M318629 八、新型說明： 【新型所屬之技術領域】 本創作係有關一種蓄光性p V C膠膜，尤指一種藉由 蓄光性螢光物之吸光、蓄光及發光屬性，俾使該蓄光性p v c膠膜具有自我發光之特性，進而達到最佳夜光持久之 效能。 【先前技術】 按，一般具有夜光效果之結構，大多在PVC材質表 面上塗佈一具有夜光效果之夜光粉，並藉由該夜光粉之特 性，俾利於夜晚昏暗時，具有夜光警示之效果。 又，另一種具有夜光效果之結構，則是將pVc材質 與具有夜光效果之夜光粉相互混合成一體，再依其所需要 之尺寸進行切割並使用於該產品上。 然，上述兩種之技術，皆利用具有夜光效果之粉末， 其目的皆是要達到在夜晚或昏暗的環境中，可以具有發光 的效果而達到警示及醒目之安全性。但是，由於其中在表 面上塗佈具有夜光效果之結構，在長期的使用下，經由摩 擦或其他外來因素，容易造成脫落的情形發生，因此對於 仪光效果也就大打折扣；另一種混合式的夜光效果之結 構，因其/昆合時需注意比例上的問題，又，該混合後的蓄 光效果不足，因此也無法使發光效能達到最佳狀態，故， 仍是有其缺點需要進一步改進。 藉此，本創作人期能針對上述缺失加以改良，以達到 能增強蓄光效能，俾利發光效能可以完全的發揮到最佳的 M318629 狀態。 【新型内容】 緣是，本創作之主要目的，係在提供一種蓄光性p v C膠膜，其係利用該蓄光性螢光物之設成，俾使該蓄光性 PVC膠膜具有較佳夜光持久之效能。 本創作之另一目的，係在提供一種蓄光性p v C膠 膜其中，該蓄光性PVC膠膜具有安全、醒目以及使用 壽命長之功效者。 • 本創作之又一目的，係在提供一種蓄光性p v C膠 膜，其中，該蓄光性PV c膠膜具有美觀之獨特性。 為達上述目的，本創作之技術手段包含·· 至少一PVC膜、一反射層，係由不透光材質所構成； 一蓄光層，係由蓄光性螢光物所構成，設在該反射層之外 表面，其具備吸光、蓄光及發光屬性；所述反射層可由P v C混合或表面喷塗方式形成，且可將蓄光層直接喷塗在 非透明之PVC白膜上，而Pvc膜可依產品需求及厚薄 射生選擇為-層或二層以上；藉此，據以構成一蓄光性p V C及反射膠膜。 進-步，該蓄光性Pvc膠膜包含單面或雙面散發多 重光譜顏色之亮光者。 【實施方式】 、 f先，請參閱第—圖所示，其係為本創作第-較佳實 施例之示意圖，其係包含有： -反射層（1 0 )，係由不透光材f所構成·， M318629 一蓄光層（2 Ο A)，係由蓄光性螢光物所構成，並且 設在該反射層（1 0 )之外表面，其具備吸光、蓄光及發 光屬性； 一外層PVC膜（30)，係設在該蓄光層（2 〇 A ) 之上；以及 一底層PVC膜（40)，係設在該反射層（1 〇 )之 底面；藉此，據以構成一單面散發亮光之蓄光性p V c膠 膜（6 0 A )〇 请再參閱第二圖所示，其係為本創作第二較佳實施例 之示意圖，其係包含有： 一反射層（1 0 )，係由不透光材質所構成； 一外蓄光層（20B)及一底蓄光層（20C)，係由 蓄光性螢光物所構成，分別設在該反射層（1 〇 )之外表 面及底面，其具備吸光、蓄光及發光屬性； 一外層PVC膜（30)，係設在該外蓄光層（2 〇 B ) 之表面；以及 一底層PVC膜（40)，係設在該底蓄光層（2 〇 c ) 之底面；藉此，據以構成一雙面皆可散發亮光之蓄光性P v C膠膜（6 0 B)。 又，第一、二較佳實施例中之該外層p V C膜（3 0 ) 及底層PVC膜（4 0)係包括由透明氣化乙烯為主構成 物所形成，並視實際所需調整P VC之柔軟度、強度及延 展性，而，該反射層（1〇)則包括由無公害白色顏料為 主構成物所形成。其可與PVC膜混合或以表面喷塗方式 形成。 M318629 承上，該蓄光性螢光物係為一發光材料，即含鳃的鋁 氧化合物（Strontium aluminates)，其化學分子式係為： SrAL204 : Eu.Dy，其主要原料包括：Sr〇、Al2〇3、Eu2〇3、M318629 VIII, new description: [New technology field] This creation is related to a light-storing p VC film, especially the light-absorbing, light-storing and luminescent properties of light-storing phosphors, so that the light-storing pvc glue The film has the characteristics of self-illumination, which in turn achieves the best nighttime performance. [Prior Art] Press, generally has a luminous effect structure, and most of the PVC material surface is coated with a luminous powder having a luminous effect, and with the characteristics of the luminous powder, it is advantageous to have a luminous warning effect when the night is dim. Further, another structure having a luminous effect is to mix a pVc material and a luminous powder having a luminous effect into one body, and then cut it according to the required size and use it on the product. However, both of the above techniques utilize a powder having a luminous effect, and the purpose is to achieve a warning and eye-catching safety at night or in a dim environment. However, since the structure having a luminous effect is coated on the surface, in the long-term use, it is easy to cause the falling off due to friction or other external factors, and thus the effect of the illuminating effect is greatly reduced; another hybrid type The structure of the luminous effect is due to the problem of proportion in the case of the Kunming, and the light storage effect after the mixing is insufficient, so that the luminous performance cannot be optimized, and therefore, there are still disadvantages that need further improvement. In this way, the creator can improve the above-mentioned deficiencies, so as to enhance the light-storing performance, and the illuminating performance can be fully utilized to the optimal M318629 state. [New content] The main purpose of this creation is to provide a light-storing pv C film which is formed by using the light-storing phosphor to make the light-storing PVC film have a good luminous durability. Performance. Another object of the present invention is to provide a light-storing p v C film in which the light-storing PVC film is safe, conspicuous, and has a long service life. • Another object of the present invention is to provide a light-storing p v C film, wherein the light-storing PV c film is aesthetically pleasing. In order to achieve the above object, the technical means of the present invention comprises: at least one PVC film and a reflective layer, which are composed of an opaque material; and a light-storing layer, which is composed of a light-storing phosphor, and is disposed on the reflective layer. The outer surface has the properties of light absorption, light storage and illumination; the reflective layer can be formed by P v C mixing or surface spraying, and the light storage layer can be directly sprayed on the non-transparent PVC white film, and the Pvc film can be According to the product requirements and the thickness of the shot, the choice is -layer or more; thereby, a light-storing p VC and a reflective film are formed. Further, the light-storing Pvc film comprises a single-sided or double-sided light emitting a multi-spectral color. [Embodiment] f, first, please refer to the first figure, which is a schematic view of the first preferred embodiment of the present invention, which comprises: - a reflective layer (10), which is made of an opaque material f M318629 A light-storing layer (2 Ο A) is composed of a light-storing phosphor and is provided on the outer surface of the reflective layer (10), which has the properties of light absorption, light storage, and light emission; a film (30) disposed on the light-storing layer (2 〇A); and a bottom PVC film (40) disposed on a bottom surface of the reflective layer (1 ;); thereby forming a single side A light-storing p V c film (60 A) emitting light, please refer to the second figure, which is a schematic view of a second preferred embodiment of the present invention, which comprises: a reflective layer (1 0 ) is composed of an opaque material; an outer light-storing layer (20B) and a bottom light-storing layer (20C) are formed of light-storing phosphors, respectively disposed on the surface of the reflective layer (1 〇) And a bottom surface, which has the properties of light absorption, light storage and illumination; an outer PVC film (30) is disposed on the surface of the outer light storage layer (2 〇 B); The underlying PVC film (40) is disposed on the bottom surface of the bottom light-storing layer (2 〇 c ); thereby constituting a light-storing P v C film (60 B) which can emit light on both sides. Moreover, the outer layer p VC film (30) and the underlying PVC film (40) in the first and second preferred embodiments are formed by transparent gasified ethylene as a main component, and are adjusted according to actual needs. The softness, strength and ductility of VC, and the reflective layer (1〇) is formed by a pollution-free white pigment as a main constituent. It can be mixed with a PVC film or formed by surface spraying. M318629 According to the above, the luminescent phosphor is a luminescent material, namely Strontium aluminates, and its chemical formula is: SrAL204: Eu.Dy, the main raw materials include: Sr〇, Al2〇 3, Eu2〇3,
Dy2〇3等為原料，該原料生成係為習知技術，並非本專利之 標的，在此容不贅述。 另外，該蓄光性螢光物可用紫外線或相當紫外線之外 部其他能量激發之，於停止激發後以肉眼仍可見相當時間 之餘輝，因其具有可於黑暗中發光之特性。又，該蓄光性 螢光物能夠在有光的時候蓄光，在沒有光亮的時候發光， 且蓄光1 0至2 0分鐘就能夠發光8至1 2小時，而吸光 2 0分鐘則能達到其飽和狀態，因此在發光時即能達到持 續發光的良好效果，尤其是吸收含有紫外線的光時，其發 光之明党度及持續時間會更好。 再者，該蓄光性螢光物之薄層結構之生產過程非一般 金屬礦物之冶煉，其係將原材料進行機械混合後裝入陶瓷 掛鍋，進入高溫電爐灼燒，其經高溫物理反應後，冷卻出 爐，機械破碎，碾磨，過篩等過程，其在生產過程中無廢 氣無污染，因此該蓄光性螢光物之薄層結構具有安全無毒 之特性。 進一步’请再參閱第三圖所不’係為本創作第三較佳 實施例之示意圖，其係包含有： 一 P V C膠層（5 0 );以及 一蓄光層（2 0 D )，係由蓄光性螢光物分佈設在該p V C膠層（5 0 )内，其具備吸光、蓄光及發光屬性，使 該P V C膠層散發亮光；藉此，據以構成一單面或雙面皆 -8 - M318629 可散發亮光之蓄光性P V C膠膜（6 0 C )。再者，該蓄光 、 層（20D)亦可設在該PVC膠層（5 0)的表面，且 其間包括設有一反射層，該反射層包括由pVc混合戋表 面喷塗所形成。 又，該蓄光層（2 0 D)係可與P V c膠層（5 〇 ) 加熱抽膜成型，或在非透明P V C膠層（5 〇 )直接噴塗 蓄光性螢光物所構成。 ' 又，該蓄光性P V C膠膜（6 0 A )、（ 6 〇 B )、（ 6 0C)上所設之蓄光性螢光物，在自然光（日光）、燈光等 _ 其它可見光之照射下，其發揮具有吸光、蓄光及發光^性， 藉其光激發光而達到該蓄光性p vc膠膜（6〇a)、（6 〇b)、（60c)發出亮光’因此，一旦到了夜晚的時候 或者在比較昏暗的環境中，該蓄光性P Vc膠膜（6 〇 A)、（ 6 Ο B )、（ 6 0 C )即會發出光芒，藉此，不論在 任何的環境下，藉由自我發光特性，進而達到最佳夜光之 持久效能，以增進其安全、醒目及使用壽命長等多重之功 效。 • 請再參閱第四〜七圖所示，本創作之蓄光性p v c膠 膜（60A)(60B)(60C)係包括設置成雨衣（7 〇 )、雨伞（8 0 )、救生筏（9〇)及遮雨蓬（1〇〇) 之型態，藉此，不論在下雨天或緊急狀況使用下，皆能因 具有其自我發光之特性，達到醒目、安全之警示效果。而 • 其層數或厚薄之選用，則依所欲製成之產品的特性而定。 進一步，清參閱第八圖所示，係為本創作之光激發光 光譜之色度座標圖，其中，該蓄光性螢光物之光激發光光 M318629 譜包括選自：紫光（ 300〜300nm)、藍光（470 • 〜480nm)、綠光（5 1 0〜5 3 Onm)、黃光（5 7 〇〜580nm)及紅光（6 30〜660nm)其中 任一。亦即添加不同之微量元素於蓄光性螢光物，即可獲 •致預定之光激發光光譜。 又，該蓄光性PVC膠膜（60A)(60B)(60 C )，係可藉由該蓄光性螢光物之光激發光光譜，依其可搭 配不同顏色的需求，來決定選擇塗佈附著相搭配之發光 色，並且運用在本創作中所提及之雨衣（7 〇 )、雨傘（8 鲁 0)、救生筏（90)及遮雨蓬（1〇〇)，不但不用再只 是侷限於單一顏色的選擇上而顯得單調乏味，亦促使該雨 衣（70)、雨伞（80)、救生筏（9 0)及遮雨蓬（工 0 0)的多重變化之效果，是以，本創作除了具有醒目安 全警示之效果外，並可在外表加印時尚圖樣或紋路等印 刷’亦具有達到其美觀獨特之視覺效果；再者，其可利用 充氣性的特點，可達斷熱防寒，以及可作為外觀線條及體 態調整之功效增進。 • 綜上所述，本創作所揭示之構造，為昔所無，且確能 達到功效之增進，並具可供產業利用性，完全符合新型專 利要件，祈請貴審查委員核賜專利，以勵創新，無任德 感。 惟，上述所揭露之圖式、說明，僅為本創作之較佳實 施例，大凡熟悉此項技藝人士，依本案精神範疇所作之修 飾或等效變化，仍應包括在本案申請專利範圍内。 •10- M318629 【圖式簡單說明】 第一圖係本創作第一較佳實施例之示意圖。 第二圖係本創作第二較佳實施例之示意圖。 第三圖係本創作第三較佳實施例之示意圖。 第四圖係本創作第一使用型態之示意圖。 第五圖係本創作第二使用型態之示意圖。 第六圖係本創作第三使用型態之示意圖。 第七圖係本創作第四使用型態之示意圖。 第八圖係本創作之光激發光光譜之色度座標圖。 【主要元件符號說明】 (1〇)反射層 (2 0 A)蓄光層 (2 Ο B)外蓄光層 (2 0 C)底蓄光層 (2 0 D)蓄光層 (3 0 )外層P V C膜 (4 0 )底層p V C膜 (5 0 ) P V C 膠層 (60A)、（6〇B)、（6〇C)蓄光性 P V C膠膜 (7 0)雨衣 (8 0 )雨傘 (9 0)救生筏 (100)遮雨蓬 -11-Dy2〇3 and the like are raw materials, and the raw material formation is a conventional technique, and is not the subject of this patent, and is not described herein. Further, the light-storing phosphor may be excited by ultraviolet rays or other energy other than ultraviolet rays, and after the excitation is stopped, the afterglow of the naked eye is still visible for a considerable period of time because of its characteristic of being able to emit light in the dark. Moreover, the light-storing phosphor can store light when there is light, emit light when there is no light, and can emit light for 8 to 12 hours after being stored for 10 to 20 minutes, and can be saturated by absorption for 20 minutes. The state, therefore, can achieve a good effect of continuous illuminating when illuminating, especially when absorbing light containing ultraviolet rays, the party and duration of illuminating will be better. Furthermore, the production process of the thin layer structure of the light-storing phosphor is not the smelting of a general metal mineral, and the raw materials are mechanically mixed and then placed in a ceramic hanging pot, and then burned in a high-temperature electric furnace, after high-temperature physical reaction, The process of cooling and discharging, mechanical crushing, milling, sieving, etc., has no waste gas and no pollution during the production process, so the thin layer structure of the light-storing phosphor has the characteristics of safety and non-toxicity. Further, please refer to the third figure, which is a schematic view of a third preferred embodiment of the present invention, which comprises: a PVC adhesive layer (50); and a light storage layer (20D). The light-storing phosphor is distributed in the p-VC adhesive layer (50), and has the functions of light absorption, light storage and light-emitting, so that the PVC glue layer emits light; thereby, according to the configuration, one side or both sides are formed. 8 - M318629 Light-storing PVC film (60 C) that emits light. Furthermore, the light-storing layer (20D) may be disposed on the surface of the PVC adhesive layer (50), and includes a reflective layer formed thereon, the reflective layer comprising a surface sprayed by a pVc mixed crucible. Further, the light-storing layer (20 D) can be formed by heating and film-forming with a P V c adhesive layer (5 〇 ) or by directly spraying a light-storing phosphor on a non-transparent P V C adhesive layer (5 〇 ). 'In addition, the light-storing phosphors on the light-storing PVC film (60 A), (6 〇B), and (60C) are exposed to natural light (daylight), light, etc. It exhibits light absorption, light storage, and illuminance, and the light-emitting p vc film (6〇a), (6 〇b), and (60c) emit light by the light-exciting light. Therefore, once at night, Or in a relatively dim environment, the light-storing P Vc film (6 〇A), (6 Ο B), (60 C) will shine, thereby, in any environment, by self The luminescent properties, in order to achieve the best lasting performance of night light, to enhance its safety, eye-catching and long service life. • Please refer to the fourth to seventh figures. The light-storing pvc film (60A) (60B) (60C) of this creation includes raincoat (7 〇), umbrella (80), and life raft (9〇). ) and the type of canopy (1〇〇), so that it can achieve eye-catching and safe warning effects due to its self-illuminating characteristics, whether it is raining or in an emergency. • The choice of the number of layers or thickness depends on the characteristics of the product to be made. Further, as shown in the eighth figure, the chromaticity coordinate diagram of the light spectrum of the light excitation of the present invention, wherein the light excitation light of the light-storing phosphor M318629 spectrum is selected from the group consisting of: purple light (300~300 nm) , blue (470 • 480 nm), green (5 1 0 to 5 3 Onm), yellow (5 7 〇 to 580 nm), and red (6 30 to 660 nm). That is, by adding different trace elements to the light-storing phosphor, a predetermined spectrum of photoexcitation light can be obtained. Moreover, the light-storing PVC film (60A) (60B) (60 C) can be selected from the coating light by the light-exciting light spectrum of the light-storing phosphor, depending on the needs of different colors. Matching the illuminating color, and using the raincoat (7 〇), umbrella (8 Lu 0), life raft (90) and awning (1 〇〇) mentioned in this creation, not only need to be limited The choice of single color is tedious, and it also promotes the multiple changes of the raincoat (70), umbrella (80), life raft (90) and awning (work 0). With the effect of eye-catching safety warnings, and printing on the exterior of fashion patterns or lines, it also has the visual effect of achieving its beautiful appearance; in addition, it can use the characteristics of aeration to achieve heat and cold resistance, and As the appearance of lines and posture adjustments, the effect is enhanced. • In summary, the structure revealed by this creation is unprecedented, and it can achieve the improvement of efficacy, and it can be used for industrial utilization. It fully complies with the new patent requirements, and asks the review committee to grant the patent. Encourage innovation, no sense of morality. However, the above-mentioned drawings and descriptions are only preferred embodiments of the present invention. Those who are familiar with the art, and the modifications or equivalent changes made in accordance with the spirit of the case should still be included in the scope of the patent application. • 10-M318629 [Simple description of the drawings] The first figure is a schematic diagram of the first preferred embodiment of the present creation. The second drawing is a schematic view of a second preferred embodiment of the present creation. The third figure is a schematic view of a third preferred embodiment of the present creation. The fourth picture is a schematic diagram of the first use form of the creation. The fifth picture is a schematic diagram of the second usage pattern of the present creation. The sixth picture is a schematic diagram of the third usage pattern of the creation. The seventh picture is a schematic diagram of the fourth usage pattern of the creation. The eighth figure is the chromaticity coordinate diagram of the light excitation spectrum of the present creation. [Description of main component symbols] (1〇) Reflective layer (20 A) Light-storing layer (2 Ο B) Outer light-storing layer (2 0 C) Bottom light-storing layer (20 D) Light-storing layer (30) Outer PVC film ( 4 0) bottom layer p VC film (50) PVC glue layer (60A), (6〇B), (6〇C) light-storing PVC film (70) raincoat (80) umbrella (90) life raft (100) awning -11-