UA46481A - Спосіб модифікації полімерних поверхонь - Google Patents
Спосіб модифікації полімерних поверхонь Download PDFInfo
- Publication number
- UA46481A UA46481A UA2001075279A UA200175279A UA46481A UA 46481 A UA46481 A UA 46481A UA 2001075279 A UA2001075279 A UA 2001075279A UA 200175279 A UA200175279 A UA 200175279A UA 46481 A UA46481 A UA 46481A
- Authority
- UA
- Ukraine
- Prior art keywords
- modifier
- peroxide
- polymer
- layer
- modification
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 42
- 238000012986 modification Methods 0.000 title claims abstract description 19
- 230000004048 modification Effects 0.000 title claims abstract description 19
- 229920000642 polymer Polymers 0.000 title claims description 62
- 239000003607 modifier Substances 0.000 claims abstract description 33
- 239000000178 monomer Substances 0.000 claims abstract description 20
- 150000002978 peroxides Chemical class 0.000 claims abstract description 18
- 229920001577 copolymer Polymers 0.000 claims abstract description 17
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 11
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 10
- 125000002081 peroxide group Chemical group 0.000 claims abstract description 7
- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 claims abstract description 6
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims abstract description 5
- 229920000098 polyolefin Polymers 0.000 claims abstract description 5
- 229920006301 statistical copolymer Polymers 0.000 claims abstract description 5
- 229920000307 polymer substrate Polymers 0.000 claims description 8
- 239000012462 polypropylene substrate Substances 0.000 claims description 3
- 238000010559 graft polymerization reaction Methods 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 abstract description 10
- 229920001155 polypropylene Polymers 0.000 abstract description 10
- -1 for example Polymers 0.000 abstract description 7
- 238000010526 radical polymerization reaction Methods 0.000 abstract description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 30
- 239000010410 layer Substances 0.000 description 17
- 239000001257 hydrogen Substances 0.000 description 9
- 229910052739 hydrogen Inorganic materials 0.000 description 9
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 125000000524 functional group Chemical group 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 230000005855 radiation Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000004642 Polyimide Substances 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920001721 polyimide Polymers 0.000 description 3
- 239000002861 polymer material Substances 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- NZZFYRREKKOMAT-UHFFFAOYSA-N diiodomethane Chemical compound ICI NZZFYRREKKOMAT-UHFFFAOYSA-N 0.000 description 2
- 229920002313 fluoropolymer Polymers 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 230000006798 recombination Effects 0.000 description 2
- 238000005215 recombination Methods 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 150000001718 carbodiimides Chemical class 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000005660 hydrophilic surface Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 1
- 238000006385 ozonation reaction Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229920005548 perfluoropolymer Polymers 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 125000006413 ring segment Chemical group 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Treatments Of Macromolecular Shaped Articles (AREA)
- Laminated Bodies (AREA)
Abstract
Способ модификации полимерных поверхностей, по которому к поверхности полимерной подкладки ковалентно прививают слой первого модификатора, к которому ковалентно прививают слой второго модификатора. В качестве первого модификатора используют пероксидсодержащий кополимер, с поверхности которого, за счет его пероксидных групп, создают слой второго модификатора привитой свободно-радикальной полимеризацией ненасыщенных мономеров, например, акриловой кислоты. В качестве полимерной подкладки для ковалентного прививания первого модификатора - пероксидсодержащего кополимера - берут полиолефиновую, например, полипропиленовую подкладку. В качестве пероксидсодержащего кополимера используют статистические кополимеры высших (мет)акрилатов, например, октилметакрилата, и пероксидного мономера, например, трет-бутилперокси-2-метил-5-гексен-3-ина.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| UA2001075279A UA46481A (uk) | 2001-07-24 | 2001-07-24 | Спосіб модифікації полімерних поверхонь |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| UA2001075279A UA46481A (uk) | 2001-07-24 | 2001-07-24 | Спосіб модифікації полімерних поверхонь |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UA46481A true UA46481A (uk) | 2002-05-15 |
Family
ID=74207890
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| UA2001075279A UA46481A (uk) | 2001-07-24 | 2001-07-24 | Спосіб модифікації полімерних поверхонь |
Country Status (1)
| Country | Link |
|---|---|
| UA (1) | UA46481A (ru) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2656050C2 (ru) * | 2012-12-18 | 2018-05-30 | Лэнксесс Бутил Пте. Лтд. | Бутилкаучук с повышенной непроницаемостью |
-
2001
- 2001-07-24 UA UA2001075279A patent/UA46481A/uk unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2656050C2 (ru) * | 2012-12-18 | 2018-05-30 | Лэнксесс Бутил Пте. Лтд. | Бутилкаучук с повышенной непроницаемостью |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Wang et al. | Studies on surface graft polymerization of acrylic acid onto PTFE film by remote argon plasma initiation | |
| Kato et al. | Polymer surface with graft chains | |
| Kang et al. | Surface modifications of polyaniline films by graft copolymerization | |
| Clochard et al. | Tailoring bulk and surface grafting of poly (acrylic acid) in electron-irradiated PVDF | |
| US20100240827A1 (en) | Method for Producing a Grafted Polymer Coating and Substrates Formed in Accordance With the Method | |
| Babaei et al. | Tuning the surface properties of oxygen-rich and nitrogen-rich plasma polymers: functional groups and surface charge | |
| JP2003510378A (ja) | 基体表面のグラフト重合 | |
| Chen et al. | Controlled grafting from poly (vinylidene fluoride) films by surface‐initiated reversible addition–fragmentation chain transfer polymerization | |
| Yu et al. | Study of radiation‐induced graft copolymerization of butyl acrylate onto chitosan in acetic acid aqueous solution | |
| Ko et al. | Synthesis and characterization of superabsorbent polymer based on carboxymethyl cellulose-graft-itaconic acid | |
| Liu et al. | Controlled grafting of polymer brushes on poly (vinylidene fluoride) films by surface‐initiated atom transfer radical polymerization | |
| Ramos‐Ballesteros et al. | γ‐Rays and Ions Irradiation | |
| Martínez-Cocoletzi et al. | Primary-amine surface functionalization of polytetrafluoroethylene films by radiation grafting of aminated polyacryloyl chloride | |
| Zhang et al. | Preparation and characterization of grafting polyacrylamide from PET films by SI‐ATRP via water‐borne system | |
| Wang et al. | Oxidation of polyethylene surface by glow discharge and subsequent graft copolymerization of acrylic acid | |
| UA46481A (uk) | Спосіб модифікації полімерних поверхонь | |
| Seto et al. | Thermosensitive surface properties of polyethylene film with poly (N‐isopropylacrylamide) chains prepared by corona discharge induced grafting | |
| JPH02173127A (ja) | 吸水性高分子物質及びその製造方法 | |
| JP2010132868A (ja) | アリールアジド基を有する高分子重合開始剤およびこれを利用した環式オレフィン共重合体表面改質方法。 | |
| Wang et al. | Immobilization of poly (ethylene oxide) on polyethylene using a plasma‐induced graft copolymerization process | |
| ES2265347T3 (es) | Metodo para funcionalizar superficies solidas. | |
| JP5066768B2 (ja) | 修飾炭素質膜 | |
| Johansson et al. | Penetration of pores in membranes by plasma polymer forming species | |
| JPS5840323A (ja) | 潤滑特性のすぐれたグラフト共重合物の製造方法 | |
| Yun et al. | Photosensitive polymer brushes grafted onto PTFE film surface for micropatterning of proteins |