TWM576164U - Anti-corrosion fluorocarbon composition - Google Patents

Anti-corrosion fluorocarbon composition Download PDF

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Publication number
TWM576164U
TWM576164U TW107216624U TW107216624U TWM576164U TW M576164 U TWM576164 U TW M576164U TW 107216624 U TW107216624 U TW 107216624U TW 107216624 U TW107216624 U TW 107216624U TW M576164 U TWM576164 U TW M576164U
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component layer
weight percent
fluorocarbon composition
fluorocarbon
weight
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TW107216624U
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高孟聰
黃鳳全
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盟鑫金屬股份有限公司
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Publication of TWM576164U publication Critical patent/TWM576164U/en

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Abstract

一種防蝕氟碳組合物,包含相互設置的一第一成分層及一第二成分層,第一成分層包括40至70重量百分比的一FEVE氟碳樹脂、5至30重量百分比的一醚類、5至30重量百分比的一醇類、0.2至2.5重量百分比的一表面調整劑、0.3至2.5重量百分比的一消泡劑以及0.2至2.5重量百分比的一搖變劑,以及第二成分層包括3至30重量百分比的一異氰酸酯,該第一成分層與該第二成分層的重量百分比為6:1至16:1,本創作之防蝕氟碳組合物藉由各種成分及特定比例含量的組合,在常溫可自乾,且完全乾燥後具有高耐腐蝕性、高耐化學性及高耐候性之功效。An anti-corrosive fluorocarbon composition includes a first component layer and a second component layer which are disposed mutually. The first component layer includes 40 to 70 weight percent of a FEVE fluorocarbon resin, 5 to 30 weight percent of an ether, 5 to 30 weight percent of an alcohol, 0.2 to 2.5 weight percent of a surface conditioner, 0.3 to 2.5 weight percent of a defoamer, and 0.2 to 2.5 weight percent of a shaker, and the second component layer includes 3 To 30% by weight of an isocyanate, and the weight percentage of the first component layer and the second component layer is 6: 1 to 16: 1. The anticorrosive fluorocarbon composition of the present invention uses a combination of various components and specific proportions, It can be self-drying at room temperature, and has the functions of high corrosion resistance, high chemical resistance and high weather resistance after completely drying.

Description

防蝕氟碳組合物Anticorrosive fluorocarbon composition

本創作係相關於一種防蝕組合物,特別是相關於一種防蝕氟碳組合物This creation relates to an anticorrosive composition, and in particular to an anticorrosive fluorocarbon composition

許多結構物的材質主要以金屬為主,當其處於高腐蝕因子的環境中,會使得金屬產生腐蝕而大幅減少其原本應有的性能,因而會於結構物上進行防蝕保護,以延長金屬結構的使用壽命。The material of many structures is mainly metal. When it is in an environment with a high corrosion factor, it will cause the metal to corrode and greatly reduce its original performance. Therefore, corrosion protection will be performed on the structure to extend the metal structure. Life.

習知防蝕方式主要有電鍍、塗佈、熱浸及陰極保護等等,其中在塗佈方式中,係為將塗料塗覆於物體表面而形成薄膜以達到保護物體表面之效果,而使用的塗料包括環氧樹脂、油脂塗料及乳膠漆。The conventional anti-corrosion methods mainly include electroplating, coating, hot dipping, and cathodic protection. Among them, in the coating method, the coating is used to form a film on the surface of the object to protect the surface of the object. Including epoxy resin, grease paint and latex paint.

然而,上述塗料皆有其使用上的缺點。舉例而言,環氧樹脂不易乾燥,油脂塗料耐蝕度低、不易乾燥、質軟,以及乳膠漆柔韌性及附著力不佳,導致應用受到限制。綜上,習知之塗料有其改良的必要。However, the above coatings all have their shortcomings in use. For example, epoxy resins are not easy to dry, grease coatings have low corrosion resistance, are not easy to dry, are soft, and the flexibility and adhesion of latex paints are not good, resulting in limited applications. In summary, there is a need to improve the conventional coatings.

緣此,本創作之目的在於提供一種防蝕氟碳組合物,能方便使用並提昇其防蝕效果。For this reason, the purpose of this creation is to provide an anticorrosive fluorocarbon composition that can be conveniently used and enhance its anticorrosive effect.

本創作為解決習知技術之問題所採用之技術手段係提供一種防蝕氟碳組合物,包含一第一成分層,包括40至70重量百分比的一FEVE氟碳樹脂、5至30重量百分比的一醚類、5至30重量百分比的一醇類、0.2至2.5重量百分比的一表面調整劑、0.3至2.5重量百分比的一消泡劑以及0.2至2.5重量百分比的一搖變劑;以及一第二成分層,設置於該第一成分層,並包括3至30重量百分比的一異氰酸酯,其中,該第一成分層與該第二成分層的重量百分比為6:1至16:1。The technical means used to solve the problems of conventional technology in this creation is to provide an anticorrosive fluorocarbon composition, which includes a first component layer, including 40 to 70 weight percent of a FEVE fluorocarbon resin, and 5 to 30 weight percent of a Ethers, 5 to 30 weight percent of an alcohol, 0.2 to 2.5 weight percent of a surface modifier, 0.3 to 2.5 weight percent of a defoamer, and 0.2 to 2.5 weight percent of a shaker; and a second The component layer is disposed on the first component layer and includes 3 to 30 weight percent of an isocyanate, wherein the weight percentage of the first component layer and the second component layer is 6: 1 to 16: 1.

在本創作的一實施例的防蝕氟碳組合物中,該第一成分層包括不超過15重量百分比的一色母顏料。In an anti-corrosive fluorocarbon composition according to an embodiment of the present invention, the first component layer includes not more than 15 weight percent of a one-color mother pigment.

在本創作的一實施例的防蝕氟碳組合物中,該第一成分層包括不超過2.5重量百分比的一催化劑。In an anti-corrosive fluorocarbon composition according to an embodiment of the present invention, the first component layer includes a catalyst not exceeding 2.5 weight percent.

在本創作的一實施例的防蝕氟碳組合物中,該第二成分層包括不超過30重量百分比的一醚類。In the anti-corrosive fluorocarbon composition according to an embodiment of the present invention, the second component layer includes not more than 30 weight percent of an ether.

在本創作的一實施例的防蝕氟碳組合物中,該第二成分層包括不超過30重量百分比的一醇類。In the anti-corrosive fluorocarbon composition according to an embodiment of the present invention, the second component layer includes not more than 30 weight percent of an alcohol.

在本創作的一實施例的防蝕氟碳組合物中,該FEVE氟碳樹脂之重量百分比為50至60。In an anti-corrosive fluorocarbon composition according to an embodiment of the present invention, the weight percentage of the FEVE fluorocarbon resin is 50 to 60.

在本創作的一實施例的防蝕氟碳組合物中,該異氰酸酯之重量百分比為5至15。In an anti-corrosive fluorocarbon composition according to an embodiment of the present invention, the weight percentage of the isocyanate is 5 to 15.

在本創作的一實施例的防蝕氟碳組合物中,該醚類為乙二醇丁醚。In an anti-corrosive fluorocarbon composition according to an embodiment of the present invention, the ether is ethylene glycol butyl ether.

在本創作的一實施例的防蝕氟碳組合物中,該醇類為正丁醇。In an anti-corrosive fluorocarbon composition according to an embodiment of the present invention, the alcohol is n-butanol.

本創作為解決習知技術之問題所採用之一另一技術手段係提供一種防蝕氟碳組合物作為金屬防蝕的用途。One of the other technical means adopted by the present author to solve the problems of the conventional technology is to provide an anticorrosive fluorocarbon composition as a metal anticorrosive application.

經由本創作所採用之技術手段,防蝕氟碳組合物藉由第一成分層與第二成分層之交聯架橋相輔加成作用在常溫可自乾,且完全乾燥後具有高耐腐蝕性、高耐化學性及高耐候性。且,無論是常溫或是高溫防蝕氟碳組合物皆能固化,而便於使用。此外,根據施用的基材材質以及環境等因素,第一成分層與第二成分層之各個成分的含量可因應調整,而達到最佳功效。Through the technical means used in this creation, the anti-corrosive fluorocarbon composition is supplemented by the cross-linking bridge of the first component layer and the second component layer. It can be self-drying at room temperature, and has high corrosion resistance after completely drying. High chemical resistance and high weather resistance. Moreover, the anti-corrosive fluorocarbon composition can be cured at normal temperature or high temperature, and is convenient to use. In addition, according to factors such as the material of the substrate to be applied and the environment, the content of each component of the first component layer and the second component layer can be adjusted accordingly to achieve the best effect.

以下根據第1圖至第6b圖,而說明本創作的實施方式。該說明並非為限制本創作的實施方式,而為本創作之實施例的一種。Hereinafter, an embodiment of the present invention will be described based on FIGS. 1 to 6b. This description is not intended to limit the implementation of this creation, but is an embodiment of this creation.

如第1圖所示,依據本創作的一實施例的一種防蝕氟碳組合物100,包含一第一成分層1及一第二成分層2。As shown in FIG. 1, an anticorrosive fluorocarbon composition 100 according to an embodiment of the present invention includes a first component layer 1 and a second component layer 2.

詳細而言,第一成分層1包括40至70重量百分比的一FEVE氟碳樹脂、5至30重量百分比的一醚類、5至30重量百分比的一醇類、0.2至2.5重量百分比的一表面調整劑、0.3至2.5重量百分比的一消泡劑以及0.2至2.5重量百分比的一搖變劑。第二成分層2設置於該第一成分層1,並包括3至30重量百分比的一異氰酸酯。該第一成分層與該第二成分層的重量百分比為6:1至16:1。In detail, the first component layer 1 includes 40 to 70 weight percent of a FEVE fluorocarbon resin, 5 to 30 weight percent of an ether, 5 to 30 weight percent of an alcohol, and 0.2 to 2.5 weight percent of a surface. A conditioning agent, 0.3 to 2.5 weight percent of a defoamer, and 0.2 to 2.5 weight percent of a shaker. The second component layer 2 is disposed on the first component layer 1 and includes 3 to 30 weight percent of a monoisocyanate. The weight percentage of the first component layer and the second component layer is 6: 1 to 16: 1.

較佳的,該FEVE氟碳樹脂之重量百分比為50至60,以及該異氰酸酯之重量百分比為5至15。Preferably, the weight percentage of the FEVE fluorocarbon resin is 50 to 60, and the weight percentage of the isocyanate is 5 to 15.

詳細而言,該FEVE氟碳樹脂可為氟乙烯-乙烯基醚共聚物樹脂、該醚類可為乙二醇丁醚、該醇類可為正丁醇,以及該消泡劑可選自VersaFlow Base。In detail, the FEVE fluorocarbon resin may be a fluoroethylene-vinyl ether copolymer resin, the ethers may be ethylene glycol butyl ether, the alcohols may be n-butanol, and the defoaming agent may be selected from VersaFlow Base.

此外,在其他實施例中,該第一成分層1還可包括不超過15重量百分比的一色母顏料及/或不超過2.5重量百分比的一催化劑;以及該第二成分層2包括不超過30重量百分比的一醚類及/或不超過30重量百分比的一醇類。In addition, in other embodiments, the first component layer 1 may further include a color master pigment not exceeding 15% by weight and / or a catalyst not exceeding 2.5% by weight; and the second component layer 2 includes not more than 30% by weight. Percent monoethers and / or monoalcohols not exceeding 30 weight percent.

在本實施例中,本創作之防蝕氟碳組合物係為塗料,藉由刷塗、噴塗、輥塗等方式覆蓋於一物體表面,而作為防蝕的用途,特別是用以金屬防蝕。當然,本創作不以此為限。本創作之防蝕氟碳組合物亦可施用於其他材質以用於防蝕。詳細而言,本創作之防蝕氟碳組合物的第一成分層與第二成分層於使用前為個別存在,於使用時才被予以相互疊置。值得注意的是,本創作之防蝕氟碳組合物100的第一成分層1與第二成分層2之存放溫度不宜超過40℃及低於5℃。In this embodiment, the anti-corrosive fluorocarbon composition of the present invention is a paint, which is applied to the surface of an object by means of brushing, spraying, roller coating, etc., and is used for corrosion prevention, especially for metal corrosion prevention. Of course, this creation is not limited to this. The anti-corrosive fluorocarbon composition of this creation can also be applied to other materials for anti-corrosion. In detail, the first component layer and the second component layer of the anti-corrosive fluorocarbon composition of the present invention exist separately before use, and are overlapped with each other only when in use. It is worth noting that the storage temperature of the first component layer 1 and the second component layer 2 of the anti-corrosive fluorocarbon composition 100 of the present invention should not exceed 40 ° C and less than 5 ° C.

參照第2a圖及第2b圖,其分別為一鍍鋅鋼板有施塗本創作之防蝕氟碳組合物(第2a圖)及未施塗本創作之防蝕氟碳組合物(第2b圖)經鹽水噴霧試驗2000小時之實驗測試。可看到未施塗本創作之防蝕氟碳組合物的鍍鋅鋼板(第2b圖)之表面明顯有銹蝕。Referring to Fig. 2a and Fig. 2b, respectively, a galvanized steel sheet with the anticorrosive fluorocarbon composition (Fig. 2a) applied with the original composition and the anticorrosive fluorocarbon composition (Fig. 2b) without the original composition are applied. Salt spray test 2000 hours experimental test. It can be seen that the surface of the galvanized steel sheet (FIG. 2b) to which the anticorrosive fluorocarbon composition of the present invention is not applied is obviously rusted.

類似地,參照第3a圖及第3b圖,其分別為一鍍鎂鋁鋅鋼板有施塗本創作之防蝕氟碳組合物(第3a圖)及未施塗本創作之防蝕氟碳組合物(第3b圖)經鹽水噴霧試驗2000小時之實驗測試。可看到未施塗本創作之防蝕氟碳組合物的鍍鎂鋁鋅鋼板(第3b圖)之表面明顯有銹蝕。Similarly, referring to FIG. 3a and FIG. 3b, they are a corrosion-resistant fluorocarbon composition (FIG. 3a) and a corrosion-resistant fluorocarbon composition (this FIG. Figure 3b) Experimental test after 2000 hours of salt spray test. It can be seen that the surface of the magnesium-aluminum-zinc-coated steel sheet (FIG. 3b) to which the anticorrosive fluorocarbon composition of the present invention is not applied is obviously rusted.

類似地,參照第4a圖及第4b圖,其分別為一厚度為2.3mm的鍍鋅鋼板有施塗本創作之防蝕氟碳組合物(第4a圖)及未施塗本創作之防蝕氟碳組合物(第4b圖)經鹽水噴霧試驗250小時之實驗測試。可看到未施塗本創作之防蝕氟碳組合物的鍍鋅鋼板(第4b圖)之表面明顯有銹蝕現象。Similarly, referring to Fig. 4a and Fig. 4b, respectively, a galvanized steel sheet having a thickness of 2.3 mm has an anti-corrosive fluorocarbon composition (FIG. 4a) to which the present invention has been applied and an anti-corrosive fluorocarbon to which the present invention has not been applied. The composition (Figure 4b) was experimentally tested for 250 hours in a salt spray test. It can be seen that the surface of the galvanized steel sheet (Fig. 4b) without the anticorrosive fluorocarbon composition of the present invention is obviously rusted.

類似地,參照第5a圖及第5b圖,其分別為一厚度為2.3mm的鍍鎂鋁鋅鋼板有施塗本創作之防蝕氟碳組合物(第5a圖)及未施塗本創作之防蝕氟碳組合物(第5b圖)經鹽水噴霧試驗500小時之實驗測試。可看到未施塗本創作之防蝕氟碳組合物的鍍鎂鋁鋅鋼板(第5b圖)之表面產生白銹。Similarly, referring to FIG. 5a and FIG. 5b, they are a Mg-plated aluminum-zinc steel plate with a thickness of 2.3 mm, respectively, with an anticorrosive fluorocarbon composition (FIG. 5a) applied and the anti-corrosion composition not applied. The fluorocarbon composition (Figure 5b) was experimentally tested for 500 hours in a salt spray test. It can be seen that white rust was generated on the surface of the magnesium-aluminum-zinc-plated steel sheet (FIG. 5b) to which the corrosion-resistant fluorocarbon composition of the present invention was not applied.

類似地,參照第6a圖及第6b圖,其分別為一熱軋耐候鋼有施塗本創作之防蝕氟碳組合物(第6a圖)及未施塗本創作之防蝕氟碳組合物(第6b圖)經5wt%鹽水噴霧試驗480小時之實驗測試。可看到未施塗本創作之防蝕氟碳組合物的熱軋耐候鋼(第6b圖)之表面明顯有銹蝕現象。Similarly, referring to Figs. 6a and 6b, they are respectively a corrosion-resistant fluorocarbon composition (FIG. 6a) with which the present invention has been applied and a corrosion-resistant fluorocarbon composition with which the present invention has not been applied (FIG. 6a). Figure 6b) Experimental test after 5wt% saline spray test for 480 hours. It can be seen that the surface of the hot-rolled weathering steel (Figure 6b) without applying the corrosion-resistant fluorocarbon composition of the present invention has obvious rust.

綜上所述,本創作之防蝕氟碳組合物使用方便,易於刷塗、噴塗,常溫可自乾,亦能經輥塗且烘烤成膜;更重要的是,本創作之防蝕氟碳組合物無論有無經過烘烤,只要漆膜乾燥完全,均具有優良的防蝕效果。In summary, the anti-corrosive fluorocarbon composition of this creation is easy to use, easy to brush and spray, and can be self-drying at room temperature. It can also be roll-coated and baked to form a film; more importantly, the anti-corrosive fluorocarbon composition of this creation Regardless of whether the material has been baked or not, as long as the paint film is completely dry, it has excellent anti-corrosion effect.

以上之敘述以及說明僅為本創作之較佳實施例之說明,對於此項技術具有通常知識者當可依據以下所界定申請專利範圍以及上述之說明而作其他之修改,惟此些修改仍應是為本創作之創作精神而在本創作之權利範圍中。The above descriptions and descriptions are merely illustrations of the preferred embodiments of this creation. Those with ordinary knowledge of this technology should make other modifications based on the scope of the patent application as defined below and the above description, but these modifications should still be made. It is within the scope of the rights of this creation for the spirit of creation.

100‧‧‧防蝕氟碳組合物100‧‧‧Anticorrosive fluorocarbon composition

1‧‧‧第一成分層 1‧‧‧ first component layer

2‧‧‧第二成分層 2‧‧‧Second component layer

第1圖係根據本創作之一實施例的一防蝕氟碳組合物的示意圖。 第2a圖係顯示經施用本創作的防蝕氟碳組合物的一鍍鋅鋼板的試驗結果照片。 第2b圖係顯示未施用本創作的防蝕氟碳組合物的一鍍鋅鋼板的試驗結果照片; 第3a圖係顯示經施用本創作的防蝕氟碳組合物的一鍍鎂鋁鋅鋼板的試驗結果照片。 第3b圖係顯示未施用本創作的防蝕氟碳組合物的一鍍鎂鋁鋅鋼板的試驗結果照片; 第4a圖係顯示經施用本創作的防蝕氟碳組合物的一鍍鋅鋼板的試驗結果照片; 第4b圖係顯示未施用本創作的防蝕氟碳組合物的一鍍鋅鋼板的試驗結果照片; 第5a圖係顯示經施用本創作的防蝕氟碳組合物的一鍍鎂鋁鋅鋼板的試驗結果照片; 第5b圖係顯示未施用本創作的防蝕氟碳組合物的一鍍鎂鋁鋅鋼板的試驗結果照片; 第6a圖係顯示經施用本創作的防蝕氟碳組合物的一熱軋耐候鋼(含銅鋼板)的試驗結果照片; 第6b圖係顯示未施用本創作的防蝕氟碳組合物的一熱軋耐候鋼(含銅鋼板)的試驗結果照片。FIG. 1 is a schematic diagram of an anti-corrosive fluorocarbon composition according to an embodiment of the present invention. Figure 2a is a photograph showing the test results of a galvanized steel sheet to which the inventive anti-corrosive fluorocarbon composition was applied. Figure 2b is a photograph showing the test results of a galvanized steel sheet without applying the anticorrosive fluorocarbon composition of the present invention; Figure 3a is showing the test results of a magnesium-plated aluminum-zinc plated steel sheet having the anticorrosive fluorocarbon composition of the present invention applied photo. Figure 3b is a photograph showing the test results of a magnesium-plated aluminum-zinc plated steel sheet to which the anticorrosive fluorocarbon composition of the present invention is not applied; Figure 4a is a test result of a galvanized steel sheet to which the inventive anticorrosive fluorocarbon composition is applied Photo; Fig. 4b is a photo showing the test results of a galvanized steel sheet without applying the anticorrosive fluorocarbon composition of the present invention; Fig. 5a is a photo of a magnesium-plated aluminum zinc plated steel sheet with the anticorrosive fluorocarbon composition of the present invention applied Photo of the test result; Figure 5b shows a photo of the test result of a magnesium-aluminum-zinc plated steel sheet without applying the anticorrosive fluorocarbon composition of the present invention; Figure 6a shows a hot rolling of the anticorrosive fluorocarbon composition of the present invention Photo of test results of weathering steel (copper-containing steel plate); Figure 6b shows a photo of the test results of a hot-rolled weathering steel (copper-containing steel plate) without applying the anticorrosive fluorocarbon composition of the present invention.

Claims (9)

一種防蝕氟碳組合物,包含: 一第一成分層,包括40至70重量百分比的一FEVE氟碳樹脂、5至30重量百分比的一醚類、5至30重量百分比的一醇類、0.2至2.5重量百分比的一表面調整劑、0.3至2.5重量百分比的一消泡劑以及0.2至2.5重量百分比的一搖變劑;以及 一第二成分層,設置於該第一成分層,並包括3至30重量百分比的一異氰酸酯, 其中,該第一成分層與該第二成分層的重量百分比為6:1至16:1。An anti-corrosive fluorocarbon composition, comprising: a first component layer comprising 40 to 70 weight percent of a FEVE fluorocarbon resin, 5 to 30 weight percent of an ether, 5 to 30 weight percent of an alcohol, 0.2 to 2.5 weight percent of a surface modifier, 0.3 to 2.5 weight percent of a defoamer, and 0.2 to 2.5 weight percent of a shaker; and a second component layer disposed on the first component layer and including 3 to 30% by weight of a monoisocyanate, wherein the weight percentage of the first component layer and the second component layer is 6: 1 to 16: 1. 如請求項1所述之防蝕氟碳組合物,其中該第一成分層包括不超過15重量百分比的一色母顏料。The anti-corrosive fluorocarbon composition according to claim 1, wherein the first component layer includes not more than 15 weight percent of a one-color mother pigment. 如請求項1所述之防蝕氟碳組合物,其中該第一成分層包括不超過2.5重量百分比的一催化劑。The anti-corrosive fluorocarbon composition according to claim 1, wherein the first component layer includes a catalyst in an amount of not more than 2.5% by weight. 如請求項1所述之防蝕氟碳組合物,其中該第二成分層包括不超過30重量百分比的一醚類。The anti-corrosive fluorocarbon composition according to claim 1, wherein the second component layer includes not more than 30% by weight of an ether. 如請求項1所述之防蝕氟碳組合物,其中該第二成分層包括不超過30重量百分比的一醇類。The anticorrosive fluorocarbon composition according to claim 1, wherein the second component layer comprises not more than 30% by weight of an alcohol. 如請求項1所述之防蝕氟碳組合物,其中該FEVE氟碳樹脂之重量百分比為50至60。The anticorrosive fluorocarbon composition according to claim 1, wherein the weight percentage of the FEVE fluorocarbon resin is 50 to 60. 如請求項1所述之防蝕氟碳組合物,其中該異氰酸酯之重量百分比為5至15。The anticorrosive fluorocarbon composition according to claim 1, wherein the weight percentage of the isocyanate is 5 to 15. 如請求項1所述之防蝕氟碳組合物,其中該醚類為乙二醇丁醚。The anticorrosive fluorocarbon composition according to claim 1, wherein the ether is ethylene glycol butyl ether. 如請求項1所述之防蝕氟碳組合物,其中該醇類為正丁醇。The anticorrosive fluorocarbon composition according to claim 1, wherein the alcohol is n-butanol.
TW107216624U 2018-12-06 2018-12-06 Anti-corrosion fluorocarbon composition TWM576164U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI704195B (en) * 2018-12-06 2020-09-11 盟鑫金屬股份有限公司 Anti-corrosion fluorocarbon composition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI704195B (en) * 2018-12-06 2020-09-11 盟鑫金屬股份有限公司 Anti-corrosion fluorocarbon composition

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