M338155 八、新型說明： 【新型所屬之技術領域】 且特別是關於一種用以除 本新型是有關於一種布料， 氣之布料。 【先前技術】 自來水於淨化過程中，為了抑制水中微生物的生長， 都會添加適量的氯氣消毒’以使水中的生菌數維持在標準 範圍内。 然而，根據-份歐洲研究報告指出，游泳池中所添加 的氯，會造成孩童氣喘或是發出哮喝聲的現象大幅增加。 另外’發表在最新一期「過敏」期刊中的論文亦指出，水 中所含的氯，會對肺臟内壁造成傷害，因此若於兒童時期 經常游泳，成年後罹患花粉熱的風險會增加七成多。此外， 科予豕更4 λ 了人體可經由皮膚吸收水中所殘留的氯氣， 因此長期接觸後，易引起皮膚甚至是其他器官的病變。 據此，急待開發一種除氯之材料，以於曰常生活中有 效除去水中餘氯’減少皮膚與氯的接觸，以降低因氣產生 的危害。 【新型内容】 因此本新型#目的京尤是在提供一種除氣型布料，用以 降低水中所含的氯對人體的危害。 本新1的目的之一是在提供一種除氯型之布料，此布 5 M338155 97 入 y’· 4·夏 i 、 .人 料包§基材與包覆基材的除氯層，其中除氯層包含了亞硫 酸鈣與甲殼素成份。甲殼素成份係選自由幾丁質、幾丁聚 醣、幾丁質衍生物、幾丁聚醣衍生物及上述任意組合所組 成之一族群，且亞硫酸鈣與甲殼素成份係均勻混合。 本新型的另一目的是在提供一種除氣型之衣物，此種 衣物係以前述之除氯型布料製成。 本新型的又一目的是在提供一種除氯型布料之製造方 法方法包含先配製甲殼素溶液。接著，將亞硫酸鈣加 2甲八又素/谷液中，以形成複合溶液。之後以利用含浸或熱 ㈣方式，將複合溶液塗覆於基材上，以於基材外形成複 口 /合液層。最後，將基材送入成型液中，以使基材外之複 合溶液層轉變成除氯層。 由於上述之除氣型布料具有一除氯層，除氯層中的亞 硫酸妈與甲殼素成份，可有效地除去水中的氯離子與氯 氣，大幅降低水中的氯含量，若應用於衣著上，將有助於 人體健康。 、 【實施方式】 激I型布料之製備 一 八你1會示本新型一實施例中，除氯型 布料的製備流程。首先，蔣田Μ 一 將甲λ又素成份加入酸性溶液中， 以配製成甲殼素溶液（步驟 (，驟102)。於此實施例中，甲 成份選自由幾丁質、幾丁平_ 说 ^ 衍生物（例如：磷酸化幾丁 # ^ 呔』t醣 吸化4 丁質或羥甲基化幾 6 M338155 (Carb〇Xy-methyl Chitin，CM哪邮及上述任意組合所植 成之一族群，而甲殼素成份之重量百分率濃度係 此外’所使用的酸性溶液可為重量百分率濃度為m〇%的 錢酸溶液或無機酸溶液。其中無機酸溶液可為鹽酸或填 酸，而有機酸溶液則可為醋酸溶液、甲酸溶液、乳酸溶液 或檸檬酸溶液。 接著，將亞硫酸鈣加入甲殼素溶液中，以形成複合溶 液（步驟104)，其中亞硫酸转與曱殼素溶液之混合重量比值 # I為G.MG。之後，利用含浸或熱壓的方式，將配製好的 複合溶液塗覆於-基材上，以於基材外形成複合溶液層（步 驟106)。此基材之材質可為萊卡、尼龍、聚胺基甲酸醋 (polyurethane，簡稱pu)彈性纖維或聚酯纖維。 另外，配製成型液（步驟1〇8)，此成型液為重量百分率 濃度M0%之鹼性溶液或陰離子聚電解質溶液。其中鹼性 溶液係為氫氧化鈉溶液、氫氧化卸溶液或氫氧化鎖溶液。 而陰離子聚電解實溶液係則可為三聚磷酸鹽溶液、氧化纖 ·.維素溶液或海藻酸鈉溶液。最後，將前述基材送入配製好 的成型液中，以使基材外之複合溶液層轉變成除氯層（步驟 - 110)。 以上述方法所製得的除氣型布料，其結構如第2圖所 不。其中覆於基材202外側的的除氣層2〇4包含了亞硫酸 約206與曱殼素成份208,其中曱殼素成份2〇8係為幾丁 貝、或丁聚醣或其他幾丁質衍生物。此外，亞硫酸鈣 和曱殼素成份208係、均勻混合，兩者之重量比值係為 0.M0。於過渡時，水中的氣氣會吸附於甲殻素成份，而水 M338155 9?, 4. 1 1 中的氣離子則疋會和亞硫酸_反應，進而產生氯化舞及亞 硫酸根離子，進而達到除氣的效果。 除氯效果测諕 為了測試所製得的除氣型布料其除氣效果如何，因此 先为別在100 ml水中，加入一定量的1〇〇、2〇〇、3〇〇、4〇〇、 500與700 ppm的次氯酸溶液，以模擬氣氣在通入水中後， 與水反應產生次氯酸（HC10)的情形。接著，將所製得的除 氯型布料浸潰在上述含有次氯酸的水中，靜置一分鐘後， 以餘氯測試劑檢測水中所殘留的氯含量，其結果係如下表 —戶斤示〇 表一除氯測試結果 除氯型布料 加入之次氯 酸濃度 100 200 300 400 500 700 (ppm) 餘氯濃度 (ppm) 0.27 0.27 0.43 0.5 0.57 1.53 除氯量 (ppm) 99.73 199.73 299.57 399.5 499.43 698.47M338155 VIII. New description: [New technical field] It is especially related to a fabric that is related to a fabric and gas. [Prior Art] In the purification process of tap water, in order to suppress the growth of microorganisms in water, an appropriate amount of chlorine gas is added to keep the number of bacteria in the water within the standard range. However, according to the European research report, the chlorine added in the swimming pool will cause a significant increase in children's asthma or screaming. In addition, the paper published in the latest issue of "Allergy" also pointed out that the chlorine contained in the water will cause damage to the inner wall of the lungs. Therefore, if you swim frequently during childhood, the risk of hay fever will increase by more than 70% in adulthood. . In addition, Keyu 豕 4 λ The human body can absorb the residual chlorine in the water through the skin, so after long-term exposure, it is easy to cause skin and even other organs. Accordingly, there is an urgent need to develop a chlorine-removing material to effectively remove residual chlorine from the water during normal life, reducing the contact between the skin and chlorine to reduce the hazard caused by the gas. [New content] Therefore, the purpose of this new type is to provide a degassing type cloth to reduce the harm of chlorine contained in water to the human body. One of the purposes of this new 1 is to provide a chlorine-removing fabric, this cloth 5 M338155 97 into the y'·4·夏i, the human material package § substrate and coated substrate of the chlorine removal layer, which The chlorine layer contains calcium sulfite and chitin components. The chitin component is selected from the group consisting of chitin, chitosan, chitin derivatives, chitosan derivatives, and any combination thereof, and the calcium sulfite and chitin components are uniformly mixed. Another object of the present invention is to provide a degassing type garment which is made of the aforementioned chlorine-removing type cloth. A further object of the present invention is to provide a method for the manufacture of a chlorine-removing fabric comprising first preparing a chitin solution. Next, calcium sulfite is added to 2 octadecanoate/troche to form a composite solution. Thereafter, the composite solution is applied to the substrate by means of impregnation or heat (iv) to form a lap/liquid layer outside the substrate. Finally, the substrate is fed into a molding liquid to convert the composite solution layer outside the substrate into a chlorine removal layer. Since the above-mentioned degassing type cloth has a dechlorination layer, the sulfite mother and chitin component in the dechlorination layer can effectively remove chlorine ions and chlorine gas in the water, and greatly reduce the chlorine content in the water, and if applied to clothing, Will contribute to human health. [Embodiment] Preparation of the stimulating type I fabric A VIII will show the preparation process of the chlorine removal type fabric in an embodiment of the present invention. First, Jiang Tianyi added the component of the gamma to the acidic solution to prepare a solution of chitin (step (step 102). In this embodiment, the component A is selected from chitin, chitin _ Said ^ derivative (for example: phosphorylated chitin # ^ 呔 t t sugar absorbing 4 butyl or methylolated several 6 M338155 (Carb 〇 Xy-methyl Chitin, CM which post and any combination of the above one planted The group, and the weight percentage concentration of the chitin component is furthermore. The acidic solution used may be a qonic acid solution or a mineral acid solution having a concentration by weight of m〇%. The inorganic acid solution may be hydrochloric acid or acid, and the organic acid may be The solution may be an acetic acid solution, a formic acid solution, a lactic acid solution or a citric acid solution. Next, calcium sulfite is added to the chitin solution to form a composite solution (step 104), wherein the mixed weight of the sulfite to the chitin solution is The ratio # I is G.MG. Thereafter, the prepared composite solution is applied to the substrate by means of impregnation or hot pressing to form a composite solution layer outside the substrate (step 106). Material can be Lycra, nylon, A urethane or urethane fiber or a polyester fiber. In addition, a molding liquid (step 1 〇 8) is prepared, and the molding liquid is an alkaline solution or an anionic polyelectrolyte solution having a weight percentage concentration of M0%. The solution is sodium hydroxide solution, hydroxide solution or hydroxide lock solution, and the anion polyelectrolyte solution can be tripolyphosphate solution, oxidized cellulose solution or sodium alginate solution. Finally, The foregoing substrate is sent to the prepared molding liquid to convert the composite solution layer outside the substrate into a chlorine removal layer (step-110). The degassing type fabric obtained by the above method has the structure as the second The degassing layer 2〇4 covering the outside of the substrate 202 comprises sulfite about 206 and a chitin component 208, wherein the chitin component 2〇8 is a chitin or a butan. Or other chitin derivatives. In addition, calcium sulfite and chitin component 208 are uniformly mixed, and the weight ratio of the two is 0. M0. During the transition, the gas in the water will adsorb to the chitin component. The water ion in the water M338155 9?, 4. 1 1 And sulfite _ reaction, and then produce chlorination dance and sulfite ions, and then achieve the effect of degassing. The effect of dechlorination test in order to test the degassing type of the resulting degassing effect, so first In 100 ml of water, add a certain amount of 1 〇〇, 2 〇〇, 3 〇〇, 4 〇〇, 500 and 700 ppm hypochlorous acid solution to simulate the reaction of gas with water to produce hypochlorite. In the case of acid (HC10), the obtained chlorine-removing cloth is immersed in the above-mentioned hypochlorous acid-containing water, and after standing for one minute, the residual chlorine content is detected by the residual chlorine test agent, and the result is as follows. The following table is the following table: Table 1 - Chlorine test results The concentration of hypochlorous acid added to the chlorine-containing fabric is 100 200 300 400 500 700 (ppm) Residual chlorine concentration (ppm) 0.27 0.27 0.43 0.5 0.57 1.53 Chlorine removal (ppm) 99.73 199.73 299.57 399.5 499.43 698.47
由表一之測試結果可知，原本加入10〇 ppm的次氯 酸，在經過除氯型布料除氯後，水中的氯含量可降低至 M338155 修正 0.27ppm ’其除氯量約可達99.73 ppm。此外，即使逐漸提 高所加入次氯酸濃度，所製備的除氯型布料，仍可大幅可 降低水中的氯含量。當所加入的次氯酸為70〇 ppm時，在 經過除氯型布料除氯後，水中的餘氣濃度僅為153 ppm， 約可除去698.47ppm的氯含量，由此可知，隨著氯含量的 上升，除氯效果則更為顯著。 綜上所述，上述實施例所製備的除氯型布料，無論水According to the test results in Table 1, the 10 〇 ppm of hypochlorous acid was added. After dechlorination of the chlorine-removing fabric, the chlorine content in the water can be reduced to M338155. The corrected chlorine content is about 0.27 ppm. The chlorine removal amount is about 99.73 ppm. In addition, even if the concentration of hypochlorous acid added is gradually increased, the chlorine-removed fabric prepared can greatly reduce the chlorine content in the water. When the added hypochlorous acid is 70〇ppm, the residual gas concentration in the water after dechlorination of the chlorine-removing fabric is only 153 ppm, which can remove the chlorine content of 698.47ppm, which shows that with the chlorine content The rise of the chlorine removal effect is more significant. In summary, the chlorine removal type cloth prepared in the above embodiment, regardless of water
中的氯含量為何，除氯型布料確實具有良好的除氯效能， 故若能穿著以此除氯型布料所製成的衣物，例如泳衣或泳 帽，將可以大幅將低人體與氯的接觸，減少因氯造成的产 害。 & 〜雖然本新型已以一實施例揭露如上，然其並非用以限 :本新型’任何熟習此技藝者，在不脫離本新型之精神和 祀圍内’當可作各種之更動與潤飾，因此本新型 圍當視後附之中請專利範圍所界定者為準。…巳 參 【圖式簡單說明】 優點與實施例 為讓本新型之上述和其他目的、特徵、 &更明顯易懂’所附圖式之詳細說明如下： 除氯型布料的製 所製得之除濾型 第1圖其係繪示本新型一實施例中 備流程。 第2圖係繪示以第1圖所述之方法 布料剖面示意圖。 M338155 【主要元件符號說明】 102 :步驟 104 ··步驟 106 :步驟 108 :步驟 110 :步驟What is the chlorine content? The chlorine-removing fabric does have good chlorine removal efficiency. Therefore, if you can wear clothes made of this type of chlorine-removing fabric, such as swimsuits or swimming caps, it will greatly reduce the contact between human body and chlorine. To reduce the production caused by chlorine. < </ RTI> Although the present invention has been disclosed in an embodiment as above, it is not intended to limit the scope of the present invention. Anyone skilled in the art can make various changes and refinements without departing from the spirit and scope of the present invention. Therefore, the scope of the patent scope is subject to the scope of the patent application. The advantages and embodiments of the present invention are as follows: FIG. 1 is a flow chart of an embodiment of the present invention. Fig. 2 is a schematic cross-sectional view showing the cloth in the manner described in Fig. 1. M338155 [Description of main component symbols] 102: Step 104 ··Step 106: Step 108: Step 110: Step
200除濾型布料 202基材 204除氯層 206亞硫酸鈣 208曱殼素成份200 filter cloth 202 base material 204 chlorine removal layer 206 calcium sulfite 208 曱 chitin ingredient
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