M415107 五、新型說明： 【新型所屬之技術領域】 本新型是有關於一種除污電極設備，特別是指一種防 止海洋生物污損之除污電極設備。 【先如技術】 虽船體、漁網、箱具或是海洋工程結構物等海事器具 浸入海中時，細菌即會附著在上述海事器具表面，經過一 段時間後’此細菌菌落即會擴大發展，並會引來更多微生 物形成初期黏膜，而初期黏膜將會引來大型附著性生物之 幼生或孢子附著，進而成長演替形成穩定附著生物群落。 這些大型海洋附著生物常會影響該海事器具原有功能，甚 至會造成損壞，而這些海事器具被生物附著破壞之現象被 稱為海洋生物污損（Biofouling)。 以往業界用於預防海洋生物附著之方式有：毒物塗 料、剝落性塗料、特殊金屬包覆，及電解法等。雖然上述 方式可用以防止海洋生物附著，但是在使用上卻各自具有 下列缺點： ' 毋物塗料方式，主要是應用含有銅、砷、鉛' 汞等重 金屬之防污塗料或是有機防污塗料，例如三丁基錫 (tributy卜TBT)，但這種有毒塗料將會嚴重污染海水，破 壞生態環境，影響水產養殖，近年來隨著世界各國環保意M415107 V. New description: [New technical field] The present invention relates to a decontamination electrode device, in particular to a decontamination electrode device for preventing marine biofouling. [First as technology] Although maritime appliances such as hulls, fishing nets, boxes or marine engineering structures are immersed in the sea, the bacteria will adhere to the surface of the above-mentioned marine equipment. After a period of time, the bacterial colonies will expand and develop. It will lead to more microbes forming the initial mucosa, and the initial mucosa will attract the attachment of young or spores of large adherent organisms, and then grow up to form a stable attached biome. These large marine attachment organisms often affect the original function of the marine equipment and even cause damage. The phenomenon that these marine appliances are destroyed by biological attachment is called Biofouling. In the past, the ways in which the industry used to prevent the attachment of marine organisms were: poison coatings, exfoliating coatings, special metal coatings, and electrolysis. Although the above methods can be used to prevent the attachment of marine organisms, they have the following disadvantages in use: 'The method of coatings for sputum is mainly applied to antifouling coatings containing heavy metals such as copper, arsenic, lead, mercury or organic antifouling coatings. For example, tributyltin (TBT), but this toxic paint will seriously pollute seawater, destroy the ecological environment, affect aquaculture, and in recent years, with the environmental protection of countries around the world
識Γ7 /張對於此種具高污染性之毒性物質都加以限制禁 用。 T 剝落性塗料方式，由於需要每隔一段時間就重新塗布 3 ίνηηι〇7 以確保其效果，在實際應用上並非完全符合需長久浸泡於 海中操作之海事器具，而且也不符合需要儘量減少上架保 養之海事工程需求。 特殊金屬包覆方式，由於採用特殊金屬例如銅，所以 需要耗費較多的設備成本。 、電解法，由於現有電解海水設備所生成之自由氯，無 法有效均句分布在水中物體的開放表面，目前市面之電解 防止附著設備僅適用於類似管路或是渠道等設施。 因此，有馨於上述除污方式各有不理想之處，所以如 何能在符合環保、使用方便且成本低廉的條件下，研發出 ，止海洋生物污損之設借，已成為海洋業界刻不容緩之議 【新型内容】 因此’本新型之目@，即在提供—種符合環保、使用 方便且，本低廉之防止海洋生物污損之除污電極設備。 於是’本新型防止海洋生物污損之除污電極設備是 2於安裝在-個海事器具與海水接觸之—外表面上，並包 二·· -個絕緣載體、-個結合體、一個導電裝置，及一個 :電裳置。該絕緣_對應位在所料事^具外圍，並包 ::鄰近所述海事器具的内側面，及一個相反於該内側 載體：=海事器具的外側面。該結合體設置在該絕緣 =之内側面’且料將該絕緣載_定結合在所述海事 導電裝置包括數個彼此間隔排列且安裝 …邑緣載體之外側面上的電極單^該供電裝置電連接 該導電裝置且供應所述電極單元電流。 本新型之功效在於：可貼附在需要防止海洋生物污損 之海事器具表面，使料僅需依固定之時間間隔，並在短 時間通以低電壓之微量電流，即能電解海 -方面可抵抗生物附著，另一方面亦可避免環 境’所以能達到防止海洋生物污損之功效。 【實施方式】 有關本新型之前述及其他技術内容、特點與功效，在 以下配合參考圖式之一個較佳實施例的詳細說明中，將可 清楚的呈現。 實施例’是用於安裝在一個海事器具i與海水接觸之一外 表面Π上’所述海事器具i可以是船體、漁網、箱具或是 ::工一程結構物…等。該除污電極設備包含：一個絕緣載 、-個結合體3、一個導電裝置4’及一個供電裝置5。 :絕緣載體2由塑膠、橡膠、或軟性電路板等絕緣材 近乃對應位在所述海事器具1外圍，並包括一個鄰 21且遠/盗具1的内側面2卜及—個相反於該内側面 ^所述海事器具1的外側面22。 該結合體3設置在該絕緣載體2之 將該絕緣#體7 m ^ ^ 的減Μ 述海事器具1之外表面11 槿、生，' 在貫施上’該結合體3亦可以是其他結合 ^ 不以本實施例為限。 該導電裝置4包括數個彼此間隔且分別安裝在該絕緣 j體2之外側面22上的電極單元4卜及電連接所述電極 單疋41之-條正導線42與—條負導線&每—電極單元 41白具有-段正電線411，及_段與該正電線川相間隔 的負電線412。所述電極單元41之正電線4ΐι皆電連接至 該正導線42，所述電極單Ml之負電線412皆電連接至 該負導線43’而且該正導線42與該負導線43彼此間隔。 所述電極單元41在本實施例中呈矩陣排列，而且每 電極單元41之正電線4丨丨與負電線4丨2内外間隔皆呈 開口朝向同-側的側立㈣。當然實施上所述電極單元Μ 之排列方式亦可以改變，例如呈同心圓排列、旋渦狀排列 或其他形狀，分布的面積大小及間隔亦可依設計而改變。 此外每-電極單元41之正電線川與負電線化的形狀也 可以改變，例如呈同心圓、、'回々字形或其他形狀，因此 排列形狀不受限於本實施例。進一步來看各電極單元Μ 的構造，每-電極單元41皆具有一個安裝在該絕緣載體2 之外側面22且由鈦合金製成之第一材料層413，及一個結 合在該第一材料層413外側且由鎵合金製成之第二材料層 414 ^當然電極單元41之材料選擇不以上述為限，亦可以 為其他能達到抵抗侵蝕電極功能之材料，在此不再說明。 該供電裝置5包括一個電連接該導電裝置4之正導線 42與負導線43的脈衝變塵器51，能將一脈衝電流輸入該 導電裝置4，會定時自動交換導通正電線411與負電線 412，不但能供應所述電極單元41電流，同時亦能避免陰 極固體沉澱物生成，所以不會影響電流通過導電裝置4。 M415107 當然在實施上該供電裝詈^ .晋6丄 置5還包括有其他構造，例如電源 供應器，惟其並非本新型重 玉®點而且在實施上也可以採用 外接電源或直接電連接所述海 河爭态具1之電源，所以在此 不再詳細說明。 本實施例之結合體3、猫缝普μ Λ 一 ^ %緣載體2及導電裝置4,為 二層相疊置之構造，组裝睹_ *丨丨田分二人 、浐時利用該結合體3將該絕緣載體 2對應黏接在所述海事5|且！ 争益具1之外表面11。須說明的是， 該除污妹設備還可以在該導電裝置4之所述電極單元41 周圍’設置-填封體（圖未示），惟在此不再說明。 使用時，使用者可每隔—段時間，或當該海事器具」 與海水接觸之外表面11附著有海洋生物時，啟動該供電裝 置5，將脈衝電流輸入所述電極單元4卜使得電‘ 與海水接觸之海事器具Μ外表面，以 而電解海水之化學式如下： 陽極反應： 2C1 - -»C12 个 +2e_ (式1) 40H~->〇2 f +2H20+4e~ (式2) C1-+20H—ClCr+H2〇+2e- (式3) 在弱鹼性海水中，產生下列反應 ci2+2〇h_->cio_+ci +h2o (式4) 在弱酸性海水中，產生下列反應 ： C12+H20->HC10+H++C1 - (式5) 陰極反應： 2H20+2e一—20Η +Η2 个 (式6) 7 M415107Identification 7 / Zhang is restricted against such highly polluting toxic substances. T peeling coating method, because it needs to be reapplied 3 ίνηηι〇7 at regular intervals to ensure its effect, it is not completely suitable for maritime appliances that need to be immersed in the sea for a long time in practical application, and it does not meet the need to minimize the maintenance of the shelves. Maritime engineering needs. The special metal coating method requires a large equipment cost due to the use of a special metal such as copper. The electrolysis method, due to the free chlorine generated by the existing electrolysis seawater equipment, cannot be effectively distributed on the open surface of objects in the water. Currently, the electrolysis prevention equipment in the market is only suitable for facilities such as pipelines or channels. Therefore, there are some unsatisfactory ways to remove the above-mentioned decontamination methods. Therefore, how to develop and stop the marine biofouling under the conditions of environmental protection, convenient use and low cost has become an urgent task for the marine industry. Discussion [new content] Therefore, the purpose of this new type is to provide a decontamination electrode device that is environmentally friendly, easy to use, and inexpensive to prevent marine biofouling. Therefore, the new decontamination electrode device for preventing marine biofouling is mounted on the outer surface of a marine device in contact with seawater, and includes two insulating carriers, a combined body, and a conductive device. And one: electric skirt. The insulation_corresponds to the periphery of the object, and the package: is adjacent to the inner side of the marine device, and a side opposite to the inner carrier: = the outer side of the marine device. The combination body is disposed on the inner side of the insulation= and the material is coupled to the maritime conductive device, and the electrode assembly includes a plurality of electrodes arranged on the outer side of the outer edge of the rim-mounted carrier. The conductive device is electrically connected and supplies the electrode unit current. The effect of the novel is that it can be attached to the surface of a marine device that needs to prevent marine biofouling, so that the material only needs to be at a fixed time interval, and a small amount of current flowing at a low voltage in a short time, that is, the sea can be electrolyzed. Resist the attachment of organisms, on the other hand, it can also avoid the environment' so it can achieve the effect of preventing marine biofouling. The above and other technical contents, features and effects of the present invention will be apparent from the following detailed description of the preferred embodiments. The embodiment 'is for mounting on an outer surface of a marine appliance i in contact with seawater'. The marine appliance i may be a hull, a fishing net, a box or a structure or the like. The decontamination electrode device comprises: an insulating carrier, a combination 3, a conductive device 4' and a power supply device 5. The insulating carrier 2 is made of an insulating material such as plastic, rubber, or a flexible circuit board, which is located at the periphery of the marine device 1, and includes an adjacent side 21 and a far side/the inner side of the pirate 1 and a The inner side surface of the marine device 1 is the inner side surface. The combined body 3 is disposed on the insulating carrier 2, and the outer surface 11 of the marine device 1 is reduced, and the combined body 3 may be other combinations. ^ is not limited to this embodiment. The conductive device 4 includes a plurality of electrode units 4 spaced apart from each other and mounted on the outer side 22 of the insulating body 2, and a positive conductor 42 and a negative conductor electrically connected to the electrode unit 41. Each of the electrode units 41 has a segment-positive electric wire 411, and a negative electric wire 412 in which the segment is spaced from the positive electric wire. The positive electric wires 4 of the electrode unit 41 are electrically connected to the positive electric wires 42, the negative electric wires 412 of the electrode single M1 are electrically connected to the negative electric wires 43' and the positive electric wires 42 and the negative electric wires 43 are spaced apart from each other. The electrode units 41 are arranged in a matrix in this embodiment, and the inner and outer wires 4 每 and the negative wires 4 丨 2 of each electrode unit 41 are spaced apart from each other in the side-to-side (4). Of course, the arrangement of the electrode units Μ can also be changed, for example, in a concentric arrangement, a spiral arrangement or other shapes, and the size and spacing of the distribution can also be changed according to design. Further, the shape of the positive electric wire and the negative electric wire of each of the electrode units 41 may be changed, for example, in a concentric circle, a 'return shape' or the like, and thus the arrangement shape is not limited to the embodiment. Further, the configuration of each electrode unit , each of the electrode units 41 has a first material layer 413 which is mounted on the outer side 22 of the insulating carrier 2 and is made of a titanium alloy, and a first material layer is bonded thereto. The second material layer 414 is made of a gallium alloy on the outside of the 413. Of course, the material selection of the electrode unit 41 is not limited to the above, and may be other materials that can resist the function of the etching electrode, and will not be described here. The power supply device 5 includes a pulse dust filter 51 electrically connected to the positive wire 42 and the negative wire 43 of the conductive device 4, and can input a pulse current into the conductive device 4, and automatically exchange the positive wire 411 and the negative wire 412 at regular intervals. Not only can the current of the electrode unit 41 be supplied, but also the formation of cathode solid precipitates can be avoided, so that the current does not affect the passage of the conductive device 4. M415107 Of course, in the implementation of the power supply assembly, the Jin 6 device 5 also includes other structures, such as a power supply, but it is not the new heavy jade® point and can also be implemented by external power supply or direct electrical connection. The Haihe River has a power supply of 1, so it will not be described in detail here. The combination body 3 of the present embodiment, the cat splicing Λ Λ ^ ^ ^ 缘 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 The body 3 correspondingly bonds the insulating carrier 2 to the maritime 5| and! Controversy has a surface 11 outside. It should be noted that the decontamination device can also be provided with a sealing body (not shown) around the electrode unit 41 of the conductive device 4, but will not be described here. In use, the user can activate the power supply device 5 every other time, or when the marine device is attached to the surface 11 in contact with the seawater, and input a pulse current into the electrode unit 4 to make electricity. The maritime equipment in contact with seawater is on the outer surface, and the chemical formula of the seawater is as follows: Anode reaction: 2C1 - -»C12 +2e_ (Formula 1) 40H~->〇2 f +2H20+4e~ (Formula 2) C1-+20H-ClCr+H2〇+2e- (Formula 3) In weakly alkaline seawater, the following reaction ci2+2〇h_->cio_+ci +h2o (Formula 4) is produced in weakly acidic seawater. The following reactions: C12 + H20 - > HC10 + H + + C1 - (Formula 5) Cathodic reaction: 2H20 + 2e - 20 Η + Η 2 (Formula 6) 7 M415107
Mg2++20H_—Mg(OH)2 I (式 7) 由反應式（式4)及（式5)，可看出溶液中有ci〇_或是 HC10，也就是自由氣（free chlorine)的存在，亦即只要施 加適當電流’就會在所述電極單元41(即陽極）表面產生足 夠的自由氣，而且自由氯只要在短時間内維持於一特定濃 度以上就具有殺菌作用，可以抑制海洋生物附著避免造 成海生物污損，並可以保護海洋環境。 此外，由於通電所產生之自由氯，在停止通電後，可 以很快地就在自然環境下分解而消散，其分解消散的方式 有：1·與海中的有機物發生反應而消耗，2與海甲的氨或 有機氮反應，產生各種形式的氯化錄而消耗，3•與陽光進 行光化學反應而分解，4.與金屬作用而分解’ 5•與藻類、 貝類作用而分解，所以不會對海洋生態環境造成衝擊。 综上所述，本新型除污電極設備可將海水電解，以於 表面產生微量的自由氣，可有效抑制海洋生物附著，而且 使用方便、成本低廉，值得一提的是，本新型藉由通電所 釋放之自由氣，停止通電後，會迅速自然消失，整個過程 f有在海水中添加任何化學物質，並不會對環境造成污 木所以本新型兼具環保以及有效抑制海洋生物之功效， 為一極具產業價值之產品，故確實能達成本新型之目的。 惟以上所述者，僅為本新型之較佳實施例而已，當不 能以此限定本新型實施之範圍，即大凡依本新型申請專利 範圍及新型s兒明内容所作之簡單的等效變化與修錦，皆仍 屬本新型專利涵蓋之範圍内。 8 M415107 【圖式簡單說明】 圖1是本新型除污電極設備的一較佳實施例的一側視 不意圖， 圖2是該較佳實施例之一部份剖視示意圖；及 圖3是該較佳實施例之一部份正視示意圖。 M415107 【主要元件符號說明】 1…… …··海事器具 411 ··· •…正電線 11 .···. •…外表面 412… •…負電線 2…… -----絕緣載體 413… …·第一材料層 21 -----内側面 414… …·第二材料層 22·..._ .....外側面 42••… •…正導線 3…… •…結合體 43·.·.· •…負導線 _____道驻要 C ...... ____愈捉罢 4 ...... 导电装置 识电展罝 41 ·..·· •…電極單元 51 ·..·· …·脈衝變壓器 10Mg2++20H_—Mg(OH)2 I (Formula 7) From the reaction formulas (Formula 4) and (Formula 5), it can be seen that there is ci〇_ or HC10 in the solution, that is, free chlorine. Existence, that is, as long as an appropriate current is applied, sufficient free gas is generated on the surface of the electrode unit 41 (ie, the anode), and the free chlorine has a bactericidal action as long as it is maintained at a specific concentration or more for a short period of time, and the ocean can be suppressed. Biological attachment avoids fouling of marine organisms and protects the marine environment. In addition, since the free chlorine generated by the energization can be quickly decomposed and dissipated in the natural environment after the energization is stopped, the decomposition and dissipation are: 1. Reacting with the organic matter in the sea, 2, and the armor Ammonia or organic nitrogen reacts to produce various forms of chlorination and consumes, 3 • decomposes with photochemical reaction of sunlight, 4. decomposes with metal action ' 5 • Decomposes with algae and shellfish, so it will not The marine ecological environment has caused an impact. In summary, the new decontamination electrode device can electrolyze seawater to generate a small amount of free gas on the surface, can effectively inhibit the attachment of marine organisms, and is convenient to use and low in cost. It is worth mentioning that the present invention is powered by electricity. The released free gas will quickly disappear naturally after the power is turned off. The whole process f has any chemical substances added to the sea water, and it does not cause soil pollution. Therefore, the new model has both environmental protection and effective suppression of marine life. A product of great industrial value can indeed achieve the purpose of this new type. However, the above is only the preferred embodiment of the present invention, and the scope of the present invention cannot be limited thereto, that is, the simple equivalent change made by the novel patent application scope and the novel content of the present invention is The repairs are still within the scope of this new patent. 8 is a schematic view of a preferred embodiment of the present invention, and FIG. 2 is a partial cross-sectional view of the preferred embodiment; and FIG. 3 is a schematic view of a preferred embodiment of the present invention; A schematic front view of one of the preferred embodiments. M415107 [Description of main component symbols] 1...... ...·· Marine appliances 411 ··· •...positive wires 11 .····.......outer surface 412...•...negative wires 2... -----insulating carrier 413 .... First material layer 21 ----- Inner side 414 ... .... Second material layer 22 · ... _ ..... Outer side 42••... •... Positive lead 3... •...combined Body 43·.·.· •... Negative wire _____ Road station C ...... ____ more catching 4 ...... Conductive device knowledge exhibition 罝 41 ·..·· •... Electrode unit 51 ······· pulse transformer 10