TWI747940B - Shoe material structure and dyeing method thereof - Google Patents

Shoe material structure and dyeing method thereof Download PDF

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TWI747940B
TWI747940B TW106128862A TW106128862A TWI747940B TW I747940 B TWI747940 B TW I747940B TW 106128862 A TW106128862 A TW 106128862A TW 106128862 A TW106128862 A TW 106128862A TW I747940 B TWI747940 B TW I747940B
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main body
shoe material
material structure
dye
structural molecules
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TW201806786A (en
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黃英俊
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黃英俊
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Abstract

一種鞋材結構的染色方法,包含有下列步驟,將一轉印紙貼附於鞋材結構的欲染色部位,其中鞋材結構具備熱可塑性之特性;透過熱壓轉印方式對鞋材結構與轉印紙加熱與加壓,藉以將轉印紙上含有染料的圖樣,從固態昇華汽化並滲透至鞋材結構中,且使鞋材結構表面形成具有染色後圖樣的表面。如此一來,即可在保持鞋材材質特性的基礎下,快速完成染色作業並提高鞋材的成色效果。A dyeing method of shoe material structure includes the following steps: attaching a transfer paper to the part to be dyed of the shoe material structure, wherein the shoe material structure has the characteristics of thermal plasticity; The printing paper is heated and pressurized to sublime and vaporize the dye-containing pattern on the transfer paper from the solid state and penetrate into the shoe material structure, so that the surface of the shoe material structure forms a surface with a dyed pattern. In this way, on the basis of maintaining the material characteristics of the shoe material, the dyeing operation can be completed quickly and the color effect of the shoe material can be improved.

Description

一種鞋材結構的染色方法Method for dyeing shoe material structure

本發明係與鞋材有關;特別是指一種應用於鞋材的染色方法以及其結構。 The invention relates to shoe materials; in particular, it refers to a dyeing method applied to shoe materials and its structure.

已知的鞋款結構係由鞋面與鞋底所構成。鞋面用於包覆足部,並將足部確實的固定在鞋底上。鞋底位於腳掌下方,用於支撐足部,且包含有接觸地面的大底,以及介於大底與鞋面之間的中底。 The known shoe structure is composed of an upper and a sole. The shoe upper is used to cover the foot and firmly fix the foot on the sole. The sole is located under the sole of the foot to support the foot, and includes an outsole that contacts the ground, and a midsole between the outsole and the upper.

目前市面上常見用於製作大底與中底的鞋底材質為熱塑性聚氨酯(Thermoplastic polyurethanes,簡稱TPU),又稱作熱塑性聚氨基甲酸酯。TPU具備了優良的耐磨性、彈性、抗撕裂性、彎曲強度、抗張強度、斷裂延伸率大、壓縮變形率低、耐低溫(-50℃)、耐油、耐脂肪族溶劑、耐碳氫溶劑、對氧及臭氣具有抵抗性、耐老化…等特性。此外,TPU材質是一種不含可塑劑的成熟環保材質,也是一種高分子彈性體,其彈性介於橡膠材料與塑膠材料之間,在現有的橡膠、塑膠材質中擁有最佳的物性。 Thermoplastic polyurethanes (TPU for short), also known as thermoplastic polyurethanes, are commonly used in the market to make outsoles and midsoles. TPU has excellent wear resistance, elasticity, tear resistance, bending strength, tensile strength, high elongation at break, low compression set, low temperature resistance (-50°C), oil resistance, aliphatic solvent resistance, carbon resistance Hydrogen solvent, resistance to oxygen and odor, anti-aging...etc. In addition, TPU is a mature and environmentally friendly material that does not contain plasticizers. It is also a polymer elastomer. Its elasticity is between rubber and plastic materials and has the best physical properties among existing rubber and plastic materials.

TPU鞋底於染色應用時,大多以液態印刷方式將色彩染料(油墨)塗佈於鞋底表面,然而,待色彩染料乾燥後容易導致鞋底表面粗糙,並降低TPU材質原本保有的透氣與散熱特性,且部分更會出現暈開甚至是油墨撥離之成色效果不彰的情況。而若改以浸泡方式將TPU鞋 底浸泡於色彩染料中,不僅需要等待多時才能完成染色,造成生產效率降低,更會導致染色後的鞋底,因受到染料之阻隔而減少原有TPU材質的特性,另外,以浸泡方式對單一個體的TPU鞋底作染色處理時,至多僅能獲得兩種顏色而已。 When TPU soles are used for dyeing applications, color dyes (inks) are mostly applied to the surface of the soles by liquid printing. However, after the color dyes are dried, the surface of the soles will be rough and reduce the original air permeability and heat dissipation characteristics of the TPU material. In some cases, blurring or even the color effect of the ink is not clear. If you change the TPU shoes by soaking Soaking the sole in the color dye not only needs to wait a long time to complete the dyeing, which will reduce the production efficiency, but also cause the dyed sole to reduce the characteristics of the original TPU material due to the barrier of the dye. When individual TPU soles are dyed, at most only two colors can be obtained.

有鑑於此,本發明之目的在於提供一種鞋材的染色方法,係可在不影響鞋材材質特性的基礎下,大幅提升染色效率以及鞋材的成色效果。 In view of this, the purpose of the present invention is to provide a method for dyeing shoe materials, which can greatly improve the dyeing efficiency and the coloring effect of shoe materials without affecting the material characteristics of the shoe materials.

緣以達成上述目的,本發明提供一種鞋材的染色方法包括有下列步驟:將一轉印紙貼附於鞋材的欲染色部位;透過熱壓轉印方式將轉印紙上含有染料的圖樣,從固態昇華汽化並滲透至鞋材中,且使鞋材表面形成具有染色後圖樣的表面。 In order to achieve the above-mentioned object, the present invention provides a method for dyeing shoe materials including the following steps: attaching a transfer paper to the part to be dyed on the shoe material; transferring the dye-containing pattern on the transfer paper through the hot-press transfer method, from The solid sublimation vaporizes and penetrates into the shoe material, and the surface of the shoe material forms a surface with a dyed pattern.

緣以達成上述目的,本發明提供的一種鞋材結構包含有一主體以及一染料;其中該主體具備熱可塑性;該染料之分子散布於該主體內部。 In order to achieve the above-mentioned objective, the present invention provides a shoe material structure comprising a main body and a dye; wherein the main body has thermoplasticity; the molecules of the dye are dispersed inside the main body.

緣以達成上述目的,本發明提供的一種鞋材結構係以熱壓轉印方式將一轉印紙上含有染料的圖樣滲透至該鞋材中。 In order to achieve the above-mentioned object, the present invention provides a shoe material structure in which a dye-containing pattern on a transfer paper is penetrated into the shoe material by a hot-press transfer method.

本發明之效果,在於透過熱壓轉印方式將轉印紙上的染料由固態昇華為汽化,並滲透至具備熱可塑性的主體內部,讓染料分子散布於主體中,藉以可在保持鞋材材質特性的基礎下,快速完成染色作業並提高鞋材的成色效果。 The effect of the present invention is to sublime the dye on the transfer paper from solid to vaporization through the hot-press transfer method, and penetrate into the interior of the main body with thermoplasticity, so that the dye molecules are dispersed in the main body, so as to maintain the material characteristics of the shoe material. Based on the foundation, the dyeing operation can be completed quickly and the color effect of the shoe material can be improved.

〔本發明〕 〔this invention〕

100:鞋材結構 100: shoe material structure

10:主體 10: main body

101:內部 101: Internal

102:頂面 102: top surface

10a:結構分子 10a: structural molecule

20a:染料的結構分子 20a: Structural molecules of dyes

40:主體 40: main body

40a、40b:結構分子 40a, 40b: structural molecules

30a:染料的結構分子 30a: Structural molecules of dyes

圖1為本發明一較佳實施例之鞋材結構的立體圖,揭示鞋材結構的頂面為染色部位。 Fig. 1 is a perspective view of a shoe material structure according to a preferred embodiment of the present invention, revealing that the top surface of the shoe material structure is a dyed part.

圖2係一放大圖,揭示圖1之鞋材結構的內部分子組成。 Figure 2 is an enlarged view showing the internal molecular composition of the shoe material structure of Figure 1.

圖3係一放大圖,揭示另一鞋材結構的內部分子組成。 Figure 3 is an enlarged view showing the internal molecular composition of another shoe material structure.

圖4係一實施例之示意圖,揭示鞋材結構的頂面為染色部位。 Fig. 4 is a schematic diagram of an embodiment, revealing that the top surface of the shoe material structure is a dyed part.

圖5係一實施例之示意圖,揭示鞋材結構應用於鞋款上,且鞋材結構得周側面為染色部位。 Fig. 5 is a schematic diagram of an embodiment, revealing that the shoe material structure is applied to the shoe style, and the peripheral side of the shoe material structure is the dyed part.

圖6係一實施例之示意圖,揭示鞋材結構的頂面為染色部位。 Fig. 6 is a schematic diagram of an embodiment, revealing that the top surface of the shoe material structure is a dyed part.

圖7係一實施例之示意圖,揭示鞋材結構的底面為染色部位。 Fig. 7 is a schematic diagram of an embodiment, revealing that the bottom surface of the shoe material structure is a dyed part.

圖8係一實施例之示意圖,揭示鞋材結構的底面為染色部位。 Fig. 8 is a schematic diagram of an embodiment, revealing that the bottom surface of the shoe material structure is a dyed part.

圖9係一實施例之示意圖,揭示鞋材結構的底面、底面與周側面為染色部位。 Fig. 9 is a schematic diagram of an embodiment, revealing that the bottom surface, the bottom surface and the peripheral side surface of the shoe material structure are dyed parts.

圖10係一實施例之示意圖,揭示鞋材結構的底面、底面與周側面為染色部位。 Fig. 10 is a schematic diagram of an embodiment, revealing that the bottom surface, the bottom surface and the peripheral side surface of the shoe material structure are dyed parts.

圖11係鞋材結構之染色方法的流程圖。 Figure 11 is a flow chart of the dyeing method of the shoe material structure.

圖12係鞋材結構之染色方法的流程圖。 Figure 12 is a flow chart of the dyeing method of the shoe material structure.

為能更清楚地說明本發明,茲舉一較佳實施例並配合圖式詳細說明如後。請參圖1與圖2所示,為本發明一較佳實施例之鞋材結構,係一種可作為中底或是大底使用的鞋底。其中,該鞋材結構100包含有一主體10以及一染料。 In order to explain the present invention more clearly, a preferred embodiment is given in conjunction with the drawings in detail as follows. Please refer to FIG. 1 and FIG. 2, which shows a shoe material structure according to a preferred embodiment of the present invention, which is a shoe sole that can be used as a midsole or an outsole. Wherein, the shoe material structure 100 includes a main body 10 and a dye.

該主體10由具備熱可塑性的材質製成,於本實施例中,其材質選自熱塑性聚氨酯(Thermoplastic polyurethanes,簡稱TPU)。於其他實施例亦可採用其他具備熱可塑特性之材質製成,不以本實施例所舉之材質為限。一提的是,該主體10於製作時,係可依據外觀需求而以透明方式或是不透明方式成色。 The main body 10 is made of a material with thermoplasticity. In this embodiment, the material is selected from Thermoplastic polyurethanes (TPU for short). In other embodiments, it can also be made of other materials with thermoplastic properties, and is not limited to the materials mentioned in this embodiment. It is mentioned that the main body 10 can be colored in a transparent or opaque manner according to the appearance requirements.

該染料具有顏色,染料的結構分子20a係小於該主體10的結構分子10a,染料的結構分子20a係小於該主體10的結構分子10a間的間隙,且染料的結構分子20a散布於該主體10的外表層與內部101,並不規則的排列於主體10的結構分子10a之間,本實施例以散布於該主體10的頂面102為例。 The dye has a color, the structural molecule 20a of the dye is smaller than the structural molecule 10a of the main body 10, the structural molecule 20a of the dye is smaller than the gap between the structural molecules 10a of the main body 10, and the structural molecules 20a of the dye are scattered on the main body 10 The outer surface layer and the inner layer 101 are arranged irregularly between the structural molecules 10a of the main body 10. In this embodiment, the top surface 102 of the main body 10 is taken as an example.

配合圖3所示,於其他實施例中,染料的結構分子30a之大小遠小於主體40的結構分子40a、40b,且染料的結構分子30a的體積小於該主體40結構分子40a、40b間的間隙。染料的結構分子30a除了散布於主體40的結構分子40a之間,更是滲入部份主體40的結構分子40a中,而使該主體40的結構分子40a帶有顏色。換言之,主體40的結構分子40a、40b中,部份分子40b之顏色維持於原色,部分分子40a則帶有染料的顏色。 As shown in FIG. 3, in other embodiments, the size of the structural molecule 30a of the dye is much smaller than that of the structural molecules 40a and 40b of the main body 40, and the volume of the structural molecule 30a of the dye is smaller than the gap between the structural molecules 40a and 40b of the main body 40 . The structural molecules 30a of the dye are not only scattered between the structural molecules 40a of the main body 40, but also penetrate part of the structural molecules 40a of the main body 40, so that the structural molecules 40a of the main body 40 are colored. In other words, among the structural molecules 40a and 40b of the main body 40, the color of part of the molecule 40b remains the original color, and the part of the molecule 40a has the color of the dye.

前述兩種之結構排列方式,皆使得主體可在不受到染料干擾下維持了TPU材質原有的特性,並讓染料的顏色顯露於鞋材結構之外表層及內部。 The aforementioned two structural arrangements allow the main body to maintain the original characteristics of the TPU material without being disturbed by the dye, and allow the color of the dye to be revealed on the outer surface and inside of the shoe material structure.

以下說明上述鞋材結構的染色方法。 The dyeing method of the above-mentioned shoe material structure is explained below.

一般而言,鞋材結構的染色流程如同圖11與圖12所示之內容,即,先準備且放置材料,將鞋材結構置放在一熱壓機上,再將一轉印紙貼附於鞋材結構上欲染色之部位。其中,鞋材結構具有相背對的一 頂面與一底面,以及位於該頂面與該底面之間的一周側面。操作人員係可根據需求而將該轉印紙貼附於鞋材結構之頂面、底面或周側面之至少其中一者上。 Generally speaking, the dyeing process of the shoe material structure is the same as that shown in Figure 11 and Figure 12, that is, the material is prepared and placed first, the shoe material structure is placed on a heat press, and then a transfer paper is attached to the The part to be dyed on the structure of the shoe material. Among them, the shoe material structure has an opposite one A top surface and a bottom surface, and a peripheral side surface located between the top surface and the bottom surface. The operator can affix the transfer paper to at least one of the top surface, bottom surface or peripheral side of the shoe material structure according to requirements.

接著,透過熱壓機以熱壓轉印方式對欲染色部位與轉印紙加熱並且加壓,藉以將轉印紙上含有染料的圖樣,從固態昇華汽化並滲透至鞋材結構中。 Then, heat and pressurize the part to be dyed and the transfer paper in a thermal press transfer method through a heat press, so that the pattern containing the dye on the transfer paper is sublimated and vaporized from the solid state and penetrated into the shoe material structure.

最後,使得鞋材結構的外表面與內部形成具有染色後圖樣的樣貌。 Finally, the outer surface and the inner surface of the shoe material structure are formed with a dyed pattern.

圖6至圖10所示之內容,即各種經過染色處理後的鞋材結構成品。其中,圖6所示之內容,係將染料的圖樣轉印於鞋材結構的頂面;圖7、圖8所示之內容,係將染料的圖樣轉印於鞋材結構的底面;圖9、圖10所示之內容,係將染料的圖樣轉印於鞋材結構的頂面、底面與周側面。 Figures 6 to 10 show the contents of various finished shoe material structures after dyeing. Among them, the content shown in Figure 6 is to transfer the dye pattern to the top surface of the shoe material structure; the content shown in Figures 7 and 8 is to transfer the dye pattern to the bottom surface of the shoe material structure; Figure 9 The content shown in Figure 10 is to transfer the dye pattern to the top, bottom and peripheral sides of the shoe material structure.

一提的是,執行上述染色方法時,熱壓過程中之熱壓時間介於5秒~100秒之間;熱壓壓力介於1.5kg/cm2~4kg/cm2之間;熱壓溫度係介於60℃~200℃之間,較佳者,熱壓溫度維持於130℃,以防止鞋材結構或是轉印紙因過熱而熔化。 One thing to mention is that when performing the above dyeing method, the hot pressing time during the hot pressing is between 5 seconds and 100 seconds; the hot pressing pressure is between 1.5kg/cm 2 ~4kg/cm 2 ; the hot pressing temperature It is between 60°C and 200°C. Preferably, the heat pressing temperature is maintained at 130°C to prevent the shoe material structure or transfer paper from melting due to overheating.

另一提的是,藉由熱壓機對欲染色部位與轉印紙加熱並且加壓之方式有多種,例如,驅使滾輪於鞋材結構表面及轉印紙上滾軋作動,或是驅使上下模具上下壓合鞋材結構,並透過加熱滾輪或是模具而間接地加熱鞋材結構與轉印紙,使轉印紙上的染料從固態昇華汽化並滲透至鞋材結構中。 Another thing to mention is that there are many ways to heat and pressurize the parts to be dyed and the transfer paper by a heat press, for example, driving a roller on the surface of the shoe material structure and the transfer paper, or driving the upper and lower molds up and down Press the shoe material structure, and indirectly heat the shoe material structure and the transfer paper through the heating roller or the mold, so that the dye on the transfer paper sublimates and vaporizes from the solid state and penetrates into the shoe material structure.

透過上述之鞋材結構的染色方法,可讓鞋材結構之外表層形成有轉印紙上的染料圖樣,並讓熱轉印紙上的染料自固態昇華汽化且 透過加壓方式滲入至鞋材結構內部,以使染料與鞋材結構中的結構分子融合,在不影響原本材質(TPU)特性之基礎下,大幅提升染料附著於鞋材結構的內部與表層的穩定性,並避免發生色彩圖樣脫落、斑駁;此外,更因著熱壓機之熱加壓緣故,而使得鞋材結構的外表層在承受加熱與加壓作用後,得以維持良好的平整性。 Through the above-mentioned dyeing method of the shoe material structure, the dye pattern on the transfer paper can be formed on the outer surface of the shoe material structure, and the dye on the heat transfer paper can be sublimated and vaporized from the solid state. It penetrates into the interior of the shoe material structure through pressure, so that the dye and the structural molecules in the shoe material structure are fused, and the adhesion of the dye to the interior and surface of the shoe material structure is greatly improved without affecting the characteristics of the original material (TPU). It is stable, and avoids the color pattern falling off and mottled. In addition, due to the heat and pressure of the heat press, the outer surface of the shoe material structure can maintain good flatness after being heated and pressurized.

以上所述僅為本發明較佳可行實施例而已,舉凡應用本發明說明書及申請專利範圍所為之等效變化,理應包含在本發明之專利範圍內。 The above are only the preferred and feasible embodiments of the present invention. Any equivalent changes made by applying the specification of the present invention and the scope of the patent application should be included in the patent scope of the present invention.

100:鞋材結構 100: shoe material structure

10:本體 10: body

Claims (7)

一種鞋材結構的染色方法,其中該鞋材結構包含有一主體;該鞋材結構的染色方法包含有下列步驟:將一轉印紙貼附於該主體的欲染色部位,且該主體於製作時係以透明方式成色;以及透過熱壓轉印方式將轉印紙上含有染料的圖樣,且染料的結構分子的體積小於該主體結構分子間的間隙,且染料的結構分子一部分散布於主體的結構分子之間,至少一部分滲入主體的部分結構分子中,而使該主體的結構分子帶有顏色;染料從固態昇華汽化並滲透至該主體中,且使該主體表面形成具有染色後圖樣的表面,其中該熱壓溫度為60℃至小於130℃,且該熱壓轉印的熱壓壓力為1.5kg/cm2至小於4kg/cm2,且該主體之材質選自熱可塑性聚氨酯。 A method for dyeing a shoe material structure, wherein the shoe material structure includes a main body; the dyeing method of the shoe material structure includes the following steps: attaching a transfer paper to the part to be dyed of the main body, and the main body is made at the time of manufacturing. Color formation in a transparent manner; and transfer the pattern containing the dye on the transfer paper through the heat and pressure transfer method, and the volume of the structural molecules of the dye is smaller than the gap between the main structural molecules, and a part of the structural molecules of the dye is scattered among the structural molecules of the main body At least a part of it penetrates into part of the structural molecules of the main body, so that the structural molecules of the main body are colored; the dye sublimates and vaporizes from the solid state and penetrates into the main body, and the surface of the main body forms a surface with a dyed pattern, wherein the The hot pressing temperature is 60° C. to less than 130° C., and the hot pressing pressure of the hot press transfer is 1.5 kg/cm 2 to less than 4 kg/cm 2 , and the material of the main body is selected from thermoplastic polyurethane. 如請求項1所述之鞋材結構的染色方法,其中熱壓轉印的熱壓時間介於5秒~100秒。 The dyeing method of the shoe material structure according to claim 1, wherein the hot pressing time of the hot pressing transfer is between 5 seconds and 100 seconds. 如請求項1所述之鞋材結構的染色方法,係以滾壓方式進行熱壓。 The dyeing method of the shoe material structure as described in claim 1 is hot pressing by rolling. 如請求項1所述之鞋材結構的染色方法,其中該主體具有相背對的一頂面與一底面,以及位於該頂面與該底面之間的一周側面;其中該轉印紙貼附於該主體之頂面、底面或周側面之至少其中一者上。 The dyeing method of the shoe material structure according to claim 1, wherein the main body has a top surface and a bottom surface opposite to each other, and a peripheral side surface located between the top surface and the bottom surface; wherein the transfer paper is attached to On at least one of the top surface, bottom surface or peripheral side of the main body. 一種以請求項1所述之染色方法染色的鞋材結構,包含:一主體,為透明且具備熱可塑性;以及一染料,其分子一部分散布於該主體的結構分子之間,至少一部分滲入該主體的部分結構分子中,而使該主體的結構分子帶有顏色,其中 該熱壓溫度為60℃至小於130℃,且該熱壓轉印的熱壓壓力為1.5kg/cm2至小於4kg/cm2A shoe material structure dyed by the dyeing method described in claim 1, comprising: a main body, which is transparent and has thermoplasticity; and a dye, a part of which is dispersed between structural molecules of the main body, and at least a part penetrates into the main body The structural molecules of the main body are colored, wherein the heat-pressing temperature is 60°C to less than 130°C, and the heat-pressing pressure of the heat-press transfer is 1.5kg/cm 2 to less than 4kg/ cm 2 . 如請求項5所述之鞋材結構,其中該染料的結構分子小於該主體的結構分子。 The shoe material structure according to claim 5, wherein the structural molecule of the dye is smaller than the structural molecule of the main body. 一種鞋材結構,包含有一主體,係以熱壓轉印方式將一轉印紙上含有染料的圖樣滲透至該主體中,該主體於製作時係以透明方式成色,且染料的結構分子的體積小於主體結構分子間的間隙,且染料的結構分子一部分散布於主體的結構分子之間,至少一部分滲入主體的部分結構分子中,而使該主體的結構分子帶有顏色,其中該主體之材質選自熱可塑性聚氨酯,其中該熱壓溫度為60℃至小於130℃,且該熱壓轉印的熱壓壓力為1.5kg/cm2至小於4kg/cm2A shoe material structure includes a main body, a pattern containing dye on a transfer paper is penetrated into the main body by a hot press transfer method, the main body is colored in a transparent manner during production, and the volume of the structural molecules of the dye is smaller than The gaps between the main structure molecules, and part of the structural molecules of the dye are scattered between the structural molecules of the main body, and at least a part of it penetrates into the partial structural molecules of the main body, so that the structural molecules of the main body are colored, wherein the material of the main body is selected from Thermoplastic polyurethane, wherein the hot pressing temperature is 60° C. to less than 130° C., and the hot pressing pressure of the hot press transfer is 1.5 kg/cm 2 to less than 4 kg/cm 2 .
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003082595A1 (en) 2002-03-29 2003-10-09 Se Da Coperation, Ltd. Process for sublimation transferring a pattern on polyurethane surface and polyurethane product transferred therefrom
TWM503413U (en) * 2015-03-20 2015-06-21 Rainbow Pigment Co Ltd Fluorescent dispersion dye painted article
TWM522853U (en) * 2016-03-01 2016-06-01 Simple Green Co Ltd Article structure with dye color-variation when being consumed

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003082595A1 (en) 2002-03-29 2003-10-09 Se Da Coperation, Ltd. Process for sublimation transferring a pattern on polyurethane surface and polyurethane product transferred therefrom
TWM503413U (en) * 2015-03-20 2015-06-21 Rainbow Pigment Co Ltd Fluorescent dispersion dye painted article
TWM522853U (en) * 2016-03-01 2016-06-01 Simple Green Co Ltd Article structure with dye color-variation when being consumed

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