TWM535711U - System for producing chlorine dioxide gel composition - Google Patents

Description

System for producing chlorine dioxide gel composition

The present invention relates to a system for producing a chlorine dioxide gel composition, and more particularly to a system for producing a purified chlorine dioxide gel composition of a food grade (no carcinogenic by-product) that is completely harmless to the human body.

Today, chlorine dioxide related products are mostly in barrels. However, the barreled chlorine dioxide aqueous solution is very inconvenient to transport. Whether it is land freight, air or sea freight, the shipping process may be caused by accidentally knocking over the whole barrel. Reimbursement; or, because of the impact of the transportation process, the temperature changes drastically, resulting in changes or loss of composition; or, due to the safety regulations of air transport, it is impossible to transport a large amount of finished chlorine dioxide solution.

At present, the by-product of the technology of producing chlorine dioxide by salt electrolysis is chlorite (ClO2-). The process can be gradually improved to reduce the amount produced, but there are other by-products such as chlorate which are carcinogenic to human body ( ClO3-), hydrogen peroxide (H2O2). Moreover, the high content of chlorine (Cl) will also make the chlorine dioxide purity of the chlorine dioxide aqueous solution product unstable and needs to be improved. At present, the finished product of chlorine dioxide aqueous solution on the market is non-edible grade (purity is about 50%), and the heavy metal standard contained in it is not strictly regulated by environmental protection laws and regulations, resulting in the chlorine dioxide aqueous solution containing harmful to the human body. The compound is as described above for chlorate (ClO3-), chlorite (ClO2-), hydrogen peroxide (H2O2, as described above), and carcinogens such as residual chlorine.

On the other hand, large-scale refrigerating devices (or large-scale refrigerating devices) for storing vegetables, fruits, and meats, medium-sized refrigerating (freezing) equipment used in the vegetable market, or electricity used in small households, whether it is a general selling place or not. Refrigerator and freezer in the refrigerator, the food stored at low temperature will have problems with mildew and breeding of fruit flies, because a small number of microorganisms and bacteria can still grow at low temperatures, such as: norovirus, so that the aforementioned Large-scale freezer, medium-sized refrigerating (freezing) equipment, general household refrigerators, and even cold storage equipment for onshore freight, air, and sea transportation are very unclean for a long time. In addition, the above-mentioned onshore freight, air, and sea freight refrigeration devices are usually loaded with various foods, plants, and meat, and also cause the spread of specific bacteria and viruses.

Chlorine dioxide is a Class A1 safe and efficient physical disinfection deodorant recommended by the World Health Organization and the World Food Organization. It can effectively sterilize and deodorize it by its strong oxidizing ability. Different from the traditional chlorine gas is the addition or substitution reaction with the reactants. Chlorine dioxide itself is a strong oxidant composed of two oxygen atoms, one oxygen atom combined with 19 electrons. The outermost electronic orbital domain has an unpaired pair. The active free electrons are selective due to a special single electron transfer mechanism. When they encounter the organic molecular group in the outer electron domain of the periphery of the processed object, they strongly absorb an electron and become a chlorinated ion. In order to cause irreversible oxidative damage and decomposition. Chlorine dioxide oxidizes microorganisms such as bacteria, viruses, insect proteins, fats and nucleic acids to achieve deactivation. The principle is to decompose and deactivate the amino acids of the microorganisms, to the higher animals of the twin cells or Plant cells have no harmful effects, thus achieving the purpose of disinfection and deodorization. On the other hand, chlorine dioxide molecules do not allow microorganisms to develop resistance or variants. Therefore, chlorine dioxide can be completely and effectively used for the physical removal (non-chemical) of the aforementioned microorganisms, bacteria, viruses.

However, since the general purity of chlorine dioxide is only about 50% and is non-edible (including various carcinogens and impurities mentioned above), it cannot be used in the above-mentioned frozen equipment for storing food, and is liquid. In addition to the problem of the above solution being overturned, chlorine dioxide may also have a pungent problem, and there are still many inconveniences placed in the refrigerator.

In the hospital ward environment, in order to prevent the spread of germs, cleaning personnel often use bleach to disinfect, so that when they go to the hospital, they will smell a strong smell. However, there are still many germs in the air of the hospital that cannot be sterilized by the above-mentioned liquids. It may not be harmful in the general area of the hospital, but if it is in the intensive care unit, negative pressure ward and other intensive care units, in the air. The existence of a specific pathogen is a big problem. On the other hand, in the medical field, so-called alcohol products such as alcohol cotton sheets are commonly used for disinfection. However, according to current research, when high-concentration alcohol is in contact with bacteria, a certain type of bacteria may form a surface. The membrane prevents alcohol from entering the inside of the bacteria and cannot completely eliminate the bacteria. Although 70% to 80% of the alcohol is absorbed by the cell membrane to achieve bactericidal effect. However, if the alcohol concentration is below 70%, it cannot be effectively sterilized. In addition, although alcohol can cope with some germs and viruses, there is no bactericidal effect on viruses that have no mantle such as enterovirus or super bacteria that are resistant in hospitals. In addition, in the case of wound dressing, such as burns, or general wounds, if the general dressing is coated with hydrogen peroxide, it will be irritating to the wound and harmful to the skin and not suitable for disinfection of the skin tissue, and as mentioned above, alcohol There are limited types of sterilization; generally, the ointment containing a special formula may cause resistance problems due to its sterilization mechanism, and the bacteria may be transformed to form another unknown pathogen.

Nowadays, the air purifying device commercially available has a filter structure that has been proven to have limited efficacy. In addition, the so-called photocatalyst or electrostatic air purifier is advertised as having a bactericidal effect, and a so-called filter containing a component such as nano silver ions and an enzyme. Although it also has a certain bactericidal effect, however, In the case of bacterial variants and superbugs, the bactericidal effect of such devices is still very limited.

On the other hand, in the process of refining, steel making, electroplating, power plants and semiconductor industries, various pollutants such as mud and the like are generated in the waste liquid sedimentation tank. Sulfur contaminants (sludge) and cyanide contaminants (soil) are most difficult to treat because they need to be treated in a specific range of acids and bases. However, the treatment of cyanide pollutants is still limited in effect today because of its strong molecular activity and the possibility of gas explosion due to high temperature or temperature difference.

Therefore, in order to overcome the aforementioned problems, there is no such creation.

For the above purposes, the present invention provides a system for producing the chlorine dioxide gel composition, wherein the chlorine dioxide used in the chlorine dioxide gel composition is food grade and the gel raw material used is also The food grade, so that the aqueous solution of chlorine dioxide can be stored in a jelly form for efficient storage and transportation, and the chlorine dioxide gel composition can be used for storing various food refrigeration and freezing devices and air quiet The air outlet of the device is circulated by the air circulation of the refrigerating and freezing device and the air cleaning device, and the strong oxidation characteristics of the high-purity chlorine dioxide are used to slowly evaporate the chlorine dioxide gel composition for various refrigeration devices and indoor environments. Sterilization and deodorization, effectively preventing the growth of micro-organisms, small insects (or eggs) and odors in the freezing device, and cleaning the indoor air in the home environment without any side effects and toxicity; it can also be used for disinfection and maintenance of medical wounds. Effectively prevent wounds from being infected by other bacteria.

To achieve the above object, the present invention provides a system for producing a chlorine dioxide gel composition comprising: a chlorine dioxide supply unit for providing an aqueous solution of chlorine dioxide; and a gel supply unit for Providing a gel raw material; a mixing unit and the chlorine dioxide a supply unit is coupled to the gel supply unit for separately mixing the aqueous chlorine dioxide solution with the gel raw material to produce a chlorine dioxide gel composition, and the chlorine dioxide in the chlorine dioxide gel composition The concentration is between 5 ppm and 500 ppm.

When implemented, further comprising a temperature control unit, wherein the mixing unit mixes the aqueous chlorine dioxide solution from the chlorine dioxide supply unit with the temperature of the gel raw material from the gel supply unit at 0-50 ° C between.

When implemented, the gel supply unit provides the gel raw material comprising 82% to 95% by weight of the total weight of the gel raw material, and the viscosity percentage is between 0.25% and 5%. The edible gum with a weight percentage between 4% and 10% and an essential oil with a weight percentage between 0.25% and 3%.

When implemented, the gel supply unit provides the gel raw material comprising 80% to 95% by weight of the total weight of the gel raw material, and the viscosity percentage is between 0.25% and 5%. An edible gum having a weight percentage of 4% to 10%, an essential oil having a weight percentage of 0.25% to 3%, an acid/alkaline activator having a weight percentage of 0.05% to 2%, at least an absorbent and a water absorbing resin. One.

When implemented, it further includes an electrolytic cell for supplying chlorine dioxide to supply the chlorine dioxide to the chlorine dioxide supply unit.

In implementation, a cooling unit is further included for cooling the chlorine dioxide supply unit, the mixing unit and the electrolytic cell with a coolant.

In practice, the cooling unit further includes a spiral circulation channel for flowing the coolant from the cooling unit, the spiral circulation channel is disposed in the chlorine dioxide supply unit, the mixing unit and the electrolytic cell Outside the perimeter.

In order to have a deeper understanding of the characteristics and functions of this creation, the following examples are described in detail with the drawings.

1‧‧‧ chlorine dioxide supply unit

2‧‧‧gel supply unit

3‧‧‧Mixed unit

4‧‧‧Dose unit

5‧‧‧Cooling unit

6‧‧‧electrolyzer

7‧‧‧Pure water supply unit

8‧‧‧temperature control unit

9‧‧‧ Dressing

11, 31, 61, A1‧‧‧ spiral circulation channel

12‧‧‧Air pump

21‧‧‧heating unit

22‧‧‧ Cooling unit

23‧‧‧Dechlorination insulation unit

51, 52, 54, 55, 57, 58‧ ‧ directional valves

53, 56‧‧‧ coolant supply pump

53, 59, 60‧‧ ‧ pump

62‧‧‧ chlorine dioxide release

63‧‧‧ chlorine dioxide output tube

91‧‧‧ sticky area

92‧‧‧Ventilated area

93‧‧‧ Coating area

A‧‧‧ chlorine dioxide aqueous solution storage tank

A2‧‧‧ chlorine dioxide finished product outlet

A3‧‧‧ chlorine dioxide finished product output tube

BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a block diagram showing the architecture of an embodiment of the system for producing the chlorine dioxide gel composition.

Figure 2 is a block diagram showing the architecture of another embodiment of the system for producing the chlorine dioxide gel composition.

Figure 3 is a block diagram showing the architecture of another embodiment of the system for producing the chlorine dioxide gel composition.

Figure 4 is a block diagram showing the structure of a gel supply unit of an embodiment of the system for producing the chlorine dioxide gel composition.

Fig. 5 is a schematic view showing the state of use of the chlorine dioxide gel composition of the present invention.

Fig. 6 is a schematic view showing the state of use of the dressing for the chlorine dioxide gel composition of the present invention.

Please refer to the first drawing of the present invention, which is a system for producing the chlorine dioxide gel composition according to an embodiment of the present invention, which comprises a chlorine dioxide supply unit 1, a gel supply unit 2, and a mixing unit. 3, a dose unit 4, a cooling unit 5, wherein the chlorine dioxide supply unit 1 is used to provide an aqueous solution of chlorine dioxide; the gel supply unit 2 is used to provide a gel material; The mixing unit 3 is connected with the chlorine dioxide supply unit 1 and the gel supply unit 2 via the dosage unit, and respectively mixes the chlorine dioxide aqueous solution with the gel raw material to produce a chlorine dioxide gel. a composition; the dosage unit 4 is for separately inputting the aqueous solution of chlorine dioxide and the gel raw material into the mixing unit 3, so that the concentration of chlorine dioxide in the chlorine dioxide gel composition produced is between Between 5 ppm and 500 ppm; the cooling unit 5 is for supplying a coolant to cool at least one of the chlorine dioxide supply unit 1 and the mixing unit 3. In another embodiment, the dosage unit 4 can also be suitably dispensed in situ in various metering devices or manually.

In another embodiment, the chlorine dioxide gel composition of the present invention for medical, environmental sanitation, animal husbandry, aquaculture has a chlorine dioxide concentration of between 5 ppm and 200 ppm. Preferably, the chlorine dioxide gel composition of the present invention is used in the treatment of medical institutions such as surgical instruments, sanitary quarantine, wound care (described in detail below), skin diseases, or gynecological treatments. The content is between 20 ppm and 100 ppm. Preferably, the chlorine dioxide content of the chlorine dioxide gel composition of the present invention is bactericidal and algae-killing for cold air circulation cooling water, disinfection of food hygiene HACCP meat carcass or sterilization of food and beverage products. It is between 20ppm and 50ppm. Preferably, if the disinfection is used in aquaculture, the chlorine dioxide content of the chlorine dioxide gel composition of the present invention is between 20 ppm and 100 ppm depending on the species of the culture. Preferably, for the animal husbandry, the chlorine dioxide content of the chlorine dioxide gel composition of the present invention is between 20 ppm and 120 ppm, wherein if the animal is disinfected in the pasture, the chlorine dioxide content is used. It is a 20 ppm chlorine dioxide gel composition; if there is no animal disinfection in the pasture, the chlorine dioxide gel composition having a chlorine dioxide content of 100 ppm to 120 ppm is used. Preferably, in the case of orthopedic disinfection, the diseased site of osteomyelitis is irrigated using the chlorine dioxide gel composition having a chlorine dioxide content of 5 ppm to 15 ppm. In another embodiment, the creation The chlorine dioxide gel composition may also be sprayed, immersed or irrigated after the chlorine dioxide content component is treated with the pure water from the pure water supply unit 7.

Please refer to the second drawing of the present invention, which is a system for producing the chlorine dioxide gel composition according to another embodiment of the present invention. The difference from the first figure is that an electrolytic cell 6 and a pure water supply are added. Unit 7 and a temperature control unit 8, wherein the electrolytic cell 6 is for producing chlorine dioxide and supplying the chlorine dioxide to the chlorine dioxide supply unit 1, the electrolytic cell 6 comprising 2% to 10% by weight Sodium chlorite and electrolyte with a weight percentage of 20% to 30% sodium chloride are electrochemically electrolyzed and electrolyzed at a current of 80 to 100 Amp and a voltage of 24 volts (V). This experiment has been confirmed by many experiments. The setting of the aforementioned parameters will have the best finished product value. Thereafter, the gas of the finished chlorine dioxide is pumped to the chlorine dioxide supply unit 1 via an air pump 12. In this embodiment, the cooling unit 5 is configured to cool at least one of the chlorine dioxide supply unit 1, the mixing unit 3 and the electrolytic cell 6 with the coolant.

In another embodiment, the cooling unit 5 further includes a spiral circulation channel disposed on the outer periphery of the chlorine dioxide supply unit 1, the mixing unit 3 and the electrolytic cell 6. Thereby, when the coolant from the cooling unit 5 flows through at least one of the chlorine dioxide supply unit 1, the mixing unit 3, and the spiral circulation passage of the electrolytic tank 6, the temperature is effectively lowered. With continued reference to FIG. 2, the system of the present invention further includes at least one directional valve (51, 52, 54, 55, 57) through which the coolant can be controlled to be supplied via the coolant. The pump 53 or 56 flows from the cooling unit 5 to at least one of the spiral circulation channels provided in the chlorine dioxide supply unit 1, the mixing unit 3, and the electrolytic cell 6, thereby coping with the production Various cooling conditions that may occur during the creation of the chlorine dioxide gel composition.

In another embodiment, the outer circumference of the electrolytic cell 6 may be provided with three spiral surrounding channels (not shown) surrounding the electrolytic cell 6 as a spoiler generating device, and the spiral surrounding channels are used for Providing a segmented, independently surrounding electrolysis cell 6 for a downward spiral flow flow, which can be disturbed in the electrolysis cell 6 when coolant from the cooling unit 5 flows into the spiral circulation channels, respectively. In the flow and electrolysis process, the electrolyte in the electrolytic cell 6 is driven by the turbulence, so that the void generated at the moment when the electrolyte generates chlorine dioxide gas (product) can be quickly replenished, thereby promoting electrolysis. efficacy. Such a large-area three-stage, independent heat exchange causes the electrolyte in the electrolytic cell 6 to generate different directions and types of turbulence, and the lower electrolyte is lifted to the upper electrolytic heating body by the turbulence (not shown). Around the display, it quickly supplements the voids generated by the instantaneous production of the electrolyzed product, thereby producing a stable quality chlorine dioxide gas product, which effectively shortens the process time. In addition, in another embodiment, the spiral surrounding passages may also have a certain space (pitch) between them without being adjacent to each other, thereby generating different degrees of spoiler. In another embodiment, the spiral surrounding channels can also be set to 2, 4, or 4 segments as needed to generate different degrees and types of turbulence.

In another embodiment, please refer to FIG. 3, which is different from the second figure in that a chlorine dioxide cooling storage tank A is further provided, and the chlorine dioxide aqueous solution heat preservation storage tank A includes a spiral surrounding passage A1. , a chlorine dioxide finished product output port A2, a chlorine dioxide finished product output pipe A3 and the pure water supply unit 7, the chlorine dioxide aqueous solution heat preservation storage tank A is set to let the two produced by the electrolytic cell 6 The finished oxidized chlorine (extracted through the chlorine dioxide vent A2) is stored to enhance the overall effectiveness of the creative process. Similarly, the spiral surrounding passage A1 is used for cooling the storage tank A of the chlorine dioxide aqueous solution, and the one-way valve 58 is configured to allow the coolant to be circulated from the cooling unit 5 to the aqueous solution of the chlorine dioxide. Store the outer edge of the tank A to avoid The chlorine dioxide aqueous solution heat preservation storage tank A is prevented from being consumed by gasification due to the temperature difference.

The ratio of chlorine dioxide to gel raw materials used in the chlorine dioxide gel composition of the present invention is an optimum ratio obtained after many experiments, and can neutralize the taste of chlorine dioxide itself to reduce the pungent taste. . The gel raw material provided by the gel supply unit 2 is a thickener having a weight percentage of 82% to 95% by weight based on the total weight of the gel raw material, a viscosity percentage of 0.25% to 5% by weight, and a weight. An edible oil with a percentage between 4% and 10% and an essential oil with a weight percentage between 0.25% and 3%. In addition, referring to FIG. 4, the gel supply unit 2 includes a heating unit 21, a cooling unit 22 and a dechlorination holding unit 23, and the gel raw material is first input to the heating unit 21 to be heated and then stirred to be uniform. In the form of a gel, the heating unit 21 is heated by steam or any heating device. In an embodiment, the heating unit may also be provided with a spiral surrounding passage for allowing vapor from a vapor supply unit to be disposed through the spiral. The steam inlet enters above one of the channels, and is then outputted by a vapor outlet provided below the spiral surrounding passage. Then, it is input to the cooling unit 22 for cooling to 0 to 50 ° C (may be between 30-50 ° C or 11 ° C to 30 ° C according to the needs of the place of use), which is one of the creations without carcinogens. The gel product is finished, and finally, the gel product is input to the chlorine removal heat preservation unit 23 for dechlorination treatment and heat preservation. In another embodiment, if necessary, a spiral circulation channel may be disposed on the outer periphery of the temperature reducing unit 22 to allow the coolant to flow in, thereby speeding down the temperature to below 11 ° C.

The chlorine dioxide gel composition of the present invention is food grade, non-toxic and non-carcinogenic. To achieve this, the pure water is produced by the pure water supply unit 7 shown in Fig. 2, and the pure water supply is provided. The unit is provided with at least one purification unit (not shown), which is composed of one alumina ceramic, one titanium dioxide ceramic or zirconia ceramic, one carbon nanotube and at least rare earth elements. The aluminum oxide ceramic, the titanium dioxide ceramic and the zirconia ceramic are used for industrial use, wherein the rare earth element is subjected to multiple calcination and cooling at a high temperature of 2600 to 2800 ° C to remove impurities. And having a micropore; the carbon nanotube is made of a graphite by calcining at 3000 ° C for food grade use, and the alumina ceramic, the titanium dioxide ceramic, the zirconia ceramic and the nanometer The carbon tube is a far-infrared ray which can generate 1012-1014HZ/sec and is left-handed magnetized, thereby being capable of cutting, processing, and processing the water molecule cluster of pure water passing through it by resonance, filtration, ion exchange, etc., and will come from the water supply source in the process. The pollutants such as heavy metals, microorganisms, ions and impurities are removed (the molecular chain is broken, the molecular cluster structure is changed and the molecule is small), and the bacteria and heavy metals are mostly removed and purified, thereby resonating. , filtering, ion exchange, etc. to cut and treat the water molecule clusters of pure water passing therethrough, thereby also making the pure water supplied by the pure water supply unit 7 slightly alkaline (pH between 5.5 and 8) between)The crude chlorine dioxide aqueous solution produced by the foregoing steps has a purity of 96% to 98%, a chlorine content of 2% to 4%, and does not contain chlorate (ClO3-) or chlorite (ClO2-). Carcinogens such as hydrogen peroxide (H2O2) have a pH slightly higher than 2.2 and a lower pungent odor. The thickener is an edible grade edible thickener such as sodium carboxymethylcellulose, sodium polyacrylate, corn candy gum, sodium alginate, carrageenan, diammonium phosphate, hydroxypropyl phosphate, and acetamidine. At least one of adipic acid di starch; edible gum is pure natural animal glue or vegetable gum or synthetic food grade glue; and essential oils are various plant essential oils such as: fruits, herbs, spices, flowers Classes, trees and synthetic essential oils. Further, when the aqueous chlorine dioxide solution from the chlorine dioxide supply unit 1 is mixed with the gel raw material from the gel supply unit 2 in the mixing unit 3, the temperature control unit 8 mixes the mixing unit 3 The temperature is maintained between 0 ° C and 50 ° C at a specific temperature, and the dechlorination holding unit 23 is also kept at a specific temperature, and in another embodiment, it is maintained at between 30 ° C and 50 ° C, 11 ° C. Between 30 ° C, etc. In any temperature range from 0 ° C to 50 ° C, the specific temperature is adjusted according to the residual chlorine content of the chlorine dioxide, whereby the chlorine dioxide aqueous solution is left at the specific temperature mentioned above. The chlorine is completely vaporized at the moment of mixing with the gel raw material, so that the aqueous chlorine dioxide solution contains no toxic chlorine at all (excluding the aforementioned 2% to 4% residual chlorine) and has a purity of 100% chlorine dioxide. Further, the chlorine dioxide gel composition of the present invention is a dechlorinated composition, and the finished chlorine dioxide gel composition of the present invention is stored in a container (bottled or bottled) and then placed. The refrigerator is waiting to be shipped.

In another embodiment, referring to FIG. 2, the gel supply unit 2 is further configured to provide at least one of an acid/alkaline activator, an absorbent, and a water absorbing resin to the mixing unit 3, the gel material. The invention comprises a pure water having a weight percentage of 80% to 95% by weight of the total weight of the gel raw material, a viscosity agent having a weight percentage of 0.25% to 5%, an edible gum having a weight percentage of 4% to 10%, and a weight. An essential oil having a percentage between 0.25% and 3%, an acid/alkaline activator having a weight percentage of 0.05% to 2%, at least one of an absorbent and a water absorbing resin. The dosage unit 4 is controlled to be output to the acid/alkaline activator, the amount of at least one of the absorbent and the water absorbing resin in the mixing unit 3 or artificially added to produce the chlorine dioxide gel combination of the present invention. Things. The acid/alkaline activator, the absorbent and the water absorbing resin are used to adjust the release rate of chlorine dioxide gas in the chlorine dioxide gel composition of the present invention. Please refer to Figure 5, after the experiment, the chlorine dioxide gel composition of the present invention is used in a general refrigerator in a capacity of 150 grams, about two weeks, depending on the type of food placed in the refrigerator, the oxidation is slightly different. Black spots grow on the chlorine gel composition. At this point, it represents that the chlorine dioxide in the chlorine dioxide gel composition has been consumed, the microorganisms begin to feed on the gel, and a new bottle of the chlorine dioxide gel composition of the present invention needs to be replaced, and then the mold can be maintained. Purification process of the freezing equipment. The chlorine dioxide gel composition of the present invention can be placed in any container. And in response to large, Medium or ultra-small refrigeration equipment and adjustment of the content and proportion of at least one of the acid/alkaline activator, the absorbent and the water absorbing resin in combination with different types of food, medicine or articles stored therein In order to meet the actual release rate of the chlorine dioxide gas required, for example, if it is in a freezer in a slaughterhouse where a large amount of meat is stored, the total amount and release rate of the chlorine dioxide gel composition used must be increased. In order to effectively avoid the growth of bacteria and microorganisms in the freezer. In addition, in the air conditioning system of the intensive care unit or clinic of a hospital or medical unit, or in the air outlet, a set of chlorine dioxide gel composition can be placed, so that the strong oxidation effect of chlorine dioxide can be used for indoor air circulation. It is disinfected and deodorized to effectively maintain the clean air of the entire medical site.

Referring to Fig. 6, the use of the chlorine dioxide gel composition of the present invention for an embodiment of a general dressing is as follows: the dressing 9 has a viscous zone 91 and a permeable zone 92, and a coating zone 93 The present invention is coated with the chlorine dioxide gel composition of the present invention, wherein the chlorine dioxide content of the chlorine dioxide gel composition is between 20 ppm and 100 ppm, and the type of the dressing may be gauze or transparent film. Dressings, hydrophilic dressings, dressings containing alginate, hydrophilic fiber dressings, sponge dressings, antibacterial dressings, collagen-containing dressings, contact dressings, compound dressings, etc., thereby allowing today's dressings The material can have further technical effects of high-order antibacterial and sterilization.

In addition, the chlorine dioxide gel composition of the present invention can also be applied to a cyanide-containing waste liquid in a metallurgical or electroplating factory, such as sodium cyanide, zinc cyanide, copper cyanide and the like and other cyanide pollutants. First, the cyanide contaminant is mixed with the chlorine dioxide aqueous solution (1500 ppm to 3000 ppm or more) produced by the electrolytic cell 6 in a weight ratio of 3:5 to perform a first-stage treatment to produce a first liquid. Strong oxidation of the aqueous chlorine dioxide solution and the treated resonance effect The pure water removes the cyanide contaminants (the molecular chain is broken and the molecular cluster structure is changed and the molecule is small). In one embodiment, after testing, it is shown that the ratio of cyanide to chlorine dioxide is preferably 3:5, and other ratios may be used depending on the contaminant. Then, because the goal of the first stage is to destroy the structure of cyanide, the problem of chlorine dioxide having a gasification temperature of 11 ° C is difficult to control the removal of cyanide pollutants, and the cyanide contaminant is changed into a waste liquid of a cyanide mixture ( The first liquid is discharged into the next sedimentation tank for the second stage treatment, and the chlorine dioxide gel composition is first decomposed by the pure water having the resonance effect (from the pure water supply unit 7). The oxidized chlorine gel is subjected to sustained release, and the chlorine dioxide gel composition of the present invention (concentration: 200 ppm to 500 ppm) is mixed with the first liquid in a weight ratio of 5:3 to 5:4 for strong oxidation. The sustained release treatment, by the strong oxidation of the resonance effect of the aqueous chlorine dioxide solution, oxidizes the cyanide pollutants into non-toxic carbon dioxide and nitrogen to meet emission standards.

In addition, the same steps as described above can also treat sulfurized contaminants. First, the first stage treatment is carried out again with the aqueous chlorine dioxide solution (1500 ppm to 3000 ppm or more) produced by the electrolytic cell 6, by the strong aqueous solution of chlorine dioxide. Oxidation and the treated pure water having a resonance effect remove the sulfide contaminants (the molecular chain is broken, the molecular cluster structure is changed and the molecule is small). Then, since the first stage aims to destroy the structure of the sulfide to form another first liquid, the waste liquid which turns the sulfide into a sulfur mixture (the other first liquid mentioned above) is discharged into the next sedimentation tank for the second stage. The treatment, the pure chlorine water having the resonance effect (from the pure water supply unit 7) is first decomposed to dissolve the chlorine dioxide gel composition to release the chlorine dioxide gel of the present invention, and then the second creation The oxidized chlorine gel composition (concentration 200 ppm to 500 ppm) is treated in the second stage by the other first liquid, since the chlorine dioxide gel composition of the present invention contains pure water having a slight alkalinity (pH value Oxidation of sulfurized contaminants to non-toxic sulfates at 5.5 to 8 (SO42-) enables emission standards to be met. Therefore, it is known from the foregoing. The amount of the chlorine dioxide aqueous solution used in the first stage and the chlorine dioxide gel composition used in the second stage can be adjusted according to the pollution situation of the sulfide contaminant and the cyanide pollutant, respectively, so that the treated The pollutants meet the emission standards, and the same steps as described above can also be used for the treatment of sewage such as phenol, thiosulfate, and mercaptan.

Next, the overall operation of the system for producing the chlorine dioxide gel composition of the present invention will be described. Referring to FIG. 2, the electrolytic cell 6 and the chlorine dioxide supply unit 1 are set as a group of electrolysis work. The unit, and the plurality of sets of electrolysis units can be operated with at least one set of pure water supply units 7, a set of gel supply units 2 and a set of cooling units 5, a set of mixing units 3 and a dose unit 4. First, the water supply source (not shown) supplies pure water to the pure water supply unit 7 for processing by a pressure pump (not shown), and is processed into a slightly alkaline liquid and output to the second The chlorine oxide supply unit 1, at this point, the pre-operation of pure water is completed. Thereafter, the gel supply unit 2 uses the dosage unit 4 in a proportion by weight of 82% to 95% by weight of pure water (provided by the pure water supply unit 7), a viscosity percentage of 0.25% to 5% by weight, Proportion of essential oils with a percentage by weight of 4% to 10% by weight, between 0.25% and 3% by weight (or between 80% and 95% by weight of pure water, weight percentage between 0.25%) Up to 5% of a thickener, 4% to 10% by weight of edible gum, 05% to 3% by weight of essential oil, 0.05% to 2% by weight of acid/alkaline activator, absorption The ratio of the agent to the at least one of the water absorbing resin is fed). After the feeding, the gel raw material is processed by the heating unit 21, the cooling unit 22 and the dechlorination holding unit 23 to become a finished gel product maintained at a specific temperature. It should be noted that the raw materials for the production of chlorine dioxide aqueous solution (finished product) must be kept below 11 °C at this time, so the air-conditioning temperature in the plant should be properly adjusted to avoid the use of such raw materials in the next step. The finished product of the oxidized chlorine produces a temperature difference resulting in the finished product of the chlorine dioxide gel composition The purity is reduced.

At the beginning of the process, first, according to the electrolysis characteristics, after the order of opening the directional valves 51, 52, 54, 55, 57 is set, the coolant is caused to flow through the spiral circulation passage 61 from the cooling unit 5, so that the electrolysis is performed. The generated high temperature is cooled. The successively produced chlorine dioxide gas will be pumped out through the chlorine dioxide outlet 62 along the chlorine dioxide output pipe 63 by the pump 12 to the chlorine dioxide supply unit 1 through the gas-liquid mixing mechanism (not shown) The treatment is carried out, and mixed with the pure water from the pure water supply unit 7 to form an aqueous solution of chlorine dioxide having a concentration of 3000 ppm or more to complete a process. At this time, the adjustable temperature sensor (not shown) configured by the chlorine dioxide supply unit 1 transmits an electronic control device (not shown) if the temperature is higher than a preset value (8 to 11 ° C). Let the coolant supply pump 53 pump the coolant to cool down, and the coolant flows through the annular passage 11 provided in the chlorine dioxide supply unit 1 to perform a spiral circulation type comprehensive flow cooling until the above-mentioned adjustable temperature sensing The high temperature message cancellation of the device stops. During the gas production of the electrolytic cell 6 and the pumping operation of the air pump 12, if the electronic control unit device receives the temperature rise message of the adjustable temperature sensor again, the above action will be repeated, and the coolant supply pump 53 will again be used to cool the coolant. Pumping to the chlorine dioxide supply unit 1 to cool down. Thereafter, the directional valve 55 is opened to deliver the aforementioned gel product from the gel supply unit 2 to the dosage unit, while the directional valve 57 is opened to oxidize the chlorine dioxide supply unit 1. The finished aqueous solution of chlorine (in one embodiment, the chlorine dioxide supply unit 1 of the present invention is prepared to be an aqueous solution of chlorine dioxide of 1500 ppm to 3000 ppm or more) is delivered to the dosage unit 4. Thereafter, the dosage unit 4 delivers the aqueous solution of chlorine dioxide and the finished gel product to the mixing unit 3 at a specific temperature (0 ° C to 50 ° C, 30 ° C to 50 ° C) with the aqueous solution of chlorine dioxide and a finished gel product. The mixture is mixed at 11 ° C to 30 ° C. After mixing, the finished chlorine dioxide gel composition is completed and transferred to a refrigerator for storage. It should be noted that the chlorine dioxide gel composition is finished. Still need to be stored at low temperature, the mixing unit 3 is also equipped with an adjustable temperature sensor (not shown). If the temperature is higher than the preset value (0 to 50 ° C), the electronic control device (not shown) The coolant supply pump 56 pumps the coolant to cool down, and the coolant flows through the annular passage 31 provided in the mixing unit 3 to perform a spiral circulation type comprehensive flow cooling until the adjustable temperature sensor is The high temperature message cancellation stops.

At the same time as the start of the process, the pure water supply unit 7 also re-processes the pure water as described above, and again treats the pure water supplied from the water supply source into a treated and slightly alkaline pure The water is output to another chlorine dioxide supply unit 1 to prepare another set of process work units for use. Similarly, at the same time, the gel supply unit 2 also begins to re-feed in accordance with the aforementioned ratio and subject the new batch of gel material to the aforementioned processing steps to prepare for the next stage of the process.

With the process operation of the present creation, the pure water supply unit 7 first pre-processes the pure water required for the chlorine dioxide supply unit of the number 1A (not shown), and then supplies the treated pure water to the chlorine dioxide supply unit 1A. And the gel unit 2A starts to feed according to the aforementioned ratio. At the beginning of the process, the first round of the first stage is performed with the electrolytic cell of the number 1A chlorine dioxide supply unit and the number 6A (not shown) and the gel supply unit 2A; when the electrolytic cell 6A performs the electrolysis operation, the pure The water supply unit 7 first pre-processes the pure water required for the chlorine dioxide supply unit of No. 1B (not shown), and then supplies another treated pure water to the chlorine dioxide supply unit of No. 1B while supplying the gel. Unit 2B begins the re-feeding and performs the aforementioned processing steps. When the chlorine dioxide supply unit of No. 1B is filled with the treated pure water and the gel supply unit 2B is fed and processed, the first round of the process is completed. The assignment will also be completed, so that the next round (second round) of phased work can be performed immediately, and so on, there will be no waiting time for the entire operation.

Therefore, this creation has the following advantages:

1. Mix food grade chlorine dioxide solution (concentration 1500-3000ppm, high purity 96%-98%, residual chlorine 4%) with food grade gel to produce food grade chlorine dioxide gel composition, no chlorine Carcinogens or contaminants such as acid chloride (ClO ₃ ^- ), chlorite (ClO ₂ ^- ), hydrogen peroxide (H ₂ O ₂ ), and the residual chlorine of the chlorine dioxide aqueous solution of the present invention is within 4%, and When the gel raw material is mixed with the chlorine dioxide aqueous solution (0 to 50 ° C), the chlorine gas is vaporized, so that the chlorine dioxide gel composition of the present invention has no chlorine residue, and can be effectively used in various refrigeration equipment and air purification. The device and the effect of disinfecting, deodorizing and sterilizing the device are greatly improved, and the chlorine dioxide gel composition can be used for storing various foods of the refrigeration and freezing device and the air outlet of the air cleaning device, by refrigerating and freezing The gas circulation of the device and the air quieting device, combined with the strong oxidation characteristics of high-purity chlorine dioxide, allows the chlorine dioxide gel composition to slowly evaporate and sterilize and deodorize various refrigeration devices and indoor environments, thereby effectively preventing microorganisms in the freezing device. Small insects (including Eggs) and breeding as well as clean air smell of indoor home environment.

2. The edible grade chlorine dioxide aqueous solution is made into a gel type to facilitate the transportation of various land, sea and air freight, and greatly reduces the loss of chlorine dioxide during transportation.

3. The food grade chlorine dioxide gel composition of the present invention (without carcinogens, dechlorination and slightly alkaline) is used for various medical dressings, effectively improving the side effects caused by the traditional treatment of wounds. It also allows the existing various dressings to produce advanced antibacterial and bactericidal effects.

4. The food grade chlorine dioxide gel composition of the present invention is used for the treatment of sulfurized pollutants and cyanide pollutants, and the chlorine dioxide gel composition of the present invention is made into a slightly alkaline and high purity. The strong oxidation effect of food grade chlorine dioxide aqueous solution effectively treats industrial pollutants such as sulfurized pollutants and cyanide pollutants into non-toxic inorganic substances.

The above is a specific embodiment of the present invention and the technical means used therein, and many changes and modifications can be derived therefrom according to the disclosure or teachings herein, and the equivalent changes made according to the concept of the present invention are produced. The role shall not be considered to be within the technical scope of this creation, and shall be preceded by Chen Ming.

According to the content disclosed above, the creation can achieve the intended purpose of creation, and provide a system for producing the chlorine dioxide gel composition, which has the value of industrial utilization and practicality, and proposes a new patent application according to law.

1‧‧‧ chlorine dioxide supply unit

2‧‧‧gel supply unit

3‧‧‧Mixed unit

4‧‧‧Dose unit

5‧‧‧Cooling unit

Claims (7)

A system for producing a chlorine dioxide gel composition, comprising: a chlorine dioxide supply unit for providing an aqueous solution of chlorine dioxide; a gel supply unit for providing a gel raw material; and a mixing unit And connecting the chlorine dioxide supply unit to the gel supply unit for separately mixing the chlorine dioxide aqueous solution with the gel raw material to produce a chlorine dioxide gel composition, and the chlorine dioxide gel The concentration of chlorine dioxide in the composition is between 5 ppm and 500 ppm. The system of claim 1, further comprising a temperature control unit, wherein the mixing unit mixes the aqueous chlorine dioxide solution from the chlorine dioxide supply unit with the gel from the gel supply unit The temperature of the raw material is maintained between 0 and 50 °C. The system of claim 1, wherein the gel material provided by the gel supply unit comprises from 82% to 95% by weight, based on the total weight of the gel material, by weight of water. A viscous agent between 0.25% and 5%, an edible gum with a weight percentage between 4% and 10%, and an essential oil with a weight percentage between 0.25% and 3%. The system of claim 1, wherein the gel raw material provided by the gel supply unit comprises: 80% to 95% by weight, based on the total weight of the gel raw material, of pure water, weight percentage Between 0.25% and 5% of the viscosity agent, 4% to 10% by weight of the edible gum, 05% to 3% by weight of the essential oil, 0.05% to 2% by weight of the acid/alkaline At least one of an activator, an absorbent, and a water absorbing resin. The system of claim 1, further comprising an electrolytic cell for producing chlorine dioxide to supply the chlorine dioxide to the chlorine dioxide supply unit. The system of claim 5, further comprising a cooling unit for cooling The agent cools the chlorine dioxide supply unit, the mixing unit and at least one of the electrolytic cells. The system of claim 6, wherein the cooling unit further comprises a spiral circulation passage for the coolant from the cooling unit to flow therein, the spiral circulation passage being disposed in the chlorine dioxide The supply unit, the mixing unit and the outer periphery of the electrolytic cell.