TWI744952B - Wear-resistant thin steel plate and manufacturing method thereof - Google Patents

Abstract

An advantageous manufacturing method of a wear-resistant thin steel plate with high flatness is provided. A method for manufacturing a wear-resistant thin steel plate, which is characterized in that it includes: a certain amount of C, Si, Mn, P, S, Cr, Al, Ti, B, and N is contained, and the remainder contains Fe and unavoidable impurities The step of continuously casting the molten steel composed of the components of the slab to obtain a slab; the step of heating the slab to 1000°C to 1300°C; and then the slab is subjected to conditions including a finishing rolling temperature of 900°C or higher The step of obtaining a thin steel sheet by hot rolling including finish rolling under the following conditions; the step of cooling the thin steel sheet under the condition that the average cooling rate between 900°C and 300°C is 30°C/sec or more; and thereafter in the coil The step of winding the thin steel sheet under the condition that the winding temperature is 200°C or lower.

Description

Wear-resistant thin steel plate and manufacturing method thereof

The invention relates to a wear-resistant steel for thin objects with a plate thickness of less than 6.0 mm, that is, a wear-resistant thin steel plate with high hardness, and a manufacturing method thereof.

Industrial machinery, parts and handling equipment used in construction, civil engineering, mining and other fields (such as power shovel, bulldozer, hopper, bucket conveyor, rock crushing device), etc. , Exposed to abrasive wear, sliding wear, impact wear and other wear caused by rocks, sand, ore, etc. Therefore, steel used for such industrial machinery, parts, and conveying equipment is required to have excellent wear resistance in order to increase the life span.

It is known that the wear resistance of steel can be improved by increasing the hardness. Therefore, high-hardness steel obtained by performing heat treatment such as quenching on alloy steel with a large amount of alloy elements such as chromium (Cr) and molybdenum (Mo) added is widely used as wear-resistant steel.

For example, Patent Document 1 describes a method for manufacturing a wear-resistant thick steel plate that contains 0.10% to 0.19% of carbon (C), and further contains appropriate amounts of silicon (Si), manganese (Mn) and carbon The steel with the equivalent Ceq of 0.35-0.44 is hot-rolled to produce a hot-rolled steel sheet. The hot-rolled steel sheet is directly or reheated to 900°C to 950°C, then quenched, and then tempered at 300°C to 500°C , Thereby making the surface hardness of 300 Hv (Vickers hardness (Vickers hardness)) or more.

Patent Document 2 describes a method for manufacturing a wear-resistant thick steel plate that contains 0.10% to 0.20% of C, and further contains appropriate amounts of Si, Mn, phosphorus (P), sulfur (S), and nitrogen ( N), aluminum (Al), oxygen (O), and any steel materials containing at least one of copper (Cu), nickel (Ni), Cr, Mo, and boron (B) are hot-rolled to produce hot-rolled For the steel sheet, the hot-rolled steel sheet is quenched directly or after being cooled and reheated to make the surface hardness 340 HB (Brinell Hardness) or higher.

Patent Document 3 describes a method for manufacturing a wear-resistant thick steel plate that contains 0.07% to 0.17% of C, and further contains appropriate amounts of Si, Mn, vanadium (V), B, and Al, and optionally Steel raw materials containing one or more of Cu, Ni, Cr, and Mo are hot-rolled to make a hot-rolled steel sheet, and the hot-rolled steel sheet is directly or temporarily air-cooled and reheated and then quenched to make the surface hardness 321 HB or more .

In the techniques disclosed in Patent Document 1 to Patent Document 3, a large amount of alloying elements are added, and phenomena such as solid solution hardening, transformation hardening, and precipitation hardening are used to increase hardness, thereby improving wear resistance.

In Patent Document 4, a wear-resistant steel is proposed, which contains 0.10% to 0.45% of C, 0.10% to 1.0% of titanium (Ti), and further contains appropriate amounts of Si, Mn, P, S, N , Al, and arbitrarily containing one or more of Cu, Ni, Cr, Mo, B for continuous casting of molten steel, and ^{more than 400 precipitates per 1 mm 2} with a size of 0.5 μm or more and mainly TiC precipitation Things. In the technique disclosed in Patent Document 4, during solidification of continuous casting, coarse precipitates mainly composed of TiC with high hardness are generated, and the wear resistance is improved by the precipitates. [Prior Art Document] [Patent Document]

Patent Document 1: Japanese Patent Laid-Open No. 62-142726 Patent Document 2: Japanese Patent Laid-Open No. 63-169359 Patent Document 3: Japanese Patent Laid-Open No. 1-142023 Patent Document 4: Japanese Patent Laid-Open No. 6-256896

Generally speaking, the thick plate process is used in the manufacture of wear-resistant steel, that is, a thick plate mill is used to hot-roll the slab to form a thick steel plate, and the thick steel plate is directly or reheated and then quenched. After tempering arbitrarily. Patent Document 1 to Patent Document 4 also describe the production of wear-resistant thick steel plates by a method of manufacturing wear-resistant steel plates using a thick plate process.

On the other hand, in recent years, as a wear-resistant steel, the demand for thin steel plates is increasing. For example, from the viewpoint of environmental restrictions, the weight of dumps is required to be lighter. Therefore, it is desirable to apply a thin steel plate to the wear-resistant steel used in the bracket of the dumper loaded with high hardness materials such as sand and soil.

However, in the previous thick plate process used in the manufacture of wear-resistant steel, the industrial production of thick steel plates with a thickness of about 6 mm is the limit, and the thick plate process cannot be applied to thin steel plates with a plate thickness of less than 6.0 mm. In manufacturing. That is, there is a problem that when a thick plate process is used to produce a thin steel sheet with a thickness of less than 6.0 mm, the characteristics of the thick plate process cannot meet the flatness specifications due to cooling strain.

Therefore, in view of the above-mentioned problems, the present invention aims to provide a wear-resistant steel sheet with high flatness and an advantageous manufacturing method thereof.

In order to solve the above-mentioned problems, the inventors of the present invention obtained the idea of manufacturing a wear-resistant steel sheet by a general hot rolling process for manufacturing a steel sheet. That is, a hot rolling mill including a rough rolling mill and a finishing rolling mill used in the hot rolling process is used to hot-roll the slab to produce a thin steel sheet. Thereafter, by cooling the thin steel sheet at an average cooling rate between 900°C and 300°C of 30°C/sec or more, the main structure of Asada loose iron can be obtained. Thereafter, by winding the thin steel sheet under the condition that the winding temperature is 200° C. or lower, a wear-resistant thin steel sheet with high hardness due to the structure of the Asada loose iron main body can be obtained. In addition, through the hot rolling process, a wear-resistant thin steel plate with high flatness can be manufactured.

The gist of the present invention completed based on the knowledge is as follows. (1) A wear-resistant thin steel plate characterized by: Calculated by mass%, containing C: 0.10%～0.30%, Si: 0.01%～1.0%, Mn: 0.30%～2.00%, P: 0.03% or less, S: 0.03% or less, Cr: 0.01%～2.00%, Al: 0.001%～0.100%, Ti: 0.001%～0.050%, B: 0.0001%～0.0100%, and N: 0.01% or less, The remaining part contains iron (Fe) and unavoidable impurities, and It has a structure with a volume ratio of martensite of 90% or more in the total plate thickness, The hardness at a depth of 0.5 mm from the surface is 360 HBW5/750 to 490 HBW5/750 in terms of Brinell hardness.

(2) The wear-resistant steel sheet as described in (1), wherein the component composition is calculated by mass%, and further includes selected from Cu: 2.00% or less, Ni: 5.00% or less, Mo: Below 3.00%, V: 1.000% or less, Tungsten (W): 1.50% or less, Calcium (Ca): less than 0.0200%, Magnesium (Mg): less than 0.0200%, and Rare Earth Metal (REM): less than 0.0500% More than one type in the group.

(3) The wear-resistant steel sheet described in (1) or (2) above has a surface roughness Ra of 40 μm or less.

(4) The wear-resistant steel sheet as described in any one of (1) to (3), wherein when a 2 m long strip is abutted against the surface of the steel sheet in the rolling direction, the surface of the steel sheet and The maximum value of the gap between the strips is 10 mm or less.

(5) A method for manufacturing a wear-resistant steel sheet, characterized by comprising: continuous casting of molten steel having the composition of the wear-resistant steel sheet as described in (1) or (2) to obtain a plate The step of slab heating; the step of heating the slab to 1000°C to 1300°C; after that, the slab is subjected to hot rolling including finishing rolling at a finishing temperature of 900°C or higher to obtain The step of thin steel plate; the step of cooling the thin steel plate under the condition that the average cooling rate between 900°C and 300°C is 30°C/sec or more; and thereafter the winding temperature is 200°C or less. Describe the winding step of the thin steel plate.

(6) The method for manufacturing a wear-resistant steel sheet as described in (5), further including a step of subjecting the thin steel sheet obtained by the winding step to temper rolling.

According to the present invention, a wear-resistant thin steel plate with high flatness and an advantageous manufacturing method thereof can be provided.

(Wear-resistant steel sheet)

Hereinafter, the wear-resistant steel sheet (hot-rolled steel sheet) of the present invention will be described.

[Ingredient composition] First, the component composition of the wear-resistant steel sheet of the present invention and the reason for its limitation will be explained. In addition, the unit of the content of each element in the component composition is all "mass %", and unless otherwise specified, it will only be represented by "%" below.

C: 0.10%～0.30% C is an element necessary to increase the hardness of the Asada scattered iron matrix. When the amount of C is too small, the amount of solid solution C in the Asada scattered iron phase decreases, so the hardness of the surface layer portion decreases and the wear resistance deteriorates. From this viewpoint, the amount of C is set to 0.10% or more, preferably 0.14% or more. On the other hand, when the amount of C is excessive, the weldability and toughness are significantly deteriorated. From this viewpoint, the amount of C is set to 0.30% or less, preferably 0.25% or less.

Si: 0.01%～1.0% Si is an element effective for deoxidation, and is an element that contributes to the increase in hardness of steel by solid solution strengthening. From the viewpoint of obtaining these effects, the amount of Si is set to 0.01% or more, preferably 0.10% or more. On the other hand, when the amount of Si is too large, it adheres to the surface of the thin steel sheet as a scale and deteriorates the surface roughness. From this viewpoint, the amount of Si is 1.0% or less, preferably 0.40% or less.

Mn: 0.30%～2.00% Mn is an element effective for improving the hardenability of steel. By adding Mn, the hardness of the quenched steel increases, and as a result, the wear resistance is improved. From the viewpoint of obtaining this effect, the amount of Mn is set to 0.30% or more, preferably 0.50% or more, and more preferably 0.60% or more. On the other hand, when the amount of Mn is too large, weldability and toughness are significantly deteriorated. From this viewpoint, the amount of Mn is set to 2.00% or less, preferably 1.50% or less.

P: Below 0.03% P is an element that has the effect of increasing the strength of steel, but it is an element that reduces toughness, particularly the toughness of the welded portion. Therefore, the amount of P is set to 0.03% or less, preferably 0.02% or less, and more preferably 0.01% or less. On the other hand, the smaller the amount of P, the better, so the lower limit is not particularly limited, and may be 0%. However, usually P is inevitably contained in steel as an impurity, so the amount of P can exceed 0% industrially. In addition, from the viewpoint of steel-making cost, the amount of P is preferably set to 0.001% or more.

S: 0.03% or less S exists in steel as sulfide-based inclusions such as MnS, and deteriorates toughness. Therefore, the amount of S is set to 0.03% or less, preferably 0.02% or less, and more preferably 0.015% or less. On the other hand, the smaller the amount of S, the better, so the lower limit is not particularly limited, and may be 0%. However, usually S is inevitably contained in steel as an impurity, so the amount of S can exceed 0% industrially. In addition, from the viewpoint of steel manufacturing cost, the amount of S is preferably set to 0.0001% or more.

Cr: 0.01%～2.00% Cr is an element effective for improving the hardenability of steel. By adding Cr, the hardness of the quenched steel increases, and as a result, the wear resistance is improved. From the viewpoint of obtaining this effect, the amount of Cr is set to 0.01% or more, preferably 0.05% or more, and more preferably 0.10% or more. On the other hand, when the amount of Cr is excessive, the weldability deteriorates. From this viewpoint, the amount of Cr is set to 2.00% or less, preferably 1.80% or less, and more preferably 1.00% or less.

Al: 0.001%～0.100% Al is an element that is effective as a deoxidizer and has the effect of forming nitrides and reducing the particle size of austenite. From the viewpoint of obtaining this effect, the amount of Al is set to 0.001% or more, preferably 0.010% or more. On the other hand, when the amount of Al is too large, toughness deteriorates. Therefore, the amount of Al is set to 0.100% or less, preferably 0.050% or less.

Ti: 0.001%～0.050% Ti is an element with a strong affinity for N, and it precipitates as TiN during solidification, and has the effect of reducing the solid solution N in steel and reducing the deterioration of toughness caused by strain aging of N after cold working. In addition, Ti also contributes to the improvement of the toughness of the welded part. From the viewpoint of obtaining these effects, the amount of Ti is set to 0.001% or more, preferably 0.005% or more, and more preferably 0.007% or more. On the other hand, when the amount of Ti is too large, the TiN particles become coarse, and the effect cannot be sufficiently obtained. Therefore, from this viewpoint, the amount of Ti is set to 0.050% or less, preferably 0.045% or less.

B: 0.0001%～0.0100% B is an element having an effect of improving hardenability by adding a very small amount, thereby increasing the strength of the steel sheet. From the viewpoint of obtaining this effect, the amount of B is set to 0.0001% or more, preferably 0.0003% or more, and more preferably 0.0010% or more. On the other hand, when the amount of B is too large, the toughness, particularly the toughness of the welded portion, decreases. Therefore, the amount of B is set to 0.0100% or less, preferably 0.0040% or less.

N: 0.01% or less N is an element that reduces ductility and toughness, so the amount of N is set to 0.01% or less. On the other hand, the smaller the amount of N, the better, so the lower limit is not particularly limited, and may be 0%. However, usually N is inevitably contained in steel as an impurity, so the amount of N can exceed 0% industrially. In addition, from the viewpoint of steel-making cost, the amount of N is preferably set to 0.0005% or more.

In addition to containing the basic components, as an optional component for the purpose of improving hardenability or weldability, it may further contain Cu: 2.00% or less, Ni: 5.00% or less, Mo: 3.00% or less, and V: 1.000% or less , W: 1.50% or less, Ca: 0.0200% or less, Mg: 0.0200% or less, and REM: 0.0500% or less.

Cu: 2.00% or less Cu is an element that can improve hardenability without significantly degrading toughness. In order to obtain this effect, it is preferable to set the amount of Cu to 0.01% or more, more preferably to 0.05% or more. On the other hand, when the amount of Cu is excessive, cracks in the steel sheet caused by the Cu-rich layer formed directly under the scale become a problem. Therefore, when Cu is added, the amount of Cu is set to 2.00% or less, preferably 1.50% or less.

Ni: 5.00% or less Ni is an element having an effect of improving hardenability and toughness. In order to obtain these effects, the amount of Ni is preferably set to 0.01% or more, more preferably set to 0.05% or more. On the other hand, when the amount of Ni is too large, an increase in manufacturing cost becomes a problem. Therefore, when adding Ni, the amount of Ni is set to 5.00% or less, preferably 4.50% or less.

Mo: 3.00% or less Mo is an element that improves the hardenability of steel. In order to obtain this effect, the amount of Mo is preferably set to 0.01% or more, more preferably set to 0.05% or more. On the other hand, when the amount of Mo is too large, the weldability decreases. Therefore, when Mo is added, the amount of Mo is set to 3.00% or less, preferably 2.00% or less.

V: 1.000% or less V is an element that improves the hardenability of steel. In order to obtain this effect, the amount of V is preferably set to 0.001% or more. On the other hand, when the amount of V is too large, the weldability decreases. Therefore, when V is added, the amount of V is set to 1.000% or less.

W: 1.50% or less W is an element that improves the hardenability of steel. In order to obtain this effect, the amount of W is preferably set to 0.01% or more. On the other hand, when the amount of W is too large, the weldability decreases. Therefore, when adding W, the amount of W is set to 1.50% or less.

Ca: 0.0200% or less Ca is an element that improves weldability by forming oxysulfide with high stability at high temperature. In order to obtain this effect, the amount of Ca is preferably set to 0.0001% or more. On the other hand, when the amount of Ca is too large, the cleanliness is lowered, and the toughness of the steel is impaired. Therefore, when adding Ca, the amount of Ca is set to 0.0200% or less.

Mg: less than 0.0200% Mg is an element that improves weldability by forming oxysulfide with high stability at high temperatures. In order to obtain this effect, the amount of Mg is preferably set to 0.0001% or more. On the other hand, when the amount of Mg is too large, the effect of adding Mg is saturated, and an effect commensurate with the content cannot be expected, which is economically disadvantageous. Therefore, when Mg is added, the amount of Mg is set to 0.0200% or less.

REM: Below 0.0500% REM (rare earth metal) is an element that improves weldability by forming highly stable oxysulfides at high temperatures. In order to obtain this effect, the amount of REM is preferably set to 0.0005% or more. On the other hand, when the amount of REM is too large, the effect of adding REM is saturated, and an effect commensurate with the content cannot be expected, which is economically disadvantageous. Therefore, when REM is added, the amount of REM is set to 0.0500% or less.

The remainder other than those mentioned in the component composition contains Fe and unavoidable impurities. In addition, Sb, Sn, Co, As, Pb, and Zn may each be contained at 1.0% or less.

[organization] The wear-resistant steel sheet of the present invention has a structure in which the volume ratio of Asada loose iron is 90% or more in the total thickness from the surface to the back surface.

The volume rate of Asada loose iron: more than 90% If the volume ratio of Asada loose iron is less than 90%, the hardness of the matrix structure of the thin steel sheet decreases, and therefore the wear resistance decreases. Therefore, the volume ratio of Asada loose iron is set to 90% or more, preferably 95% or more. The remaining part of the structure except for Asada iron is not particularly limited, and can be selected from the group consisting of ferrite, pearlite, austenitic iron, and bainite More than one kind. On the other hand, the higher the volume ratio of Asada scattered iron, the better, and therefore the upper limit of the volume ratio is not particularly limited, and may be 100%. In addition, the volume ratio of the said Asada loose iron was set to a value in the total thickness of the wear-resistant steel sheet from the surface to the back surface. The volume ratio of the Asada powder can be measured by the method described in the examples.

[hardness] Brinell hardness: 360 HBW5/750～490 HBW5/750 The wear resistance of the thin steel sheet can be improved by increasing the hardness of the surface layer portion of the thin steel sheet. Here, in the present invention, Brinell hardness is used as an index for evaluating wear resistance characteristics. When the Brinell hardness of the surface layer part of the thin steel sheet is less than 360 HBW, sufficient wear resistance cannot be obtained. On the other hand, when the Brinell hardness of the surface layer portion of the thin steel sheet exceeds 490 HBW, the bending workability deteriorates. Therefore, in the present invention, the hardness of the surface layer portion of the thin steel sheet is set to 360 HBW to 490 HBW in terms of Brinell hardness. In addition, here, the "hardness of the surface layer portion" refers to the hardness at a depth of 0.5 mm from the surface of the wear-resistant steel sheet. The reason for this is that the decarburized layer of the surface layer of the thin steel sheet is substantially removed, and the variation of the measured value is reduced. In addition, in the present invention, the "Brinell hardness" is a value measured with a load of 750 kgf using a tungsten steel ball with a diameter of 5 mm (unit: HBW5/750). The Brinell hardness can be measured by the method described in the examples.

[Board Thickness] The thickness of the wear-resistant thin steel plate of the present invention is less than 6.0 mm, preferably 4.5 mm or less, and more preferably 4.0 mm or less. In addition, the lower limit of the plate thickness is not particularly limited, but in terms of limitations on the hot rolling process, it is approximately 2.0 mm or more.

[Surface roughness] Surface roughness Ra: 40 μm or less In the case of the wear-resistant thick steel plate manufactured by the previous thick plate process, it is always in contact with the atmosphere during the cooling (quenching) process after hot rolling, and exposed to the atmosphere at a high temperature of 200°C or more for a long time For about 20 hours, a large amount of scale grows on the surface of the steel sheet, and the surface roughness Ra immediately after cooling is about 50 μm to 150 μm. In contrast, the wear-resistant steel sheet of the present invention is wound into a hot-rolled coil during a hot rolling process. In this state, the surface of the steel sheet is not exposed to the atmosphere, so it is exposed to the atmosphere at a high temperature of 200°C or higher. The time is approximately 30 seconds after finishing rolling to winding, and the amount of scale on the surface of the steel sheet is small. As a result, the wear-resistant steel sheet of the present invention can have a surface roughness Ra of 40 μm or less. The lower the surface roughness, the more beautiful the surface of the thin steel sheet and the better the paintability. Therefore, the present invention is also applicable to the case of coating wear-resistant thin steel plates for use. In addition, since the surface roughness is small, when the wear-resistant steel sheet of the present invention is used mainly in a portion contacting the rotating body such as the cover of the shaft center for wind power generation, it does not become a resistance to rotation. Furthermore, in the wear-resistant steel sheet of the present invention, the lower limit of the surface roughness Ra is not particularly limited, but in terms of limitations on the hot rolling process, it is approximately 10 μm or more.

[flatness] In the previous thick plate manufacturing process, the shape correction of the thick steel plate after quenching or subsequent tempering was performed using a leveller. The shape correction performed by the leveling machine is based on the Bauschinger effect. In principle, it is just to disperse the strain to homogenize it. The correctable area is narrow and the correction effect is limited. In the case of a thick steel plate, since the cooling strain is small, high flatness can be obtained even for shape correction by a leveler. However, in the case of thin steel sheets that are greatly affected by cooling strain, shape correction by a leveler cannot achieve high flatness. That is, when a thin steel plate with a thickness of less than 6.0 mm is to be manufactured by a thick plate process, a thin steel plate with high flatness cannot be obtained. In contrast, the wear-resistant steel sheet of the present invention is manufactured by a hot rolling process. In the hot rolling process, the hot-rolled coil is rewinded on the skin pass line, and the front-rear tension is given to extend the thin steel plate. On this basis, a leveler is added, so the range of correction is wide. The correction effect is high. Therefore, the wear-resistant steel sheet of the present invention can achieve high flatness. Specifically, the maximum gap between the surface of the steel sheet and the strip can be achieved when a 2 m strip is abutted against the surface of the steel sheet in the rolling direction. The value is 10 mm or less, more preferably 5 mm or less. The maximum value of the gap is as small as possible, and it can be 0 mm or more.

(Manufacturing method of wear-resistant steel sheet) The manufacturing method of the wear-resistant steel sheet of the present invention includes: a step of continuously casting molten steel having the composition to obtain a slab; a step of heating the slab to a predetermined temperature; Next, a step of performing hot rolling on the slab to obtain a thin steel plate; a step of cooling the thin steel plate under a predetermined condition thereafter; and a step of winding the thin steel plate under a predetermined condition thereafter. The hot-rolled coil obtained in this way is rewound and subjected to arbitrary temper rolling for the purpose of shape correction, whereby the wear-resistant steel sheet of the present invention can be obtained. Hereinafter, each step will be described in detail.

[Continuous Casting] The slab is obtained by smelting the steel having the composition by a conventional method using melting equipment such as a converter and an electric furnace, and continuous casting. The conditions of continuous casting are not particularly limited, as long as it is performed by a conventional method.

[Slab heating] Heating temperature: 1000℃～1300℃ When the heating temperature is too low, the carbide is not completely dissolved, and the solid solution C is insufficient, so the strength is likely to decrease. In addition, the hardenability is insufficient, and the hardness of the surface layer portion of the thin steel sheet is reduced, so the wear resistance is deteriorated. From this viewpoint, the heating temperature is set to 1000°C or higher, preferably 1100°C or higher, and more preferably 1200°C or higher. On the other hand, if the heating temperature is too high, the structure becomes coarser and the toughness decreases. Therefore, the heating temperature is set to 1300°C or lower. In addition, the heating temperature of a slab shall be the temperature of the surface of a slab.

[Hot Rolled] After that, hot rolling is performed on the slab to obtain a thin steel sheet. This step is not performed using a hot rolling mill (thick plate mill) used in a thick plate process, but a hot rolling mill including a rough rolling mill and a finishing mill used in a hot rolling process for manufacturing thin steel sheets. In addition, the thickness of the thin steel sheet obtained by this step is as described above as the thickness of the wear-resistant thin steel sheet of the present invention.

Finishing rolling temperature: above 900℃ When the finish rolling temperature is too low, the hardenability is insufficient, and the hardness of the surface layer portion of the thin steel sheet is lowered, so the wear resistance is deteriorated. From this viewpoint, the finishing temperature is set to 900°C or higher. The upper limit of the finish rolling temperature is not particularly limited, but when the finish rolling temperature is too high, the rolling efficiency deteriorates. From this viewpoint, the finishing temperature is preferably set to 1000°C or lower. In addition, in the present invention, the "finish rolling temperature" is the temperature of the surface of the thin steel sheet. However, in the case of the thin steel sheet, the temperature of the central part of the sheet thickness is also approximately the same as the surface temperature.

[cool down] Average cooling rate between 900°C and 300°C: 30°C/sec or more Next, by cooling the thin steel plate, the structure of the main body of Asada loose iron is obtained. At this time, by the rapid cooling from the finishing rolling temperature, the austenitic iron crystal grains at the time of finishing rolling become Asada scattered iron crystal grains while maintaining their grain size. Here, when the average cooling rate between 900° C. and 300° C. is less than 30° C./sec, the volume ratio of Asada loose iron is less than 90%, and the hardness of the surface layer portion cannot be ensured, and the wear resistance is deteriorated. Therefore, the average cooling rate between 900°C and 300°C is set to 30°C/sec or more, preferably 50°C/sec or more. On the other hand, the upper limit of the average cooling rate is not particularly limited, but in terms of restrictions on cooling equipment, the average cooling rate is approximately 150° C./sec or less. In addition, in the present invention, the "average cooling rate" is determined based on the decrease in the surface temperature of the steel sheet. The cooling means of the thin steel plate is not particularly limited, but from the viewpoint of obtaining the average cooling rate, it is preferable to use water cooling.

[Winding] Winding temperature: below 200℃ Next, the thin steel sheet is wound to obtain a hot rolled coil. When the winding temperature exceeds 200°C, the volume ratio of Asada loose iron is less than 90%, the hardness of the surface layer part cannot be ensured, and the wear resistance is deteriorated. Therefore, the winding temperature is set to 200°C or lower, preferably 150°C or lower. The lower limit of the winding temperature is not particularly limited, but in order to wind and transport the steel sheet, the winding temperature is preferably 50°C or higher. In addition, in the present invention, the "winding temperature" is the temperature of the surface of the thin steel sheet.

Furthermore, in the present invention, after the thin steel sheet is cooled after finish rolling, it may be directly wound without reheating (tempering). After finishing rolling, the time to winding is preferably 30 seconds to 90 seconds.

[Quenched and tempered rolling] It is preferable to rewind the hot-rolled coil obtained by the winding step, and subject the thin steel sheet to temper rolling for the purpose of shape correction. In temper rolling, shape correction is performed by elongating the steel sheet by about 0.1% to 1.0%. Furthermore, in temper rolling, it is preferable to use a tension leveler. [Example]

The molten steel having the component composition shown in Table 1 was cast to obtain a slab. For each slab, the "hot rolling process" or the "thick plate process" is applied as shown in Table 2 to manufacture steel plates. At this time, as the common parameters in the two processes, "slab heating temperature", "finishing rolling temperature" and "average cooling rate" are shown in Table 2. In addition, as a parameter related only to the "hot rolling process", the "coiling temperature" is shown in Table 2. No reheating after cooling was performed at any level. The plate thickness at each level is also shown in Table 2.

In addition, the "average cooling rate" of the level of the hot rolling process shows the average cooling rate between 900°C and 300°C at a level where the finishing temperature is 900°C or higher and the winding temperature is 300°C or lower. When the finishing temperature is less than 900°C and the coiling temperature is 300°C or less, the average cooling rate from the finishing temperature to 300°C is shown. When the finishing temperature is less than 900°C and the coiling temperature exceeds 300°C Below, the average cooling rate from the finishing temperature to the winding temperature is shown. In addition, the "average cooling rate" for the level of the thick plate process shows the average cooling rate between 900°C and 300°C when the finishing temperature is 900°C or higher, and when the finishing temperature is less than 900°C Below, the average cooling rate from the finish rolling temperature to 300°C is shown.

Regarding the standard of the hot rolling process, tempering rolling is carried out. Regarding the standard of the thick plate manufacturing process, the shape correction of the cooled (quenched) thick steel plate is carried out by a leveling machine.

[Volume rate of Asada scattered iron] From the center in the width direction of each level of the steel plate, a sample exposing a cross section in the thickness direction parallel to the rolling direction was collected, and the cross section was mirror-polished, and then the nitrate etching solution (Nital) was corroded. Using a scanning electron microscope (Scanning Electron Microscope, SEM), observe and photograph the total of the field of view including the surface of the steel plate (two fields of view on one side and the other side) and the field of view including the center of the plate thickness in the cross section in the thickness direction at 400 times magnification Three horizons. By using an image analysis device to analyze the obtained image, the area fraction of Asada scattered iron is obtained. In this specification, when the area fraction of Asada loose iron in all three fields of view is 90% or more, it is considered that the volume fraction of Asada loose iron in the total plate thickness is 90% or more. Therefore, the smallest value among the area fractions of Asada loose iron in the three fields of view is described in Table 2 as the "Asada loose iron volume fraction".

[Brinell hardness] Samples are collected from thin or thick steel plates of various levels, and the surface layer of each sample is ground 0.5 mm (0.5 mm thickness from the surface), and then the surface is mirror-polished, according to Japanese Industrial Standards (JIS) Z2243 (2008), the Brinell hardness was measured at 5 points on the mirror polished surface, and the average of the 5 points is shown in the "Brinell hardness" column of Table 2. A tungsten steel ball with a diameter of 5 mm was used in the measurement, and the load was set to 750 kgf.

[Surface roughness] For each level of thin steel plate or thick steel plate, the arithmetic average height Ra specified in JIS B 0601-2001 was measured by the non-contact measurement method, and the results are shown in Table 2.

[flatness] Use a clearance gauge to measure the gap between the surface of the steel plate and the long strip when a 2 m long strip is brought into contact with the surface of each level of thin or thick steel plate in the rolling direction, and find the maximum value. This measurement was performed at a total of three locations at the center and both ends in the width direction of the steel sheet, and the average value of the three maximum values is shown in Table 2.

[Table 1] Table 1 Steel type Composition (mass%) Remark C Si Mn P S Cr Al Ti B N Cu Ni Mo V W Ca Mg REM A 0.20 0.36 0.70 0.011 0.002 0.72 0.029 0.012 0.0020 0.0036 - - - - - - - - Meet the steel B 0.21 0.29 0.71 0.006 0.004 0.70 0.039 0.014 0.0010 0.0039 - - - - - - - - Meet the steel C 0.14 0.35 1.17 0.010 0.003 0.11 0.031 0.014 0.0010 0.0033 - - 0.13 - - - - - Meet the steel D 0.15 0.34 1.16 0.008 0.002 0.12 0.033 0.011 0.0010 0.0036 - - 0.11 - - - - - Meet the steel E 0.17 0.41 1.35 0.018 0.003 0.45 0.025 - 0.0011 0.0025 - - - - - - - - Comparative steel F 0.16 0.29 1.33 0.014 0.005 0.28 0.035 0.009 0.0013 0.0031 - - - - - - - - Meet the steel G 0.31 0.22 1.11 0.008 0.008 0.91 0.045 0.023 0.0018 0.0041 - - - - - - - - Comparative steel H 0.30 0.01 1.41 0.009 0.004 2.40 0.031 0.034 0.0010 0.0044 - - - - - - - - Comparative steel I 0.15 0.41 1.35 0.018 0.003 0.22 0.036 0.123 0.0020 0.0034 - - - - - - - - Comparative steel J 0.09 0.02 1.71 0.012 0.008 0.21 0.028 0.019 0.0010 0.0038 - - - - - - - - Comparative steel K 0.16 0.22 1.11 0.008 0.008 - 0.041 0.023 0.0030 0.0036 - - - - - - - - Comparative steel L 0.30 0.38 0.74 0.021 0.012 0.21 0.044 0.032 0.02 0.0041 - - - - - - - - Comparative steel M 0.30 0.01 2.50 0.050 0.009 0.32 0.038 0.084 - 0.0039 - - - - - - - - Comparative steel N 0.14 0.36 1.18 0.009 0.003 0.10 0.030 0.012 0.0010 0.0033 - - - - - - - - Meet the steel O 0.13 0.01 1.09 0.018 0.011 0.01 0.041 0.012 - 0.0021 - - - - - - - - Comparative steel P 0.16 0.91 1.20 0.008 0.001 0.06 0.038 0.041 0.0020 0.0044 - - - - - - - - Meet the steel Q 0.21 0.26 0.71 0.006 0.004 0.73 0.039 0.014 0.0010 0.0039 0.03 - - - - - - - Meet the steel R 0.23 0.28 0.73 0.006 0.005 0.70 0.039 0.014 0.0020 0.0039 - 0.02 - - - - - - Meet the steel S 0.14 0.35 1.17 0.010 0.003 0.11 0.031 0.012 0.0010 0.0041 - - 0.13 0.002 - - - - Meet the steel T 0.21 0.22 0.71 0.006 0.004 0.70 0.039 0.014 0.0030 0.0039 - - - - 0.04 - - - Meet the steel U 0.14 0.35 1.14 0.010 0.003 0.11 0.031 0.014 0.0010 0.0033 - - 0.12 - - 0.0006 - - Meet the steel V 0.21 0.29 0.76 0.006 0.004 0.74 0.039 0.013 0.0020 0.0036 - - - - - - 0.0001 - Meet the steel W 0.22 0.31 0.71 0.006 0.005 0.70 0.039 0.014 0.0010 0.0031 - - - - - - - 0.0010 Meet the steel X 0.32 0.21 1.16 0.011 0.007 0.93 0.045 0.023 0.0018 0.0043 - - - - - - - - Comparative steel ･The remainder is Fe and unavoidable impurities. ･Underlined means outside the scope of the invention.

[Table 2] Table 2 No. Steel type step Manufacturing conditions Board thickness (mm) Asada bulk iron volume rate (%) Brinell hardness (HBW) Surface roughness Ra (μm) flatness Remark Slab heating temperature (℃) Finishing rolling temperature (℃) Average cooling rate (℃/sec) Winding temperature (℃) 1 A Hot rolled 1251 908 65 110 3.2 98 457 19 4 mm/2000 mm Invention Examples 2 B Hot rolled 1258 907 77 122 3.2 98 449 twenty two 2 mm/2000 mm Invention Examples 3 C Hot rolled 1277 905 72 118 4.0 95 401 27 1 mm/2000 mm Invention Examples 4 D Hot rolled 1280 912 76 106 3.2 96 411 twenty one 3 mm/2000 mm Invention Examples 5 E Thick plate 1175 911 35 - 8.0 98 451 101 17 mm/2000 mm Comparative example 6 F Thick plate 1162 901 41 - 6.0 96 459 103 21 mm/2000 mm Comparative example 7 G Thick plate 1158 910 35 - 8.0 95 523 93 13 mm/2000 mm Comparative example 8 H Hot rolled 1288 902 45 114 3.2 93 498 twenty three 4 mm/2000 mm Comparative example 9 I Hot rolled 1211 903 33 191 3.2 91 333 33 2 mm/2000 mm Comparative example 10 J Hot rolled 1266 909 70 150 3.2 91 320 39 1 mm/2000 mm Comparative example 11 K Hot rolled 1279 909 45 133 4.0 88 345 25 3 mm/2000 mm Comparative example 12 L Hot rolled 1229 907 55 129 3.2 92 494 38 4 mm/2000 mm Comparative example 13 M Hot rolled 1255 901 38 133 3.2 88 492 32 2 mm/2000 mm Comparative example 14 N Hot rolled 1276 912 28 350 3.2 55 330 twenty two 8 mm/2000 mm Comparative example 15 O Hot rolled 1281 921 35 189 3.2 77 342 35 4 mm/2000 mm Comparative example 16 C Hot rolled 1269 820 40 120 3.2 63 301 38 4 mm/2000 mm Comparative example 17 C Hot rolled 1252 908 41 350 3.2 42 288 31 5 mm/2000 mm Comparative example 18 C Hot rolled 1249 911 25 198 3.2 29 261 29 2 mm/2000 mm Comparative example 19 P Hot rolled 1273 901 77 119 3.2 93 402 79 2 mm/2000 mm Invention Examples 20 Q Hot rolled 1279 911 72 121 3.8 94 455 twenty two 3 mm/2000 mm Invention Examples twenty one R Hot rolled 1283 902 69 109 4.0 91 462 13 4 mm/2000 mm Invention Examples twenty two S Hot rolled 1274 908 71 107 3.2 95 408 19 2 mm/2000 mm Invention Examples twenty three T Hot rolled 1286 911 88 113 3.2 91 459 33 1 mm/2000 mm Invention Examples twenty four U Hot rolled 1281 901 91 88 4.0 91 398 29 8 mm/2000 mm Invention Examples 25 V Hot rolled 1259 903 72 130 3.2 94 457 36 4 mm/2000 mm Invention Examples 26 W Hot rolled 1249 907 77 141 3.2 92 466 26 2 mm/2000 mm Invention Examples 27 X Hot rolled 1261 908 71 118 3.2 93 531 33 1 mm/2000 mm Comparative example ･Underlined means outside the scope of the invention. [Industrial availability]

According to the present invention, a wear-resistant thin steel plate with high flatness and an advantageous manufacturing method thereof can be provided.

without

without

Claims (7)

A wear-resistant thin steel plate, characterized in that it contains carbon: 0.10%~0.30%, silicon: 0.01%~1.0%, manganese: 0.30%~2.00%, phosphorus: less than 0.03%, and sulfur: Below 0.03%, Chromium: 0.01%~2.00%, Aluminum: 0.001%~0.100%, Titanium: 0.001%~0.050%, Boron: 0.0001%~0.0100%, and Nitrogen: below 0.01%, the remainder contains iron and unavoidable The composition of impurities, and the volume ratio of Asada scattered iron in the total plate thickness is 90% or more. The hardness at a depth of 0.5mm from the surface is 360HBW5/750~490HBW5/750 in terms of Brinell hardness. . The wear-resistant thin steel plate according to claim 1, wherein the composition of the component, in terms of mass%, further contains selected from copper: 2.00% or less, nickel: 5.00% or less, molybdenum: 3.00% or less, One or more of the group consisting of vanadium: 1.000% or less, tungsten: 1.50% or less, calcium: 0.0200% or less, magnesium: 0.0200% or less, and rare earth metals: 0.0500% or less. The wear-resistant steel sheet described in claim 1 or claim 2 has a surface roughness Ra of 40 μm or less. The wear-resistant steel sheet according to claim 1 or claim 2, wherein the maximum value of the gap between the surface of the steel plate and the long strip when a 2 m long strip is abutted against the surface of the steel plate in the rolling direction is Below 10mm. The wear-resistant steel sheet according to claim 3, wherein the maximum value of the gap between the surface of the steel sheet and the long strip when a 2 m long strip is brought into contact with the surface of the steel sheet in the rolling direction is 10 mm or less. A method for manufacturing a wear-resistant thin steel plate, which is characterized in that it comprises the step of continuously casting molten steel having the composition of the wear-resistant thin steel plate as described in claim 1 or claim 2 to obtain a slab; The step of heating the slab to 1000°C to 1300°C; and then the step of performing hot rolling on the slab including finishing rolling performed at a finishing temperature of 900°C or higher to obtain a thin steel plate; The step of cooling the thin steel sheet under the condition that the average cooling rate between 900°C and 300°C is 30°C/sec or more; and Afterwards, the winding step of winding the thin steel sheet under the condition of a winding temperature of 200°C or less; the manufactured wear-resistant thin steel sheet has a structure with a volume ratio of Asada scattered iron of 90% or more in the total plate thickness, The hardness at a depth of 0.5 mm from the surface is 360HBW5/750 to 490HBW5/750 in terms of Brinell hardness. The method for manufacturing a wear-resistant thin steel sheet according to claim 6, further including a step of subjecting the thin steel sheet obtained by the winding step to temper rolling.