TWI749322B - Elastic conductive composite fabric - Google Patents
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本發明涉及智慧穿戴式產品領域,尤其涉及一種彈性導電複合織物。 The invention relates to the field of smart wearable products, in particular to an elastic conductive composite fabric.
近年來,人們對智慧穿戴式產品的需求越來越高,而隨著智慧穿戴式產品的發展,智慧穿戴式產品的使用定位主要以運動、定位、通話等為主,特別是在健康休閒生活的風潮下,運動健身成為智慧穿戴式產品的重要應用領域,運動過程中肢體運動(如:屈曲和伸展等)的變換及幅度,直接影響健身的成效;然而,不當的運動,可能造成永久性的傷害。現有技術中,智慧穿戴式產品常由導電織物製作而成。現有技術中的導電織物通常為高彈性導電針織布,該類織物通過調整超細金屬纖維與彈性紗線的混紡比率,以控制導電織物的手感、高彈性及高導電性。然而,現有技術中的高彈性導電針織布並不能通過高彈性導電針織布直觀的瞭解使用者的肢體運動的變換及幅度。 In recent years, people’s demand for smart wearable products has increased. With the development of smart wearable products, the positioning of smart wearable products is mainly based on sports, positioning, and calls, especially in healthy and leisure life. Under the current trend, sports fitness has become an important application field of smart wearable products. The transformation and amplitude of body movements (such as flexion and extension) during exercise directly affects the effectiveness of fitness; however, improper exercise may cause permanent s damage. In the prior art, smart wearable products are often made of conductive fabrics. The conductive fabric in the prior art is usually a highly elastic conductive knitted fabric. This type of fabric adjusts the blending ratio of ultrafine metal fibers and elastic yarns to control the feel, high elasticity and high conductivity of the conductive fabric. However, the highly elastic conductive knitted fabric in the prior art cannot intuitively understand the change and amplitude of the user's limb movement through the highly elastic conductive knitted fabric.
有鑑於此,本發明提供一種能夠直觀瞭解使用者的肢體運動的變換及幅度的彈性導電複合織物。 In view of this, the present invention provides an elastic conductive composite fabric that can intuitively understand the change and amplitude of the user's limb movement.
一種彈性導電複合織物,包括一織物層及一形成在所述織物層上的彈性導電層。所述織物層具有彈性。所述彈性導電層由至少一彈性體及導電 填料複合而成。所述彈性導電複合織物的電阻值與彈性應變增量滿足如下關係:R T =R+nε/R T =R+m e nε 。其中,ε為彈性應變增量;R為彈性應變增量為0時的電阻值;RT為所述彈性導電複合織物受到外力發生形變時的電阻值;m和n是係數,為小數或整數。 An elastic conductive composite fabric includes a fabric layer and an elastic conductive layer formed on the fabric layer. The fabric layer has elasticity. The elastic conductive layer is composited by at least one elastomer and conductive filler. The resistance value and the elastic strain increment of the elastic conductive composite fabric satisfy the following relationship: R T =R+nε/R T =R+m e nε . Among them, ε is the elastic strain increment; R is the resistance value when the elastic strain increment is 0; R T is the resistance value when the elastic conductive composite fabric is deformed by an external force; m and n are coefficients, which are decimals or integers. .
進一步地,所述織物層包括一織物層本體及多條彈性紗線,所述彈性紗線沿一第一方向及/或第二方向設置於所述織物層本體內,其中,所述第一方向是指沿X軸方向,所述第二方向是指沿Y軸方向。 Further, the fabric layer includes a fabric layer body and a plurality of elastic yarns, and the elastic yarns are arranged in the fabric layer body along a first direction and/or a second direction, wherein the first The direction refers to the direction along the X axis, and the second direction refers to the direction along the Y axis.
進一步地,所述彈性導電複合織物具有彈性係數E1,所述織物層本體具有彈性係數E2,所述E1與E2之間的比值介於1.2~1.6之間。 Further, the elastic conductive composite fabric has an elastic coefficient E 1 , the fabric layer body has an elastic coefficient E 2 , and the ratio between the E 1 and E 2 is between 1.2 and 1.6.
進一步地,所述彈性導電層具有黏著性,所述彈性導電層黏著在所述織物層上。 Further, the elastic conductive layer has adhesiveness, and the elastic conductive layer is adhered to the fabric layer.
進一步地,在所述彈性導電層中,所述導電填料的品質百分含量為30%~60%,所述彈性導電層的電阻值介於10-1~104歐姆之間。 Further, in the elastic conductive layer, the quality percentage of the conductive filler is 30% to 60%, and the resistance value of the elastic conductive layer is between 10 -1 to 10 4 ohms.
進一步地,在所述彈性導電層中,所述導電填料的品質百分含量為10%~30%,所述彈性導電層的電阻值介於102~105歐姆之間。 Further, in the elastic conductive layer, the quality percentage of the conductive filler is 10% to 30%, and the resistance value of the elastic conductive layer is between 10 2 to 10 5 ohms.
進一步地,當所述彈性導電複合織物的電阻值與彈性應變增量滿足R T =R+nε時,其中,n介於1.0~2.5。 Further, when the resistance value and the elastic strain increment of the elastic conductive composite fabric satisfy R T =R+nε , where n is between 1.0 and 2.5.
進一步地,所述彈性導電複合織物的電阻值與彈性應變增量滿足R T =R+m e nε 時,m介於9.0~10.0;n介於0.05~0.06。 Further, when the resistance value and the elastic strain increment of the elastic conductive composite fabric satisfy R T =R+m e nε , m is between 9.0 and 10.0; n is between 0.05 and 0.06.
進一步地,所述導電填料的形態為顆粒、粉末、線狀或纖維形態,所述填料的材質為金、銀、結構銀、銅、鐵、鎳、不銹鋼、碳黑、石墨烯、納米管或具有導電性的高分子聚合物。 Further, the shape of the conductive filler is in the form of particles, powder, wire or fiber, and the material of the filler is gold, silver, structural silver, copper, iron, nickel, stainless steel, carbon black, graphene, nanotubes or High molecular polymer with conductivity.
進一步地,所述彈性體為彈性高分子材料,所述彈性體為苯乙烯類、烯烴類、雙烯類、氯乙烯類、氨酯類、酯類、醯胺類、有機氟類、有機矽類或乙烯類熱塑性彈性體。 Further, the elastomer is an elastic polymer material, and the elastomer is styrene, olefin, diene, vinyl chloride, urethane, ester, amide, organic fluorine, or silicone Type or ethylene type thermoplastic elastomer.
本發明提供的彈性導電複合織物具有與具有彈性的織物層連接在一起的彈性導電層,所述彈性導電層可以連接各種外接裝置或電子元件,且所述彈性導電複合織物的彈性應變與其電阻變化相對應並存在指數或線性關係,因此,通過偵測所述彈性導電複合織物的電阻值變化,可以得到所述彈性導電複合織物的應變增量,根據所述應變增量的變化能夠解析肢體屈曲和伸展運動的變化。 The elastic conductive composite fabric provided by the present invention has an elastic conductive layer connected with an elastic fabric layer, the elastic conductive layer can be connected to various external devices or electronic components, and the elastic strain of the elastic conductive composite fabric and its resistance change Correspondingly, there is an exponential or linear relationship. Therefore, by detecting the change in the resistance value of the elastic conductive composite fabric, the strain increment of the elastic conductive composite fabric can be obtained, and the limb flexion can be analyzed according to the change in the strain increment And stretching exercises.
100:彈性導電複合織物 100: Elastic conductive composite fabric
12:織物層 12: Fabric layer
121:織物層本體 121: Fabric layer body
122:彈性紗線 122: elastic yarn
11:彈性導電層 11: Elastic conductive layer
D1:第一方向 D1: First direction
D2:第二方向 D2: second direction
圖1為本發明較佳實施方式提供的一種彈性導電複合織物的側視示意圖。 Fig. 1 is a schematic side view of an elastic conductive composite fabric provided by a preferred embodiment of the present invention.
圖2為圖1所示的彈性導電複合織物的織物層的俯視圖。 Fig. 2 is a top view of the fabric layer of the elastic conductive composite fabric shown in Fig. 1.
圖3是沿圖2所示的線III-III的剖視圖。 Fig. 3 is a cross-sectional view taken along the line III-III shown in Fig. 2.
圖4是沿圖2所示的線IV-IV的剖視圖。 Fig. 4 is a cross-sectional view taken along the line IV-IV shown in Fig. 2.
下面將結合本發明實施方式中的附圖,對本發明實施方式中的技術方案進行清楚、完整地描述,顯然,所描述的實施方式僅是本發明一部分實施方式,而不是全部的實施方式。基於本發明中的實施方式,本領域普通技術人員在沒有做出創造性勞動前提下所獲得的所有其他實施方式,都屬於本發明保護的範圍。 The technical solutions in the embodiments of the present invention will be described clearly and completely in conjunction with the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, rather than all of them. Based on the embodiments of the present invention, all other embodiments obtained by a person of ordinary skill in the art without creative work shall fall within the protection scope of the present invention.
需要說明的是,當一個元件被認為是“連接”另一個元件,它可以是直接連接到另一個元件或者可能同時存在居中設置的元件。本文所使用的術語“及/或”包括一個或多個相關的所列項目的任意的和所有的組合。 It should be noted that when an element is considered to be "connected" to another element, it can be directly connected to another element or a centrally arranged element may exist at the same time. The term "and/or" as used herein includes any and all combinations of one or more related listed items.
除非另有定義,本文所使用的所有的技術和科學術語與屬於本發明的技術領域的技術人員通常理解的含義相同。本文中在本發明的說明書中所使用的術語只是為了描述具體的實施方式的目的,不是旨在於限制本發明。 Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by those skilled in the technical field of the present invention. The terminology used in the description of the present invention herein is only for the purpose of describing specific embodiments, and is not intended to limit the present invention.
請參閱圖1-4,本發明較佳實施方式提供一種彈性導電複合織物100,所述彈性導電複合織物100包括一織物層12及一形成在所述織物層12上的彈性導電層11。所述織物層12具有彈性。所述彈性導電層11由至少一彈性體及導電填料複合而成。所述彈性導電複合織物100的電阻值與彈性應變增量滿足如下關係:R T =R+nε/R T =R+m e nε 。其中,所述ε為彈性應變增量;R為彈性應變增量為0時的電阻值;RT為所述彈性導電複合織物100受到外力發生形變時的電阻值;m和n是係數,為小數或整數。
Referring to FIGS. 1-4, a preferred embodiment of the present invention provides an elastic
由於所述彈性導電複合織物100具有彈性,因此,所述彈性導電複合織物100在被載入拉張外力時,能夠即時響應產生彈性形變且能夠在拉張外力被卸載後迅速回復至原始狀態。
Since the elastic
由於所述彈性導電複合織物100具有導電性,因此,所述彈性導電複合織物100可以連接各種外接裝置或電子元件且所述彈性導電複合織物的彈性應變與其電阻變化相對應並存在指數或線性關係,因此,所述彈性導電複合織物的電阻值可轉換為對應的輸出信號,所述輸出信號可以在一終端產品中被使用者直接觀察到,使用者可根據能夠即時解析肢體屈曲和伸展運動的變化。
Since the elastic
其中,所述織物層12包括一織物層本體121及多條彈性紗線122。其中,所述彈性紗線122沿一第一方向D1及/或第二方向D2織於所述織物層本
體121內。其中,所述第一方向是指沿X軸方向,所述第二方向是指沿Y軸方向。在本實施方式中,所述彈性紗線122沿一第一方向D1設置於所述織物層本體121內。
Wherein, the
其中,所述彈性紗線122為60~100丹尼的纖維,優選地,所述彈性紗線122為80丹尼的纖維。
Wherein, the
其中,所述織物層12於所述第一方向D1及/或第二方向D2的伸長量為所述織物層12初始長度的10%~50%。其中,所述織物層12的伸長量可根據穿戴者身形設計,並根據身形調整所述彈性紗線122的丹尼數及所述述織物層12的結構。
Wherein, the elongation of the
其中,所述彈性導電複合織物100具有彈性係數E1,所述織物層12本體具有彈性係數E2,所述E1與E2之間的比值介於1.2~1.6之間,以使得所述彈性導電複合織物100在被穿戴過程中能即時回應肢體屈曲和伸展動作。
Wherein, the elastic
其中,所述織物層本體121可以為針織物或立體織物結構。該織物層本體121的材質可以為TC混紡紗、聚酯、尼龍、聚丙腈等。其中,TC混紡紗是指滌綸和棉混紡紗。
Wherein, the
其中,所述彈性紗線122的材質為聚氨酯(polyurethane,PU)材料,可為OP紗、spandex纖維、Lycra纖維等。在本實施方式中,所述彈性紗線122的材質為商品名為Lycra的纖維。
Wherein, the material of the
在一實施方式中,所述彈性導電層11為一預成型的圖形化薄膜,所述預成型的圖形化薄膜低溫壓合在所述織物層12上,以使得所述預成型的圖形化薄膜與所述織物層12連接。其中,所述低溫為90℃~130℃。
In one embodiment, the elastic
在另一實施方式中,所述彈性導電層11是將所述彈性體及所述導電填料複合形成的溶液直接塗布或網印在所述織物層12上、經圖形化及低溫熱風乾燥後形成的。其中,所述低溫為80℃~140℃。
In another embodiment, the elastic
上述所述彈性導電層11與所述織物層12的連接方式使得所述彈性導電層11具有黏著性且可與所述織物層12結合,從而使得所述彈性導電複合織物能夠被彎折或扭曲,而不發生介面脫層現象。
The above-mentioned connection manner of the elastic
在一實施方式中,在所述彈性導電層11中,所述導電填料的品質百分含量為30%~60%,所述彈性導電層11的電阻值介於10-1~104歐姆之間。
In one embodiment, in the elastic
在另一實施方式中,在所述彈性導電層11中,所述導電填料的品質百分含量為10%~30%,所述彈性導電層11的電阻值介於102~105歐姆之間。
In another embodiment, in the elastic
其中,所述導電填料的形態為顆粒、粉末、線狀或纖維形態。 Wherein, the conductive filler is in the form of particles, powder, threads or fibers.
其中,所述導電填料的材質為可導電的金屬材質或非金屬材質。具體地,所述導電填料的材質為金、銀、銅、鐵、鎳、不銹鋼等金屬材質或碳黑、石墨烯、納米管、具有導電性的高分子聚合物等非金屬材質。 Wherein, the material of the conductive filler is a conductive metal material or a non-metal material. Specifically, the conductive filler is made of metal materials such as gold, silver, copper, iron, nickel, and stainless steel, or non-metallic materials such as carbon black, graphene, nanotubes, and high-molecular polymers with conductivity.
其中,所述彈性體為彈性高分子材料。所述彈性體可以為苯乙烯類、烯烴類、雙烯類、氯乙烯類、氨酯類、酯類、醯胺類、有機氟類、有機矽類、乙烯類熱塑性彈性體。具體地,所述彈性體可以為苯乙烯/丁二烯/苯乙烯嵌段共聚物(SBS);苯乙烯/異戊二烯/苯乙烯嵌段共聚物(SIS);苯乙烯/已烯-丁烯/苯乙烯嵌段共聚物(SEBS)和苯乙烯/乙烯-丙烯/苯乙烯嵌段共聚物(SEPS)、熱塑性聚氨酯(TPU)等。 Wherein, the elastomer is an elastic polymer material. The elastomer may be styrene, olefin, diene, vinyl chloride, urethane, ester, amide, organic fluorine, silicone, or vinyl thermoplastic elastomer. Specifically, the elastomer may be styrene/butadiene/styrene block copolymer (SBS); styrene/isoprene/styrene block copolymer (SIS); styrene/hexene- Butene/styrene block copolymer (SEBS), styrene/ethylene-propylene/styrene block copolymer (SEPS), thermoplastic polyurethane (TPU), etc.
其中,當所述彈性導電複合織物的電阻值與彈性應變增量滿足R T =R+nε時,n介於1.0~2.5。 Wherein, when the resistance value and the elastic strain increment of the elastic conductive composite fabric satisfy R T =R+nε , n is between 1.0 and 2.5.
其中,當所述彈性導電複合織物的電阻值與彈性應變增量滿足R T =R+m e nε 時,m介於9.0~10.0;n介於0.05~0.06。 Wherein, when the resistance value and the elastic strain increment of the elastic conductive composite fabric satisfy R T =R+m e nε , m is between 9.0 and 10.0; n is between 0.05 and 0.06.
下面將通過具體實施例來對本發明進行具體說明。 Hereinafter, the present invention will be described in detail through specific embodiments.
實施例1 Example 1
首先,將品質百分含量為30%的導電填料與TPU(彈性體)均勻混合,並將混合均勻後的所述導電填料與彈性體置於具有圖形的治具中預先成膜,得到一彈性導電層11,再在低溫90~130℃,2MPa~8Mpa的壓力的條件下,將所述彈性導電層11與所述織物層12壓合8~35秒,使得所述彈性導電層11與所述織物層12連結在一起,得到一彈性導電複合織物100。其中,所述彈性導電複合織物100的電阻值介於100Ω~103Ω之間。之後,施與一張力於所述彈性導電複合織物100,所述彈性導電複合織物100在所述張力作用下伸展。最後,測量不同張力下的所述彈性導電複合織物100的電阻值與所述彈性導電複合織物100的長度應變增量。
First, the conductive filler with a quality percentage of 30% is uniformly mixed with TPU (elastomer), and the uniformly mixed conductive filler and elastomer are placed in a patterned jig to form a film in advance to obtain an elastic For the
其中,在實施例1中,所述彈性導電複合織物100的長度應變增量為ε,則所述彈性導電複合織物100的電阻值RT與應變增量ε關係為:RT=10.35e0.33ε,此處ε可為整數或小數。
Wherein, in Example 1, the length strain increment of the elastic conductive
實施例2 Example 2
首先,將品質百分含量為60%的導電填料與TPU及SEBS(彈性體)均勻混合,並將混合均勻後的所述導電填料與彈性體直接塗布在所述織物層12上,再以110℃熱風烘乾20分鐘,得到一彈性導電層11及一彈性導電複合織物100。其中,所述彈性導電複合織物100的電阻值介於10-1Ω~102Ω之間。之後,施與一張力於所述彈性導電複合織物100,所述彈性導電複合織物100在所述張力作用下伸展。最後,測量不同張力下的所述彈性導電複合織物100的電阻值與所述彈性導電複合織物100的長度應變增量。
First, the conductive filler with a quality percentage of 60% is uniformly mixed with TPU and SEBS (elastomer), and the uniformly mixed conductive filler and elastomer are directly coated on the
其中,在實施例2中,所述彈性導電複合織物100的長度應變增量為ε,則所述彈性導電複合織物100的電阻值RT與應變增量ε關係為:RT=0.75+1.68εε,此處ε可為整數或小數。
Wherein, in Example 2, the length strain increment of the elastic conductive
本發明還提供一種應用所述彈性導電複合織物100以偵測並顯示所述彈性導電複合織物的電阻值及電阻值變化的電子產品200。
The present invention also provides an electronic product 200 using the elastic conductive
由上可知,所述彈性導電複合織物100的彈性應變增量與其電阻變化相對應並存在指數或線性關係,因此,通過偵測所述彈性導電複合織物的電阻值變化,可以得到所述彈性導電複合織物100的應變增量,根據所述應變增量的變化能夠解析肢體屈曲和伸展運動的變化。
It can be seen from the above that the elastic strain increment of the elastic conductive
另外,所述彈性導電複合織物100的織物層12與人體絕緣,且所述彈性導電層11並未與人體直接接觸,因此,人體並不會影響所述彈性導電複合織物100的電阻值。
In addition, the
再者,所述彈性導電複合織物100還具有透氣、親膚及舒適柔軟的性能。
Furthermore, the elastic conductive
以上所述,僅是本發明的較佳實施方式而已,並非對本發明任何形式上的限制,雖然本發明已是較佳實施方式揭露如上,並非用以限定本發明,任何熟悉本專業的技術人員,在不脫離本發明技術方案範圍內,當可利用上述揭示的技術內容做出些許更動或修飾為等同變化的等效實施方式,但凡是未脫離本發明技術方案內容,依據本發明的技術實質對以上實施方式所做的任何簡單修改、等同變化與修飾,均仍屬於本發明技術方案的範圍內。 The above are only the preferred embodiments of the present invention and do not limit the present invention in any form. Although the present invention has been disclosed as the preferred embodiments, it is not intended to limit the present invention. Anyone familiar with the profession , Without departing from the scope of the technical solution of the present invention, when the technical content disclosed above can be used to make some changes or modification into equivalent implementations with equivalent changes, provided that the technical content of the present invention is not deviated from the technical essence of the present invention Any simple modifications, equivalent changes and modifications made to the above embodiments still fall within the scope of the technical solutions of the present invention.
100:彈性導電複合織物 100: Elastic conductive composite fabric
12:織物層 12: Fabric layer
11:彈性導電層 11: Elastic conductive layer
D1:第一方向 D1: First direction
D2:第二方向 D2: second direction
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