TWM573893U - Cleaning apparatus - Google Patents

Cleaning apparatus Download PDF

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Publication number
TWM573893U
TWM573893U TW107215710U TW107215710U TWM573893U TW M573893 U TWM573893 U TW M573893U TW 107215710 U TW107215710 U TW 107215710U TW 107215710 U TW107215710 U TW 107215710U TW M573893 U TWM573893 U TW M573893U
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Taiwan
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gas
liquid
fluid
cleaning device
cleaning
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TW107215710U
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Chinese (zh)
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黃富源
吳宗恩
王志成
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弘塑科技股份有限公司
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Priority to TW107215710U priority Critical patent/TWM573893U/en
Publication of TWM573893U publication Critical patent/TWM573893U/en

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Abstract

本揭示提供一種清洗裝置,用於去除晶片堆疊結構上之殘留物。清洗裝置包含:承載台,用於放置晶片堆疊結構,以及二流體噴嘴,可相對於承載台移動至與兩相鄰的晶片之間的間隔對準,其中二流體噴嘴用於施加包含化學液體和氣體的氣液混合流體至晶片堆疊結構上。經由氣液混合流體的化學液體使在間隙內之殘留物從其附著的表面分離,以及經由氣液混合流體的氣體施加的衝擊力將殘留物從間隙內帶出。 The present disclosure provides a cleaning apparatus for removing residues from a wafer stack structure. The cleaning apparatus includes: a carrier for placing the wafer stack structure, and a two-fluid nozzle movable relative to the carrier to an interval alignment with two adjacent wafers, wherein the two-fluid nozzle is for applying a chemical liquid and The gas-liquid mixed gas of the gas is applied to the wafer stack structure. The chemical liquid in the gap is separated from the surface to which it adheres via the chemical liquid of the gas-liquid mixed fluid, and the residual force is carried out from the gap by the impact force applied by the gas of the gas-liquid mixed fluid.

Description

清洗裝置 Cleaning device

本揭示是關於一種清洗裝置,特別是關於一種用於去除晶片堆疊結構上之殘留物的清洗裝置。 The present disclosure relates to a cleaning apparatus, and more particularly to a cleaning apparatus for removing residues on a wafer stack structure.

一般三維積體電路封裝製程包括:製作導孔(Via Formation)、填充導孔(Via Filling)、晶圓薄化(Wafer Thinning)、及晶圓接合(Wafer Bonding)等四大步驟,並且在每一個步驟前後必須進行晶圓洗淨步驟,以避免在處理過程中晶圓發生污染。進一步言之,晶圓接合的步驟大致上可分成晶片到晶圓(Chip to Wafer,C2W)、晶片到晶片(Chip to Chip,C2C)、晶圓到晶圓(Wafer to Wafer,W2W)等三種型式。然而,無論是晶圓與晶圓或晶圓與晶片接合所形成之間隙通常為20至50μm,因此如何去除此類微小間隙內之殘留物為目前急需克服挑戰之技術瓶頸。 The general three-dimensional integrated circuit packaging process includes four steps of making a Via Formation, a Via Filling, a Wafer Thinning, and a Wafer Bonding, and each A wafer cleaning step must be performed before and after a step to avoid contamination of the wafer during processing. Furthermore, the steps of wafer bonding can be roughly divided into three types: chip to wafer (C2W), chip to chip (C2C), wafer to wafer (Wafer to Wafer, W2W). Type. However, whether the gap formed by wafer-to-wafer or wafer-to-wafer bonding is usually 20 to 50 μm, how to remove the residue in such a small gap is a technical bottleneck that is urgently needed to overcome the challenge.

公告號為TW I539515號之台灣專利案已公開一種晶片堆疊結構之洗淨方法及洗淨設備,其可清洗晶圓與晶片接合之微小間隙內的助焊劑或其他雜質。然而,在該專利案中,其是採用在抽液裝置的底端設置滾輪型或毛刷型的滑移結構,如此抽液裝置是藉由滑移結構在基板上滑動以移動至一待清洗位置。也就是說,抽液裝置會對晶片堆疊結構施加下壓力,容易導致晶片損傷或破碎。 The Taiwan Patent Publication No. TW I539515 discloses a cleaning method and a cleaning apparatus for a wafer stack structure which can clean flux or other impurities in a minute gap between a wafer and a wafer. However, in the patent, it is to adopt a roller type or a brush type sliding structure at the bottom end of the liquid suction device, so that the liquid suction device slides on the substrate by the sliding structure to move to a to be cleaned. position. That is to say, the liquid suction device exerts a downward pressure on the wafer stack structure, which easily causes damage or breakage of the wafer.

有鑑於此,有必要提出一種清洗裝置,以解決習知技術中存在的問題。 In view of the above, it is necessary to propose a cleaning device to solve the problems in the prior art.

為解決上述習知技術之問題,本揭示之目的在於提供一種清洗裝置,藉由非接觸的方式清洗晶片堆疊結構,進而避免對晶片堆疊結構施加下壓力導致晶片損壞的問題。 In order to solve the above problems of the prior art, it is an object of the present disclosure to provide a cleaning apparatus for cleaning a wafer stack structure in a non-contact manner, thereby avoiding the problem of damage to the wafer caused by applying a downward pressure to the wafer stack structure.

為達成上述目的,本揭示提供一種清洗裝置,用於去除一晶片堆疊結構上之殘留物,該晶片堆疊結構包含一基板和複數個晶片,該晶片與該基板相隔一間隙,以及該殘留物位在該晶片與該基板之間的該間隙中,其中該清洗裝置包含:一承載台,用於放置該晶片堆疊結構;一供液裝置,用於提供一化學液體;一供氣裝置,用於提供一氣體;以及一二流體噴嘴,可相對於該承載台移動至與兩相鄰的晶片之間的間隔對準,其中該二流體噴嘴與該供液裝置和該供氣裝置連接,用於施加包含該化學液體和該氣體的氣液混合流體至該晶片堆疊結構之該基板上,使得該氣液混合流體沿著該間隙之第一側流入該間隙內,其中經由該氣液混合流體的該化學液體使在該間隙內之該殘留物從其附著的表面分離,以及經由該氣液混合流體的該氣體施加的衝擊力將該殘留物經由該間隙之第二側帶出。 In order to achieve the above object, the present disclosure provides a cleaning apparatus for removing a residue on a wafer stack structure, the wafer stack structure including a substrate and a plurality of wafers, the wafer is separated from the substrate by a gap, and the residue level In the gap between the wafer and the substrate, wherein the cleaning device comprises: a carrier for placing the wafer stack structure; a liquid supply device for providing a chemical liquid; and a gas supply device for Providing a gas; and a two-fluid nozzle movable relative to the carrier to an interval alignment with two adjacent wafers, wherein the two-fluid nozzle is coupled to the liquid supply device and the gas supply device for Applying a gas-liquid mixed fluid comprising the chemical liquid and the gas to the substrate of the wafer stack structure such that the gas-liquid mixed fluid flows into the gap along a first side of the gap, wherein the gas-liquid mixed fluid is passed through the gas-liquid mixed fluid The chemical liquid separates the residue in the gap from the surface to which it adheres, and the impact force applied by the gas of the gas-liquid mixed fluid passes the residue through the residue The second side of the band gap out.

於本揭示其中之一較佳實施例當中,該清洗裝置還包含:一精密驅動裝置,用於控制該二流體噴嘴相對該承載台沿著一垂直方向移動和沿著一水平方向移動。 In a preferred embodiment of the present disclosure, the cleaning apparatus further includes: a precision driving device for controlling the movement of the two fluid nozzles in a vertical direction relative to the loading platform and in a horizontal direction.

於本揭示其中之一較佳實施例當中,該精密驅動裝置包含一垂直升降機構用於控制該二流體噴嘴相對該承載台沿著該垂直方向移動, 該垂直升降機構包括步進馬達。 In a preferred embodiment of the present disclosure, the precision driving device includes a vertical lifting mechanism for controlling the movement of the two fluid nozzles relative to the loading table in the vertical direction. The vertical lifting mechanism includes a stepping motor.

於本揭示其中之一較佳實施例當中,該精密驅動裝置包含一水平移動機構用於控制該二流體噴嘴相對該承載台沿著該水平方向移動,該水平移動機構包括X-Y軸座標工作桌(X-Y Table)。 In a preferred embodiment of the present disclosure, the precision driving device includes a horizontal moving mechanism for controlling movement of the two-fluid nozzle relative to the loading table in the horizontal direction, the horizontal moving mechanism including an XY-axis coordinate working table ( XY Table).

於本揭示其中之一較佳實施例當中,該清洗裝置還包含一腔體,其中該承載台與該二流體噴嘴設置在該腔體內,且該腔體之底部設有一抽氣口。 In a preferred embodiment of the present disclosure, the cleaning device further includes a cavity, wherein the carrier and the two-fluid nozzle are disposed in the cavity, and a suction port is disposed at a bottom of the cavity.

於本揭示其中之一較佳實施例當中,該清洗裝置還包含一氣液分離裝置,其中該氣液分離裝置與該腔體之該抽氣口連接,用於將經由該抽氣口抽出的該氣液混合流體進行氣液分離。 In a preferred embodiment of the present disclosure, the cleaning device further includes a gas-liquid separation device, wherein the gas-liquid separation device is coupled to the suction port of the cavity for extracting the gas and liquid through the suction port. The mixed fluid is subjected to gas-liquid separation.

於本揭示其中之一較佳實施例當中,該供氣裝置包含一加熱器,用於將該供氣裝置內的該氣體加熱至與該化學液體的溫度相近。 In a preferred embodiment of the present disclosure, the gas supply device includes a heater for heating the gas in the gas supply device to a temperature close to the chemical liquid.

於本揭示其中之一較佳實施例當中,該供氣裝置包含一加濕器,用於增加該供氣裝置內的該氣體的濕度。 In a preferred embodiment of the present disclosure, the gas supply device includes a humidifier for increasing the humidity of the gas in the gas supply device.

於本揭示其中之一較佳實施例當中,該承載台包含另一加熱器,用於將該承載台上的該晶片堆疊結構加熱以保持在一製程溫度。 In one preferred embodiment of the present disclosure, the carrier includes another heater for heating the wafer stack on the stage to maintain a process temperature.

於本揭示其中之一較佳實施例當中,該清洗裝置包含複數個二流體噴嘴,以一排並列的方式對齊排列,並且該複數個二流體噴嘴可相對於該承載台移動至與兩排相鄰的晶片之間的間隔對準。 In a preferred embodiment of the present disclosure, the cleaning device includes a plurality of two-fluid nozzles aligned in a row and juxtaposed, and the plurality of two-fluid nozzles are movable relative to the carrier to two rows The spacing between adjacent wafers is aligned.

於本揭示其中之一較佳實施例當中,該清洗裝置之該二流體噴嘴的前端設置為相對於該清洗晶片堆疊結構的表面傾斜一角度。 In a preferred embodiment of the present disclosure, the front end of the two-fluid nozzle of the cleaning device is disposed at an angle to the surface of the cleaning wafer stack.

於本揭示其中之一較佳實施例當中,該二流體噴嘴包含高壓 清洗噴嘴。 In a preferred embodiment of the present disclosure, the two-fluid nozzle comprises a high pressure Clean the nozzle.

相較於先前技術,本揭示藉由在清洗裝置中採用二流體噴嘴施加氣液混合流體至晶片堆疊結構上,並藉由氣液混合流體清洗晶片堆疊結構之間隙的殘留物。清洗時,氣液混合流體的化學液體使在間隙內之殘留物從其附著的表面分離,以及氣液混合流體的氣體施加的衝擊力將殘留物經由間隙之第二側帶出。藉此設計,本揭示可實現以非接觸的方式清洗晶片堆疊結構,進而避免對晶片堆疊結構施加下壓力導致晶片損壞的問題。 In contrast to the prior art, the present disclosure applies a gas-liquid mixed fluid to a wafer stack structure using a two-fluid nozzle in a cleaning device, and cleans the residue in the gap of the wafer stack structure by a gas-liquid mixed fluid. During cleaning, the chemical liquid of the gas-liquid mixed fluid separates the residue in the gap from the surface to which it adheres, and the impact force exerted by the gas of the gas-liquid mixed fluid carries the residue out through the second side of the gap. By this design, the present disclosure can achieve a non-contact cleaning of the wafer stack structure, thereby avoiding the problem of applying a downforce to the wafer stack structure resulting in wafer damage.

1‧‧‧清洗裝置 1‧‧‧cleaning device

100‧‧‧腔體 100‧‧‧ cavity

101‧‧‧抽氣口 101‧‧‧Exhaust port

110‧‧‧承載台 110‧‧‧Loading station

111‧‧‧加熱器 111‧‧‧heater

120‧‧‧供液裝置 120‧‧‧Liquid supply device

121‧‧‧供應端 121‧‧‧Supply

122‧‧‧管路 122‧‧‧pipe

123‧‧‧化學液體 123‧‧‧Chemical liquid

130‧‧‧供氣裝置 130‧‧‧ gas supply unit

131‧‧‧氣體供應端 131‧‧‧ gas supply

132‧‧‧管路 132‧‧‧ pipeline

133‧‧‧氣體 133‧‧‧ gas

134‧‧‧加熱器 134‧‧‧heater

135‧‧‧加濕器 135‧‧‧ humidifier

140‧‧‧二流體噴嘴 140‧‧‧Two fluid nozzle

150‧‧‧氣液混合流體 150‧‧‧ gas-liquid mixed fluid

160‧‧‧氣液分離裝置 160‧‧‧ gas-liquid separation device

161‧‧‧液體回收槽 161‧‧‧Liquid recovery tank

170‧‧‧精密驅動裝置 170‧‧‧Precision drive

2‧‧‧晶片堆疊結構 2‧‧‧ wafer stack structure

S‧‧‧基板 S‧‧‧Substrate

C‧‧‧晶片 C‧‧‧ wafer

B‧‧‧連接件 B‧‧‧Connecting parts

G‧‧‧間隙 G‧‧‧ gap

D‧‧‧間隔 D‧‧‧ interval

R‧‧‧殘留物 R‧‧‧residue

P1‧‧‧第一側 P1‧‧‧ first side

P2‧‧‧第二側 P2‧‧‧ second side

3‧‧‧乾燥裝置 3‧‧‧Drying device

310‧‧‧旋轉夾持台 310‧‧‧Rotary clamping table

320‧‧‧第一噴嘴 320‧‧‧first nozzle

330‧‧‧二流體噴嘴 330‧‧‧Two fluid nozzle

440、540‧‧‧二流體噴嘴 440, 540‧‧‧ two fluid nozzle

θ‧‧‧角度 Θ‧‧‧ angle

第1圖顯示本揭示之第一較佳實施例之清洗裝置之示意圖;第2圖顯示第1圖之清洗裝置之局部結構示意圖;第3圖顯示清洗裝置之移動機構之示意圖;第4圖顯示本揭示之清洗方法中對應使用之乾燥裝置之示意圖;第5圖顯示本揭示之第二較佳實施例之清洗裝置之局部示意圖;以及第6圖顯示本揭示之第三較佳實施例之清洗裝置之局部示意圖。 1 is a schematic view showing a cleaning apparatus of a first preferred embodiment of the present disclosure; FIG. 2 is a partial structural view showing the cleaning apparatus of FIG. 1; FIG. 3 is a schematic view showing a moving mechanism of the cleaning apparatus; A schematic view of a drying device corresponding to the cleaning method of the present disclosure; FIG. 5 is a partial schematic view showing the cleaning device of the second preferred embodiment of the present disclosure; and FIG. 6 is a view showing the cleaning of the third preferred embodiment of the present disclosure. A partial schematic of the device.

為了讓本揭示之上述及其他目的、特徵、優點能更明顯易懂,下文將特舉本揭示較佳實施例,並配合所附圖式,作詳細說明如下。 The above and other objects, features, and advantages of the present invention will become more apparent and understood.

微處理器的晶片包括邏輯單元和複數個快取記憶體,若邏輯單元和快取記憶體皆以二維(Two-Dimensional,2-D)圖案配置,則晶片的實體尺寸將限制快取記憶體的數量(因為大面積晶片的製程不良所造成),從而侷限了微處理器的性能。為解決晶片上的2-D資源問題,目前正積極開發建 構三維(Three-Dimensional,3-D)積體電路。一般來說,典型的3D-IC製程包括:製作導孔(Via Formation)、填充導孔(Via Filling)、晶圓薄化(Wafer Thinning)、及晶圓接合(Wafer Bonding)等四大步驟,並且在每一個步驟前後必須進行晶圓洗淨的步驟,以避免晶圓在處理過程中發生污染。進一步言之,晶圓接合的步驟大致上可分成晶片到晶圓(Chip to Wafer,C2W)、晶片到晶片(Chip to Chip,C2C)、晶圓到晶圓(Wafer to Wafer,W2W)等三種型式。然而,無論是晶圓與晶圓或晶圓與晶片接合所形成之間隙通常為20~50μm。本揭示的清洗裝置與清洗方法可實現去除此類微小間隙內殘留物。 The microprocessor chip includes a logic unit and a plurality of cache memories. If both the logic unit and the cache memory are configured in a two-dimensional (2-D) pattern, the physical size of the wafer will limit the cache memory. The number of bodies (due to poor processing of large-area wafers) limits the performance of the microprocessor. In order to solve the problem of 2-D resources on the wafer, a Three-Dimensional (3-D) integrated circuit is being actively developed. In general, a typical 3D-IC process includes four steps: making a Via Formation, filling a Via Filling, Wafer Thinning, and Wafer Bonding. And the wafer cleaning step must be performed before and after each step to avoid contamination of the wafer during processing. Furthermore, the steps of wafer bonding can be roughly divided into three types: chip to wafer (C2W), chip to chip (C2C), wafer to wafer (Wafer to Wafer, W2W). Type. However, the gap between wafer and wafer or wafer and wafer bonding is typically 20 to 50 μm . The cleaning apparatus and cleaning method of the present disclosure can achieve the removal of residues in such minute gaps.

請參照第1圖,其顯示本揭示之第一較佳實施例之清洗裝置1之示意圖。清洗裝置1是用於去除晶片堆疊結構2上之殘留物R,其中殘留物R可能為先前製程殘留下來的物質,例如助焊劑、樹脂、黏膠、微粒、有機物、無機物等。晶片堆疊結構2為一種三維積體電路板,其包含基板S和複數個以陣列排列的晶片C。晶片C與基板S之間設有複數個連接件B。連接件B可為焊接基板S與晶片C的錫球或任何適當的元件。連接件B用於連接基板S與晶片C且使基板S與晶片C相隔一間隙G,其中清洗裝置1欲去除的物質為位在基板S與晶片C之間的間隙G內的殘留物R。 Referring to Figure 1, there is shown a schematic view of a cleaning apparatus 1 of a first preferred embodiment of the present disclosure. The cleaning device 1 is for removing the residue R on the wafer stack structure 2, wherein the residue R may be a substance remaining in a previous process, such as flux, resin, adhesive, particles, organic matter, inorganic matter, and the like. The wafer stack structure 2 is a three-dimensional integrated circuit board including a substrate S and a plurality of wafers C arranged in an array. A plurality of connecting members B are disposed between the wafer C and the substrate S. Connector B can be a solder ball or any suitable component that solders substrate S to wafer C. The connector B is used to connect the substrate S and the wafer C and to separate the substrate S from the wafer C by a gap G, wherein the substance to be removed by the cleaning device 1 is the residue R located in the gap G between the substrate S and the wafer C.

如第1圖所示,清洗裝置1主要包含腔體100、承載台110、供液裝置120、供氣裝置130、二流體噴嘴140、氣液分離裝置160,其中承載台110與二流體噴嘴140設在腔體100內。腔體100之底部設有抽氣口101,並且氣液分離裝置160與腔體100之抽氣口101連接。承載台110用於放置晶片堆疊結構2。承載台110包含加熱器111,用於將承載台110上的晶片堆疊結構2加熱以保持在適當的製程溫度。 As shown in FIG. 1 , the cleaning device 1 mainly includes a cavity 100 , a loading platform 110 , a liquid supply device 120 , a gas supply device 130 , a two-fluid nozzle 140 , and a gas-liquid separation device 160 , wherein the loading platform 110 and the two-fluid nozzle 140 It is disposed in the cavity 100. A suction port 101 is provided at the bottom of the cavity 100, and the gas-liquid separation device 160 is connected to the suction port 101 of the cavity 100. The carrier 110 is used to place the wafer stack structure 2. The carrier 110 includes a heater 111 for heating the wafer stack structure 2 on the carrier 110 to maintain the proper process temperature.

請參照第1圖和第2圖,其中第2圖顯示第1圖之清洗裝置1之局部結構示意圖。供液裝置120包含液體供應端121和管路122,其中液體供應端121內裝有化學液體123。供氣裝置130包含氣體供應端131和管路132,其中氣體供應端131內裝有氣體133。可選地,氣體133可為氮氣、潔淨乾空氣(Clean Dry Air,CDA)等等。二流體噴嘴140與供液裝置120和供氣裝置130連接,用於將供液裝置120提供的化學液體123和供氣裝置130提供的氣體133兩者混合形成氣液混合流體150,並將氣液混合流體150噴出至晶片堆疊結構2之基板S上。 Please refer to FIG. 1 and FIG. 2, wherein FIG. 2 is a partial schematic view showing the cleaning device 1 of FIG. The liquid supply device 120 includes a liquid supply end 121 and a line 122, wherein the liquid supply end 121 contains a chemical liquid 123 therein. The gas supply device 130 includes a gas supply end 131 and a line 132, wherein the gas supply end 131 contains a gas 133 therein. Alternatively, the gas 133 may be nitrogen, Clean Dry Air (CDA), or the like. The two-fluid nozzle 140 is connected to the liquid supply device 120 and the gas supply device 130 for mixing the chemical liquid 123 provided by the liquid supply device 120 and the gas 133 provided by the gas supply device 130 to form a gas-liquid mixed fluid 150, and the gas The liquid mixed fluid 150 is ejected onto the substrate S of the wafer stack structure 2.

如第2圖所示,供氣裝置130還包含加熱器134和加濕器135。為了要去除晶片堆疊結構2上的殘留物R,採用帶有一定溫度的化學液體123能加快化學液體123與殘留物R之間的反應,使得殘留物R從其附著的表面分離。然而,當氣體133與化學液體123混合時,氣體133會使化學液體123的溫度下降。因此,本揭示藉由提供加熱器134使得供氣裝置130內的氣體133可被加熱至與化學液體123的溫度相近,進而避免化學液體123因低溫氣體133的影響而導致溫度下降的問題。又,本揭示藉由提供加濕器135來增加供氣裝置130內的氣體133的濕度,以防止化學液體123的溫度受到氣體133濕度影響而產生變化。 As shown in FIG. 2, the air supply device 130 further includes a heater 134 and a humidifier 135. In order to remove the residue R on the wafer stack 2, the use of a chemical liquid 123 with a certain temperature accelerates the reaction between the chemical liquid 123 and the residue R, so that the residue R is separated from the surface to which it adheres. However, when the gas 133 is mixed with the chemical liquid 123, the gas 133 causes the temperature of the chemical liquid 123 to drop. Therefore, the present disclosure provides the heater 134 so that the gas 133 in the gas supply device 130 can be heated to be close to the temperature of the chemical liquid 123, thereby preventing the chemical liquid 123 from being lowered due to the influence of the low temperature gas 133. Further, the present disclosure increases the humidity of the gas 133 in the air supply device 130 by providing the humidifier 135 to prevent the temperature of the chemical liquid 123 from being affected by the humidity of the gas 133.

請參照第3圖,其顯示清洗裝置1之移動機構之示意圖。清洗裝置1的移動機構可由精密驅動裝置170來實施。精密驅動裝置170具有垂直升降機構和水平移動機構。精密驅動裝置170之垂直升降機構和水平移動機構分別電性連接至主控裝置(例如電腦),進而可通過主控裝置內的控制程序來設定清洗裝置1之移動機構的作動。 Please refer to FIG. 3, which shows a schematic diagram of the moving mechanism of the cleaning device 1. The moving mechanism of the cleaning device 1 can be implemented by the precision driving device 170. The precision driving device 170 has a vertical lifting mechanism and a horizontal moving mechanism. The vertical lifting mechanism and the horizontal moving mechanism of the precision driving device 170 are electrically connected to the main control device (for example, a computer), and the operation of the moving mechanism of the cleaning device 1 can be set by a control program in the main control device.

如第3圖所示,精密驅動裝置170與二流體噴嘴140連接。垂直升降機構具有與二流體噴嘴140連接之連接件和精密驅動元件(例如步進馬達),用於控制二流體噴嘴140相對承載台110沿著垂直方向移動(即遠離或靠近承載台110的方向)。通過精密驅動元件的設置,可精確控制二流體噴嘴140上下移動位置。較佳地,精密驅動裝置170可搭配座標量測機構,記錄二流體噴嘴140在垂直方向上的移動位置與速度。另外,水平移動機構是用於控制二流體噴嘴140的水平移動。舉例來說,水平移動機構可採用X-Y軸座標工作桌(X-Y Table),以精確控制二流體噴嘴140之水平移動,進而精確對準至清洗位置。又,X-Y軸座標工作桌可搭配記錄二流體噴嘴140移動位置之點位記錄裝置,以利於量產時能快速尋找同一圖案之晶片堆疊結構2所需要之二流體噴嘴140之定位點。應當注意的是,為了配合上述精確點位設定,承載台110較佳地是採用真空吸附的方式將晶片堆疊結構2保持於其上,如此可確保晶片堆疊結構2不會在清洗過程中與承載台110產生相對移動。 As shown in FIG. 3, the precision drive unit 170 is coupled to the two-fluid nozzle 140. The vertical lifting mechanism has a connector connected to the two-fluid nozzle 140 and a precision driving element (for example, a stepping motor) for controlling the movement of the two-fluid nozzle 140 in the vertical direction relative to the carrier 110 (ie, away from or near the stage 110). ). By setting the precision driving element, the position of the two-fluid nozzle 140 to move up and down can be precisely controlled. Preferably, the precision driving device 170 can be combined with a coordinate measuring mechanism to record the moving position and speed of the two-fluid nozzle 140 in the vertical direction. In addition, the horizontal movement mechanism is for controlling the horizontal movement of the two-fluid nozzle 140. For example, the horizontal moving mechanism can employ an X-Y axis table (X-Y Table) to precisely control the horizontal movement of the two-fluid nozzle 140 to accurately align to the cleaning position. Moreover, the X-Y axis coordinate working table can be used with a point recording device for recording the moving position of the two-fluid nozzle 140, so as to facilitate the rapid positioning of the positioning point of the two-fluid nozzle 140 required for the wafer stack structure 2 of the same pattern during mass production. It should be noted that in order to cooperate with the precise point setting described above, the carrier 110 preferably holds the wafer stack 2 thereon by vacuum adsorption, thus ensuring that the wafer stack 2 is not carried during the cleaning process. Stage 110 produces relative movement.

本揭示之目的在於提供一種清洗裝置及方法,其中清洗裝置1藉由非接觸的方式清洗晶片堆疊結構2,進而避免對晶片堆疊結構2施加下壓力導致晶片C損壞的問題。本揭示的清洗方法的部分步驟是由清洗裝置1來執行,其中清洗方法的具體步驟搭配上述清洗裝置1詳述於後。 It is an object of the present disclosure to provide a cleaning apparatus and method in which the cleaning apparatus 1 cleans the wafer stack structure 2 in a non-contact manner, thereby avoiding the problem that the wafer C is damaged by applying a downward pressure to the wafer stack structure 2. Part of the steps of the cleaning method of the present disclosure is performed by the cleaning device 1, wherein the specific steps of the cleaning method are detailed later with the cleaning device 1.

本揭示之清洗方法包含下述步驟,首先,請參照第1圖,在承載台110上放置晶片堆疊結構2。開啟承載台110上之加熱器111,將承載台110上的晶片堆疊結構2加熱,以保持晶片堆疊結構2在適當的製程溫度。通過溫度的保持,能使得後續施加的化學液體123保持在適當的製程溫度而不 會被降溫,進而加快化學液體123與殘留物R之間的反應,以將殘留物R從其附著的表面分離。 The cleaning method of the present disclosure includes the following steps. First, referring to FIG. 1, the wafer stack structure 2 is placed on the stage 110. The heater 111 on the stage 110 is opened to heat the wafer stack 2 on the stage 110 to maintain the wafer stack 2 at a suitable process temperature. By maintaining the temperature, the subsequently applied chemical liquid 123 can be maintained at an appropriate process temperature without It will be cooled, thereby accelerating the reaction between the chemical liquid 123 and the residue R to separate the residue R from the surface to which it adheres.

如第1圖和第3圖所示,當晶片堆疊結構2放置完成之後,藉由精密驅動裝置170控制二流體噴嘴140在承載台110上方移動,以將二流體噴嘴140移動至與兩相鄰的晶片C之間的間隔D對準,以及移動至與間隙G之第一側P1對準。 As shown in FIGS. 1 and 3, after the wafer stack 2 is placed, the two-fluid nozzle 140 is controlled to move over the stage 110 by the precision driving device 170 to move the two-fluid nozzle 140 to be adjacent to the two. The spacing D between the wafers C is aligned and moved to align with the first side P1 of the gap G.

如第1圖和第2圖所示,藉由加濕器135增加供氣裝置130內的氣體133的濕度,以及藉由加熱器134將供氣裝置130內的氣體133加熱至與化學液體123的溫度相近。接著,供氣裝置130和供液裝置120分別將氣體133和化學液體123傳輸到二流體噴嘴140。氣體133和化學液體123在二流體噴嘴140內部混合後形成氣液混合流體150。 As shown in FIGS. 1 and 2, the humidity of the gas 133 in the air supply device 130 is increased by the humidifier 135, and the gas 133 in the air supply device 130 is heated to the chemical liquid 123 by the heater 134. The temperature is similar. Next, the gas supply device 130 and the liquid supply device 120 transfer the gas 133 and the chemical liquid 123 to the two-fluid nozzle 140, respectively. The gas 133 and the chemical liquid 123 are mixed inside the two-fluid nozzle 140 to form a gas-liquid mixed fluid 150.

接著,如第1圖所示,藉由二流體噴嘴140施加氣液混合流體150至晶片堆疊結構2之基板S上,使得氣液混合流體150沿著間隙G之第一側P1流入間隙G內。經由氣液混合流體150的化學液體123與在間隙G內之殘留物R發生化學清洗反應,促使殘留物R從其附著的表面分離,以及經由氣液混合流體150的氣體133所施加的衝擊力將殘留物R經由間隙G之第二側P2帶出。應當注意的是,二流體噴嘴140在噴灑氣液混合流體150的同時,精密驅動裝置170會控制二流體噴嘴140沿著水平方向移動。較佳地,二流體噴嘴140是沿著兩相鄰的晶片C之間的間隔D平行移動。然而,在另一實施例中,為了使控制程序簡單化,可將精密驅動裝置170設定為當沿著X方向移動時,只是將二流體噴嘴140從兩相鄰的晶片C之間的間隔D移動至另兩相鄰的晶片C之間的間隔D,當二流體噴嘴140沿著X方向噴灑完整面晶片堆疊結 構2之後,將承載台110旋轉90度。接者使精密驅動裝置170設定二流體噴嘴140沿著Y方向移動時,二流體噴嘴140會對應至兩相鄰的晶片C之間的間隔D,並且沿著間隔D延伸的方向平行移動,此時氣液混合流體150的噴灑作業會同步進行,並且再一次進行上述的全面噴灑作業,如此可確保晶片堆疊結構2的間隙G皆會被清洗乾淨。 Next, as shown in FIG. 1, the gas-liquid mixed fluid 150 is applied to the substrate S of the wafer stack structure 2 by the two-fluid nozzle 140, so that the gas-liquid mixed fluid 150 flows into the gap G along the first side P1 of the gap G. . The chemical liquid 123 passing through the gas-liquid mixed fluid 150 undergoes a chemical cleaning reaction with the residue R in the gap G, causing the residue R to be separated from the surface to which it adheres, and the impact force applied by the gas 133 of the gas-liquid mixed fluid 150. The residue R is taken out via the second side P2 of the gap G. It should be noted that while the two-fluid nozzle 140 is spraying the gas-liquid mixed fluid 150, the precision driving device 170 controls the two-fluid nozzle 140 to move in the horizontal direction. Preferably, the two-fluid nozzle 140 is moved in parallel along the interval D between two adjacent wafers C. However, in another embodiment, in order to simplify the control program, the precision driving device 170 can be set to only move the two-fluid nozzle 140 from the interval D between two adjacent wafers C when moving in the X direction. Moving to the interval D between the other two adjacent wafers C, when the two-fluid nozzle 140 sprays the full-face wafer stack junction along the X direction After the structure 2, the stage 110 is rotated by 90 degrees. When the precision driving device 170 sets the two-fluid nozzle 140 to move in the Y direction, the two-fluid nozzle 140 corresponds to the interval D between two adjacent wafers C, and moves in parallel along the direction in which the interval D extends. The spraying operation of the gas-liquid mixed fluid 150 is simultaneously performed, and the above-described full-spraying operation is performed again, so that the gap G of the wafer stack structure 2 is cleaned.

在本揭示中,供液裝置120除了可以提供化學液體123以外,還可以提供清洗液體,例如純水、去離子水等。並且,在經由氣液混合流體150將在間隙G內的殘留物R去除之後,供液裝置120可切換為提供清洗液體至二流體噴嘴140,使得二流體噴嘴140對晶片堆疊結構2噴灑清洗液體,以去除晶片堆疊結構2上的氣液混合流體150。 In the present disclosure, the liquid supply device 120 may provide a cleaning liquid such as pure water, deionized water or the like in addition to the chemical liquid 123. Also, after the residue R in the gap G is removed via the gas-liquid mixed fluid 150, the liquid supply device 120 can be switched to supply the cleaning liquid to the two-fluid nozzle 140, so that the two-fluid nozzle 140 sprays the cleaning liquid on the wafer stack structure 2. To remove the gas-liquid mixed fluid 150 on the wafer stack 2.

另一方面,如第1圖所示,當二流體噴嘴140對晶片堆疊結構2噴灑氣液混合流體150或清洗液體的同時,可藉由氣液分離裝置160將經由腔體100之抽出口101抽出的液體和氣體進行氣液分離。較佳地,氣液分離裝置160設置有過濾器,其可將抽取的固體殘留物R先行過濾,接著將液體和氣體分離,最後將液體導入液體回收槽161內,以及將氣體排出。因此,經由氣液分離後回收的液體可經由適當地處理後再利用。此外,可在液體回收槽161加設流量計用以記錄抽液流量值。 On the other hand, as shown in FIG. 1, when the two-fluid nozzle 140 sprays the gas-liquid mixed fluid 150 or the cleaning liquid on the wafer stack structure 2, the gas-liquid separation device 160 can take the outlet 101 through the cavity 100. The extracted liquid and gas are subjected to gas-liquid separation. Preferably, the gas-liquid separation device 160 is provided with a filter which filters the extracted solid residue R first, then separates the liquid from the gas, finally introduces the liquid into the liquid recovery tank 161, and discharges the gas. Therefore, the liquid recovered after the gas-liquid separation can be reused after being appropriately treated. Further, a flow meter may be added to the liquid recovery tank 161 for recording the pumping flow rate value.

在將晶片堆疊結構2的間隙G內的殘留物R去除之後,晶片堆疊結構2會被移動至乾燥裝置內,以對晶片堆疊結構2進行最後的清潔與乾燥步驟。請參照第4圖所示,其顯示本揭示之清洗方法中對應使用之乾燥裝置3之示意圖。乾燥裝置3包含旋轉夾持台310、第一噴嘴320、和二流體噴嘴330。第一噴嘴320與液體供應端連接,以及二流體噴嘴330與揮發性溶劑 供應端和氣體供應端連接。當晶片堆疊結構2移動至乾燥裝置內之後,第一噴嘴320對晶片堆疊結構2之基板S之背面噴灑清洗液體,以去除基板S之背面上殘留的氣液混合流體150,其中清洗液體可為純水、去離子水等。 After the residue R in the gap G of the wafer stack structure 2 is removed, the wafer stack structure 2 is moved into the drying device to perform a final cleaning and drying step on the wafer stack structure 2. Referring to Figure 4, there is shown a schematic diagram of the drying apparatus 3 used in the cleaning method of the present disclosure. The drying device 3 includes a rotating clamping table 310, a first nozzle 320, and a two-fluid nozzle 330. The first nozzle 320 is connected to the liquid supply end, and the two-fluid nozzle 330 and the volatile solvent The supply end is connected to the gas supply end. After the wafer stack structure 2 is moved into the drying device, the first nozzle 320 sprays the cleaning liquid on the back surface of the substrate S of the wafer stack structure 2 to remove the gas-liquid mixed fluid 150 remaining on the back surface of the substrate S, wherein the cleaning liquid may be Pure water, deionized water, etc.

接著,當晶片堆疊結構2的正反兩面都清洗乾淨後,通過二流體噴嘴330對晶片堆疊結構2同時供給揮發性溶劑和乾燥氣體,以去除晶片堆疊結構2之表面的水分,其中揮發性溶劑可為異丙醇(Isopropyl Alcohol,IPA),以及乾燥氣體可為氮氣。可選地,當晶片堆疊結構2的正反兩面都清洗乾淨後,也可採用將晶片堆疊結構2放置在烤箱內來去除晶片堆疊結構2之表面的水分,不侷限於此。 Then, after the front and back sides of the wafer stack 2 are cleaned, the wafer stack 2 is simultaneously supplied with a volatile solvent and a drying gas through the two-fluid nozzle 330 to remove moisture on the surface of the wafer stack 2, wherein the volatile solvent It may be Isopropyl Alcohol (IPA), and the drying gas may be nitrogen. Alternatively, after the front and back sides of the wafer stack 2 are cleaned, the moisture of the surface of the wafer stack 2 may be removed by placing the wafer stack 2 in the oven, without being limited thereto.

請參照第5圖,其顯示本揭示之第二較佳實施例之清洗裝置之局部示意圖。第二較佳實施例之清洗裝置大致相同於第一較佳實施例之清洗裝置1,差別在於,第二較佳實施例之清洗裝置是採用複數個二流體噴嘴240的設置,如此可一次性地清洗晶片堆疊結構2之晶片C與基板S之間的複數個間隙G。具體來說,複數個二流體噴嘴440是以一排並列的方式對齊排列,並且複數個二流體噴嘴440可移動至與兩排相鄰的晶片C之間的複數個間隙G對準。藉此設計,可有效地縮短晶片堆疊結構2之清洗時間,以提升清洗效能。 Please refer to FIG. 5, which shows a partial schematic view of the cleaning device of the second preferred embodiment of the present disclosure. The cleaning device of the second preferred embodiment is substantially the same as the cleaning device 1 of the first preferred embodiment, except that the cleaning device of the second preferred embodiment is provided with a plurality of two-fluid nozzles 240, so that it can be disposable A plurality of gaps G between the wafer C and the substrate S of the wafer stack structure 2 are cleaned. Specifically, a plurality of two-fluid nozzles 440 are aligned in a row in a side-by-side arrangement, and a plurality of two-fluid nozzles 440 are movable to align with a plurality of gaps G between two adjacent rows of wafers C. By this design, the cleaning time of the wafer stack structure 2 can be effectively shortened to improve the cleaning performance.

請參照第6圖,其顯示本揭示之第三較佳實施例之清洗裝置之局部示意圖。第三較佳實施例之清洗裝置大致相同於第一較佳實施例之清洗裝置1,差別在於,第三較佳實施例之清洗裝置是將二流體噴嘴540的前端設置為相對於清洗晶片堆疊結構2的表面傾斜一角度θ。較佳地,該角度θ為30至60度。並且,搭配精密驅動裝置控制二流體噴嘴朝單一方向移動 且進行噴灑作業,使得殘留物R可以帶往同一方向移動。舉例來說,當二流體噴嘴540是以右上朝向左下的方向傾斜,以及精密驅動裝置控制二流體噴嘴由右往左的方向移動且進行噴灑作業時,殘留物R會被帶往左邊的方向移動。藉此設計,可防止殘留物R被沖回已清洗過的間隙G內。 Referring to Figure 6, there is shown a partial schematic view of a cleaning apparatus in accordance with a third preferred embodiment of the present disclosure. The cleaning apparatus of the third preferred embodiment is substantially the same as the cleaning apparatus 1 of the first preferred embodiment, except that the cleaning apparatus of the third preferred embodiment sets the front end of the two-fluid nozzle 540 to be stacked with respect to the cleaning wafer. The surface of the structure 2 is inclined by an angle θ. Preferably, the angle θ is 30 to 60 degrees. And with a precision drive to control the two-fluid nozzle to move in a single direction The spraying operation is performed so that the residue R can be moved in the same direction. For example, when the two-fluid nozzle 540 is inclined in the upper right direction toward the lower left direction, and the precision driving device controls the two-fluid nozzle to move from the right to the left direction and performs the spraying operation, the residue R is moved to the left direction. . With this design, the residue R can be prevented from being flushed back into the cleaned gap G.

綜上所述,本揭示藉由在清洗裝置中採用二流體噴嘴施加氣液混合流體至晶片堆疊結構上,並藉由氣液混合流體清洗晶片堆疊結構之間隙的殘留物。清洗時,氣液混合流體的化學液體使在間隙內之殘留物從其附著的表面分離,以及氣液混合流體的氣體施加的衝擊力將殘留物經由間隙之第二側帶出。本揭示之採用二流體噴嘴施加氣液混合流體至晶片堆疊結構上,也可採用高壓清洗(High Pressure Cleaner,HPC)噴嘴施加高壓流體至晶片堆疊結構上,並藉由高壓液體來清洗晶片堆疊結構之間隙內的殘留物。清洗時,高壓液體使在間隙內之殘留物從其附著的表面分離,以及高壓液體施加的衝擊力將殘留物經由間隙之第二側帶出。藉此設計,本揭示可實現以非接觸的方式清洗晶片堆疊結構,進而避免清洗噴頭直接對晶片堆疊結構施加下壓力,而導致晶片損壞的問題。 In summary, the present disclosure applies a gas-liquid mixed fluid to the wafer stack structure by using a two-fluid nozzle in the cleaning device, and cleans the residue in the gap of the wafer stack structure by the gas-liquid mixed fluid. During cleaning, the chemical liquid of the gas-liquid mixed fluid separates the residue in the gap from the surface to which it adheres, and the impact force exerted by the gas of the gas-liquid mixed fluid carries the residue out through the second side of the gap. The present disclosure uses a two-fluid nozzle to apply a gas-liquid mixed fluid to the wafer stack structure. High pressure cleaner (HPC) nozzles can also be used to apply high pressure fluid to the wafer stack structure, and the wafer stack structure is cleaned by high pressure liquid. Residues in the gap. Upon cleaning, the high pressure liquid separates the residue within the gap from its attached surface, and the impact force exerted by the high pressure liquid carries the residue out through the second side of the gap. By this design, the present disclosure can achieve cleaning of the wafer stack structure in a non-contact manner, thereby avoiding the problem that the cleaning nozzle directly applies a downward pressure to the wafer stack structure, resulting in wafer damage.

以上僅是本揭示的較佳實施方式,應當指出,對於所屬領域技術人員,在不脫離本揭示原理的前提下,還可以做出若干改進和潤飾,這些改進和潤飾也應視為本揭示的保護範圍。 The above is only a preferred embodiment of the present disclosure, and it should be noted that those skilled in the art can also make several improvements and refinements without departing from the principles of the present disclosure. These improvements and refinements should also be considered as protected range.

Claims (12)

一種清洗裝置,用於去除一晶片堆疊結構上之殘留物,該晶片堆疊結構包含一基板和複數個晶片,該晶片與該基板相隔一間隙,以及該殘留物位在該晶片與該基板之間的該間隙中,其中該清洗裝置包含:一承載台,用於放置該晶片堆疊結構;一供液裝置,用於提供一化學液體;一供氣裝置,用於提供一氣體;以及一二流體噴嘴,可相對於該承載台移動至與兩相鄰的晶片之間的間隔對準,其中該二流體噴嘴與該供液裝置和該供氣裝置連接,用於施加包含該化學液體和該氣體的氣液混合流體至該晶片堆疊結構之該基板上,使得該氣液混合流體沿著該間隙之第一側流入該間隙內,其中經由該氣液混合流體的該化學液體使在該間隙內之該殘留物從其附著的表面分離,以及經由該氣液混合流體的該氣體施加的衝擊力將該殘留物經由該間隙之第二側帶出。 A cleaning device for removing residues on a wafer stack structure, the wafer stack structure comprising a substrate and a plurality of wafers, the wafer being separated from the substrate by a gap, and the residue being located between the wafer and the substrate In the gap, wherein the cleaning device comprises: a loading platform for placing the wafer stack structure; a liquid supply device for providing a chemical liquid; a gas supply device for supplying a gas; and a two fluid a nozzle movable relative to the carrier to an interval between two adjacent wafers, wherein the two-fluid nozzle is coupled to the liquid supply device and the gas supply device for applying the chemical liquid and the gas a gas-liquid mixed fluid onto the substrate of the wafer stack structure such that the gas-liquid mixed fluid flows into the gap along a first side of the gap, wherein the chemical liquid passing through the gas-liquid mixed fluid is within the gap The residue is separated from the surface to which it is attached, and the residue is carried out via the second side of the gap by the impact force applied by the gas of the gas-liquid mixed fluid. 如申請專利範圍第1項之清洗裝置,其中該清洗裝置還包含:一精密驅動裝置,用於控制該二流體噴嘴相對該承載台沿著一垂直方向移動和沿著一水平方向移動。 The cleaning device of claim 1, wherein the cleaning device further comprises: a precision driving device for controlling the movement of the two-fluid nozzle relative to the loading table in a vertical direction and in a horizontal direction. 如申請專利範圍第2項之清洗裝置,其中該精密驅動裝置包含一垂直升降機構用於控制該二流體噴嘴相對該承載台沿著該垂直方向移動,該垂直升降機構包括步進馬達。 The cleaning device of claim 2, wherein the precision driving device comprises a vertical lifting mechanism for controlling movement of the two fluid nozzles relative to the loading table in the vertical direction, the vertical lifting mechanism comprising a stepping motor. 如申請專利範圍第2項之清洗裝置,其中該精密驅動裝置包含一水平移動機構用於控制該二流體噴嘴相對該承載台沿著該水平方向移動,該水平移 動機構包括X-Y軸座標工作桌(X-Y Table)。 The cleaning device of claim 2, wherein the precision driving device comprises a horizontal moving mechanism for controlling movement of the two-fluid nozzle relative to the loading table in the horizontal direction, the horizontal shift The moving mechanism includes an X-Y axis work table (X-Y Table). 如申請專利範圍第1項之清洗裝置,還包含一腔體,其中該承載台與該二流體噴嘴設置在該腔體內,且該腔體之底部設有一抽氣口。 The cleaning device of claim 1, further comprising a cavity, wherein the carrier and the two-fluid nozzle are disposed in the cavity, and a suction port is disposed at a bottom of the cavity. 如申請專利範圍第5項之清洗裝置,還包含一氣液分離裝置,其中該氣液分離裝置與該腔體之該抽氣口連接,用於將經由該抽氣口抽出的該氣液混合流體進行氣液分離。 The cleaning device of claim 5, further comprising a gas-liquid separation device, wherein the gas-liquid separation device is connected to the suction port of the cavity for gasifying the gas-liquid mixed fluid pumped through the suction port Liquid separation. 如申請專利範圍第1項之清洗裝置,其中該供氣裝置包含一加熱器,用於將該供氣裝置內的該氣體加熱至與該化學液體的溫度相近。 The cleaning device of claim 1, wherein the gas supply device comprises a heater for heating the gas in the gas supply device to be close to a temperature of the chemical liquid. 如申請專利範圍第1項之清洗裝置,其中該供氣裝置包含一加濕器,用於增加該供氣裝置內的該氣體的濕度。 The cleaning device of claim 1, wherein the gas supply device comprises a humidifier for increasing the humidity of the gas in the gas supply device. 如申請專利範圍第1項之清洗裝置,其中該承載台包含另一加熱器,用於將該承載台上的該晶片堆疊結構加熱以保持在一製程溫度。 A cleaning apparatus according to claim 1, wherein the stage includes another heater for heating the wafer stack structure on the stage to maintain a process temperature. 如申請專利範圍第1項之清洗裝置,其中該清洗裝置包含複數個二流體噴嘴,以一排並列的方式對齊排列,並且該複數個二流體噴嘴可相對於該承載台移動至與兩排相鄰的晶片之間的間隔對準。 The cleaning device of claim 1, wherein the cleaning device comprises a plurality of two-fluid nozzles aligned in a row and juxtaposed, and the plurality of two-fluid nozzles are movable relative to the carrier to two rows The spacing between adjacent wafers is aligned. 如申請專利範圍第1項之清洗裝置,其中該清洗裝置之該二流體噴嘴的前端設置為相對於該清洗晶片堆疊結構的表面傾斜一角度。 The cleaning device of claim 1, wherein the front end of the two-fluid nozzle of the cleaning device is disposed at an angle to the surface of the cleaning wafer stack. 如申請專利範圍第1項之清洗裝置,其中該二流體噴嘴包含高壓清洗噴嘴。 The cleaning device of claim 1, wherein the two-fluid nozzle comprises a high pressure cleaning nozzle.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI673789B (en) * 2018-11-19 2019-10-01 弘塑科技股份有限公司 Cleaning apparatus and method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI673789B (en) * 2018-11-19 2019-10-01 弘塑科技股份有限公司 Cleaning apparatus and method

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