TWI843033B - 無鹼玻璃板 - Google Patents
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- 239000011521 glass Substances 0.000 title claims abstract description 118
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims abstract description 272
- 229910004298 SiO 2 Inorganic materials 0.000 claims abstract description 219
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims abstract description 13
- 229910021193 La 2 O 3 Inorganic materials 0.000 claims abstract description 8
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 111
- 238000001816 cooling Methods 0.000 description 53
- 238000002844 melting Methods 0.000 description 31
- 230000008018 melting Effects 0.000 description 31
- 238000000034 method Methods 0.000 description 29
- 239000006060 molten glass Substances 0.000 description 24
- 230000007423 decrease Effects 0.000 description 20
- 238000004519 manufacturing process Methods 0.000 description 18
- 238000010438 heat treatment Methods 0.000 description 17
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 16
- 239000002994 raw material Substances 0.000 description 12
- 238000004031 devitrification Methods 0.000 description 11
- 239000010408 film Substances 0.000 description 11
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 11
- 239000010948 rhodium Substances 0.000 description 11
- 239000006066 glass batch Substances 0.000 description 8
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000011819 refractory material Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 238000005485 electric heating Methods 0.000 description 6
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum oxide Inorganic materials [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 6
- 238000007500 overflow downdraw method Methods 0.000 description 6
- KTUFCUMIWABKDW-UHFFFAOYSA-N oxo(oxolanthaniooxy)lanthanum Chemical compound O=[La]O[La]=O KTUFCUMIWABKDW-UHFFFAOYSA-N 0.000 description 6
- 229910052697 platinum Inorganic materials 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 238000005452 bending Methods 0.000 description 4
- 238000005401 electroluminescence Methods 0.000 description 4
- 239000004973 liquid crystal related substance Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 4
- 239000010409 thin film Substances 0.000 description 4
- 238000002834 transmittance Methods 0.000 description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 3
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 3
- 229910010413 TiO 2 Inorganic materials 0.000 description 3
- 238000005352 clarification Methods 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 239000011733 molybdenum Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 238000010583 slow cooling Methods 0.000 description 3
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 2
- 229910006404 SnO 2 Inorganic materials 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Inorganic materials O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000006025 fining agent Substances 0.000 description 2
- 239000002803 fossil fuel Substances 0.000 description 2
- 239000003915 liquefied petroleum gas Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000009774 resonance method Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- YEAUATLBSVJFOY-UHFFFAOYSA-N tetraantimony hexaoxide Chemical compound O1[Sb](O2)O[Sb]3O[Sb]1O[Sb]2O3 YEAUATLBSVJFOY-UHFFFAOYSA-N 0.000 description 2
- 238000007088 Archimedes method Methods 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910018068 Li 2 O Inorganic materials 0.000 description 1
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 1
- 238000006124 Pilkington process Methods 0.000 description 1
- 229910018967 Pt—Rh Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910021417 amorphous silicon Inorganic materials 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 description 1
- 238000003280 down draw process Methods 0.000 description 1
- -1 etc. can be used Chemical compound 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005816 glass manufacturing process Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229920005591 polysilicon Polymers 0.000 description 1
- NOTVAPJNGZMVSD-UHFFFAOYSA-N potassium monoxide Inorganic materials [K]O[K] NOTVAPJNGZMVSD-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910001631 strontium chloride Inorganic materials 0.000 description 1
- AHBGXTDRMVNFER-UHFFFAOYSA-L strontium dichloride Chemical compound [Cl-].[Cl-].[Sr+2] AHBGXTDRMVNFER-UHFFFAOYSA-L 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
Abstract
本發明的無鹼玻璃板的特徵在於:作為玻璃組成,以莫耳%計而含有55%~80%的SiO2
、10%~25%的Al2
O3
、0%~4%的B2
O3
、0%~30%的MgO、0%~25%的CaO、0%~15%的SrO、0%~15%的BaO、0%~5%的ZnO、0%~未滿1.0%的Y2
O3
+La2
O3
,實質不含鹼金屬氧化物,且應變點為750℃以上。
Description
本發明是有關於一種無鹼玻璃板,尤其是有關於一種適合於液晶顯示器、有機電致發光(electroluminescence,EL)顯示器等平板顯示器中的用以形成薄膜電晶體(Thin Film Transistor,TFT)電路的基板或對用以形成TFT電路的樹脂基板進行保持的玻璃載板(carrier glass)的無鹼玻璃板。
眾所周知,為了實現驅動控制,液晶面板或有機EL面板具備薄膜電晶體(TFT)。
關於對顯示器進行驅動的薄膜電晶體,已知有非晶矽、低溫多晶矽、高溫多晶矽等。近年來,伴隨大型液晶顯示器、智慧型手機(smart phone)、平板個人電腦(tablet personal computer)等的普及,顯示器的高解析度化的需求提高。低溫多晶矽TFT可滿足該需求,但經過500℃~600℃的高溫成膜製程。但是,先前的玻璃板於高溫成膜製程的前後熱收縮量變大,因此會引起薄膜電晶體的圖案偏移。因此,為了顯示器的高解析度化,要求低熱收縮的玻璃板。近年來,正在研究顯示器的進一步高精細化,於該情況下,需要使玻璃板進一步低熱收縮化。
[現有技術文獻]
[專利文獻]
[專利文獻1]日本專利第5769617號公報
[發明所欲解決之課題]
作為使玻璃板的熱收縮下降的方法,主要可列舉兩種方法。第一種方法是預先於成膜製程的熱處理溫度附近對玻璃板進行保持並加以緩冷的方法。該方法中,在緩冷時,玻璃結構鬆弛而收縮,因此可抑制之後的高溫成膜製程中的熱收縮量。但是,該方法會導致製造步驟數或製造時間的增加,因此玻璃板的製造成本會高漲。
第二種方法是提高玻璃板的應變點的方法。溢流下拉(over flow down draw)法通常以相對較短的時間自熔融溫度冷卻至成形溫度。因該影響而玻璃板的假想溫度變高,玻璃板的熱收縮變大。因此,若提高玻璃板的應變點,則成膜製程的熱處理溫度下的玻璃板的黏度變大,難以進行結構鬆弛。結果,可抑制玻璃板的熱收縮。而且,成膜製程的熱處理溫度越高,相對於熱收縮的減低而高應變點化的效果越大。因此,於低溫多晶矽TFT的情況下,理想的是盡可能使玻璃板高應變點化。
專利文獻1中揭示有包含Y2
O3
及/或La2
O3
的高應變點玻璃。但是,由於Y2
O3
及La2
O3
為稀土類元素,因此原料成本高,存在使玻璃板的製造成本高漲的問題。
本發明是鑒於所述情況而成,其技術性課題為發明出應變點高且可使製造成本低廉化的無鹼玻璃板。
[解決課題之手段]
本發明者等人進行了努力研究,結果發現,藉由對各成分的含量進行嚴格地限制,並且將應變點限制為規定值以上而可解決所述技術性課題,從而作為本發明來提出。即,本發明的無鹼玻璃板的特徵在於:作為玻璃組成,以莫耳%計而含有55%~80%的SiO2
、10%~25%的Al2
O3
、0%~4%的B2
O3
、0%~30%的MgO、0%~25%的CaO、0%~15%的SrO、0%~15%的BaO、0%~5%的ZnO、0%~未滿1.0%的Y2
O3
+La2
O3
,實質不含鹼金屬氧化物,且應變點為750℃以上。此處,「Y2
O3
+La2
O3
」是指Y2
O3
與La2
O3
的合計量。所謂「實質不含鹼金屬氧化物」,是指玻璃組成中的鹼金屬氧化物(Li2
O、Na2
O、K2
O)的含量未滿0.5莫耳%的情況。「應變點」是指基於美國材料與試驗協會(American Society for Testing and Materials,ASTM)C336的方法進行測定而得的值。
另外,本發明的無鹼玻璃板較佳為滿足[SiO2
]+14×[Al2
O3
]-15×[B2
O3
]+6×[MgO]+[CaO]+14×[SrO]+16×[BaO]≧360莫耳%的關係。此處,[SiO2
]是指SiO2
的莫耳%含量,[Al2
O3
]是指Al2
O3
的莫耳%含量,[B2
O3
]是指B2
O3
的莫耳%含量,[MgO]是指MgO的莫耳%含量,[CaO]是指CaO的莫耳%含量,[SrO]是指SrO的莫耳%含量,[BaO]是指BaO的莫耳%含量。
另外,本發明的無鹼玻璃板較佳為滿足17.8×[SiO2
]+23.1×[Al2
O3
]+3.7×[B2
O3
]+12.9×[MgO]+14.1×[CaO]+15.5×[SrO]+15.0×[BaO]+7.2×[ZnO]≧1786莫耳%的關係。
另外,本發明的無鹼玻璃板較佳為Rh的含量為0.1質量ppm~3質量ppm。此處,「Rh」不僅包含Rh,亦包含RhO2
、Rh2
O3
,RhO2
、Rh2
O3
換算為Rh而進行表述。
另外,本發明的無鹼玻璃板較佳為楊氏模量(Young’s modulus)為82 GPa以上。此處,「楊氏模量」可藉由彎曲共振法而進行測定。
本發明的無鹼玻璃板的特徵在於:作為玻璃組成,以莫耳%計而含有55%~80%的SiO2
、10%~25%的Al2
O3
、0%~4%的B2
O3
、0%~30%的MgO、0%~25%的CaO、0%~15%的SrO、0%~15%的BaO、0%~5%的ZnO、0%~未滿1.0%的Y2
O3
+La2
O3
,實質不含鹼金屬氧化物。以下示出如所述般限定各成分的含量的理由。再者,於各成分的含量的說明中,除有特別說明的情況以外,%表達表示莫耳%。
SiO2
為形成玻璃骨架的成分,且是提高應變點的成分。因此,SiO2
的含量較佳為55%以上、60%以上、63%以上、65%以上、67%以上、尤其是68%以上。另一方面,若SiO2
的含量過多,則高溫黏度變高,熔融性容易下降。因此,SiO2
的含量較佳為80%以下、78%以下、75%以下、74%以下、73%以下、尤其是72%以下。
Al2
O3
為形成玻璃骨架的成分,且是提高應變點的成分,進而是抑制分相的成分。因此,Al2
O3
的含量較佳為10%以上、10.5%以上、11%以上、11.5%以上、尤其是12%以上。另一方面,若Al2
O3
的含量過多,則高溫黏度變高,熔融性容易下降。因此,Al2
O3
的含量較佳為25%以下、22%以下、20%以下、18%以下、16%以下、15%以下、尤其是14%以下。
SiO2
與Al2
O3
的合計量較佳為70%以上、75%以上、80%以上、81%以上、82%以上、83%以上、84%以上、尤其是85%以上。若SiO2
與Al2
O3
的合計量過少,則應變點容易下降。另一方面,若SiO2
與Al2
O3
的合計量過多,則高溫黏度變高,熔融性容易下降。因此,SiO2
與Al2
O3
的合計量較佳為90%以下、89%以下、88%以下、87%以下、尤其是86%以下。
B2
O3
為任意成分,但只要導入少量,便提高熔融性。因此,B2
O3
的含量較佳為0.01%以上、0.1%以上、0.2%以上、0.3%以上、0.4%以上、尤其是0.5%以上。另一方面,若B2
O3
的含量過多,則應變點大幅下降,β-OH大幅增加。詳細情況將於後敘述,若β-OH變多,則熱收縮率變大。因此,B2
O3
的含量較佳為4%以下、3.5%以下、3%以下、2.5%以下、2%以下、1.5%以下、尤其是1%以下。
MgO為降低高溫黏性並提高熔融性的成分,且是藉由與其他成分的平衡而提高耐失透性的成分。進而,就機械特性的觀點而言,為顯著提高楊氏模量的成分。因此,MgO的含量較佳為0%以上、0.5%以上、1%以上、1.5%以上、尤其是2%以上。另一方面,若MgO的含量過多,則應變點容易下降,或與其他成分的平衡崩潰而失透傾向變強。因此,MgO的含量較佳為30%以下、15%以下、10%以下、9%以下、8%以下、7.5%以下、7%以下、6.5%以下、尤其是6%以下。
CaO為降低高溫黏性並提高熔融性的成分,且是藉由與其他成分的平衡而提高耐失透性的成分。因此,CaO的含量較佳為0%以上、0.5%以上、1%以上、1.5%以上、尤其是2%以上。另一方面,若CaO的含量過多,則應變點容易下降。因此,CaO的含量較佳為25%以下、15%以下、10%以下、9%以下、8%以下、7.5%以下、7%以下、6.5%以下、尤其是6%以下。
SrO為降低高溫黏性並提高熔融性的成分,且是藉由與其他成分的平衡而提高耐失透性的成分。因此,SrO的含量較佳為0%以上、0.5%以上、1%以上、1.5%以上、尤其是2%以上。另一方面,若SrO的含量過多,則應變點容易下降。因此,SrO的含量較佳為15%以下、10%以下、9%以下、8%以下、7%以下、6%以下、5%以下、尤其是4%以下。
BaO為降低高溫黏性並提高熔融性的成分,且是藉由與其他成分的平衡而提高耐失透性的成分。因此,BaO的含量較佳為0%以上、0.5%以上、1%以上、1.5%以上、2%以上、2.5%以上、尤其是3%以上。另一方面,若BaO的含量過多,則應變點容易下降。因此,BaO的含量較佳為15%以下、10%以下、9%以下、8%以下、7.5%以下、7%以下、6.5%以下、尤其是6%以下。
SrO與BaO的合計量較佳為0%以上、2%以上、3%以上、4%以上、尤其是5%以上。若SrO與BaO的合計量過少,則熔融性容易下降。另一方面,若SrO與BaO的合計量過多,則損及玻璃組成的成分平衡,耐失透性容易下降。因此,SrO與BaO的合計量較佳為20%以下、16%以下、14%以下、12%以下、10%以下、9%以下、尤其是8%以下。
MgO、CaO、SrO及BaO的合計量較佳為9.9%以上、12%以上、12.5%以上、13%以上、13.5%以上、尤其是14%以上。若MgO、CaO、SrO及BaO的合計量過少,則熔融性容易下降。另一方面,若MgO、CaO、SrO及BaO的合計量過多,則應變點下降,或損及玻璃組成的成分平衡,耐失透性容易下降。因此,MgO、CaO、SrO及BaO的合計量較佳為25%以下、20%以下、16%以下、15.5%以下、15%以下、14.5%以下、尤其是14%以下。
莫耳%比[B2
O3
]/([SrO]+[BaO])較佳為0~0.5、0~0.45、0~0.4、0~0.35、0.01~0.3、0.05~0.25、尤其是0.1~0.2。若莫耳%比[B2
O3
]/([SrO]+[BaO])成為所述範圍外,則本發明的玻璃系中,各成分的平衡崩潰,耐失透性容易下降。再者,「[B2
O3
]/([SrO]+[BaO])」是指將B2
O3
的含量除以SrO與BaO的合計量所得的值。
[SiO2
]+14×[Al2
O3
]-15×[B2
O3
]+6×[MgO]+[CaO]+14×[SrO]+16×[BaO]較佳為300%以上、330%以上、350%以上、360%以上、370%以上、380%以上、390%以上、400%以上、410%以上、420%以上、430%以上。若[SiO2
]+14×[Al2
O3
]-15×[B2
O3
]+6×[MgO]+[CaO]+14×[SrO]+16×[BaO]過小,則難以兼具高應變點、高楊氏模量及高耐失透性。
17.8×[SiO2
]+23.1×[Al2
O3
]+3.7×[B2
O3
]+12.9×[MgO]+14.1×[CaO]+15.5×[SrO]+15.0×[BaO]+7.2×[ZnO]較佳為1740%以上、1750%以上、1760%以上、1770%以上、1780%以上、尤其是1786%以上。若17.8×[SiO2
]+23.1×[Al2
O3
]+3.7×[B2
O3
]+12.9×[MgO]+14.1×[CaO]+15.5×[SrO]+15.0×[BaO]+7.2×[ZnO]過大,則玻璃板的熱收縮容易變大。
[Al2
O3
]+[B2
О3
]-[CaО]-[SrО]-[BaO]較佳為0%以上、0.1%以上、尤其是1.0%以上。若[Al2
O3
]+[B2
О3
]-[CaО]-[SrО]-[BaO]過小,則玻璃中的非交聯氧等變多,容易產生結構性不均衡,因此於高溫成膜製程中,玻璃板容易熱收縮。另一方面,若[Al2
O3
]+[B2
О3
]-[CaО]-[SrО]-[BaO]過大,則熔融負荷變高,或耐失透性變低,玻璃板的製造成本容易高漲。因此,[Al2
O3
]+[B2
О3
]-[CaО]-[SrО]-[BaO]較佳為10.0%以下、6.0%以下、5.0%以下、4.5%以下、4.0%以下、3.0%以下、尤其是2.0%以下。
Y2
O3
為提高應變點、楊氏模量等的成分,但若其含量過多,則密度、原料成本容易增加。因此,Y2
O3
的含量較佳為0%~0.8%、0%~0.7%、0%~0.5%、0%~0.2%、尤其是0%~0.1%。
La2
O3
為提高應變點、楊氏模量等的成分,但若其含量過多,則密度、原料成本容易增加。因此,La2
O3
的含量較佳為0%~0.8%、0%~0.7%、0%~0.5%、0%~0.2%、尤其是0%~0.1%。
Y2
O3
與La2
O3
的合計量較佳為0%~未滿1.0%、0%~0.8%、0%~0.7%、0%~0.5%、0%~0.2%、尤其是0%~0.1%。但是,若Y2
O3
與La2
O3
的合計量過多,則密度、原料成本容易增加。
本發明的無鹼玻璃板除所述成分以外,亦可於玻璃組成中包含以下成分。
ZnO為提高熔融性的成分,但若大量含有ZnO,則玻璃容易失透,且應變點容易下降。ZnO的含量較佳為0%~5%、0%~3%、0%~0.5%、0%~0.3%、尤其是0%~0.2%。
P2
O5
為維持應變點並且使Al系失透結晶的液相溫度顯著下降的成分,但若大量含有P2
O5
,則楊氏模量下降,或玻璃分相。另外,有如下擔憂:P自玻璃擴散而對TFT的性能造成影響。因此,P2
O5
的含量較佳為0%~1.5%、0%~1.2%、0%~1%、尤其是0%~0.5%。
TiO2
為降低高溫黏性並提高熔融性的成分,並且是抑制曝曬(solarization)的成分,但若大量含有TiO2
,則玻璃著色,透過率容易下降。因此,TiO2
的含量較佳為0質量ppm~500質量ppm、0.1質量ppm~100質量ppm、0.1質量ppm~50質量ppm、0.5質量ppm~30質量ppm、1質量ppm~20質量ppm、3質量ppm~15質量ppm、尤其是5質量ppm~10質量ppm。
SnO2
為於高溫區域具有良好的澄清作用的成分,並且是提高應變點的成分,且是使高溫黏性下降的成分。SnO2
的含量較佳為0%~1%、0.001%~1%、0.05%~0.5%、尤其是0.08%~0.2%。若SnO2
的含量多,則SnO2
的失透結晶容易析出。再者,若SnO2
的含量少於0.001%,則難以享有所述效果。
SnO2
適合作為澄清劑,但只要不會大幅損及玻璃特性,則亦可使用SnO2
以外的澄清劑。具體而言,可以合計量計添加As2
O3
、Sb2
O3
、CeO2
、F2
、Cl2
、SO3
、C至例如0.5%為止,亦可以合計量計添加Al、Si等金屬粉末至例如0.5%為止。
As2
O3
與Sb2
O3
的澄清性優異,但就環境的觀點而言,較佳為儘量不導入。進而,若於玻璃中大量含有As2
O3
,則有耐曝曬性下降的傾向,因此As2
O3
的含量較佳為1000質量ppm以下、100質量ppm以下、尤其是未滿30質量ppm。另外,Sb2
O3
的含量較佳為1000質量ppm以下、100質量ppm以下、尤其是未滿30質量ppm。
Cl具有促進無鹼玻璃的熔融的效果,若添加Cl,則可使熔融溫度低溫化,並且促進澄清劑的作用,結果,可使熔融成本低廉化並且實現玻璃製造窯的長壽命化。但是,若Cl的含量過多,則應變點下降。因此,Cl的含量較佳為0.5%以下、尤其是0.1%以下。再者,作為Cl的導入原料,可使用氯化鍶等鹼土類金屬氧化物的氯化物或氯化鋁等。
Rh為熔融設備中所含的成分,且是將玻璃於高溫下熔融時熔出至玻璃坯料中的成分。另一方面,Rh為與SnO2
共存時使玻璃著色的成分。Rh的含量較佳為0質量ppm~3質量ppm、0.1質量ppm~3質量ppm、0.2質量ppm~2.5質量ppm、0.3質量ppm~2質量ppm、0.4質量ppm~1.5質量ppm、尤其是0.5質量ppm~1質量ppm。再者,若使熔融溫度下降,則Rh的含量容易下降。
Ir為耐熱性高於Pt或Pt-Rh合金且可減低與熔融玻璃的界面中的熔融玻璃的發泡的成分。另外,Ir為熔融設備中所含的成分,且是將玻璃於高溫下熔融時熔出至玻璃坯料中的成分。另一方面,若Ir的熔出量變多,則有於玻璃中以異物的形式析出的擔憂。因此,Ir的含量較佳為以0質量ppm~10質量ppm、0.01質量ppm~10質量ppm、0.02質量ppm~5質量ppm、0.03質量ppm~3質量ppm、0.04質量ppm~2質量ppm、尤其是0.05質量ppm~1質量ppm為宜。再者,「Ir」不僅包含Ir,亦包含IrO2
、Ir2
O3
,IrO2
、Ir2
O3
換算為Ir而進行表述。
鉬為熔融步驟中的電極中所使用的成分,且是將玻璃於高溫下熔融時以MoO3
的形式熔出至玻璃坯料中的成分。MoO3
的含量較佳為0質量ppm~50質量ppm、1質量ppm~50質量ppm、3質量ppm~40質量ppm、5質量ppm~30質量ppm、5質量ppm~25質量ppm、尤其是5質量ppm~20質量ppm。再者,若MoO3
的含量過少,則難以利用加熱電極對熔融玻璃進行通電加熱,因此難以減低β-OH。
ZrO2
為熔融步驟中的耐火材料中所含的成分,且是將玻璃於高溫下熔融時熔出至玻璃坯料中的成分。另外,ZrO2
為提高液相溫度或耐候性的成分。另一方面,於過度減少ZrO2
的含量的情況下,需要於熔融步驟中使用昂貴的耐火材料,有使玻璃板的製造成本高漲的擔憂。因此,ZrO2
的含量較佳為以0質量ppm~2000質量ppm、500質量ppm~2000質量ppm、550質量ppm~1500質量ppm、尤其是600質量ppm~1200質量ppm為宜。
Fe2
O3
為以原料雜質的形式混入的成分,且是使電阻率下降的成分。Fe2
O3
的含量較佳為50質量ppm~300質量ppm、80質量ppm~250質量ppm、尤其是100質量ppm~200質量ppm。若Fe2
O3
的含量過少,則原料成本容易高漲。另一方面,若Fe2
O3
的含量過多,則熔融玻璃的電阻率上升而難以進行電熔融。
本發明的無鹼玻璃板實質不含鹼金屬氧化物,但並不排除以不可避免的雜質的形式混入的情況。於鹼金屬氧化物以不可避免的雜質的形式混入的情況下,鹼金屬氧化物的含量(Li2
O、Na2
O及K2
O的合計量)較佳為10質量ppm~1000質量ppm、30質量ppm~600質量ppm、50質量ppm~300質量ppm、70質量ppm~200質量ppm、尤其是80質量ppm~150質量ppm。尤其是Na2
O的含量較佳為30質量ppm~600質量ppm、50質量ppm~300質量ppm、70質量ppm~200質量ppm、尤其是80質量ppm~150質量ppm。若鹼金屬氧化物的含量過少,則高純度原料的使用變得不可或缺,配合料(batch)成本高漲。另外,導電度變得過低而難以進行電熔融。另一方面,若鹼金屬氧化物的含量過多,則有如下擔憂:於熱處理步驟中,鹼離子擴散至半導體膜中。
本發明的無鹼玻璃板較佳為具有以下特性。
熱膨脹係數較佳為46×10-7
/℃以下、42×10-7
/℃以下、40×10-7
/℃以下、38×10-7
/℃以下、尤其是26×10-7
/℃以上且36×10-7
/℃以下。若熱膨脹係數過高,則因高溫成膜製程中的溫度不均而於玻璃板上容易產生局部尺寸變化。
密度較佳為2.80 g/cm3
以下、2.75 g/cm3
以下、2.70 g/cm3
以下、2.65 g/cm3
以下、2.60 g/cm3
以下、2.55 g/cm3
以下、尤其是2.45 g/cm3
~2.50 g/cm3
。若密度過高,則玻璃板的彎曲量容易變大,因此於顯示器的製造步驟等中,容易助長應力引起的圖案偏移。
應變點為750℃以上,較佳為760℃以上、765℃以上、770℃以上、775℃以上、780℃以上、785℃以上、790℃以上、795℃以上、800℃以上。若應變點過低,則於高溫成膜製程中,玻璃板容易熱收縮。
緩冷點較佳為800℃以上、805℃以上、810℃以上、820℃以上、830℃以上、840℃以上、尤其是850℃以上。若緩冷點過低,則於高溫成膜製程中,玻璃板容易熱收縮。
軟化點較佳為1040℃以上、1060℃以上、1080℃以上、尤其是1100℃以上。若軟化點過低,則於高溫成膜製程中,玻璃板容易熱收縮。
高溫黏度102.5
dPa·s下的溫度較佳為1750℃以下、1720℃以下、1700℃以下、1690℃以下、1680℃以下、尤其是1670℃以下。若102.5
dPa·s下的溫度變高,則熔融性、澄清性容易下降,玻璃板的製造成本高漲。
楊氏模量較佳為80 GPa以上、81 GPa以上、82 GPa以上、尤其是83 GPa以上。若楊氏模量過低,則玻璃板的彎曲量容易變大,因此於顯示器的製造步驟等中,容易助長應力引起的圖案偏移。
比楊氏模量較佳為30 GPa/g·cm-3
以上、31 GPa/g·cm-3
以上、32 GPa/g·cm-3
以上、尤其是33 GPa/g·cm-3
以上。若比楊氏模量過低,則玻璃板的彎曲量容易變大,因此於顯示器的製造步驟等中,容易助長應力引起的圖案偏移。
β-OH為表示玻璃中的水分量的指標,若使β-OH下降,則可提高應變點。另外,即便於玻璃組成相同的情況下,β-OH小者的應變點以下溫度下的熱收縮率亦變小。β-OH較佳為0.30/mm以下、0.25/mm以下、0.20/mm以下、0.15/mm以下、尤其是0.10/mm以下。再者,若β-OH過小,則熔融性容易下降。因此,β-OH較佳為0.01/mm以上、尤其是0.03/mm以上。
作為使β-OH下降的方法,可列舉以下方法。(1)選擇含水量低的原料。(2)向玻璃中添加使β-OH下降的成分(Cl、SO3
等)。(3)使爐內環境中的水分量下降。(4)於熔融玻璃中進行N2
起泡。(5)採用小型熔融爐。(6)增多熔融玻璃的流量。(7)採用電熔融法。
此處,「β-OH」是指使用傅立葉轉換紅外光譜法(Fourier transform infrared spectroscopy,FT-IR)測定玻璃的透過率,並使用下述數式1而求出的值。
[數式1]
β-OH=(1/X)log(T1
/T2
)
X:板厚(mm)
T1
:參照波長3846 cm-1
下的透過率(%)
T2
:羥基吸收波長3600 cm-1
附近的最小透過率(%)
本發明的無鹼玻璃板較佳為於板厚方向的中央部具有溢流匯流面。即,較佳為利用溢流下拉法成形而成。所謂溢流下拉法是使熔融玻璃自楔形的耐火材料的兩側溢出,且使溢出的熔融玻璃於楔形的下端匯流,並且向下方延伸成形而成形為平板形狀的方法。溢流下拉法中,應成為玻璃板的表面的面不接觸耐火材料,而以自由表面的狀態來成形。因此,可廉價地製造未研磨且表面品質良好的玻璃板。進而,大面積化或薄壁化亦容易。
除溢流下拉法以外,例如亦可利用流孔下引(slot down)法、再拉(redraw)法、浮動(float)法、滾壓(roll out)法來成形。
於本發明的無鹼玻璃板中,板厚並無特別限定,較佳為1.0 mm以下、0.7 mm以下、0.5 mm以下、尤其是0.05 mm~0.4 mm。板厚越小,越容易使液晶面板或有機EL面板輕量化。再者,板厚可利用玻璃製造時的流量或成形速度(拉板速度)等來調整。
於工業上製造本發明的無鹼玻璃板的方法較佳為包括:熔融步驟,藉由將玻璃配合料投入至熔融爐中,利用加熱電極進行通電加熱而獲得熔融玻璃,所述玻璃配合料是以作為玻璃組成,以莫耳%計而含有55%~80%的SiO2
、10%~25%的Al2
O3
、0%~4%的B2
O3
、0%~30%的MgO、0%~25%的CaO、0%~15%的SrO、0%~15%的BaO、0%~5%的ZnO、0%~未滿1.0%的Y2
O3
+La2
O3
,實質不含鹼金屬氧化物的方式調合而成;以及成形步驟,藉由溢流下拉法而將所獲得的熔融玻璃成形為板厚0.1 mm~0.7 mm的無鹼玻璃板。
玻璃板的製造步驟通常包括熔融步驟、澄清步驟、供給步驟、攪拌步驟、成形步驟。熔融步驟是將調合有玻璃原料的玻璃配合料熔融而獲得熔融玻璃的步驟。澄清步驟是藉由澄清劑等的作用而使熔融步驟中所獲得的熔融玻璃進行澄清的步驟。供給步驟是於各步驟間移送熔融玻璃的步驟。攪拌步驟是將熔融玻璃攪拌、均質化的步驟。成形步驟是將熔融玻璃成形為玻璃板的步驟。再者,視需要亦可將所述以外的步驟、例如將熔融玻璃調節為適合於成形的狀態的狀態調節步驟併入攪拌步驟後。
於在工業上製造無鹼玻璃板的情況下,通常藉由利用燃燒器的燃燒火焰的加熱而熔融。燃燒器通常配置於熔融窯的上方,作為燃料,使用化石燃料,具體而言為重油等液體燃料或液化石油氣(Liquefied Petroleum Gas,LPG)等氣體燃料等。燃燒火焰可藉由將化石燃料與氧氣混合而獲得。但是,該方法中,由於熔融時大量的水分混入至熔融玻璃中,因此β-OH容易上升。因此,當製造本發明的無鹼玻璃板時,較佳為進行利用加熱電極的通電加熱,較佳為不進行利用燃燒器的燃燒火焰的加熱,而藉由利用加熱電極的通電加熱來熔融即完全電熔融。藉此,熔融時水分難以混入至熔融玻璃中,因此容易將β-OH限制為0.30/mm以下、0.25/mm以下、0.20/mm以下、0.15/mm以下、尤其是0.10/mm以下。進而,若進行利用加熱電極的通電加熱,則用以獲得熔融玻璃的每單位質量的能量的量下降,並且熔融揮發物變少,因此可減低環境負荷。
進而,關於該通電加熱,玻璃配合料中的水分量越少,越容易減低玻璃板中的β-OH。而且,B2
O3
的導入原料容易成為最大的水分的混入源。因此,就製造低β-OH的玻璃板的觀點而言,較佳為使B2
O3
的含量盡可能少。另外,玻璃配合料中的水分量越少,玻璃配合料於熔融窯內越容易均勻地擴展,因此容易製造均質且高品質的玻璃板。
利用加熱電極的通電加熱較佳為藉由如下方式來進行:對以與熔融窯內的熔融玻璃接觸的方式設置於熔融窯的底部或側部的加熱電極施加交流電壓。加熱電極中使用的材料較佳為具備耐熱性與對熔融玻璃的耐蝕性者,例如可使用氧化錫、鉬、鉑、銠等,尤其就爐內設置的自由度的觀點而言,較佳為鉬。
本發明的無鹼玻璃板由於實質不含鹼金屬氧化物,因此電阻率高。因此,於利用加熱電極進行通電加熱的情況下,不僅於熔融玻璃中,於構成熔融窯的耐火材料中亦流通電流,有構成熔融窯的耐火材料提前受損的擔憂。為了防止所述情況,爐內耐火材料較佳為使用電阻率高的氧化鋯系耐火材料、尤其是氧化鋯電鑄耐火磚(electrocast brick),另外,較佳為向熔融玻璃(玻璃組成)中導入少量的使電阻率下降的成分(Fe2
O3
等),Fe2
O3
的含量較佳為50質量ppm~300質量ppm、80質量ppm~250質量ppm、尤其是100質量ppm~200質量ppm。進而,氧化鋯系耐火材料中的ZrO2
的含量較佳為85質量%以上、尤其是90質量%以上。
[實施例1]
以下,基於實施例對本發明進行說明。但是,以下實施例僅為例示。本發明並不受以下實施例任何限定。
表1~表49示出本發明的實施例(試樣No.1~試樣No.679)。再者,試樣No.281~試樣No.679的玻璃特性並非實測值,而是根據組成因數進行計算而得的計算值。
[表1]
No.1 | No.2 | No.3 | No.4 | No.5 | No.6 | No.7 | No.8 | No.9 | No.10 | No.11 | No.12 | No.13 | No.14 | ||
莫耳% | SiO2 | 72.9 | 58.8 | 64.1 | 71.7 | 75.1 | 59.8 | 59.8 | 59.8 | 59.8 | 64.8 | 64.8 | 64.8 | 64.8 | 69.8 |
Al2 O3 | 11.3 | 11.6 | 12.7 | 14.2 | 14.8 | 25.0 | 25.0 | 25.0 | 25.0 | 20.0 | 20.0 | 20.0 | 20.0 | 15.0 | |
B2 O3 | 0.3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 3.1 | 29.4 | 0.0 | 0.0 | 0.0 | 15.0 | 0.0 | 0.0 | 0.0 | 15.0 | 0.0 | 0.0 | 0.0 | 15.0 | |
CaO | 7.2 | 0.0 | 23.0 | 0.0 | 0.0 | 0.0 | 15.0 | 0.0 | 0.0 | 0.0 | 15.0 | 0.0 | 0.0 | 0.0 | |
SrO | 0.5 | 0.0 | 0.0 | 13.9 | 0.0 | 0.0 | 0.0 | 15.0 | 0.0 | 0.0 | 0.0 | 15.0 | 0.0 | 0.0 | |
BaO | 4.5 | 0.0 | 0.0 | 0.0 | 9.9 | 0.0 | 0.0 | 0.0 | 15.0 | 0.0 | 0.0 | 0.0 | 15.0 | 0.0 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | |
[SiO2 ]+[Al2 O3 ] | 84.2 | 70.4 | 76.8 | 85.9 | 89.9 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | |
[MgO]+[CaO]+[SrO]+[BaO] | 15.3 | 29.4 | 23.0 | 13.9 | 9.9 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | |
[SrO]+[BaO] | 5.0 | 0.0 | 0.0 | 13.9 | 9.9 | 0.0 | 0.0 | 15.0 | 15.0 | 0.0 | 0.0 | 15.0 | 15.0 | 0.0 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.1 | - | - | 0.0 | 0.0 | - | - | 0.0 | 0.0 | - | - | 0.0 | 0.0 | - | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | -0.6 | 11.6 | -10.4 | 0.2 | 5.0 | 25.0 | 10.0 | 10.0 | 10.0 | 20.0 | 5.0 | 5.0 | 5.0 | 15.0 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 331.4 | 397.7 | 264.4 | 464.9 | 440.4 | 499.8 | 424.8 | 619.8 | 649.8 | 434.8 | 359.8 | 554.8 | 584.8 | 369.8 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1776.5 | 1694.4 | 1758.6 | 1819.5 | 1827.4 | 1835.4 | 1853.4 | 1874.4 | 1866.9 | 1808.9 | 1826.9 | 1847.9 | 1840.4 | 1782.4 | |
熱膨脹係數(10-7 /℃) | 39.8 | 42.0 | 50.7 | 42.9 | 36.0 | 32.0 | 38.2 | 40.9 | 43.5 | 30.4 | 37.6 | 41.7 | 45.3 | 28.7 | |
密度(g/cm3 ) | 2.617 | 2.610 | 2.608 | 2.699 | 2.731 | 2.590 | 2.612 | 2.818 | 3.015 | 2.537 | 2.566 | 2.778 | 2.977 | 2.482 | |
應變點(℃) | 756 | 742 | 754 | 822 | 835 | 未測定 | 809 | 822 | 未測定 | 未測定 | 808 | 824 | 832 | 未測定 | |
緩冷點(℃) | 813 | 787 | 802 | 886 | 904 | 未測定 | 858 | 875 | 未測定 | 未測定 | 861 | 880 | 894 | 未測定 | |
軟化點(℃) | 1058 | 960 | 988 | 1165 | 未測定 | 未測定 | 1042 | 未測定 | 未測定 | 未測定 | 1060 | 1091 | 1120 | 1044 | |
104.5 dPa·s(℃) | 1401 | 1180 | 1243 | 1438 | 1516 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 1327 | 1365 | 1413 | 1330 | |
104.0 dPa·s(℃) | 1574 | 1296 | 1382 | 1602 | 1688 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 1453 | 1506 | 1554 | 1475 | |
103.0 dPa·s(℃) | 1682 | 1374 | 1475 | 1708 | 1800 | 1578 | 未測定 | 未測定 | 未測定 | 未測定 | 1538 | 1595 | 1645 | 1568 | |
102.5 dPa·s(℃) | 1335 | 1138 | 1193 | 1379 | 1458 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 1277 | 1312 | 1358 | 未測定 | |
楊氏模量(GPa) | 81.0 | 99.2 | 85.9 | 79.5 | 77.8 | 102.3 | 94.0 | 89.5 | 84.5 | 97.2 | 89.5 | 84.8 | 80.3 | 91.9 | |
比楊氏模量(GPa/g·cm-3 ) | 30.9 | 38.0 | 32.9 | 29.5 | 28.5 | 39.5 | 36.0 | 31.8 | 28.0 | 38.3 | 34.9 | 30.5 | 27.0 | 37.0 | |
β-OH(mm-1 ) | 0.13 | 0.08 | 0.08 | 0.04 | 0.04 | 0.07 | 0.14 | 0.14 | 0.07 | 0.11 | 0.05 | 0.07 | 0.05 | 0.12 |
[表2]
No.15 | No.16 | No.17 | No.18 | No.19 | No.20 | No.21 | No.22 | No.23 | No.24 | No.25 | No.26 | No.27 | No.28 | ||
莫耳% | SiO2 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 64.8 | 64.8 | 64.8 | 64.8 | 69.8 | 69.8 | 69.8 |
Al2 O3 | 15.0 | 15.0 | 15.0 | 20.0 | 20.0 | 20.0 | 20.0 | 25.0 | 25.0 | 25.0 | 25.0 | 15.0 | 15.0 | 15.0 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 0.0 | 0.0 | 0.0 | 10.0 | 0.0 | 0.0 | 0.0 | 10.0 | 0.0 | 0.0 | 0.0 | 7.5 | 7.5 | 7.5 | |
CaO | 15.0 | 0.0 | 0.0 | 0.0 | 10.0 | 0.0 | 0.0 | 0.0 | 10.0 | 0.0 | 0.0 | 7.5 | 0.0 | 0.0 | |
SrO | 0.0 | 15.0 | 0.0 | 0.0 | 0.0 | 10.0 | 0.0 | 0.0 | 0.0 | 10.0 | 0.0 | 0.0 | 7.5 | 0.0 | |
BaO | 0.0 | 0.0 | 15.0 | 0.0 | 0.0 | 0.0 | 10.0 | 0.0 | 0.0 | 0.0 | 10.0 | 0.0 | 0.0 | 7.5 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | |
[SiO2 ]+[Al2 O3 ] | 84.8 | 84.8 | 84.8 | 89.8 | 89.8 | 89.8 | 89.8 | 89.8 | 89.8 | 89.8 | 89.8 | 84.8 | 84.8 | 84.8 | |
[MgO]+[CaO]+[SrO]+[BaO] | 15.0 | 15.0 | 15.0 | 10.0 | 10.0 | 10.0 | 10.0 | 10.0 | 10.0 | 10.0 | 10.0 | 15.0 | 15.0 | 15.0 | |
[SrO]+[BaO] | 0.0 | 15.0 | 15.0 | 0.0 | 0.0 | 10.0 | 10.0 | 0.0 | 0.0 | 10.0 | 10.0 | 0.0 | 7.5 | 7.5 | |
[B2 O3 ]/([SrO]+[BaO]) | - | 0.0 | 0.0 | - | - | 0.0 | 0.0 | - | - | 0.0 | 0.0 | - | 0.0 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 0.0 | 0.0 | 0.0 | 20.0 | 10.0 | 10.0 | 10.0 | 25.0 | 15.0 | 15.0 | 15.0 | 7.5 | 7.5 | 7.5 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 294.8 | 489.8 | 519.8 | 409.8 | 359.8 | 489.8 | 509.8 | 474.8 | 424.8 | 554.8 | 574.8 | 332.3 | 429.8 | 444.8 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1800.4 | 1821.4 | 1813.9 | 1833.4 | 1845.4 | 1859.4 | 1854.4 | 1859.9 | 1871.9 | 1885.9 | 1880.9 | 1791.4 | 1801.9 | 1798.2 | |
熱膨脹係數(10-7 /℃) | 39.1 | 44.6 | 49.0 | 26.5 | 30.7 | 32.9 | 34.9 | 未測定 | 未測定 | 未測定 | 未測定 | 33.0 | 35.5 | 36.6 | |
密度(g/cm3 ) | 2.518 | 2.734 | 2.934 | 2.491 | 2.508 | 2.649 | 2.784 | 未測定 | 未測定 | 未測定 | 未測定 | 2.501 | 2.612 | 2.722 | |
應變點(℃) | 808 | 823 | 832 | 未測定 | 809 | 823 | 824 | 未測定 | 未測定 | 未測定 | 未測定 | 773 | 776 | 780 | |
緩冷點(℃) | 862 | 882 | 896 | 未測定 | 870 | 881 | 888 | 未測定 | 未測定 | 未測定 | 未測定 | 828 | 833 | 839 | |
軟化點(℃) | 1073 | 1107 | 1137 | 未測定 | 1078 | 1101 | 1123 | 未測定 | 未測定 | 未測定 | 未測定 | 1048 | 1060 | 1073 | |
104.5 dPa·s(℃) | 1362 | 1416 | 1471 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 1345 | 1368 | 1405 | |
104.0 dPa·s(℃) | 1515 | 1573 | 1630 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 1497 | 1522 | 1558 | |
103.0 dPa·s(℃) | 1612 | 1674 | 1736 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 1596 | 1621 | 1644 | |
102.5 dPa·s(℃) | 1305 | 1356 | 1407 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 1287 | 1309 | 1341 | |
楊氏模量(GPa) | 84.8 | 79.8 | 75.0 | 94.2 | 89.1 | 86.0 | 82.6 | 未測定 | 未測定 | 未測定 | 未測定 | 89.1 | 86.5 | 83.9 | |
比楊氏模量(GPa/g·cm-3 ) | 33.7 | 29.2 | 25.6 | 37.8 | 35.5 | 32.5 | 29.7 | 未測定 | 未測定 | 未測定 | 未測定 | 35.6 | 33.1 | 30.8 | |
β-OH(mm-1 ) | 0.07 | 0.13 | 0.13 | 0.15 | 0.15 | 0.15 | 0.07 | 0.05 | 0.04 | 0.15 | 0.06 | 0.06 | 0.08 | 0.08 |
[表3]
No.29 | No.30 | No.31 | No.32 | No.33 | No.34 | No.35 | No.36 | No.37 | No.38 | No.39 | No.40 | No.41 | No.42 | ||
莫耳% | SiO2 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 63.8 | 63.8 | 63.8 | 63.8 | 63.8 |
Al2 O3 | 15.0 | 15.0 | 15.0 | 13.0 | 13.0 | 13.0 | 13.0 | 13.0 | 13.0 | 18.0 | 18.0 | 18.0 | 18.0 | 18.0 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 0.0 | 0.0 | 0.0 | 8.5 | 8.5 | 8.5 | 0.0 | 0.0 | 0.0 | 9.0 | 9.0 | 9.0 | 0.0 | 0.0 | |
CaO | 7.5 | 7.5 | 0.0 | 8.5 | 0.0 | 0.0 | 8.5 | 8.5 | 0.0 | 9.0 | 0.0 | 0.0 | 9.0 | 9.0 | |
SrO | 7.5 | 0.0 | 7.5 | 0.0 | 8.5 | 0.0 | 8.5 | 0.0 | 8.5 | 0.0 | 9.0 | 0.0 | 9.0 | 0.0 | |
BaO | 0.0 | 7.5 | 7.5 | 0.0 | 0.0 | 8.5 | 0.0 | 8.5 | 8.5 | 0.0 | 0.0 | 9.0 | 0.0 | 9.0 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | |
[SiO2 ]+[Al2 O3 ] | 84.8 | 84.8 | 84.8 | 82.8 | 82.8 | 82.8 | 82.8 | 82.8 | 82.8 | 81.8 | 81.8 | 81.8 | 81.8 | 81.8 | |
[MgO]+[CaO]+[SrO]+[BaO] | 15.0 | 15.0 | 15.0 | 17.0 | 17.0 | 17.0 | 17.0 | 17.0 | 17.0 | 18.0 | 18.0 | 18.0 | 18.0 | 18.0 | |
[SrO]+[BaO] | 7.5 | 7.5 | 15.0 | 0.0 | 8.5 | 8.5 | 8.5 | 8.5 | 17.0 | 0.0 | 9.0 | 9.0 | 9.0 | 9.0 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | 0.0 | - | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | - | 0.0 | 0.0 | 0.0 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 0.0 | 0.0 | 0.0 | 4.5 | 4.5 | 4.5 | -4.0 | -4.0 | -4.0 | 9.0 | 9.0 | 9.0 | 0.0 | 0.0 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 392.3 | 407.3 | 504.8 | 311.3 | 421.8 | 438.8 | 379.3 | 396.3 | 506.8 | 378.8 | 495.8 | 513.8 | 450.8 | 468.8 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1810.9 | 1807.2 | 1817.7 | 1772.2 | 1784.1 | 1779.9 | 1794.3 | 1790.1 | 1802.0 | 1794.4 | 1807.0 | 1802.5 | 1817.8 | 1813.3 | |
熱膨脹係數(10-7 /℃) | 41.0 | 43.0 | 46.4 | 35.5 | 38.3 | 40.3 | 44.5 | 46.9 | 49.6 | 36.6 | 39.1 | 40.1 | 45.1 | 46.8 | |
密度(g/cm3 ) | 2.623 | 2.736 | 2.838 | 2.503 | 2.631 | 2.757 | 2.654 | 2.782 | 2.901 | 2.565 | 2.695 | 2.825 | 2.708 | 2.838 | |
應變點(℃) | 806 | 798 | 816 | 760 | 767 | 770 | 774 | 762 | 768 | 766 | 771 | 777 | 802 | 797 | |
緩冷點(℃) | 863 | 856 | 879 | 814 | 823 | 829 | 830 | 819 | 828 | 818 | 824 | 814 | 856 | 855 | |
軟化點(℃) | 1075 | 1091 | 1117 | 1035 | 1048 | 1060 | 1052 | 1051 | 1063 | 1019 | 1032 | 1042 | 1060 | 1065 | |
104.5 dPa·s(℃) | 1393 | 1411 | 1444 | 1339 | 1362 | 1383 | 1367 | 1382 | 1404 | 1283 | 1305 | 1326 | 1328 | 1346 | |
104.0 dPa·s(℃) | 1547 | 1570 | 1605 | 1495 | 1519 | 1545 | 1528 | 1549 | 1576 | 1417 | 1442 | 1467 | 1468 | 1489 | |
103.0 dPa·s(℃) | 1648 | 1673 | 1708 | 1597 | 1620 | 1651 | 1633 | 1656 | 1686 | 1505 | 1531 | 1559 | 1559 | 1582 | |
102.5 dPa·s(℃) | 1330 | 1352 | 1382 | 1280 | 1301 | 1321 | 1306 | 1318 | 1338 | 1233 | 1253 | 1273 | 1276 | 1292 | |
楊氏模量(GPa) | 83.0 | 80.5 | 78.1 | 87.9 | 85.2 | 82.1 | 81.9 | 79.3 | 77.1 | 93.1 | 90.0 | 86.7 | 85.7 | 82.9 | |
比楊氏模量(GPa/g·cm-3 ) | 31.6 | 29.4 | 27.5 | 35.1 | 32.4 | 29.8 | 30.9 | 28.5 | 26.6 | 36.3 | 33.4 | 30.7 | 31.6 | 29.2 | |
β-OH(mm-1 ) | 0.10 | 0.09 | 0.14 | 0.05 | 0.08 | 0.07 | 0.07 | 0.09 | 0.09 | 0.08 | 0.14 | 0.08 | 0.07 | 0.07 |
[表4]
No.43 | No.44 | No.45 | No.46 | No.47 | No.48 | No.49 | No.50 | No.51 | No.52 | No.53 | No.54 | No.55 | No.56 | ||
莫耳% | SiO2 | 63.8 | 63.8 | 63.8 | 63.8 | 63.8 | 63.8 | 63.8 | 69.8 | 69.8 | 69.8 | 69.8 | 66.5 | 69.8 | 69.8 |
Al2 O3 | 18.0 | 16.0 | 16.0 | 16.0 | 16.0 | 16.0 | 16.0 | 15.0 | 15.0 | 15.0 | 15.0 | 14.3 | 15.0 | 15.0 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 0.0 | 10.0 | 10.0 | 10.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
CaO | 0.0 | 10.0 | 0.0 | 0.0 | 10.0 | 10.0 | 0.0 | 10.0 | 10.0 | 5.0 | 5.0 | 4.8 | 0.0 | 0.0 | |
SrO | 9.0 | 0.0 | 10.0 | 0.0 | 10.0 | 0.0 | 10.0 | 5.0 | 0.0 | 10.0 | 5.0 | 0.0 | 10.0 | 5.0 | |
BaO | 9.0 | 0.0 | 0.0 | 10.0 | 0.0 | 10.0 | 10.0 | 0.0 | 5.0 | 0.0 | 5.0 | 14.3 | 5.0 | 10.0 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | |
[SiO2 ]+[Al2 O3 ] | 81.8 | 79.8 | 79.8 | 79.8 | 79.8 | 79.8 | 79.8 | 84.8 | 84.8 | 84.8 | 84.8 | 80.8 | 84.8 | 84.8 | |
[MgO]+[CaO]+[SrO]+[BaO] | 18.0 | 20.0 | 20.0 | 20.0 | 20.0 | 20.0 | 20.0 | 15.0 | 15.0 | 15.0 | 15.0 | 19.0 | 15.0 | 15.0 | |
[SrO]+[BaO] | 18.0 | 0.0 | 10.0 | 10.0 | 10.0 | 10.0 | 20.0 | 5.0 | 5.0 | 10.0 | 10.0 | 14.3 | 15.0 | 15.0 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | - | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 0.0 | 6.0 | 6.0 | 6.0 | -4.0 | -4.0 | -4.0 | 0.0 | 0.0 | 0.0 | 0.0 | -4.8 | 0.0 | 0.0 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 585.8 | 357.8 | 487.8 | 507.8 | 437.8 | 457.8 | 587.8 | 359.8 | 369.8 | 424.8 | 434.8 | 499.8 | 499.8 | 509.8 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1825.9 | 1775.2 | 1789.2 | 1784.2 | 1801.2 | 1796.2 | 1810.2 | 1807.4 | 1804.9 | 1814.4 | 1811.9 | 1794.6 | 1818.9 | 1816.4 | |
熱膨脹係數(10-7 /℃) | 49.9 | 38.8 | 41.5 | 43.8 | 47.3 | 50.7 | 53.8 | 40.9 | 42.1 | 42.4 | 43.8 | 53.2 | 45.9 | 47.4 | |
密度(g/cm3 ) | 2.959 | 2.568 | 2.716 | 2.863 | 2.736 | 2.880 | 3.024 | 2.591 | 2.665 | 2.662 | 2.734 | 2.989 | 2.804 | 2.875 | |
應變點(℃) | 817 | 756 | 761 | 766 | 779 | 768 | 777 | 804 | 798 | 808 | 800 | 758 | 818 | 818 | |
緩冷點(℃) | 876 | 807 | 813 | 820 | 832 | 823 | 833 | 861 | 856 | 867 | 862 | 816 | 880 | 882 | |
軟化點(℃) | 1053 | 1008 | 1020 | 1033 | 1034 | 1036 | 1052 | 1080 | 1082 | 1089 | 1094 | 1041 | 1112 | 1121 | |
104.5 dPa·s(℃) | 1382 | 1269 | 1294 | 1314 | 1309 | 1325 | 1364 | 1374 | 1392 | 1398 | 1410 | 1359 | 1430 | 1453 | |
104.0 dPa·s(℃) | 1528 | 1404 | 1433 | 1456 | 1451 | 1472 | 1504 | 1534 | 1547 | 1556 | 1568 | 1517 | 1591 | 1617 | |
103.0 dPa·s(℃) | 1620 | 1492 | 1524 | 1547 | 1543 | 1565 | 1598 | 1630 | 1649 | 1658 | 1669 | 1617 | 1698 | 1730 | |
102.5 dPa·s(℃) | 1316 | 1219 | 1241 | 1260 | 1256 | 1269 | 1305 | 1316 | 1332 | 1338 | 1349 | 1297 | 1369 | 1389 | |
楊氏模量(GPa) | 80.0 | 92.1 | 88.7 | 85.1 | 84.7 | 81.6 | 79.0 | 83.7 | 82.0 | 82.2 | 81.1 | 78.4 | 79.2 | 77.5 | |
比楊氏模量(GPa/g·cm-3 ) | 27.0 | 35.9 | 32.7 | 29.7 | 31.0 | 28.3 | 26.1 | 32.3 | 30.8 | 30.9 | 29.7 | 26.2 | 28.2 | 27.0 | |
β-OH(mm-1 ) | 0.05 | 0.11 | 0.15 | 0.06 | 0.11 | 0.06 | 0.04 | 0.08 | 0.09 | 0.10 | 0.11 | 0.09 | 0.09 | 0.03 |
[表5]
No.57 | No.58 | No.59 | No.60 | No.61 | No.62 | No.63 | No.64 | No.65 | No.66 | No.67 | No.68 | No.69 | No.70 | ||
莫耳% | SiO2 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 |
Al2 O3 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 5.0 | 5.0 | 5.0 | 5.0 | 5.0 | 5.0 | 10.0 | 10.0 | 10.0 | 0.0 | 6.0 | 7.0 | 2.5 | 2.5 | |
CaO | 10.0 | 5.0 | 5.0 | 0.0 | 0.0 | 0.0 | 5.0 | 0.0 | 0.0 | 5.0 | 0.0 | 0.0 | 12.5 | 10.0 | |
SrO | 0.0 | 5.0 | 0.0 | 10.0 | 5.0 | 0.0 | 0.0 | 5.0 | 0.0 | 0.0 | 9.0 | 4.0 | 0.0 | 2.5 | |
BaO | 0.0 | 0.0 | 5.0 | 0.0 | 5.0 | 10.0 | 0.0 | 0.0 | 5.0 | 10.0 | 0.0 | 4.0 | 0.0 | 0.0 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | |
[SiO2 ]+[Al2 O3 ] | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | |
[MgO]+[CaO]+[SrO]+[BaO] | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | |
[SrO]+[BaO] | 0.0 | 5.0 | 5.0 | 10.0 | 10.0 | 10.0 | 0.0 | 5.0 | 5.0 | 10.0 | 9.0 | 8.0 | 0.0 | 2.5 | |
[B2 O3 ]/([SrO]+[BaO]) | - | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | - | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | - | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 5.0 | 5.0 | 5.0 | 5.0 | 5.0 | 5.0 | 10.0 | 10.0 | 10.0 | 0.0 | 6.0 | 7.0 | 2.5 | 2.5 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 319.8 | 384.8 | 394.8 | 449.8 | 459.8 | 469.8 | 344.8 | 409.8 | 419.8 | 444.8 | 441.8 | 441.8 | 307.3 | 339.8 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1794.4 | 1801.4 | 1798.9 | 1808.4 | 1805.9 | 1803.4 | 1788.4 | 1795.4 | 1792.9 | 1809.4 | 1805.8 | 1801.2 | 1797.4 | 1800.9 | |
熱膨脹係數(10-7 /℃) | 35.4 | 36.9 | 37.8 | 38.4 | 39.5 | 40.7 | 32.2 | 33.7 | 34.3 | 44.6 | 37.2 | 37.0 | 37.5 | 38.0 | |
密度(g/cm3 ) | 2.505 | 2.582 | 2.656 | 2.654 | 2.725 | 2.796 | 2.492 | 2.569 | 2.644 | 2.790 | 2.637 | 2.671 | 2.513 | 2.550 | |
應變點(℃) | 776 | 776 | 773 | 782 | 782 | 788 | 771 | 773 | 774 | 798 | 777 | 774 | 786 | 784 | |
緩冷點(℃) | 833 | 834 | 833 | 841 | 843 | 850 | 825 | 830 | 832 | 860 | 836 | 833 | 842 | 842 | |
軟化點(℃) | 1052 | 1058 | 1064 | 1070 | 1076 | 1087 | 1043 | 1051 | 1056 | 1100 | 1065 | 1066 | 1062 | 1064 | |
104.5 dPa·s(℃) | 1345 | 1364 | 1375 | 1381 | 1393 | 1411 | 1334 | 1351 | 1359 | 1432 | 1376 | 1380 | 1356 | 1363 | |
104.0 dPa·s(℃) | 1498 | 1523 | 1532 | 1538 | 1553 | 1571 | 1484 | 1501 | 1513 | 1594 | 1533 | 1538 | 1510 | 1519 | |
103.0 dPa·s(℃) | 1595 | 1625 | 1632 | 1639 | 1655 | 1674 | 1581 | 1601 | 1611 | 1694 | 1632 | 1638 | 1608 | 1617 | |
102.5 dPa·s(℃) | 1288 | 1305 | 1315 | 1321 | 1332 | 1349 | 1278 | 1293 | 1301 | 1368 | 1316 | 1320 | 1299 | 1305 | |
楊氏模量(GPa) | 88.3 | 87.1 | 85.3 | 84.9 | 83.4 | 81.7 | 90.7 | 88.7 | 86.9 | 78.9 | 86.0 | 85.3 | 86.9 | 86.4 | |
比楊氏模量(GPa/g·cm-3 ) | 35.3 | 33.7 | 32.1 | 32.0 | 30.6 | 29.2 | 36.4 | 34.5 | 32.9 | 28.3 | 32.6 | 31.9 | 34.6 | 33.9 | |
β-OH(mm-1 ) | 0.04 | 0.14 | 0.09 | 0.15 | 0.08 | 0.12 | 0.08 | 0.13 | 0.14 | 0.03 | 0.09 | 0.12 | 0.06 | 0.06 |
[表6]
No.71 | No.72 | No.73 | No.74 | No.75 | No.76 | No.77 | No.78 | No.79 | No.80 | No.81 | No.82 | No.83 | No.84 | ||
莫耳% | SiO2 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 |
Al2 O3 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 0.0 | 1.0 | 1.0 | 1.0 | 2.5 | 2.5 | 2.5 | 2.5 | 7.5 | |
CaO | 10.0 | 5.0 | 5.0 | 5.0 | 5.0 | 10.0 | 6.0 | 6.0 | 6.0 | 0.0 | 0.0 | 0.0 | 0.0 | 2.5 | |
SrO | 0.0 | 7.5 | 5.0 | 2.5 | 0.0 | 2.5 | 8.0 | 4.0 | 0.0 | 12.5 | 7.5 | 5.0 | 0.0 | 0.0 | |
BaO | 2.5 | 0.0 | 2.5 | 5.0 | 7.5 | 2.5 | 0.0 | 4.0 | 8.0 | 0.0 | 5.0 | 7.5 | 12.5 | 5.0 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | |
[SiO2 ]+[Al2 O3 ] | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | |
[MgO]+[CaO]+[SrO]+[BaO] | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | |
[SrO]+[BaO] | 2.5 | 7.5 | 7.5 | 7.5 | 7.5 | 5.0 | 8.0 | 8.0 | 8.0 | 12.5 | 12.5 | 12.5 | 12.5 | 5.0 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 0.0 | 1.0 | 1.0 | 1.0 | 2.5 | 2.5 | 2.5 | 2.5 | 7.5 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 344.8 | 404.8 | 409.8 | 414.8 | 419.8 | 364.8 | 403.8 | 411.8 | 419.8 | 469.8 | 479.8 | 484.8 | 494.8 | 407.3 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1799.7 | 1807.9 | 1806.7 | 1805.4 | 1804.2 | 1806.2 | 1810.4 | 1808.4 | 1806.4 | 1814.9 | 1812.4 | 1811.2 | 1808.7 | 1795.9 | |
熱膨脹係數(10-7 /℃) | 38.5 | 39.5 | 39.9 | 40.5 | 41.0 | 41.2 | 41.0 | 41.6 | 42.5 | 41.3 | 42.3 | 43.0 | 44.3 | 36.0 | |
密度(g/cm3 ) | 2.583 | 2.621 | 2.654 | 2.689 | 2.719 | 2.624 | 2.632 | 2.685 | 2.736 | 2.693 | 2.748 | 2.785 | 2.844 | 2.649 | |
應變點(℃) | 780 | 783 | 782 | 779 | 780 | 797 | 795 | 790 | 788 | 793 | 790 | 788 | 795 | 774 | |
緩冷點(℃) | 838 | 842 | 841 | 839 | 840 | 856 | 854 | 850 | 849 | 853 | 852 | 851 | 860 | 832 | |
軟化點(℃) | 1066 | 1072 | 1074 | 1076 | 1080 | 1080 | 1080 | 1082 | 1088 | 1085 | 1092 | 1098 | 1118 | 1062 | |
104.5 dPa·s(℃) | 1368 | 1381 | 1388 | 1392 | 1403 | 1387 | 1390 | 1400 | 1410 | 1400 | 1417 | 1426 | 1441 | 1370 | |
104.0 dPa·s(℃) | 1522 | 1539 | 1546 | 1552 | 1565 | 1545 | 1548 | 1560 | 1572 | 1559 | 1580 | 1590 | 1602 | 1527 | |
103.0 dPa·s(℃) | 1621 | 1638 | 1646 | 1654 | 1667 | 1646 | 1649 | 1661 | 1675 | 1660 | 1683 | 1692 | 1704 | 1627 | |
102.5 dPa·s(℃) | 1310 | 1321 | 1328 | 1331 | 1341 | 1327 | 1330 | 1339 | 1348 | 1339 | 1354 | 1363 | 1380 | 1311 | |
楊氏模量(GPa) | 85.6 | 85.0 | 84.3 | 83.3 | 82.5 | 83.3 | 83.9 | 82.7 | 81.4 | 83.0 | 81.2 | 80.6 | 78.1 | 86.5 | |
比楊氏模量(GPa/g·cm-3 ) | 33.2 | 32.4 | 31.8 | 31.0 | 30.4 | 31.7 | 31.9 | 30.8 | 29.8 | 30.8 | 29.5 | 28.9 | 27.5 | 32.6 | |
β-OH(mm-1 ) | 0.03 | 0.13 | 0.14 | 0.14 | 0.11 | 0.11 | 0.15 | 0.04 | 0.14 | 0.03 | 0.07 | 0.15 | 0.09 | 0.13 |
[表7]
No.85 | No.86 | No.87 | No.88 | No.89 | No.90 | No.91 | No.92 | No.93 | No.94 | No.95 | No.96 | No.97 | No.98 | ||
莫耳% | SiO2 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 68.8 |
Al2 O3 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 1.0 | |
MgO | 7.5 | 5.0 | 5.0 | 5.0 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 3.5 | 3.5 | 3.5 | 3.5 | 2.5 | |
CaO | 0.0 | 2.5 | 2.5 | 0.0 | 7.5 | 2.5 | 2.5 | 2.5 | 0.0 | 4.0 | 5.0 | 3.0 | 3.5 | 5.0 | |
SrO | 2.5 | 2.5 | 0.0 | 2.5 | 0.0 | 5.0 | 2.5 | 0.0 | 2.5 | 0.0 | 0.0 | 0.0 | 1.5 | 0.0 | |
BaO | 5.0 | 5.0 | 7.5 | 7.5 | 5.0 | 5.0 | 7.5 | 10.0 | 10.0 | 7.5 | 6.5 | 8.5 | 6.5 | 7.5 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | |
[SiO2 ]+[Al2 O3 ] | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 84.8 | 83.8 | |
[MgO]+[CaO]+[SrO]+[BaO] | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | |
[SrO]+[BaO] | 7.5 | 7.5 | 7.5 | 10.0 | 5.0 | 10.0 | 10.0 | 10.0 | 12.5 | 7.5 | 6.5 | 8.5 | 8.0 | 7.5 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.1 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 7.5 | 5.0 | 5.0 | 5.0 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 3.5 | 3.5 | 3.5 | 3.5 | 3.5 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 439.8 | 427.3 | 432.3 | 464.8 | 382.3 | 447.3 | 452.3 | 457.3 | 489.8 | 424.8 | 409.8 | 439.8 | 429.3 | 403.8 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1799.4 | 1802.4 | 1801.2 | 1804.7 | 1801.9 | 1808.9 | 1807.7 | 1806.4 | 1809.9 | 1803.0 | 1802.1 | 1803.9 | 1804.2 | 1790.1 | |
熱膨脹係數(10-7 /℃) | 36.9 | 39.1 | 38.9 | 40.1 | 39.7 | 41.3 | 42.0 | 42.7 | 43.8 | 40.3 | 39.5 | 41.0 | 40.3 | 41.2 | |
密度(g/cm3 ) | 2.685 | 2.691 | 2.727 | 2.764 | 2.660 | 2.731 | 2.765 | 2.804 | 2.834 | 2.731 | 2.701 | 2.760 | 2.723 | 2.725 | |
應變點(℃) | 778 | 777 | 780 | 783 | 782 | 786 | 788 | 789 | 797 | 780 | 779 | 782 | 780 | 767 | |
緩冷點(℃) | 837 | 837 | 840 | 844 | 841 | 846 | 849 | 852 | 860 | 841 | 839 | 844 | 840 | 827 | |
軟化點(℃) | 1068 | 1072 | 1075 | 1081 | 1072 | 1084 | 1088 | 1094 | 1104 | 1078 | 1074 | 1084 | 1077 | 1065 | |
104.5 dPa·s(℃) | 1379 | 1385 | 1393 | 1401 | 1384 | 1404 | 1414 | 1420 | 1438 | 1395 | 1391 | 1404 | 1396 | 1381 | |
104.0 dPa·s(℃) | 1537 | 1544 | 1551 | 1562 | 1544 | 1563 | 1576 | 1580 | 1602 | 1555 | 1548 | 1566 | 1556 | 1539 | |
103.0 dPa·s(℃) | 1639 | 1644 | 1651 | 1664 | 1646 | 1664 | 1678 | 1680 | 1706 | 1654 | 1649 | 1671 | 1655 | 1640 | |
102.5 dPa·s(℃) | 1319 | 1325 | 1332 | 1340 | 1324 | 1343 | 1351 | 1358 | 1374 | 1334 | 1330 | 1342 | 1335 | 1321 | |
楊氏模量(GPa) | 85.4 | 84.6 | 83.5 | 82.6 | 83.9 | 82.5 | 81.3 | 80.7 | 79.6 | 82.9 | 83.4 | 82.4 | 83.3 | 81.4 | |
比楊氏模量(GPa/g·cm-3 ) | 31.8 | 31.4 | 30.6 | 29.9 | 31.5 | 30.2 | 29.4 | 28.8 | 28.1 | 30.4 | 30.9 | 29.8 | 30.6 | 29.9 | |
β-OH(mm-1 ) | 0.05 | 0.12 | 0.12 | 0.08 | 0.15 | 0.04 | 0.11 | 0.07 | 0.05 | 0.07 | 0.06 | 0.13 | 0.09 | 0.03 |
[表8]
No.99 | No.100 | No.101 | No.102 | No.103 | No.104 | No.105 | No.106 | No.107 | No.108 | No.109 | No.110 | No.111 | No.112 | ||
莫耳% | SiO2 | 70.8 | 70.8 | 69.8 | 69.8 | 68.8 | 68.8 | 70.8 | 70.8 | 69.8 | 69.8 | 68.8 | 68.8 | 71.8 | 71.8 |
Al2 O3 | 15.0 | 14.0 | 16.0 | 14.0 | 16.0 | 15.0 | 15.0 | 14.0 | 16.0 | 14.0 | 16.0 | 15.0 | 14.0 | 13.0 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 4.7 | 5.0 | 4.7 | 5.3 | 5.0 | 5.3 | 3.3 | 3.5 | 3.3 | 3.7 | 3.5 | 3.7 | 4.7 | 5.0 | |
CaO | 2.3 | 2.5 | 2.3 | 2.7 | 2.5 | 2.7 | 4.7 | 5.0 | 4.7 | 5.3 | 5.0 | 5.3 | 2.3 | 2.5 | |
SrO | 2.3 | 2.5 | 2.3 | 2.7 | 2.5 | 2.7 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 2.3 | 2.5 | |
BaO | 4.7 | 5.0 | 4.7 | 5.3 | 5.0 | 5.3 | 6.1 | 6.5 | 6.1 | 6.9 | 6.5 | 6.9 | 4.7 | 5.0 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | |
[SiO2 ]+[Al2 O3 ] | 85.8 | 84.8 | 85.8 | 83.8 | 84.8 | 83.8 | 85.8 | 84.8 | 85.8 | 83.8 | 84.8 | 83.8 | 85.8 | 84.8 | |
[MgO]+[CaO]+[SrO]+[BaO] | 14.0 | 15.0 | 14.0 | 16.0 | 15.0 | 16.0 | 14.0 | 15.0 | 14.0 | 16.0 | 15.0 | 16.0 | 14.0 | 15.0 | |
[SrO]+[BaO] | 7.0 | 7.5 | 7.0 | 8.0 | 7.5 | 8.0 | 6.1 | 6.5 | 6.1 | 6.9 | 6.5 | 6.9 | 7.0 | 7.5 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 5.7 | 4.0 | 6.7 | 3.3 | 6.0 | 4.3 | 4.3 | 2.5 | 5.3 | 1.7 | 4.5 | 2.7 | 4.7 | 3.0 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 418.5 | 414.3 | 431.5 | 423.1 | 440.3 | 436.1 | 402.1 | 396.8 | 415.1 | 404.5 | 422.8 | 417.5 | 405.5 | 401.3 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1806.0 | 1797.1 | 1811.3 | 1793.6 | 1807.7 | 1798.9 | 1805.7 | 1796.8 | 1811.0 | 1793.2 | 1807.4 | 1798.5 | 1800.7 | 1791.8 | |
熱膨脹係數(10-7 /℃) | 37.0 | 38.7 | 36.7 | 40.2 | 38.5 | 40.2 | 38.1 | 39.8 | 37.7 | 41.5 | 39.3 | 41.4 | 37.0 | 38.8 | |
密度(g/cm3 ) | 2.667 | 2.682 | 2.676 | 2.706 | 2.700 | 2.716 | 2.677 | 2.692 | 2.687 | 2.718 | 2.711 | 2.726 | 2.658 | 2.674 | |
應變點(℃) | 781 | 774 | 782 | 769 | 779 | 773 | 784 | 777 | 787 | 770 | 783 | 776 | 780 | 772 | |
緩冷點(℃) | 841 | 834 | 842 | 828 | 838 | 832 | 845 | 837 | 846 | 831 | 843 | 835 | 841 | 833 | |
軟化點(℃) | 1077 | 1072 | 1073 | 1062 | 1068 | 1062 | 1081 | 1075 | 1078 | 1065 | 1071 | 1064 | 1081 | 1073 | |
104.5 dPa·s(℃) | 1400 | 1396 | 1385 | 1381 | 1375 | 1369 | 1403 | 1401 | 1392 | 1386 | 1378 | 1375 | 1412 | 1412 | |
104.0 dPa·s(℃) | 1559 | 1555 | 1540 | 1539 | 1528 | 1525 | 1563 | 1562 | 1548 | 1545 | 1531 | 1532 | 1577 | 1578 | |
103.0 dPa·s(℃) | 1660 | 1657 | 1637 | 1639 | 1626 | 1623 | 1664 | 1667 | 1648 | 1648 | 1627 | 1632 | 1681 | 1678 | |
102.5 dPa·s(℃) | 1338 | 1334 | 1325 | 1320 | 1316 | 1310 | 1341 | 1338 | 1332 | 1324 | 1319 | 1315 | 1348 | 1347 | |
楊氏模量(GPa) | 84.5 | 83.7 | 85.5 | 83.5 | 85.5 | 84.6 | 83.6 | 82.5 | 84.7 | 82.9 | 84.6 | 83.6 | 83.6 | 82.7 | |
比楊氏模量(GPa/g·cm-3 ) | 31.7 | 31.2 | 31.9 | 30.9 | 31.7 | 31.2 | 31.2 | 30.6 | 31.5 | 30.5 | 31.2 | 30.7 | 31.4 | 30.9 | |
β-OH(mm-1 ) | 0.06 | 0.11 | 0.10 | 0.15 | 0.13 | 0.03 | 0.09 | 0.06 | 0.15 | 0.05 | 0.09 | 0.11 | 0.15 | 0.15 |
[表9]
No.113 | No.114 | No.115 | No.116 | No.117 | No.118 | No.119 | No.120 | No.121 | No.122 | No.123 | No.124 | No.125 | No.126 | ||
莫耳% | SiO2 | 70.8 | 69.8 | 71.8 | 71.8 | 70.8 | 71.8 | 70.8 | 69.8 | 68.8 | 67.8 | 71.8 | 71.8 | 70.8 | 70.3 |
Al2 O3 | 13.0 | 13.0 | 14.0 | 13.0 | 13.0 | 14.0 | 14.0 | 14.0 | 15.0 | 16.0 | 13.0 | 12.0 | 13.0 | 14.0 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 5.3 | 5.7 | 3.3 | 3.5 | 3.7 | 7.0 | 7.5 | 8.0 | 8.0 | 8.0 | 7.5 | 8.0 | 8.0 | 7.8 | |
CaO | 2.7 | 2.8 | 4.7 | 5.0 | 5.3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SrO | 2.7 | 2.8 | 0.0 | 0.0 | 0.0 | 7.0 | 7.5 | 8.0 | 8.0 | 8.0 | 7.5 | 8.0 | 8.0 | 7.8 | |
BaO | 5.3 | 5.7 | 6.1 | 6.5 | 6.9 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | |
[SiO2 ]+[Al2 O3 ] | 83.8 | 82.8 | 85.8 | 84.8 | 83.8 | 85.8 | 84.8 | 83.8 | 83.8 | 83.8 | 84.8 | 83.8 | 83.8 | 84.3 | |
[MgO]+[CaO]+[SrO]+[BaO] | 16.0 | 17.0 | 14.0 | 15.0 | 16.0 | 14.0 | 15.0 | 16.0 | 16.0 | 16.0 | 15.0 | 16.0 | 16.0 | 15.5 | |
[SrO]+[BaO] | 8.0 | 8.5 | 6.1 | 6.5 | 6.9 | 7.0 | 7.5 | 8.0 | 8.0 | 8.0 | 7.5 | 8.0 | 8.0 | 7.8 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 2.3 | 1.7 | 3.3 | 1.5 | 0.7 | 7.0 | 6.5 | 6.0 | 7.0 | 8.0 | 5.5 | 4.0 | 5.0 | 6.3 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 410.1 | 419.0 | 389.1 | 383.8 | 391.5 | 407.8 | 416.8 | 425.8 | 438.8 | 451.8 | 403.8 | 399.8 | 412.8 | 421.3 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1788.3 | 1784.7 | 1800.4 | 1791.5 | 1787.9 | 1800.2 | 1796.6 | 1793.0 | 1798.3 | 1803.6 | 1791.3 | 1782.4 | 1787.7 | 1794.8 | |
熱膨脹係數(10-7 /℃) | 40.3 | 41.5 | 37.9 | 39.9 | 41.5 | 34.4 | 35.7 | 36.5 | 36.7 | 37.0 | 35.6 | 37.1 | 37.0 | 36.4 | |
密度(g/cm3 ) | 2.698 | 2.724 | 2.668 | 2.685 | 2.710 | 2.584 | 2.601 | 2.621 | 2.630 | 2.640 | 2.592 | 2.602 | 2.611 | 2.612 | |
應變點(℃) | 766 | 761 | 782 | 772 | 765 | 780 | 777 | 773 | 775 | 777 | 772 | 764 | 767 | 772 | |
緩冷點(℃) | 826 | 820 | 844 | 833 | 826 | 839 | 835 | 830 | 832 | 833 | 830 | 822 | 825 | 829 | |
軟化點(℃) | 1063 | 1052 | 1084 | 1075 | 1064 | 1071 | 1063 | 1054 | 1052 | 1049 | 1065 | 1057 | 1055 | 1058 | |
104.5 dPa·s(℃) | 1392 | 1375 | 1418 | 1414 | 1396 | 1394 | 1377 | 1364 | 1355 | 1343 | 1389 | 1382 | 1372 | 1368 | |
104.0 dPa·s(℃) | 1558 | 1538 | 1585 | 1583 | 1561 | 1556 | 1537 | 1520 | 1509 | 1492 | 1549 | 1544 | 1531 | 1524 | |
103.0 dPa·s(℃) | 1659 | 1641 | 1688 | 1692 | 1668 | 1662 | 1641 | 1622 | 1607 | 1587 | 1652 | 1649 | 1633 | 1623 | |
102.5 dPa·s(℃) | 1328 | 1312 | 1353 | 1348 | 1332 | 1332 | 1316 | 1304 | 1296 | 1286 | 1327 | 1319 | 1311 | 1308 | |
楊氏模量(GPa) | 82.9 | 83.1 | 82.7 | 82.0 | 81.9 | 85.9 | 86.1 | 86.4 | 87.4 | 88.4 | 85.3 | 84.6 | 85.4 | 86.2 | |
比楊氏模量(GPa/g·cm-3 ) | 30.7 | 30.5 | 31.0 | 30.5 | 30.2 | 33.2 | 33.1 | 33.0 | 33.2 | 33.5 | 32.9 | 32.5 | 32.7 | 33.0 | |
β-OH(mm-1 ) | 0.14 | 0.15 | 0.09 | 0.07 | 0.09 | 0.06 | 0.08 | 0.10 | 0.12 | 0.03 | 0.04 | 0.11 | 0.09 | 0.15 |
[表10]
No.127 | No.128 | No.129 | No.130 | No.131 | No.132 | No.133 | No.134 | No.135 | No.136 | No.137 | No.138 | No.139 | No.140 | ||
莫耳% | SiO2 | 69.8 | 71.8 | 70.8 | 69.8 | 71.8 | 70.8 | 69.8 | 67.8 | 65.8 | 69.8 | 69.8 | 67.8 | 65.8 | 69.8 |
Al2 O3 | 14.5 | 13.5 | 14.5 | 14.5 | 13.5 | 14.5 | 15.5 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 7.8 | 4.8 | 4.8 | 5.2 | 3.4 | 3.4 | 3.4 | 7.5 | 7.5 | 6.5 | 5.5 | 0.0 | 0.0 | 0.0 | |
CaO | 0.0 | 2.4 | 2.4 | 2.6 | 4.8 | 4.8 | 4.8 | 0.0 | 0.0 | 0.0 | 0.0 | 10.0 | 10.0 | 9.0 | |
SrO | 7.8 | 2.4 | 2.4 | 2.6 | 0.0 | 0.0 | 0.0 | 7.5 | 7.5 | 6.5 | 5.5 | 0.0 | 0.0 | 0.0 | |
BaO | 0.0 | 4.8 | 4.8 | 5.2 | 6.3 | 6.3 | 6.3 | 0.0 | 0.0 | 0.0 | 0.0 | 5.0 | 5.0 | 4.0 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 2.0 | 4.0 | 2.0 | 4.0 | 2.0 | 4.0 | 2.0 | |
SnO2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | |
[SiO2 ]+[Al2 O3 ] | 84.3 | 85.3 | 85.3 | 84.3 | 85.3 | 85.3 | 85.3 | 82.8 | 80.8 | 84.8 | 84.8 | 82.8 | 80.8 | 84.8 | |
[MgO]+[CaO]+[SrO]+[BaO] | 15.5 | 14.5 | 14.5 | 15.5 | 14.5 | 14.5 | 14.5 | 15.0 | 15.0 | 13.0 | 11.0 | 15.0 | 15.0 | 13.0 | |
[SrO]+[BaO] | 7.8 | 7.3 | 7.3 | 7.8 | 6.3 | 6.3 | 6.3 | 7.5 | 7.5 | 6.5 | 5.5 | 5.0 | 5.0 | 4.0 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 6.8 | 3.8 | 4.8 | 4.2 | 2.4 | 3.4 | 4.4 | 7.5 | 7.5 | 8.5 | 9.5 | 0.0 | 0.0 | 2.0 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 427.8 | 403.4 | 416.4 | 425.2 | 386.5 | 399.5 | 412.5 | 427.8 | 425.8 | 409.8 | 389.8 | 367.8 | 365.8 | 352.8 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1797.5 | 1796.3 | 1801.6 | 1798.0 | 1795.9 | 1801.2 | 1806.5 | 1780.7 | 1759.5 | 1787.9 | 1773.9 | 1783.7 | 1762.5 | 1790.2 | |
熱膨脹係數(10-7 /℃) | 36.3 | 38.1 | 37.7 | 39.0 | 38.9 | 38.9 | 38.5 | 36.5 | 37.5 | 33.6 | 31.9 | 42.2 | 43.0 | 38.7 | |
密度(g/cm3 ) | 2.617 | 2.665 | 2.675 | 2.699 | 2.676 | 2.686 | 2.694 | 2.662 | 2.710 | 2.623 | 2.631 | 2.715 | 2.763 | 2.659 | |
應變點(℃) | 773 | 774 | 776 | 772 | 776 | 779 | 780 | 757 | 742 | 762 | 751 | 763 | 742 | 770 | |
緩冷點(℃) | 831 | 835 | 836 | 832 | 837 | 839 | 841 | 812 | 796 | 820 | 808 | 820 | 796 | 830 | |
軟化點(℃) | 1056 | 1077 | 1075 | 1065 | 1080 | 1078 | 1075 | 1031 | 1008 | 1046 | 1035 | 1045 | 1015 | 1061 | |
104.5 dPa·s(℃) | 1364 | 1408 | 1399 | 1383 | 1412 | 1401 | 1392 | 1331 | 1295 | 1354 | 1346 | 1349 | 1311 | 1373 | |
104.0 dPa·s(℃) | 1518 | 1570 | 1559 | 1543 | 1576 | 1561 | 1549 | 1481 | 1440 | 1509 | 1500 | 1501 | 1459 | 1529 | |
103.0 dPa·s(℃) | 1616 | 1672 | 1661 | 1643 | 1680 | 1662 | 1649 | 1577 | 1536 | 1607 | 1599 | 1600 | 1555 | 1629 | |
102.5 dPa·s(℃) | 1305 | 1345 | 1337 | 1322 | 1348 | 1339 | 1331 | 1273 | 1240 | 1295 | 1286 | 1291 | 1254 | 1313 | |
楊氏模量(GPa) | 86.4 | 83.1 | 83.9 | 84.0 | 82.1 | 83.0 | 83.7 | 88.1 | 88.9 | 87.6 | 88.2 | 83.8 | 85.3 | 84.1 | |
比楊氏模量(GPa/g·cm-3 ) | 33.0 | 31.2 | 31.4 | 31.1 | 30.7 | 30.9 | 31.1 | 33.1 | 32.8 | 33.4 | 33.5 | 30.9 | 30.9 | 31.6 | |
β-OH(mm-1 ) | 0.09 | 0.07 | 0.12 | 0.03 | 0.14 | 0.14 | 0.11 | 0.13 | 0.06 | 0.07 | 0.08 | 0.10 | 0.09 | 0.07 |
[表11]
No.141 | No.142 | No.143 | No.144 | No.145 | No.146 | No.147 | No.148 | No.149 | No.150 | No.151 | No.152 | No.153 | No.154 | ||
莫耳% | SiO2 | 69.8 | 69.8 | 70.8 | 70.8 | 69.8 | 69.8 | 68.8 | 68.8 | 68.9 | 68.9 | 68.9 | 68.9 | 70.5 | 69.5 |
Al2 O3 | 15.0 | 11.4 | 11.4 | 10.4 | 12.4 | 10.4 | 12.4 | 11.4 | 13.6 | 13.6 | 14.1 | 14.6 | 13.1 | 13.1 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 3.4 | 2.4 | 3.4 | 2.4 | 0.3 | 0.3 | |
MgO | 0.0 | 9.3 | 8.3 | 9.3 | 8.3 | 10.3 | 9.3 | 10.3 | 1.7 | 1.7 | 1.7 | 1.7 | 6.1 | 7.1 | |
CaO | 8.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 9.4 | 10.4 | 8.4 | 8.4 | 3.8 | 3.8 | |
SrO | 0.0 | 9.3 | 9.3 | 9.3 | 9.3 | 9.3 | 9.3 | 9.3 | 1.6 | 1.6 | 1.6 | 1.6 | 2.1 | 2.1 | |
BaO | 3.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 1.2 | 1.2 | 1.7 | 2.2 | 3.9 | 3.9 | |
ZnO | 4.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | |
[SiO2 ]+[Al2 O3 ] | 84.8 | 81.2 | 82.2 | 81.2 | 82.2 | 80.2 | 81.2 | 80.2 | 82.5 | 82.5 | 83.0 | 83.5 | 83.6 | 82.6 | |
[MgO]+[CaO]+[SrO]+[BaO] | 11.0 | 18.6 | 17.6 | 18.6 | 17.6 | 19.6 | 18.6 | 19.6 | 13.9 | 14.9 | 13.4 | 13.9 | 15.9 | 16.9 | |
[SrO]+[BaO] | 3.0 | 9.3 | 9.3 | 9.3 | 9.3 | 9.3 | 9.3 | 9.3 | 2.8 | 2.8 | 3.3 | 3.8 | 6.0 | 6.0 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 1.2 | 0.9 | 1.0 | 0.6 | 0.1 | 0.1 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 4.0 | 2.1 | 2.1 | 1.1 | 3.1 | 1.1 | 3.1 | 2.1 | 4.8 | 2.8 | 5.8 | 4.8 | 3.6 | 3.6 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 335.8 | 415.4 | 410.4 | 402.4 | 423.4 | 407.4 | 428.4 | 420.4 | 269.5 | 285.5 | 283.5 | 313.5 | 381.6 | 386.6 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1775.5 | 1769.9 | 1774.8 | 1764.6 | 1780.1 | 1759.7 | 1775.2 | 1765.0 | 1750.4 | 1760.8 | 1755.4 | 1770.7 | 1781.9 | 1777.0 | |
熱膨脹係數(10-7 /℃) | 35.7 | 40.5 | 39.9 | 40.9 | 39.9 | 42.5 | 40.2 | 41.2 | 37.4 | 38.9 | 37.0 | 37.5 | 38.5 | 39.1 | |
密度(g/cm3 ) | 2.653 | 2.649 | 2.638 | 2.644 | 2.670 | 2.671 | 2.659 | 2.662 | 2.528 | 2.546 | 2.543 | 2.572 | 2.644 | 2.655 | |
應變點(℃) | 754 | 754 | 758 | 750 | 761 | 743 | 757 | 749 | 736 | 745 | 740 | 752 | 761 | 755 | |
緩冷點(℃) | 812 | 809 | 814 | 805 | 818 | 797 | 812 | 804 | 795 | 803 | 799 | 812 | 819 | 812 | |
軟化點(℃) | 1043 | 1033 | 1042 | 1031 | 1043 | 1015 | 1032 | 1023 | 1028 | 1032 | 1033 | 1043 | 1054 | 1043 | |
104.5 dPa·s(℃) | 1355 | 1343 | 1361 | 1348 | 1356 | 1318 | 1338 | 1326 | 1339 | 1341 | 1346 | 1354 | 1377 | 1356 | |
104.0 dPa·s(℃) | 1512 | 1503 | 1524 | 1510 | 1516 | 1476 | 1494 | 1483 | 1499 | 1498 | 1504 | 1510 | 1540 | 1515 | |
103.0 dPa·s(℃) | 1613 | 1607 | 1627 | 1616 | 1619 | 1580 | 1594 | 1585 | 1602 | 1598 | 1606 | 1610 | 1643 | 1617 | |
102.5 dPa·s(℃) | 1295 | 1283 | 1299 | 1286 | 1295 | 1259 | 1278 | 1267 | 1279 | 1281 | 1286 | 1294 | 1315 | 1296 | |
楊氏模量(GPa) | 85.6 | 84.7 | 84.0 | 83.8 | 85.0 | 84.8 | 85.6 | 85.5 | 85.9 | 81.9 | 80.7 | 81.9 | 83.9 | 84.6 | |
比楊氏模量(GPa/g·cm-3 ) | 32.3 | 32.0 | 31.8 | 31.7 | 31.8 | 31.8 | 32.2 | 32.1 | 34.0 | 32.2 | 31.7 | 31.9 | 31.7 | 31.9 | |
β-OH(mm-1 ) | 0.05 | 0.08 | 0.04 | 0.08 | 0.14 | 0.05 | 0.11 | 0.09 | 0.14 | 0.04 | 0.05 | 0.09 | 0.11 | 0.13 |
[表12]
No.155 | No.156 | No.157 | No.158 | No.159 | No.160 | No.161 | No.162 | No.163 | No.164 | No.165 | No.166 | No.167 | No.168 | ||
莫耳% | SiO2 | 68.5 | 69.5 | 68.5 | 69.8 | 68.8 | 69.8 | 69.8 | 69.8 | 69.8 | 69.8 | 68.8 | 68.8 | 68.8 | 68.8 |
Al2 O3 | 13.1 | 14.1 | 14.1 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | |
B2 O3 | 0.3 | 0.3 | 0.3 | 1.0 | 2.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 2.0 | 2.0 | 2.0 | 2.0 | |
MgO | 8.1 | 6.1 | 7.1 | 7.5 | 7.5 | 7.5 | 7.5 | 7.5 | 7.5 | 7.5 | 7.5 | 7.5 | 7.5 | 7.5 | |
CaO | 3.8 | 3.8 | 3.8 | 0.0 | 0.0 | 1.0 | 0.0 | 2.0 | 1.0 | 0.0 | 1.0 | 0.0 | 2.0 | 1.0 | |
SrO | 2.1 | 2.1 | 2.1 | 7.5 | 7.5 | 6.5 | 6.5 | 5.5 | 5.5 | 5.5 | 6.5 | 6.5 | 5.5 | 5.5 | |
BaO | 3.9 | 3.9 | 3.9 | 0.0 | 0.0 | 0.0 | 1.0 | 0.0 | 1.0 | 2.0 | 0.0 | 1.0 | 0.0 | 1.0 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | |
[SiO2 ]+[Al2 O3 ] | 81.6 | 83.6 | 82.6 | 83.8 | 82.8 | 83.8 | 83.8 | 83.8 | 83.8 | 83.8 | 82.8 | 82.8 | 82.8 | 82.8 | |
[MgO]+[CaO]+[SrO]+[BaO] | 17.9 | 15.9 | 16.9 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | |
[SrO]+[BaO] | 6.0 | 6.0 | 6.0 | 7.5 | 7.5 | 6.5 | 7.5 | 5.5 | 6.5 | 7.5 | 6.5 | 7.5 | 5.5 | 6.5 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.1 | 0.1 | 0.1 | 0.1 | 0.3 | 0.2 | 0.1 | 0.2 | 0.2 | 0.1 | 0.3 | 0.3 | 0.4 | 0.3 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 3.6 | 4.6 | 4.6 | 7.5 | 8.5 | 7.5 | 7.5 | 7.5 | 7.5 | 7.5 | 8.5 | 8.5 | 8.5 | 8.5 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 391.6 | 394.6 | 399.6 | 400.8 | 384.8 | 387.8 | 402.8 | 374.8 | 389.8 | 404.8 | 371.8 | 386.8 | 358.8 | 373.8 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1772.1 | 1787.2 | 1782.3 | 1782.5 | 1768.4 | 1781.1 | 1782.0 | 1779.7 | 1780.6 | 1781.5 | 1767.0 | 1767.9 | 1765.6 | 1766.5 | |
熱膨脹係數(10-7 /℃) | 39.6 | 37.9 | 38.8 | 35.4 | 35.8 | 35.3 | 35.3 | 35.1 | 35.5 | 36.4 | 35.7 | 36.2 | 35.3 | 35.6 | |
密度(g/cm3 ) | 2.667 | 2.653 | 2.664 | 2.595 | 2.590 | 2.581 | 2.609 | 2.566 | 2.594 | 2.625 | 2.575 | 2.602 | 2.561 | 2.589 | |
應變點(℃) | 750 | 765 | 759 | 762 | 750 | 760 | 761 | 760 | 760 | 761 | 748 | 748 | 746 | 746 | |
緩冷點(℃) | 807 | 822 | 816 | 820 | 807 | 817 | 819 | 816 | 817 | 819 | 805 | 806 | 803 | 804 | |
軟化點(℃) | 1033 | 1052 | 1042 | 1047 | 1032 | 1045 | 1048 | 1043 | 1047 | 1050 | 1031 | 1033 | 1029 | 1032 | |
104.5 dPa·s(℃) | 1337 | 1364 | 1347 | 1365 | 1341 | 1357 | 1364 | 1355 | 1361 | 1370 | 1343 | 1345 | 1339 | 1340 | |
104.0 dPa·s(℃) | 1492 | 1522 | 1503 | 1527 | 1496 | 1512 | 1523 | 1513 | 1519 | 1528 | 1497 | 1501 | 1494 | 1497 | |
103.0 dPa·s(℃) | 1590 | 1623 | 1602 | 1629 | 1595 | 1610 | 1622 | 1612 | 1617 | 1627 | 1596 | 1602 | 1592 | 1596 | |
102.5 dPa·s(℃) | 1278 | 1304 | 1288 | 1303 | 1281 | 1297 | 1303 | 1295 | 1301 | 1308 | 1283 | 1285 | 1279 | 1281 | |
楊氏模量(GPa) | 85.4 | 84.9 | 85.6 | 85.0 | 84.0 | 85.5 | 84.7 | 85.9 | 85.2 | 84.4 | 84.5 | 83.8 | 84.9 | 84.1 | |
比楊氏模量(GPa/g·cm-3 ) | 32.0 | 32.0 | 32.1 | 32.7 | 32.4 | 33.1 | 32.5 | 33.5 | 32.8 | 32.1 | 32.8 | 32.2 | 33.1 | 32.5 | |
β-OH(mm-1 ) | 0.12 | 0.06 | 0.07 | 0.09 | 0.03 | 0.11 | 0.13 | 0.03 | 0.08 | 0.06 | 0.09 | 0.15 | 0.08 | 0.12 |
[表13]
No.169 | No.170 | No.171 | No.172 | No.173 | No.174 | No.175 | No.176 | No.177 | No.178 | No.179 | No.180 | No.181 | No.182 | ||
莫耳% | SiO2 | 68.8 | 70.2 | 69.8 | 69.8 | 69.8 | 68.9 | 68.9 | 68.9 | 68.9 | 70.0 | 69.5 | 70.2 | 69.7 | 68.9 |
Al2 O3 | 14.0 | 12.9 | 12.9 | 12.9 | 12.9 | 13.6 | 13.6 | 13.6 | 13.6 | 13.1 | 13.1 | 12.9 | 12.9 | 13.6 | |
B2 O3 | 2.0 | 0.3 | 0.3 | 0.3 | 0.3 | 3.4 | 2.4 | 3.4 | 2.4 | 0.3 | 0.3 | 0.0 | 0.0 | 3.9 | |
MgO | 7.5 | 6.3 | 6.5 | 7.0 | 6.5 | 2.2 | 2.7 | 2.7 | 3.2 | 6.1 | 6.1 | 6.4 | 6.4 | 1.7 | |
CaO | 0.0 | 3.9 | 4.0 | 4.0 | 4.5 | 8.4 | 8.4 | 7.4 | 7.4 | 3.8 | 3.8 | 3.8 | 3.8 | 8.4 | |
SrO | 5.5 | 2.2 | 2.2 | 1.7 | 1.7 | 1.6 | 1.6 | 1.6 | 1.6 | 2.1 | 2.1 | 2.1 | 2.1 | 1.6 | |
BaO | 2.0 | 4.0 | 4.1 | 4.1 | 4.1 | 1.7 | 2.2 | 2.2 | 2.7 | 3.9 | 3.9 | 3.9 | 3.9 | 1.2 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.5 | 1.0 | 0.5 | 1.0 | 0.5 | |
SnO2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | |
[SiO2 ]+[Al2 O3 ] | 82.8 | 83.1 | 82.7 | 82.7 | 82.7 | 82.5 | 82.5 | 82.5 | 82.5 | 83.1 | 82.6 | 83.1 | 82.6 | 82.5 | |
[MgO]+[CaO]+[SrO]+[BaO] | 15.0 | 16.4 | 16.8 | 16.8 | 16.8 | 13.9 | 14.9 | 13.9 | 14.9 | 15.9 | 15.9 | 16.2 | 16.2 | 12.9 | |
[SrO]+[BaO] | 7.5 | 6.2 | 6.3 | 5.8 | 5.8 | 3.3 | 3.8 | 3.8 | 4.3 | 6.0 | 6.0 | 6.0 | 6.0 | 2.8 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.3 | 0.0 | 0.0 | 0.1 | 0.1 | 1.0 | 0.6 | 0.9 | 0.6 | 0.1 | 0.1 | 0.0 | 0.0 | 1.4 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 8.5 | 3.1 | 2.9 | 3.4 | 2.9 | 5.3 | 3.8 | 5.8 | 4.3 | 3.6 | 3.6 | 3.1 | 3.1 | 6.3 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 388.8 | 382.8 | 385.3 | 381.3 | 378.8 | 279.5 | 305.5 | 289.5 | 315.5 | 381.1 | 380.6 | 384.8 | 384.3 | 261.0 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1767.4 | 1779.0 | 1777.4 | 1776.1 | 1776.7 | 1750.3 | 1760.5 | 1750.1 | 1760.4 | 1776.6 | 1771.3 | 1778.3 | 1773.0 | 1741.8 | |
熱膨脹係數(10-7 /℃) | 36.4 | 39.2 | 39.9 | 39.3 | 39.7 | 37.4 | 38.6 | 37.4 | 38.7 | 39.0 | 38.9 | 39.2 | 39.2 | 36.1 | |
密度(g/cm3 ) | 2.618 | 2.654 | 2.661 | 2.653 | 2.653 | 2.540 | 2.571 | 2.552 | 2.586 | 2.657 | 2.668 | 2.659 | 2.672 | 2.523 | |
應變點(℃) | 748 | 756 | 753 | 754 | 754 | 734 | 741 | 733 | 740 | 754 | 750 | 757 | 752 | 726 | |
緩冷點(℃) | 806 | 814 | 812 | 812 | 812 | 793 | 800 | 792 | 799 | 813 | 807 | 814 | 809 | 785 | |
軟化點(℃) | 1035 | 1048 | 1043 | 1043 | 1043 | 1027 | 1031 | 1027 | 1032 | 1045 | 1038 | 1046 | 1039 | 1022 | |
104.5 dPa·s(℃) | 1347 | 1367 | 1361 | 1359 | 1358 | 1342 | 1343 | 1344 | 1344 | 1364 | 1354 | 1366 | 1356 | 1342 | |
104.0 dPa·s(℃) | 1503 | 1529 | 1524 | 1519 | 1518 | 1499 | 1503 | 1503 | 1504 | 1525 | 1512 | 1525 | 1513 | 1502 | |
103.0 dPa·s(℃) | 1602 | 1633 | 1629 | 1622 | 1620 | 1599 | 1604 | 1605 | 1606 | 1629 | 1613 | 1627 | 1616 | 1605 | |
102.5 dPa·s(℃) | 1287 | 1305 | 1299 | 1298 | 1297 | 1282 | 1283 | 1283 | 1284 | 1302 | 1293 | 1304 | 1295 | 1281 | |
楊氏模量(GPa) | 未測定 | 84.1 | 84.1 | 84.4 | 84.1 | 80.7 | 81.9 | 80.8 | 81.8 | 84.2 | 84.6 | 84.6 | 84.9 | 80.3 | |
比楊氏模量(GPa/g·cm-3 ) | 未測定 | 31.7 | 31.6 | 31.8 | 31.7 | 31.8 | 31.9 | 31.7 | 31.6 | 31.7 | 31.7 | 31.8 | 31.8 | 31.8 | |
β-OH(mm-1 ) | 0.12 | 0.10 | 0.10 | 0.06 | 0.08 | 0.14 | 0.07 | 0.09 | 0.11 | 0.07 | 0.14 | 0.03 | 0.08 | 0.05 |
[表14]
No.183 | No.184 | No.185 | No.186 | No.187 | No.188 | No.189 | No.190 | No.191 | No.192 | No.193 | No.194 | No.195 | No.196 | ||
莫耳% | SiO2 | 68.9 | 70.0 | 69.5 | 69.8 | 69.8 | 69.8 | 69.8 | 69.4 | 69.9 | 68.9 | 68.9 | 68.9 | 68.9 | 70.1 |
Al2 O3 | 13.6 | 13.4 | 13.7 | 13.1 | 13.1 | 13.1 | 13.1 | 13.6 | 13.6 | 14.0 | 14.0 | 14.0 | 14.0 | 12.8 | |
B2 O3 | 3.4 | 0.5 | 0.7 | 1.0 | 1.0 | 1.0 | 1.0 | 3.4 | 3.4 | 3.0 | 3.0 | 3.0 | 3.0 | 0.5 | |
MgO | 1.7 | 6.1 | 6.1 | 6.1 | 6.1 | 6.1 | 6.6 | 2.7 | 2.7 | 3.2 | 3.7 | 2.7 | 3.2 | 6.1 | |
CaO | 8.4 | 3.8 | 3.8 | 4.3 | 4.3 | 4.8 | 4.3 | 6.9 | 6.4 | 6.9 | 6.4 | 6.9 | 6.4 | 4.8 | |
SrO | 1.6 | 2.1 | 2.1 | 2.1 | 1.6 | 1.6 | 1.6 | 1.6 | 1.6 | 1.6 | 1.6 | 2.1 | 2.1 | 1.6 | |
BaO | 1.2 | 3.9 | 3.9 | 3.4 | 3.9 | 3.4 | 3.4 | 2.2 | 2.2 | 2.2 | 2.2 | 2.2 | 2.2 | 3.9 | |
ZnO | 1.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | |
[SiO2 ]+[Al2 O3 ] | 82.5 | 83.4 | 83.2 | 82.9 | 82.9 | 82.9 | 82.9 | 83.0 | 83.5 | 82.9 | 82.9 | 82.9 | 82.9 | 82.9 | |
[MgO]+[CaO]+[SrO]+[BaO] | 12.9 | 15.9 | 15.9 | 15.9 | 15.9 | 15.9 | 15.9 | 13.4 | 12.9 | 13.9 | 13.9 | 13.9 | 13.9 | 16.4 | |
[SrO]+[BaO] | 2.8 | 6.0 | 6.0 | 5.5 | 5.5 | 5.0 | 5.0 | 3.8 | 3.8 | 3.8 | 3.8 | 4.3 | 4.3 | 5.5 | |
[B2 O3 ]/([SrO]+[BaO]) | 1.2 | 0.1 | 0.1 | 0.2 | 0.2 | 0.2 | 0.2 | 0.9 | 0.9 | 0.8 | 0.8 | 0.7 | 0.7 | 0.1 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 5.8 | 4.1 | 4.6 | 4.3 | 4.3 | 4.3 | 4.8 | 6.3 | 6.8 | 6.3 | 6.8 | 5.8 | 6.3 | 3.0 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 268.5 | 382.3 | 383.0 | 362.9 | 363.9 | 356.4 | 358.9 | 289.5 | 289.5 | 303.6 | 306.1 | 307.6 | 310.1 | 368.0 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1743.5 | 1780.7 | 1779.5 | 1771.6 | 1771.4 | 1770.9 | 1770.3 | 1752.0 | 1753.8 | 1757.3 | 1756.7 | 1758.6 | 1758.0 | 1775.0 | |
熱膨脹係數(10-7 /℃) | 36.3 | 38.4 | 38.5 | 38.1 | 38.3 | 38.0 | 37.6 | 36.2 | 35.4 | 36.7 | 36.2 | 37.2 | 37.0 | 39.1 | |
密度(g/cm3 ) | 2.539 | 2.644 | 2.648 | 2.624 | 2.632 | 2.617 | 2.616 | 2.549 | 2.542 | 2.558 | 2.559 | 2.568 | 2.568 | 2.640 | |
應變點(℃) | 725 | 758 | 756 | 750 | 750 | 750 | 750 | 734 | 737 | 738 | 737 | 740 | 738 | 753 | |
緩冷點(℃) | 784 | 816 | 814 | 808 | 809 | 808 | 808 | 794 | 797 | 797 | 796 | 799 | 797 | 810 | |
軟化點(℃) | 1020 | 1049 | 1046 | 1041 | 1042 | 1040 | 1040 | 1031 | 1035 | 1031 | 1029 | 1033 | 1031 | 1043 | |
104.5 dPa·s(℃) | 1340 | 1368 | 1363 | 1358 | 1361 | 1360 | 1355 | 1350 | 未測定 | 未測定 | 1340 | 1346 | 1341 | 1363 | |
104.0 dPa·s(℃) | 1498 | 1528 | 1520 | 1517 | 1523 | 1522 | 1513 | 1508 | 未測定 | 未測定 | 1499 | 1506 | 1498 | 1526 | |
103.0 dPa·s(℃) | 1599 | 1630 | 1619 | 1622 | 1628 | 1626 | 1614 | 1612 | 未測定 | 未測定 | 1599 | 1605 | 1600 | 1630 | |
102.5 dPa·s(℃) | 1279 | 1307 | 1302 | 1297 | 1299 | 1298 | 1294 | 1289 | 未測定 | 未測定 | 1280 | 1280 | 1282 | 1301 | |
楊氏模量(GPa) | 81.2 | 84.1 | 84.4 | 83.6 | 83.3 | 83.8 | 83.9 | 80.4 | 80.2 | 81.6 | 82.0 | 81.3 | 81.4 | 84.0 | |
比楊氏模量(GPa/g·cm-3 ) | 32.0 | 31.8 | 31.9 | 31.9 | 31.7 | 32.0 | 32.1 | 31.5 | 31.6 | 31.9 | 32.0 | 31.7 | 31.7 | 31.8 | |
β-OH(mm-1 ) | 0.13 | 0.06 | 0.05 | 0.12 | 0.07 | 0.11 | 0.12 | 0.10 | 0.13 | 0.04 | 0.03 | 0.06 | 0.06 | 0.10 |
[表15]
No.197 | No.198 | No.199 | No.200 | No.201 | No.202 | No.203 | No.204 | No.205 | No.206 | No.207 | No.208 | No.209 | No.210 | ||
莫耳% | SiO2 | 70.1 | 70.1 | 70.1 | 70.1 | 69.6 | 70.1 | 70.1 | 70.1 | 70.1 | 70.1 | 70.1 | 70.1 | 69.3 | 69.7 |
Al2 O3 | 12.8 | 12.8 | 12.8 | 12.8 | 12.8 | 12.8 | 12.8 | 12.8 | 12.8 | 12.8 | 12.8 | 12.8 | 13.6 | 13.6 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.5 | 0.7 | 0.4 | 1.0 | 0.7 | 0.7 | 0.7 | 0.6 | 3.0 | 2.6 | |
MgO | 6.1 | 5.6 | 5.1 | 4.6 | 5.1 | 5.9 | 5.7 | 5.6 | 5.7 | 5.3 | 5.7 | 5.9 | 3.2 | 3.7 | |
CaO | 5.3 | 6.3 | 7.3 | 8.3 | 7.3 | 4.6 | 4.6 | 5.5 | 5.6 | 6.0 | 5.7 | 5.3 | 6.9 | 6.4 | |
SrO | 1.6 | 1.1 | 0.6 | 0.0 | 0.6 | 1.3 | 1.3 | 0.9 | 1.0 | 0.4 | 1.2 | 1.4 | 1.1 | 0.6 | |
BaO | 3.9 | 3.9 | 3.9 | 4.0 | 3.9 | 3.9 | 3.9 | 3.9 | 3.9 | 4.5 | 3.6 | 3.7 | 2.7 | 3.2 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.5 | 1.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | |
[SiO2 ]+[Al2 O3 ] | 82.9 | 82.9 | 82.9 | 82.9 | 82.4 | 82.9 | 82.9 | 82.9 | 82.9 | 82.9 | 82.9 | 82.9 | 82.9 | 83.3 | |
[MgO]+[CaO]+[SrO]+[BaO] | 16.9 | 16.9 | 16.9 | 16.9 | 16.9 | 15.7 | 15.5 | 15.9 | 16.2 | 16.2 | 16.2 | 16.3 | 13.9 | 13.9 | |
[SrO]+[BaO] | 5.5 | 5.0 | 4.5 | 4.0 | 4.5 | 5.2 | 5.2 | 4.8 | 4.9 | 4.9 | 4.8 | 5.1 | 3.8 | 3.8 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | 0.0 | 0.0 | 0.1 | 0.1 | 0.1 | 0.2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.8 | 0.7 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 2.0 | 1.5 | 1.0 | 0.5 | 1.5 | 3.7 | 3.4 | 3.5 | 3.0 | 2.6 | 3.0 | 3.0 | 5.9 | 6.0 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 376.0 | 367.0 | 358.0 | 349.2 | 350.0 | 359.4 | 362.7 | 348.4 | 355.0 | 354.2 | 353.1 | 359.8 | 299.4 | 309.3 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1780.2 | 1780.1 | 1780.0 | 1779.8 | 1772.9 | 1769.3 | 1769.2 | 1769.4 | 1772.5 | 1772.7 | 1772.6 | 1773.7 | 1754.9 | 1759.7 | |
熱膨脹係數(10-7 /℃) | 39.5 | 39.9 | 40.2 | 40.4 | 40.1 | 38.0 | 38.2 | 38.4 | 39.2 | 39.2 | 39.1 | 38.8 | 37.3 | 36.9 | |
密度(g/cm3 ) | 2.649 | 2.643 | 2.636 | 2.632 | 2.634 | 2.637 | 2.649 | 2.618 | 2.627 | 2.638 | 2.621 | 2.628 | 2.561 | 2.572 | |
應變點(℃) | 758 | 758 | 758 | 759 | 749 | 748 | 746 | 745 | 750 | 750 | 750 | 750 | 736 | 740 | |
緩冷點(℃) | 816 | 815 | 815 | 816 | 806 | 806 | 804 | 804 | 808 | 809 | 808 | 808 | 794 | 799 | |
軟化點(℃) | 1045 | 1045 | 1044 | 1045 | 1036 | 1040 | 1040 | 1039 | 1041 | 1042 | 1041 | 1042 | 1030 | 1035 | |
104.5 dPa·s(℃) | 1365 | 1362 | 1361 | 1362 | 1355 | 1363 | 1356 | 1358 | 1357 | 1360 | 1357 | 1359 | 1358 | 1358 | |
104.0 dPa·s(℃) | 1526 | 1522 | 1521 | 1523 | 1515 | 1525 | 1516 | 1518 | 1519 | 1521 | 1520 | 1518 | 1518 | 1524 | |
103.0 dPa·s(℃) | 1629 | 1625 | 1623 | 1625 | 1618 | 1628 | 1618 | 1621 | 1622 | 1623 | 1625 | 1620 | 1625 | 1631 | |
102.5 dPa·s(℃) | 1303 | 1301 | 1300 | 1301 | 1293 | 1301 | 1295 | 1297 | 1296 | 1299 | 1296 | 1298 | 1295 | 1295 | |
楊氏模量(GPa) | 84.5 | 84.6 | 84.4 | 84.2 | 84.0 | 84.0 | 84.4 | 83.3 | 83.4 | 83.4 | 83.6 | 84.0 | 80.9 | 81.5 | |
比楊氏模量(GPa/g·cm-3 ) | 31.9 | 32.0 | 32.0 | 32.0 | 31.9 | 31.9 | 31.9 | 31.8 | 31.7 | 31.6 | 31.9 | 31.9 | 31.6 | 31.7 | |
β-OH(mm-1 ) | 0.12 | 0.07 | 0.03 | 0.11 | 0.12 | 0.13 | 0.10 | 0.08 | 0.07 | 0.06 | 0.09 | 0.12 | 0.14 | 0.03 |
[表16]
No.211 | No.212 | No.213 | No.214 | No.215 | No.216 | No.217 | No.218 | No.219 | No.220 | No.221 | No.222 | No.223 | No.224 | ||
莫耳% | SiO2 | 70.1 | 69.7 | 70.3 | 70.3 | 63.7 | 72.9 | 63.1 | 70.3 | 70.5 | 70.4 | 72.9 | 70.4 | 70.5 | 70.3 |
Al2 O3 | 13.6 | 13.6 | 12.8 | 12.8 | 18.0 | 11.3 | 18.0 | 12.8 | 12.5 | 12.5 | 11.6 | 12.6 | 12.4 | 12.6 | |
B2 O3 | 2.2 | 2.1 | 0.7 | 0.7 | 1.1 | 0.3 | 1.7 | 0.7 | 0.7 | 1.0 | 0.3 | 0.7 | 0.7 | 0.8 | |
MgO | 4.2 | 3.7 | 5.3 | 5.3 | 6.0 | 3.1 | 6.0 | 5.1 | 5.7 | 3.3 | 2.8 | 5.1 | 5.1 | 5.7 | |
CaO | 5.9 | 6.4 | 6.0 | 6.0 | 9.0 | 7.2 | 9.0 | 6.2 | 4.4 | 7.6 | 7.2 | 6.2 | 6.2 | 4.4 | |
SrO | 0.1 | 1.1 | 0.4 | 0.2 | 0.0 | 0.5 | 0.0 | 0.4 | 2.1 | 0.4 | 0.5 | 0.4 | 0.4 | 2.1 | |
BaO | 3.7 | 3.2 | 4.3 | 4.5 | 2.0 | 4.5 | 2.0 | 4.3 | 3.9 | 4.6 | 4.5 | 4.4 | 4.5 | 3.9 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | |
[SiO2 ]+[Al2 O3 ] | 83.7 | 83.3 | 83.1 | 83.1 | 81.7 | 84.2 | 81.1 | 83.1 | 83.0 | 82.9 | 84.5 | 83.0 | 82.9 | 82.9 | |
[MgO]+[CaO]+[SrO]+[BaO] | 13.9 | 14.4 | 16.0 | 16.0 | 17.0 | 15.3 | 17.0 | 16.0 | 16.1 | 15.9 | 15.0 | 16.1 | 16.2 | 16.1 | |
[SrO]+[BaO] | 3.8 | 4.3 | 4.7 | 4.7 | 2.0 | 5.0 | 2.0 | 4.7 | 6.0 | 5.0 | 5.0 | 4.8 | 4.9 | 6.0 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.6 | 0.5 | 0.1 | 0.1 | 0.6 | 0.1 | 0.9 | 0.1 | 0.1 | 0.2 | 0.1 | 0.1 | 0.1 | 0.1 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 6.1 | 5.0 | 2.8 | 2.8 | 8.1 | -0.6 | 8.7 | 2.6 | 2.8 | 0.9 | -0.3 | 2.3 | 2.0 | 3.0 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 319.2 | 323.8 | 351.2 | 351.6 | 376.2 | 331.4 | 366.6 | 350.2 | 365.4 | 337.0 | 333.8 | 349.1 | 348.0 | 365.1 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1764.5 | 1765.6 | 1773.3 | 1773.2 | 1788.0 | 1776.5 | 1779.6 | 1773.5 | 1772.9 | 1770.5 | 1779.6 | 1772.2 | 1770.8 | 1772.0 | |
熱膨脹係數(10-7 /℃) | 36.6 | 37.7 | 39.0 | 39.1 | 未測定 | 未測定 | 未測定 | 39.5 | 39.3 | 40.6 | 未測定 | 39.1 | 39.9 | 39.2 | |
密度(g/cm3 ) | 2.580 | 2.589 | 2.629 | 2.631 | 未測定 | 未測定 | 未測定 | 2.629 | 2.639 | 2.637 | 未測定 | 2.632 | 2.635 | 2.640 | |
應變點(℃) | 744 | 744 | 750 | 751 | 761 | 753 | 752 | 749 | 748 | 742 | 754 | 744 | 744 | 744 | |
緩冷點(℃) | 804 | 804 | 809 | 809 | 815 | 814 | 805 | 807 | 805 | 801 | 815 | 804 | 803 | 803 | |
軟化點(℃) | 1041 | 1039 | 1043 | 1044 | 1021 | 1059 | 1011 | 1043 | 1044 | 1040 | 1062 | 1042 | 1041 | 1041 | |
104.5 dPa·s(℃) | 1363 | 1361 | 1362 | 1362 | 1285 | 1393 | 1278 | 1364 | 1367 | 1366 | 1405 | 1363 | 1365 | 1365 | |
104.0 dPa·s(℃) | 1524 | 1521 | 1524 | 1524 | 1423 | 1566 | 1412 | 1525 | 1530 | 1531 | 1578 | 1527 | 1528 | 1528 | |
103.0 dPa·s(℃) | 1629 | 1624 | 1628 | 1628 | 1511 | 1675 | 1500 | 1627 | 1633 | 1636 | 1693 | 1632 | 1633 | 1633 | |
102.5 dPa·s(℃) | 1301 | 1299 | 1300 | 1301 | 1234 | 1328 | 1227 | 1302 | 1305 | 1303 | 1339 | 1301 | 1303 | 1303 | |
楊氏模量(GPa) | 81.7 | 81.7 | 83.1 | 83.0 | 未測定 | 未測定 | 未測定 | 83.1 | 83.0 | 81.5 | 未測定 | 83.1 | 82.9 | 83.3 | |
比楊氏模量(GPa/g·cm-3 ) | 31.7 | 31.6 | 31.6 | 31.5 | 未測定 | 未測定 | 未測定 | 31.6 | 31.5 | 30.9 | 未測定 | 31.6 | 31.5 | 31.5 | |
β-OH(mm-1 ) | 0.03 | 0.15 | 0.11 | 0.13 | 0.03 | 0.15 | 0.12 | 0.04 | 0.10 | 0.15 | 0.15 | 0.08 | 0.13 | 0.10 |
[表17]
No.225 | No.226 | No.227 | No.228 | No.229 | No.230 | No.231 | No.232 | No.233 | No.234 | No.235 | No.236 | No.237 | No.238 | ||
莫耳% | SiO2 | 70.1 | 70.1 | 70.2 | 70.1 | 70.0 | 69.6 | 70.2 | 69.4 | 69.4 | 69.4 | 69.4 | 69.4 | 69.4 | 69.4 |
Al2 O3 | 12.7 | 12.7 | 12.8 | 12.7 | 12.6 | 12.8 | 12.0 | 13.6 | 13.6 | 13.1 | 13.1 | 13.6 | 13.6 | 13.6 | |
B2 O3 | 0.9 | 0.7 | 0.7 | 0.8 | 0.7 | 0.9 | 0.8 | 2.4 | 2.4 | 2.4 | 2.4 | 2.4 | 1.9 | 1.9 | |
MgO | 5.7 | 5.1 | 5.0 | 5.6 | 5.7 | 4.9 | 3.0 | 2.7 | 2.7 | 2.7 | 2.2 | 2.7 | 3.2 | 3.2 | |
CaO | 4.4 | 6.2 | 6.2 | 4.6 | 4.4 | 6.3 | 7.6 | 7.2 | 7.2 | 7.2 | 7.7 | 6.7 | 7.2 | 6.7 | |
SrO | 2.1 | 0.5 | 0.3 | 2.1 | 2.2 | 0.3 | 1.0 | 1.6 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | |
BaO | 3.9 | 4.5 | 4.6 | 3.9 | 4.2 | 5.0 | 5.2 | 2.9 | 4.2 | 4.7 | 4.7 | 4.7 | 4.2 | 4.7 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | |
[SiO2 ]+[Al2 O3 ] | 82.8 | 82.8 | 83.0 | 82.8 | 82.6 | 82.4 | 82.2 | 83.0 | 83.0 | 82.5 | 82.5 | 83.0 | 83.0 | 83.0 | |
[MgO]+[CaO]+[SrO]+[BaO] | 16.1 | 16.3 | 16.1 | 16.2 | 16.5 | 16.5 | 16.8 | 14.4 | 14.4 | 14.9 | 14.9 | 14.4 | 14.9 | 14.9 | |
[SrO]+[BaO] | 6.0 | 5.0 | 4.9 | 6.0 | 6.4 | 5.3 | 6.2 | 4.5 | 4.5 | 5.0 | 5.0 | 5.0 | 4.5 | 5.0 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.2 | 0.1 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.4 | 0.4 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 3.2 | 2.2 | 2.4 | 2.9 | 2.5 | 2.1 | -1.0 | 4.3 | 4.3 | 3.3 | 2.8 | 4.3 | 3.8 | 3.8 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 364.8 | 353.2 | 352.9 | 365.9 | 372.5 | 355.2 | 349.0 | 316.0 | 318.6 | 319.6 | 317.1 | 326.1 | 329.1 | 336.6 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1771.1 | 1772.2 | 1773.4 | 1772.3 | 1772.3 | 1769.6 | 1769.1 | 1763.0 | 1762.4 | 1758.3 | 1758.9 | 1762.8 | 1767.0 | 1767.4 | |
熱膨脹係數(10-7 /℃) | 39.4 | 39.5 | 39.2 | 39.3 | 40.0 | 40.5 | 42.8 | 38.1 | 38.4 | 39.6 | 40.0 | 38.7 | 38.8 | 38.9 | |
密度(g/cm3 ) | 2.640 | 2.640 | 2.639 | 2.642 | 2.656 | 2.655 | 2.675 | 2.586 | 2.607 | 2.624 | 2.624 | 2.620 | 2.615 | 2.630 | |
應變點(℃) | 744 | 746 | 748 | 745 | 745 | 743 | 738 | 741 | 742 | 734 | 734 | 740 | 743 | 742 | |
緩冷點(℃) | 803 | 804 | 806 | 804 | 803 | 802 | 796 | 800 | 802 | 794 | 794 | 800 | 802 | 802 | |
軟化點(℃) | 1040 | 1040 | 1042 | 1041 | 1040 | 1035 | 1032 | 1037 | 1038 | 1033 | 1033 | 1038 | 1038 | 1039 | |
104.5 dPa·s(℃) | 1362 | 1361 | 1361 | 1362 | 1363 | 1356 | 1360 | 1358 | 1363 | 1356 | 1357 | 1360 | 1361 | 1363 | |
104.0 dPa·s(℃) | 1524 | 1524 | 1524 | 1524 | 1526 | 1518 | 1527 | 1519 | 1525 | 1521 | 1522 | 1522 | 1526 | 1525 | |
103.0 dPa·s(℃) | 1629 | 1627 | 1627 | 1628 | 1631 | 1618 | 1632 | 1625 | 1629 | 1624 | 1627 | 1628 | 1640 | 1628 | |
102.5 dPa·s(℃) | 1300 | 1299 | 1299 | 1300 | 1301 | 1294 | 1296 | 1296 | 1300 | 1294 | 1294 | 1298 | 1298 | 1301 | |
楊氏模量(GPa) | 83.3 | 83.2 | 83.1 | 83.2 | 83.0 | 82.5 | 81.2 | 81.2 | 80.7 | 80.1 | 79.9 | 80.5 | 81.6 | 81.3 | |
比楊氏模量(GPa/g·cm-3 ) | 31.6 | 31.5 | 31.5 | 31.5 | 31.3 | 31.1 | 30.4 | 31.4 | 31.0 | 30.5 | 30.4 | 30.7 | 31.2 | 30.9 | |
β-OH(mm-1 ) | 0.05 | 0.08 | 0.07 | 0.09 | 0.03 | 0.08 | 0.09 | 0.09 | 0.10 | 0.08 | 0.15 | 0.08 | 0.14 | 0.07 |
[表18]
No.239 | No.240 | No.241 | No.242 | No.243 | No.244 | No.245 | No.246 | No.247 | No.248 | No.249 | No.250 | No.251 | No.252 | ||
莫耳% | SiO2 | 69.4 | 71.3 | 72.3 | 72.3 | 72.3 | 72.3 | 72.3 | 72.3 | 72.3 | 71.3 | 71.3 | 71.3 | 71.8 | 71.3 |
Al2 O3 | 13.1 | 10.7 | 10.7 | 10.7 | 10.7 | 10.7 | 11.7 | 11.7 | 11.7 | 11.7 | 11.7 | 11.7 | 10.7 | 10.7 | |
B2 O3 | 1.9 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 3.7 | 0.0 | 0.0 | 1.0 | 1.0 | 2.0 | 1.0 | 2.0 | 3.0 | 1.0 | 2.0 | 3.0 | 1.0 | 1.0 | |
CaO | 6.7 | 11.5 | 11.5 | 11.5 | 10.5 | 9.5 | 10.5 | 9.5 | 8.5 | 10.5 | 9.5 | 8.5 | 11.5 | 11.5 | |
SrO | 0.3 | 1.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.8 | 1.3 | |
BaO | 4.7 | 5.0 | 5.0 | 4.0 | 5.0 | 5.0 | 4.0 | 4.0 | 4.0 | 5.0 | 5.0 | 5.0 | 4.0 | 4.0 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | |
[SiO2 ]+[Al2 O3 ] | 82.5 | 82.0 | 83.0 | 83.0 | 83.0 | 83.0 | 84.0 | 84.0 | 84.0 | 83.0 | 83.0 | 83.0 | 82.5 | 82.0 | |
[MgO]+[CaO]+[SrO]+[BaO] | 15.4 | 17.8 | 16.8 | 16.8 | 16.8 | 16.8 | 15.8 | 15.8 | 15.8 | 16.8 | 16.8 | 16.8 | 17.3 | 17.8 | |
[SrO]+[BaO] | 5.0 | 6.3 | 5.3 | 4.3 | 5.3 | 5.3 | 4.3 | 4.3 | 4.3 | 5.3 | 5.3 | 5.3 | 4.8 | 5.3 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.4 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 3.3 | -7.1 | -6.1 | -5.1 | -5.1 | -4.1 | -3.1 | -2.1 | -1.1 | -4.1 | -3.1 | -2.1 | -5.6 | -6.1 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 332.6 | 330.8 | 317.8 | 307.8 | 322.8 | 327.8 | 320.8 | 325.8 | 330.8 | 335.8 | 340.8 | 345.8 | 314.3 | 320.8 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1762.3 | 1773.6 | 1775.9 | 1773.8 | 1774.7 | 1773.5 | 1782.8 | 1781.6 | 1780.4 | 1780.0 | 1778.8 | 1777.6 | 1772.7 | 1771.5 | |
熱膨脹係數(10-7 /℃) | 39.4 | 46.5 | 45.0 | 43.5 | 44.0 | 43.3 | 42.0 | 41.0 | 40.3 | 44.0 | 43.0 | 42.3 | 44.8 | 45.5 | |
密度(g/cm3 ) | 2.630 | 2.697 | 2.666 | 2.631 | 2.661 | 2.659 | 2.623 | 2.620 | 2.616 | 2.668 | 2.665 | 2.662 | 2.645 | 2.661 | |
應變點(℃) | 736 | 744 | 750 | 750 | 747 | 746 | 764 | 760 | 759 | 755 | 753 | 752 | 743 | 743 | |
緩冷點(℃) | 796 | 799 | 807 | 807 | 805 | 804 | 822 | 820 | 818 | 813 | 811 | 810 | 800 | 799 | |
軟化點(℃) | 1033 | 1023 | 1037 | 1038 | 1037 | 1039 | 1057 | 1056 | 1056 | 1043 | 1044 | 1044 | 1031 | 1026 | |
104.5 dPa·s(℃) | 1356 | 1347 | 1369 | 1370 | 1374 | 1384 | 1393 | 1389 | 1379 | 1372 | 1375 | 1378 | 1358 | 1348 | |
104.0 dPa·s(℃) | 1520 | 1517 | 1542 | 1543 | 1547 | 1556 | 1564 | 1561 | 1551 | 1541 | 1544 | 1546 | 1529 | 1517 | |
103.0 dPa·s(℃) | 1628 | 1628 | 1655 | 1654 | 1661 | 1667 | 1673 | 1675 | 1664 | 1650 | 1652 | 1653 | 1642 | 1626 | |
102.5 dPa·s(℃) | 1294 | 1283 | 1303 | 1305 | 1308 | 1317 | 1327 | 1324 | 1316 | 1308 | 1310 | 1313 | 1294 | 1285 | |
楊氏模量(GPa) | 81.3 | 80.3 | 80.2 | 81.1 | 80.3 | 80.8 | 81.2 | 81.6 | 82.1 | 80.9 | 81.3 | 81.7 | 80.6 | 80.7 | |
比楊氏模量(GPa/g·cm-3 ) | 30.9 | 29.8 | 30.1 | 30.8 | 30.2 | 30.4 | 31.0 | 31.1 | 31.4 | 30.3 | 30.5 | 30.7 | 30.5 | 30.3 | |
β-OH(mm-1 ) | 0.07 | 0.11 | 0.14 | 0.14 | 0.04 | 0.06 | 0.12 | 0.12 | 0.10 | 0.04 | 0.15 | 0.12 | 0.13 | 0.10 |
[表19]
No.253 | No.254 | No.255 | No.256 | No.257 | No.258 | No.259 | No.260 | No.261 | No.262 | No.263 | No.264 | No.265 | No.266 | ||
莫耳% | SiO2 | 71.8 | 71.8 | 71.8 | 71.8 | 71.3 | 71.3 | 71.5 | 71.5 | 71.5 | 71.5 | 71.7 | 72.0 | 71.7 | 72.0 |
Al2 O3 | 10.7 | 10.7 | 10.9 | 11.1 | 11.1 | 11.3 | 11.0 | 11.0 | 11.0 | 11.0 | 10.7 | 10.7 | 10.7 | 10.7 | |
B2 O3 | 0.0 | 0.0 | 0.3 | 0.6 | 0.3 | 0.6 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 0.0 | 0.0 | 1.0 | 1.0 | |
CaO | 11.0 | 10.5 | 11.0 | 10.5 | 11.0 | 10.5 | 11.0 | 10.5 | 10.5 | 10.0 | 11.1 | 10.8 | 10.1 | 9.8 | |
SrO | 1.3 | 1.8 | 0.8 | 0.8 | 1.1 | 1.1 | 0.3 | 1.8 | 1.3 | 1.8 | 1.3 | 1.3 | 1.3 | 1.3 | |
BaO | 4.0 | 4.0 | 4.0 | 4.0 | 4.0 | 4.0 | 5.0 | 4.0 | 4.5 | 4.5 | 5.0 | 5.0 | 5.0 | 5.0 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | |
[SiO2 ]+[Al2 O3 ] | 82.5 | 82.5 | 82.7 | 82.9 | 82.4 | 82.6 | 82.5 | 82.5 | 82.5 | 82.5 | 82.4 | 82.7 | 82.4 | 82.7 | |
[MgO]+[CaO]+[SrO]+[BaO] | 17.3 | 17.3 | 16.8 | 16.3 | 17.1 | 16.6 | 17.3 | 17.3 | 17.3 | 17.3 | 17.4 | 17.1 | 17.4 | 17.1 | |
[SrO]+[BaO] | 5.3 | 5.8 | 4.8 | 4.8 | 5.1 | 5.1 | 5.3 | 5.8 | 5.8 | 6.3 | 6.3 | 6.3 | 6.3 | 6.3 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | 0.1 | 0.1 | 0.1 | 0.1 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | -5.6 | -5.6 | -4.6 | -3.6 | -4.7 | -3.7 | -5.3 | -5.3 | -5.3 | -5.3 | -6.7 | -6.4 | -5.7 | -5.4 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 320.8 | 327.3 | 312.1 | 309.9 | 318.6 | 316.4 | 326.7 | 331.2 | 332.2 | 338.7 | 330.8 | 330.8 | 335.8 | 335.8 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1773.4 | 1774.1 | 1771.3 | 1770.0 | 1771.7 | 1770.4 | 1774.5 | 1775.7 | 1775.4 | 1776.1 | 1775.1 | 1776.2 | 1773.9 | 1775.0 | |
熱膨脹係數(10-7 /℃) | 44.6 | 44.8 | 44.1 | 43.4 | 44.2 | 43.4 | 45.3 | 44.8 | 45.0 | 45.1 | 46.3 | 45.7 | 45.4 | 44.8 | |
密度(g/cm3 ) | 2.654 | 2.661 | 2.638 | 2.631 | 2.650 | 2.641 | 2.672 | 2.662 | 2.671 | 2.679 | 2.690 | 2.686 | 2.686 | 2.681 | |
應變點(℃) | 745 | 744 | 743 | 740 | 741 | 740 | 747 | 746 | 744 | 747 | 745 | 746 | 742 | 742 | |
緩冷點(℃) | 802 | 801 | 800 | 799 | 799 | 798 | 803 | 803 | 801 | 804 | 801 | 802 | 799 | 800 | |
軟化點(℃) | 1032 | 1032 | 1034 | 1036 | 1031 | 1034 | 1034 | 1033 | 1032 | 1034 | 1029 | 1032 | 1031 | 1034 | |
104.5 dPa·s(℃) | 1360 | 1359 | 1363 | 1368 | 1357 | 1361 | 1360 | 1362 | 1362 | 1362 | 1357 | 1363 | 1360 | 1366 | |
104.0 dPa·s(℃) | 1531 | 1530 | 1535 | 1540 | 1527 | 1531 | 1530 | 1533 | 1532 | 1533 | 1528 | 1537 | 1533 | 1539 | |
103.0 dPa·s(℃) | 1642 | 1641 | 1646 | 1652 | 1636 | 1639 | 1641 | 1644 | 1642 | 1643 | 1640 | 1647 | 1646 | 1651 | |
102.5 dPa·s(℃) | 1296 | 1295 | 1298 | 1303 | 1293 | 1297 | 1296 | 1297 | 1297 | 1298 | 1292 | 1298 | 1295 | 1301 | |
楊氏模量(GPa) | 80.6 | 80.6 | 80.4 | 80.2 | 80.6 | 80.4 | 80.6 | 80.6 | 80.5 | 80.5 | 79.9 | 80.0 | 80.3 | 80.4 | |
比楊氏模量(GPa/g·cm-3 ) | 30.4 | 30.3 | 30.5 | 30.5 | 30.4 | 30.5 | 30.1 | 30.3 | 30.1 | 30.1 | 29.7 | 29.8 | 29.9 | 30.0 | |
β-OH(mm-1 ) | 0.10 | 0.05 | 0.05 | 0.08 | 0.04 | 0.13 | 0.14 | 0.15 | 0.03 | 0.03 | 0.04 | 0.13 | 0.09 | 0.08 |
[表20]
No.267 | No.268 | No.269 | No.270 | No.271 | No.272 | No.273 | No.274 | No.275 | No.276 | No.277 | No.278 | No.279 | No.280 | ||
莫耳% | SiO2 | 72.2 | 69.6 | 71.2 | 69.4 | 71.5 | 72.0 | 72.0 | 72.0 | 72.0 | 71.8 | 71.6 | 69.8 | 71.8 | 71.6 |
Al2 O3 | 10.7 | 10.7 | 10.7 | 11.3 | 10.4 | 11.3 | 11.9 | 12.4 | 12.1 | 11.2 | 11.9 | 14.0 | 11.9 | 12.4 | |
B2 O3 | 0.0 | 0.4 | 0.1 | 2.4 | 0.8 | 0.5 | 1.0 | 1.5 | 1.8 | 0.2 | 0.2 | 0.0 | 1.2 | 1.9 | |
MgO | 0.0 | 2.0 | 0.7 | 1.6 | 0.6 | 0.0 | 0.0 | 0.0 | 0.0 | 2.0 | 4.0 | 2.0 | 0.0 | 0.0 | |
CaO | 10.6 | 10.8 | 10.8 | 10.2 | 10.4 | 10.1 | 9.4 | 8.8 | 8.8 | 8.8 | 6.8 | 6.0 | 9.4 | 8.8 | |
SrO | 1.3 | 1.3 | 1.3 | 0.4 | 0.5 | 1.2 | 1.1 | 1.0 | 1.0 | 0.8 | 0.3 | 8.0 | 1.1 | 1.0 | |
BaO | 5.0 | 5.0 | 5.0 | 4.4 | 5.6 | 4.7 | 4.4 | 4.1 | 4.1 | 5.0 | 5.0 | 0.0 | 4.4 | 4.1 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | |
[SiO2 ]+[Al2 O3 ] | 82.9 | 80.3 | 81.9 | 80.8 | 81.9 | 83.3 | 83.9 | 84.4 | 84.1 | 83.0 | 83.5 | 83.8 | 83.7 | 84.0 | |
[MgO]+[CaO]+[SrO]+[BaO] | 16.9 | 19.1 | 17.8 | 16.6 | 17.1 | 16.0 | 14.9 | 13.9 | 13.9 | 16.6 | 16.1 | 16.0 | 14.9 | 13.9 | |
[SrO]+[BaO] | 6.3 | 6.3 | 6.3 | 4.8 | 6.1 | 5.9 | 5.5 | 5.1 | 5.1 | 5.8 | 5.3 | 8.0 | 5.5 | 5.1 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.1 | 0.0 | 0.5 | 0.1 | 0.1 | 0.2 | 0.3 | 0.4 | 0.0 | 0.0 | 0.0 | 0.2 | 0.4 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | -6.2 | -6.0 | -6.3 | -1.3 | -5.3 | -4.2 | -2.0 | 0.0 | 0.0 | -3.2 | 0.0 | 0.0 | -1.8 | 0.4 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 330.8 | 334.4 | 332.7 | 288.4 | 315.7 | 324.8 | 318.8 | 311.5 | 302.8 | 337.6 | 350.2 | 395.8 | 315.6 | 305.1 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1776.9 | 1760.8 | 1771.4 | 1743.7 | 1762.0 | 1776.0 | 1775.8 | 1774.7 | 1768.9 | 1774.8 | 1777.2 | 1800.2 | 1773.0 | 1769.0 | |
熱膨脹係數(10-7 /℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
密度(g/cm3 ) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
應變點(℃) | 未測定 | 727 | 740 | 713 | 727 | 747 | 751 | 756 | 749 | 745 | 749 | 777 | 751 | 746 | |
緩冷點(℃) | 未測定 | 782 | 797 | 771 | 784 | 806 | 未測定 | 未測定 | 812 | 804 | 809 | 835 | 813 | 803 | |
軟化點(℃) | 未測定 | 1005 | 1024 | 1004 | 1016 | 1043 | 未測定 | 未測定 | 1058 | 1043 | 1051 | 1062 | 1058 | 1031 | |
104.5 dPa·s(℃) | 未測定 | 1318 | 1349 | 1327 | 1350 | 1384 | 未測定 | 未測定 | 1399 | 1380 | 1387 | 1377 | 1395 | 1345 | |
104.0 dPa·s(℃) | 未測定 | 1483 | 1519 | 1494 | 1524 | 1559 | 未測定 | 未測定 | 1572 | 1552 | 1557 | 1536 | 1565 | 1503 | |
103.0 dPa·s(℃) | 未測定 | 1589 | 1630 | 1600 | 1636 | 1670 | 未測定 | 未測定 | 1682 | 1662 | 1667 | 1638 | 1674 | 1604 | |
102.5 dPa·s(℃) | 未測定 | 1256 | 1285 | 1264 | 1284 | 1317 | 未測定 | 未測定 | 1333 | 1314 | 1322 | 1316 | 1330 | 1284 | |
楊氏模量(GPa) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
比楊氏模量(GPa/g·cm-3 ) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
β-OH(mm-1 ) | 0.08 | 0.05 | 0.10 | 0.04 | 0.10 | 0.03 | 0.11 | 0.06 | 0.09 | 0.03 | 0.15 | 0.12 | 0.07 | 0.15 |
[表21]
No.281 | No.282 | No.283 | No.284 | No.285 | No.286 | No.287 | No.288 | No.289 | No.290 | No.291 | No.292 | No.293 | No.294 | ||
莫耳% | SiO2 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 |
Al2 O3 | 13.5 | 13.5 | 13.5 | 13.5 | 13.5 | 13.0 | 13.0 | 13.0 | 13.0 | 13.0 | 13.0 | 13.0 | 13.0 | 13.0 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.5 | 0.0 | 0.0 | 0.0 | 0.0 | 1.0 | 0.0 | 0.0 | 0.0 | 0.5 | |
MgO | 3.3 | 3.3 | 3.3 | 3.8 | 3.3 | 3.3 | 3.3 | 3.3 | 4.3 | 3.3 | 3.3 | 3.3 | 3.8 | 3.3 | |
CaO | 4.7 | 4.7 | 5.2 | 4.7 | 4.7 | 4.7 | 4.7 | 5.7 | 4.7 | 4.7 | 4.7 | 5.2 | 4.7 | 4.7 | |
SrO | 0.0 | 0.5 | 0.0 | 0.0 | 0.0 | 0.0 | 1.0 | 0.0 | 0.0 | 0.0 | 0.5 | 0.0 | 0.0 | 0.0 | |
BaO | 6.6 | 6.1 | 6.1 | 6.1 | 6.1 | 7.1 | 6.1 | 6.1 | 6.1 | 6.1 | 6.6 | 6.6 | 6.6 | 6.6 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 85.4 | 85.4 | 85.4 | 85.4 | 85.4 | 84.9 | 84.9 | 84.9 | 84.9 | 84.9 | 84.9 | 84.9 | 84.9 | 84.9 | |
[MgO]+[CaO]+[SrO]+[BaO] | 14.5 | 14.5 | 14.5 | 14.6 | 14.0 | 15.0 | 15.0 | 15.0 | 15.1 | 14.0 | 15.0 | 15.1 | 15.1 | 14.6 | |
[SrO]+[BaO] | 6.6 | 6.6 | 6.1 | 6.1 | 6.1 | 7.1 | 7.1 | 6.1 | 6.1 | 6.1 | 7.1 | 6.6 | 6.6 | 6.6 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | 0.0 | 0.0 | 0.1 | 0.0 | 0.0 | 0.0 | 0.0 | 0.2 | 0.0 | 0.0 | 0.0 | 0.1 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 2.2 | 2.3 | 2.2 | 2.7 | 3.3 | 1.2 | 1.3 | 1.2 | 2.2 | 3.3 | 1.2 | 1.2 | 1.7 | 2.2 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 390.8 | 389.2 | 382.8 | 386.0 | 374.7 | 391.8 | 389.2 | 376.3 | 382.0 | 360.2 | 390.8 | 384.3 | 387.0 | 376.5 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1798.6 | 1798.4 | 1798.1 | 1798.0 | 1792.5 | 1794.6 | 1794.6 | 1793.6 | 1792.9 | 1782.8 | 1794.8 | 1794.6 | 1794.4 | 1789.3 | |
熱膨脹係數(10-7 /℃) | 39.1 | 39.0 | 38.8 | 38.4 | 38.1 | 40.3 | 40.0 | 39.7 | 38.9 | 38.2 | 40.2 | 40.0 | 39.6 | 39.2 | |
密度(g/cm3 ) | 2.687 | 2.679 | 2.672 | 2.672 | 2.662 | 2.703 | 2.688 | 2.675 | 2.673 | 2.655 | 2.696 | 2.689 | 2.688 | 2.679 | |
應變點(℃) | 776 | 776 | 775 | 774 | 768 | 770 | 771 | 770 | 768 | 756 | 770 | 770 | 769 | 763 | |
緩冷點(℃) | 838 | 838 | 837 | 836 | 832 | 833 | 833 | 831 | 829 | 821 | 833 | 832 | 831 | 827 | |
軟化點(℃) | 1082 | 1081 | 1079 | 1078 | 1076 | 1077 | 1075 | 1072 | 1071 | 1066 | 1076 | 1074 | 1074 | 1071 | |
104.5 dPa·s(℃) | 1415 | 1413 | 1411 | 1411 | 1411 | 1411 | 1409 | 1405 | 1404 | 1405 | 1410 | 1408 | 1408 | 1408 | |
104.0 dPa·s(℃) | 1581 | 1580 | 1577 | 1576 | 1578 | 1581 | 1578 | 1573 | 1571 | 1574 | 1579 | 1577 | 1575 | 1578 | |
103.0 dPa·s(℃) | 1686 | 1685 | 1682 | 1681 | 1684 | 1687 | 1684 | 1679 | 1677 | 1681 | 1685 | 1683 | 1681 | 1683 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 82.0 | 82.1 | 82.3 | 82.6 | 81.7 | 81.4 | 81.6 | 82.0 | 82.5 | 80.8 | 81.5 | 81.7 | 82.0 | 81.2 | |
比楊氏模量(GPa/g·cm-3 ) | 30.5 | 30.6 | 30.8 | 30.9 | 30.7 | 30.1 | 30.4 | 30.7 | 30.9 | 30.4 | 30.2 | 30.4 | 30.5 | 30.3 | |
β-OH(mm-1 ) | 0.14 | 0.14 | 0.06 | 0.13 | 0.15 | 0.15 | 0.15 | 0.08 | 0.07 | 0.03 | 0.15 | 0.11 | 0.13 | 0.08 |
[表22]
No.295 | No.296 | No.297 | No.298 | No.299 | No.300 | No.301 | No.302 | No.303 | No.304 | No.305 | No.306 | No.307 | No.308 | ||
莫耳% | SiO2 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 |
Al2 O3 | 12.5 | 12.5 | 12.5 | 12.5 | 12.5 | 12.5 | 12.5 | 12.5 | 12.5 | 12.5 | 12.5 | 12.5 | 12.5 | 12.5 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 1.5 | 0.0 | 0.0 | 0.0 | 0.5 | 0.0 | 0.0 | 0.0 | 1.0 | 0.0 | |
MgO | 3.3 | 3.3 | 3.3 | 4.8 | 3.3 | 3.3 | 3.3 | 3.8 | 3.3 | 3.3 | 3.3 | 4.3 | 3.3 | 3.3 | |
CaO | 4.7 | 4.7 | 6.2 | 4.7 | 4.7 | 4.7 | 5.2 | 4.7 | 4.7 | 4.7 | 5.7 | 4.7 | 4.7 | 5.2 | |
SrO | 0.0 | 1.5 | 0.0 | 0.0 | 0.0 | 0.5 | 0.0 | 0.0 | 0.0 | 1.0 | 0.0 | 0.0 | 0.0 | 0.5 | |
BaO | 7.6 | 6.1 | 6.1 | 6.1 | 6.1 | 7.1 | 7.1 | 7.1 | 7.1 | 6.6 | 6.6 | 6.6 | 6.6 | 6.6 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 84.4 | 84.4 | 84.4 | 84.4 | 84.4 | 84.4 | 84.4 | 84.4 | 84.4 | 84.4 | 84.4 | 84.4 | 84.4 | 84.4 | |
[MgO]+[CaO]+[SrO]+[BaO] | 15.5 | 15.5 | 15.5 | 15.5 | 14.0 | 15.5 | 15.6 | 15.6 | 15.0 | 15.5 | 15.6 | 15.6 | 14.5 | 15.6 | |
[SrO]+[BaO] | 7.6 | 7.6 | 6.1 | 6.1 | 6.1 | 7.6 | 7.1 | 7.1 | 7.1 | 7.6 | 6.6 | 6.6 | 6.6 | 7.1 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | 0.0 | 0.0 | 0.2 | 0.0 | 0.0 | 0.0 | 0.1 | 0.0 | 0.0 | 0.0 | 0.2 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 0.2 | 0.3 | 0.2 | 1.8 | 3.3 | 0.2 | 0.2 | 0.7 | 1.2 | 0.2 | 0.2 | 1.2 | 2.2 | 0.2 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 392.8 | 389.2 | 369.8 | 377.4 | 345.7 | 391.8 | 385.3 | 388.0 | 377.3 | 390.8 | 377.8 | 383.0 | 361.8 | 384.3 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1790.5 | 1790.8 | 1789.1 | 1787.3 | 1773.1 | 1790.8 | 1790.5 | 1789.9 | 1784.9 | 1791.0 | 1790.1 | 1788.8 | 1779.2 | 1790.8 | |
熱膨脹係數(10-7 /℃) | 41.4 | 41.1 | 40.5 | 39.3 | 38.3 | 41.3 | 41.1 | 40.7 | 40.4 | 41.2 | 40.9 | 40.0 | 39.3 | 41.0 | |
密度(g/cm3 ) | 2.719 | 2.697 | 2.677 | 2.674 | 2.647 | 2.712 | 2.705 | 2.704 | 2.696 | 2.705 | 2.692 | 2.689 | 2.672 | 2.698 | |
應變點(℃) | 764 | 765 | 764 | 763 | 745 | 764 | 764 | 763 | 757 | 764 | 764 | 763 | 751 | 764 | |
緩冷點(℃) | 826 | 826 | 824 | 823 | 811 | 826 | 825 | 824 | 821 | 826 | 824 | 823 | 815 | 825 | |
軟化點(℃) | 1072 | 1069 | 1064 | 1064 | 1056 | 1071 | 1069 | 1069 | 1066 | 1070 | 1067 | 1067 | 1061 | 1068 | |
104.5 dPa·s(℃) | 1407 | 1404 | 1398 | 1398 | 1398 | 1406 | 1404 | 1404 | 1404 | 1405 | 1401 | 1401 | 1401 | 1403 | |
104.0 dPa·s(℃) | 1578 | 1575 | 1568 | 1565 | 1571 | 1577 | 1575 | 1574 | 1577 | 1576 | 1571 | 1569 | 1575 | 1573 | |
103.0 dPa·s(℃) | 1686 | 1682 | 1675 | 1672 | 1677 | 1684 | 1682 | 1681 | 1683 | 1683 | 1678 | 1677 | 1680 | 1680 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 80.8 | 81.2 | 81.7 | 82.4 | 79.9 | 80.9 | 81.1 | 81.4 | 80.5 | 81.1 | 81.4 | 81.9 | 80.2 | 81.3 | |
比楊氏模量(GPa/g·cm-3 ) | 29.7 | 30.1 | 30.5 | 30.8 | 30.2 | 29.8 | 30.0 | 30.1 | 29.9 | 30.0 | 30.3 | 30.5 | 30.0 | 30.1 | |
β-OH(mm-1 ) | 0.06 | 0.14 | 0.05 | 0.04 | 0.05 | 0.13 | 0.07 | 0.13 | 0.05 | 0.06 | 0.12 | 0.08 | 0.03 | 0.08 |
[表23]
No.309 | No.310 | No.311 | No.312 | No.313 | No.314 | No.315 | No.316 | No.317 | No.318 | No.319 | No.320 | No.321 | No.322 | ||
莫耳% | SiO2 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 |
Al2 O3 | 12.5 | 12.5 | 12.5 | 12.5 | 12.5 | 12.0 | 12.0 | 12.0 | 12.0 | 12.0 | 12.0 | 12.0 | 12.0 | 12.0 | |
B2 O3 | 0.0 | 0.5 | 0.0 | 0.5 | 0.5 | 0.0 | 0.0 | 0.0 | 0.0 | 2.0 | 0.0 | 0.0 | 0.0 | 1.0 | |
MgO | 3.8 | 3.3 | 3.8 | 3.3 | 3.8 | 3.3 | 3.3 | 3.3 | 5.3 | 3.3 | 3.3 | 3.3 | 4.3 | 3.3 | |
CaO | 4.7 | 4.7 | 5.2 | 5.2 | 4.7 | 4.7 | 4.7 | 6.7 | 4.7 | 4.7 | 4.7 | 5.7 | 4.7 | 4.7 | |
SrO | 0.5 | 0.5 | 0.0 | 0.0 | 0.0 | 0.0 | 2.0 | 0.0 | 0.0 | 0.0 | 1.0 | 0.0 | 0.0 | 0.0 | |
BaO | 6.6 | 6.6 | 6.6 | 6.6 | 6.6 | 8.1 | 6.1 | 6.1 | 6.1 | 6.1 | 7.1 | 7.1 | 7.1 | 7.1 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 84.4 | 84.4 | 84.4 | 84.4 | 84.4 | 83.9 | 83.9 | 83.9 | 83.9 | 83.9 | 83.9 | 83.9 | 83.9 | 83.9 | |
[MgO]+[CaO]+[SrO]+[BaO] | 15.6 | 15.1 | 15.6 | 15.1 | 15.1 | 16.0 | 16.0 | 16.0 | 16.0 | 14.0 | 16.0 | 16.1 | 16.1 | 15.0 | |
[SrO]+[BaO] | 7.1 | 7.1 | 6.6 | 6.6 | 6.6 | 8.1 | 8.1 | 6.1 | 6.1 | 6.1 | 8.1 | 7.1 | 7.1 | 7.1 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.1 | 0.0 | 0.1 | 0.1 | 0.0 | 0.0 | 0.0 | 0.0 | 0.3 | 0.0 | 0.0 | 0.0 | 0.1 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 0.7 | 1.2 | 0.7 | 1.2 | 1.7 | -0.8 | -0.7 | -0.8 | 1.3 | 3.3 | -0.8 | -0.8 | 0.2 | 1.2 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 387.0 | 376.5 | 380.5 | 370.0 | 372.5 | 393.8 | 389.2 | 363.3 | 373.4 | 331.2 | 391.8 | 378.8 | 384.0 | 362.8 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1790.6 | 1786.0 | 1789.9 | 1785.3 | 1784.7 | 1786.5 | 1787.0 | 1784.6 | 1782.2 | 1763.4 | 1787.0 | 1786.0 | 1784.8 | 1775.2 | |
熱膨脹係數(10-7 /℃) | 40.6 | 40.2 | 40.4 | 40.1 | 39.7 | 42.6 | 42.1 | 41.4 | 39.8 | 38.4 | 42.4 | 42.0 | 41.2 | 40.5 | |
密度(g/cm3 ) | 2.697 | 2.688 | 2.690 | 2.681 | 2.680 | 2.736 | 2.706 | 2.680 | 2.675 | 2.640 | 2.721 | 2.708 | 2.706 | 2.688 | |
應變點(℃) | 763 | 757 | 763 | 757 | 757 | 758 | 758 | 758 | 758 | 736 | 758 | 758 | 758 | 746 | |
緩冷點(℃) | 824 | 820 | 823 | 819 | 819 | 818 | 818 | 816 | 817 | 800 | 818 | 817 | 817 | 809 | |
軟化點(℃) | 1068 | 1065 | 1066 | 1064 | 1063 | 1065 | 1062 | 1057 | 1058 | 1045 | 1063 | 1061 | 1061 | 1054 | |
104.5 dPa·s(℃) | 1403 | 1403 | 1401 | 1401 | 1401 | 1402 | 1399 | 1391 | 1391 | 1390 | 1401 | 1397 | 1397 | 1396 | |
104.0 dPa·s(℃) | 1572 | 1575 | 1570 | 1573 | 1572 | 1575 | 1570 | 1561 | 1558 | 1568 | 1572 | 1567 | 1566 | 1574 | |
103.0 dPa·s(℃) | 1679 | 1680 | 1677 | 1678 | 1678 | 1683 | 1678 | 1670 | 1667 | 1671 | 1681 | 1676 | 1675 | 1677 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 81.6 | 80.7 | 81.7 | 80.9 | 81.1 | 80.1 | 80.7 | 81.4 | 82.4 | 79.0 | 80.4 | 80.8 | 81.3 | 79.6 | |
比楊氏模量(GPa/g·cm-3 ) | 30.2 | 30.0 | 30.4 | 30.2 | 30.3 | 29.3 | 29.8 | 30.4 | 30.8 | 29.9 | 29.6 | 29.8 | 30.0 | 29.6 | |
β-OH(mm-1 ) | 0.06 | 0.04 | 0.06 | 0.15 | 0.03 | 0.05 | 0.03 | 0.11 | 0.05 | 0.11 | 0.13 | 0.14 | 0.08 | 0.14 |
[表24]
No.323 | No.324 | No.325 | No.326 | No.327 | No.328 | No.329 | No.330 | No.331 | No.332 | No.333 | No.334 | No.335 | No.336 | ||
莫耳% | SiO2 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 |
Al2 O3 | 12.0 | 12.0 | 12.0 | 12.0 | 12.0 | 12.0 | 14.5 | 14.5 | 14.5 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | |
B2 O3 | 0.0 | 0.0 | 1.0 | 0.0 | 1.0 | 1.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 3.3 | 4.3 | 3.3 | 4.3 | 3.3 | 4.3 | 3.3 | 3.3 | 2.8 | 3.3 | 3.3 | 2.3 | 3.3 | 2.8 | |
CaO | 5.7 | 4.7 | 4.7 | 5.7 | 5.7 | 4.7 | 4.7 | 4.2 | 4.7 | 4.7 | 3.7 | 4.7 | 4.2 | 4.7 | |
SrO | 1.0 | 1.0 | 1.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
BaO | 6.1 | 6.1 | 6.1 | 6.1 | 6.1 | 6.1 | 5.6 | 6.1 | 6.1 | 5.1 | 6.1 | 6.1 | 5.6 | 5.6 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 83.9 | 83.9 | 83.9 | 83.9 | 83.9 | 83.9 | 86.4 | 86.4 | 86.4 | 86.9 | 86.9 | 86.9 | 86.9 | 86.9 | |
[MgO]+[CaO]+[SrO]+[BaO] | 16.0 | 16.0 | 15.0 | 16.1 | 15.0 | 15.0 | 13.5 | 13.5 | 13.6 | 13.0 | 13.0 | 13.1 | 13.1 | 13.1 | |
[SrO]+[BaO] | 7.1 | 7.1 | 7.1 | 6.1 | 6.1 | 6.1 | 5.6 | 6.1 | 6.1 | 5.1 | 6.1 | 6.1 | 5.6 | 5.6 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | 0.1 | 0.0 | 0.2 | 0.2 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | -0.8 | 0.3 | 1.3 | 0.2 | 1.2 | 2.3 | 4.2 | 4.2 | 3.7 | 5.2 | 5.2 | 4.2 | 5.2 | 4.7 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 376.3 | 381.4 | 360.2 | 368.5 | 347.3 | 352.4 | 388.8 | 395.8 | 394.0 | 387.8 | 402.3 | 398.0 | 395.3 | 393.0 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1786.0 | 1784.8 | 1775.2 | 1783.9 | 1774.2 | 1773.0 | 1806.7 | 1807.1 | 1808.2 | 1810.8 | 1811.6 | 1813.3 | 1811.7 | 1812.7 | |
熱膨脹係數(10-7 /℃) | 41.8 | 40.9 | 40.2 | 40.6 | 39.9 | 39.1 | 36.9 | 37.1 | 37.5 | 35.7 | 36.3 | 37.0 | 36.0 | 36.4 | |
密度(g/cm3 ) | 2.693 | 2.691 | 2.673 | 2.677 | 2.660 | 2.657 | 2.654 | 2.667 | 2.669 | 2.638 | 2.664 | 2.667 | 2.651 | 2.652 | |
應變點(℃) | 758 | 758 | 746 | 757 | 746 | 747 | 785 | 785 | 787 | 788 | 790 | 794 | 789 | 791 | |
緩冷點(℃) | 817 | 817 | 809 | 816 | 808 | 808 | 846 | 847 | 849 | 847 | 850 | 854 | 849 | 850 | |
軟化點(℃) | 1059 | 1060 | 1053 | 1057 | 1051 | 1051 | 1092 | 1095 | 1097 | 1097 | 1102 | 1106 | 1100 | 1101 | |
104.5 dPa·s(℃) | 1395 | 1395 | 1394 | 1391 | 1390 | 1391 | 1418 | 1421 | 1422 | 1418 | 1424 | 1428 | 1421 | 1423 | |
104.0 dPa·s(℃) | 1565 | 1564 | 1571 | 1559 | 1567 | 1564 | 1580 | 1583 | 1585 | 1580 | 1587 | 1590 | 1583 | 1584 | |
103.0 dPa·s(℃) | 1674 | 1673 | 1674 | 1668 | 1670 | 1669 | 1681 | 1685 | 1687 | 1677 | 1684 | 1689 | 1680 | 1682 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 81.1 | 81.6 | 79.9 | 82.0 | 80.3 | 80.7 | 83.2 | 82.9 | 82.7 | 83.8 | 83.2 | 82.8 | 83.5 | 83.4 | |
比楊氏模量(GPa/g·cm-3 ) | 30.1 | 30.3 | 29.9 | 30.6 | 30.2 | 30.4 | 31.3 | 31.1 | 31.0 | 31.8 | 31.2 | 31.0 | 31.5 | 31.4 | |
β-OH(mm-1 ) | 0.09 | 0.11 | 0.10 | 0.12 | 0.09 | 0.09 | 0.12 | 0.03 | 0.05 | 0.05 | 0.09 | 0.09 | 0.06 | 0.12 |
[表25]
No.337 | No.338 | No.339 | No.340 | No.341 | No.342 | No.343 | No.344 | No.345 | No.346 | No.347 | No.348 | No.349 | No.350 | ||
莫耳% | SiO2 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 |
Al2 O3 | 15.0 | 15.5 | 15.5 | 15.5 | 15.5 | 15.5 | 15.5 | 15.5 | 15.5 | 15.5 | 16.0 | 16.0 | 16.0 | 16.0 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 2.8 | 3.3 | 3.3 | 1.8 | 3.3 | 2.8 | 3.3 | 2.3 | 2.8 | 2.3 | 3.3 | 3.3 | 1.3 | 3.3 | |
CaO | 4.2 | 4.7 | 3.2 | 4.7 | 4.2 | 4.7 | 3.7 | 4.7 | 3.7 | 4.2 | 4.7 | 2.7 | 4.7 | 3.7 | |
SrO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
BaO | 6.1 | 4.6 | 6.1 | 6.1 | 5.1 | 5.1 | 5.6 | 5.6 | 6.1 | 6.1 | 4.1 | 6.1 | 6.1 | 5.1 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 86.9 | 87.4 | 87.4 | 87.4 | 87.4 | 87.4 | 87.4 | 87.4 | 87.4 | 87.4 | 87.9 | 87.9 | 87.9 | 87.9 | |
[MgO]+[CaO]+[SrO]+[BaO] | 13.1 | 12.5 | 12.5 | 12.5 | 12.6 | 12.6 | 12.6 | 12.6 | 12.6 | 12.6 | 12.0 | 12.0 | 12.0 | 12.1 | |
[SrO]+[BaO] | 6.1 | 4.6 | 6.1 | 6.1 | 5.1 | 5.1 | 5.6 | 5.6 | 6.1 | 6.1 | 4.1 | 6.1 | 6.1 | 5.1 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 4.7 | 6.2 | 6.2 | 4.8 | 6.2 | 5.7 | 6.2 | 5.2 | 5.7 | 5.2 | 7.2 | 7.2 | 5.3 | 7.2 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 400.5 | 386.8 | 408.8 | 401.4 | 394.3 | 392.0 | 401.8 | 397.0 | 406.5 | 404.0 | 385.8 | 415.3 | 405.4 | 400.8 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1813.2 | 1814.8 | 1816.1 | 1817.9 | 1815.7 | 1816.3 | 1816.2 | 1817.3 | 1817.2 | 1817.8 | 1818.9 | 1820.6 | 1823.0 | 1820.2 | |
熱膨脹係數(10-7 /℃) | 36.7 | 34.7 | 35.5 | 36.6 | 34.9 | 35.3 | 35.2 | 35.9 | 35.8 | 36.2 | 33.6 | 34.7 | 36.1 | 34.2 | |
密度(g/cm3 ) | 2.666 | 2.622 | 2.662 | 2.665 | 2.635 | 2.636 | 2.649 | 2.651 | 2.663 | 2.664 | 2.605 | 2.659 | 2.664 | 2.633 | |
應變點(℃) | 792 | 791 | 794 | 800 | 792 | 794 | 793 | 797 | 796 | 798 | 794 | 798 | 806 | 795 | |
緩冷點(℃) | 852 | 848 | 853 | 860 | 849 | 851 | 851 | 856 | 855 | 857 | 848 | 854 | 865 | 850 | |
軟化點(℃) | 1104 | 1102 | 1109 | 1114 | 1104 | 1106 | 1106 | 1110 | 1110 | 1112 | 1106 | 1114 | 1119 | 1110 | |
104.5 dPa·s(℃) | 1426 | 1417 | 1427 | 1432 | 1421 | 1422 | 1424 | 1427 | 1429 | 1430 | 1416 | 1428 | 1437 | 1422 | |
104.0 dPa·s(℃) | 1588 | 1582 | 1593 | 1596 | 1585 | 1586 | 1589 | 1591 | 1594 | 1595 | 1585 | 1601 | 1603 | 1593 | |
103.0 dPa·s(℃) | 1686 | 1672 | 1683 | 1690 | 1675 | 1678 | 1679 | 1684 | 1685 | 1687 | 1666 | 1681 | 1691 | 1673 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 83.0 | 84.4 | 83.5 | 82.8 | 84.1 | 83.9 | 83.8 | 83.4 | 83.3 | 83.1 | 85.0 | 83.8 | 82.9 | 84.4 | |
比楊氏模量(GPa/g·cm-3 ) | 31.1 | 32.2 | 31.4 | 31.1 | 31.9 | 31.8 | 31.6 | 31.5 | 31.3 | 31.2 | 32.6 | 31.5 | 31.1 | 32.1 | |
β-OH(mm-1 ) | 0.08 | 0.03 | 0.08 | 0.03 | 0.04 | 0.09 | 0.15 | 0.15 | 0.04 | 0.11 | 0.05 | 0.07 | 0.06 | 0.03 |
[表26]
No.351 | No.352 | No.353 | No.354 | No.355 | No.356 | No.357 | No.358 | No.359 | No.360 | No.361 | No.362 | No.363 | No.364 | ||
莫耳% | SiO2 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 |
Al2 O3 | 16.0 | 16.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 2.3 | 2.3 | 10.0 | 10.0 | 10.0 | 8.0 | 8.0 | 8.0 | 6.0 | 6.0 | 6.0 | 6.0 | 6.0 | 6.0 | |
CaO | 4.7 | 3.7 | 4.0 | 0.0 | 0.0 | 6.0 | 0.0 | 0.0 | 8.0 | 0.0 | 0.0 | 4.0 | 4.0 | 0.0 | |
SrO | 0.0 | 0.0 | 0.0 | 4.0 | 0.0 | 0.0 | 6.0 | 0.0 | 0.0 | 8.0 | 0.0 | 4.0 | 0.0 | 4.0 | |
BaO | 5.1 | 6.1 | 0.0 | 0.0 | 4.0 | 0.0 | 0.0 | 6.0 | 0.0 | 0.0 | 8.0 | 0.0 | 4.0 | 4.0 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 87.9 | 87.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | |
[MgO]+[CaO]+[SrO]+[BaO] | 12.1 | 12.1 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | |
[SrO]+[BaO] | 5.1 | 6.1 | 0.0 | 4.0 | 4.0 | 0.0 | 6.0 | 6.0 | 0.0 | 8.0 | 8.0 | 4.0 | 4.0 | 8.0 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | - | 0.0 | 0.0 | - | 0.0 | 0.0 | - | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 6.2 | 6.2 | 10.0 | 10.0 | 10.0 | 8.0 | 8.0 | 8.0 | 6.0 | 6.0 | 6.0 | 6.0 | 6.0 | 6.0 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 396.0 | 410.5 | 331.9 | 383.9 | 391.9 | 321.9 | 399.9 | 411.9 | 311.9 | 415.9 | 431.9 | 363.9 | 371.9 | 423.9 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1821.4 | 1822.3 | 1788.6 | 1794.2 | 1792.2 | 1791.0 | 1799.4 | 1796.4 | 1793.4 | 1804.6 | 1800.6 | 1799.0 | 1797.0 | 1802.6 | |
熱膨脹係數(10-7 /℃) | 34.9 | 35.4 | 30.1 | 31.2 | 31.9 | 31.3 | 33.1 | 34.4 | 32.6 | 35.2 | 37.0 | 33.9 | 34.7 | 36.1 | |
密度(g/cm3 ) | 2.635 | 2.661 | 2.488 | 2.541 | 2.597 | 2.493 | 2.572 | 2.657 | 2.497 | 2.603 | 2.717 | 2.550 | 2.606 | 2.660 | |
應變點(℃) | 800 | 802 | 771 | 780 | 782 | 770 | 778 | 780 | 773 | 780 | 779 | 774 | 773 | 779 | |
緩冷點(℃) | 856 | 859 | 830 | 836 | 839 | 828 | 837 | 841 | 831 | 841 | 847 | 834 | 833 | 843 | |
軟化點(℃) | 1113 | 1116 | 1048 | 1057 | 1063 | 1053 | 1065 | 1077 | 1058 | 1076 | 1093 | 1066 | 1069 | 1084 | |
104.5 dPa·s(℃) | 1426 | 1433 | 1358 | 1370 | 1381 | 1364 | 1385 | 1402 | 1370 | 1399 | 1422 | 1385 | 1396 | 1411 | |
104.0 dPa·s(℃) | 1594 | 1601 | 1517 | 1534 | 1546 | 1521 | 1548 | 1566 | 1527 | 1563 | 1587 | 1544 | 1557 | 1575 | |
103.0 dPa·s(℃) | 1678 | 1685 | 1613 | 1629 | 1641 | 1619 | 1646 | 1664 | 1626 | 1664 | 1689 | 1645 | 1658 | 1677 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 84.0 | 83.4 | 89.5 | 88.2 | 87.0 | 88.6 | 86.6 | 84.8 | 87.7 | 85.0 | 82.6 | 86.3 | 85.1 | 83.8 | |
比楊氏模量(GPa/g·cm-3 ) | 31.9 | 31.3 | 36.0 | 34.7 | 33.5 | 35.5 | 33.7 | 31.9 | 35.1 | 32.7 | 30.4 | 33.9 | 32.7 | 31.5 | |
β-OH(mm-1 ) | 0.11 | 0.11 | 0.12 | 0.14 | 0.12 | 0.04 | 0.04 | 0.08 | 0.08 | 0.15 | 0.11 | 0.05 | 0.04 | 0.09 |
[表27]
No.365 | No.366 | No.367 | No.368 | No.369 | No.370 | No.371 | No.372 | No.373 | No.374 | No.375 | No.376 | No.377 | No.378 | ||
莫耳% | SiO2 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 |
Al2 O3 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 6.0 | 6.0 | 6.0 | 6.0 | 6.0 | 6.0 | 4.0 | 4.0 | 4.0 | 4.0 | 4.0 | 4.0 | 4.0 | 4.0 | |
CaO | 6.0 | 6.0 | 2.0 | 2.0 | 0.0 | 0.0 | 10.0 | 0.0 | 0.0 | 8.0 | 8.0 | 6.0 | 6.0 | 6.0 | |
SrO | 2.0 | 0.0 | 6.0 | 0.0 | 2.0 | 6.0 | 0.0 | 10.0 | 0.0 | 2.0 | 0.0 | 4.0 | 0.0 | 2.0 | |
BaO | 0.0 | 2.0 | 0.0 | 6.0 | 6.0 | 2.0 | 0.0 | 0.0 | 10.0 | 0.0 | 2.0 | 0.0 | 4.0 | 2.0 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | |
[MgO]+[CaO]+[SrO]+[BaO] | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | |
[SrO]+[BaO] | 2.0 | 2.0 | 6.0 | 6.0 | 8.0 | 8.0 | 0.0 | 10.0 | 10.0 | 2.0 | 2.0 | 4.0 | 4.0 | 4.0 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | - | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 6.0 | 6.0 | 6.0 | 6.0 | 6.0 | 6.0 | 4.0 | 4.0 | 4.0 | 4.0 | 4.0 | 4.0 | 4.0 | 4.0 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 337.9 | 341.9 | 389.9 | 401.9 | 427.9 | 419.9 | 301.9 | 431.9 | 451.9 | 327.9 | 331.9 | 353.9 | 361.9 | 357.9 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1796.2 | 1795.2 | 1801.8 | 1798.8 | 1801.6 | 1803.6 | 1795.8 | 1809.8 | 1804.8 | 1798.6 | 1797.6 | 1801.4 | 1799.4 | 1800.4 | |
熱膨脹係數(10-7 /℃) | 33.3 | 33.7 | 34.6 | 35.8 | 36.5 | 35.7 | 34.0 | 37.4 | 39.7 | 34.7 | 35.1 | 35.4 | 36.2 | 35.8 | |
密度(g/cm3 ) | 2.524 | 2.552 | 2.576 | 2.661 | 2.688 | 2.631 | 2.502 | 2.634 | 2.776 | 2.528 | 2.556 | 2.554 | 2.611 | 2.583 | |
應變點(℃) | 773 | 772 | 776 | 776 | 779 | 780 | 781 | 788 | 785 | 779 | 778 | 779 | 777 | 778 | |
緩冷點(℃) | 832 | 830 | 837 | 839 | 845 | 842 | 838 | 849 | 855 | 838 | 836 | 839 | 837 | 837 | |
軟化點(℃) | 1062 | 1063 | 1070 | 1080 | 1089 | 1080 | 1064 | 1090 | 1111 | 1068 | 1069 | 1072 | 1075 | 1074 | |
104.5 dPa·s(℃) | 1377 | 1383 | 1392 | 1409 | 1416 | 1405 | 1375 | 1413 | 1440 | 1383 | 1389 | 1391 | 1402 | 1396 | |
104.0 dPa·s(℃) | 1535 | 1541 | 1553 | 1572 | 1581 | 1569 | 1533 | 1578 | 1609 | 1541 | 1547 | 1550 | 1563 | 1556 | |
103.0 dPa·s(℃) | 1636 | 1642 | 1654 | 1673 | 1683 | 1670 | 1634 | 1681 | 1712 | 1643 | 1650 | 1653 | 1666 | 1659 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 87.0 | 86.4 | 85.7 | 83.9 | 83.2 | 84.4 | 86.7 | 83.4 | 80.4 | 86.1 | 85.5 | 85.4 | 84.2 | 84.8 | |
比楊氏模量(GPa/g·cm-3 ) | 34.5 | 33.9 | 33.2 | 31.5 | 30.9 | 32.1 | 34.7 | 31.7 | 29.0 | 34.0 | 33.4 | 33.4 | 32.2 | 32.8 | |
β-OH(mm-1 ) | 0.14 | 0.03 | 0.15 | 0.12 | 0.05 | 0.07 | 0.11 | 0.06 | 0.07 | 0.05 | 0.04 | 0.03 | 0.05 | 0.15 |
[表28]
No.379 | No.380 | No.381 | No.382 | No.383 | No.384 | No.385 | No.386 | No.387 | No.388 | No.389 | No.390 | No.391 | No.392 | ||
莫耳% | SiO2 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 |
Al2 O3 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 4.0 | 4.0 | 4.0 | 4.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | |
CaO | 4.0 | 4.0 | 4.0 | 4.0 | 10.0 | 10.0 | 8.0 | 8.0 | 8.0 | 6.0 | 6.0 | 6.0 | 6.0 | 4.0 | |
SrO | 6.0 | 0.0 | 2.0 | 4.0 | 2.0 | 0.0 | 4.0 | 0.0 | 2.0 | 6.0 | 0.0 | 2.0 | 4.0 | 8.0 | |
BaO | 0.0 | 6.0 | 4.0 | 2.0 | 0.0 | 2.0 | 0.0 | 4.0 | 2.0 | 0.0 | 6.0 | 4.0 | 2.0 | 0.0 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | |
[MgO]+[CaO]+[SrO]+[BaO] | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | |
[SrO]+[BaO] | 6.0 | 6.0 | 6.0 | 6.0 | 2.0 | 2.0 | 4.0 | 4.0 | 4.0 | 6.0 | 6.0 | 6.0 | 6.0 | 8.0 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 4.0 | 4.0 | 4.0 | 4.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 379.9 | 391.9 | 387.9 | 383.9 | 317.9 | 321.9 | 343.9 | 351.9 | 347.9 | 369.9 | 381.9 | 377.9 | 373.9 | 395.9 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1804.2 | 1801.2 | 1802.2 | 1803.2 | 1801.0 | 1800.0 | 1803.8 | 1801.8 | 1802.8 | 1806.6 | 1803.6 | 1804.6 | 1805.6 | 1809.4 | |
熱膨脹係數(10-7 /℃) | 36.0 | 37.4 | 36.9 | 36.5 | 36.2 | 36.6 | 36.9 | 37.8 | 37.3 | 37.6 | 38.9 | 38.5 | 38.0 | 38.3 | |
密度(g/cm3 ) | 2.581 | 2.666 | 2.638 | 2.609 | 2.533 | 2.561 | 2.559 | 2.616 | 2.587 | 2.586 | 2.671 | 2.642 | 2.614 | 2.612 | |
應變點(℃) | 780 | 778 | 779 | 780 | 788 | 786 | 787 | 785 | 786 | 788 | 786 | 786 | 787 | 791 | |
緩冷點(℃) | 841 | 841 | 840 | 841 | 847 | 845 | 848 | 844 | 846 | 850 | 847 | 847 | 848 | 852 | |
軟化點(℃) | 1077 | 1084 | 1081 | 1079 | 1076 | 1077 | 1081 | 1083 | 1082 | 1085 | 1091 | 1089 | 1087 | 1091 | |
104.5 dPa·s(℃) | 1398 | 1415 | 1409 | 1404 | 1388 | 1393 | 1396 | 1406 | 1401 | 1403 | 1418 | 1413 | 1408 | 1411 | |
104.0 dPa·s(℃) | 1559 | 1578 | 1572 | 1565 | 1548 | 1554 | 1556 | 1569 | 1563 | 1565 | 1584 | 1578 | 1572 | 1574 | |
103.0 dPa·s(℃) | 1662 | 1682 | 1675 | 1669 | 1650 | 1657 | 1660 | 1673 | 1666 | 1669 | 1688 | 1682 | 1676 | 1679 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 84.7 | 82.9 | 83.5 | 84.1 | 85.2 | 84.6 | 84.5 | 83.3 | 83.9 | 83.8 | 82.0 | 82.6 | 83.2 | 83.2 | |
比楊氏模量(GPa/g·cm-3 ) | 32.8 | 31.1 | 31.7 | 32.2 | 33.6 | 33.0 | 33.0 | 31.8 | 32.4 | 32.4 | 30.7 | 31.3 | 31.8 | 31.8 | |
β-OH(mm-1 ) | 0.06 | 0.13 | 0.12 | 0.06 | 0.13 | 0.13 | 0.15 | 0.11 | 0.09 | 0.05 | 0.12 | 0.14 | 0.10 | 0.06 |
[表29]
No.393 | No.394 | No.395 | No.396 | No.397 | No.398 | No.399 | No.400 | No.401 | No.402 | No.403 | No.404 | No.405 | No.406 | ||
莫耳% | SiO2 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 | 71.9 |
Al2 O3 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
CaO | 4.0 | 4.0 | 4.0 | 4.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SrO | 0.0 | 6.0 | 4.0 | 2.0 | 10.0 | 0.0 | 8.0 | 6.0 | 4.0 | 2.0 | 10.0 | 8.0 | 6.0 | 4.0 | |
BaO | 8.0 | 2.0 | 4.0 | 6.0 | 0.0 | 10.0 | 2.0 | 4.0 | 6.0 | 8.0 | 4.0 | 6.0 | 8.0 | 10.0 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | 85.9 | |
[MgO]+[CaO]+[SrO]+[BaO] | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | |
[SrO]+[BaO] | 8.0 | 8.0 | 8.0 | 8.0 | 10.0 | 10.0 | 10.0 | 10.0 | 10.0 | 10.0 | 14.0 | 14.0 | 14.0 | 14.0 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 411.9 | 399.9 | 403.9 | 407.9 | 421.9 | 441.9 | 425.9 | 429.9 | 433.9 | 437.9 | 471.9 | 475.9 | 479.9 | 483.9 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1805.4 | 1808.4 | 1807.4 | 1806.4 | 1812.2 | 1807.2 | 1811.2 | 1810.2 | 1809.2 | 1808.2 | 1818.2 | 1817.2 | 1816.2 | 1815.2 | |
熱膨脹係數(10-7 /℃) | 40.1 | 38.7 | 39.2 | 39.6 | 39.0 | 41.2 | 39.5 | 39.9 | 40.4 | 40.8 | 42.9 | 43.4 | 43.8 | 44.3 | |
密度(g/cm3 ) | 2.726 | 2.640 | 2.669 | 2.697 | 2.639 | 2.781 | 2.667 | 2.696 | 2.724 | 2.752 | 2.753 | 2.782 | 2.810 | 2.838 | |
應變點(℃) | 789 | 791 | 790 | 789 | 796 | 793 | 795 | 795 | 794 | 794 | 817 | 816 | 816 | 816 | |
緩冷點(℃) | 852 | 852 | 851 | 852 | 856 | 859 | 856 | 856 | 857 | 858 | 876 | 877 | 878 | 879 | |
軟化點(℃) | 1103 | 1093 | 1096 | 1099 | 1097 | 1117 | 1100 | 1104 | 1109 | 1113 | 1123 | 1127 | 1130 | 1132 | |
104.5 dPa·s(℃) | 1431 | 1416 | 1421 | 1426 | 1419 | 1443 | 1424 | 1429 | 1434 | 1438 | 1445 | 1449 | 1453 | 1457 | |
104.0 dPa·s(℃) | 1599 | 1581 | 1587 | 1593 | 1584 | 1615 | 1590 | 1596 | 1602 | 1609 | 1621 | 1627 | 1633 | 1639 | |
103.0 dPa·s(℃) | 1703 | 1685 | 1691 | 1697 | 1688 | 1717 | 1694 | 1700 | 1706 | 1712 | 1720 | 1725 | 1730 | 1735 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 80.8 | 82.6 | 82.0 | 81.4 | 82.5 | 79.5 | 81.9 | 81.3 | 80.7 | 80.1 | 79.0 | 78.4 | 77.8 | 77.2 | |
比楊氏模量(GPa/g·cm-3 ) | 29.6 | 31.3 | 30.7 | 30.2 | 31.3 | 28.6 | 30.7 | 30.2 | 29.6 | 29.1 | 28.7 | 28.2 | 27.7 | 27.2 | |
β-OH(mm-1 ) | 0.12 | 0.04 | 0.04 | 0.14 | 0.07 | 0.08 | 0.15 | 0.07 | 0.15 | 0.05 | 0.05 | 0.05 | 0.05 | 0.14 |
[表30]
No.407 | No.408 | No.409 | No.410 | No.411 | No.412 | No.413 | No.414 | No.415 | No.416 | No.417 | No.418 | No.419 | No.420 | ||
莫耳% | SiO2 | 71.7 | 71.5 | 71.3 | 71.1 | 70.9 | 70.7 | 70.5 | 70.3 | 70.1 | 69.9 | 69.7 | 69.5 | 69.3 | 69.1 |
Al2 O3 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | |
B2 O3 | 0.2 | 0.4 | 0.6 | 0.8 | 1.0 | 1.2 | 1.4 | 1.6 | 1.8 | 2.0 | 2.2 | 2.4 | 2.6 | 2.8 | |
MgO | 3.3 | 3.3 | 3.3 | 3.3 | 3.3 | 3.3 | 3.3 | 3.3 | 3.3 | 3.3 | 3.3 | 3.3 | 3.3 | 3.3 | |
CaO | 4.7 | 4.7 | 4.7 | 4.7 | 4.7 | 4.7 | 4.7 | 4.7 | 4.7 | 4.7 | 4.7 | 4.7 | 4.7 | 4.7 | |
SrO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
BaO | 6.1 | 6.1 | 6.1 | 6.1 | 6.1 | 6.1 | 6.1 | 6.1 | 6.1 | 6.1 | 6.1 | 6.1 | 6.1 | 6.1 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 85.7 | 85.5 | 85.3 | 85.1 | 84.9 | 84.7 | 84.5 | 84.3 | 84.1 | 83.9 | 83.7 | 83.5 | 83.3 | 83.1 | |
[MgO]+[CaO]+[SrO]+[BaO] | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | 14.0 | |
[SrO]+[BaO] | 6.1 | 6.1 | 6.1 | 6.1 | 6.1 | 6.1 | 6.1 | 6.1 | 6.1 | 6.1 | 6.1 | 6.1 | 6.1 | 6.1 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.1 | 0.1 | 0.1 | 0.2 | 0.2 | 0.2 | 0.3 | 0.3 | 0.3 | 0.4 | 0.4 | 0.4 | 0.5 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 3.5 | 3.7 | 3.9 | 4.1 | 4.3 | 4.5 | 4.7 | 4.9 | 5.1 | 5.3 | 5.5 | 5.7 | 5.9 | 6.1 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 386.0 | 382.8 | 379.6 | 376.4 | 373.2 | 370.0 | 366.8 | 363.6 | 360.4 | 357.2 | 354.0 | 350.8 | 347.6 | 344.4 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1799.3 | 1796.5 | 1793.7 | 1790.9 | 1788.1 | 1785.2 | 1782.4 | 1779.6 | 1776.8 | 1774.0 | 1771.1 | 1768.3 | 1765.5 | 1762.7 | |
熱膨脹係數(10-7 /℃) | 38.0 | 38.0 | 38.1 | 38.1 | 38.1 | 38.2 | 38.2 | 38.2 | 38.3 | 38.3 | 38.3 | 38.4 | 38.4 | 38.4 | |
密度(g/cm3 ) | 2.668 | 2.667 | 2.666 | 2.664 | 2.663 | 2.662 | 2.660 | 2.659 | 2.657 | 2.656 | 2.655 | 2.653 | 2.652 | 2.651 | |
應變點(℃) | 776 | 772 | 768 | 764 | 760 | 757 | 753 | 750 | 747 | 744 | 741 | 739 | 736 | 734 | |
緩冷點(℃) | 839 | 835 | 832 | 828 | 825 | 821 | 818 | 815 | 811 | 808 | 805 | 802 | 799 | 796 | |
軟化點(℃) | 1082 | 1078 | 1074 | 1070 | 1066 | 1063 | 1059 | 1056 | 1053 | 1050 | 1047 | 1043 | 1040 | 1036 | |
104.5 dPa·s(℃) | 1413 | 1410 | 1406 | 1403 | 1399 | 1396 | 1392 | 1389 | 1385 | 1382 | 1378 | 1374 | 1371 | 1367 | |
104.0 dPa·s(℃) | 1577 | 1573 | 1569 | 1565 | 1561 | 1557 | 1553 | 1549 | 1545 | 1541 | 1537 | 1533 | 1530 | 1526 | |
103.0 dPa·s(℃) | 1682 | 1678 | 1675 | 1671 | 1668 | 1664 | 1660 | 1656 | 1652 | 1648 | 1644 | 1640 | 1636 | 1632 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 82.4 | 82.2 | 82.0 | 81.8 | 81.6 | 81.4 | 81.2 | 81.0 | 80.8 | 80.6 | 80.5 | 80.3 | 80.1 | 79.9 | |
比楊氏模量(GPa/g·cm-3 ) | 30.9 | 30.8 | 30.8 | 30.7 | 30.6 | 30.6 | 30.5 | 30.5 | 30.4 | 30.4 | 30.3 | 30.2 | 30.2 | 30.1 | |
β-OH(mm-1 ) | 0.12 | 0.03 | 0.10 | 0.11 | 0.08 | 0.10 | 0.05 | 0.13 | 0.04 | 0.10 | 0.04 | 0.05 | 0.07 | 0.12 |
[表31]
No.421 | No.422 | No.423 | No.424 | No.425 | No.426 | No.427 | No.428 | No.429 | No.430 | No.431 | No.432 | No.433 | No.434 | ||
莫耳% | SiO2 | 68.9 | 68.9 | 69.4 | 69.9 | 70.4 | 70.9 | 71.4 | 72.4 | 72.9 | 73.4 | 73.9 | 74.4 | 74.9 | 73.6 |
Al2 O3 | 14.0 | 15.5 | 15.3 | 15.0 | 14.8 | 14.5 | 14.3 | 13.8 | 13.5 | 13.3 | 13.0 | 12.8 | 12.5 | 12.0 | |
B2 O3 | 3.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 3.3 | 3.6 | 3.6 | 3.5 | 3.4 | 3.4 | 3.3 | 3.2 | 3.2 | 3.1 | 3.0 | 3.0 | 2.9 | 3.3 | |
CaO | 4.7 | 5.2 | 5.1 | 5.0 | 4.9 | 4.8 | 4.8 | 4.6 | 4.5 | 4.4 | 4.3 | 4.3 | 4.2 | 4.8 | |
SrO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
BaO | 6.1 | 6.7 | 6.6 | 6.5 | 6.4 | 6.3 | 6.2 | 6.0 | 5.9 | 5.7 | 5.6 | 5.5 | 5.4 | 6.2 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 82.9 | 84.4 | 84.7 | 84.9 | 85.2 | 85.4 | 85.7 | 86.2 | 86.4 | 86.7 | 86.9 | 87.2 | 87.4 | 85.6 | |
[MgO]+[CaO]+[SrO]+[BaO] | 14.0 | 15.5 | 15.3 | 15.0 | 14.8 | 14.5 | 14.3 | 13.8 | 13.5 | 13.3 | 13.0 | 12.8 | 12.5 | 14.3 | |
[SrO]+[BaO] | 6.1 | 6.7 | 6.6 | 6.5 | 6.4 | 6.3 | 6.2 | 6.0 | 5.9 | 5.7 | 5.6 | 5.5 | 5.4 | 6.2 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.5 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 6.3 | 3.6 | 3.6 | 3.5 | 3.4 | 3.4 | 3.3 | 3.2 | 3.2 | 3.1 | 3.0 | 3.0 | 2.9 | 1.0 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 341.2 | 420.2 | 415.1 | 409.9 | 404.7 | 399.6 | 394.4 | 384.1 | 378.9 | 373.7 | 368.6 | 363.4 | 358.2 | 365.7 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1759.9 | 1804.7 | 1804.3 | 1803.9 | 1803.4 | 1803.0 | 1802.6 | 1801.7 | 1801.3 | 1800.9 | 1800.5 | 1800.0 | 1799.6 | 1790.4 | |
熱膨脹係數(10-7 /℃) | 38.5 | 40.6 | 40.2 | 39.7 | 39.3 | 38.8 | 38.4 | 37.5 | 37.1 | 36.7 | 36.3 | 36.0 | 35.6 | 38.6 | |
密度(g/cm3 ) | 2.649 | 2.719 | 2.710 | 2.702 | 2.694 | 2.686 | 2.678 | 2.662 | 2.653 | 2.645 | 2.637 | 2.629 | 2.621 | 2.662 | |
應變點(℃) | 732 | 777 | 778 | 778 | 779 | 779 | 780 | 781 | 782 | 782 | 783 | 783 | 784 | 769 | |
緩冷點(℃) | 793 | 836 | 837 | 838 | 839 | 840 | 842 | 844 | 845 | 846 | 847 | 848 | 849 | 832 | |
軟化點(℃) | 1032 | 1066 | 1069 | 1072 | 1075 | 1079 | 1083 | 1092 | 1096 | 1101 | 1106 | 1111 | 1116 | 1085 | |
104.5 dPa·s(℃) | 1363 | 1383 | 1388 | 1394 | 1400 | 1406 | 1411 | 1422 | 1427 | 1433 | 1438 | 1443 | 1447 | 1422 | |
104.0 dPa·s(℃) | 1522 | 1536 | 1543 | 1551 | 1558 | 1565 | 1573 | 1588 | 1596 | 1604 | 1612 | 1620 | 1628 | 1601 | |
103.0 dPa·s(℃) | 1628 | 1635 | 1643 | 1652 | 1660 | 1668 | 1677 | 1693 | 1701 | 1708 | 1716 | 1723 | 1730 | 1707 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 79.7 | 83.9 | 83.6 | 83.4 | 83.2 | 83.0 | 82.8 | 82.3 | 82.1 | 81.9 | 81.7 | 81.5 | 81.3 | 81.0 | |
比楊氏模量(GPa/g·cm-3 ) | 30.1 | 30.8 | 30.9 | 30.9 | 30.9 | 30.9 | 30.9 | 30.9 | 31.0 | 31.0 | 31.0 | 31.0 | 31.0 | 30.4 | |
β-OH(mm-1 ) | 0.14 | 0.07 | 0.06 | 0.09 | 0.15 | 0.10 | 0.05 | 0.03 | 0.08 | 0.09 | 0.04 | 0.08 | 0.08 | 0.14 |
[表32]
No.435 | No.436 | No.437 | No.438 | No.439 | No.440 | No.441 | No.442 | No.443 | No.444 | No.445 | No.446 | No.447 | No.448 | ||
莫耳% | SiO2 | 73.2 | 72.7 | 72.3 | 71.1 | 70.6 | 70.2 | 69.8 | 69.4 | 71.8 | 71.6 | 71.5 | 71.3 | 71.2 | 71.0 |
Al2 O3 | 12.5 | 13.0 | 13.5 | 15.0 | 15.5 | 16.0 | 16.5 | 17.0 | 14.0 | 13.9 | 13.9 | 13.9 | 13.9 | 13.8 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.2 | 0.4 | 0.6 | 0.8 | 1.0 | 1.2 | |
MgO | 3.3 | 3.3 | 3.3 | 3.2 | 3.2 | 3.2 | 3.2 | 3.2 | 3.3 | 3.3 | 3.2 | 3.2 | 3.2 | 3.2 | |
CaO | 4.7 | 4.7 | 4.7 | 4.6 | 4.6 | 4.6 | 4.5 | 4.5 | 4.7 | 4.6 | 4.6 | 4.6 | 4.6 | 4.6 | |
SrO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
BaO | 6.2 | 6.1 | 6.1 | 6.0 | 6.0 | 5.9 | 5.9 | 5.9 | 6.1 | 6.0 | 6.0 | 6.0 | 6.0 | 6.0 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 85.7 | 85.7 | 85.8 | 86.1 | 86.1 | 86.2 | 86.3 | 86.4 | 85.7 | 85.6 | 85.4 | 85.2 | 85.0 | 84.9 | |
[MgO]+[CaO]+[SrO]+[BaO] | 14.2 | 14.2 | 14.1 | 13.8 | 13.8 | 13.7 | 13.6 | 13.5 | 14.0 | 13.9 | 13.9 | 13.9 | 13.9 | 13.8 | |
[SrO]+[BaO] | 6.2 | 6.1 | 6.1 | 6.0 | 6.0 | 5.9 | 5.9 | 5.9 | 6.1 | 6.0 | 6.0 | 6.0 | 6.0 | 6.0 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.1 | 0.1 | 0.1 | 0.2 | 0.2 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 1.6 | 2.1 | 2.7 | 4.4 | 5.0 | 5.5 | 6.1 | 6.6 | 3.5 | 3.7 | 3.8 | 4.0 | 4.2 | 4.4 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 371.6 | 377.5 | 383.4 | 401.0 | 406.9 | 412.7 | 418.6 | 424.5 | 385.5 | 381.7 | 377.9 | 374.1 | 370.3 | 366.6 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1793.3 | 1796.3 | 1799.2 | 1808.0 | 1811.0 | 1813.9 | 1816.9 | 1819.8 | 1799.3 | 1796.4 | 1793.6 | 1790.7 | 1787.8 | 1785.0 | |
熱膨脹係數(10-7 /℃) | 38.4 | 38.3 | 38.1 | 37.7 | 37.5 | 37.4 | 37.3 | 37.2 | 37.9 | 37.9 | 37.9 | 37.9 | 37.9 | 37.9 | |
密度(g/cm3 ) | 2.664 | 2.666 | 2.668 | 2.674 | 2.676 | 2.678 | 2.680 | 2.682 | 2.667 | 2.665 | 2.663 | 2.661 | 2.658 | 2.656 | |
應變點(℃) | 772 | 775 | 778 | 785 | 787 | 789 | 791 | 793 | 776 | 772 | 768 | 764 | 761 | 757 | |
緩冷點(℃) | 835 | 838 | 841 | 845 | 846 | 846 | 846 | 846 | 839 | 836 | 832 | 829 | 825 | 822 | |
軟化點(℃) | 1086 | 1086 | 1087 | 1088 | 1088 | 1088 | 1088 | 1088 | 1083 | 1079 | 1075 | 1071 | 1068 | 1065 | |
104.5 dPa·s(℃) | 1421 | 1420 | 1419 | 1411 | 1407 | 1403 | 1399 | 1395 | 1414 | 1411 | 1408 | 1405 | 1402 | 1399 | |
104.0 dPa·s(℃) | 1596 | 1591 | 1586 | 1570 | 1564 | 1559 | 1555 | 1550 | 1578 | 1574 | 1571 | 1568 | 1565 | 1562 | |
103.0 dPa·s(℃) | 1702 | 1697 | 1691 | 1670 | 1663 | 1655 | 1648 | 1640 | 1682 | 1680 | 1678 | 1675 | 1672 | 1670 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 81.4 | 81.8 | 82.2 | 83.4 | 83.8 | 84.2 | 84.6 | 85.0 | 82.3 | 82.1 | 81.9 | 81.7 | 81.5 | 81.3 | |
比楊氏模量(GPa/g·cm-3 ) | 30.5 | 30.7 | 30.8 | 31.2 | 31.3 | 31.4 | 31.6 | 31.7 | 30.9 | 30.8 | 30.8 | 30.7 | 30.7 | 30.6 | |
β-OH(mm-1 ) | 0.04 | 0.09 | 0.14 | 0.13 | 0.10 | 0.15 | 0.04 | 0.04 | 0.05 | 0.05 | 0.09 | 0.11 | 0.09 | 0.15 |
[表33]
No.449 | No.450 | No.451 | No.452 | No.453 | No.454 | No.455 | No.456 | No.457 | No.458 | No.459 | No.460 | No.461 | No.462 | ||
莫耳% | SiO2 | 70.9 | 70.7 | 70.6 | 70.5 | 70.3 | 70.2 | 70.0 | 69.9 | 69.7 | 74.1 | 73.7 | 73.4 | 73.0 | 72.6 |
Al2 O3 | 13.8 | 13.8 | 13.7 | 13.7 | 13.7 | 13.7 | 13.6 | 13.6 | 13.6 | 14.4 | 14.4 | 14.3 | 14.2 | 14.1 | |
B2 O3 | 1.4 | 1.6 | 1.8 | 2.0 | 2.2 | 2.4 | 2.6 | 2.8 | 3.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 3.2 | 3.2 | 3.2 | 3.2 | 3.2 | 3.2 | 3.2 | 3.2 | 3.2 | 0.3 | 0.8 | 1.3 | 1.8 | 2.3 | |
CaO | 4.6 | 4.6 | 4.6 | 4.6 | 4.6 | 4.6 | 4.5 | 4.5 | 4.5 | 4.8 | 4.8 | 4.8 | 4.7 | 4.7 | |
SrO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
BaO | 6.0 | 6.0 | 6.0 | 5.9 | 5.9 | 5.9 | 5.9 | 5.9 | 5.9 | 6.3 | 6.2 | 6.2 | 6.2 | 6.1 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 84.7 | 84.5 | 84.4 | 84.2 | 84.0 | 83.8 | 83.7 | 83.5 | 83.3 | 88.5 | 88.1 | 87.6 | 87.2 | 86.8 | |
[MgO]+[CaO]+[SrO]+[BaO] | 13.8 | 13.8 | 13.7 | 13.7 | 13.7 | 13.7 | 13.6 | 13.6 | 13.6 | 11.4 | 11.8 | 12.3 | 12.7 | 13.1 | |
[SrO]+[BaO] | 6.0 | 6.0 | 6.0 | 5.9 | 5.9 | 5.9 | 5.9 | 5.9 | 5.9 | 6.3 | 6.2 | 6.2 | 6.2 | 6.1 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.2 | 0.3 | 0.3 | 0.3 | 0.4 | 0.4 | 0.4 | 0.5 | 0.5 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 4.6 | 4.8 | 5.0 | 5.2 | 5.4 | 5.6 | 5.8 | 6.0 | 6.2 | 3.4 | 3.4 | 3.3 | 3.3 | 3.3 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 362.8 | 359.0 | 355.2 | 351.4 | 347.7 | 343.9 | 340.1 | 336.3 | 332.5 | 382.8 | 383.9 | 385.0 | 386.0 | 387.1 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1782.1 | 1779.2 | 1776.3 | 1773.5 | 1770.6 | 1767.7 | 1764.9 | 1762.0 | 1759.1 | 1817.9 | 1815.3 | 1812.6 | 1810.0 | 1807.3 | |
熱膨脹係數(10-7 /℃) | 37.9 | 37.8 | 37.8 | 37.8 | 37.8 | 37.8 | 37.8 | 37.8 | 37.7 | 36.0 | 36.3 | 36.6 | 37.0 | 37.3 | |
密度(g/cm3 ) | 2.654 | 2.652 | 2.649 | 2.647 | 2.645 | 2.642 | 2.640 | 2.638 | 2.636 | 2.651 | 2.654 | 2.657 | 2.660 | 2.663 | |
應變點(℃) | 754 | 750 | 747 | 744 | 741 | 739 | 736 | 734 | 732 | 809 | 805 | 801 | 795 | 790 | |
緩冷點(℃) | 819 | 815 | 812 | 809 | 806 | 803 | 800 | 797 | 794 | 876 | 870 | 864 | 858 | 853 | |
軟化點(℃) | 1062 | 1058 | 1055 | 1052 | 1049 | 1046 | 1043 | 1039 | 1036 | 1128 | 1125 | 1121 | 1115 | 1106 | |
104.5 dPa·s(℃) | 1396 | 1394 | 1391 | 1387 | 1384 | 1381 | 1378 | 1375 | 1372 | 1464 | 1456 | 1448 | 1440 | 1432 | |
104.0 dPa·s(℃) | 1559 | 1556 | 1553 | 1550 | 1547 | 1543 | 1540 | 1537 | 1534 | 1642 | 1631 | 1620 | 1610 | 1600 | |
103.0 dPa·s(℃) | 1667 | 1664 | 1661 | 1658 | 1654 | 1651 | 1648 | 1645 | 1641 | 1735 | 1727 | 1719 | 1710 | 1702 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 81.0 | 80.8 | 80.6 | 80.4 | 80.2 | 80.0 | 79.8 | 79.5 | 79.3 | 80.8 | 81.1 | 81.4 | 81.7 | 82.0 | |
比楊氏模量(GPa/g·cm-3 ) | 30.5 | 30.5 | 30.4 | 30.4 | 30.3 | 30.3 | 30.2 | 30.2 | 30.1 | 30.5 | 30.6 | 30.6 | 30.7 | 30.8 | |
β-OH(mm-1 ) | 0.05 | 0.11 | 0.08 | 0.15 | 0.13 | 0.13 | 0.15 | 0.05 | 0.07 | 0.12 | 0.07 | 0.06 | 0.12 | 0.07 |
[表34]
No.463 | No.464 | No.465 | No.466 | No.467 | No.468 | No.469 | No.470 | No.471 | No.472 | No.473 | No.474 | No.475 | No.476 | ||
莫耳% | SiO2 | 72.2 | 71.5 | 71.1 | 70.8 | 70.4 | 70.0 | 69.6 | 74.1 | 73.8 | 73.4 | 73.0 | 72.6 | 72.3 | 71.5 |
Al2 O3 | 14.1 | 13.9 | 13.9 | 13.8 | 13.7 | 13.6 | 13.6 | 14.4 | 14.4 | 14.3 | 14.2 | 14.1 | 14.1 | 13.9 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 2.8 | 3.8 | 4.3 | 4.8 | 5.3 | 5.8 | 6.3 | 3.4 | 3.4 | 3.3 | 3.3 | 3.3 | 3.3 | 3.2 | |
CaO | 4.7 | 4.6 | 4.6 | 4.6 | 4.6 | 4.5 | 4.5 | 1.7 | 2.2 | 2.7 | 3.2 | 3.7 | 4.2 | 5.2 | |
SrO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
BaO | 6.1 | 6.0 | 6.0 | 6.0 | 5.9 | 5.9 | 5.9 | 6.3 | 6.2 | 6.2 | 6.2 | 6.1 | 6.1 | 6.0 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 86.3 | 85.4 | 85.0 | 84.5 | 84.1 | 83.6 | 83.2 | 88.6 | 88.1 | 87.7 | 87.2 | 86.8 | 86.3 | 85.4 | |
[MgO]+[CaO]+[SrO]+[BaO] | 13.6 | 14.5 | 14.9 | 15.4 | 15.8 | 16.3 | 16.7 | 11.3 | 11.8 | 12.2 | 12.7 | 13.1 | 13.6 | 14.5 | |
[SrO]+[BaO] | 6.1 | 6.0 | 6.0 | 6.0 | 5.9 | 5.9 | 5.9 | 6.3 | 6.2 | 6.2 | 6.2 | 6.1 | 6.1 | 6.0 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 3.3 | 3.2 | 3.2 | 3.2 | 3.2 | 3.2 | 3.2 | 6.5 | 5.9 | 5.4 | 4.9 | 4.3 | 3.8 | 2.7 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 388.2 | 390.4 | 391.5 | 392.6 | 393.7 | 394.7 | 395.8 | 398.2 | 396.7 | 395.2 | 393.7 | 392.2 | 390.7 | 387.6 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1804.6 | 1799.3 | 1796.7 | 1794.0 | 1791.4 | 1788.7 | 1786.0 | 1814.4 | 1812.4 | 1810.3 | 1808.2 | 1806.2 | 1804.1 | 1800.0 | |
熱膨脹係數(10-7 /℃) | 37.6 | 38.3 | 38.7 | 39.0 | 39.4 | 39.7 | 40.1 | 33.7 | 34.4 | 35.1 | 35.8 | 36.5 | 37.3 | 38.8 | |
密度(g/cm3 ) | 2.667 | 2.673 | 2.676 | 2.680 | 2.683 | 2.686 | 2.689 | 2.643 | 2.648 | 2.652 | 2.657 | 2.661 | 2.666 | 2.675 | |
應變點(℃) | 785 | 776 | 772 | 769 | 766 | 764 | 762 | 798 | 795 | 792 | 789 | 786 | 783 | 777 | |
緩冷點(℃) | 847 | 838 | 833 | 829 | 825 | 822 | 819 | 861 | 858 | 856 | 852 | 849 | 846 | 839 | |
軟化點(℃) | 1096 | 1078 | 1071 | 1065 | 1060 | 1056 | 1052 | 1128 | 1124 | 1118 | 1111 | 1103 | 1095 | 1079 | |
104.5 dPa·s(℃) | 1424 | 1408 | 1400 | 1391 | 1383 | 1374 | 1366 | 1457 | 1450 | 1444 | 1437 | 1430 | 1423 | 1409 | |
104.0 dPa·s(℃) | 1590 | 1571 | 1561 | 1552 | 1543 | 1534 | 1525 | 1637 | 1626 | 1616 | 1606 | 1597 | 1588 | 1572 | |
103.0 dPa·s(℃) | 1693 | 1675 | 1665 | 1656 | 1646 | 1636 | 1626 | 1721 | 1716 | 1710 | 1705 | 1698 | 1691 | 1677 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 82.3 | 82.9 | 83.2 | 83.5 | 83.7 | 84.0 | 84.3 | 82.2 | 82.3 | 82.4 | 82.4 | 82.5 | 82.5 | 82.6 | |
比楊氏模量(GPa/g·cm-3 ) | 30.9 | 31.0 | 31.1 | 31.1 | 31.2 | 31.3 | 31.4 | 31.1 | 31.1 | 31.1 | 31.0 | 31.0 | 31.0 | 30.9 | |
β-OH(mm-1 ) | 0.10 | 0.06 | 0.05 | 0.03 | 0.14 | 0.11 | 0.04 | 0.06 | 0.10 | 0.15 | 0.05 | 0.05 | 0.11 | 0.13 |
[表35]
No.477 | No.478 | No.479 | No.480 | No.481 | No.482 | No.483 | No.484 | No.485 | No.486 | No.487 | No.488 | No.489 | No.490 | ||
莫耳% | SiO2 | 71.1 | 70.7 | 70.4 | 70.0 | 69.6 | 71.8 | 71.6 | 71.5 | 71.3 | 71.2 | 71.0 | 70.9 | 70.7 | 70.6 |
Al2 O3 | 13.8 | 13.8 | 13.7 | 13.6 | 13.6 | 14.0 | 13.9 | 13.9 | 13.9 | 13.9 | 13.8 | 13.8 | 13.8 | 13.7 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 3.2 | 3.2 | 3.2 | 3.2 | 3.2 | 3.3 | 3.3 | 3.2 | 3.2 | 3.2 | 3.2 | 3.2 | 3.2 | 3.2 | |
CaO | 5.7 | 6.2 | 6.7 | 7.2 | 7.7 | 4.7 | 4.6 | 4.6 | 4.6 | 4.6 | 4.6 | 4.6 | 4.6 | 4.6 | |
SrO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.2 | 0.4 | 0.6 | 0.8 | 1.0 | 1.2 | 1.4 | 1.6 | 1.8 | |
BaO | 6.0 | 6.0 | 5.9 | 5.9 | 5.9 | 6.1 | 6.0 | 6.0 | 6.0 | 6.0 | 6.0 | 6.0 | 6.0 | 6.0 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 85.0 | 84.5 | 84.1 | 83.6 | 83.2 | 85.7 | 85.6 | 85.4 | 85.2 | 85.0 | 84.9 | 84.7 | 84.5 | 84.4 | |
[MgO]+[CaO]+[SrO]+[BaO] | 14.9 | 15.4 | 15.8 | 16.3 | 16.7 | 14.2 | 14.3 | 14.5 | 14.7 | 14.9 | 15.0 | 15.2 | 15.4 | 15.5 | |
[SrO]+[BaO] | 6.0 | 6.0 | 5.9 | 5.9 | 5.9 | 6.3 | 6.4 | 6.6 | 6.8 | 7.0 | 7.2 | 7.4 | 7.6 | 7.8 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 2.1 | 1.6 | 1.1 | 0.5 | 0.0 | 3.1 | 2.9 | 2.6 | 2.4 | 2.2 | 2.0 | 1.8 | 1.6 | 1.4 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 386.1 | 384.6 | 383.1 | 381.5 | 380.0 | 391.3 | 393.3 | 395.3 | 397.3 | 399.3 | 401.4 | 403.4 | 405.4 | 407.4 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1797.9 | 1795.8 | 1793.8 | 1791.7 | 1789.6 | 1801.7 | 1801.1 | 1800.6 | 1800.1 | 1799.6 | 1799.1 | 1798.6 | 1798.1 | 1797.6 | |
熱膨脹係數(10-7 /℃) | 39.5 | 40.3 | 41.1 | 41.9 | 42.6 | 38.3 | 38.7 | 39.0 | 39.4 | 39.8 | 40.1 | 40.5 | 40.9 | 41.2 | |
密度(g/cm3 ) | 2.679 | 2.684 | 2.688 | 2.693 | 2.697 | 2.674 | 2.678 | 2.683 | 2.687 | 2.692 | 2.696 | 2.700 | 2.705 | 2.709 | |
應變點(℃) | 774 | 771 | 769 | 766 | 762 | 780 | 779 | 778 | 777 | 776 | 775 | 774 | 773 | 772 | |
緩冷點(℃) | 835 | 831 | 828 | 824 | 820 | 842 | 841 | 840 | 839 | 838 | 837 | 835 | 834 | 833 | |
軟化點(℃) | 1072 | 1066 | 1061 | 1056 | 1052 | 1085 | 1083 | 1081 | 1079 | 1077 | 1075 | 1073 | 1071 | 1069 | |
104.5 dPa·s(℃) | 1401 | 1394 | 1386 | 1378 | 1370 | 1415 | 1413 | 1411 | 1409 | 1406 | 1404 | 1402 | 1400 | 1398 | |
104.0 dPa·s(℃) | 1564 | 1556 | 1547 | 1538 | 1529 | 1579 | 1576 | 1574 | 1572 | 1570 | 1568 | 1565 | 1563 | 1560 | |
103.0 dPa·s(℃) | 1669 | 1660 | 1652 | 1643 | 1634 | 1683 | 1681 | 1679 | 1677 | 1675 | 1672 | 1670 | 1668 | 1665 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 82.7 | 82.7 | 82.8 | 82.8 | 82.9 | 82.5 | 82.5 | 82.4 | 82.4 | 82.3 | 82.3 | 82.2 | 82.2 | 82.1 | |
比楊氏模量(GPa/g·cm-3 ) | 30.9 | 30.8 | 30.8 | 30.8 | 30.7 | 30.9 | 30.8 | 30.7 | 30.7 | 30.6 | 30.5 | 30.5 | 30.4 | 30.3 | |
β-OH(mm-1 ) | 0.14 | 0.09 | 0.12 | 0.11 | 0.11 | 0.10 | 0.07 | 0.05 | 0.07 | 0.10 | 0.07 | 0.03 | 0.08 | 0.04 |
[表36]
No.491 | No.492 | No.493 | No.494 | No.495 | No.496 | No.497 | No.498 | No.499 | No.500 | No.501 | No.502 | No.503 | No.504 | ||
莫耳% | SiO2 | 70.5 | 70.3 | 70.2 | 70.0 | 69.9 | 69.7 | 74.2 | 73.8 | 73.4 | 73.0 | 72.6 | 72.3 | 71.5 | 71.1 |
Al2 O3 | 13.7 | 13.7 | 13.7 | 13.6 | 13.6 | 13.6 | 14.4 | 14.4 | 14.3 | 14.2 | 14.1 | 14.1 | 13.9 | 13.8 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 3.2 | 3.2 | 3.2 | 3.2 | 3.2 | 3.2 | 3.4 | 3.4 | 3.3 | 3.3 | 3.3 | 3.3 | 3.2 | 3.2 | |
CaO | 4.6 | 4.6 | 4.6 | 4.5 | 4.5 | 4.5 | 4.8 | 4.8 | 4.8 | 4.7 | 4.7 | 4.7 | 4.6 | 4.6 | |
SrO | 2.0 | 2.2 | 2.4 | 2.6 | 2.8 | 3.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
BaO | 5.9 | 5.9 | 5.9 | 5.9 | 5.9 | 5.9 | 3.1 | 3.6 | 4.1 | 4.6 | 5.1 | 5.6 | 6.6 | 7.1 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 84.2 | 84.0 | 83.8 | 83.7 | 83.5 | 83.3 | 88.6 | 88.2 | 87.7 | 87.2 | 86.8 | 86.3 | 85.4 | 85.0 | |
[MgO]+[CaO]+[SrO]+[BaO] | 15.7 | 15.9 | 16.1 | 16.2 | 16.4 | 16.6 | 11.3 | 11.7 | 12.2 | 12.7 | 13.1 | 13.6 | 14.5 | 14.9 | |
[SrO]+[BaO] | 7.9 | 8.1 | 8.3 | 8.5 | 8.7 | 8.9 | 3.1 | 3.6 | 4.1 | 4.6 | 5.1 | 5.6 | 6.6 | 7.1 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 1.2 | 1.0 | 0.8 | 0.6 | 0.4 | 0.2 | 6.5 | 6.0 | 5.4 | 4.9 | 4.3 | 3.8 | 2.7 | 2.1 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 409.4 | 411.5 | 413.5 | 415.5 | 417.5 | 419.5 | 351.0 | 357.4 | 363.9 | 370.3 | 376.8 | 383.2 | 396.1 | 402.5 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1797.1 | 1796.6 | 1796.1 | 1795.6 | 1795.0 | 1794.5 | 1811.8 | 1810.1 | 1808.5 | 1806.9 | 1805.3 | 1803.7 | 1800.4 | 1798.8 | |
熱膨脹係數(10-7 /℃) | 41.6 | 42.0 | 42.3 | 42.7 | 43.1 | 43.4 | 32.0 | 32.9 | 33.9 | 34.9 | 35.9 | 37.0 | 39.1 | 40.2 | |
密度(g/cm3 ) | 2.713 | 2.718 | 2.722 | 2.727 | 2.731 | 2.735 | 2.556 | 2.575 | 2.594 | 2.613 | 2.633 | 2.652 | 2.690 | 2.709 | |
應變點(℃) | 771 | 770 | 769 | 767 | 766 | 765 | 792 | 790 | 788 | 787 | 785 | 783 | 778 | 775 | |
緩冷點(℃) | 832 | 830 | 829 | 827 | 826 | 824 | 850 | 850 | 849 | 848 | 846 | 845 | 840 | 837 | |
軟化點(℃) | 1067 | 1065 | 1063 | 1062 | 1060 | 1058 | 1114 | 1111 | 1107 | 1102 | 1097 | 1092 | 1082 | 1077 | |
104.5 dPa·s(℃) | 1396 | 1394 | 1391 | 1389 | 1387 | 1385 | 1437 | 1434 | 1431 | 1428 | 1424 | 1420 | 1412 | 1408 | |
104.0 dPa·s(℃) | 1558 | 1555 | 1553 | 1550 | 1548 | 1545 | 1613 | 1606 | 1600 | 1594 | 1589 | 1585 | 1576 | 1572 | |
103.0 dPa·s(℃) | 1663 | 1661 | 1658 | 1656 | 1653 | 1650 | 1698 | 1696 | 1695 | 1693 | 1690 | 1688 | 1681 | 1677 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 82.1 | 82.1 | 82.0 | 82.0 | 81.9 | 81.9 | 84.2 | 84.0 | 83.7 | 83.4 | 83.1 | 82.8 | 82.3 | 82.0 | |
比楊氏模量(GPa/g·cm-3 ) | 30.3 | 30.2 | 30.1 | 30.1 | 30.0 | 29.9 | 33.0 | 32.6 | 32.3 | 31.9 | 31.6 | 31.2 | 30.6 | 30.3 | |
β-OH(mm-1 ) | 0.10 | 0.04 | 0.12 | 0.14 | 0.10 | 0.10 | 0.11 | 0.09 | 0.15 | 0.13 | 0.04 | 0.03 | 0.04 | 0.14 |
[表37]
No.505 | No.506 | No.507 | No.508 | No.509 | No.510 | No.511 | No.512 | No.513 | No.514 | No.515 | No.516 | No.517 | No.518 | ||
莫耳% | SiO2 | 70.7 | 70.3 | 70.0 | 69.6 | 68.9 | 69.4 | 69.9 | 70.4 | 70.9 | 71.4 | 72.4 | 72.9 | 73.4 | 73.9 |
Al2 O3 | 13.8 | 13.7 | 13.6 | 13.5 | 14.4 | 14.2 | 13.9 | 13.7 | 13.5 | 13.2 | 12.8 | 12.5 | 12.3 | 12.1 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 3.2 | 3.2 | 3.2 | 3.2 | 5.5 | 5.4 | 5.4 | 5.3 | 5.2 | 5.1 | 4.9 | 4.8 | 4.7 | 4.6 | |
CaO | 4.6 | 4.6 | 4.5 | 4.5 | 2.8 | 2.7 | 2.7 | 2.6 | 2.6 | 2.5 | 2.5 | 2.4 | 2.4 | 2.3 | |
SrO | 0.0 | 0.0 | 0.0 | 0.0 | 2.8 | 2.7 | 2.7 | 2.6 | 2.6 | 2.5 | 2.5 | 2.4 | 2.4 | 2.3 | |
BaO | 7.6 | 8.1 | 8.6 | 9.1 | 5.5 | 5.4 | 5.4 | 5.3 | 5.2 | 5.1 | 4.9 | 4.8 | 4.7 | 4.6 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 84.5 | 84.0 | 83.6 | 83.1 | 83.3 | 83.6 | 83.8 | 84.1 | 84.4 | 84.6 | 85.2 | 85.4 | 85.7 | 86.0 | |
[MgO]+[CaO]+[SrO]+[BaO] | 15.4 | 15.9 | 16.3 | 16.8 | 16.6 | 16.3 | 16.1 | 15.8 | 15.5 | 15.3 | 14.7 | 14.5 | 14.2 | 13.9 | |
[SrO]+[BaO] | 7.6 | 8.1 | 8.6 | 9.1 | 8.3 | 8.2 | 8.0 | 7.9 | 7.8 | 7.6 | 7.4 | 7.2 | 7.1 | 7.0 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 1.6 | 1.0 | 0.5 | -0.1 | 3.3 | 3.3 | 3.2 | 3.2 | 3.1 | 3.1 | 2.9 | 2.9 | 2.8 | 2.8 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 409.0 | 415.4 | 421.9 | 428.3 | 433.7 | 428.3 | 422.9 | 417.6 | 412.2 | 406.8 | 396.0 | 390.6 | 385.2 | 379.9 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1797.2 | 1795.6 | 1794.0 | 1792.3 | 1795.3 | 1795.0 | 1794.7 | 1794.4 | 1794.2 | 1793.9 | 1793.3 | 1793.1 | 1792.8 | 1792.5 | |
熱膨脹係數(10-7 /℃) | 41.3 | 42.4 | 43.5 | 44.6 | 41.2 | 40.7 | 40.3 | 39.8 | 39.3 | 38.9 | 38.0 | 37.6 | 37.2 | 36.8 | |
密度(g/cm3 ) | 2.729 | 2.748 | 2.767 | 2.786 | 2.721 | 2.713 | 2.705 | 2.696 | 2.688 | 2.680 | 2.664 | 2.655 | 2.647 | 2.639 | |
應變點(℃) | 772 | 769 | 766 | 762 | 766 | 767 | 767 | 768 | 768 | 769 | 770 | 770 | 771 | 771 | |
緩冷點(℃) | 834 | 831 | 827 | 823 | 825 | 826 | 827 | 828 | 829 | 830 | 832 | 833 | 835 | 836 | |
軟化點(℃) | 1073 | 1069 | 1065 | 1060 | 1058 | 1061 | 1063 | 1065 | 1068 | 1071 | 1078 | 1083 | 1087 | 1092 | |
104.5 dPa·s(℃) | 1404 | 1399 | 1395 | 1390 | 1372 | 1378 | 1384 | 1390 | 1396 | 1402 | 1413 | 1418 | 1424 | 1429 | |
104.0 dPa·s(℃) | 1567 | 1562 | 1556 | 1550 | 1529 | 1536 | 1543 | 1551 | 1558 | 1566 | 1581 | 1589 | 1597 | 1605 | |
103.0 dPa·s(℃) | 1673 | 1668 | 1663 | 1658 | 1628 | 1637 | 1646 | 1654 | 1663 | 1671 | 1687 | 1695 | 1703 | 1710 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 81.7 | 81.4 | 81.1 | 80.8 | 83.9 | 83.7 | 83.5 | 83.2 | 83.0 | 82.8 | 82.4 | 82.2 | 81.9 | 81.7 | |
比楊氏模量(GPa/g·cm-3 ) | 29.9 | 29.6 | 29.3 | 29.0 | 30.8 | 30.8 | 30.9 | 30.9 | 30.9 | 30.9 | 30.9 | 30.9 | 31.0 | 31.0 | |
β-OH(mm-1 ) | 0.14 | 0.04 | 0.04 | 0.05 | 0.12 | 0.05 | 0.05 | 0.09 | 0.13 | 0.13 | 0.13 | 0.12 | 0.10 | 0.12 |
[表38]
No.519 | No.520 | No.521 | No.522 | No.523 | No.524 | No.525 | No.526 | No.527 | No.528 | No.529 | No.530 | No.531 | No.532 | ||
莫耳% | SiO2 | 74.4 | 74.9 | 74.4 | 74.0 | 73.6 | 73.1 | 72.7 | 72.3 | 71.5 | 71.1 | 70.7 | 70.2 | 69.8 | 69.4 |
Al2 O3 | 11.8 | 11.6 | 10.0 | 10.5 | 11.0 | 11.5 | 12.0 | 12.5 | 13.5 | 14.0 | 14.5 | 15.0 | 15.5 | 16.0 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 4.6 | 4.5 | 5.2 | 5.1 | 5.1 | 5.1 | 5.1 | 5.0 | 5.0 | 4.9 | 4.9 | 4.9 | 4.9 | 4.8 | |
CaO | 2.3 | 2.2 | 2.6 | 2.6 | 2.6 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.4 | 2.4 | 2.4 | |
SrO | 2.3 | 2.2 | 2.6 | 2.6 | 2.6 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.4 | 2.4 | 2.4 | |
BaO | 4.6 | 4.5 | 5.2 | 5.1 | 5.1 | 5.1 | 5.1 | 5.0 | 5.0 | 4.9 | 4.9 | 4.9 | 4.9 | 4.8 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 86.2 | 86.5 | 84.4 | 84.5 | 84.6 | 84.6 | 84.7 | 84.8 | 85.0 | 85.1 | 85.2 | 85.2 | 85.3 | 85.4 | |
[MgO]+[CaO]+[SrO]+[BaO] | 13.7 | 13.4 | 15.5 | 15.4 | 15.3 | 15.3 | 15.2 | 15.1 | 14.9 | 14.8 | 14.7 | 14.7 | 14.6 | 14.5 | |
[SrO]+[BaO] | 6.8 | 6.7 | 7.8 | 7.7 | 7.7 | 7.6 | 7.6 | 7.5 | 7.5 | 7.4 | 7.4 | 7.3 | 7.3 | 7.2 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 2.7 | 2.7 | -0.3 | 0.2 | 0.8 | 1.3 | 1.9 | 2.4 | 3.6 | 4.1 | 4.7 | 5.2 | 5.8 | 6.3 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 374.5 | 369.1 | 367.0 | 372.7 | 378.4 | 384.2 | 389.9 | 395.7 | 407.1 | 412.9 | 418.6 | 424.4 | 430.1 | 435.8 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1792.2 | 1792.0 | 1775.9 | 1778.8 | 1781.8 | 1784.7 | 1787.7 | 1790.7 | 1796.6 | 1799.5 | 1802.5 | 1805.5 | 1808.4 | 1811.4 | |
熱膨脹係數(10-7 /℃) | 36.4 | 36.1 | 39.6 | 39.4 | 39.2 | 39.0 | 38.8 | 38.6 | 38.3 | 38.1 | 38.0 | 37.9 | 37.7 | 37.6 | |
密度(g/cm3 ) | 2.631 | 2.622 | 2.660 | 2.662 | 2.664 | 2.666 | 2.668 | 2.670 | 2.674 | 2.676 | 2.678 | 2.680 | 2.682 | 2.684 | |
應變點(℃) | 772 | 772 | 751 | 754 | 757 | 760 | 763 | 766 | 772 | 774 | 776 | 778 | 779 | 781 | |
緩冷點(℃) | 837 | 838 | 811 | 814 | 818 | 821 | 825 | 828 | 834 | 836 | 837 | 839 | 839 | 839 | |
軟化點(℃) | 1097 | 1102 | 1062 | 1066 | 1069 | 1071 | 1073 | 1074 | 1075 | 1075 | 1074 | 1074 | 1073 | 1072 | |
104.5 dPa·s(℃) | 1434 | 1439 | 1410 | 1411 | 1411 | 1411 | 1410 | 1409 | 1405 | 1402 | 1399 | 1396 | 1392 | 1388 | |
104.0 dPa·s(℃) | 1613 | 1621 | 1595 | 1592 | 1589 | 1586 | 1582 | 1578 | 1568 | 1563 | 1558 | 1552 | 1547 | 1542 | |
103.0 dPa·s(℃) | 1718 | 1725 | 1700 | 1699 | 1696 | 1693 | 1689 | 1685 | 1673 | 1667 | 1660 | 1653 | 1645 | 1638 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 81.5 | 81.3 | 80.2 | 80.6 | 81.0 | 81.4 | 81.8 | 82.2 | 83.0 | 83.4 | 83.8 | 84.2 | 84.6 | 84.9 | |
比楊氏模量(GPa/g·cm-3 ) | 31.0 | 31.0 | 30.2 | 30.3 | 30.4 | 30.5 | 30.7 | 30.8 | 31.0 | 31.2 | 31.3 | 31.4 | 31.5 | 31.7 | |
β-OH(mm-1 ) | 0.03 | 0.15 | 0.08 | 0.05 | 0.15 | 0.03 | 0.05 | 0.12 | 0.08 | 0.12 | 0.09 | 0.05 | 0.15 | 0.10 |
[表39]
No.533 | No.534 | No.535 | No.536 | No.537 | No.538 | No.539 | No.540 | No.541 | No.542 | No.543 | No.544 | No.545 | No.546 | ||
莫耳% | SiO2 | 71.8 | 71.6 | 71.5 | 71.3 | 71.2 | 71.0 | 70.9 | 70.7 | 70.6 | 70.5 | 70.3 | 70.2 | 70.0 | 69.9 |
Al2 O3 | 13.0 | 12.9 | 12.9 | 12.9 | 12.9 | 12.8 | 12.8 | 12.8 | 12.8 | 12.7 | 12.7 | 12.7 | 12.7 | 12.6 | |
B2 O3 | 0.2 | 0.4 | 0.6 | 0.8 | 1.0 | 1.2 | 1.4 | 1.6 | 1.8 | 2.0 | 2.2 | 2.4 | 2.6 | 2.8 | |
MgO | 5.0 | 5.0 | 5.0 | 5.0 | 4.9 | 4.9 | 4.9 | 4.9 | 4.9 | 4.9 | 4.9 | 4.9 | 4.9 | 4.9 | |
CaO | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.4 | 2.4 | 2.4 | 2.4 | 2.4 | |
SrO | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.4 | 2.4 | 2.4 | 2.4 | 2.4 | |
BaO | 5.0 | 5.0 | 5.0 | 5.0 | 4.9 | 4.9 | 4.9 | 4.9 | 4.9 | 4.9 | 4.9 | 4.9 | 4.9 | 4.9 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 84.7 | 84.6 | 84.4 | 84.2 | 84.1 | 83.9 | 83.7 | 83.5 | 83.4 | 83.2 | 83.0 | 82.9 | 82.7 | 82.5 | |
[MgO]+[CaO]+[SrO]+[BaO] | 15.0 | 14.9 | 14.9 | 14.9 | 14.8 | 14.8 | 14.8 | 14.8 | 14.7 | 14.7 | 14.7 | 14.6 | 14.6 | 14.6 | |
[SrO]+[BaO] | 7.5 | 7.5 | 7.5 | 7.4 | 7.4 | 7.4 | 7.4 | 7.4 | 7.4 | 7.3 | 7.3 | 7.3 | 7.3 | 7.3 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.1 | 0.1 | 0.1 | 0.1 | 0.2 | 0.2 | 0.2 | 0.2 | 0.3 | 0.3 | 0.3 | 0.4 | 0.4 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 3.2 | 3.4 | 3.6 | 3.8 | 4.0 | 4.2 | 4.4 | 4.6 | 4.7 | 4.9 | 5.1 | 5.3 | 5.5 | 5.7 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 397.6 | 393.8 | 390.0 | 386.2 | 382.4 | 378.6 | 374.8 | 371.0 | 367.2 | 363.4 | 359.6 | 355.8 | 352.0 | 348.1 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1790.8 | 1787.9 | 1785.1 | 1782.2 | 1779.4 | 1776.5 | 1773.7 | 1770.8 | 1768.0 | 1765.1 | 1762.3 | 1759.4 | 1756.6 | 1753.7 | |
熱膨脹係數(10-7 /℃) | 38.4 | 38.4 | 38.4 | 38.4 | 38.4 | 38.3 | 38.3 | 38.3 | 38.3 | 38.3 | 38.3 | 38.3 | 38.2 | 38.2 | |
密度(g/cm3 ) | 2.669 | 2.667 | 2.665 | 2.663 | 2.660 | 2.658 | 2.656 | 2.653 | 2.651 | 2.649 | 2.647 | 2.644 | 2.642 | 2.640 | |
應變點(℃) | 766 | 762 | 759 | 756 | 753 | 750 | 747 | 744 | 741 | 739 | 736 | 734 | 731 | 729 | |
緩冷點(℃) | 828 | 825 | 821 | 818 | 815 | 812 | 809 | 806 | 803 | 800 | 797 | 794 | 791 | 788 | |
軟化點(℃) | 1071 | 1068 | 1064 | 1061 | 1057 | 1054 | 1051 | 1047 | 1044 | 1040 | 1037 | 1033 | 1029 | 1025 | |
104.5 dPa·s(℃) | 1405 | 1402 | 1399 | 1396 | 1393 | 1390 | 1387 | 1384 | 1381 | 1378 | 1375 | 1372 | 1369 | 1366 | |
104.0 dPa·s(℃) | 1571 | 1568 | 1565 | 1562 | 1559 | 1556 | 1553 | 1550 | 1547 | 1544 | 1541 | 1538 | 1535 | 1531 | |
103.0 dPa·s(℃) | 1676 | 1674 | 1671 | 1668 | 1665 | 1662 | 1658 | 1655 | 1652 | 1648 | 1645 | 1642 | 1638 | 1635 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 82.4 | 82.2 | 81.9 | 81.7 | 81.5 | 81.3 | 81.1 | 80.9 | 80.6 | 80.4 | 80.2 | 80.0 | 79.8 | 79.6 | |
比楊氏模量(GPa/g·cm-3 ) | 30.9 | 30.8 | 30.7 | 30.7 | 30.6 | 30.6 | 30.5 | 30.5 | 30.4 | 30.4 | 30.3 | 30.3 | 30.2 | 30.1 | |
β-OH(mm-1 ) | 0.10 | 0.03 | 0.06 | 0.09 | 0.07 | 0.12 | 0.13 | 0.12 | 0.06 | 0.06 | 0.04 | 0.10 | 0.05 | 0.04 |
[表40]
No.547 | No.548 | No.549 | No.550 | No.551 | No.552 | No.553 | No.554 | No.555 | No.556 | No.557 | No.558 | No.559 | No.560 | ||
莫耳% | SiO2 | 69.7 | 74.2 | 73.8 | 73.4 | 73.0 | 72.7 | 72.3 | 71.5 | 71.1 | 70.8 | 70.4 | 70.0 | 69.6 | 73.7 |
Al2 O3 | 12.6 | 13.4 | 13.3 | 13.3 | 13.2 | 13.1 | 13.1 | 12.9 | 12.9 | 12.8 | 12.7 | 12.7 | 12.6 | 13.3 | |
B2 O3 | 3.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 4.8 | 2.0 | 2.5 | 3.0 | 3.5 | 4.0 | 4.5 | 5.5 | 6.0 | 6.5 | 7.0 | 7.5 | 8.0 | 5.1 | |
CaO | 2.4 | 2.6 | 2.6 | 2.6 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.4 | 2.4 | 2.4 | 0.0 | |
SrO | 2.4 | 2.6 | 2.6 | 2.6 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.4 | 2.4 | 2.4 | 2.6 | |
BaO | 4.8 | 5.2 | 5.1 | 5.1 | 5.1 | 5.1 | 5.0 | 5.0 | 4.9 | 4.9 | 4.9 | 4.9 | 4.8 | 5.1 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 82.4 | 87.6 | 87.1 | 86.7 | 86.2 | 85.8 | 85.3 | 84.5 | 84.0 | 83.6 | 83.1 | 82.7 | 82.2 | 87.1 | |
[MgO]+[CaO]+[SrO]+[BaO] | 14.5 | 12.3 | 12.8 | 13.2 | 13.7 | 14.1 | 14.6 | 15.4 | 15.9 | 16.3 | 16.8 | 17.2 | 17.7 | 12.8 | |
[SrO]+[BaO] | 7.3 | 7.7 | 7.7 | 7.7 | 7.6 | 7.6 | 7.5 | 7.5 | 7.4 | 7.4 | 7.3 | 7.3 | 7.3 | 7.7 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.4 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 5.9 | 3.1 | 3.1 | 3.1 | 3.0 | 3.0 | 3.0 | 3.0 | 3.0 | 3.0 | 2.9 | 2.9 | 2.9 | 5.6 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 344.3 | 395.1 | 396.2 | 397.2 | 398.3 | 399.3 | 400.4 | 402.4 | 403.5 | 404.5 | 405.6 | 406.6 | 407.7 | 409.1 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1750.9 | 1809.6 | 1806.9 | 1804.3 | 1801.6 | 1798.9 | 1796.3 | 1791.0 | 1788.3 | 1785.6 | 1783.0 | 1780.3 | 1777.7 | 1803.5 | |
熱膨脹係數(10-7 /℃) | 38.2 | 36.4 | 36.8 | 37.1 | 37.4 | 37.8 | 38.1 | 38.8 | 39.1 | 39.5 | 39.8 | 40.2 | 40.6 | 34.9 | |
密度(g/cm3 ) | 2.637 | 2.652 | 2.656 | 2.659 | 2.662 | 2.665 | 2.669 | 2.675 | 2.678 | 2.682 | 2.685 | 2.688 | 2.691 | 2.650 | |
應變點(℃) | 727 | 798 | 792 | 786 | 781 | 776 | 772 | 767 | 764 | 763 | 761 | 760 | 758 | 784 | |
緩冷點(℃) | 786 | 863 | 857 | 851 | 846 | 841 | 836 | 827 | 823 | 820 | 817 | 814 | 812 | 851 | |
軟化點(℃) | 1021 | 1127 | 1121 | 1112 | 1102 | 1091 | 1082 | 1069 | 1064 | 1059 | 1054 | 1049 | 1044 | 1114 | |
104.5 dPa·s(℃) | 1363 | 1456 | 1448 | 1440 | 1432 | 1424 | 1416 | 1399 | 1391 | 1382 | 1374 | 1365 | 1356 | 1442 | |
104.0 dPa·s(℃) | 1528 | 1634 | 1623 | 1613 | 1603 | 1593 | 1583 | 1564 | 1554 | 1544 | 1535 | 1525 | 1515 | 1615 | |
103.0 dPa·s(℃) | 1631 | 1733 | 1724 | 1716 | 1707 | 1698 | 1689 | 1669 | 1659 | 1649 | 1639 | 1629 | 1618 | 1714 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 79.3 | 80.8 | 81.1 | 81.4 | 81.7 | 82.0 | 82.3 | 82.9 | 83.2 | 83.5 | 83.8 | 84.1 | 84.4 | 82.3 | |
比楊氏模量(GPa/g·cm-3 ) | 30.1 | 30.5 | 30.5 | 30.6 | 30.7 | 30.8 | 30.8 | 31.0 | 31.1 | 31.1 | 31.2 | 31.3 | 31.3 | 31.1 | |
β-OH(mm-1 ) | 0.07 | 0.11 | 0.09 | 0.06 | 0.12 | 0.11 | 0.10 | 0.14 | 0.05 | 0.07 | 0.06 | 0.11 | 0.11 | 0.14 |
[表41]
No.561 | No.562 | No.563 | No.564 | No.565 | No.566 | No.567 | No.568 | No.569 | No.570 | No.571 | No.572 | No.573 | No.574 | ||
莫耳% | SiO2 | 73.4 | 73.0 | 72.6 | 72.3 | 71.5 | 71.2 | 70.8 | 70.4 | 70.1 | 69.7 | 73.7 | 73.4 | 73.0 | 72.6 |
Al2 O3 | 13.3 | 13.2 | 13.1 | 13.1 | 12.9 | 12.9 | 12.8 | 12.7 | 12.7 | 12.6 | 13.3 | 13.3 | 13.2 | 13.1 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 5.1 | 5.1 | 5.1 | 5.0 | 5.0 | 4.9 | 4.9 | 4.9 | 4.9 | 4.8 | 5.1 | 5.1 | 5.1 | 5.1 | |
CaO | 0.5 | 1.0 | 1.5 | 2.0 | 3.0 | 3.5 | 4.0 | 4.5 | 5.0 | 5.5 | 2.6 | 2.6 | 2.5 | 2.5 | |
SrO | 2.6 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.5 | 2.4 | 2.4 | 2.4 | 0.0 | 0.5 | 1.0 | 1.5 | |
BaO | 5.1 | 5.1 | 5.1 | 5.0 | 5.0 | 4.9 | 4.9 | 4.9 | 4.9 | 4.8 | 5.1 | 5.1 | 5.1 | 5.1 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 86.6 | 86.2 | 85.8 | 85.3 | 84.5 | 84.0 | 83.6 | 83.2 | 82.7 | 82.3 | 87.1 | 86.6 | 86.2 | 85.8 | |
[MgO]+[CaO]+[SrO]+[BaO] | 13.3 | 13.7 | 14.1 | 14.6 | 15.4 | 15.9 | 16.3 | 16.7 | 17.2 | 17.6 | 12.8 | 13.3 | 13.7 | 14.1 | |
[SrO]+[BaO] | 7.7 | 7.6 | 7.6 | 7.5 | 7.5 | 7.4 | 7.4 | 7.3 | 7.3 | 7.3 | 5.1 | 5.6 | 6.1 | 6.6 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 5.1 | 4.6 | 4.1 | 3.5 | 2.5 | 1.9 | 1.4 | 0.9 | 0.4 | -0.2 | 5.6 | 5.1 | 4.6 | 4.1 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 407.6 | 406.0 | 404.5 | 402.9 | 399.9 | 398.3 | 396.8 | 395.2 | 393.7 | 392.1 | 375.8 | 380.9 | 386.0 | 391.2 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1801.5 | 1799.5 | 1797.6 | 1795.6 | 1791.6 | 1789.7 | 1787.7 | 1785.7 | 1783.7 | 1781.8 | 1799.9 | 1798.7 | 1797.4 | 1796.1 | |
熱膨脹係數(10-7 /℃) | 35.6 | 36.3 | 37.0 | 37.7 | 39.2 | 39.9 | 40.7 | 41.4 | 42.2 | 42.9 | 34.1 | 34.9 | 35.8 | 36.6 | |
密度(g/cm3 ) | 2.654 | 2.659 | 2.663 | 2.667 | 2.676 | 2.681 | 2.685 | 2.689 | 2.694 | 2.698 | 2.616 | 2.627 | 2.638 | 2.649 | |
應變點(℃) | 781 | 778 | 775 | 772 | 766 | 763 | 760 | 757 | 754 | 751 | 779 | 777 | 775 | 774 | |
緩冷點(℃) | 847 | 843 | 839 | 835 | 827 | 823 | 819 | 815 | 810 | 806 | 844 | 842 | 840 | 837 | |
軟化點(℃) | 1105 | 1097 | 1089 | 1081 | 1069 | 1063 | 1058 | 1052 | 1047 | 1041 | 1100 | 1094 | 1089 | 1084 | |
104.5 dPa·s(℃) | 1435 | 1429 | 1422 | 1415 | 1400 | 1393 | 1385 | 1378 | 1370 | 1362 | 1432 | 1428 | 1423 | 1418 | |
104.0 dPa·s(℃) | 1606 | 1598 | 1590 | 1582 | 1565 | 1557 | 1548 | 1539 | 1529 | 1520 | 1602 | 1596 | 1590 | 1585 | |
103.0 dPa·s(℃) | 1708 | 1701 | 1694 | 1687 | 1671 | 1663 | 1654 | 1645 | 1636 | 1627 | 1703 | 1699 | 1695 | 1690 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 82.4 | 82.4 | 82.5 | 82.5 | 82.6 | 82.7 | 82.7 | 82.8 | 82.8 | 82.9 | 83.2 | 83.1 | 82.9 | 82.8 | |
比楊氏模量(GPa/g·cm-3 ) | 31.0 | 31.0 | 31.0 | 30.9 | 30.9 | 30.8 | 30.8 | 30.8 | 30.8 | 30.7 | 31.8 | 31.6 | 31.4 | 31.3 | |
β-OH(mm-1 ) | 0.12 | 0.08 | 0.14 | 0.03 | 0.15 | 0.15 | 0.06 | 0.09 | 0.13 | 0.06 | 0.15 | 0.15 | 0.03 | 0.13 |
[表42]
No.575 | No.576 | No.577 | No.578 | No.579 | No.580 | No.581 | No.582 | No.583 | No.584 | No.585 | No.586 | No.587 | No.588 | ||
莫耳% | SiO2 | 72.3 | 71.5 | 71.2 | 70.8 | 70.4 | 70.1 | 69.7 | 74.2 | 73.8 | 73.4 | 73.0 | 72.7 | 72.3 | 71.5 |
Al2 O3 | 13.1 | 12.9 | 12.9 | 12.8 | 12.7 | 12.7 | 12.6 | 13.4 | 13.3 | 13.3 | 13.2 | 13.1 | 13.1 | 12.9 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
MgO | 5.0 | 5.0 | 4.9 | 4.9 | 4.9 | 4.9 | 4.8 | 5.2 | 5.1 | 5.1 | 5.1 | 5.1 | 5.0 | 5.0 | |
CaO | 2.5 | 2.5 | 2.5 | 2.5 | 2.4 | 2.4 | 2.4 | 2.6 | 2.6 | 2.6 | 2.5 | 2.5 | 2.5 | 2.5 | |
SrO | 2.0 | 3.0 | 3.5 | 4.0 | 4.5 | 5.0 | 5.5 | 2.6 | 2.6 | 2.6 | 2.5 | 2.5 | 2.5 | 2.5 | |
BaO | 5.0 | 5.0 | 4.9 | 4.9 | 4.9 | 4.9 | 4.8 | 2.0 | 2.5 | 3.0 | 3.5 | 4.0 | 4.5 | 5.5 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 85.3 | 84.5 | 84.0 | 83.6 | 83.2 | 82.7 | 82.3 | 87.6 | 87.1 | 86.7 | 86.2 | 85.8 | 85.3 | 84.5 | |
[MgO]+[CaO]+[SrO]+[BaO] | 14.6 | 15.4 | 15.9 | 16.3 | 16.7 | 17.2 | 17.6 | 12.3 | 12.8 | 13.2 | 13.7 | 14.1 | 14.6 | 15.4 | |
[SrO]+[BaO] | 7.0 | 8.0 | 8.4 | 8.9 | 9.4 | 9.9 | 10.3 | 4.6 | 5.1 | 5.6 | 6.0 | 6.5 | 7.0 | 8.0 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 3.5 | 2.5 | 1.9 | 1.4 | 0.9 | 0.4 | -0.2 | 6.3 | 5.7 | 5.2 | 4.6 | 4.1 | 3.5 | 2.5 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 396.3 | 406.5 | 411.6 | 416.8 | 421.9 | 427.0 | 432.1 | 363.6 | 369.9 | 376.2 | 382.5 | 388.8 | 395.1 | 407.7 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1794.9 | 1792.4 | 1791.1 | 1789.8 | 1788.6 | 1787.3 | 1786.1 | 1802.9 | 1801.4 | 1799.8 | 1798.3 | 1796.7 | 1795.2 | 1792.1 | |
熱膨脹係數(10-7 /℃) | 37.5 | 39.4 | 40.3 | 41.2 | 42.2 | 43.1 | 44.0 | 32.5 | 33.4 | 34.4 | 35.4 | 36.4 | 37.4 | 39.5 | |
密度(g/cm3 ) | 2.661 | 2.683 | 2.694 | 2.705 | 2.717 | 2.728 | 2.739 | 2.558 | 2.577 | 2.596 | 2.615 | 2.634 | 2.653 | 2.691 | |
應變點(℃) | 771 | 767 | 764 | 761 | 758 | 755 | 752 | 781 | 779 | 778 | 776 | 774 | 772 | 766 | |
緩冷點(℃) | 834 | 828 | 824 | 821 | 817 | 813 | 809 | 844 | 843 | 841 | 839 | 837 | 834 | 828 | |
軟化點(℃) | 1079 | 1070 | 1066 | 1061 | 1056 | 1051 | 1046 | 1100 | 1095 | 1091 | 1086 | 1082 | 1078 | 1071 | |
104.5 dPa·s(℃) | 1413 | 1402 | 1397 | 1391 | 1386 | 1380 | 1374 | 1429 | 1426 | 1422 | 1419 | 1415 | 1411 | 1403 | |
104.0 dPa·s(℃) | 1579 | 1567 | 1561 | 1554 | 1547 | 1540 | 1532 | 1600 | 1595 | 1590 | 1586 | 1582 | 1578 | 1569 | |
103.0 dPa·s(℃) | 1685 | 1673 | 1667 | 1661 | 1654 | 1647 | 1640 | 1697 | 1695 | 1693 | 1690 | 1687 | 1683 | 1675 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 82.7 | 82.5 | 82.3 | 82.2 | 82.1 | 82.0 | 81.9 | 84.3 | 84.0 | 83.7 | 83.4 | 83.1 | 82.9 | 82.3 | |
比楊氏模量(GPa/g·cm-3 ) | 31.1 | 30.7 | 30.6 | 30.4 | 30.2 | 30.1 | 29.9 | 32.9 | 32.6 | 32.2 | 31.9 | 31.6 | 31.2 | 30.6 | |
β-OH(mm-1 ) | 0.11 | 0.14 | 0.08 | 0.11 | 0.12 | 0.15 | 0.05 | 0.13 | 0.03 | 0.05 | 0.04 | 0.04 | 0.07 | 0.12 |
[表43]
No.589 | No.590 | No.591 | No.592 | No.593 | No.594 | No.595 | No.596 | No.597 | No.598 | No.599 | No.600 | No.601 | No.602 | ||
莫耳% | SiO2 | 71.1 | 70.8 | 70.4 | 70.0 | 69.6 | 67.6 | 68.1 | 68.6 | 69.1 | 69.6 | 70.1 | 71.1 | 71.6 | 72.1 |
Al2 O3 | 12.9 | 12.8 | 12.7 | 12.7 | 12.6 | 14.4 | 14.2 | 14.0 | 13.8 | 13.5 | 13.3 | 12.9 | 12.7 | 12.4 | |
B2 O3 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | |
MgO | 4.9 | 4.9 | 4.9 | 4.9 | 4.8 | 6.7 | 6.6 | 6.5 | 6.4 | 6.3 | 6.2 | 6.0 | 5.9 | 5.8 | |
CaO | 2.5 | 2.5 | 2.4 | 2.4 | 2.4 | 4.2 | 4.1 | 4.1 | 4.0 | 3.9 | 3.9 | 3.7 | 3.7 | 3.6 | |
SrO | 2.5 | 2.5 | 2.4 | 2.4 | 2.4 | 2.3 | 2.3 | 2.2 | 2.2 | 2.2 | 2.1 | 2.1 | 2.0 | 2.0 | |
BaO | 6.0 | 6.5 | 7.0 | 7.5 | 8.0 | 4.3 | 4.2 | 4.2 | 4.1 | 4.0 | 4.0 | 3.8 | 3.8 | 3.7 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 84.0 | 83.6 | 83.1 | 82.7 | 82.2 | 82.0 | 82.3 | 82.6 | 82.9 | 83.1 | 83.4 | 84.0 | 84.3 | 84.5 | |
[MgO]+[CaO]+[SrO]+[BaO] | 15.9 | 16.3 | 16.8 | 17.2 | 17.7 | 17.5 | 17.3 | 17.0 | 16.7 | 16.4 | 16.2 | 15.6 | 15.4 | 15.1 | |
[SrO]+[BaO] | 8.5 | 9.0 | 9.4 | 9.9 | 10.4 | 6.6 | 6.5 | 6.4 | 6.3 | 6.2 | 6.1 | 5.9 | 5.8 | 5.7 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 1.9 | 1.4 | 0.8 | 0.3 | -0.3 | 4.0 | 3.9 | 3.8 | 3.8 | 3.7 | 3.7 | 3.5 | 3.5 | 3.4 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 414.0 | 420.3 | 426.6 | 432.9 | 439.2 | 410.6 | 405.7 | 400.9 | 396.1 | 391.3 | 386.5 | 376.9 | 372.1 | 367.3 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1790.5 | 1789.0 | 1787.4 | 1785.8 | 1784.3 | 1784.3 | 1784.2 | 1784.1 | 1784.0 | 1783.9 | 1783.8 | 1783.6 | 1783.5 | 1783.4 | |
熱膨脹係數(10-7 /℃) | 40.6 | 41.7 | 42.7 | 43.8 | 44.9 | 41.0 | 40.5 | 40.1 | 39.7 | 39.2 | 38.8 | 37.9 | 37.5 | 37.1 | |
密度(g/cm3 ) | 2.710 | 2.729 | 2.748 | 2.766 | 2.785 | 2.689 | 2.681 | 2.674 | 2.666 | 2.659 | 2.652 | 2.637 | 2.629 | 2.622 | |
應變點(℃) | 764 | 761 | 757 | 754 | 751 | 757 | 757 | 758 | 758 | 759 | 759 | 760 | 760 | 761 | |
緩冷點(℃) | 824 | 821 | 817 | 813 | 808 | 811 | 812 | 813 | 814 | 815 | 817 | 819 | 820 | 821 | |
軟化點(℃) | 1067 | 1063 | 1059 | 1054 | 1050 | 1041 | 1043 | 1045 | 1047 | 1049 | 1052 | 1056 | 1059 | 1061 | |
104.5 dPa·s(℃) | 1399 | 1395 | 1390 | 1386 | 1381 | 1338 | 1344 | 1350 | 1356 | 1363 | 1369 | 1381 | 1387 | 1393 | |
104.0 dPa·s(℃) | 1564 | 1558 | 1552 | 1545 | 1538 | 1494 | 1500 | 1507 | 1514 | 1522 | 1529 | 1544 | 1552 | 1560 | |
103.0 dPa·s(℃) | 1670 | 1665 | 1660 | 1655 | 1649 | 1585 | 1594 | 1603 | 1612 | 1622 | 1631 | 1649 | 1657 | 1666 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 82.0 | 81.7 | 81.5 | 81.2 | 80.9 | 85.3 | 85.1 | 84.8 | 84.6 | 84.4 | 84.1 | 83.7 | 83.5 | 83.2 | |
比楊氏模量(GPa/g·cm-3 ) | 30.3 | 30.0 | 29.6 | 29.3 | 29.0 | 31.7 | 31.7 | 31.7 | 31.7 | 31.7 | 31.7 | 31.7 | 31.7 | 31.7 | |
β-OH(mm-1 ) | 0.10 | 0.10 | 0.03 | 0.07 | 0.09 | 0.04 | 0.15 | 0.09 | 0.14 | 0.12 | 0.06 | 0.10 | 0.06 | 0.13 |
[表44]
No.603 | No.604 | No.605 | No.606 | No.607 | No.608 | No.609 | No.610 | No.611 | No.612 | No.613 | No.614 | No.615 | No.616 | ||
莫耳% | SiO2 | 72.6 | 73.1 | 73.6 | 73.0 | 72.6 | 72.2 | 71.8 | 71.4 | 71.0 | 70.2 | 69.8 | 69.4 | 69.0 | 68.6 |
Al2 O3 | 12.2 | 12.0 | 11.8 | 10.1 | 10.6 | 11.1 | 11.6 | 12.1 | 12.6 | 13.6 | 14.1 | 14.6 | 15.1 | 15.6 | |
B2 O3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | |
MgO | 5.7 | 5.6 | 5.5 | 6.3 | 6.3 | 6.2 | 6.2 | 6.2 | 6.1 | 6.1 | 6.0 | 6.0 | 6.0 | 5.9 | |
CaO | 3.5 | 3.5 | 3.4 | 3.9 | 3.9 | 3.9 | 3.9 | 3.8 | 3.8 | 3.8 | 3.8 | 3.7 | 3.7 | 3.7 | |
SrO | 2.0 | 1.9 | 1.9 | 2.2 | 2.2 | 2.1 | 2.1 | 2.1 | 2.1 | 2.1 | 2.1 | 2.1 | 2.1 | 2.0 | |
BaO | 3.6 | 3.6 | 3.5 | 4.0 | 4.0 | 4.0 | 4.0 | 3.9 | 3.9 | 3.9 | 3.9 | 3.8 | 3.8 | 3.8 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 84.8 | 85.1 | 85.4 | 83.1 | 83.2 | 83.3 | 83.4 | 83.5 | 83.6 | 83.8 | 83.9 | 84.0 | 84.1 | 84.2 | |
[MgO]+[CaO]+[SrO]+[BaO] | 14.8 | 14.5 | 14.3 | 16.4 | 16.4 | 16.3 | 16.2 | 16.1 | 16.0 | 15.8 | 15.7 | 15.6 | 15.5 | 15.4 | |
[SrO]+[BaO] | 5.6 | 5.5 | 5.4 | 6.2 | 6.2 | 6.1 | 6.1 | 6.1 | 6.0 | 6.0 | 5.9 | 5.9 | 5.9 | 5.8 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 3.4 | 3.3 | 3.2 | 0.3 | 0.8 | 1.4 | 1.9 | 2.5 | 3.0 | 4.2 | 4.7 | 5.3 | 5.8 | 6.4 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 362.5 | 357.7 | 352.8 | 346.6 | 352.4 | 358.3 | 364.1 | 370.0 | 375.8 | 387.6 | 393.4 | 399.3 | 405.1 | 411.0 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1783.3 | 1783.3 | 1783.2 | 1765.6 | 1768.6 | 1771.6 | 1774.7 | 1777.7 | 1780.7 | 1786.7 | 1789.8 | 1792.8 | 1795.8 | 1798.8 | |
熱膨脹係數(10-7 /℃) | 36.7 | 36.4 | 36.0 | 39.4 | 39.2 | 39.0 | 38.9 | 38.7 | 38.5 | 38.2 | 38.1 | 38.0 | 37.8 | 37.7 | |
密度(g/cm3 ) | 2.615 | 2.607 | 2.600 | 2.631 | 2.633 | 2.636 | 2.638 | 2.640 | 2.642 | 2.646 | 2.648 | 2.651 | 2.653 | 2.655 | |
應變點(℃) | 761 | 762 | 762 | 745 | 747 | 750 | 752 | 755 | 757 | 761 | 763 | 764 | 766 | 767 | |
緩冷點(℃) | 822 | 823 | 825 | 802 | 804 | 807 | 810 | 812 | 815 | 820 | 822 | 823 | 824 | 824 | |
軟化點(℃) | 1064 | 1067 | 1071 | 1041 | 1044 | 1046 | 1049 | 1051 | 1053 | 1055 | 1055 | 1055 | 1055 | 1054 | |
104.5 dPa·s(℃) | 1399 | 1405 | 1410 | 1381 | 1381 | 1381 | 1380 | 1379 | 1377 | 1373 | 1370 | 1367 | 1364 | 1361 | |
104.0 dPa·s(℃) | 1568 | 1576 | 1584 | 1555 | 1553 | 1550 | 1548 | 1544 | 1541 | 1532 | 1527 | 1522 | 1517 | 1512 | |
103.0 dPa·s(℃) | 1674 | 1683 | 1691 | 1664 | 1662 | 1659 | 1655 | 1650 | 1645 | 1634 | 1628 | 1621 | 1615 | 1609 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 83.0 | 82.8 | 82.5 | 81.6 | 82.0 | 82.4 | 82.8 | 83.1 | 83.5 | 84.3 | 84.7 | 85.1 | 85.5 | 85.8 | |
比楊氏模量(GPa/g·cm-3 ) | 31.7 | 31.7 | 31.7 | 31.0 | 31.1 | 31.3 | 31.4 | 31.5 | 31.6 | 31.9 | 32.0 | 32.1 | 32.2 | 32.3 | |
β-OH(mm-1 ) | 0.13 | 0.10 | 0.10 | 0.14 | 0.12 | 0.10 | 0.05 | 0.07 | 0.07 | 0.14 | 0.09 | 0.03 | 0.09 | 0.09 |
[表45]
No.617 | No.618 | No.619 | No.620 | No.621 | No.622 | No.623 | No.624 | No.625 | No.626 | No.627 | No.628 | No.629 | No.630 | ||
莫耳% | SiO2 | 68.2 | 70.7 | 70.5 | 70.3 | 70.2 | 70.0 | 69.9 | 69.7 | 69.6 | 69.5 | 69.3 | 69.2 | 69.0 | 68.9 |
Al2 O3 | 16.1 | 13.1 | 13.1 | 13.0 | 13.0 | 13.0 | 13.0 | 12.9 | 12.9 | 12.9 | 12.9 | 12.8 | 12.8 | 12.8 | |
B2 O3 | 0.3 | 0.1 | 0.5 | 0.7 | 0.9 | 1.1 | 1.3 | 1.5 | 1.7 | 1.9 | 2.1 | 2.3 | 2.5 | 2.7 | |
MgO | 5.9 | 6.1 | 6.1 | 6.1 | 6.1 | 6.1 | 6.0 | 6.0 | 6.0 | 6.0 | 6.0 | 6.0 | 6.0 | 6.0 | |
CaO | 3.7 | 3.8 | 3.8 | 3.8 | 3.8 | 3.8 | 3.8 | 3.8 | 3.7 | 3.7 | 3.7 | 3.7 | 3.7 | 3.7 | |
SrO | 2.0 | 2.1 | 2.1 | 2.1 | 2.1 | 2.1 | 2.1 | 2.1 | 2.1 | 2.1 | 2.1 | 2.1 | 2.1 | 2.0 | |
BaO | 3.8 | 3.9 | 3.9 | 3.9 | 3.9 | 3.9 | 3.9 | 3.9 | 3.8 | 3.8 | 3.8 | 3.8 | 3.8 | 3.8 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 84.3 | 83.9 | 83.5 | 83.4 | 83.2 | 83.0 | 82.9 | 82.7 | 82.5 | 82.4 | 82.2 | 82.0 | 81.9 | 81.7 | |
[MgO]+[CaO]+[SrO]+[BaO] | 15.4 | 15.9 | 15.9 | 15.8 | 15.8 | 15.8 | 15.7 | 15.7 | 15.7 | 15.6 | 15.6 | 15.6 | 15.5 | 15.5 | |
[SrO]+[BaO] | 5.8 | 6.0 | 6.0 | 6.0 | 6.0 | 6.0 | 5.9 | 5.9 | 5.9 | 5.9 | 5.9 | 5.9 | 5.9 | 5.9 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.1 | 0.0 | 0.1 | 0.1 | 0.2 | 0.2 | 0.2 | 0.3 | 0.3 | 0.3 | 0.4 | 0.4 | 0.4 | 0.5 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 6.9 | 3.4 | 3.8 | 4.0 | 4.2 | 4.4 | 4.6 | 4.8 | 5.0 | 5.1 | 5.3 | 5.5 | 5.7 | 5.9 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 416.8 | 385.5 | 377.9 | 374.1 | 370.4 | 366.6 | 362.8 | 359.0 | 355.3 | 351.5 | 347.7 | 343.9 | 340.2 | 336.4 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1801.8 | 1786.6 | 1780.9 | 1778.0 | 1775.2 | 1772.4 | 1769.5 | 1766.7 | 1763.8 | 1761.0 | 1758.2 | 1755.3 | 1752.5 | 1749.6 | |
熱膨脹係數(10-7 /℃) | 37.5 | 38.4 | 38.4 | 38.3 | 38.3 | 38.3 | 38.3 | 38.3 | 38.3 | 38.2 | 38.2 | 38.2 | 38.2 | 38.2 | |
密度(g/cm3 ) | 2.657 | 2.646 | 2.642 | 2.640 | 2.637 | 2.635 | 2.633 | 2.631 | 2.629 | 2.626 | 2.624 | 2.622 | 2.620 | 2.617 | |
應變點(℃) | 768 | 763 | 757 | 754 | 751 | 748 | 745 | 743 | 740 | 738 | 735 | 733 | 730 | 728 | |
緩冷點(℃) | 824 | 821 | 815 | 812 | 809 | 806 | 803 | 801 | 798 | 795 | 793 | 790 | 788 | 785 | |
軟化點(℃) | 1053 | 1057 | 1051 | 1048 | 1045 | 1042 | 1038 | 1035 | 1031 | 1028 | 1024 | 1020 | 1017 | 1013 | |
104.5 dPa·s(℃) | 1358 | 1378 | 1372 | 1369 | 1366 | 1364 | 1361 | 1358 | 1355 | 1352 | 1349 | 1346 | 1343 | 1340 | |
104.0 dPa·s(℃) | 1506 | 1539 | 1534 | 1531 | 1528 | 1526 | 1523 | 1520 | 1517 | 1514 | 1512 | 1509 | 1506 | 1503 | |
103.0 dPa·s(℃) | 1603 | 1642 | 1637 | 1634 | 1631 | 1628 | 1625 | 1622 | 1619 | 1616 | 1613 | 1609 | 1606 | 1603 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 86.2 | 84.1 | 83.7 | 83.5 | 83.3 | 83.0 | 82.8 | 82.6 | 82.4 | 82.2 | 81.9 | 81.7 | 81.5 | 81.3 | |
比楊氏模量(GPa/g·cm-3 ) | 32.5 | 31.8 | 31.7 | 31.6 | 31.6 | 31.5 | 31.5 | 31.4 | 31.3 | 31.3 | 31.2 | 31.2 | 31.1 | 31.1 | |
β-OH(mm-1 ) | 0.11 | 0.11 | 0.10 | 0.15 | 0.11 | 0.11 | 0.11 | 0.08 | 0.06 | 0.10 | 0.10 | 0.11 | 0.07 | 0.12 |
[表46]
No.631 | No.632 | No.633 | No.634 | No.635 | No.636 | No.637 | No.638 | No.639 | No.640 | No.641 | No.642 | No.643 | No.644 | ||
莫耳% | SiO2 | 68.8 | 68.6 | 68.5 | 72.9 | 72.5 | 72.1 | 71.7 | 71.4 | 71.0 | 70.2 | 69.8 | 69.5 | 69.1 | 68.7 |
Al2 O3 | 12.8 | 12.7 | 12.7 | 13.5 | 13.4 | 13.4 | 13.3 | 13.2 | 13.2 | 13.0 | 13.0 | 12.9 | 12.8 | 12.8 | |
B2 O3 | 2.9 | 3.1 | 3.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | |
MgO | 5.9 | 5.9 | 5.9 | 3.1 | 3.6 | 4.1 | 4.6 | 5.1 | 5.6 | 6.6 | 7.1 | 7.6 | 8.1 | 8.6 | |
CaO | 3.7 | 3.7 | 3.7 | 3.9 | 3.9 | 3.9 | 3.9 | 3.8 | 3.8 | 3.8 | 3.8 | 3.7 | 3.7 | 3.7 | |
SrO | 2.0 | 2.0 | 2.0 | 2.2 | 2.2 | 2.1 | 2.1 | 2.1 | 2.1 | 2.1 | 2.1 | 2.1 | 2.1 | 2.0 | |
BaO | 3.8 | 3.8 | 3.8 | 4.0 | 4.0 | 4.0 | 4.0 | 3.9 | 3.9 | 3.9 | 3.9 | 3.8 | 3.8 | 3.8 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 81.5 | 81.3 | 81.2 | 86.4 | 85.9 | 85.5 | 85.0 | 84.6 | 84.1 | 83.3 | 82.8 | 82.4 | 81.9 | 81.5 | |
[MgO]+[CaO]+[SrO]+[BaO] | 15.5 | 15.5 | 15.4 | 13.2 | 13.7 | 14.1 | 14.6 | 15.0 | 15.5 | 16.3 | 16.8 | 17.2 | 17.7 | 18.1 | |
[SrO]+[BaO] | 5.8 | 5.8 | 5.8 | 6.2 | 6.2 | 6.1 | 6.1 | 6.1 | 6.0 | 6.0 | 5.9 | 5.9 | 5.9 | 5.8 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.5 | 0.5 | 0.6 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 6.1 | 6.3 | 6.5 | 3.7 | 3.7 | 3.7 | 3.7 | 3.6 | 3.6 | 3.6 | 3.6 | 3.5 | 3.5 | 3.5 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 332.6 | 328.8 | 325.1 | 374.7 | 375.9 | 377.1 | 378.2 | 379.4 | 380.5 | 382.9 | 384.0 | 385.2 | 386.3 | 387.5 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1746.8 | 1744.0 | 1741.1 | 1799.6 | 1796.9 | 1794.3 | 1791.6 | 1789.0 | 1786.4 | 1781.1 | 1778.4 | 1775.8 | 1773.2 | 1770.5 | |
熱膨脹係數(10-7 /℃) | 38.2 | 38.1 | 38.1 | 36.3 | 36.6 | 37.0 | 37.3 | 37.7 | 38.0 | 38.7 | 39.1 | 39.4 | 39.8 | 40.2 | |
密度(g/cm3 ) | 2.615 | 2.613 | 2.611 | 2.624 | 2.627 | 2.630 | 2.634 | 2.637 | 2.641 | 2.648 | 2.651 | 2.654 | 2.658 | 2.661 | |
應變點(℃) | 725 | 723 | 721 | 778 | 773 | 769 | 766 | 763 | 761 | 758 | 756 | 755 | 753 | 751 | |
緩冷點(℃) | 783 | 780 | 778 | 842 | 837 | 832 | 828 | 824 | 821 | 815 | 812 | 810 | 808 | 806 | |
軟化點(℃) | 1009 | 1006 | 1002 | 1094 | 1084 | 1075 | 1068 | 1063 | 1058 | 1049 | 1045 | 1039 | 1034 | 1027 | |
104.5 dPa·s(℃) | 1337 | 1334 | 1331 | 1425 | 1417 | 1409 | 1400 | 1392 | 1383 | 1366 | 1358 | 1349 | 1341 | 1332 | |
104.0 dPa·s(℃) | 1500 | 1498 | 1495 | 1593 | 1583 | 1573 | 1564 | 1555 | 1546 | 1528 | 1519 | 1510 | 1501 | 1492 | |
103.0 dPa·s(℃) | 1600 | 1597 | 1594 | 1698 | 1688 | 1679 | 1669 | 1660 | 1650 | 1629 | 1619 | 1609 | 1598 | 1587 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 81.1 | 80.8 | 80.6 | 82.2 | 82.5 | 82.7 | 83.0 | 83.3 | 83.6 | 84.2 | 84.5 | 84.8 | 85.1 | 85.4 | |
比楊氏模量(GPa/g·cm-3 ) | 31.0 | 30.9 | 30.9 | 31.3 | 31.4 | 31.5 | 31.5 | 31.6 | 31.7 | 31.8 | 31.9 | 31.9 | 32.0 | 32.1 | |
β-OH(mm-1 ) | 0.14 | 0.11 | 0.08 | 0.10 | 0.15 | 0.11 | 0.09 | 0.06 | 0.06 | 0.09 | 0.03 | 0.07 | 0.09 | 0.14 |
[表47]
No.645 | No.646 | No.647 | No.648 | No.649 | No.650 | No.651 | No.652 | No.653 | No.654 | No.655 | No.656 | No.657 | No.658 | ||
莫耳% | SiO2 | 68.3 | 72.8 | 72.4 | 72.1 | 71.7 | 71.3 | 71.0 | 70.2 | 69.9 | 69.5 | 69.1 | 68.8 | 68.4 | 72.0 |
Al2 O3 | 12.7 | 13.5 | 13.4 | 13.4 | 13.3 | 13.2 | 13.2 | 13.0 | 13.0 | 12.9 | 12.8 | 12.8 | 12.7 | 13.4 | |
B2 O3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | |
MgO | 9.1 | 6.3 | 6.3 | 6.2 | 6.2 | 6.2 | 6.1 | 6.1 | 6.0 | 6.0 | 6.0 | 5.9 | 5.9 | 6.2 | |
CaO | 3.7 | 0.8 | 1.3 | 1.8 | 2.3 | 2.8 | 3.3 | 4.3 | 4.8 | 5.3 | 5.8 | 6.3 | 6.8 | 3.9 | |
SrO | 2.0 | 2.2 | 2.2 | 2.1 | 2.1 | 2.1 | 2.1 | 2.1 | 2.1 | 2.1 | 2.1 | 2.0 | 2.0 | 0.1 | |
BaO | 3.8 | 4.0 | 4.0 | 4.0 | 4.0 | 3.9 | 3.9 | 3.9 | 3.9 | 3.8 | 3.8 | 3.8 | 3.8 | 4.0 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 81.0 | 86.3 | 85.9 | 85.4 | 85.0 | 84.6 | 84.1 | 83.3 | 82.8 | 82.4 | 82.0 | 81.5 | 81.1 | 85.4 | |
[MgO]+[CaO]+[SrO]+[BaO] | 18.6 | 13.3 | 13.7 | 14.2 | 14.6 | 15.0 | 15.5 | 16.3 | 16.8 | 17.2 | 17.6 | 18.1 | 18.5 | 14.2 | |
[SrO]+[BaO] | 5.8 | 6.2 | 6.2 | 6.1 | 6.1 | 6.1 | 6.0 | 6.0 | 5.9 | 5.9 | 5.9 | 5.8 | 5.8 | 4.1 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 3.5 | 6.8 | 6.3 | 5.8 | 5.2 | 4.7 | 4.1 | 3.1 | 2.5 | 2.0 | 1.4 | 0.9 | 0.4 | 5.7 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 388.7 | 390.5 | 389.0 | 387.6 | 386.1 | 384.6 | 383.2 | 380.2 | 378.8 | 377.3 | 375.8 | 374.4 | 372.9 | 360.9 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1767.9 | 1795.4 | 1793.5 | 1791.5 | 1789.6 | 1787.6 | 1785.7 | 1781.8 | 1779.8 | 1777.9 | 1775.9 | 1774.0 | 1772.0 | 1788.5 | |
熱膨脹係數(10-7 /℃) | 40.5 | 34.1 | 34.8 | 35.4 | 36.2 | 36.9 | 37.6 | 39.1 | 39.9 | 40.7 | 41.4 | 42.2 | 42.9 | 34.8 | |
密度(g/cm3 ) | 2.665 | 2.617 | 2.621 | 2.626 | 2.630 | 2.635 | 2.640 | 2.649 | 2.653 | 2.658 | 2.662 | 2.667 | 2.672 | 2.599 | |
應變點(℃) | 749 | 773 | 771 | 769 | 767 | 764 | 762 | 757 | 754 | 751 | 748 | 745 | 742 | 766 | |
緩冷點(℃) | 804 | 838 | 834 | 831 | 828 | 825 | 821 | 814 | 811 | 807 | 803 | 799 | 796 | 827 | |
軟化點(℃) | 1021 | 1083 | 1077 | 1071 | 1066 | 1062 | 1058 | 1049 | 1045 | 1040 | 1034 | 1029 | 1023 | 1064 | |
104.5 dPa·s(℃) | 1323 | 1416 | 1409 | 1403 | 1396 | 1389 | 1382 | 1368 | 1360 | 1353 | 1345 | 1338 | 1330 | 1395 | |
104.0 dPa·s(℃) | 1483 | 1582 | 1574 | 1566 | 1559 | 1551 | 1544 | 1529 | 1521 | 1513 | 1504 | 1496 | 1487 | 1556 | |
103.0 dPa·s(℃) | 1577 | 1685 | 1678 | 1671 | 1664 | 1656 | 1648 | 1631 | 1622 | 1613 | 1604 | 1596 | 1587 | 1661 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 85.7 | 83.6 | 83.7 | 83.7 | 83.8 | 83.8 | 83.9 | 84.0 | 84.0 | 84.1 | 84.1 | 84.1 | 84.2 | 84.4 | |
比楊氏模量(GPa/g·cm-3 ) | 32.1 | 32.0 | 31.9 | 31.9 | 31.8 | 31.8 | 31.8 | 31.7 | 31.7 | 31.6 | 31.6 | 31.5 | 31.5 | 32.5 | |
β-OH(mm-1 ) | 0.06 | 0.08 | 0.04 | 0.13 | 0.11 | 0.04 | 0.09 | 0.07 | 0.10 | 0.14 | 0.04 | 0.05 | 0.13 | 0.12 |
[表48]
No.659 | No.660 | No.661 | No.662 | No.663 | No.664 | No.665 | No.666 | No.667 | No.668 | No.669 | No.670 | No.671 | No.672 | ||
莫耳% | SiO2 | 71.7 | 71.3 | 71.0 | 70.2 | 69.9 | 69.5 | 69.2 | 68.8 | 68.4 | 72.8 | 72.4 | 72.1 | 71.7 | 71.3 |
Al2 O3 | 13.3 | 13.2 | 13.2 | 13.0 | 13.0 | 12.9 | 12.8 | 12.8 | 12.7 | 13.5 | 13.4 | 13.4 | 13.3 | 13.2 | |
B2 O3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | |
MgO | 6.2 | 6.2 | 6.1 | 6.1 | 6.0 | 6.0 | 6.0 | 5.9 | 5.9 | 6.3 | 6.3 | 6.2 | 6.2 | 6.2 | |
CaO | 3.9 | 3.8 | 3.8 | 3.8 | 3.8 | 3.7 | 3.7 | 3.7 | 3.7 | 3.9 | 3.9 | 3.9 | 3.9 | 3.8 | |
SrO | 0.6 | 1.1 | 1.6 | 2.6 | 3.1 | 3.6 | 4.1 | 4.6 | 5.1 | 2.2 | 2.2 | 2.1 | 2.1 | 2.1 | |
BaO | 4.0 | 3.9 | 3.9 | 3.9 | 3.9 | 3.8 | 3.8 | 3.8 | 3.8 | 0.9 | 1.4 | 1.9 | 2.4 | 2.9 | |
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[SiO2 ]+[Al2 O3 ] | 85.0 | 84.6 | 84.1 | 83.3 | 82.8 | 82.4 | 82.0 | 81.6 | 81.1 | 86.3 | 85.9 | 85.4 | 85.0 | 84.6 | |
[MgO]+[CaO]+[SrO]+[BaO] | 14.6 | 15.0 | 15.5 | 16.3 | 16.8 | 17.2 | 17.6 | 18.0 | 18.5 | 13.3 | 13.7 | 14.2 | 14.6 | 15.0 | |
[SrO]+[BaO] | 4.6 | 5.0 | 5.5 | 6.5 | 7.0 | 7.4 | 7.9 | 8.4 | 8.9 | 3.1 | 3.6 | 4.0 | 4.5 | 5.0 | |
[B2 O3 ]/([SrO]+[BaO]) | 0.1 | 0.1 | 0.1 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 5.2 | 4.7 | 4.1 | 3.1 | 2.5 | 2.0 | 1.5 | 1.0 | 0.4 | 6.8 | 6.3 | 5.8 | 5.2 | 4.7 | |
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 366.1 | 371.3 | 376.5 | 386.9 | 392.1 | 397.3 | 402.5 | 407.7 | 412.9 | 343.7 | 350.0 | 356.4 | 362.7 | 369.0 | |
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1787.3 | 1786.1 | 1784.9 | 1782.5 | 1781.3 | 1780.1 | 1778.9 | 1777.7 | 1776.5 | 1792.6 | 1791.1 | 1789.7 | 1788.2 | 1786.7 | |
熱膨脹係數(10-7 /℃) | 35.7 | 36.6 | 37.5 | 39.3 | 40.2 | 41.2 | 42.1 | 43.0 | 43.9 | 32.5 | 33.4 | 34.3 | 35.3 | 36.3 | |
密度(g/cm3 ) | 2.610 | 2.622 | 2.633 | 2.655 | 2.667 | 2.678 | 2.689 | 2.701 | 2.712 | 2.531 | 2.550 | 2.569 | 2.588 | 2.606 | |
應變點(℃) | 765 | 763 | 762 | 757 | 755 | 753 | 750 | 748 | 745 | 769 | 768 | 766 | 765 | 763 | |
緩冷點(℃) | 825 | 823 | 820 | 815 | 811 | 808 | 805 | 801 | 797 | 830 | 829 | 827 | 825 | 823 | |
軟化點(℃) | 1062 | 1059 | 1057 | 1051 | 1047 | 1043 | 1038 | 1033 | 1029 | 1067 | 1065 | 1063 | 1061 | 1059 | |
104.5 dPa·s(℃) | 1390 | 1385 | 1380 | 1370 | 1365 | 1359 | 1354 | 1349 | 1343 | 1395 | 1392 | 1389 | 1386 | 1382 | |
104.0 dPa·s(℃) | 1551 | 1547 | 1542 | 1531 | 1525 | 1519 | 1513 | 1506 | 1499 | 1558 | 1554 | 1550 | 1547 | 1544 | |
103.0 dPa·s(℃) | 1656 | 1651 | 1645 | 1634 | 1628 | 1621 | 1615 | 1608 | 1602 | 1660 | 1657 | 1654 | 1651 | 1648 | |
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |
楊氏模量(GPa) | 84.3 | 84.2 | 84.0 | 83.8 | 83.7 | 83.5 | 83.4 | 83.3 | 83.2 | 85.6 | 85.3 | 85.0 | 84.8 | 84.5 | |
比楊氏模量(GPa/g·cm-3 ) | 32.3 | 32.1 | 31.9 | 31.6 | 31.4 | 31.2 | 31.0 | 30.8 | 30.7 | 33.8 | 33.5 | 33.1 | 32.8 | 32.4 | |
β-OH(mm-1 ) | 0.08 | 0.07 | 0.13 | 0.08 | 0.05 | 0.12 | 0.15 | 0.08 | 0.08 | 0.04 | 0.13 | 0.13 | 0.06 | 0.14 |
[表49]
No.673 | No.674 | No.675 | No.676 | No.677 | No.678 | No.679 | ||||
莫耳% | SiO2 | 71.0 | 70.2 | 69.9 | 69.5 | 69.1 | 68.8 | 68.4 | ||
Al2 O3 | 13.2 | 13.0 | 13.0 | 12.9 | 12.8 | 12.8 | 12.7 | |||
B2 O3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | |||
MgO | 6.1 | 6.1 | 6.0 | 6.0 | 6.0 | 5.9 | 5.9 | |||
CaO | 3.8 | 3.8 | 3.8 | 3.7 | 3.7 | 3.7 | 3.7 | |||
SrO | 2.1 | 2.1 | 2.1 | 2.1 | 2.1 | 2.0 | 2.0 | |||
BaO | 3.4 | 4.4 | 4.9 | 5.4 | 5.9 | 6.4 | 6.9 | |||
ZnO | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |||
SnO2 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |||
[SiO2 ]+[Al2 O3 ] | 84.1 | 83.3 | 82.8 | 82.4 | 82.0 | 81.5 | 81.1 | |||
[MgO]+[CaO]+[SrO]+[BaO] | 15.5 | 16.3 | 16.8 | 17.2 | 17.7 | 18.1 | 18.5 | |||
[SrO]+[BaO] | 5.5 | 6.5 | 7.0 | 7.5 | 8.0 | 8.4 | 8.9 | |||
[B2 O3 ]/([SrO]+[BaO]) | 0.1 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | 0.0 | |||
[Al2 O3 ]+[B2 O3 ]-[CaO]-[SrO]-[BaO] | 4.1 | 3.1 | 2.5 | 2.0 | 1.4 | 0.9 | 0.4 | |||
[SiO2 ]+14[Al2 O3 ]-15[B2 O3 ] +6[MgO]+[CaO]+14[SrO]+16[BaO] | 375.4 | 388.0 | 394.4 | 400.7 | 407.0 | 413.4 | 419.7 | |||
17.8[SiO2 ]+23.1[Al2 O3 ]+3.7[B2 O3 ]+12.9[MgO] +14.1[CaO]+15.5[SrO]+15.0[BaO]+7.2[ZnO] | 1785.2 | 1782.2 | 1780.7 | 1779.3 | 1777.8 | 1776.3 | 1774.8 | |||
熱膨脹係數(10-7 /℃) | 37.3 | 39.4 | 40.5 | 41.6 | 42.6 | 43.7 | 44.7 | |||
密度(g/cm3 ) | 2.625 | 2.663 | 2.682 | 2.701 | 2.720 | 2.739 | 2.757 | |||
應變點(℃) | 762 | 757 | 755 | 753 | 750 | 748 | 746 | |||
緩冷點(℃) | 821 | 815 | 811 | 808 | 804 | 801 | 797 | |||
軟化點(℃) | 1056 | 1051 | 1048 | 1044 | 1039 | 1035 | 1031 | |||
104.5 dPa·s(℃) | 1379 | 1371 | 1367 | 1363 | 1359 | 1355 | 1351 | |||
104.0 dPa·s(℃) | 1540 | 1532 | 1528 | 1523 | 1517 | 1511 | 1505 | |||
103.0 dPa·s(℃) | 1644 | 1635 | 1631 | 1626 | 1621 | 1616 | 1611 | |||
102.5 dPa·s(℃) | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | 未測定 | |||
楊氏模量(GPa) | 84.2 | 83.6 | 83.3 | 83.1 | 82.8 | 82.5 | 82.2 | |||
比楊氏模量(GPa/g·cm-3 ) | 32.1 | 31.4 | 31.1 | 30.8 | 30.4 | 30.1 | 29.8 | |||
β-OH(mm-1 ) | 0.08 | 0.08 | 0.05 | 0.13 | 0.09 | 0.15 | 0.12 |
首先,將以成為表中的玻璃組成的方式調合玻璃原料而成的玻璃配合料放入鉑坩堝中,然後於1600℃~1650℃下熔融24小時。在玻璃配合料熔解時,使用鉑攪拌棒加以攪拌,進行均質化。繼而,使熔融玻璃流出至碳板上而成形為板狀後,於緩冷點附近的溫度下緩冷30分鐘。針對所獲得的各試樣,對熱膨脹係數、密度、應變點、緩冷點、軟化點、高溫黏度104.5
dPa·s下的溫度、高溫黏度104.0
dPa·s下的溫度、高溫黏度103.0
dPa·s下的溫度、高溫黏度102.5
dPa·s下的溫度、楊氏模量、比楊氏模量、β-OH進行評價。
熱膨脹係數是利用膨脹計測定30℃~380℃的溫度範圍內的平均熱膨脹係數而得的值。
密度是利用周知的阿基米德(Archimedes)法進行測定而得的值。
應變點、緩冷點、軟化點是基於ASTM C336、C338的方法進行測定而得的值。
高溫黏度104.5
dPa·s、高溫黏度104.0
dPa·s、高溫黏度103.0
dPa·s、高溫黏度102.5
dPa·s下的溫度是利用鉑球提拉法進行測定而得的值。
楊氏模量是藉由彎曲共振法進行測定而得的值。
比楊氏模量是將楊氏模量除以密度而得的值。
β-OH是利用所述方法進行測定而得的值。
根據表1~表49可知,試樣No.1~試樣No.679的應變點高且於玻璃組成中不含Y2
O3
與La2
O3
,因此認為可使製造成本低廉化。
[實施例2]
表50是表示β-OH與熱收縮率的關係的資料。試樣A與試樣B具有試樣No.1的玻璃組成,但β-OH不同。針對該試樣A、試樣B,測定於500℃下保持1小時時的熱收縮率與於600℃下保持1小時時的熱收縮率。
[表50]
A | B | |
玻璃組成 | 試樣No.1 | 試樣No.1 |
β-OH | 0.13 mm-1 | 0.36 mm-1 |
500℃-1 hr.的熱收縮率 | 8 ppm | 10 ppm |
600℃-1 hr.的熱收縮率 | 31 ppm | 39 ppm |
熱收縮率可以如下方式進行測定。首先,對玻璃板平行地刻印兩處直線狀的標記後,相對於該標記而在垂直的方向上進行分割,從而獲得兩個玻璃片。繼而,針對其中一玻璃片,自常溫以5℃/分鐘的升溫速度升溫至500℃或600℃,於500℃或600℃下保持1小時後,以5℃/分鐘的降溫速度冷卻至常溫。繼而,以分割面對齊的方式排列熱處理完畢的玻璃片與未熱處理的玻璃片,利用接著膠帶加以固定後,測定兩者的標記的偏移量ΔL。最後測定ΔL/L0
的值,將其設為熱收縮率。再者,L0
是熱處理前的玻璃片的長度。
根據表50可知,即便於玻璃組成相同的情況下,β-OH低者亦可減低熱收縮率。
[實施例3]
針對具有所述試樣No.1、試樣No.15、試樣No.115的玻璃組成的玻璃,使用已存的設備於先前的溫度條件下進行熔融,藉由溢流下拉法而成形玻璃板後,藉由螢光X射線分析來測定微量成分的含量。將其結果示於表51中。
[表51]
[實施例4]
(wt:ppm) | No.1 | No.15 | No.115 |
Rh | 0.8 | 0.5 | 0.6 |
Pt | 0.1 | 0.1 | 0.1 |
Ir | 0.1~1 | 0.1~1 | 0.1~1 |
ZrO2 | 300 | 350 | 320 |
Sb2 O3 | <30 | <30 | <30 |
Fe2 O3 | 100 | 90 | 110 |
MoO3 | 未測定 | 未測定 | 未測定 |
TiO2 | 10 | 8 | 12 |
Na2 O | 120 | 90 | 100 |
針對具有所述試樣No.1、試樣No.15、試樣No.115的玻璃組成的玻璃,使用與[實施例3]中所使用的設備不同的已存設備於高於先前的溫度下進行熔融,藉由溢流下拉法而成形玻璃板後,藉由螢光X射線分析來測定微量成分的含量。將其結果示於表52中。
[表52]
(wt:ppm) | No.1 | No.15 | No.115 |
Rh | 0.6 | 0.4 | 0.9 |
Pt | 未測定 | 未測定 | 未測定 |
Ir | 未測定 | 未測定 | 未測定 |
ZrO2 | 1200 | 500 | 1500 |
Sb2 O3 | 未測定 | 未測定 | 未測定 |
Fe2 O3 | 130 | 300 | 100 |
MoO3 | 10 | 3 | 20 |
TiO2 | 未測定 | 未測定 | 未測定 |
Na2 O | 未測定 | 未測定 | 未測定 |
無
無
Claims (4)
- 一種無鹼玻璃板,其特徵在於:作為玻璃組成,以莫耳%計而含有55%~80%的SiO2、10%~25%的Al2O3、0.4%~4%的B2O3、0.5%~30%的MgO、0%~7%的CaO、0%~5%的SrO、0.5%~15%的BaO、0%~5%的ZnO、0%~未滿1.0%的Y2O3+La2O3,實質不含鹼金屬氧化物,且應變點為750℃以上,滿足17.8×[SiO2]+23.1×[Al2O3]+3.7×[B2O3]+12.9×[MgO]+14.1×[CaO]+15.5×[SrO]+15.0×[BaO]+7.2×[ZnO]≧1786莫耳%的關係。
- 如請求項1所述的無鹼玻璃板,其中滿足[SiO2]+14×[Al2O3]-15×[B2O3]+6×[MgO]+[CaO]+14×[SrO]+16×[BaO]≧360莫耳%的關係。
- 如請求項1或請求項2所述的無鹼玻璃板,其中Rh的含量為0.1質量ppm~3質量ppm。
- 如請求項1或請求項2所述的無鹼玻璃板,其中楊氏模量為82GPa以上。
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