US10342616B2 - Window for surgical laser - Google Patents
Window for surgical laser Download PDFInfo
- Publication number
- US10342616B2 US10342616B2 US15/491,528 US201715491528A US10342616B2 US 10342616 B2 US10342616 B2 US 10342616B2 US 201715491528 A US201715491528 A US 201715491528A US 10342616 B2 US10342616 B2 US 10342616B2
- Authority
- US
- United States
- Prior art keywords
- window
- layer
- laser
- light
- laser window
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active, expires
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229910052681 coesite Inorganic materials 0.000 claims abstract description 16
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract description 16
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 16
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 16
- 229910052682 stishovite Inorganic materials 0.000 claims abstract description 16
- 229910052905 tridymite Inorganic materials 0.000 claims abstract description 16
- 230000037431 insertion Effects 0.000 claims abstract description 3
- 238000003780 insertion Methods 0.000 claims abstract description 3
- SBIBMFFZSBJNJF-UHFFFAOYSA-N selenium;zinc Chemical compound [Se]=[Zn] SBIBMFFZSBJNJF-UHFFFAOYSA-N 0.000 claims description 9
- 238000000576 coating method Methods 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 claims description 7
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- 229910004613 CdTe Inorganic materials 0.000 claims description 3
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 3
- 239000011780 sodium chloride Substances 0.000 claims description 3
- 210000001215 vagina Anatomy 0.000 claims description 3
- 238000005286 illumination Methods 0.000 claims description 2
- 238000011282 treatment Methods 0.000 claims description 2
- 238000013532 laser treatment Methods 0.000 description 8
- 238000004476 mid-IR spectroscopy Methods 0.000 description 5
- 229910003460 diamond Inorganic materials 0.000 description 4
- 239000010432 diamond Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000006117 anti-reflective coating Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000002103 nanocoating Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 210000000664 rectum Anatomy 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 238000001356 surgical procedure Methods 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B18/00—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body
- A61B18/18—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body by applying electromagnetic radiation, e.g. microwaves
- A61B18/20—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body by applying electromagnetic radiation, e.g. microwaves using laser
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B1/00—Instruments for performing medical examinations of the interior of cavities or tubes of the body by visual or photographical inspection, e.g. endoscopes; Illuminating arrangements therefor
- A61B1/00131—Accessories for endoscopes
- A61B1/00135—Oversleeves mounted on the endoscope prior to insertion
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B1/00—Instruments for performing medical examinations of the interior of cavities or tubes of the body by visual or photographical inspection, e.g. endoscopes; Illuminating arrangements therefor
- A61B1/06—Instruments for performing medical examinations of the interior of cavities or tubes of the body by visual or photographical inspection, e.g. endoscopes; Illuminating arrangements therefor with illuminating arrangements
- A61B1/063—Instruments for performing medical examinations of the interior of cavities or tubes of the body by visual or photographical inspection, e.g. endoscopes; Illuminating arrangements therefor with illuminating arrangements for monochromatic or narrow-band illumination
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B1/00—Instruments for performing medical examinations of the interior of cavities or tubes of the body by visual or photographical inspection, e.g. endoscopes; Illuminating arrangements therefor
- A61B1/303—Instruments for performing medical examinations of the interior of cavities or tubes of the body by visual or photographical inspection, e.g. endoscopes; Illuminating arrangements therefor for the vagina, i.e. vaginoscopes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B90/00—Instruments, implements or accessories specially adapted for surgery or diagnosis and not covered by any of the groups A61B1/00 - A61B50/00, e.g. for luxation treatment or for protecting wound edges
- A61B90/30—Devices for illuminating a surgical field, the devices having an interrelation with other surgical devices or with a surgical procedure
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
- A61N5/00—Radiation therapy
- A61N5/06—Radiation therapy using light
- A61N5/0601—Apparatus for use inside the body
- A61N5/0603—Apparatus for use inside the body for treatment of body cavities
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
- A61N5/00—Radiation therapy
- A61N5/06—Radiation therapy using light
- A61N5/067—Radiation therapy using light using laser light
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S3/00—Lasers, i.e. devices using stimulated emission of electromagnetic radiation in the infrared, visible or ultraviolet wave range
- H01S3/02—Constructional details
- H01S3/03—Constructional details of gas laser discharge tubes
- H01S3/034—Optical devices within, or forming part of, the tube, e.g. windows, mirrors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S3/00—Lasers, i.e. devices using stimulated emission of electromagnetic radiation in the infrared, visible or ultraviolet wave range
- H01S3/14—Lasers, i.e. devices using stimulated emission of electromagnetic radiation in the infrared, visible or ultraviolet wave range characterised by the material used as the active medium
- H01S3/22—Gases
- H01S3/223—Gases the active gas being polyatomic, i.e. containing two or more atoms
- H01S3/2232—Carbon dioxide (CO2) or monoxide [CO]
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B18/00—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body
- A61B2018/00315—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body for treatment of particular body parts
- A61B2018/00482—Digestive system
- A61B2018/005—Rectum
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B18/00—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body
- A61B2018/00315—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body for treatment of particular body parts
- A61B2018/00559—Female reproductive organs
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B18/00—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body
- A61B18/18—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body by applying electromagnetic radiation, e.g. microwaves
- A61B18/20—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body by applying electromagnetic radiation, e.g. microwaves using laser
- A61B2018/2035—Beam shaping or redirecting; Optical components therefor
- A61B2018/20553—Beam shaping or redirecting; Optical components therefor with special lens or reflector arrangement
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B18/00—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body
- A61B18/18—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body by applying electromagnetic radiation, e.g. microwaves
- A61B18/20—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body by applying electromagnetic radiation, e.g. microwaves using laser
- A61B18/22—Surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body by applying electromagnetic radiation, e.g. microwaves using laser the beam being directed along or through a flexible conduit, e.g. an optical fibre; Couplings or hand-pieces therefor
- A61B2018/2255—Optical elements at the distal end of probe tips
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
- A61N5/00—Radiation therapy
- A61N5/06—Radiation therapy using light
- A61N5/0601—Apparatus for use inside the body
- A61N5/0603—Apparatus for use inside the body for treatment of body cavities
- A61N2005/0608—Rectum
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
- A61N5/00—Radiation therapy
- A61N5/06—Radiation therapy using light
- A61N5/0601—Apparatus for use inside the body
- A61N5/0603—Apparatus for use inside the body for treatment of body cavities
- A61N2005/0611—Vagina
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
- A61N5/00—Radiation therapy
- A61N5/06—Radiation therapy using light
- A61N2005/0658—Radiation therapy using light characterised by the wavelength of light used
- A61N2005/0659—Radiation therapy using light characterised by the wavelength of light used infrared
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
- A61N5/00—Radiation therapy
- A61N5/06—Radiation therapy using light
- A61N2005/0664—Details
-
- A61N2005/067—
Definitions
- the present invention relates to a window component for a laser tool. Certain embodiments relate to a laser medical probe.
- Diamond is useful as a window material as it has low absorption for infrared wavelengths in order to transmit a high power laser beam.
- diamond is expensive.
- Diamond windows are discussed in U.S. Pat. No. 9,040,131, which is hereby incorporated by reference.
- SiO2 is a biocompatible compound. It has been used in laser windows for wavelengths from around 0.2 to 3.5 microns but has not been suitable for mid-IR wavelengths, due to its low transmissivity at those wavelengths.
- a biocompatible coating for windows for mid-IR wavelength lasers has not been found that is easily applied and inexpensive.
- the present invention is directed to a laminated laser window, comprising: an inner layer transparent to light having wavelengths between 3.5 micrometers and 12 micrometers; and constituting an outer surface of the window, a nanometric-thick outer layer of SiO2.
- the window is thereby configured to allow passage of light having said wavelengths therethrough.
- the outer layer of SiO2 is not more than 150 nm thick, is between 100 nm and 150 nm thick, or is less than 100 nm thick.
- the inner layer is at least one selected from the group comprising Ge, GeAs, CdTe, ZnSe, NaCl, KCl and ZnSe
- the window allows passage of light having a wavelength of 10.6 micrometers.
- the window allows passage of light generated by a CO2 laser.
- the first layer is an innermost layer of the window.
- the intervening layer is an AR layer.
- a medical device for illumination of living tissue with light
- the device body has a wall with an outer surface and a laser window as described earlier in this summary constituting at least a portion of the wall, thereby allowing light having said wavelengths to pass from inside said body to outside said body through said laser window.
- the outer layer of said laser window in the device is located to allow it to contact bodily tissue during use of the device.
- the body of the device is for insertion into a bodily cavity, such as the vagina.
- the device further comprises a CO2 laser.
- the device body constitutes a sheath for a treatment device.
- the a nanometric outer layer of SiO2 is used in a laser window for coating an inner layer, the inner layer transparent to light having wavelengths between 3.5 micrometers and 12 micrometers.
- FIG. 1 is a perspective view of a laser treatment device comprising a laser window in accordance with an embodiment of the invention.
- FIG. 2 is a perspective view of the device of FIG. 1 with the window removed.
- FIG. 3 is a cross sectional view of a section of the laser window inside a bodily cavity.
- window 14 sheath 6 laser treatment head 2 laser beam 4 axis 12 deflector 22 inner layer 23 outer surface 25 body cavity 27
- SiO2-based nano-coatings have been developed for glass and glazed ceramic.
- the non-stick coatings enable smooth, glass-like surfaces to have less contact with dirt particles.
- Coating characteristics include hydrophobicity, food safety (inert), and anti-stick properties.
- An example of such a coating is manufactured by Nano-Care Kunststoff AG (see, http://www.nanocare-ag.com/glas_keramik/).
- SiO2 is substantially transmissive at mid-IR wavelengths.
- high transparency windows particularly ZnSe, coated with nanoscale SiO2
- FIG. 1 shows an exemplary window 14 forming part of a biocompatible disposable sheath 6 fitted on a laser treatment head 2 for use in externally-accessible bodily cavities, such as the vagina or rectum.
- the laser treatment head is described in U.S. patent application Ser. No. 15/473,621, filed 2017 Mar. 30, which is hereby included by reference as if fully set-forth herein.
- Window 14 comprises an inner layer 23 that is transparent to light having wavelengths between 3.5 micrometers and 12 micrometers.
- the external surface of the inner layer is coated by an outer layer 25 of nanometric SiO2.
- the inner layer 23 comprises ZnSe. In some embodiments, the inner layer 23 has an AR/AR coating, with the external AR coating lying between inner layer 23 and outer layer 25 . Window 14 is substantially transmissive to a CO2 laser.
- FIG. 2 shows the laser treatment head 2 with the sheath removed.
- laser treatment head 2 In use, laser treatment head 2 is inserted into an externally accessible bodily cavity. Laser beam 4 passing through laser treatment head 2 coaxially with linear axis 12 impinges on deflector 22 and is deflected laterally, away from laser treatment head 2 , through window 14 to the wall 27 of the bodily cavity.
- FIG. 3 shows a cross sectional view of a portion of window 14 and of wall 27 of the bodily cavity.
- the thickness of the SiO2 layer is less than 100 micron, preferably 100-150 nm.
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Surgery (AREA)
- Physics & Mathematics (AREA)
- Biomedical Technology (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Optics & Photonics (AREA)
- Pathology (AREA)
- Medical Informatics (AREA)
- Heart & Thoracic Surgery (AREA)
- Molecular Biology (AREA)
- Radiology & Medical Imaging (AREA)
- Electromagnetism (AREA)
- Biophysics (AREA)
- Plasma & Fusion (AREA)
- Otolaryngology (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Gynecology & Obstetrics (AREA)
- Reproductive Health (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Laser Surgery Devices (AREA)
- Radiation-Therapy Devices (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15/491,528 US10342616B2 (en) | 2016-04-19 | 2017-04-19 | Window for surgical laser |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201662324418P | 2016-04-19 | 2016-04-19 | |
US15/491,528 US10342616B2 (en) | 2016-04-19 | 2017-04-19 | Window for surgical laser |
Publications (2)
Publication Number | Publication Date |
---|---|
US20170296272A1 US20170296272A1 (en) | 2017-10-19 |
US10342616B2 true US10342616B2 (en) | 2019-07-09 |
Family
ID=60039760
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US15/491,528 Active 2037-07-15 US10342616B2 (en) | 2016-04-19 | 2017-04-19 | Window for surgical laser |
Country Status (5)
Country | Link |
---|---|
US (1) | US10342616B2 (de) |
EP (1) | EP3446377A4 (de) |
KR (1) | KR20190004716A (de) |
IL (1) | IL262474A (de) |
WO (1) | WO2017182970A1 (de) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107970526B (zh) * | 2018-01-03 | 2019-09-03 | 张金玲 | 一种妇科临床光疗装置 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20010001118A1 (en) * | 1996-12-10 | 2001-05-10 | Asah Medico A/S | Apparatus for tissue treatment |
US20020045811A1 (en) * | 1985-03-22 | 2002-04-18 | Carter Kittrell | Laser ablation process and apparatus |
US20110019174A1 (en) | 2008-02-27 | 2011-01-27 | Wouter Anthon Soer | Optical element, lithographic apparatus including such an optical element, device manufacturing method, and device manufactured thereby |
US8187481B1 (en) | 2005-05-05 | 2012-05-29 | Coho Holdings, Llc | Random texture anti-reflection optical surface treatment |
WO2016044212A1 (en) | 2014-09-17 | 2016-03-24 | Corning Incorporated | High-efficiency multiwavelength beam expander employing dielectric-enhanced mirrors |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4122853A (en) * | 1977-03-14 | 1978-10-31 | Spectra-Med | Infrared laser photocautery device |
US4170997A (en) * | 1977-08-26 | 1979-10-16 | Hughes Aircraft Company | Medical laser instrument for transmitting infrared laser energy to a selected part of the body |
US6249369B1 (en) * | 1999-07-09 | 2001-06-19 | Gentex Corporation | Coupled electrochromic compounds with photostable dication oxidation states |
US6904073B2 (en) * | 2001-01-29 | 2005-06-07 | Cymer, Inc. | High power deep ultraviolet laser with long life optics |
EP2397873A4 (de) * | 2009-02-13 | 2012-09-05 | Panasonic Corp | Optisches ir-filter und herstellungsverfahren dafür |
JP5489824B2 (ja) * | 2010-04-02 | 2014-05-14 | 富士フイルム株式会社 | 反射防止膜及び赤外線用光学素子 |
CN103771725A (zh) * | 2012-10-22 | 2014-05-07 | 中国科学院上海硅酸盐研究所 | 一种新型多功能节能玻璃镀膜结构及制备方法 |
US20160097681A1 (en) * | 2013-03-14 | 2016-04-07 | Qualcomm Mems Technologies, Inc. | Microbolometer supported by glass substrate |
-
2017
- 2017-04-19 WO PCT/IB2017/052259 patent/WO2017182970A1/en active Application Filing
- 2017-04-19 KR KR1020187032813A patent/KR20190004716A/ko not_active Application Discontinuation
- 2017-04-19 EP EP17785546.7A patent/EP3446377A4/de not_active Withdrawn
- 2017-04-19 US US15/491,528 patent/US10342616B2/en active Active
-
2018
- 2018-10-18 IL IL262474A patent/IL262474A/en unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20020045811A1 (en) * | 1985-03-22 | 2002-04-18 | Carter Kittrell | Laser ablation process and apparatus |
US20010001118A1 (en) * | 1996-12-10 | 2001-05-10 | Asah Medico A/S | Apparatus for tissue treatment |
US8187481B1 (en) | 2005-05-05 | 2012-05-29 | Coho Holdings, Llc | Random texture anti-reflection optical surface treatment |
US20110019174A1 (en) | 2008-02-27 | 2011-01-27 | Wouter Anthon Soer | Optical element, lithographic apparatus including such an optical element, device manufacturing method, and device manufactured thereby |
WO2016044212A1 (en) | 2014-09-17 | 2016-03-24 | Corning Incorporated | High-efficiency multiwavelength beam expander employing dielectric-enhanced mirrors |
Non-Patent Citations (2)
Title |
---|
PCT/IB17/52259, filed Apr. 19, 2017, like the present application, claims the benefit of U.S. Appl. No. 62/324,418. The ISR and IPRP (written opinion) dated Aug. 7, 2017. They are being submitted with this IDS. The (‘Y’) citations are listed above in this IDS. |
PCT/IB17/52259, filed Apr. 19, 2017, like the present application, claims the benefit of U.S. Appl. No. 62/324,418. The ISR and IPRP (written opinion) dated Aug. 7, 2017. They are being submitted with this IDS. The ('Y') citations are listed above in this IDS. |
Also Published As
Publication number | Publication date |
---|---|
US20170296272A1 (en) | 2017-10-19 |
WO2017182970A1 (en) | 2017-10-26 |
IL262474A (en) | 2018-12-31 |
KR20190004716A (ko) | 2019-01-14 |
EP3446377A4 (de) | 2019-11-27 |
EP3446377A1 (de) | 2019-02-27 |
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