TWM264664U - Bipolar plate for air-cooled proton exchange membrane fuel cell stack - Google Patents

Bipolar plate for air-cooled proton exchange membrane fuel cell stack Download PDF

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Publication number
TWM264664U
TWM264664U TW093209585U TW93209585U TWM264664U TW M264664 U TWM264664 U TW M264664U TW 093209585 U TW093209585 U TW 093209585U TW 93209585 U TW93209585 U TW 93209585U TW M264664 U TWM264664 U TW M264664U
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Taiwan
Prior art keywords
air
bipolar plate
fuel cell
cell stack
exchange membrane
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TW093209585U
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Chinese (zh)
Inventor
Yong-Song Chen
Ming-Chih Chuang
Biing-Jyh Weng
Tien-I Hou
Ji-Fa Liu
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Chung Shan Inst Of Science
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Priority to TW093209585U priority Critical patent/TWM264664U/en
Publication of TWM264664U publication Critical patent/TWM264664U/en

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Description

M264664 勾、創作說明(1) 要為改良電池組中雙 【新型所屬之技術領域 本創作為燃料電池1之設計,主 極板的形式。 i 【先前技術】 燃料電池是將氫梟β|妳丄 的裝置。其特色為只產二I由電化學反應轉換成電力 產生裝置。 …、和7 ’因此是一極環保的電力 貝子父換膜燃料 壓,則需將多個單電外* 特。右需得到較大電 壓。電池組的堆疊:ί f :起形成電池組,以提高電 電極組/雙極板……雙核電流收集板/單極板/膜 導電石n膜電極組即為一單電池,雙極板a 守电石墨板或金屬板,將备 ^為 集板接觸的導雷柄口女母早電池串聯^來,與電流吹 ί敕ί ϋ電流經由電流收集板導出。銘板是用來失緊固 疋整個電池組。 承固 ,而膜電極組產生電的同時也會同時廣生熱和水, =將熱量移除,則會影 組的姝能;產生u 不能迅速排出,也會阻塞反應氣體的流動,造U ί=ί二因此設計良好的電池組不但要可以將氣體分配ϊ =極組,以發揮每一 的性能,並可以將j 的熱和i移除,以維持長時間運作。 生 目則市面上可購得之氣冷式燃料電池錤商品有加拿大M264664 Hook, creation instructions (1) To improve the middle of the battery pack [Technical field to which the new type belongs This design is the design of the fuel cell 1, the form of the main electrode plate. i [Prior art] Fuel cells are devices that convert hydrogen ββ | 丄 to you. It is characterized by producing only two Is which are converted from electrochemical reactions into electricity generating devices. …, And 7 ′ are therefore a very environmentally friendly power source. If you need to change the fuel pressure of the membrane, you need to separate multiple single power sources *. A larger voltage is required on the right. Stacking of battery packs: ί f: forming a battery pack to improve the electric electrode group / bipolar plate ... dual-core current collecting plate / unipolar plate / membrane conductive stone n membrane electrode group is a single battery, bipolar plate a A galvanized graphite or metal plate is connected in series with the female lead battery of the lightning guide handle that is prepared for contacting the collector plate, and the current is blown through the current collecting plate through the current collecting plate. The nameplate is used to loosen the entire battery pack. When the membrane electrode group generates electricity, it also generates heat and water at the same time. = When the heat is removed, the energy of the group will be affected. If u cannot be discharged quickly, it will also block the flow of the reaction gas and cause U ί = ί 二 Therefore, a well-designed battery pack must not only be able to distribute the gas ϊ = pole group to exert the performance of each, but also to remove the heat and i of j to maintain long-term operation. Air-cooled fuel cells available in the market

M264664 四、創作說明(2)M264664 Fourth, creation instructions (2)

Ballard公司之1· 2KW氣冷式電池組及美國H -Power公司之 250及500W電池組。由Baiiard公司發表的專利US 6 0 6 6 4 0 9可以得知其電池組所設計的冷卻方式,每一個雙 極板是由兩片導電碳板結合而成,兩面分別是氫氣及空氣 流道’中間夾層部分是直線型的冷卻流道,由冷卻風扇將 環境中的冷空氣送入冷卻流道來散熱。由於每一個雙極板 是由兩片結合而成,因此體積、重量增加許多,這將不利 於發展成攜帶型的電力系統。 Η - Power公司之設計可參考美國專利US 5 7 7 6 6 2 5,其 發明特點是在雙極板之兩面分別建立雙向流道,因為在流 道中越末端的氣體會攜帶越多反應後產生的水,這些水可 以補償相鄰流道中剛流進來的乾燥氣體不足的水分。因 此’每一流道的入口是和相鄰流道的出口並列,為了不使 入口和出口的氣體相混,就必需在這些孔位附近增加螺栓 來碟保氣密。其商品的電池組上即有2 7支固定螺栓,不但 增加重量,也增加組裝上的成本。 【新型内容】 本創作之目的在設計氣冷式質子交換膜燃料電池組, 使$單位體積功率密度大、氣密佳、散熱排水效果好、組 裝容易,並使其中每一單電池的效能均能完全發揮。雙極 板佔電池組體積的主要部分,因此雙極板的形式會影響電 池組的整體性能,本創作之雙極板可使氩氣和空氣流向相 反’達到均衡質子交換膜的濕度,並將固定螺栓孔位設置Ballard's 1.2KW air-cooled battery pack and American H-Power's 250 and 500W battery packs. The patent US 6 0 6 6 4 0 9 issued by Baiiard Company can know the cooling method designed for its battery pack. Each bipolar plate is a combination of two conductive carbon plates with hydrogen and air flow channels on both sides. 'The middle sandwich part is a linear cooling flow path, and the cooling fan sends cold air from the environment into the cooling flow path to dissipate heat. Since each bipolar plate is a combination of two pieces, the volume and weight increase a lot, which is not conducive to the development of a portable power system. Η-The design of Power Company can refer to the US patent US 5 7 7 6 6 2 5 and its invention is characterized by the establishment of two-way flow channels on the two sides of the bipolar plate, because the more end gas in the flow channel will carry more reaction and produce Water, which can compensate for the insufficient moisture of the dry gas just flowing in the adjacent flow channel. Therefore, the inlet of each flow channel is juxtaposed with the outlet of the adjacent flow channel. In order not to mix the gas at the inlet and the outlet, it is necessary to add bolts near these holes to keep the airtight. Its commercial battery pack has 27 fixing bolts, which not only increases weight but also increases assembly costs. [New content] The purpose of this creation is to design an air-cooled proton exchange membrane fuel cell stack, so that the power density per unit volume is large, the airtightness is good, the heat dissipation and drainage effect is good, and the assembly is easy. Can fully play. The bipolar plate occupies a major part of the volume of the battery pack, so the form of the bipolar plate will affect the overall performance of the battery pack. The bipolar plate of this creation can make argon and air flow in opposite directions to achieve equilibrium humidity of the proton exchange membrane, and Fixed bolt hole position setting

M264664 四、創作說明(3) 於散熱鰭片上,以減少體積浪費。 本創作之燃料電池組如第1圖所示。上銘板1 a及下鋁 板lb間堆疊有上電流收集板6a、雙極板2、下電流收集板 6 b,雙極板間夾有膜電極組4並由氣密墊片3加以密封,並 以固定螺栓5鎖緊後完成。氫氣經由上鋁板之入口 3 1 a流經 氫氣入口主流道3 1 b,然後分佈到電極反應的區域,再經 由氮氣出口主流道3 1 c流到下紹板上的出口 3 1 d排出。空氣 則由入口 2 1 a流經雙極板之空氣入口主流道2 1 b,然後分佈 到電極反應的區域,再經由空氣出口主流道2 1 c流到下鋁 板的出口 21d排出。 雙,^主要功能為引導反應氣體至反應的電極區域, = 面為陽極,引導空氣的那一面為陰極, 另一面氫氣入口产的广啦埤。汉工芏軋出口處的區域是 度。 处的區域,因此可以均衡質子交換膜的濕 的電池纟且1 、、' a叶將四個氣體的主要流道孔分置在方 的,這會降低;ϋ材料,由於使用的氣體都是乾燥 反應過程中合產生=膜的濕度進而使性能降低。但是在 膜,則可以維持一定沾如果利用這些水來潤濕質子交換 氣體流動方向樺加,2性能。在反應過程中,水分會隨著 氣體入口附近^曹早ί果兩面的氣體流動方向一樣,則在 濕的。在本創作中,=換膜是偏乾燥的’而出口附近是偏 的,如第2圖,々5 ’氧氣的流動方向和空氣的流向是相反 好是另一面空《氣氣那—面的出口附近會較為濕潤,而剛 二軋、入D區域。反之,空氣出口處的區域是M264664 4. Creation instructions (3) on the heat sink fins to reduce volume waste. The fuel cell stack of this creation is shown in Figure 1. An upper current collecting plate 6a, a bipolar plate 2, and a lower current collecting plate 6b are stacked between the upper name plate 1a and the lower aluminum plate lb. A membrane electrode group 4 is sandwiched between the bipolar plates and sealed by an airtight gasket 3. Completed after locking with the fixing bolt 5. Hydrogen flows through the inlet 3 1 a of the upper aluminum plate through the hydrogen inlet main channel 3 1 b, and then is distributed to the electrode reaction area, and then flows through the nitrogen outlet main channel 3 1 c to the outlet 3 1 d of the lower plate. The air flows from the inlet 2 1 a through the air inlet main channel 2 1 b of the bipolar plate, and then distributes to the electrode reaction area, and then flows through the air outlet main channel 2 1 c to the lower aluminum plate outlet 21d and is discharged. Double, ^ The main function is to guide the reaction gas to the area of the electrode of the reaction, = the side is the anode, the side that guides the air is the cathode, and the other side is the wide range produced by the hydrogen inlet. The area at the Hangong rolling exit is degrees. Area, so we can equalize the wet cell of the proton exchange membrane, and 1, 1, 'a leaves the four main flow channel holes of the gas in a square, which will reduce; the material, because the gas used is dry During the reaction process, the humidity of the film is combined to reduce the performance. But in the membrane, you can maintain a certain degree of performance if you use these water to wet the proton exchange gas flow direction, 2 properties. During the reaction, moisture will follow the gas flow near the gas inlet, and the direction of gas flow on both sides of the fruit will be the same, but it will be wet. In this creation, = the membrane change is relatively dry, and the vicinity of the exit is biased, as shown in Figure 2, 々5 'the flow direction of oxygen is opposite to the flow direction of air. It will be wet near the exit, but just rolled into D area. Conversely, the area at the air outlet is

M264664 四、創作說明(4) 形電極的四邊。但是由於主流道孔不需太大,因此沒有充 分利用到石墨板,也就會增加電池組重量。本創作將電極 形狀設計為長方形且將氣體出入口的主流道孔的位置分置 在兩個短邊,充分利用每塊區域。如第3圖所示。 在反應過程中產生的熱也會使電池組溫度升高,溫度 太高會使得質子交膜過於乾燥而降低其導電性,所以必需 增加散熱鰭片,以增加散熱面積。為了減少體積浪費,因 此將固定螺栓的孔位設置在散熱鰭片上,也就是將螺栓設 置在電池組内部,而且此螺栓可以當作定位用,使每一片 雙極板在組裝時容易對位。M264664 IV. Creation instructions (4) Four sides of the electrode. However, because the mainstream channel holes do not need to be too large, the graphite plate is not fully utilized, which will increase the weight of the battery pack. In this creation, the shape of the electrode is designed to be rectangular, and the positions of the main channel holes of the gas inlet and outlet are separated on two short sides to make full use of each area. As shown in Figure 3. The heat generated in the reaction process will also increase the temperature of the battery pack. Too high a temperature will make the proton-exchange membrane too dry and reduce its conductivity. Therefore, it is necessary to increase the heat dissipation fins to increase the heat dissipation area. In order to reduce volume waste, the holes of the fixing bolts are set on the heat sink fins, that is, the bolts are set inside the battery pack, and the bolts can be used for positioning, so that each bipolar plate can be easily aligned during assembly.

反應電極周圍及主流道周圍需維持氣密,因此需要以 氣密墊片3將反應電極的周圍圍住,以免陰陽兩極的氣體 相通。在雙極板上除了電極反應的區域和氣體進出口的主 要流道孔,其餘部份作為氣密墊片區域,而氣密墊片寬度 為3至5毫米,如第4圖。 【實施方式】 實例1 :It is necessary to maintain airtightness around the reaction electrode and around the main channel. Therefore, it is necessary to surround the periphery of the reaction electrode with an airtight gasket 3 to prevent the communication between the anode and the cathode. Except for the electrode reaction area and the main flow channel holes of the gas inlet and outlet on the bipolar plate, the rest is used as the airtight gasket area, and the width of the airtight gasket is 3 to 5 mm, as shown in Figure 4. [Embodiment] Example 1:

單極板採用石墨材質的薄板,其外型如第3圖,尺寸 為80毫米xl60毫米x2毫米;中間反應電極區域尺寸為40毫 米X 1 3 0毫米;兩側散熱鰭片寬度為1 5毫米,厚度為1 . 5毫 米,每側鑽有3個固定螺栓孔,間隔為4 5毫米;氫氣主要 流道入、出口尺寸為4毫米X 6毫米;空氣主要流道入、出 口尺寸為4毫米x25毫米。膜電極組的外型如第2圖中之4,The unipolar plate is a thin sheet made of graphite. Its appearance is as shown in Figure 3. The dimensions are 80 mm x 160 mm x 2 mm. The size of the intermediate reaction electrode area is 40 mm X 130 mm. The width of the heat sink fins on both sides is 15 mm. , The thickness is 1.5 mm, with 3 fixing bolt holes drilled on each side, the interval is 45 mm; the main hydrogen channel inlet and outlet dimensions are 4 mm X 6 mm; the main air channel inlet and outlet dimensions are 4 mm x25 mm. The shape of the membrane electrode group is shown as 4 in Figure 2.

第9頁 M264664Page 9 M264664

第ίο頁 M264664 圖式簡單說明 第1圖:本創作之燃料電池組分解圖。 1 a :上铭板 1 b :下鋁板 2 :雙極板 3 :氣密墊片 4 :膜電極組 5 :固定螺栓鎖 6a :上電流收集板 6 b :下電流收集板 21a :上鋁板之空氣入口 2 1 b :雙極板之空氣入口主流道 2 1 c :雙極板之空氣出口主流道 21d :下鋁板之空氣出口 31a :上鋁板之氫氣入口 3 1 b :雙極板之氫氣入口主流道 3 1 c :雙極板之氫氣出口主流道 3 1 d :下鋁板之氫氣出口 第2圖:膜電極組與氣體流動方向。 4 :膜電極組 2 0 b :空氣流動方向 3 0 b :氫氣流動方向 第3圖:雙極板設計圖。Page ίο M264664 Brief description of the drawings Figure 1: Exploded view of the fuel cell stack of this creation. 1 a: upper nameplate 1 b: lower aluminum plate 2: bipolar plate 3: airtight gasket 4: membrane electrode group 5: fixed bolt lock 6a: upper current collecting plate 6b: lower current collecting plate 21a: upper aluminum plate Air inlet 2 1 b: Bipolar plate air inlet mainstream channel 2 1 c: Bipolar plate air outlet mainstream channel 21d: Lower aluminum plate air outlet 31a: Upper aluminum plate hydrogen inlet 3 1 b: Bipolar plate hydrogen inlet Main flow path 3 1 c: Hydrogen outlet of bipolar plate Main flow path 3 1 d: Hydrogen outlet of lower aluminum plate Figure 2: Membrane electrode group and gas flow direction. 4: Membrane electrode group 2 0 b: Air flow direction 3 0 b: Hydrogen flow direction Figure 3: Bipolar plate design.

M264664M264664

第12頁 圖式簡單說明 2 :雙 極 板 20a 空 氣 流 道 21b 雙 極 板 之 空 氣 入 α 主 流 道 21c 雙 極 板 之 空 氣 出 α 主 流 道 30a 氫 氣 流 道 31b 雙 極 板 之 氫 氣 入 D 主 流 道 31c 雙 極 板 之 氫 氣 出 口 主 流 道 50 固 定 螺 栓 孔 位 60 散 熱 鰭 片 第4圖: 氣 密 墊 片 形 式 〇 第5圖: 單 電 池 性 能 曲 線 圖 〇 第6圖: 電 池 組 性 能 曲 線 圖 〇 第7圖: 電 池 組 長 時 間 性 能 測 試 圖Brief description of the diagram on page 12 2: Bipolar plate 20a air flow channel 21b Bipolar plate air in α main channel 21c Bipolar plate air out α main channel 30a Hydrogen flow channel 31b Bipolar plate hydrogen in D main channel 31c Hydrogen outlet main channel of bipolar plate 50 Fixing bolt hole position 60 Radiating fins Figure 4: Form of airtight gasket 0 Figure 5: Single cell performance curve 0 Figure 6: Battery pack performance curve 0 7 Figure: Long-term performance test chart of the battery pack

Claims (1)

M264664M264664 六、申請專利範圍 …,二」」 1. 一種氣冷式質子交換膜燃料電池組之雙極板形式,其 形式為: (1 )形狀為長方形,中間為電極反應區域,二長邊為散 熱鰭片,氫氣及空氣的主要流道入、出口分別在二短 邊,氫氣主要流道入口和空氣主要流道出口並排在同一 短邊,空氣主要流道入口和氫氣主要流道出口並排在另 一短邊,使兩種氣體相向流動; (2 )散熱鰭片上設置有固定螺栓孔位; (3 )雙極板上電極反應區域、氣體主要入/出口及散熱 鰭片外的區域為氣密墊片區域。6. Scope of patent application ..., two "" 1. A bipolar plate of an air-cooled proton exchange membrane fuel cell stack, the form is: (1) the shape is rectangular, the middle is the electrode reaction area, and the two long sides are for heat dissipation The main inlets and outlets of the fins, hydrogen and air are on the two short sides respectively. The inlet of the main flow of hydrogen and the outlet of the main flow of air are side by side. The inlet of the main flow of air and the outlet of the main flow of hydrogen are side by side. One short side allows the two gases to flow toward each other; (2) There are fixing bolt holes on the heat sink fins; (3) The electrode reaction area on the bipolar plate, the main gas inlet / outlet and the area outside the heat sink fins are airtight Shim area. 2. 如申請專利範圍為第1項氣冷式質子交換膜燃料電池組 之雙極板形式,散熱鰭片上的固定螺栓孔位,亦為組裝 時之定位孔。 3. 如申請專利範圍為第1項氣冷式質子交換膜燃料電池組 之雙極板形式,其氣密墊片區域寬度為3至5毫米。2. If the scope of the patent application is the first bipolar plate of an air-cooled proton exchange membrane fuel cell stack, the fixing bolt holes on the heat sink fins are also the positioning holes during assembly. 3. If the scope of the patent application is the first bipolar plate of an air-cooled proton exchange membrane fuel cell stack, the width of the airtight gasket area is 3 to 5 mm. 第13頁Page 13
TW093209585U 2004-06-18 2004-06-18 Bipolar plate for air-cooled proton exchange membrane fuel cell stack TWM264664U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI398032B (en) * 2010-10-11 2013-06-01 Ind Tech Res Inst Assembling method of air-cooled fuel cell
US8546046B2 (en) 2009-11-20 2013-10-01 Industrial Technology Research Institute Method for fabricating bi-polar plate of fuel cell and bi-polar plate of fuel cell
CN110459780A (en) * 2019-07-25 2019-11-15 南方科技大学 A kind of fuel battery double plates and fuel cell

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8546046B2 (en) 2009-11-20 2013-10-01 Industrial Technology Research Institute Method for fabricating bi-polar plate of fuel cell and bi-polar plate of fuel cell
US8841045B2 (en) 2009-11-20 2014-09-23 Industrial Technology Reserach Institute Method for fabricating bi-polar plate of fuel cell
TWI398032B (en) * 2010-10-11 2013-06-01 Ind Tech Res Inst Assembling method of air-cooled fuel cell
CN110459780A (en) * 2019-07-25 2019-11-15 南方科技大学 A kind of fuel battery double plates and fuel cell

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