TWI704195B - Anti-corrosion fluorocarbon composition - Google Patents
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Abstract
Description
本發明係相關於一種防蝕組合物,特別是相關於一種防蝕氟碳組合物The present invention relates to an anti-corrosion composition, in particular to an anti-corrosion fluorocarbon composition
許多結構物的材質主要以金屬為主,當其處於高腐蝕因子的環境中,會使得金屬產生腐蝕而大幅減少其原本應有的性能,因而會於結構物上進行防蝕保護,以延長金屬結構的使用壽命。Many structures are mainly made of metal. When they are in an environment with high corrosion factors, the metal will corrode and greatly reduce its original performance. Therefore, the structure will be protected against corrosion to extend the metal structure. Life.
習知防蝕方式主要有電鍍、塗佈、熱浸及陰極保護等等,其中在塗佈方式中,係為將塗料塗覆於物體表面而形成薄膜以達到保護物體表面之效果,而使用的塗料包括環氧樹脂、油脂塗料及乳膠漆。The conventional anti-corrosion methods mainly include electroplating, coating, hot dipping, cathodic protection, etc. Among them, the coating method is to coat the paint on the surface of the object to form a thin film to achieve the effect of protecting the surface of the object. Including epoxy resin, grease paint and latex paint.
然而,上述塗料皆有其使用上的缺點。舉例而言,環氧樹脂不易乾燥,油脂塗料耐蝕度低、不易乾燥、質軟,以及乳膠漆柔韌性及附著力不佳,導致應用受到限制。綜上,習知之塗料有其改良的必要。However, the above-mentioned coatings all have disadvantages in their use. For example, epoxy resin is not easy to dry, grease paint has low corrosion resistance, is not easy to dry, soft, and latex paint has poor flexibility and adhesion, which limits its application. In summary, the conventional paint has its need for improvement.
緣此,本發明之目的在於提供一種防蝕氟碳組合物,能方便使用並提昇其防蝕效果。For this reason, the purpose of the present invention is to provide an anti-corrosion fluorocarbon composition that can be used conveniently and improve its anti-corrosion effect.
本發明為解決習知技術之問題所採用之技術手段係提供一種防蝕氟碳組合物,包含一第一成分,包括40至70重量百分比的一FEVE氟碳樹脂、5至30重量百分比的一醚類、5至30重量百分比的一醇類、0.2至2.5重量百分比的一表面調整劑、0.3至2.5重量百分比的一消泡劑以及0.2至2.5重量百分比的一搖變劑;以及一第二成分,包括3至30重量百分比的一異氰酸酯,其中,該第一成分與該第二成分的重量百分比為6:1至16:1。The technical means adopted by the present invention to solve the problems of the prior art is to provide an anticorrosive fluorocarbon composition comprising a first component, including 40 to 70 weight percent of a FEVE fluorocarbon resin, and 5 to 30 weight percent of an ether Type, 5 to 30 weight percent of an alcohol, 0.2 to 2.5 weight percent of a surface modifier, 0.3 to 2.5 weight percent of a defoaming agent, and 0.2 to 2.5 weight percent of a thixotropic agent; and a second component , Including 3 to 30 weight percent of an isocyanate, wherein the weight percent of the first component and the second component is 6:1 to 16:1.
在本發明的一實施例的防蝕氟碳組合物中,該第一成分包括不超過15重量百分比的一色母顏料。In the anticorrosive fluorocarbon composition of an embodiment of the present invention, the first component includes a master pigment not exceeding 15% by weight.
在本發明的一實施例的防蝕氟碳組合物中,該第一成分包括不超過2.5重量百分比的一催化劑。In the anticorrosive fluorocarbon composition of an embodiment of the present invention, the first component includes a catalyst not exceeding 2.5% by weight.
在本發明的一實施例的防蝕氟碳組合物中,該第二成分包括不超過30重量百分比的一醚類。In the anticorrosive fluorocarbon composition of an embodiment of the present invention, the second component includes not more than 30 weight percent of monoethers.
在本發明的一實施例的防蝕氟碳組合物中,該第二成分包括不超過30重量百分比的一醇類。In the anticorrosive fluorocarbon composition of an embodiment of the present invention, the second component includes not more than 30 weight percent of an alcohol.
在本發明的一實施例的防蝕氟碳組合物中,該FEVE氟碳樹脂之重量百分比為50至60。In the anticorrosive fluorocarbon composition of an embodiment of the present invention, the weight percentage of the FEVE fluorocarbon resin is 50-60.
在本發明的一實施例的防蝕氟碳組合物中,該異氰酸酯之重量百分比為5至15。In the anticorrosive fluorocarbon composition of an embodiment of the present invention, the weight percentage of the isocyanate is 5-15.
在本發明的一實施例的防蝕氟碳組合物中,該醚類為乙二醇丁醚。In the anticorrosive fluorocarbon composition of an embodiment of the present invention, the ether is ethylene glycol butyl ether.
在本發明的一實施例的防蝕氟碳組合物中,該醇類為正丁醇。In the anticorrosive fluorocarbon composition of an embodiment of the present invention, the alcohol is n-butanol.
本發明為解決習知技術之問題所採用之一另一技術手段係提供一種防蝕氟碳組合物作為金屬防蝕的用途。Another technical means adopted by the present invention to solve the problems of the conventional technology is to provide an anticorrosive fluorocarbon composition as a metal anticorrosion application.
經由本發明所採用之技術手段,防蝕氟碳組合物藉由第一成分與第二成分之交聯架橋相輔加成作用在常溫可自乾,且完全乾燥後具有高耐腐蝕性、高耐化學性及高耐候性。且,無論是常溫或是高溫防蝕氟碳組合物皆能固化,而便於使用。此外,根據施用的基材材質以及環境等因素,第一成分與第二成分之各個成分的含量可因應調整,而達到最佳功效。Through the technical means adopted by the present invention, the anticorrosive fluorocarbon composition can be self-dried at room temperature through the cross-linking and bridging of the first component and the second component, and has high corrosion resistance and high resistance after being completely dried. Chemical and high weather resistance. Moreover, the anticorrosive fluorocarbon composition can be cured at room temperature or high temperature, and is convenient to use. In addition, according to the applied substrate material and environmental factors, the content of each component of the first component and the second component can be adjusted accordingly to achieve the best effect.
以下根據第1a圖~第5b圖,而說明本發明的實施方式。該說明並非為限制本發明的實施方式,而為本發明之實施例的一種。Hereinafter, the embodiments of the present invention will be described based on Figs. 1a to 5b. This description is not intended to limit the implementation of the present invention, but is a kind of embodiment of the present invention.
依據本發明的一實施例的一種防蝕氟碳組合物,包含一第一成分及一第二成分。An anticorrosive fluorocarbon composition according to an embodiment of the present invention includes a first component and a second component.
詳細而言,第一成分包括40至70重量百分比的一FEVE氟碳樹脂、5至30重量百分比的一醚類、5至30重量百分比的一醇類、0.2至2.5重量百分比的一表面調整劑、0.3至2.5重量百分比的一消泡劑以及0.2至2.5重量百分比的一搖變劑。第二成分包括3至30重量百分比的一異氰酸酯。該第一成分與該第二成分的重量百分比為6:1至16:1。In detail, the first component includes 40 to 70 weight percent of a FEVE fluorocarbon resin, 5 to 30 weight percent of an ether, 5 to 30 weight percent of an alcohol, and 0.2 to 2.5 weight percent of a surface modifier , 0.3 to 2.5 weight percent of a defoaming agent and 0.2 to 2.5 weight percent of a thixotropic agent. The second component includes 3 to 30 weight percent monoisocyanate. The weight percentage of the first component to the second component is 6:1 to 16:1.
較佳的,該FEVE氟碳樹脂之重量百分比為50至60,以及該異氰酸酯之重量百分比為5至15。Preferably, the weight percentage of the FEVE fluorocarbon resin is 50-60, and the weight percentage of the isocyanate is 5-15.
詳細而言,該FEVE氟碳樹脂可為氟乙烯-乙烯基醚共聚物樹脂、該醚類可為乙二醇丁醚、該醇類可為正丁醇,以及該消泡劑可選自VersaFlow Base。In detail, the FEVE fluorocarbon resin can be a vinyl fluoride-vinyl ether copolymer resin, the ether can be ethylene glycol butyl ether, the alcohol can be n-butanol, and the defoamer can be selected from VersaFlow Base.
此外,在其他實施例中,該第一成分還可包括不超過15重量百分比的一色母顏料及/或不超過2.5重量百分比的一催化劑;以及該第二成分包括不超過30重量百分比的一醚類及/或不超過30重量百分比的一醇類。In addition, in other embodiments, the first component may further include a master pigment not exceeding 15% by weight and/or a catalyst not exceeding 2.5% by weight; and the second component may include a monoether not exceeding 30% by weight. And/or an alcohol with no more than 30 weight percent.
在本實施例中,本發明之防蝕氟碳組合物係為塗料,藉由刷塗、噴塗、輥塗等方式覆蓋於一物體表面,而作為防蝕的用途,特別是用以金屬防蝕。當然,本發明不以此為限。本發明之防蝕氟碳組合物亦可施用於其他材質以用於防蝕。詳細而言,本發明之防蝕氟碳組合物的第一成分與第二成分於使用前為個別存在,於使用時才被予以相互混合。較佳地,本發明之防蝕氟碳組合物的第一成分與第二成分之存放溫度不宜超過40℃及低於5℃。In this embodiment, the anticorrosive fluorocarbon composition of the present invention is a coating, which is coated on the surface of an object by brushing, spraying, roller coating, etc., for the purpose of anti-corrosion, especially for metal anti-corrosion. Of course, the present invention is not limited to this. The anti-corrosion fluorocarbon composition of the present invention can also be applied to other materials for anti-corrosion. In detail, the first component and the second component of the anticorrosive fluorocarbon composition of the present invention exist separately before use, and are mixed with each other during use. Preferably, the storage temperature of the first component and the second component of the anticorrosive fluorocarbon composition of the present invention should not exceed 40°C and lower than 5°C.
參照第1a圖及第1b圖,其分別為一鍍鋅鋼板有施塗本發明之防蝕氟碳組合物(第1a圖)及未施塗本發明之防蝕氟碳組合物(第1b圖)經鹽水噴霧試驗2000小時之實驗測試。可看到未施塗本發明之防蝕氟碳組合物的鍍鋅鋼板(第1b圖)之表面明顯有銹蝕現象。Referring to Figure 1a and Figure 1b, which are respectively a galvanized steel sheet with the anticorrosive fluorocarbon composition of the present invention applied (Figure 1a) and without the anticorrosive fluorocarbon composition of the present invention (Figure 1b). The salt spray test is a 2000-hour experimental test. It can be seen that the surface of the galvanized steel sheet (Figure 1b) to which the anticorrosive fluorocarbon composition of the present invention has not been applied has obvious corrosion.
類似地,參照第2a圖及第2b圖,其分別為一鍍鎂鋁鋅鋼板有施塗本發明之防蝕氟碳組合物(第2a圖)及未施塗本發明之防蝕氟碳組合物(第2b圖)經鹽水噴霧試驗2000小時之實驗測試。可看到未施塗本發明之防蝕氟碳組合物的鍍鎂鋁鋅鋼板(第2b圖)之表面明顯有銹蝕現象。Similarly, referring to Figures 2a and 2b, which are respectively a magnesium-aluminum-zinc-coated steel sheet with the anticorrosive fluorocarbon composition of the present invention applied (Figure 2a) and without the anticorrosive fluorocarbon composition of the present invention ( Figure 2b) Experimental test of 2000 hours of salt spray test. It can be seen that the surface of the magnesium-aluminum-zinc-plated steel sheet (Figure 2b) to which the anti-corrosion fluorocarbon composition of the present invention is not applied is obviously rusted.
類似地,參照第3a圖及第3b圖,其分別為一厚度為2.3mm的鍍鋅鋼板有施塗本發明之防蝕氟碳組合物(第3a圖)及未施塗本發明之防蝕氟碳組合物(第3b圖)經鹽水噴霧試驗250小時之實驗測試。可看到未施塗本發明之防蝕氟碳組合物的鍍鋅鋼板(第3b圖)之表面明顯有銹蝕現象。Similarly, referring to Figures 3a and 3b, which are respectively a galvanized steel sheet with a thickness of 2.3mm that has the anticorrosive fluorocarbon composition of the present invention applied (Figure 3a) and the anticorrosive fluorocarbon of the present invention is not applied. The composition (Figure 3b) was tested in a 250-hour salt spray test. It can be seen that the galvanized steel sheet (Figure 3b) to which the anticorrosive fluorocarbon composition of the present invention has not been applied has obvious corrosion on the surface.
類似地,參照第4a圖及第4b圖,其分別為一厚度為2.3mm的鍍鎂鋁鋅鋼板有施塗本發明之防蝕氟碳組合物(第4a圖)及未施塗本發明之防蝕氟碳組合物(第4b圖)經鹽水噴霧試驗500小時之實驗測試。可看到未施塗本發明之防蝕氟碳組合物的鍍鎂鋁鋅鋼板(第4b圖)之表面產生白銹。Similarly, referring to Figures 4a and 4b, which are respectively a 2.3mm-thick magnesium-aluminum-zinc coated steel sheet with the anticorrosive fluorocarbon composition of the present invention (Figure 4a) and without the anticorrosion of the present invention The fluorocarbon composition (Figure 4b) was tested in a 500-hour salt spray test. It can be seen that white rust is produced on the surface of the magnesium-aluminum-zinc-plated steel sheet (Figure 4b) to which the anticorrosive fluorocarbon composition of the present invention is not applied.
類似地,參照第5a圖及第5b圖,其分別為一熱軋耐候鋼有施塗本發明之防蝕氟碳組合物(第5a圖)及未施塗本發明之防蝕氟碳組合物(第5b圖)經5wt%鹽水噴霧試驗480小時之實驗測試。可看到未施塗本發明之防蝕氟碳組合物的熱軋耐候鋼(第5b圖)之表面明顯有銹蝕現象。Similarly, referring to Figures 5a and 5b, which are respectively a hot-rolled weathering steel applied with the anticorrosive fluorocarbon composition of the present invention (Figure 5a) and without the anticorrosive fluorocarbon composition of the present invention (Figure 5a) Figure 5b) 480 hours of experimental test after 5wt% salt water spray test. It can be seen that the surface of the hot-rolled weathering steel (Figure 5b) to which the anticorrosive fluorocarbon composition of the present invention is not applied has obvious rust.
綜上所述,本發明之防蝕氟碳組合物使用方便,易於刷塗、噴塗,常溫可自乾,亦能經輥塗且烘烤成膜;更重要的是,本發明之防蝕氟碳組合物無論有無經過烘烤,只要漆膜乾燥完全,均具有優良的防蝕效果。In summary, the anticorrosive fluorocarbon composition of the present invention is convenient to use, easy to brush and spray, and can be self-dried at room temperature. It can also be rolled and baked to form a film; more importantly, the anticorrosive fluorocarbon composition of the present invention Whether the material is baked or not, as long as the paint film is completely dry, it has an excellent anti-corrosion effect.
以上之敘述以及說明僅為本創作之較佳實施例之說明,對於此項技術具有通常知識者當可依據以下所界定申請專利範圍以及上述之說明而作其他之修改,惟此些修改仍應是為本創作之發明精神而在本創作之權利範圍中。The above descriptions and descriptions are only descriptions of the preferred embodiments of this creation. Those with general knowledge of this technology should make other modifications based on the scope of patent application defined below and the above descriptions, but these modifications should still be made. It is the inventive spirit of this creation and within the scope of rights of this creation.
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第1a圖係顯示經施用本發明的防蝕氟碳組合物的一鍍鋅鋼板的試驗結果照片; 第1b圖係顯示未施用本發明的防蝕氟碳組合物的一鍍鋅鋼板的試驗結果照片; 第2a圖係顯示經施用本發明的防蝕氟碳組合物的一鍍鎂鋁鋅鋼板的試驗結果照片; 第2b圖係顯示未施用本發明的防蝕氟碳組合物的一鍍鎂鋁鋅鋼板的試驗結果照片; 第3a圖係顯示經施用本發明的防蝕氟碳組合物的一鍍鋅鋼板的試驗結果照片; 第3b圖係顯示未施用本發明的防蝕氟碳組合物的一鍍鋅鋼板的試驗結果照片; 第4a圖係顯示經施用本發明的防蝕氟碳組合物的一鍍鎂鋁鋅鋼板的試驗結果照片; 第4b圖係顯示未施用本發明的防蝕氟碳組合物的一鍍鎂鋁鋅鋼板的試驗結果照片; 第5a圖係顯示經施用本發明的防蝕氟碳組合物的一熱軋耐候鋼(含銅鋼板)的試驗結果照片; 第5b圖係顯示未施用本發明的防蝕氟碳組合物的一熱軋耐候鋼(含銅鋼板)的試驗結果照片。Figure 1a is a photo showing the test result of a galvanized steel sheet to which the anticorrosive fluorocarbon composition of the present invention is applied; Figure 1b is a photo showing the test result of a galvanized steel sheet to which the anticorrosive fluorocarbon composition of the present invention is not applied; Figure 2a is a photo showing the test results of a magnesium-aluminum-zinc-coated steel sheet to which the anti-corrosion fluorocarbon composition of the present invention is applied; Figure 2b is a picture of a magnesium-aluminum-zinc-coated steel sheet that does not apply the anti-corrosion fluorocarbon composition of the present invention Test result photos; Figure 3a is a photo showing the test results of a galvanized steel sheet to which the anticorrosive fluorocarbon composition of the present invention is applied; Figure 3b is a picture of a galvanized steel sheet that does not apply the anticorrosive fluorocarbon composition of the present invention Photographs of the test results; Figure 4a is a photo showing the test results of a magnesium-aluminum-zinc steel plate to which the anticorrosive fluorocarbon composition of the present invention has been applied; Figure 4b is a photo showing a magnesium plated without the anticorrosive fluorocarbon composition of the present invention Photographs of the test results of aluminum-zinc steel sheets; Figure 5a is a photo showing the test results of a hot-rolled weathering steel (copper-containing steel plate) to which the anticorrosive fluorocarbon composition of the present invention is applied; Figure 5b shows that the corrosion protection of the present invention is not applied Photograph of test results of a hot-rolled weathering steel (copper-containing steel plate) of fluorocarbon composition.
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CN103555173A (en) * | 2013-10-22 | 2014-02-05 | 东南大学 | Normal temperature curing solvent type two-component erasable coating and preparation method thereof |
CN106221396A (en) * | 2016-08-12 | 2016-12-14 | 德阳烯碳科技有限公司 | A kind of Graphene heat radiation coating and preparation method thereof |
CN108165151A (en) * | 2017-12-25 | 2018-06-15 | 南京长江涂料有限公司 | A kind of watersoluble fluorine-carbon modified acrylic polyurethane finish paint and preparation method thereof |
TWM576164U (en) * | 2018-12-06 | 2019-04-01 | 盟鑫金屬股份有限公司 | Anti-corrosion fluorocarbon composition |
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