TWM577850U - Chlorine dioxide gel composition production system and chlorine dioxide aqueous solution production system - Google Patents

Abstract

The present invention provides a chlorine dioxide gel composition production system comprising: an electrolytic cell, a condensation device, a first ion adsorption device, at least one mixing tank, a gel supply unit, and at least one mixing unit. The present invention further provides a chlorine dioxide gel composition production system comprising: a chlorine dioxide supply unit, a first ion adsorption device, a gel supply unit, and at least one mixing unit. The present invention further provides a chlorine dioxide aqueous solution production system comprising: an electrolytic cell, a condensation device, a first ion adsorption device, and at least one mixing tank.

Description

Chlorine dioxide gel composition production system and chlorine dioxide aqueous solution production system

The present invention relates to a chlorine dioxide gel composition production system and a chlorine dioxide aqueous solution production system, and more particularly to an aqueous chlorine dioxide solution which is produced by an electrochemical method or a salt electrolysis method and has harmful products which are harmful to human body. The treatment makes the concentration of the chlorine dioxide aqueous solution produced by electrolysis greatly increased, and the by-products are greatly reduced; and the chlorine dioxide gel composition after mixing with the gel is also a high-concentration, food-grade chlorine dioxide gel combination. Production system and chlorine dioxide aqueous production system.

At present, the by-product of the technology of producing chlorine dioxide by salt electrolysis is chlorite (ClO ^2- ). The process can be gradually improved to reduce the amount produced, but there are other by-products such as chlorine which are carcinogenic to organisms. Acid (ClO ^3- ), hydrogen peroxide (H ₂ O ₂ ). Further, the chlorine (Cl) content is too high, and the chlorine dioxide purity of the chlorine dioxide aqueous solution product is also unstable and needs to be improved. At present, the finished product of chlorine dioxide aqueous solution on the market is non-edible grade (purity is about 50%), and the heavy metal standard contained in it is not strictly regulated by environmental protection laws and regulations, resulting in the chlorine dioxide aqueous solution containing harmful to the human body. The compound is a carcinogen such as chlorate (ClO ^3- ), chlorite (ClO ^2- ), hydrogen peroxide (H ₂ O ₂ , as described above), and residual chlorine as mentioned above. Furthermore, although the purity of chlorine dioxide produced by electrochemical method can reach more than 95%, the remaining chlorine content is still about 4%, and the key raw material required for electrochemical method is sodium chlorite for oil production. The by-products and key production technologies are in a small number of countries and enterprises, and it is easy to have doubts about the monopoly of raw materials.

Today, chlorine dioxide related products are mostly in barrels. However, the barreled chlorine dioxide aqueous solution is very inconvenient to transport. Whether it is land freight, air or sea freight, the shipping process may be caused by accidentally knocking over the whole barrel. Reimbursement; or, because of the impact of the transportation process, the temperature changes drastically, resulting in changes or loss of composition; or, due to the safety regulations of air transport, it is impossible to transport a large amount of finished chlorine dioxide solution. On the other hand, large-scale refrigerating devices (or large-scale refrigerating devices) for storing vegetables, fruits, and meats, medium-sized refrigerating (freezing) equipment used in the vegetable market, or electricity used in small households, whether it is a general selling place or not. In the refrigerator and freezer of the refrigerator, the food stored at low temperatures will have problems with mildew and breeding of fruit flies. The reason is that a small number of bacteria and viruses can still grow at low temperatures, such as norovirus, so that the aforementioned equipment is very unclean for a long time. In addition, the above-mentioned onshore freight, air, and sea freight freezing devices are usually loaded with various foods, plants, and meat, and also cause the danger of specific bacteria and viruses spreading to the human body or pets.

Chlorine dioxide is a Class A1 safe and efficient physical disinfection deodorant recommended by the World Health Organization and the World Food Organization. It can effectively sterilize and deodorize it by its strong oxidizing ability. Different from the traditional chlorine gas is the addition or substitution reaction with the reactants. Chlorine dioxide itself is a strong oxidant composed of two oxygen atoms, one oxygen atom combined with 19 electrons. The outermost electronic orbital domain has an unpaired pair. The active free electrons are selective due to a special single electron transfer mechanism. When they encounter the organic molecular group in the outer electron domain of the periphery of the processed object, they strongly absorb an electron and become a chlorinated ion. In order to cause irreversible oxidative damage and decomposition. Chlorine dioxide oxidizes microorganisms such as bacteria, viruses, insect proteins, fats and nucleic acids to achieve deactivation. The principle is to oxidize and decompose amino acids to achieve deactivation. Sexuality has no harmful effects on higher animals or plant cells of twin cells, thus achieving the purpose of disinfection and deodorization. On the other hand, chlorine dioxide molecules do not allow microorganisms to develop resistance or variants. Therefore, chlorine dioxide can be completely and effectively used for the physical removal (non-chemical) of the aforementioned microorganisms, bacteria, viruses.

However, since the general purity of chlorine dioxide is only about 50% and is non-edible (including various carcinogens and impurities mentioned above), it cannot be used in the above-mentioned frozen equipment for storing food, and is liquid. In addition to the problem of the above solution being overturned, chlorine dioxide may also have a pungent problem, and there are still many inconveniences placed in the refrigerator.

Furthermore, in the hospital ward environment, in order to prevent the spread of germs, the cleaning staff often uses bleach to disinfect, so that the hospital will smell a strong smell. However, there are still many germs in the air of the hospital that cannot be sterilized by the above-mentioned liquids. It may not be harmful in the general area of the hospital, but if it is in the intensive care unit, negative pressure ward and other intensive care units, in the air. The existence of a specific pathogen is a big problem. On the other hand, in the medical field, so-called alcohol products such as alcohol cotton sheets are commonly used for disinfection. However, current research has found that when high-concentration alcohol comes into contact with bacteria, it will form a layer on the surface of certain types of bacteria. The membrane prevents alcohol from entering the interior of the bacteria and does not completely destroy the bacteria. Furthermore, although 70% to 80% of alcohol is absorbed by the cell membrane to achieve bactericidal effect. However, if the alcohol concentration is below 70%, it cannot be effectively sterilized. In addition, although alcohol can cope with some pathogens and viruses, it is not effective for viruses such as enteroviruses that do not have a mantle or a superbug that is resistant in hospitals. In addition, in the case of wound dressing, such as burns, or general wounds, if the general dressing is coated with hydrogen peroxide, it will be irritating to the wound and harmful to the skin and not suitable for disinfection of the skin tissue, and as mentioned above, alcohol The type of sterilization is limited; it usually contains a special formula of ointment. Its bactericidal mechanism may cause problems of drug resistance, and the bacteria may be transformed to form another unknown pathogen.

In the aquaculture industry, after the feed water precipitated in the culture pond is allowed to stand for a period of time, it will start to ferment and produce chemical mutations, releasing toxic substances and rapidly deteriorating the water quality; and the number of micro-bacteria precipitated in the bottom fermentation is rapidly multiplying. The oxygen and nutrients are shared with the aquatic organisms, and the nitrous acid, hydrogen sulfide and ammonia are accumulated in excess, which ultimately makes the water body unable to survive and cause the whole pond to die. Therefore, the use of high purity, non-toxic and pH-neutral chlorine dioxide is currently the trend in the aquaculture industry. On the other hand, in the treatment of tap water, the tap water field is also the main component of the use of chlorine dioxide as a disinfecting water body. However, the existing tap water field still uses the salt electrolysis method as the production method of chlorine dioxide added for tap water. However, such chlorine dioxide will produce carcinogens such as chlorate (ClO ₃ ^- ), chlorite (ClO ₂ ^- ), hydrogen peroxide (H ₂ O ₂ ) and chlorine (Cl) in the production process. by-product.

Furthermore, in terms of food hygiene and safety, if chlorine dioxide is to be used as a food additive, the purity of chlorine dioxide needs to be 95% or more and 2% or less of residual chlorine in accordance with the regulations of relevant international agencies. On the other hand, the export of aquatic products and meat from the EU is banned by chlorine, ozone and ultraviolet lamps. The use of chlorine dioxide for food hygiene is clearly a mainstream trend in the future. However, most of the chlorine dioxide currently on the market is produced by salt electrolysis, and its by-products are such as the production of chlorate (ClO ₃ ^- ), chlorite (ClO ₂ ^- ), hydrogen peroxide (H ₂ O ₂ ), and The chlorine (Cl) content is too high (52% to 55%), and the purity of the chlorine dioxide produced is about 48% to 52%, which makes the purity of the product unstable with the pH (the acidity is too high). Therefore, it is not possible to comply with the EPA's specifications for food additives. In addition, chlorite and chlorate react rapidly in water or in moist human tissues, and ingestion or ingestion of chlorite or chlorate may cause irritation in the mouth, esophagus or stomach. Low concentrations of chlorine can cause irritation to the nose, throat and eyes, while higher concentrations of chlorine can cause changes in breathing rate, coughing and damage to the lungs. The harm of hydrogen peroxide is long-term and chronic. Although there is no immediate danger of low concentration of hydrogen peroxide, there is still a carcinogenic crisis in long-term consumption. In other words, today's salt electrolysis process produces the aforementioned four major possible carcinogenic by-products, posing a major crisis for human food safety.

In addition, the current industry test for chlorine dioxide is still measured by a spectrophotometer, and the spectrophotometer itself still has a fascination (or stray light) due to poor design of the instrument and easily affects the measurement accuracy of the absorption spectrum of the substance. Because the aforementioned fading will reduce the linear range of the luminometer and reduce the absorbance. In addition, the electronic circuit design of the spectrophotometer itself also affects the amount of noise coupled to the transmitted signal, thereby affecting the accuracy of the measurement and reducing the sensitivity of the instrument. However, internationally, it has been modified many years ago to measure the purity of chlorine dioxide, whether high concentration (10 to 100 mg/L) or low concentration (0.1 to 10 mg/L), in other words, food safety, by iodometric method. Considerations for aquaculture and drinking water hygiene practices have been directed towards testing techniques that can detect traces of chlorine dioxide by-product residues. In other words, in the context of the continuous development of techniques for the detection of traces of chlorine dioxide and its by-products, there is an urgent need for methods and systems for producing high purity chlorine dioxide. In addition, countries around the world decided to use the five-step iodometric method as a test technique to detect the purity of chlorine dioxide, and have been researching and discussing the inspection technology for detecting the purity of chlorine dioxide in the past few years.

In addition, in terms of the by-products produced by chlorine dioxide itself in the sterilization process, the disinfection by-product is defined as a substance produced by the reaction of a disinfectant, a chemical agent or a chemical oxidant with a precursor substance in water in the treatment of drinking water. Disinfection by-products, the substances produced under different reaction conditions are also different. At present, the known organic by-products of chlorine dioxide in water are copper, aldehydes and acids. The main inorganic by-products also contain chlorate (ClO ₃ ^- ), chlorite (ClO ₂ ^- ), chlorine, in the existing In the tap water disinfection system, chlorite is the main reaction end product, about 50% to 70% of chlorine dioxide is converted into chlorite; and about 30% of chlorate, chlorine and chloride ions are formed. Chlorate and chlorite may affect the oxygen-carrying function of heme and the detoxification function of red blood cells. On the other hand, when low-purity chlorine dioxide is used, low-purity chlorine dioxide also causes a reduction reaction of the chlorate to lower the purity and fail to achieve the desired disinfecting effect.

On the issue of food safety, there were news reports that pesticide residues in vegetables and fruits exceeded the standard. Or, there are doubts about nuclear ray residues in food imports from nuclear-hazard areas in Japan. In addition, there are problems in the export of bananas to the blackened outer skin of the whole batch of containers, and the import of whole batches of tea to the extent that no pesticide residues have been detected, resulting in damage to the goodwill of domestic farmers.

Therefore, in order to overcome the aforementioned problems, there is no such creation.

The purpose of the present invention is to provide a chlorine dioxide gel composition production system and a chlorine dioxide aqueous solution production system, and the gel raw material used in the process is also a food grade, which is processed by an ion adsorption device to produce The chlorine dioxide gel composition is food grade, thereby allowing the aqueous chlorine dioxide solution to be stored in a gel form for efficient storage and transportation, and also allowing the chlorine dioxide gel composition to be used for storing food. The air outlets of various refrigerating and freezing devices and air-cleaning devices are circulated by the air circulation of the refrigerating and freezing device and the air-cleaning device, and the strong oxidation characteristics of high-purity chlorine dioxide are used to slowly evaporate the chlorine dioxide gel composition. It sterilizes and deodorizes various refrigeration devices and indoor environments, effectively prevents the growth of microorganisms, insects and eggs in the freezing device, and cleans the air in the indoor environment without any side effects and toxicity. It can also be used for disinfection of medical wounds. And maintenance, and effectively prevent wounds from being infected by other bacteria. Benchuang Another object of the invention is to provide a chlorine dioxide aqueous solution production system for removing by-products of chlorine dioxide by a combination of an ion absorption device, a cation adsorption membrane and an intake pipe having a special filtration precision; In the electrolysis operation, the mixing tank can simultaneously filter the residual chlorine dioxide gas therein, thereby solving the problem that the factory worker may inhale the residual chlorine dioxide gas. In addition, another purpose of the creation is to provide a combination of different materials (a material capable of emitting one of far-infrared rays and an ore capable of emitting a small amount of nuclear radiation) in the resonance device, and the material and the ore are detected for nuclear radiation. In the safe range, the chlorine dioxide aqueous solution produced by the salt electrolysis method is treated, and the resonance devices are arranged in parallel and in series according to the amount of the chlorine dioxide aqueous solution to be treated, so that the chlorine dioxide aqueous solution is The electrolytic by-products (carcinogens) are also greatly reduced and degraded, whereby the aqueous chlorine dioxide solution produced by the salt electrolysis method is treated into a non-carcinogenic food-grade food-grade chlorine dioxide aqueous solution and a carcinogen-free food grade. Chlorine dioxide gel composition.

To achieve the foregoing objective, the present invention provides a chlorine dioxide gel composition production system comprising: an electrolytic cell, a condensation device, a first ion adsorption device, at least one mixing tank, a gel supply unit, and at least one Mixing unit. The electrolytic cell is used to produce chlorine dioxide gas. The condensing device is connected to the electrolytic cell by a pipeline for receiving and cooling the chlorine dioxide gas to generate a cooled chlorine dioxide gas. The first ion adsorption device is connected to the condensation device by a line for ion-adsorbing the cooled chlorine dioxide gas to generate an ion-adsorbed chlorine dioxide gas. The at least one mixing tank is connected to the ion absorbing device in a line for receiving and mixing the ion-adsorbed chlorine dioxide gas with pure water to produce an aqueous solution of chlorine dioxide. The gel supply unit is used to provide a gel material. The at least one mixing unit and the at least one mixing tank and the gel supply The unit is connected to mix the aqueous chlorine dioxide solution with the gel raw material to produce a chlorine dioxide gel composition.

In one embodiment, the system further includes a second ion adsorption device connected to the at least one mixing tank by a pipeline for chlorine dioxide overflowing in the at least one mixing tank. The gas is subjected to ion adsorption treatment to produce an ion-adsorbed chlorine dioxide gas. In another embodiment, the system further includes a chloride ion adsorption unit connected to the second ion adsorption device for performing chlorine ion adsorption treatment on the ion-adsorbed chlorine dioxide gas. Produce a harmless gas. In another embodiment, the system further includes an air extraction device, and the overflowed chlorine dioxide gas is introduced into the second ion adsorption device via the pipeline through the air suction device.

In one embodiment, the system further includes at least one resonance device connected to the at least one mixing tank by a pipeline, the at least one resonance device having a material capable of emitting one of far infrared rays and a trace of nuclear radiation At least one of the ores is for receiving the aqueous chlorine dioxide solution and subjecting the aqueous chlorine dioxide solution to a resonance treatment, so that the aqueous chlorine dioxide solution absorbs at least one of far-infrared energy and trace nuclear radiation to reduce the chlorine dioxide. a chlorine-containing by-product of the aqueous solution to produce a resonance-treated aqueous chlorine dioxide solution, wherein the at least one resonance device comprises at least one spiral conduit; the material capable of emitting far infrared rays and the ore capable of emitting a small amount of nuclear radiation are included In the outer periphery of the at least one spiral conduit or the at least one spiral conduit.

In one embodiment, the system has a plurality of mixing tanks and mixing units for receiving different concentrations of the aqueous chlorine dioxide solution and the chlorine dioxide gel composition, respectively.

In one embodiment, the electrolytic cell comprises a positive electrode rod and a plurality of negative metal rod groups, and the plurality of negative metal rod groups are arranged around the positive rod, wherein each negative metal The rod group is composed of at least two metal rods having different electrical resistivities, thereby causing turbulence in the electrolyte in the electrolytic cell. In another embodiment, each of the negative metal rod sets is composed of an aluminum rod and a copper rod.

The present invention further provides a chlorine dioxide gel composition production system comprising: a chlorine dioxide supply unit, a first ion adsorption device, a gel supply unit, and at least one mixing unit. The chlorine dioxide supply unit is provided with an aqueous solution of chlorine dioxide, wherein the aqueous chlorine dioxide solution is produced by salt electrolysis or electrochemical methods. The first ion adsorption device is connected to the chlorine dioxide supply unit for ion-adsorbing the aqueous chlorine dioxide solution to produce an ion-adsorbed chlorine dioxide aqueous solution. The gel supply unit is for providing a gel material. The at least one mixing unit is configured to receive the ion-adsorbed chlorine dioxide aqueous solution from the first ion adsorption device and mix the ion-adsorbed chlorine dioxide aqueous solution with the gel raw material to produce chlorine dioxide Gel composition.

The present invention further provides a chlorine dioxide aqueous solution production system comprising: an electrolytic cell, a condensation device, a first ion adsorption device, and at least one mixing tank. The electrolytic cell is configured to produce chlorine dioxide gas, wherein the electrolytic cell comprises a positive electrode bar and a plurality of negative metal bar groups, and the plurality of negative metal bar groups are arranged around the positive electrode bar, wherein each negative metal bar group is at least Two kinds of metal rods with different resistivities are formed, so that the electrolyte in the electrolytic tank is disturbed. The condensing device is connected to the electrolytic cell by a pipeline for receiving and cooling the chlorine dioxide gas to generate a cooled chlorine dioxide gas. The first ion adsorption device is connected to the condensation device by a line for ion-adsorbing the cooled chlorine dioxide gas to generate an ion-adsorbed chlorine dioxide gas. The at least one mixing tank is connected to the ion absorbing device in a pipeline for receiving and the ion absorbing treatment The chlorine dioxide gas is mixed with pure water to produce an aqueous solution of chlorine dioxide.

1‧‧‧electrolyzer

1', 1", 1'''‧‧‧ chlorine dioxide supply unit

2‧‧‧Condensing device

3, 3'‧‧‧ first ion adsorption device

6‧‧‧Second ion adsorption unit

31‧‧‧ Third ion adsorption device

32‧‧‧fourth ion adsorption device

33‧‧‧ fifth ion adsorption device

7‧‧‧temperature control system

8‧‧‧Resonance device

10, 10' ‧ ‧ storage tank

11‧‧‧Electrode

12‧‧‧Cation adsorption membrane

13, 131, 132, 133, 414, 415, 416‧‧ ‧ spiral circulation channels

1311, 1321, 1331‧‧‧ coolant inlet

1312, 1322, 1332‧‧‧ coolant outlet

14‧‧‧Exhaust pipe

15‧‧‧First direction筏

16‧‧‧Second direction筏

17‧‧‧ Third Direction筏

18‧‧‧Bronze rod

18’‧‧‧Aluminum rod

19‧‧‧ chlorine dioxide output tube

41, 41A, 41B, 41C, 42‧‧ ‧ mixing tank

411‧‧‧ overflow

413‧‧‧Intake pipe

51, 51A, 51B, 51C, 51'‧‧‧ mixed units

52, 52'‧‧‧ gel supply unit

71‧‧‧cooler

72‧‧‧ coolant supply unit

72a‧‧‧Export

72b‧‧‧Return port

73‧‧‧ coolant supply pump

9‧‧‧ chloride ion adsorption unit

P‧‧‧Exhaust device

Figure 1 is a block diagram showing the architecture of an embodiment of the present aqueous chlorine dioxide production system.

Figure 2 is a block diagram showing the architecture of another embodiment of the present aqueous chlorine dioxide production system.

Figure 3 is a block diagram showing the architecture of an embodiment of the chlorine dioxide gel composition production system of the present invention.

Figure 4 is a block diagram showing the architecture of another embodiment of the chlorine dioxide gel composition production system of the present invention.

Fig. 5 is a structural view of the electrolytic cell 1 of the embodiment of the chlorine dioxide aqueous solution production system and the chlorine dioxide gel composition production system of the present invention.

Fig. 6 is a plan view of the electrolytic cell 1 of the embodiment of the production system of the chlorine dioxide aqueous solution production system and the chlorine dioxide gel composition of the present invention.

Fig. 7 is a structural view showing a mixing tank 41 of an embodiment of the present invention for producing a chlorine dioxide aqueous solution production system and a chlorine dioxide gel composition.

Figure 8 is a block diagram showing the architecture of another embodiment of the chlorine dioxide gel composition production system of the present invention.

Figure 9 is a block diagram showing the architecture of another embodiment of the chlorine dioxide gel composition production system of the present invention.

Figure 10 is another implementation of the creation of a chlorine dioxide aqueous solution production system. Schematic diagram of the architecture of the example.

Figure 11 is a schematic diagram of the resonance test of the resonant device 8 of the present invention.

For the sake of a better understanding of the features and functions of the present invention, the same reference numerals are used to refer to the same or equivalent elements in the drawings.

Please refer to the first drawing of the present invention. The system for producing an aqueous chlorine dioxide solution comprises: an electrolytic cell 1, a condensation device 2, a first ion adsorption device 3, a mixing tank 41, and an overflow port 411. a second ion adsorption device 6, a temperature control system 7, and a chloride ion adsorption unit 9. The electrolytic cell 1 is used to produce chlorine dioxide by electrolysis. The chlorine dioxide gas generated in the electrolytic cell 1 is taken out of the electrolytic cell 1 by the action of siphoning by means of a suction device (P in the figure). Thereafter, the condensing device 2 cools the chlorine dioxide gas to generate a temperature-reduced chlorine dioxide gas, so that the chlorine dioxide from the electrolytic cell 1 does not cause an increase in the by-product concentration, resulting in a decrease in the chlorine dioxide concentration. Thereafter, the cooled chlorine dioxide gas is sent to the first ion adsorption device 3 by the action of siphoning by suctioning the suction device. The first ion adsorption device 3 is connected to the condensation device 2, and the chlorine dioxide is subjected to ion adsorption treatment for filtering the ions to physically or chemically filter the ions to make the chlorine dioxide gas. By-products are adsorbed. The mixing tank 41 is connected to the first ion adsorbing device 3 for receiving and mixing the ion-adsorbed chlorine dioxide with pure water to produce an aqueous solution of chlorine dioxide. In another embodiment, the condensing device 2 and the first ion absorbing device 3 in FIG. 1 are also interchangeable to achieve the technical effect of the present invention, and the configurations are also in other embodiments of the present creation. It can be implemented as such. The second ion adsorption device 6 is connected to the mixing tank 41 to perform ion adsorption treatment on the chlorine dioxide gas overflowing in the mixing tank 41 to generate an ion absorption. a treated chlorine dioxide gas; and the chloride ion adsorption unit 9 is connected to the second ion adsorption device 6 for further ion chloride adsorption of the ion-adsorbed chlorine dioxide gas to generate a harmless gas . The air extracting device is connected to the second ion adsorbing device 6 and also provides power for discharging the dissolved chlorine dioxide gas in the mixing tank 41. The second ion adsorption device 6 and the chloride ion adsorption unit 9 are arranged in such a manner that the long-term operation of the air suction device causes the temperature to exceed 11 ° C or more, causing residual chlorine dioxide gas to overflow, so this is required. It is set up to avoid the inhalation of chlorine dioxide gas that may spill out of the nose during the operation of the electrolysis unit and to avoid environmental pollution caused by leakage of chlorine dioxide gas outside the factory.

The structure of the first ion adsorption device 3 and the second ion adsorption device 6 is a titanium-shaped rectangular waterproof and dense type of a box body, and an air inlet is provided below the water level, and the first ion adsorption device 3 and the second ion adsorption device are adsorbed. The device 6 is provided with an air outlet at the uppermost part of the water surface, and the air inlet and the air outlet are arranged on opposite sides and at the high and low positions, and the pure water is adjusted to about 10 to 1 electrolytic waste liquid (or dilute sulfuric acid aqueous solution) to make pure water. It is slightly acidic and is added to the position of the window marking below the air outlet. A magnesium rod is immersed in the electrolysis waste liquid (or dilute sulfuric acid aqueous solution), and the magnesium rod is subjected to ion adsorption of chlorine dioxide gas by passing two positively charged chlorine dioxide under acidic environmental conditions. The magnesium rod is gradually depleted by the ion adsorption, and it is necessary to monitor the window provided by the first ion adsorption device 3 and the second ion adsorption device 6 and replace the magnesium rod in time. The first ion adsorption device 3 and the second ion adsorption device 6 are provided with a safety pressure valve of 7 kg or less for protection of the production system.

The structure of the chloride ion adsorption unit 9 is a waterproof structure of a box titanium plate material. The chloride ion adsorption unit 9 has a movable separation cover plate above the screw, and is fixed by screws and has an air inlet and an air outlet below. The air inlet and the air outlet are arranged in opposite planes and at the upper and lower positions, and a hole mesh plate of about 3 mm is arranged therein, and the left and right sides of the 40 mm below the bottom of the box are welded, and the welding constraint is 30×30 (mm). L-shaped fixing piece, a stencil of about 290 mm×140 mm×3 mm aperture is placed above the fixing piece, and an activated carbon unit is placed above the stencil, and a water-tight perspective window is installed in front of the chloride ion adsorption unit 9 for viewing The activated carbon unit adsorbs changes in chloride ions. Similarly, a pressure safety valve with a low pressure of 7 kg or less is installed above the chloride ion adsorption unit 9 for protection of the production system.

In another embodiment, the present invention is a configuration in which a plurality of the ion absorbing devices 3 can be connected in parallel or in series. Parallel connection of a plurality of the ion absorbing devices 8 can process a larger amount of chlorine dioxide gas at a time in response to a large amount of chlorine dioxide gas; and a plurality of the ion absorbing devices 3 can be connected in series to enhance processing. The effectiveness of the chlorine dioxide gas can more effectively remove chlorine and various by-products in the chlorine dioxide gas in response to an excessive amount of toxic by-products of the chlorine dioxide gas.

Please refer to FIG. 2 of the present invention. The difference between this embodiment and the embodiment of FIG. 1 is that a resonance device 8 and a reservoir 10 are further disposed between the first ion adsorption device 3 and the mixing tank 41. The resonance device 8 is in communication with the mixing tank 41. The resonance device 8 has at least one of an ore capable of emitting one of far-infrared rays and a small amount of nuclear radiation (within a safe range) for accepting salt electrolysis. And generating the chlorine dioxide aqueous solution and subjecting the chlorine dioxide aqueous solution to a resonance treatment, so that the chlorine dioxide aqueous solution absorbs at least one of far-infrared energy and trace nuclear radiation to reduce chlorine-containing by-products of the chlorine dioxide aqueous solution, The resonance-treated aqueous chlorine dioxide solution is stored in the storage tank 10, and the chlorine-containing by-product concentration is 10% or less. Further, the material capable of emitting far infrared rays is a carbon nanotube prepared by calcining graphite at 3000 ° C, and the carbon nanotube can generate far infrared rays of 10 ¹² -10 ¹⁴ HZ / sec; or The material capable of emitting far infrared rays is obtained by refining rare earth elements at 1800 ° C; and the ore comprises at least one of alumina series ceramics, titanium dioxide ceramics, zirconia ceramics and rare earth elements. The storage tank 10 is for storing a resonance-treated aqueous chlorine dioxide solution. Please refer to the following Table 1, Table 2 and Table 3 for the results detected by the Gamma Spectrum Analysis (Pure Detector). The radiation generated by the ore of this creation is within the safe range. The carbon nanotubes do not contain radiation. In another embodiment, the resonant device 8 may also include only the material capable of emitting far infrared rays. Or, in another embodiment, the resonance device 8 may also include only the ore of a small amount of nuclear radiation. Further, as described above, in the embodiment shown in Fig. 2, the electrolytic cell 1 uses chlorine electrolysis to produce chlorine dioxide, and the salt electrolysis method produces chlorine dioxide in the manner of electrode catalysis. The salt water is mainly used as an electrolytic solution. After electrolysis, a mixed gas such as chlorine, chlorine dioxide, hydrogen peroxide or ozone is generated at the anode, and an alkaline waste liquid and hydrogen gas are obtained at the cathode. The concentration of chlorine dioxide in the aqueous chlorine dioxide solution produced by the salt electrolysis method is between 40% and 60% and less than 1000 ppm. This is an industrial grade chlorine dioxide purity, which still contains a large amount of electrolysis in the salt electrolysis method. A large number of by-products produced during the process. Therefore, the present invention causes the aqueous chlorine dioxide solution to absorb at least one of far-infrared energy and trace nuclear radiation via the resonance device, and by-products such as chlorate generated during the electrolysis of the chlorine dioxide mentioned above. ClO ₃ ^- ), chlorite (ClO ₂ ^- ), hydrogen peroxide (H ₂ O ₂ ) and chlorine are removed to produce the treated aqueous chlorine dioxide solution, whereby one of the treated chlorine dioxide aqueous solutions is added The molecular cluster or molecular chain of the product is broken. Furthermore, as previously mentioned, the resonant device 8 is comprised of at least one helical conduit that is set counterclockwise or clockwise depending on the geographic location of use. In an embodiment, if the spiral conduit is a single one, it is integrally formed. In another embodiment, if the spiral conduit is plural, it is dispersed in the resonance device 8. The material capable of emitting far infrared rays and the ore capable of emitting a trace amount of nuclear radiation are included in a periphery of the at least one spiral pipe or in the at least one spiral pipe. In another embodiment, the ore and the material are granulated in a periphery of the at least one spiral conduit or the at least one spiral conduit.

Referring to Table 4, the aqueous chlorine dioxide solution after one treatment by the resonance treatment device 8 is determined by sodium thiosulfate titration and residual chlorine detection in water - spectrophotometry, and the total residual chlorine is 0.03 ppm. It is lower than the 2% standard stipulated in current international regulations.

In another embodiment, the chlorine dioxide gas is subjected to a plurality of treatments (the plurality of the resonance devices 8 are connected in series) by at least one of the material and the ore. The resonant device 8 of the present invention may include at least one of the material capable of emitting far infrared rays and the ore emitting a small amount of nuclear radiation within a safe range. The resonance device of the present invention can perform the foregoing parallel or series arrangement of the plurality of resonance devices by the combination of the ore capable of emitting a far-infrared material, emitting a small amount of nuclear radiation, and at least one of the material and the ore. Salt electrolysis Aqueous chlorine dioxide solutions of various chlorine dioxides of different purity and different pollutant contents are produced. Referring to Table 5, the total residual chlorine of the chlorine dioxide aqueous solution after the resonance treatment of the resonance treatment device 8 is 0.01 ppm, the chlorine removal effect is obviously better, and the purity of the chlorine dioxide can be effectively maintained.

In order to ensure that the chlorine dioxide aqueous solution after the primary, secondary and tertiary treatments of the resonance device 5 has no radiation residual, please refer to FIG. 10, which indicates that the 200 ppm chlorine dioxide aqueous solution is initially passed through the resonance device 8 (first The path of the secondary resonance, B represents the route of the second resonance, and C represents the route of the third resonance. The results of detection of the three-time resonance chlorine dioxide aqueous solution obtained in the D route by the Gamma spectrum analysis method (pure sputum detector) are shown in Table 6. It can be seen from Table 6 that the chlorine dioxide aqueous solution after one to three treatments by the resonance device 8 of the present invention has no radiation residual.

In another embodiment, the inspection report of the aqueous chlorine dioxide solution produced in the embodiment of Figure 1 of the present creation is shown in Table 8. As can be seen from Table 7, the original aqueous solution of chlorine dioxide still contained a small amount of chlorite. As can be seen from Table 8, after treatment by the above-mentioned apparatus of the present invention, by-products such as chlorite have been reduced to no detectable.

Referring to FIG. 3, the difference between this embodiment and the embodiment of FIG. 1 is that a gel supply unit 52 and at least one mixing unit 51 are further provided, wherein the gel supply unit 52 is used to provide a gel material. The mixing unit 51 is connected to the mixing tank 41 and the gel supply unit 52, respectively, for mixing the chlorine dioxide aqueous solution with the gel raw material to produce a chlorine dioxide gel composition. In one embodiment, the gel supply unit 52 provides the gel raw material comprising 82% to 95% by weight of the total weight of the gel raw material, and the weight percentage is between 0.25% and 5%. The thickener, the edible gum with a weight percentage between 4% and 10%, and the essential oil with a weight percentage between 0.25% and 3%. In another embodiment, the concentration of chlorine dioxide in the chlorine dioxide gel composition is between 100 ppm and 3000 ppm. In addition, the gel supply unit 52 includes a heating unit and a cooling unit (not shown). The gel material is first input to the heating unit and heated to be uniformly gelled. The heating unit is steam or Any one of the heating devices performs heating. In an embodiment, the heating unit may also be provided with a spiral surrounding passage for allowing vapor from a vapor supply unit to enter via a steam inlet disposed above the spiral surrounding passage, and then disposed in the spiral surrounding passage. One of the steam outlets below is output. Then, it is input to the cooling unit and cooled to form a chlorine dioxide gel composition which is a carcinogen-free one. Please refer to In the fourth embodiment, the difference between this embodiment and the embodiment of the second drawing of the present invention is that a gel supply unit 52, at least one mixing unit 51 and another storage tank 10 are further provided, so that the two of the mixing tanks 41 The oxidized chlorine aqueous solution is subjected to resonance treatment and stored in the other storage tank 10, wherein the by-products and harmful ions have been reduced to a minimum amount, and then added to the food grade gel provided by the gel supply unit 52, and then mixed into the Chlorine dioxide gel composition.

Further, since the chlorine dioxide gel composition of the present invention is food grade, non-toxic and free of carcinogens, in order to achieve the purpose, the pure water supplied from the mixing tank 41 and the mixing unit 51 is supplied by one pure water. a unit (not shown) is provided, the pure water supply unit is provided with at least one purification unit (not shown), which is made of alumina ceramic, titanium dioxide ceramic or zirconia ceramic, carbon nanotube and rare earth element At least one of the rare earth elements is subjected to multiple calcination and cooling at a high temperature of 2600 ° C to 2800 ° C to remove impurities and have micropores; and the carbon nanotubes are passed through a graphite at 3000 ° C It is made by calcination and used for food grade treatment, and the alumina ceramic, the titania ceramic, the zirconia ceramic and the carbon nanotube are magnetized by generating far infrared rays of 10 ¹² -10 ¹⁴ HZ/sec. Thereby, water molecules clusters of pure water passing through them can be cut and treated by resonance, filtration, ion exchange, etc., and pollutants such as heavy metals, microorganisms, ions and impurities from the water supply source are removed in the process (molecules) Chain is broken The molecular cluster structure is changed and the small molecule is formed. It also removes and purifies bacteria and heavy metals, thereby cutting and processing the water clusters of pure water passing through them by resonance, filtration, ion exchange, and the like. Thereby, the pure water supplied by the pure water supply unit is also made slightly alkaline (pH between 5.5 and 8). The crude chlorine dioxide aqueous solution produced by the foregoing steps has a purity of 96% to 98%, a chlorine content of 2% to 4%, and does not contain chlorate (ClO ₃ ^- ) or chlorite (ClO ₂ ^- Carcinogens such as hydrogen peroxide (H ₂ O ₂ ). In another embodiment, the pure water supply unit of the present invention may further comprise a redox unit, a hydrogen ion potential reduction unit or an acid-base neutralization unit for redox, hydrogen ion potential reduction or acid, respectively. The manner in which the base is neutralized converts the pure water into a slightly alkaline liquid, while the slightly alkaline liquid will not corrode the relevant pipeline of the present creation.

Further, the thickener is an edible grade edible thickener such as sodium carboxymethylcellulose, sodium polyacrylate, corn candy gum, sodium alginate, carrageenan, diammonium phosphate, hydroxypropyl phosphate, and B. Deuterated at least one of adipic acid di starch. The edible gum is a natural animal glue or vegetable glue or a synthetic food grade glue. The essential oils are various plant essential oils such as fruits, herbs, spices, flowers, trees and synthetic essential oils. Further, when the mixing unit 51 performs mixing, the temperature control system 7 maintains the temperature at which the mixing unit 51 is mixed at a specific temperature. The specific temperature is adjusted according to the residual chlorine content of the chlorine dioxide, whereby at the specific temperature, the residual chlorine of the chlorine dioxide aqueous solution is completely vaporized at the moment of mixing with the gel raw material, so that The oxidized chlorine aqueous solution contains no toxic chlorine at all and has a purity of 100% chlorine dioxide. In other words, the chlorine dioxide gel composition of the present invention is a chlorine dioxide gel composition containing almost no by-products.

In another embodiment, the gel supply unit 52 is further configured to provide at least one of an acid/alkaline activator, an absorbent, and a water absorbing resin to the mixing unit 51, the gel raw material comprising the gel raw material. The weight percentage of the total weight is between 80% and 95% pure water, the viscosity percentage is between 0.25% and 5%, the weight percentage is between 4% and 10%, and the weight percentage is between 0.25% and 3 % of essential oil, at least one of 0.05% to 2% by weight of acid/alkaline activator, absorbent and water absorbing resin. a dosage unit (not shown) for controlling output to the acid/alkaline activator, the amount of at least one of the absorbent and the water absorbing resin in the mixing unit 51 or artificially added to produce the oxidizing of the present invention Chlorine gel composition. The acid/alkaline activator, the suction The charge and the water absorbing resin are used to adjust the release rate of the chlorine dioxide gas in the chlorine dioxide gel composition of the present invention. The chlorine dioxide gel composition of the present invention can be placed in any container. And in response to a large, medium, or ultra-small refrigeration device in combination with storing different types of foods, drugs, or articles, at least one of the acid/alkaline activator, the absorbent, and the water absorbing resin is required. The content and ratio are adjusted to meet the actual release rate of chlorine dioxide gas, for example, if it is in the freezer of a slaughterhouse where large quantities of meat are stored, the total amount and release of the chlorine dioxide gel composition used. The rate must be increased to effectively prevent the growth of bacteria and microorganisms in the freezer. In addition, in the air conditioning system of the intensive care unit or clinic of a hospital or medical unit, or in the air outlet, a set of chlorine dioxide gel composition can be placed, so that the strong oxidation effect of chlorine dioxide itself is circulated indoors. The air is disinfected and deodorized to effectively maintain the clean air of the entire medical site.

In another embodiment, the chlorine dioxide gel composition of the present invention for medical, environmental sanitation, animal husbandry, aquaculture has a chlorine dioxide concentration of between 5 ppm and 200 ppm. Preferably, if used in a medical institution such as surgical instruments, sanitary quarantine, wound care, skin diseases, or gynecology, the chlorine dioxide content of the chlorine dioxide gel composition of the present invention is between 20 ppm and Between 100ppm. Preferably, the chlorine dioxide content of the chlorine dioxide gel composition of the present invention is bactericidal and algae-killing for cold air circulation cooling water, disinfection of food hygiene HACCP meat carcass or sterilization of food and beverage products. It is between 20ppm and 50ppm. Preferably, if the disinfection is used in aquaculture, the chlorine dioxide content of the chlorine dioxide gel composition of the present invention is between 20 ppm and 100 ppm depending on the species of the culture. Preferably, for use in the livestock industry, the chlorine dioxide gel composition of the present invention has a chlorine dioxide content of between 20 ppm and 120 ppm. Preferably, in the case of orthopedic disinfection, the use of the A chlorine dioxide gel composition having a chlorine dioxide content of 5 ppm to 15 ppm is used to immerse the affected part of osteomyelitis.

In addition, an embodiment of the present chlorine dioxide gel composition for general dressing is described as follows: the dressing of the present invention has a viscous zone and a venting zone, and a coating zone is coated with the second creation. a oxidized chlorine gel composition, wherein the chlorine dioxide content of the chlorine dioxide gel composition is between 20 ppm and 100 ppm, and the type of the dressing may be gauze, a transparent film dressing, a hydrophilic dressing, and a Alginate dressings, hydrophilic fiber dressings, sponge dressings, antibacterial dressings, collagen-containing dressings, contact dressings, compound dressings, etc., so that today's dressing materials can be further antibacterial, The technical effect of sterilization.

Referring to Fig. 5, the electrolytic cell 1 of the present invention includes an anode, a cathode, and an exhaust pipe 14, and the two electrodes are spaced apart by a high-density transparent film (not shown), and are electrolyzed by a DC power source. The present invention is carried out by a salt electrolysis method or an electrochemical method as described above. The anode itself is provided with a metal mesh and the outer layer thereof is plated with a corrosion-resistant noble metal such as a combination of ruthenium, osmium or a combination of the foregoing metals. This anode is used for electrolysis. The cathode is composed of titanium and may be other conventional metals. The anode is formed into a circular multi-layer coating of the same length and different diameters centered on the main axis, and has a circular multi-layered gap electrolysis net. The electrolytic cell 1 further includes an electrode 11 around which a cation adsorption film 12 is sprayed on the high-density permeable membrane, and the cation adsorption film 12 is used for adsorbing the electrolytic cell. The negatively charged ions, such as chlorate (ClO ^3- ) and chlorite (ClO ^2- ), are used to cause the chlorine-containing by-products contained in the electrolysis process to wait for the negative ions to adsorb.

In addition, referring to FIG. 6, the electrolytic cell includes a positive electrode bar and a plurality of negative electrode metal rod groups, and the plurality of negative electrode metal rod groups are arranged around the positive electrode rod. In the electrolytic production, in order to effectively remove by-products, the anode metal rod group is disposed in the electrolytic cell 1, and each negative metal rod group is composed of at least two metal rods having different resistivities. In one embodiment, the negative metal rod group comprises a material copper rod 6 (18) and an aluminum rod 6 (18'), centered on the positive rod, each 30°, outside the cation adsorption film 12 On the inner circumferential line of the inner side of the electrolytic cell 1, the copper rod 6 is cross-mounted and the aluminum rod 6 is branched, and the length thereof is larger than the length of the cation adsorption film 12 plus 3 cm (as a loss of ion adsorption), the copper rod The diameter of the aluminum rod is equal, and the sum of the diameters of the safe current is greater than the maximum full load current of the electrolysis plus 50% (as a loss consideration for ion adsorption). The negative metal rod is made of a copper rod and is made of a different material from the aluminum rod. Due to the difference in electrical resistivity and electrical resistance, different powers can be generated to generate different temperature differences, so that a turbulent flow can be generated, and the electrolytic cell 1 is driven by the turbulent flow. The electrolyte in the middle can quickly replenish the voids generated by the electrolyte at the moment of generating chlorine dioxide gas. In another embodiment, other metals or alloys or the like may also be used. Each negative metal rod group is composed of three or more metal rods having different resistivities according to actual needs. Because of the specific gravity relationship of the electrolyte, the waste strong alkali liquid is easy to precipitate under the tank, so that when the acidity and alkalinity of the electrolyte is monitored, the pH is lower than the set point, the automatic timing is added to supplement the original electrolyte, and the same amount of waste liquid is discharged at the same time. control. Further, the copper rod and the aluminum rod, in an acidic environment, the copper rod will carry two positive electricity, and the aluminum rod will carry three positive charges, so that by-products generated in the electrolysis such as chlorite ClO ₂ ^- Partial adsorption of carcinogenic by-products such as chlorate ClO ₃ ^- and chloride ion CL ^- .

Referring to FIG. 5, another spoiler generating device for the electrolytic cell 1 is disposed on the outer periphery of the electrolytic cell 1, and includes: a spiral circulation channel 13 which is disposed in the spiral circulation channel 13 The outer circumference of the electrolytic cell 1 and the spiral circulation channel 13 can be divided into a plurality of sections (131, 132, 133) and each of which is provided with at least one coolant inflow port (1311, 1321, 1331). The temperature control system 7 is for providing a coolant when the coolant from the temperature control system 7 When the spiral circulation passages are respectively passed through the coolant inlets (1311, 1321, and 1331), the electrolyte in the electrolytic tank is disturbed. In the electrolysis process, the electrolyte in the electrolytic cell 1 is driven by the turbulence, so that the void generated by the electrolyte at the moment of generating chlorine dioxide gas (product) can be quickly replenished, thereby improving the efficiency of electrolysis. . Thereafter, the coolant outlets 1312, 1322, and 1332 are again discharged to the one of the temperature control systems 7 to be recirculated by the cooler 71. Such a large-area three-stage, independent heat exchange causes the electrolyte in the electrolytic cell 1 to generate different directions and types of turbulence, and the underlying electrolyte is lifted to the periphery of the electrode 11 by the turbulence. Quickly replenish the voids generated by the instantaneous production of the electrolyzed product, thereby producing a chlorine dioxide gas of stable quality, which effectively shortens the process time.

Referring to FIG. 7, the mixing tank 41 is connected to the first ion adsorption device 3 by an air inlet pipe 413. The intake pipe 413 is formed of titanium powder and has a filtration precision of 5 μm to 30 μm and a relative gas permeability coefficient of 5×10 ⁻⁴ L/cm ² minPa, and is used for extracting the cooled chlorine dioxide for pumping. In the process, the cooled chlorine dioxide gas is filtered, and by-products such as residual chlorine-containing by-products, impurities, and the like are removed by filtration. On the other hand, the temperature-treated and ion-adsorbed chlorine dioxide gas treated by the intake pipe 413 which is formed by titanium powder and having a filtration precision of 5 μm to 30 μm enables the molecular weight of chlorine dioxide to be more The solution is combined with the pure water treated by the pure water supply unit in the subsequent treatment of the present invention, thereby effectively reducing the loss of the self-oxidizing ability of the chlorine dioxide gas produced by the present invention when mixed with ordinary pure water. In addition, the present intake pipe 413 having a filtration accuracy of 5 μm to 30 μm is about 2000 times different from a conventional intake pipe having a hole diameter of 2 mm or more, so that the purity of the chlorine dioxide aqueous solution produced by the present invention can be maximized. Jiahua is far superior to the ones that can be achieved by conventional methods. Further, the use of the intake pipe 413 formed by the titanium powder and having a filtration accuracy of 5 μm to 30 μm in the mixing tank 41 can also prevent excessive foaming or excessive generation in the mixing tank 41 as described below after the electrolytic production. Overflow, avoiding one side of production and one waste.

Please refer to FIG. 8. In another embodiment, the mixing tank of the present invention may be a plurality of different concentrations (eg, 3000 ppm, 200 ppm, 100 ppm) of chlorine dioxide aqueous solution (41A, 41B, 41C). The mixing unit of the present invention may also be a plurality of chlorine dioxides having different chlorine dioxide concentrations after being mixed with the gels provided by the gel supply unit 52 in the mixing units 51A, 51B, and 51C, respectively. Production of gel compositions.

In the embodiment of Fig. 9, the chlorine dioxide supply unit 1', 1", 1"' is supplied with an aqueous solution of an aqueous solution of chlorine dioxide produced by an electrochemical method, and a dioxide produced by a salt electrolysis method. a chlorine aqueous solution, a commercially available industrial chlorine dioxide aqueous solution. The first ion adsorption device 3' is connected to the chlorine dioxide supply units 1', 1", 1"' for the aqueous chlorine dioxide solution. Ion adsorption treatment is separately performed to produce different concentrations of chlorine dioxide aqueous solution subjected to ion adsorption treatment. A gel supply unit 52' is used to supply the aforementioned gel material. And at least one mixing unit 51' is configured to receive the different concentrations of the aqueous chlorine dioxide solution from the first ion adsorption device 3' and to mix the same with the gel material to produce a plurality of different concentrations. Oxidized chlorine gel composition.

Referring to FIG. 10, in another embodiment, the difference from the foregoing embodiment is that another storage tank 10 is connected with a third ion adsorption device 31 for once again storing the stored chlorine dioxide aqueous solution at the time of shipment. Ion adsorption treatment. The other mixing tank 42 is for receiving the ion-adsorbed chlorine dioxide gas from the first ion adsorbing device 3, so that the entire production line has two or more routes. Further, the mixing tank 42 treats the stored chlorine dioxide aqueous solution through a fourth ion adsorption device 32 after being output, and then transports it to the storage tank 10' for storage. Thereafter, when the aqueous chlorine dioxide solution stored in the storage tank 10' is to be shipped, it is subjected to a fifth ion adsorption device 33 and another The chloride ion adsorption unit 9 is processed and then transported. The reason for setting in this embodiment is to prevent the chlorine dioxide aqueous solution from being generated by the temperature change and other factors during storage, so that the chlorine dioxide aqueous solution of each storage tank is shipped again by the aforementioned device. deal with.

Next, the overall operation of the present invention will be described. Taking the embodiment of FIG. 3 as an example, the present invention is to set the electrolytic cell 1 and the mixing tank 41 as a group of electrolytic working units, and the electrolysis working unit can be matched with a group of pure The water supply unit, a set of temperature control systems 7, a set of condensing units 2 and a set of first ion sorbing units 3 operate. First, a water supply source supplies pure water to the pure water supply unit for treatment by a water supply pressure pump to be treated as pure water, and is output to the mixing tank 41 and the mixing unit 51, thereby performing electrolysis work and gelation. The pre-operation of pure water during the production of the composition is completed.

In the beginning of the operation of the electrolysis and gel composition of the present invention, the embodiment of Fig. 3 is taken as an example. First, the first direction 筏15 and the second in the electrolytic cell 1 are set according to the characteristics of the electrolyte. After the direction 筏16 and the opening sequence of the third direction 筏17, the coolant is caused to flow through the first spiral circulation channel 131, the second spiral circulation channel 132 and the third spiral circulation channel 133 by the temperature control system 7; Or the electrolyte solution in the electrolytic cell 1 is disturbed by the foregoing negative electrode metal rod group provided in the electrolytic cell 1, and the electrolyte is driven by the turbulence to make the electrolyte generate gas. The voids generated in an instant are quickly replenished, and the high temperature generated in the electrolysis operation is also cooled. The successively produced chlorine dioxide gas is pumped through the chlorine dioxide discharge port 18 to the outside along the chlorine dioxide output pipe 19 by an air pump to the condensing device 2 for cooling, thereby generating a temperature-lowering chlorine dioxide gas. Thereafter, the cooled chlorine dioxide gas is sent to the first ion adsorption device 3 to perform ion adsorption treatment to generate an ion-adsorbed chlorine dioxide gas, and the ion-adsorbed chlorine dioxide gas is passed through the ion-adsorbed chlorine dioxide gas. The intake pipe 413 has a 5 μm to With a filtration accuracy of 30 μm, the negatively charged ions such as chlorine-containing by-products are again subjected to filtration treatment and transported to the mixing tank 41. In the mixing tank 41, the ion-adsorbed chlorine dioxide gas is treated by a gas-liquid mixing mechanism (not shown), and mixed with the treated pure water (slightly alkaline) to produce a dioxide. Chlorine solution (pH value increased from 2.2 to near neutral). When the chlorine dioxide aqueous solution gradually fills the mixing tank 41, it flows through the overflow port 411 to the mixing unit 51 to produce a gel. In the embodiment of Fig. 4, when the aqueous chlorine dioxide solution (produced by salt electrolysis) is gradually filled in the mixing tank 41, the purity and the amount of by-products of the chlorine dioxide produced by the salt electrolysis method are The number and arrangement of the resonance devices are set (in parallel or in series), and then the resonance device 8 is first passed through the overflow port 411 to perform resonance processing, and then flows to the mixing unit 51. Thereafter, the corresponding directional valve (not shown) is opened, and the gel raw material from the gel supply unit 52 is sent to the mixing unit 51 for mixing, and the finished chlorine dioxide gel composition is finished. That is, it is completed and transferred to the refrigerator for storage. The mixing tank 41 and the adjustable temperature sensor disposed by the mixing unit 51 (or the adjustable temperature sensor configured by the electrolytic tank 1 and the second mixing tank 43) if the temperature is higher than a preset value ( Preferably, 8 to 11 ° C, more preferably 2 to 3 ° C, a signaling electronic control device (not shown) is used to cause the coolant supply pump 73 to pump the coolant to cool down, and to flow into the spiral circulation channel for cooling. The flow of the agent is subjected to a spiral circulation of the overall flow cooling until the high temperature message cancellation of the adjustable temperature sensor on the device stops. During the gas production operation of the electrolytic cell 1 and the pumping operation of the air pump, if the electronic control unit device receives the temperature rise message of the adjustable temperature sensor again, the above action will be repeated, and the coolant supply pump 73 will be used to cool the coolant. The pumping is sent to the mixing tank 41 or the mixing unit 51 to cool down. At the same time as the start of the electrolysis operation, the pure water supply unit also re-processes the pure water, and again treats the pure water supplied from the water supply source into a treated pure water and outputs another mixing tank. With the mixing unit, to prepare Another group of electrolysis working units is used with the gel composition production unit. It should be noted that the finished chlorine dioxide gel composition must be stored at a low temperature, and the mixing unit 51 is also equipped with an adjustable temperature sensor (not shown). If the temperature is higher than the preset value, the power is sent. a control device (not shown) for causing the coolant supply pump to pump the coolant to cool down, and the coolant flows through the annular passage provided in the mixing unit 51 for spiral flow-type comprehensive flow cooling until the foregoing The high temperature message cancellation of the tuned temperature sensor stops.

At the same time as the start of the process, the pure water supply unit also re-processes the pure water as described above, and again treats the pure water supplied from the water supply source into a treated and slightly alkaline pure water. The output is output to another mixing tank and mixing unit to prepare another set of process units for use. Similarly, at the same time, the gel supply unit 52 also begins to re-feed in accordance with the foregoing ratio and subject the new batch of gel material to the aforementioned processing steps to prepare for the next stage of the process. With the inventive process, the pure water supply unit first pre-processes the pure water required for the mixing tank 41 of No. 41A (not shown), and then supplies the treated pure water to the mixing tank 41A; and the gel supply unit 41B is then fed in accordance with the aforementioned ratio. At the beginning of the process, the first round of the first stage is performed by the electrolytic cell of the number 41A chlorine dioxide supply unit and the number 1A (not shown) and the gel supply unit 52A; when the electrolytic cell 1A performs the electrolysis operation, The pure water supply unit first pre-processes the pure water required for the mixing tank of No. 41B (not shown), and then supplies another treated pure water to the mixing tank of No. 41B, and starts the re-feeding of the gel supply unit 52B. And the foregoing processing steps are carried out. When the mixing tank of No. 41B is filled with the treated pure water and the gel supply unit 52B is fed and processed, the first round of the processing operation is also completed, so that The next round (second round) phased work is immediately carried out, and so on, there is no waiting time for the entire work process.

Before the production is completed, shipped, stored and stored, the room temperature exceeds the gasification temperature by 11 °C. For example, it is shipped, transported, sent to the outdoor temperature stored in the air-conditioned room, the unit of the air-conditioning room is faulty, and the power is cut off. Wait. In this creation, the chlorine dioxide aqueous solution or the chlorine dioxide gel composition is ion-adsorbed by the plasma adsorption device as the case may be.

The chlorine dioxide aqueous solution and gel composition produced by the foregoing embodiments of the present invention can be used as a degradation of food vegetables, fruit residual pesticides and residual nuclear radiation. There are more than 400 kinds of pesticides on the market, which are divided into water-based and oil-based. The structure of the products is divided into seven categories: (1) organic ammonia pesticides (2) organophosphorus pesticides (3) carbamate pesticides ( 4) Dithiocarbamate pesticides (5) One benzene ring pesticide (6) Two benzene ring pesticides (7) No benzene ring pesticides. As shown in Table 9-1 to Table 9-5, after testing the beet roots in the vegetable market and cleaning the gelled chlorine dioxide solution and the gel composition, the samples were tested for the following 201 pesticide residues. None of the pesticide residues were detected.

Therefore, this creation has the following advantages:

1. Mixing food grade chlorine dioxide solution (concentration 1500-3000ppm, high purity 96%-98%, residual chlorine 4%) with food grade gel to produce food grade chlorine dioxide gel composition via ion adsorption The synergistic effect of the arrangement of the device and the resonance device makes it free of carcinogens or pollutants such as chlorate (ClO ₃ ^- ), chlorite (ClO ₂ ^- ), hydrogen peroxide (H ₂ O ₂ ), etc. The residual chlorine in the aqueous solution of chlorine dioxide is in the range of 10% to 4%, and the chlorine is vaporized at the instant when the gel raw material is mixed with the aqueous chlorine dioxide solution, so that the chlorine dioxide gel composition of the present invention has no chlorine residue. The utility model can be effectively used in various refrigeration equipments and air cleaning devices, and greatly improves the disinfection, deodorization and sterilization effects of the foregoing devices, and the chlorine dioxide gel composition can be used for various refrigeration and freezing devices for storing foods. With the air outlet of the air quiet device, the air circulation of the refrigeration and freezing device and the air quiet device, combined with the strong oxidation characteristics of high-purity chlorine dioxide, allows the chlorine dioxide gel composition to slowly evaporate to various refrigeration devices. Indoor environment Sterilize and deodorize, effectively prevent the air in the freezing device, small insects, eggs and indoor air in the home environment.

2. The edible grade chlorine dioxide aqueous solution is made into a gel type to facilitate the transportation of various land, sea and air freight, and greatly reduces the loss of chlorine dioxide during transportation.

3. The food grade chlorine dioxide gel composition of the present invention (carcinogen-free, dechlorinated and slightly alkaline) is used for various medical dressings, thereby effectively improving the defects caused by the traditional medicine for treating wounds. It also allows the existing various dressings to produce advanced antibacterial and bactericidal effects.

4. By the combination of the different materials in the resonance device of the present invention (as described above, one of the far-infrared rays and one ore that emits a small amount of nuclear radiation), the dioxide generated by the salt electrolysis method The chlorine solution is treated in parallel with the arrangement of the resonance devices in parallel and in series, so that the microorganisms, heavy metals and chemical substances in the treated chlorine dioxide aqueous solution are not only reduced; but also the strong oxidation effect of the chlorine dioxide itself is maintained. Optimized; also causes the electrolytic by-products (carcinogens) of chlorine dioxide itself to be greatly reduced, thereby treating the aqueous chlorine dioxide solution produced by the salt electrolysis process into a food-grade chlorine dioxide aqueous solution and chlorine dioxide. Gel composition.

5. The method and system of the present invention can treat a chlorine dioxide aqueous solution of a lower purity and a higher electrolytic by-product produced by a lower cost salt electrolysis method into a food grade chlorine dioxide aqueous solution and a chlorine dioxide gel. combination. In other words, through the method and system of the present invention, the aqueous chlorine dioxide solution produced by the salt electrolysis method with lower production cost can be processed into a high-value food-grade chlorine dioxide aqueous solution, and has an overall unit life and is good for the human body and food. A variety of unpredictable technical effects such as harmlessness. The ore of this creation has been tested by radiation to confirm that there is no radiation residue in the resonant chlorine dioxide aqueous solution, and it will not cause damage to the operator.

6. The chlorine dioxide generated is treated by the ion absorption device, the cation adsorption film and the inlet pipe having a specific filtration precision, and the ion absorption device can be arranged in parallel or in series to make the dioxide The by-product drop in the aqueous chlorine solution (carcinogen) is minimal, and the strong oxidation effect of chlorine dioxide itself is maintained and optimized.

7. The electrolytic unit of the present invention can simultaneously filter the chlorine dioxide gas remaining or overflowed in the mixing tank during the electrolysis operation, thereby solving the problem that the factory worker may inhale the residual chlorine dioxide gas.

8. The chlorine dioxide aqueous solution and chlorine dioxide gel composition produced by the device of the present invention can be applied to agricultural planting to eliminate insecticides, to replace the traditional pesticides by farmers, and to make underground fertilizers due to resonance small molecules. So that the fertilizer is easily absorbed completely without residual soil, so that the soil acidity and alkalinity, from acid to neutral rapid growth, change the soil without the need to fallow; or because of the resonance of the agricultural land, the groundwater level is raised by the siphon effect To maintain the soil moisture; and to make the crops massaged by the texture tissue, the nutrient absorption is sufficient, increase the yield and early harvest.

The above is a specific embodiment of the present invention and the technical means used therein, and many changes and modifications can be derived therefrom according to the disclosure or teachings herein, and the equivalent changes made according to the concept of the present invention are produced. The role shall not be considered to be within the technical scope of this creation, and shall be preceded by Chen Ming.

According to the content disclosed above, this creation can achieve the intended purpose of creation, providing a chlorine dioxide gel composition production system and a chlorine dioxide aqueous solution production system, which has the value of industrial utilization and practicality. New patent application.

Claims (10)

A chlorine dioxide gel composition production system comprising: an electrolytic cell for producing chlorine dioxide gas; and a condensing device connected to the electrolytic cell by a pipeline for receiving and receiving the chlorine dioxide gas Cooling is performed to generate a chlorine dioxide gas that has been subjected to a temperature-lowering treatment; a first ion adsorption device is connected to the condensation device by a line for ion-adsorbing the cooled chlorine dioxide gas to Producing an ion-adsorbed chlorine dioxide gas; at least one mixing tank connected to the ion absorbing device for receiving and mixing the ion-adsorbed chlorine dioxide gas with pure water Producing an aqueous solution of chlorine dioxide; a gel supply unit for supplying a gel raw material; and at least one mixing unit connected to the gel supply unit and the at least one mixing tank for the aqueous chlorine dioxide solution The gel raw material is mixed to produce a chlorine dioxide gel composition. The chlorine dioxide gel composition production system of claim 1, further comprising a second ion adsorption device connected to the at least one mixing tank by a pipeline The chlorine dioxide gas overflowing in the at least one mixing tank is subjected to ion adsorption treatment to generate an ion-adsorbed chlorine dioxide gas. The chlorine dioxide gel composition production system according to claim 2, further comprising a chlorine ion adsorption unit connected to the second ion adsorption device for the ion adsorption treatment The chlorine dioxide gas is subjected to chloride ion adsorption treatment to produce a harmless gas. The chlorine dioxide gel composition production system according to claim 2, further comprising an air suction device, wherein the overflow chlorine dioxide gas enters the first phase through the pipeline through the air suction device Diion adsorption device. The chlorine dioxide gel composition production system of claim 1, further comprising at least one resonance device connected to the at least one mixing tank by a pipeline, the at least one resonance device having an energy At least one of a material emitting one of far infrared rays and a trace of nuclear radiation for accepting the aqueous solution of chlorine dioxide and subjecting the aqueous solution of chlorine dioxide to resonance treatment, so that the aqueous solution of chlorine dioxide absorbs far infrared energy and trace nuclear radiation At least one of the chlorine dioxide by-products of the aqueous chlorine dioxide solution to produce a resonantly treated aqueous chlorine dioxide solution, wherein the at least one resonant device comprises at least one helical conduit; The material and the ore capable of emitting a trace amount of nuclear radiation are included in a periphery of the at least one spiral conduit or in the at least one spiral conduit. The chlorine dioxide gel composition production system according to claim 1, which has a plurality of mixing tanks and mixing units for respectively receiving different concentrations of the chlorine dioxide aqueous solution and the chlorine dioxide gel composition. . The chlorine dioxide gel composition production system according to claim 1, wherein the electrolytic cell comprises a positive electrode bar and a plurality of negative electrode metal rod groups, and the plurality of negative electrode metal rod groups are arranged around the positive electrode rod. Each of the negative metal rod groups is composed of at least two metal rods having different electrical resistivities, so that the electrolyte in the electrolytic tank is disturbed. The chlorine dioxide gel composition production system according to claim 7, wherein each negative metal rod group is composed of an aluminum rod and a copper rod. A chlorine dioxide gel composition production system comprising: a chlorine dioxide supply unit, which provides an aqueous solution of chlorine dioxide, wherein the aqueous chlorine dioxide solution is produced by salt electrolysis or electrochemical method; a first ion An adsorption device connected to the chlorine dioxide supply unit for ion-adsorbing the aqueous chlorine dioxide solution to produce an ion-adsorbed chlorine dioxide aqueous solution; a gel supply unit for providing a condensation Glue raw material; At least one mixing unit for receiving the ion-adsorbed chlorine dioxide aqueous solution from the first ion adsorption device and mixing the ion-adsorbed chlorine dioxide aqueous solution with the gel raw material to produce dioxide Chlorine gel composition. A chlorine dioxide aqueous solution production system comprising: an electrolytic cell for producing chlorine dioxide gas, wherein the electrolytic cell comprises a positive electrode bar and a plurality of negative electrode metal rod groups, and the plurality of negative electrode metal rod groups surround the positive electrode rod Arrangement, wherein each negative metal rod group is composed of at least two metal rods having different resistivities, thereby causing turbulence in the electrolyte in the electrolytic cell; a condensing device, which is a line and the electrolysis a tank connection for receiving and cooling the chlorine dioxide gas to generate a cooled chlorine dioxide gas; a first ion adsorption device connected to the condensation device by a line for cooling the temperature Treating the chlorine dioxide gas for ion adsorption treatment to generate an ion-adsorbed chlorine dioxide gas; and a mixing tank connected to the ion absorption device for receiving and ion-adsorbing The chlorine dioxide gas is mixed with pure water to produce an aqueous solution of chlorine dioxide.