TWI766595B - Method for bonding two semiconductor structures - Google Patents

Method for bonding two semiconductor structures Download PDF

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TWI766595B
TWI766595B TW110106737A TW110106737A TWI766595B TW I766595 B TWI766595 B TW I766595B TW 110106737 A TW110106737 A TW 110106737A TW 110106737 A TW110106737 A TW 110106737A TW I766595 B TWI766595 B TW I766595B
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substrate
bonding layer
bonding
pattern
area
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TW110106737A
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TW202234464A (en
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蔡傅守
林永溢
呂泱儒
施宇隆
莊晴陽
林佶民
李昆儒
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聯華電子股份有限公司
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Abstract

The invention provides a method for bonding two semiconductor structures, the method includes the following steps: providing a substrate, an element pattern is formed on the substrate and a peripheral area is defined on the substrate, inclining the substrate at an angle, carrying out an oblique angle deposition step, forming a bonding layer on the substrate and the element pattern, and carrying out a planarization step to remove part of the bonding layer.

Description

鍵合兩半導體結構的方法 Method for bonding two semiconductor structures

本發明係有關於半導體製程,尤其是關於一種利用斜角沉積的方式,改善半導體晶圓鍵合品質的方法。 The present invention relates to a semiconductor manufacturing process, and more particularly, to a method for improving the bonding quality of semiconductor wafers by means of bevel deposition.

在半導體製程領域中,不同晶圓或是不同的裸晶(die)上可包含有不同的電路元件。為了節省產品空間,常將不同晶圓或是不同的裸晶相互鍵合,以達到立體堆疊結構,並且減小產品的面積提高產品的元件密度。 In the field of semiconductor manufacturing, different wafers or different dies may contain different circuit elements. In order to save product space, different wafers or different bare die are often bonded to each other to achieve a three-dimensional stack structure, and to reduce the area of the product and increase the component density of the product.

在不同的晶圓或裸晶彼此鍵合時,位於邊界的部分經常可能發生問題。舉例來說,在兩個裸晶彼此鍵合時,可能由於用於鍵合的材料層(例如氧化矽層)未能完整地覆蓋整個裸晶的邊界區,導致兩裸晶之間的邊界區產生一空隙,如此一來後續的製程中,該空隙處的結構較為脆弱,容易導致成品的損壞。 When different wafers or dies are bonded to each other, problems can often occur at the borders. For example, when two dies are bonded to each other, the boundary region between the two dies may not be completely covered by the material layer (such as a silicon oxide layer) used for bonding. A void is generated, so that in the subsequent manufacturing process, the structure at the void is relatively fragile, which is likely to cause damage to the finished product.

為了避免以上問題,本發明提供一種鍵合兩半導體結構的方法,包含提供一基底,該基底上形成有一圖案,且該基底上定義有一周邊區,將該基底傾斜一角度,並進行一斜角沉積步驟,在該基底與該圖案上形成一鍵合層,進行一平坦化步驟,移除部分該鍵合層,以及在該平坦化步驟之後,更包含將 該基底與一第二基底鍵合。 In order to avoid the above problems, the present invention provides a method for bonding two semiconductor structures, including providing a substrate, a pattern is formed on the substrate, and a peripheral area is defined on the substrate, the substrate is inclined at an angle, and a bevel angle is performed depositing step, forming a bonding layer on the substrate and the pattern, performing a planarizing step, removing part of the bonding layer, and after the planarizing step, further comprising: The substrate is bonded with a second substrate.

在一些實施例中,若晶圓或裸晶上的圖案(例如元件圖案)無法覆蓋完整的晶圓或是裸晶時,在鍵合層(例如氧化矽)沉積於圖案後,將會在晶圓或是裸晶留下部分未被沉積鍵合層的區域,該區域在兩片晶圓或裸晶彼此鍵合之後,會產生空隙並且影響元件的效能。本發明的其中一特徵在於,在另一些改善的實施例中,使用斜角沉積的方式,讓上述未被填滿的周邊區能夠充分地填滿鍵合層,因此在兩晶圓被彼此鍵合後,並不容易在周邊區產生空隙,提高元件的品質。 In some embodiments, if the pattern (eg, device pattern) on the wafer or die cannot cover the entire wafer or die, after the bonding layer (eg, silicon oxide) is deposited on the pattern, it will The circle or die leaves a portion of the area where the bonding layer is not deposited, which can create voids and affect the performance of the device after the two wafers or dies are bonded to each other. One of the features of the present invention is that, in other improved embodiments, an oblique deposition method is used, so that the unfilled peripheral area can be fully filled with the bonding layer, so that the two wafers are bonded to each other when the two wafers are bonded to each other. After bonding, it is not easy to generate voids in the peripheral area, which improves the quality of the device.

10:基底 10: Base

12:元件區 12: Component area

14:周邊區 14: Surrounding area

16:元件圖案 16: Component pattern

18:未填滿區域 18:Unfilled area

20:鍵合層 20: Bonding layer

30:基底 30: Base

40:突出側壁 40: Protruding side walls

第1圖到第3圖繪示根據本發明一實施例的鍵合兩晶圓的剖面結構流程示意圖。 FIG. 1 to FIG. 3 are schematic diagrams illustrating a cross-sectional structure flow of bonding two wafers according to an embodiment of the present invention.

第4圖到第6圖繪示根據本發明另一實施例的鍵合兩晶圓的剖面結構流程示意圖。 FIG. 4 to FIG. 6 are schematic diagrams illustrating a cross-sectional structure flow of bonding two wafers according to another embodiment of the present invention.

為使熟習本發明所屬技術領域之一般技藝者能更進一步了解本發明,下文特列舉本發明之較佳實施例,並配合所附圖式,詳細說明本發明的構成內容及所欲達成之功效。 In order to enable those of ordinary skill in the technical field to which the present invention pertains to further understand the present invention, preferred embodiments of the present invention are specifically listed below, and in conjunction with the accompanying drawings, the composition of the present invention and the desired effect will be described in detail. .

為了方便說明,本發明之各圖式僅為示意以更容易了解本發明,其詳細的比例可依照設計的需求進行調整。在文中所描述對於圖形中相對元件之上下關係,在本領域之人皆應能理解其係指物件之相對位置而言,因此皆可以 翻轉而呈現相同之構件,此皆應同屬本說明書所揭露之範圍,在此容先敘明。 For the convenience of description, the drawings of the present invention are only schematic diagrams to facilitate the understanding of the present invention, and the detailed proportions thereof can be adjusted according to design requirements. As for the upper and lower relationship of the relative elements in the drawings described in the text, those skilled in the art should understand that it refers to the relative positions of the objects, so they can be Turning over to present the same components should all fall within the scope disclosed in this specification, and will be described here first.

請參考第1圖到第3圖,第1圖到第3圖繪示根據本發明一實施例的鍵合兩晶圓的剖面結構流程示意圖。如第1圖所示,首先,提供一基底10,基底10上包含有元件區12以及周邊區14,其中元件區12上包含有至少一元件圖案16,元件圖案16例如為各種電子元件圖案,如導電線路、電晶體、開關、電容、電阻等。而元件圖案16形成於基底10上的元件區12內,卻未形成於周邊區14內。 Please refer to FIGS. 1 to 3. FIGS. 1 to 3 are schematic diagrams illustrating a cross-sectional structure flow of bonding two wafers according to an embodiment of the present invention. As shown in FIG. 1, first, a substrate 10 is provided, the substrate 10 includes an element area 12 and a peripheral area 14, wherein the element area 12 includes at least one element pattern 16, and the element pattern 16 is, for example, various electronic element patterns, Such as conductive lines, transistors, switches, capacitors, resistors, etc. The device pattern 16 is formed in the device region 12 on the substrate 10 but not formed in the peripheral region 14 .

此處所述的基底10例如為常見的半導體基底,如矽基底、矽鍺基底、碳化矽基底、絕緣覆矽基底(silicon-on-insulator,SOI),或由其他半導體材料製成的基底。在實務上,此處所述的基底10可能是一整片晶圓(wafer)或是經過切割的裸晶(die),均屬於本發明的涵蓋範圍內。 The substrate 10 described here is, for example, a common semiconductor substrate, such as a silicon substrate, a silicon germanium substrate, a silicon carbide substrate, a silicon-on-insulator (SOI) substrate, or a substrate made of other semiconductor materials. In practice, the substrate 10 described herein may be a whole wafer or a diced die, which are all within the scope of the present invention.

另外值得注意的是,在一些實施例中,元件圖案16靠近周邊區14的地方可能會產生類似斜角的剖面結構,其產生的原因可能包含因為元件圖案靠近周邊區的部分,所具有的元件較少或是排列較為鬆散,因此導致該區域的應力支撐比起其他區域略低。不過本發明不限定元件圖案16必須要包含有斜角,不論元件圖案16的剖面是否包含有斜角均屬於本發明的涵蓋範圍內。 It is also worth noting that, in some embodiments, a cross-sectional structure similar to an oblique angle may be generated where the element pattern 16 is close to the peripheral area 14 , and the reason for this may include that the part of the element pattern close to the peripheral area has elements Fewer or looser arrangements result in slightly lower stress support in this area than in other areas. However, the present invention does not limit that the element pattern 16 must include an oblique angle, and whether or not the cross-section of the element pattern 16 includes an oblique angle falls within the scope of the present invention.

如第2圖所示,為了讓基底10與另一片基底(圖未示)進行鍵合,在基底10上沉積一鍵合層20,其中可以用物理氣相沉積(PVD)、化學氣相沉積(CVD)或原子層沉積(ALD)等方式形成鍵合層20,鍵合層20的材質例如為氧化矽,但不限於此。其中鍵合層20覆蓋住元件區12的元件圖案16以及部份的周邊區14。接著,可能會經過一次平坦化步驟,例如為化學機械研磨(CMP)以移除多餘的鍵合 層20。值得注意的是,在一些情況中,鍵合層20可能因為在沉積過程中並未沉積足夠的厚度在周邊區14內,或是因為鍵合層20在平坦化步驟過程中,在周邊區14內的鍵合層20被移除的速率較快(因為靠近邊界受到的應力可能更大)等原因,導致平坦化步驟後,鍵合層20並未完整地覆蓋周邊區14,導致周邊區14的部分基底10被曝露,在此可以定義出一未填滿區域18(如第2圖所示)。或是在一些實施例中,雖然鍵合層20完整地覆蓋周邊區14而沒有基底10被曝露,但位於周邊區14的鍵合層20的頂面較低(比位於元件圖案16上的鍵合層20頂面更低),也可能會產生未填滿區域18。以上若存在有未填滿區域的情況,都可能會影響到後續鍵合步驟。 As shown in FIG. 2, in order to bond the substrate 10 with another substrate (not shown), a bonding layer 20 is deposited on the substrate 10, wherein physical vapor deposition (PVD), chemical vapor deposition can be used. The bonding layer 20 is formed by means of (CVD) or atomic layer deposition (ALD), and the material of the bonding layer 20 is silicon oxide, for example, but not limited thereto. The bonding layer 20 covers the device pattern 16 of the device region 12 and part of the peripheral region 14 . Next, there may be a planarization step, such as chemical mechanical polishing (CMP), to remove excess bonds Layer 20. It should be noted that, in some cases, the bonding layer 20 may not be deposited in sufficient thickness in the peripheral region 14 during the deposition process, or because the bonding layer 20 may be in the peripheral region 14 during the planarization step. The inner bonding layer 20 is removed at a faster rate (because the stress close to the boundary may be greater) and other reasons, resulting in that after the planarization step, the bonding layer 20 does not completely cover the peripheral area 14, resulting in the peripheral area 14 A portion of the substrate 10 is exposed, where an underfilled area 18 may be defined (as shown in FIG. 2). Or in some embodiments, although the bonding layer 20 completely covers the peripheral region 14 without the substrate 10 being exposed, the top surface of the bonding layer 20 on the peripheral region 14 is lower (than the bonding layer 20 on the element pattern 16) The top surface of the lamination layer 20 is lower), an underfilled area 18 may also be created. If there are any underfilled areas above, it may affect the subsequent bonding steps.

如第3圖所示,當將基底10與另一片基底30透過接觸鍵合層20彼此鍵合在一起時,由於上述所留下的未填滿區域18存在,因此在基底10與基底30之間會留下空隙(也就是未填滿區域18)。後續步驟中,該空隙會成為結構上的薄弱點,造成元件容易從此處斷裂或是分離,且若經歷一些浸泡的製程,溶劑也可能會從該空隙滲入到兩基底之間,不利於產品的品質。 As shown in FIG. 3 , when the substrate 10 and the other substrate 30 are bonded to each other through the contact bonding layer 20 , due to the existence of the unfilled area 18 left above, there is no gap between the substrate 10 and the substrate 30 . A gap will be left between (ie, the area 18 is not filled). In the subsequent steps, the gap will become a weak point in the structure, which will cause the component to easily break or separate from here. If it undergoes some soaking processes, the solvent may also penetrate into the gap between the two substrates, which is not conducive to the product quality. quality.

為了避免上述情況的發生,本發明提出另一種改良的鍵合兩晶圓的方法。請參考第4圖到第6圖,第4圖到第6圖繪示根據本發明另一實施例的鍵合兩晶圓的剖面結構流程示意圖。首先,第4圖接續第1圖的結構,也就是說與上述實施例相同,提供一基底10,基底10上包含有元件區12以及周邊區14,其中元件區12上包含有至少一元件圖案16,元件圖案16例如為各種電子元件圖案,如導電線路、電晶體、開關、電容、電阻等。而元件圖案16形成於基底10上的元件區12內,卻未形成於周邊區14內。 In order to avoid the above situation, the present invention proposes another improved method for bonding two wafers. Please refer to FIGS. 4 to 6 . FIGS. 4 to 6 are schematic diagrams illustrating a cross-sectional structure flow of bonding two wafers according to another embodiment of the present invention. First, FIG. 4 continues the structure of FIG. 1, that is to say, the same as the above-mentioned embodiment, a substrate 10 is provided, the substrate 10 includes an element area 12 and a peripheral area 14, wherein the element area 12 includes at least one element pattern. 16. The element pattern 16 is, for example, various electronic element patterns, such as conductive lines, transistors, switches, capacitors, resistors, and the like. The device pattern 16 is formed in the device region 12 on the substrate 10 but not formed in the peripheral region 14 .

接下來如第4圖所示,沉積一鍵合層20。本實施例與上述實施例不同之處在於,本實施例在進行沉積步驟以形成鍵合層20時,先將基底10傾斜一角度,本實施例中並不特定限制角度,僅須滿足傾斜後周邊區14的水平位置高於元件區12內的元件圖案16即可。接著同樣以物理氣相沉積(PVD)、化學氣相沉積(CVD)或原子層沉積(ALD)等方式形成鍵合層20。由於沉積步驟會先從水平位置較高處開始沉積,因此在傾斜基底10之後,鍵合層20更容易填滿周邊區14,因此相較於上述實施例更不容易產生未填滿區域。 Next, as shown in FIG. 4, a bonding layer 20 is deposited. The difference between this embodiment and the above-mentioned embodiment is that when the deposition step is performed to form the bonding layer 20 in this embodiment, the substrate 10 is first inclined at an angle. The horizontal position of the peripheral area 14 may be higher than that of the element patterns 16 in the element area 12 . Next, the bonding layer 20 is formed by physical vapor deposition (PVD), chemical vapor deposition (CVD), or atomic layer deposition (ALD). Since the deposition step starts from a higher horizontal position first, after the substrate 10 is tilted, the bonding layer 20 is more likely to fill the peripheral region 14 , and thus less likely to generate an unfilled region than the above-described embodiment.

在本發明的一些實施例中,傾斜基底角度後進行沉積的方法,也可以搭配旋轉基底等製程進行,以提高沉積的材料層的均勻度。舉例來說,可以用定速旋轉基底搭配傾斜沉積製程,如此一來,基底的每一個不同邊界都可沉積均勻厚度的材料層。上述實施例也屬於本發明的涵蓋範圍內。 In some embodiments of the present invention, the deposition method after tilting the substrate angle can also be performed in conjunction with processes such as rotating the substrate, so as to improve the uniformity of the deposited material layer. For example, a constant-speed rotating substrate can be used with an oblique deposition process, so that a layer of material of uniform thickness can be deposited on each of the different boundaries of the substrate. The above-described embodiments also fall within the scope of the present invention.

接下來,如第5圖所示,將基底10回到原本的水平面(進行傾斜之前的水平方向)後,進行平坦化步驟,以移除多餘的鍵合層20,然後如第6圖所示,將另外一個基底30接觸基底10上的鍵合層20,以鍵合基底10與基底30。 Next, as shown in FIG. 5, after returning the substrate 10 to the original horizontal plane (the horizontal direction before tilting), a planarization step is performed to remove the excess bonding layer 20, and then as shown in FIG. 6 , the other substrate 30 is brought into contact with the bonding layer 20 on the substrate 10 to bond the substrate 10 and the substrate 30 .

值得注意的是,本實施例中因為在沉積鍵合層20之前,先將基底10傾斜一角度(如第4圖所示),所以沉積過程中更容易把基底10上的周邊區14優先填滿,也有可能會突出部分的周邊區14,因此在後續進行平坦化步驟完成後(第5圖),周邊區14內的鍵合層20可能會包含有一突出側壁40。該突出側壁40可以有效地保護基底10與基底30之間的鍵合結構,而不容易出現類似上述第一實施例(第3圖)所示的結構薄弱點。因此也有助於提高半導體元件的品質。 It is worth noting that in this embodiment, since the substrate 10 is inclined at an angle (as shown in FIG. 4 ) before the bonding layer 20 is deposited, it is easier to preferentially fill the peripheral region 14 on the substrate 10 during the deposition process. If it is full, a portion of the peripheral area 14 may protrude. Therefore, after the subsequent planarization step is completed (FIG. 5), the bonding layer 20 in the peripheral area 14 may include a protruding sidewall 40. The protruding sidewalls 40 can effectively protect the bonding structure between the substrate 10 and the substrate 30 , and are not prone to structural weak points similar to those shown in the first embodiment ( FIG. 3 ). Therefore, it also contributes to the improvement of the quality of the semiconductor element.

綜上所述,在一些實施例中,例如第1圖至第3圖所示的實施例,若晶圓或裸晶上的圖案(例如元件圖案)無法覆蓋完整的晶圓或是裸晶時,在鍵合層(例如氧化矽)沉積於圖案後,將會在晶圓或是裸晶留下部分未被沉積鍵合層的區域,該區域在兩片晶圓或裸晶彼此鍵合之後,會產生空隙並且影響元件的效能。本發明的其中一特徵在於,在另一些改善的實施例中(例如第4圖至第6圖所示的實施例),使用斜角沉積的方式,讓上述未被填滿的周邊區能夠充分地填滿鍵合層,因此在兩晶圓被彼此鍵合後,並不容易在周邊區產生空隙,提高元件的品質。 To sum up, in some embodiments, such as the embodiments shown in FIG. 1 to FIG. 3 , if the pattern (eg device pattern) on the wafer or die cannot cover the entire wafer or die , After the bonding layer (such as silicon oxide) is deposited on the pattern, there will be a part of the wafer or bare die where the bonding layer is not deposited. This area is after the two wafers or bare die are bonded to each other. , will create voids and affect the performance of the device. One of the features of the present invention is that in other improved embodiments (such as the embodiments shown in FIGS. 4 to 6 ), the method of bevel deposition is used, so that the above-mentioned unfilled peripheral area can be fully Therefore, after the two wafers are bonded to each other, it is not easy to generate voids in the peripheral area, which improves the quality of the device.

以上所述僅為本發明之較佳實施例,凡依本發明申請專利範圍所做之均等變化與修飾,皆應屬本發明之涵蓋範圍。 The above descriptions are only preferred embodiments of the present invention, and all equivalent changes and modifications made according to the scope of the patent application of the present invention shall fall within the scope of the present invention.

10:基底 10: Base

12:元件區 12: Component area

14:周邊區 14: Surrounding area

16:元件圖案 16: Component pattern

20:鍵合層 20: Bonding layer

Claims (6)

一種鍵合兩半導體結構的方法,包含:提供一基底,該基底上形成有一元件圖案,且該基底上定義有一周邊區;將該基底傾斜一角度,並進行一斜角沉積步驟,在該基底與該元件圖案上形成一鍵合層;該斜角沉積步驟完成後,先將該基底回復至一原先水平方向,然後進行一平坦化步驟,移除部分該鍵合層。 A method for bonding two semiconductor structures, comprising: providing a substrate on which an element pattern is formed, and defining a peripheral region on the substrate; inclining the substrate at an angle, and performing an oblique angle deposition step, on the substrate A bonding layer is formed on the element pattern; after the oblique deposition step is completed, the substrate is first restored to an original horizontal direction, and then a planarization step is performed to remove part of the bonding layer. 如申請專利範圍第1項所述的方法,其中,在該斜角沉積步驟後,該基底上的該周邊區內包含有該鍵合層。 The method of claim 1, wherein the bonding layer is included in the peripheral region on the substrate after the bevel deposition step. 如申請專利範圍第1項所述的方法,其中該基底上的該圖案也具有一斜角,該斜角靠近該周邊區。 The method of claim 1, wherein the pattern on the substrate also has a bevel, and the bevel is close to the peripheral area. 如申請專利範圍第1項所述的方法,其中,在該平坦化步驟之後,更包含將該基底與一第二基底鍵合。 The method of claim 1, wherein after the planarizing step, further comprising bonding the substrate with a second substrate. 如申請專利範圍第4項所述的方法,其中,在該基底與該第二基底鍵合之後,該鍵合層位於該基底與該第二基底之間的該周邊區中。 The method of claim 4, wherein after the substrate and the second substrate are bonded, the bonding layer is located in the peripheral region between the substrate and the second substrate. 如申請專利範圍第1項所述的方法,其中該鍵合層包含有氧化矽。 The method of claim 1, wherein the bonding layer comprises silicon oxide.
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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100248463A1 (en) * 2009-03-31 2010-09-30 Tobias Letz Enhancing adhesion of interlayer dielectric materials of semiconductor devices by suppressing silicide formation at the substrate edge
TW201234449A (en) * 2010-10-19 2012-08-16 Lam Res Corp Methods for depositing bevel protective film

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100248463A1 (en) * 2009-03-31 2010-09-30 Tobias Letz Enhancing adhesion of interlayer dielectric materials of semiconductor devices by suppressing silicide formation at the substrate edge
TW201234449A (en) * 2010-10-19 2012-08-16 Lam Res Corp Methods for depositing bevel protective film

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