TWM612854U - Atomic layer deposition device - Google Patents
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- TWM612854U TWM612854U TW110202008U TW110202008U TWM612854U TW M612854 U TWM612854 U TW M612854U TW 110202008 U TW110202008 U TW 110202008U TW 110202008 U TW110202008 U TW 110202008U TW M612854 U TWM612854 U TW M612854U
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本新型係關於一種原子層沉積裝置,尤其指一種透過載盤與擋件形成反應空間以調節製程流體(例如,前驅物或滌洗氣體)之流場的原子層沉積裝置。The present invention relates to an atomic layer deposition device, in particular to an atomic layer deposition device that forms a reaction space through a carrier plate and a stopper to adjust the flow field of a process fluid (for example, a precursor or a scrubbing gas).
積體電路技術的發展已經成熟,且目前電子產品朝向輕薄短小、高性能、高可靠性與智能化的趨勢發展。電子產品中的電晶體之微縮技術至關重要,小尺寸的電晶體會對電子產品的性能產生重要影響,當電晶體的尺寸愈小,可減少電流傳輸時間並降低耗能,以達到快速運算並節能的效果。在現今微小的電晶體中,部分關鍵的薄膜層幾乎僅有幾個原子的厚度,而發展這些微量結構的技術之一為原子層沉積製程(atomic layer deposition process, ALD process)。The development of integrated circuit technology has matured, and current electronic products are developing towards the trend of light, thin, short, high performance, high reliability and intelligence. The miniaturization technology of transistors in electronic products is very important. Small size transistors will have an important impact on the performance of electronic products. When the size of the transistor becomes smaller, the current transmission time and energy consumption can be reduced to achieve fast calculations. And the effect of energy saving. In today's tiny transistors, some of the key thin film layers are almost only a few atoms thick, and one of the technologies to develop these microstructures is the atomic layer deposition process (ALD process).
原子層沉積製程是一種將物質以單原子的形式一層一層地鍍於基材表面的技術,其中於製程中,係使反應的前驅物與基材或前一層膜的材料表面進行化學吸附,以生產既薄且均勻的薄膜。於原子層沉積製程中,均勻的沉積薄膜是電晶體微縮的重要基礎,如何有效的控制薄膜均勻度為現今的電晶體發展的重要課題。The atomic layer deposition process is a technique in which substances are deposited layer by layer on the surface of the substrate in the form of single atoms. In the process, the precursor of the reaction is chemically adsorbed on the surface of the substrate or the previous layer of film. Produce thin and uniform films. In the atomic layer deposition process, a uniform deposited film is an important basis for the reduction of transistors, and how to effectively control the uniformity of the film is an important issue for the development of today's transistors.
目前原子層沉積製程的均勻度之控制仍未完善,其中一個問題來自前驅物的流場未受到妥善的控制(例如,原子層沉積製程的前驅物如何在不干擾均勻的沉積行為下抽離腔體)。現行的原子層沉積設備之設計多使用大型的密閉式腔體,其可於原子層沉積製程中容納大量的前驅物,並確保前驅物滯留於腔體中與基材接觸以進行沉積,其中密閉式的腔體設計可避免前驅物在沉積與反應完成之前提早流失。當沉積與反應完成,腔體內的前驅物再透過腔體之底部抽氣口排出。At present, the uniformity control of the atomic layer deposition process is still not perfect. One of the problems is that the flow field of the precursor is not properly controlled (for example, how does the precursor of the atomic layer deposition process draw out of the cavity without disturbing the uniform deposition behavior? body). The current atomic layer deposition equipment is designed to use a large closed chamber, which can accommodate a large number of precursors during the atomic layer deposition process, and ensures that the precursors stay in the chamber and contact the substrate for deposition, which is closed The type of cavity design can avoid the premature loss of precursors before the deposition and reaction are completed. When the deposition and reaction are completed, the precursors in the cavity are then discharged through the suction port at the bottom of the cavity.
然而,此種大型的密閉式腔體需使用大量的前驅物,將使製程成本過高。再者,若排出前驅物的時間控制失當,則單一的抽氣裝置(底部抽氣口)則可能導致前驅物形成擾流,使得基材受沉積的均勻度受到不良影響。However, such a large closed cavity requires a large amount of precursors, which will make the process cost too high. Furthermore, if the time control of the discharge of the precursor is improper, a single suction device (the bottom suction port) may cause the precursor to form a turbulent flow, which will adversely affect the uniformity of the substrate deposition.
為了降低製程成本,其中一種方法是縮減腔體的容積以減少前驅物用量,然而此法將造成前驅物形成擾流,進而導致前驅物重複與基材接觸,而使基材受沉積的均勻度下降。故如何降低製程成本且妥善控制前驅物沉積於基材的均勻度,為現今原子層沉積製程待克服之議題。In order to reduce the cost of the process, one of the methods is to reduce the volume of the cavity to reduce the amount of precursors. However, this method will cause the precursors to form turbulence, which will cause the precursors to repeatedly contact the substrate, and the substrate will be deposited uniformly. decline. Therefore, how to reduce the process cost and properly control the uniformity of the precursors deposited on the substrate are issues to be overcome in the current atomic layer deposition process.
因此,為了克服習知技術的不足之處,本新型實施例提供一種原子層沉積裝置,可減少前驅物(precursor)用量並使前驅物可呈現受控制的流場,以藉此調節前驅物沉積於基材的均勻度。Therefore, in order to overcome the shortcomings of the conventional technology, the embodiment of the present invention provides an atomic layer deposition apparatus that can reduce the amount of precursor (precursor) and enable the precursor to exhibit a controlled flow field, thereby adjusting the deposition of the precursor. For the uniformity of the substrate.
基於前述目的的至少其中之一者,本新型實施例提供之原子層沉積裝置包括腔體、前驅物進氣口、加熱台、載盤、擋件與至少一中空部件。所述腔體具有容置空間,而加熱台設置於腔體的容置空間內,其中加熱台具有一頂表面。所述載盤位於加熱台的頂表面,並用以承載基材。所述前驅物進氣口流體連通腔體的容置空間,用以輸送至少一前驅物到容置空間。所述中空部件流體連通腔體的容置空間,且高於載盤,並具有至少一抽氣孔。所述擋件高於載盤並圍繞中空部件,且具有阻擋部與接觸部,其中擋件連接腔體或中空部件,而在擋件受到重力向下位移時,阻擋部用以將擋件限制在腔體或中空部件。Based on at least one of the foregoing objectives, the atomic layer deposition apparatus provided by the embodiment of the present invention includes a cavity, a precursor air inlet, a heating stage, a tray, a stopper, and at least one hollow component. The cavity has an accommodating space, and the heating platform is arranged in the accommodating space of the cavity, wherein the heating platform has a top surface. The carrier plate is located on the top surface of the heating table and is used to carry the substrate. The precursor air inlet fluidly communicates with the accommodating space of the cavity, and is used to transport at least one precursor to the accommodating space. The hollow part is in fluid communication with the accommodating space of the cavity, is higher than the carrier plate, and has at least one air suction hole. The stopper is higher than the tray and surrounds the hollow part, and has a blocking part and a contact part, wherein the blocking part is connected to the cavity or the hollow part, and when the blocking part is displaced downward by gravity, the blocking part is used to restrict the blocking part In the cavity or hollow part.
可選地,所述原子層沉積裝置還包括升降裝置,連接加熱台,其中升降裝置驅動加熱台與載盤靠近中空部件,而載盤接觸擋件的接觸部並帶動擋件垂直位移,以使擋件與載盤圍繞出反應空間。Optionally, the atomic layer deposition apparatus further includes a lifting device connected to the heating platform, wherein the lifting device drives the heating platform and the carrier plate to approach the hollow part, and the carrier plate contacts the contact part of the stopper and drives the stopper to move vertically, so that The stopper and the carrier plate surround the reaction space.
基於前述目的的至少其中之一者,本新型實施例提供之原子層沉積製程方法應用前述的原子層沉積裝置包括腔體、前驅物進氣口、加熱台、載盤、擋件、馬達與至少一中空部件。所述腔體具有容置空間。所述前驅物進氣口流體連通腔體的容置空間,用以輸送至少一前驅物到容置空間。所述加熱台設置於腔體的容置空間內,且具有頂表面。所述載盤位於加熱台的頂表面,並用以承載至少一基材。所述中空部件流體連通容置空間且高於載盤,並具有至少一抽氣孔。所述擋件高於載盤並圍繞中空部件,且具有阻擋部與接觸部。所述馬達連接擋件的阻擋部,並用以驅動擋件垂直位移。Based on at least one of the foregoing objectives, the atomic layer deposition process method provided by the embodiment of the present invention applies the foregoing atomic layer deposition apparatus including a cavity, a precursor air inlet, a heating stage, a tray, a stopper, a motor, and at least A hollow part. The cavity has an accommodating space. The precursor air inlet fluidly communicates with the accommodating space of the cavity, and is used to transport at least one precursor to the accommodating space. The heating stage is arranged in the accommodating space of the cavity and has a top surface. The carrier plate is located on the top surface of the heating table and is used to carry at least one substrate. The hollow part is in fluid communication with the accommodating space and is higher than the carrier plate, and has at least one suction hole. The stopper is higher than the tray and surrounds the hollow part, and has a blocking portion and a contact portion. The motor is connected to the blocking part of the blocking member and used for driving the vertical displacement of the blocking member.
可選地,所述原子層沉積系統還包括升降裝置,連接加熱台,其中升降裝置驅動加熱台與載盤靠近中空部件,而擋件與載盤圍繞出反應空間。Optionally, the atomic layer deposition system further includes a lifting device connected to the heating platform, wherein the lifting device drives the heating platform and the carrier plate to approach the hollow part, and the stopper and the carrier plate surround the reaction space.
可選地,所述擋件的接觸部還包括遮擋環,且相鄰載盤,以在擋件與載盤圍繞出反應空間時,減少前驅物自擋件與載盤之間洩漏。Optionally, the contact portion of the stopper further includes a shielding ring and is adjacent to the carrier plate, so as to reduce the leakage of the precursor from the stopper and the carrier plate when the stopper and the carrier plate surround the reaction space.
可選地,所述原子層沉積裝置還包括緩衝單元,位於擋件的阻擋部與接觸部之間,以在擋件向下位移時緩衝擋件。Optionally, the atomic layer deposition apparatus further includes a buffer unit located between the barrier portion and the contact portion of the barrier to buffer the barrier when the barrier is displaced downward.
可選地,所述緩衝單元為彈簧或線性滑軌緩衝單元。Optionally, the buffer unit is a spring or a linear slide rail buffer unit.
可選地,所述接觸部為環形圈體,而擋件還包括複數連接桿,位於阻擋部與接觸部之間。Optionally, the contact part is an annular ring body, and the stopper further includes a plurality of connecting rods located between the stop part and the contact part.
可選地,所述原子層沉積裝置還包括至少一開口,流體連通容置空間,用以將氣體導入腔體與擋件之間,以防止該前驅物沉積於擋件。Optionally, the atomic layer deposition apparatus further includes at least one opening in fluid communication with the accommodating space for introducing gas between the cavity and the stopper to prevent the precursor from being deposited on the stopper.
可選地,所述原子層沉積裝置還包括至少一抽氣口,流體連通腔體,且與前驅物進氣口彼此相對,用以排出容置空間內的至少一流體。Optionally, the atomic layer deposition apparatus further includes at least one air suction port, which is in fluid communication with the cavity, and is opposite to the precursor air intake port for exhausting at least one fluid in the accommodating space.
可選地,所述前驅物進氣口為噴頭。Optionally, the precursor air inlet is a nozzle.
可選地,所述載盤為是圓盤。Optionally, the carrier disk is a circular disk.
簡言之,本新型實施例提供的原子層沉積裝置,可透過擋件與載盤圍繞反應空間,以使原子層沉積製程中的前驅物自中空部件被抽離,藉此以動態的方式對基材進行反應與沉積,進而調控基材受沉積時的均勻度,故於對原子層沉積有需求的市場(例如,積體電路)具有優勢。In short, the atomic layer deposition apparatus provided by the embodiment of the present invention can surround the reaction space through the stopper and the carrier plate, so that the precursors in the atomic layer deposition process are drawn away from the hollow part, thereby performing dynamic alignment. The substrate undergoes reaction and deposition to control the uniformity of the substrate during deposition. Therefore, markets that require atomic layer deposition (for example, integrated circuits) have advantages.
為讓本新型之上述和其他目的、特徵及優點能更明顯易懂,配合所附圖示,做詳細說明如下。In order to make the above and other objects, features and advantages of the present invention more obvious and understandable, detailed descriptions are made as follows in conjunction with the accompanying drawings.
為充分瞭解本新型之目的、特徵及功效,茲藉由下述具體之實施例,並配合所附之圖式,對本新型做一詳細說明,說明如後。In order to fully understand the purpose, features and effects of the present invention, a detailed description of the present invention is given with the following specific embodiments and accompanying drawings. The description is as follows.
首先,請參照圖1與圖2,圖1是本新型實施例的原子層沉積裝置的示意圖。如圖1所示,原子層沉積裝置1包括腔體101、加熱台102、載盤106、擋件105、至少一中空部件103以及前驅物進氣口104。所述具有腔體101具有容置空間S,而前驅物進氣口104流體連通腔體101的容置空間S,並用以輸送至少一前驅物G101到容置空間S。在其他實施例中,前驅物進氣口104也可以是噴頭1041,並鑲嵌於腔體101頂部,或設置在腔體101的容置空間S內。First, please refer to FIGS. 1 and 2. FIG. 1 is a schematic diagram of an atomic layer deposition apparatus according to an embodiment of the present invention. As shown in FIG. 1, the atomic
所述加熱台102設置在腔體101的容置空間S內,且加熱台102具有頂表面,而載盤106位於加熱台102的頂表面,並用以承載至少一基材W,其中載盤106可以是圓盤。在一個實施例中,基材W可以是晶圓。The
所述中空部件103流體連通腔體101的容置空間S且高於載盤106,並具有至少一抽氣孔O103。中空部件103可連接泵(圖未示),以抽離腔體101的容置空間S內的流體,其中流體可能是空氣、滌洗氣體、前驅物或為製程開始之前所留在容置空間S中的任何物質。在一個實施例中,抽氣孔O103位於中空部件103的底部。在其他實施例中,抽氣孔O103也可以位於中空部件103的側邊。The
所述擋件105高於載盤106並圍繞中空部件103,具體而言,擋件105具有阻擋部1053與接觸部1051,而阻擋部1053高於接觸部1051。所述阻擋部1053是用以限制擋件105的位置,使擋件105受重力之下不掉落到腔體101的底部。請參照圖1,在一個實施例中,擋件105連接腔體101,而在擋件105受到重力向下位移時,阻擋部1053用以將擋件105限制在腔體101,使擋件105不掉落。具體而言,擋件105可直接連接腔體101,例如透過鎖固或卡合的方式將擋件105限制在腔體101。或者,擋件105也可以間接連接腔體101,例如透過其他構件將擋件105與腔體101連接。所述擋件105連接腔體101的位置,不限制是腔體101的頂部或側邊。The
請參照圖2,在其他實施例中,擋件105也可以連接中空部件103,而在擋件105受到重力向下位移時,阻擋部1053用以將擋件105限制在中空部件103,其中,擋件105需圍繞中空部件103的抽氣孔O103,以使抽氣孔O103位於在反應空間S1。2, in other embodiments, the
在一個實施例中,擋件105的阻擋部1053與接觸部1051之間還可以具有緩衝單元107。在擋件105受到重力向下位移時,緩衝單元107可以緩衝擋件105,使擋件105不會快速地向下位移,如此,可減少因擋件105快速位移所造成的髒污產生。在一個實施例中,緩衝單元107可以是彈簧1071,但本新型不以此為限制。In an embodiment, a
請參照圖3,圖3是本新型實施例的擋件的示意圖。在一個實施例中,擋件105可連接線性滑軌,例如擋件105被限制在線性滑軌之間,而緩衝單元107則是線性滑軌緩衝單元1072,以減緩擋件105受重力向下位移時的速度,如此,可降低髒污產生的機率。所述線性滑軌可設置在中空部件103,以使擋件105與中空部件103連接,或者,線性滑軌也可以與腔體101連接,以使擋件105與腔體101連接。Please refer to FIG. 3, which is a schematic diagram of the stopper of the embodiment of the present invention. In one embodiment, the
所述原子層沉積裝置1還具有升降裝置108,而升降裝置108連接加熱台102。當升降裝置108驅動加熱台102與載盤106靠近中空部件103時,載盤106可接觸自然垂落的擋件105,並帶動擋件105垂直向上位移。具體而言,載盤106接觸擋件105的接觸部1051並帶動擋件105垂直位移,以使擋件105與載盤106圍繞出反應空間S1。The atomic
請參照圖4與圖5,圖4是本新型實施例的擋件的俯視示意圖,而圖5是本新型實施例的擋件的立體示意圖。具體而言,擋件105接觸部1051為環形圈體,而擋件105還包括複數連接桿1052,連接桿1052位於阻擋部1053與接觸部1051之間,且多個連接桿1052平均地配置並連接接觸部1051。當升降裝置108驅動加熱台102與載盤106靠近中空部件103時,載盤106會接觸擋件105的接觸部1051並帶動擋件105向上位移,而擋件105則形成牆面並與載盤106圍繞出反應空間S1。所述前驅物G101可被保留在反應空間S1中以與基材W反應,而不需對腔體101提供填充容置空間S的前驅物G101使用量,故可節省前驅物G101的用量。Please refer to FIGS. 4 and 5. FIG. 4 is a top view of the stopper according to an embodiment of the present invention, and FIG. 5 is a perspective view of the stopper according to an embodiment of the present invention. Specifically, the
透過升降裝置108調整升降裝置108與中空部件103之間的距離,可控制反應空間S1的大小,如此,可調控前驅物G101對基材W沉積時的基材W的均勻度。具體而言,小空間的反應空間S1可降低前驅物G101的擾流,前驅物G101可緩慢而穩定地被中空部件103抽離,如此,可使基材W受前驅物G101沉積後的均勻度提高。By adjusting the distance between the lifting
再者,還可透過中空部件103、載盤106與擋件105形成上抽氣路徑,以引導過剩的前驅物G101被抽離腔體101,有別於傳統沉積設備只可透過底部抽氣口抽除過剩的前驅物G101。藉由本新型所述的原子層沉積裝置的結構設計,可使過剩的前驅物G101形成穩定而緩慢的氣流,以使基材W可受到前驅物G101均勻地沉積。Furthermore, the
所述原子層沉積裝置1還可以具有開口1012,流體連通容置空間S,並用以將氣體G導入腔體101與擋件105之間。具體而言,氣體G是不與前驅物G101反應的氣體,例如氮氣或惰性氣體。如圖1所示,開口1012可設置在腔體101的頂部,而氣體G被導入到腔體101與擋件105之間,以形成氣牆,並防止前驅物G101沉積於擋件105。在一個實施例中,氣體G被導入到腔體101與擋件105的阻擋部1053之間,但本新型不以此為限制,氣體G也可以透過開口2012被導入到腔體101與擋件105的連接桿1052之間,或被導入到腔體101與擋件105的接觸部1051之間。在其他實施例中,開口1012也可以設置在腔體101的側邊,並通入氣體G於腔體101與擋件之間。The atomic
在一個實施例中,原子層沉積裝置1還包括抽氣口1011,流體連通腔體101,且抽氣口1011與前驅物進氣口104彼此相對,並用以排出容置空間S內的至少一流體,其中流體可能是空氣、滌洗氣體、前驅物或為製程開始之前所留在容置空間S中的任何物質。在一個實施例中,抽氣口位於腔體101的底部,且連接泵。當抽氣口1011對腔體101下抽氣時,可形成一下抽氣路徑。當抽氣口1011與前驅物進氣口104彼此相對的配置,也可提升對前驅物G101或滌洗氣體的流動控制。In one embodiment, the atomic
請參照圖6,圖6是本新型再一實施例的擋件的立體示意圖。在一個實施例中,擋件205的接觸部2051還包括複數開孔O2051,以在抽氣口1011排出容置空間S內的流體時,調節流體的流動。具體而言,可設計不同數量與/或不同大小的開孔O2051,來調整下抽氣時流體的流速與流量。Please refer to FIG. 6. FIG. 6 is a perspective view of a stopper according to still another embodiment of the present invention. In an embodiment, the
在一個實施例中,原子層沉積製程的步驟可如下所述。首先,透過抽氣口1011對腔體101的容置空間S抽氣,而升降裝置108驅動加熱台102、載盤106與擋件105、205垂直向上位移,使載盤106與擋件105、205圍繞出反應空間S1。當擋件105的接觸部1051不具有開孔O2051時,容置空間S內的流體可自載盤106與擋件105之間的縫隙被抽氣口1011抽離。當擋件205的接觸部2051具有開孔O2051時,容置空間S內的流體還可自開孔O2051被抽氣口1011抽離。In one embodiment, the steps of the atomic layer deposition process can be described as follows. First, the accommodating space S of the
接著,前驅物G101透過前驅物進氣口104被提供至腔體101的容置空間S,並擴散到基材W上方以與基材W表面的材料進行反應與沉積。當前驅物G101注入腔體101達到目標量後(根據製程參數以決定目標量),前驅物進氣口104停止供應前驅物G101到腔體101。Next, the precursor G101 is provided to the accommodating space S of the
接著,滌洗氣體(例如但不限制為氮氣)被提供至腔體101的容置空間S,以對前驅物G101進行滌洗(purge),同步地,透過中空部件103、載盤106與擋件105、205所形成的反應空間S1及上抽氣路徑,可將腔體101內的前驅物G101抽離。Next, a scrubbing gas (for example, but not limited to nitrogen) is provided to the accommodating space S of the
具體而言,前驅物G101多數存在於反應空間S1,並藉由連接中空部件103的泵將前驅物G101緩慢地抽離,使前驅物G101呈現慢速流場。如此,前驅物G101可以動態的方式對基材W進行反應與沉積。同樣地,滌洗氣體的流場也可受到穩定地控制。Specifically, most of the precursor G101 exists in the reaction space S1, and the precursor G101 is slowly drawn off by the pump connected to the
當腔體101內的前驅物G101與滌洗氣體呈現慢速的流動,流場將可穩定地被控制,並避免擾流產生,以使基材W受原子層沉積時的均勻度受到良好的控制。When the precursor G101 and the scrubbing gas in the
在其他實施例中,中空部件對腔體101的容置空間S抽氣,也可以與抽氣口1011對腔體101的容置空間S抽氣同步進行,即,對基材W沉積之前,可同步透過抽氣口1011與中空部件103對腔體101的容置空間S抽氣。In other embodiments, the hollow member pumping air to the accommodating space S of the
接著,請參照圖7,圖7是本新型又一實施例的原子層沉積裝置的示意圖。所述原子層沉積裝置2與前述實施例大致相同,差別僅在原子層沉積裝置2的擋件105的接觸部1051還包括遮擋環,以及原子層沉積裝置2還包括馬達109。Next, please refer to FIG. 7, which is a schematic diagram of an atomic layer deposition apparatus according to another embodiment of the present invention. The atomic
所述遮擋環R1051相鄰載盤106,並用以密合擋件105與載盤106之間的縫隙,以在擋件105與載盤106圍繞出反應空間S1時,減少前驅物G101自擋件105與載盤106之間洩漏。所述遮擋環R1051可應用於前述實施例。同樣地,擋件105可以是包括或不包括開孔O2051。The shielding ring R1051 is adjacent to the
具體而言,原子層沉積裝置2包括腔體101、加熱台102、載盤106、擋件105、馬達109、至少一中空部件103以及前驅物進氣口104。所述馬達109連接擋件105,具體而言,馬達109連接擋件105的阻擋部1053,並用以驅動擋件105垂直位移,以使擋件不僅僅受重力或升降裝置108間接地帶動而位移。當透過馬達109調整擋件105的位置,可進一步調控腔體101內的流體的流動。Specifically, the atomic
在一個實施例中,開口2012是設置在腔體101的側邊,而氣體G被導入到腔體101與擋件105之間,以形成氣牆,並防止前驅物G101沉積於擋件105。舉例而言,氣體G被導入到腔體101與擋件105的接觸部1051之間,但本新型不以此為限制,氣體G也可以被導入到擋件105的任意處與腔體101之間。或者,開口2012也可以設置在腔體101的頂部。In one embodiment, the
在一個實施例中,原子層沉積製程的步驟可如下所述。首先,透過抽氣口1011對腔體101的容置空間S抽氣,升降裝置108驅動加熱台102、載盤106與擋件105垂直向上位移,而馬達109驅動擋件105垂直向下位移。所述載盤106與擋件105之間可具有或不具有縫隙,並透過調整升降裝置108與/或馬達109的移動或驅動力,以控制縫隙大小,藉此調整容置空間S內的流體的流量與流速。In one embodiment, the steps of the atomic layer deposition process can be described as follows. First, the accommodating space S of the
接著,前驅物G101透過前驅物進氣口104被提供至腔體101的容置空間S,並擴散到基材W上方以與基材W表面的材料進行反應與沉積,而馬達109可驅動擋件105位移,以調整前驅物G101的流動。舉例而言,當馬達109驅動擋件105位移,使載盤106與擋件105之間具有縫隙時,前驅物G101可被抽氣口1011抽離。藉由調整縫隙大小,以調控前驅物G101的流量與流速。Next, the precursor G101 is provided to the accommodating space S of the
當前驅物G101注入腔體101達到目標量後(根據製程參數以決定目標量),前驅物進氣口104停止供應前驅物G101到腔體101。After the precursor G101 is injected into the
接著,滌洗氣體(例如但不限制為氮氣)被提供至腔體101的容置空間S,以對前驅物G101進行滌洗(purge),同步地,透過中空部件103、載盤106與擋件105所形成的反應空間S1及上抽氣路徑,可將腔體101內的前驅物G101抽離。同樣地,馬達109可驅動擋件105位移,以調整前驅物G101的流動。舉例而言,當馬達109驅動擋件105位移,使載盤106與擋件105之間具有縫隙時,前驅物G101可同時被抽氣口1011與中空部件103抽離。藉由調整縫隙大小,以調控前驅物G101的流量與流速。Next, a scrubbing gas (for example, but not limited to nitrogen) is provided to the accommodating space S of the
同樣地,前驅物G101可以動態的方式對基材W進行反應與沉積,而滌洗氣體的流場也可受到穩定地控制。當腔體內的前驅物G101與滌洗氣體呈現慢速的流動,流場將可穩定地被控制,並避免擾流產生,以使基材W受原子層沉積時的均勻度受到良好的控制。Similarly, the precursor G101 can react and deposit the substrate W in a dynamic manner, and the flow field of the scrubbing gas can also be stably controlled. When the precursor G101 and the scrubbing gas in the cavity exhibit a slow flow, the flow field can be stably controlled and the generation of turbulence can be avoided, so that the uniformity of the atomic layer deposition of the substrate W is well controlled.
同樣地,在其他實施例中,中空部件對腔體101的容置空間S抽氣,也可以與抽氣口1011對腔體101的容置空間S抽氣同步進行,即,對基材W沉積之前,可同步透過抽氣口1011與中空部件103對腔體的容置空間S抽氣。Similarly, in other embodiments, the hollow member pumping air to the accommodating space S of the
所述原子層沉積裝置1、2還可包括遮蔽件110與至少一進氣口1013,所述遮蔽件110設置於容置空間S內,並遮擋部分腔體101的內表面 S0,且遮蔽件110與腔體101的內表面S0之間具有間隙,而間隙連通容置空間S。所述進氣口1013位於腔體101的內表面S0,且遮蔽件110遮蔽進氣口1013,而進氣口1013用以將氣體G導入遮蔽件110與腔體101的內表面S0之間,使得氣體G擴散到遮蔽件110與腔體101之間的間隙,並經由間隙擴散到腔體101的容置空間S,其中氣體G例如但不限制為氮氣或惰性氣體。The atomic
具體而言,所述內表面S0包括內牆面S2與內底面S3,遮蔽件110遮擋部分內牆面S2及部分內底面S3,而氣體G則經由進氣口1013導入並擴散到遮蔽件110與內牆面S2之間的間隙,及擴散到遮蔽件110與內底面S3及內牆面S2之間的間隙,並經由間隙擴散至容置空間S。Specifically, the inner surface S0 includes an inner wall surface S2 and an inner bottom surface S3, the shielding
透過進氣口1013於腔體101的內表面S0與遮蔽件110之間通入氣體G,使氣體G流通於內表面S0與遮蔽件110之間後,再進入腔體101的容置空間S以產生正壓,以輔助多數的未反應前驅物G101被抽氣口1011與/或中空部件103抽除。殘餘少量之未反應前驅物G101則可黏附於遮蔽件110而非附著於腔體101的內表面S0,以降低腔體101內的髒污累積,進而延長腔體101壽命並使設備的清潔週期可被延長。Gas G is introduced between the inner surface S0 of the
所述原子層沉積裝置1、2與使用其的製程方法的效果請參照表1與表2,表1為經原子層沉積製程並長20奈米薄膜的晶圓厚度表,如表1所示,晶圓的厚度均勻度為0.368並達到良好的效果。表2為經原子層沉積製程並長120奈米薄膜的晶圓厚度表,如表2所示,晶圓的厚度均勻度為0.407並達到良好的效果。
綜合以上所述,相較於習知技術,本新型實施例所述之原子層沉積裝置之技術效果,係說明如下。In summary, compared with the prior art, the technical effects of the atomic layer deposition apparatus according to the embodiment of the present invention are described as follows.
習知技術中,原子層沉積製程多使用大型腔體並通入大量反應前驅物以對基材進行反應與沉積,故使製程之成本較高,而傳統的降低成本的方法是縮減腔體的容積,但此方法常造成前驅物於腔體內部產生擾流,導致基材受沉積後的均勻度不佳。反觀本新型所述之原子層沉積裝置,可透過中空部件、擋件與載盤形成反應空間,以節省製程前驅物的用量,並透過中空部件抽氣使前驅物形成穩定慢速且均勻的流場,以優化基材受沉積後的均勻度。In the prior art, the atomic layer deposition process mostly uses a large cavity and passes a large amount of reaction precursors to react and deposit the substrate, so the cost of the process is higher, and the traditional method to reduce the cost is to reduce the cavity. However, this method often causes the precursor to produce turbulence inside the cavity, resulting in poor uniformity of the substrate after deposition. On the other hand, the atomic layer deposition device of the present invention can form a reaction space through the hollow part, the stopper and the carrier plate, so as to save the amount of the process precursor, and the hollow part is pumped to make the precursor form a stable, slow and uniform flow. Field to optimize the uniformity of the substrate after deposition.
本新型在上文中已以較佳實施例揭露,然熟習本項技術者應理解的是,上述實施例僅用於描繪本新型,而不應解讀為限制本新型之範圍。應注意的是,舉凡與前述實施例等效之變化與置換,均應設為涵蓋於本新型之範疇內。The present invention has been disclosed in preferred embodiments above. However, those familiar with the art should understand that the above-mentioned embodiments are only used to describe the present invention and should not be interpreted as limiting the scope of the present invention. It should be noted that all changes and substitutions equivalent to the foregoing embodiments should be included in the scope of the present invention.
1:原子層沉積裝置
101:腔體
1011:抽氣口
1012:開口
1013:進氣口
102:加熱台
103:中空部件
104:前驅物進氣口
1041:噴頭
105、205:擋件
1051:接觸部
1052:連接桿
1053:阻擋部
106:載盤
107:緩衝單元
1071:彈簧
1072:線性滑軌緩衝單元
108:升降裝置
109:馬達
110:遮蔽件
G:氣體
G101:前驅物
O103:抽氣孔
O2051:開孔
R1051:遮擋環
S:容置空間
S0:內表面
S1:反應空間
S2:內牆面
S3:內底面
W:基材
1: Atomic layer deposition device
101: Cavity
1011: Exhaust Port
1012: opening
1013: air inlet
102: heating table
103: Hollow parts
104: Precursor air inlet
1041:
圖1是本新型實施例的原子層沉積裝置的示意圖。Fig. 1 is a schematic diagram of an atomic layer deposition apparatus according to an embodiment of the present invention.
圖2是本新型另一實施例的原子層沉積裝置的示意圖。Fig. 2 is a schematic diagram of an atomic layer deposition apparatus according to another embodiment of the present invention.
圖3是本新型實施例的擋件的示意圖。Fig. 3 is a schematic diagram of the stopper of the embodiment of the present invention.
圖4是本新型實施例的擋件的俯視示意圖。Fig. 4 is a schematic top view of the stopper of the embodiment of the present invention.
圖5是本新型實施例的擋件的立體示意圖。Fig. 5 is a three-dimensional schematic diagram of the stopper of the embodiment of the present invention.
圖6是本新型再一實施例的擋件的立體示意圖。Fig. 6 is a three-dimensional schematic diagram of a stopper according to still another embodiment of the present invention.
圖7是本新型又一實施例的原子層沉積裝置的示意圖。Fig. 7 is a schematic diagram of an atomic layer deposition apparatus according to another embodiment of the present invention.
1:原子層沉積裝置 1: Atomic layer deposition device
101:腔體 101: Cavity
1011:抽氣口 1011: Exhaust Port
1012:開口 1012: opening
1013:進氣口 1013: air inlet
102:加熱台 102: heating table
103:中空部件 103: Hollow parts
104:前驅物進氣口 104: Precursor air inlet
1041:噴頭 1041: print head
105:擋件 105: stop
1051:接觸部 1051: Contact
1052:連接桿 1052: connecting rod
1053:阻擋部 1053: blocking part
106:載盤 106: Disk
107:緩衝單元 107: Buffer unit
1071:彈簧 1071: Spring
108:升降裝置 108: Lifting device
110:遮蔽件 110: Shield
G:氣體 G: gas
G101:前驅物 G101: Precursor
O103:抽氣孔 O103: Exhaust hole
S:容置空間 S: accommodating space
S0:內表面 S0: inner surface
S1:反應空間 S1: reaction space
S2:內牆面 S2: inner wall
S3:內底面 S3: inner bottom surface
W:基材 W: Substrate
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US11685996B2 (en) * | 2021-03-05 | 2023-06-27 | Sky Tech Inc. | Atomic layer deposition device |
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