluble in water, a high polish can be applied to the eoated paper, because such adhesives do not become soft in the course of the polishing process. The leaf metal can be very tirmly attached, and the adhesive is not liable to penetrate through such small holes as sometimes occur in leaf metal.
Provided that the eoated web is Separated from the carrier web immediately after removal of the pressure, it will be clear that a plurality of leaf metal feed rolls may be used side by side, or one behind the other, each having a separate pressure roll, the several pressure rolls being arranged at the periphery of a larger roll for the web to be eoated. Several strips of leaf metal can thus be placed side by side on a web, slightly overlapping each other to obviate gaps.
The invention is illustrated in the accompanying drawing, in which.-
Figure l is a diagram' illustrating one method of carrying the process into effect. Fg. 2 is a sectional diagram, illustrating an'- other mode of operation, and Fig. 3 is a similar view, illustrating a third mode of operation; Fig. 4 is a mutilated plan view of the leaf metal rolls and webs shown in Fig. 3, and Fig. 5 is a section of the webs on the line A--B of Fig. 4. Fig. 6 is a sectional diagram illustrating another mode of operation, Fig. 7 being a mutilated plan view of the leaf metal rolls and webs, Fig. 8 a section of the webs on the line C-D of Fig. 7, and Fig. 9 a olan view of one of the webs.
Referring in the first instance to Fig. 1,
tothe roller c by suitable gearing, so that'as the two rollers are rotated the leaf metal is transferred to the web b at the place of contact. The web b thus coated may be fedV to a drying apparatus and thereuponl either wound onto a roller, cut into sheets or otherwise treated, while the web e having transferred the leaf metal, is wound up on the roller b.
It will be apparent that'it is possible to regulate the period during which those parts of the webs b and e, f, which are brought together, remain in contact with each other; this can be done by making them travel together around a greater or less part of the circumference of one of the rollers c, g, with regulatable pressure. Two or more rolls may be arranged side by side, with a similar number of pressure rollers g provided adjacent the periphery of the roller c.
The adhesive is preferably applied to the Web b beforehand, the web then being dried and rolled. The prepared web, with the dried adhesive thereon, is subsequently, before being coated with metal leaf, unrolled and passed through water, and then rolled up again while wet, so that the adhesive be-A comes active and is distributed in the form of an even film by the pressure applied in rolling. The web itself becomes uniformly saturated with moisture from both sides, so that when used after a few hours it travels smoothly, without creasing, over the roller c.
The above described mode of operation requires uniform saturation of the web b with water, in order to obtain Smooth and uniform coating of leaf metal. The quantity of adhesive applied is so regulated that the coated paper has the requisite fiexibility when subsequently passing through the polishing machine.
In certain cases, for instance with thin or porous kinds of paper, the 'adhesive alone will sutice to completely saturate the paper with mosture. The described saturating process may also be used indepcndently of the above described process of producing metal coated aper.
In the above described mode of operation the contact of the two webs is brought about by and between two rollers.
As the leaf' metal is not in the form of a continuous strip but consists of a number of leaves arranged one behind the other on the paper backing, or carrier, it may occur that individual leaves become detached from the backing'while passing over the roller, and may slide forward and vbecome crumpled between the rollers, in which condition it is then applied to the paper strip to be coated, a portion of the latter remaining bare. In order to avoidthis contingency,
the lweb coated with the adhesive may be drawn with its coated side facing inward over a convexcurved surface, the web or webs carrying the metal leaf being causcd to travel between the said convex surface and the adhesive web, so that theleaf metal is pressed by the stretched webs against the ad esive surface. This arrangement not only obviates 'the above mentioneddisad- Vantage but renders the use of toothed gearing and other transmission gear unnecessary. The movement of all the rollers and the control of this movement are effected solely by the pull of the web of paper coated with the metal leaf. The convex surface is preferably formed by a plurality 'of rollers arranged in' a curve, this Varrangement being better than a single large roller, inasmuch as it prevents the occurrence of creases even when coating wide webs. An arrangement working on this principle is shown diagrammatically in Fig. 2, in which al designates the paper roll, and bl the web drawn therefrom to be coated with leaf metal fl drawn from a roll dl together with a carrier web el of paper or the like. i is a fixed or rotating roller, on the periphery k of which the web of paper bl is brou ht into contact with the leaf metal. lis a ro ler of large diameter, which draws off the coated web from the periphery le, and at the same time draws the webs bl and el from their respective rolls. The roll al is preferably provided withv a suitable brake device in order to keep the paper and leaf metal webs at the proper tension when passing around the roller h is the roll on which the carrier webel is rewound.
The operation is as follows: The draw-ofi' roller Z is rotated and by adhesion moves the Vwet, adhesive web bl, pulling the said web off its roll al. The web bl passing around the roller z' with its adhesive side facing the latter, meets at m the web el, with the leaf metal facing outward, so that the leaf metal is transferred to the adhesive side of the web bl. The latter pulls the web el with the leaf metal fl off the roll all at the same` speed as that at which it travels itself. While the webs are travelingover surface le intimate, smooth and uniform connection of metal with paper -is effected. The blank web el leaves the coated web at n and is wound on the roll k for subsequent use, and the metal coated web is dried by any known drying apparatus, androlled up for further treatment' or use. The web el prevents the metal leaf which it carries from being damaged by thel surface k and also enables very thin and wet paper to be coated, as it takes part of the tension.
The arrangement shown diagrammatically in Figs. 3, 4 and 5 is substantially similar to that shown in Fig. 2, but in this case there are two pairs of carrer webs el, el,
carrier webs (24, with are of the same width as drawn from rolls dz, da, with leaf metal fz, f3 thereon, the two rolls forming each pair lying coaxially side by side, and the rolls da* being set back, so that the webs can bc made to overlap, as shown at o in Figs. 4 and 5. The carrier webs with the leaf metal meet at m2 the adhesive paper web bz drawn from the roll az, and then travel under the web b2 over the surface 702 of the roller iz, and thence to the roller lz. At In,2 the carrier web se arates from the coated paper web 62. On t e surface 7::2 of the roller iz the edges p of the webs 62, lying upon the leaf metal f3 carried by the webs es, cut away the overlapped parts o of this leaf, so that clean joints are made where the strips of leaf metal meet at the sides. Of course the material forming the webs 62 must be thin but yet strong in order that the edges of these webs are capable of performing this Cutting action.
In the arrangement shown in Figs. 6 to 9, the curved path k* for a plurality of fixed or rotatable rollers q arranged in an are. The web of paper b* to be coated with metal leaf travels from a roll a* to mi, and then over the rollers g to a roller 14. There are two rolls cl* supplying metal leaf f4 thereon. There are also two rolls als supplying carrier webs 05 with metal leaf f5 thereon. The several carrier webs travel side by side, their edges practically meeting, and the strips of metal leaf f* are of the same width as the carriers et The strips of metal leaf f5 on the carrier 65 are, however, wider than the said carriers, so that these strips overlap the strips f4, as shown in Figs. 7 and 8. lVhile wound on the rolls (ZE the strips f5 are covered by protective strips 66, which the strips of leaf metal f5 and lie between the latter and the carrier webs 65. In the course of unwinding, the strips e, which serve only for protection during packing, transport, Storage etc., are wound up separately, as at h6 and leave the leaf metal exposed for transfer to the web 64. i
Above the roller l* there is pressure roll fr, weighted or acted on by Springs, so that it bears on the carrier webs. After passing between this roll r and the roller l* the carthe webs is formed by rier webs e4, 65 are wound up separately to form a roll hi, and the coated web b* continues its travel in another direction.
In all forms of the invention, suitable means, such as the take-up roller h illustrated in Figs. 1 and 2, is provided to wind up the carrier web after the metal leaf has been transferred to the adhesive web. The carrier web, after removal of the metal leaf therefrom is caused to travel in one direc-` tion by the roller h, while the adhesive web provided with the leaf is caused by manual or mechanical means to travel in a different direction, thus causing the carrier web to separate from the coated web.
What I claim as my invention and desire to secure by Letters Patent of the United States is- 1'. The herein described process of applying metal leaf to a web, which process consists in simultaneously passin an adhesive web and a carrier having meta leaf thereon while in contact with each other abouta platen surface, exertmg pressure against said surface through tensoning of said'carrier and said web whereby a continuing surface pressure is exerted upon said web and said carrier' to insure application of said leaf to said web, and finally separating said carrier and said lweb after pressure i thereon has ceased.
2. The herein described rocess of applying metal leaf to a web, w ich process consists in simultaneously passing an adhesive web and a plurality of carriers each provided with metal leaf thereon, while in contact with each` other about a platen surface, exerting pressure against saidl surface through tensioning of said carriers and said web whereby aicontinuing surface pressure is exerted upon said web and said carriers to insure application of saidl metal leaf from all of said carriers to said web, and finally separating said carriers and said web after such pressure has ceased. I
In testimony whereof I hereunto aflix my signature in the presence of two witnesses. EMIL BRANDT.
Witnesses:
A. V. W. Corrnn, RICHARD Lnmr.
US1913779095 1913-07-15 1913-07-15 Process of coating webs of paper with leaf metal. Expired - Lifetime US1096822A (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2433441A (en) * 1947-12-30 Electrolytic production of thin
US2485607A (en) * 1945-10-26 1949-10-25 Du Mont Allen B Lab Inc Process of preparing and coating screen material on tubes
US2489337A (en) * 1945-08-10 1949-11-29 Us Sec War Aerial reflecting signal target
US2625496A (en) * 1950-09-30 1953-01-13 Swift & Sons Inc M Decalcomania for metal transfers
US3022078A (en) * 1956-01-25 1962-02-20 Tdk Electronics Co Ltd Magnetic record sheet for a magnetic recording and reading apparatus
US3043728A (en) * 1958-03-17 1962-07-10 Nat Res Corp Apparatus and process for metallic vapor coating
US3335044A (en) * 1964-03-06 1967-08-08 Brousse Georges Process for printing periodicals and product produced thereby
US3433698A (en) * 1963-05-13 1969-03-18 Raymond T Billings Apparatus for coating elongate work
US4250209A (en) * 1978-05-10 1981-02-10 Lurex B.V. Transfer metallizing process and product produced thereby

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2433441A (en) * 1947-12-30 Electrolytic production of thin
US2489337A (en) * 1945-08-10 1949-11-29 Us Sec War Aerial reflecting signal target
US2485607A (en) * 1945-10-26 1949-10-25 Du Mont Allen B Lab Inc Process of preparing and coating screen material on tubes
US2625496A (en) * 1950-09-30 1953-01-13 Swift & Sons Inc M Decalcomania for metal transfers
US3022078A (en) * 1956-01-25 1962-02-20 Tdk Electronics Co Ltd Magnetic record sheet for a magnetic recording and reading apparatus
US3043728A (en) * 1958-03-17 1962-07-10 Nat Res Corp Apparatus and process for metallic vapor coating
US3433698A (en) * 1963-05-13 1969-03-18 Raymond T Billings Apparatus for coating elongate work
US3335044A (en) * 1964-03-06 1967-08-08 Brousse Georges Process for printing periodicals and product produced thereby
US4250209A (en) * 1978-05-10 1981-02-10 Lurex B.V. Transfer metallizing process and product produced thereby

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