TWI824179B - Coating and method for manufacturing the same - Google Patents
Coating and method for manufacturing the same Download PDFInfo
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- TWI824179B TWI824179B TW109131937A TW109131937A TWI824179B TW I824179 B TWI824179 B TW I824179B TW 109131937 A TW109131937 A TW 109131937A TW 109131937 A TW109131937 A TW 109131937A TW I824179 B TWI824179 B TW I824179B
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- particles
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- containing compound
- base material
- coating
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- 238000000576 coating method Methods 0.000 title claims abstract description 25
- 239000011248 coating agent Substances 0.000 title claims abstract description 24
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 7
- 238000000034 method Methods 0.000 title claims abstract description 5
- 239000002245 particle Substances 0.000 claims abstract description 95
- 239000000463 material Substances 0.000 claims abstract description 53
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000292 calcium oxide Substances 0.000 claims abstract description 8
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003086 colorant Substances 0.000 claims abstract description 6
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910001950 potassium oxide Inorganic materials 0.000 claims abstract description 4
- 150000001875 compounds Chemical class 0.000 claims description 46
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 41
- 239000001301 oxygen Substances 0.000 claims description 41
- 229910052760 oxygen Inorganic materials 0.000 claims description 41
- 239000000843 powder Substances 0.000 claims description 18
- 229920005989 resin Polymers 0.000 claims description 7
- 239000011347 resin Substances 0.000 claims description 7
- 239000000758 substrate Substances 0.000 claims description 7
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 235000013599 spices Nutrition 0.000 claims description 6
- 235000008632 Santalum album Nutrition 0.000 claims description 5
- 239000011230 binding agent Substances 0.000 claims description 5
- 239000002023 wood Substances 0.000 claims description 5
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 4
- 241000271309 Aquilaria crassna Species 0.000 claims description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 244000086363 Pterocarpus indicus Species 0.000 claims description 4
- 235000009984 Pterocarpus indicus Nutrition 0.000 claims description 4
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- 125000000129 anionic group Chemical group 0.000 claims description 4
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 4
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 4
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 4
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 4
- 239000000395 magnesium oxide Substances 0.000 claims description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 3
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 3
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 2
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- 229920000180 alkyd Polymers 0.000 claims description 2
- 239000010426 asphalt Substances 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- QXDMQSPYEZFLGF-UHFFFAOYSA-L calcium oxalate Chemical compound [Ca+2].[O-]C(=O)C([O-])=O QXDMQSPYEZFLGF-UHFFFAOYSA-L 0.000 claims description 2
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 claims description 2
- 229920001971 elastomer Polymers 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 2
- 239000001095 magnesium carbonate Substances 0.000 claims description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 2
- 239000002480 mineral oil Substances 0.000 claims description 2
- 235000010446 mineral oil Nutrition 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000003208 petroleum Substances 0.000 claims description 2
- 229920001568 phenolic resin Polymers 0.000 claims description 2
- 239000005011 phenolic resin Substances 0.000 claims description 2
- 229920006122 polyamide resin Polymers 0.000 claims description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 2
- 235000010333 potassium nitrate Nutrition 0.000 claims description 2
- 239000004323 potassium nitrate Substances 0.000 claims description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
- 239000004317 sodium nitrate Substances 0.000 claims description 2
- 235000010344 sodium nitrate Nutrition 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 2
- 239000008158 vegetable oil Substances 0.000 claims description 2
- 239000001993 wax Substances 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- 241000221035 Santalaceae Species 0.000 claims 2
- 239000002304 perfume Substances 0.000 claims 2
- 239000000377 silicon dioxide Substances 0.000 claims 2
- 235000012239 silicon dioxide Nutrition 0.000 claims 2
- 239000004927 clay Substances 0.000 claims 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 238000002156 mixing Methods 0.000 abstract description 3
- 239000000976 ink Substances 0.000 description 11
- 238000004040 coloring Methods 0.000 description 5
- 239000003973 paint Substances 0.000 description 4
- 240000000513 Santalum album Species 0.000 description 3
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 2
- 235000017491 Bambusa tulda Nutrition 0.000 description 2
- 241001330002 Bambuseae Species 0.000 description 2
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 2
- 239000011425 bamboo Substances 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- -1 calcium ions Chemical class 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- YAGKRVSRTSUGEY-UHFFFAOYSA-N ferricyanide Chemical compound [Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] YAGKRVSRTSUGEY-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 150000002927 oxygen compounds Chemical class 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000010803 wood ash Substances 0.000 description 1
Landscapes
- Materials For Medical Uses (AREA)
- Paints Or Removers (AREA)
Abstract
Description
本發明係有關於一種塗料及其製法。 The present invention relates to a coating and a preparation method thereof.
習知塗料被廣泛應用於生活、印刷如油墨、染料。染料、油墨會經轉移後滲透至紙層中,待油墨乾燥後便於該紙層上形成印跡。然而,對於印刷而言,油墨是否能順利的乾燥非常的重要,油墨易於印刷後固著速度太慢且固著性不佳,導致手或其他物體接觸後容易沾附油墨,影響印刷品的完整性。 It is known that coatings are widely used in daily life and printing such as inks and dyes. The dye and ink will penetrate into the paper layer after transfer. After the ink dries, it will facilitate the formation of imprints on the paper layer. However, for printing, it is very important whether the ink can dry smoothly. The ink is easy to fix after printing, and the fixation speed is too slow and the fixability is poor. As a result, the ink is easy to stick to the hands or other objects after contact, affecting the integrity of the printed matter. .
因此,有必要提供一種新穎且具有進步性之塗料,以解決上述之問題。 Therefore, it is necessary to provide a novel and progressive coating to solve the above problems.
本發明之主要目的在於提供一種塗料,其固著性佳及遮蓋力佳。 The main purpose of the present invention is to provide a coating with good fixation and hiding power.
為達成上述目的,本發明提供一種塗料,包括:一基料,其包括色料及連結料;及複數含氧化合物微粒,該複數含氧化合物微粒混合於該基料,該複數含氧化合物微粒包括氧化鈣微粒及氧化鉀微粒。 In order to achieve the above object, the present invention provides a coating, including: a base material, which includes a colorant and a binder; and a plurality of oxygen-containing compound particles, the plurality of oxygen-containing compound particles are mixed with the base material, the plurality of oxygen-containing compound particles include Calcium oxide particles and potassium oxide particles.
本發明另提供一種製造如上所述之塗料之製法,包括以下步驟:備一可燃地目標基材,燃燒該可燃地目標基材之後形成粉末狀之該複數含氧化 合物微粒及殘渣;篩除該殘渣;備該基料;混合該基料及該複數含氧化合物微粒使該複數含氧化合物微粒均勻混合於該基料中;其中,該可燃地目標基材包括木材、黏粉及材料粉。 The present invention also provides a method for manufacturing the coating as described above, which includes the following steps: preparing a combustible target substrate, and burning the combustible target substrate to form a powder of the plurality of oxidized compounds. Compound particles and residue; screen out the residue; prepare the base material; mix the base material and the plurality of oxygen-containing compound particles so that the plurality of oxygen-containing compound particles are evenly mixed in the base material; wherein, the flammable target base material includes Wood, sticky powder and material powder.
以下僅以實施例說明本發明可能之實施態樣,然並非用以限制本發明所欲保護之範疇,合先敘明。 The following examples are only used to illustrate the possible implementation modes of the present invention, but are not intended to limit the scope of protection of the present invention.
本發明之一較佳實施例,本發明之塗料包括一基料,其包括色料及連結料;及複數含氧化合物微粒,該複數含氧化合物微粒混合於該基料,該複數含氧化合物微粒包括氧化鈣微粒及氧化鉀微粒,藉此該塗料的固著性佳、遮覆性佳、增加容積、降低成本、調整塗料的酸鹼值、穩定性佳。具體地說,該色料包括陰離子色料微粒,該陰離子色料微粒可與該複數氧化合物微粒的金屬陽離子(如鈣離子、鉀離子、或其他金屬離子等)結合,故吸墨性、油墨固著性佳、光澤度佳、遮蓋力佳。 In a preferred embodiment of the present invention, the coating of the present invention includes a base material, which includes a colorant and a binder; and a plurality of oxygen-containing compound particles, the plurality of oxygen-containing compound particles are mixed with the base material, and the plurality of oxygen-containing compound particles Including calcium oxide particles and potassium oxide particles, the coating has good fixation and covering properties, increases volume, reduces costs, adjusts the pH value of the coating, and has good stability. Specifically, the coloring material includes anionic coloring material particles, and the anionic coloring material particles can be combined with the metal cations (such as calcium ions, potassium ions, or other metal ions, etc.) of the complex oxygen compound particles, so the ink absorbency and ink Good fixation, good gloss and good covering power.
於本實施例中該基料為油墨,該基料呈液態狀;該連結料包括樹脂,該連結料另包括溶劑、蠟、植物油、礦物油至少其中一者,該樹脂包括松香、松香衍生物、石油樹脂、瀝青、酚醛樹脂、醇酸樹脂、聚醯胺樹脂、纖維衍生物、橡膠、丙烯酸樹脂至少其中一者,而得以包覆及結合該複數含氧化合 物微粒。該色料另包括水可溶性偶氮類、不可溶偶氮類、酞花菁酮類、喹吖啶酮類、硫酸鹽類、氧化鋅、鉻酸鹽類至少其中一者,使該塗料具有顏色。 In this embodiment, the base material is ink, and the base material is in a liquid state; the linking material includes resin, and the linking material further includes at least one of solvent, wax, vegetable oil, and mineral oil, and the resin includes rosin and rosin derivatives. , petroleum resin, asphalt, phenolic resin, alkyd resin, polyamide resin, fiber derivatives, rubber, and at least one of acrylic resin to coat and combine the plurality of oxygen-containing compounds particles. The coloring material also includes at least one of water-soluble azos, insoluble azos, phthalocyanines, quinacridones, sulfates, zinc oxide, and chromates, so that the paint has color .
該氧化鈣微粒佔該複數含氧化合物微粒30.00wt%至90.00wt%;較佳地,該氧化鈣微粒佔該複數含氧化合物微粒40.00wt%至80.00wt%,具較佳地遮蓋力及油墨固著性、增加容積降低成本。 The calcium oxide particles account for 30.00wt% to 90.00wt% of the oxygen-containing compound particles; preferably, the calcium oxide particles account for 40.00wt% to 80.00wt% of the oxygen-containing compound particles, which has better hiding power and ink Fixability, increase volume and reduce cost.
該複數含氧化合物微粒另包括氧化鎂,以提升抗菌效果、且可降低油墨的黏度而易於印刷。 The plurality of oxygen-containing compound particles also include magnesium oxide to enhance the antibacterial effect and reduce the viscosity of the ink to facilitate printing.
該複數含氧化合物微粒另包括二氧化矽微粒,該二氧化矽微粒佔該複數含氧化合物微粒5.00wt%至12.00wt%,以增加整體的黏稠度、抗沉澱及消光性,並且可減少色料的使用以降低成本。 The plurality of oxygen-containing compound particles also include silica particles. The silica particles account for 5.00wt% to 12.00wt% of the plurality of oxygen-containing compound particles to increase the overall viscosity, anti-sedimentation and matting properties, and can reduce coloration. materials to reduce costs.
該複數含氧化合物微粒另包括氧化鋁、氧化鈉、氧化鐵至少其中一者;該複數含氧化合物微粒包括碳酸鈣微粒、碳酸鉀微粒、碳酸鈉微粒、碳酸鎂微粒、硝酸鈣微粒、硝酸鉀微粒、硝酸鈉微粒、草酸鈣微粒、鐵氰酸鹽至少其中一者,以提升塗料的黏稠度、抑制該塗料乾燥、維持塗料的酸鹼中和度且著色性及顯色性佳、可作為調色用;再者可減少色料的使用以降低製造成本。 The plurality of oxygen-containing compound particles further includes at least one of aluminum oxide, sodium oxide, and iron oxide; the plurality of oxygen-containing compound particles include calcium carbonate particles, potassium carbonate particles, sodium carbonate particles, magnesium carbonate particles, calcium nitrate particles, and potassium nitrate At least one of particles, sodium nitrate particles, calcium oxalate particles, and ferricyanate can increase the viscosity of the paint, inhibit the drying of the paint, maintain the acid-base neutralization of the paint, and have good coloring and color rendering properties. It can be used as For color mixing; in addition, the use of color materials can be reduced to reduce manufacturing costs.
該複數含氧化合物微粒的重量百分比範圍為1.00wt%至80.00wt%,該基料的重量百分比範圍為20.00%至99.00%;各該含氧化合物微粒之粒徑大於等於300目;該連結料包覆該複數含氧化合物微粒,故遮覆性佳並提供平滑或磨砂(如含氧化合物微粒之粒徑大於等於800目時)的表面效果;在使用時該複數含氧化合物微粒可結合於該基料均勻的分佈於被塗物(例如紙、牆)。 The weight percentage of the plurality of oxygen-containing compound particles ranges from 1.00wt% to 80.00wt%, and the weight percentage of the base material ranges from 20.00% to 99.00%; the particle size of each oxygen-containing compound particle is greater than or equal to 300 mesh; the connecting material The plurality of oxygen-containing compound particles is coated, so the covering property is good and the surface effect is smooth or frosted (for example, when the particle size of the oxygen-containing compound particles is greater than or equal to 800 mesh); when used, the plurality of oxygen-containing compound particles can be combined with The base material is evenly distributed on the substrate to be coated (such as paper, wall).
該塗料另包括複數香料微粒,該連結料包覆該複數香料微粒;於本實施例中,該香料微粒包括檀香粉、檀香灰、紫檀粉、紫檀灰、沉香粉、沉 香木灰至少其中一者,讓該塗料呈現香味且該複數香料微粒可分佈於該連結料中且穩定結合並一同被吸附於被塗物。 The coating also includes a plurality of spice particles, and the connecting material coats the plurality of spice particles; in this embodiment, the spice particles include sandalwood powder, sandalwood ash, rosewood powder, rosewood ash, agarwood powder, agarwood powder, and sandalwood powder. At least one of the fragrant wood ash allows the coating to present a fragrance, and the plurality of fragrance particles can be distributed in the binder and stably combined and adsorbed to the object to be coated together.
本發明另提供一種製造如上所述之塗料之製法,包括以下步驟:備一可燃地目標基材(包括竹枝(木材)、黏粉、材料粉),燃燒該可燃地目標基材之後形成粉末狀之該複數含氧化合物微粒及殘渣(如未燒盡之殘渣如竹枝(木材));篩除該殘渣;備該基料;混合該基料及該複數含氧化合物微粒使該複數含氧化合物微粒均勻混合於該基料中,步驟簡單而易於製造,該可燃地目標基材成本低廉、可產生該複數含氧化合物微粒、利用燃燒後的該可燃地目標基材所產生的該複數含氧化合物微粒具有環保及輕量化。 The present invention also provides a method for manufacturing the coating as described above, which includes the following steps: preparing a combustible target substrate (including bamboo branches (wood), sticky powder, and material powder), and burning the combustible target substrate to form a powder. The plurality of oxygenated compound particles and the residue (such as unburned residues such as bamboo branches (wood)); screening out the residue; preparing the base material; mixing the base material and the plurality of oxygenated compound particles to make the plurality of oxygenated compound particles Evenly mixed in the base material, the steps are simple and easy to manufacture. The combustible target base material is low in cost and can produce the plurality of oxygen-containing compound particles. The plurality of oxygen-containing compounds produced by burning the combustible target base material are utilized. Particles are environmentally friendly and lightweight.
Claims (9)
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101709152A (en) * | 2009-12-02 | 2010-05-19 | 中国农业科学院植物保护研究所 | Natural plant dye, preparation method and application thereof |
CN103975027A (en) * | 2011-12-09 | 2014-08-06 | 日本板硝子株式会社 | Photoluminescent pigment |
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2020
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101709152A (en) * | 2009-12-02 | 2010-05-19 | 中国农业科学院植物保护研究所 | Natural plant dye, preparation method and application thereof |
CN103975027A (en) * | 2011-12-09 | 2014-08-06 | 日本板硝子株式会社 | Photoluminescent pigment |
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