TWI734747B - Adhesive tape - Google Patents

Adhesive tape Download PDF

Info

Publication number
TWI734747B
TWI734747B TW106105050A TW106105050A TWI734747B TW I734747 B TWI734747 B TW I734747B TW 106105050 A TW106105050 A TW 106105050A TW 106105050 A TW106105050 A TW 106105050A TW I734747 B TWI734747 B TW I734747B
Authority
TW
Taiwan
Prior art keywords
adhesive
tape
adhesive tape
adhesive layer
rubber
Prior art date
Application number
TW106105050A
Other languages
Chinese (zh)
Other versions
TW201736544A (en
Inventor
山本智章
園田誠
Original Assignee
日商寺岡製作所股份有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 日商寺岡製作所股份有限公司 filed Critical 日商寺岡製作所股份有限公司
Publication of TW201736544A publication Critical patent/TW201736544A/en
Application granted granted Critical
Publication of TWI734747B publication Critical patent/TWI734747B/en

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/10Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
    • B32B3/14Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by a face layer formed of separate pieces of material which are juxtaposed side-by-side
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J121/00Adhesives based on unspecified rubbers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/21Paper; Textile fabrics
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/20Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself
    • C09J2301/204Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself the adhesive coating being discontinuous
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/30Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/312Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/40Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/408Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00Presence of inorganic and organic materials
    • C09J2400/20Presence of organic materials
    • C09J2400/26Presence of textile or fabric
    • C09J2400/263Presence of textile or fabric in the substrate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2421/00Presence of unspecified rubber

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesive Tapes (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Laminated Bodies (AREA)

Abstract

Disclosed is an adhesive tape having an adhesive layer on at least one side of a base wherein the adhesive layer preferably contains a rubber-based adhesive, the adhesive layer partially comprises non-adhesive parts 1 in an optional pattern as well as adhesive parts 2, the adhesive layer is composed of a solid type adhesive composition, and the thickness of adhesive layer is 0.03 to 0.6mm. The adhesive tape has excellent peeling workability, it can be also suitably used in a case there is a place where one does not want to contact with an adhesive, and it has excellent properties such as rough-surface adhesive property, water resistance and cold resistance.

Description

黏著帶 Adhesive tape

本發明係關於有效使用於例如粗面塗裝用遮蔽膠帶等用途,剝離作業性優異、且粗面接著性、耐水性及耐寒性等諸項特性均優異的黏著帶。 The present invention relates to an adhesive tape that is effectively used in applications such as masking tapes for rough coating, has excellent peeling workability, and has excellent properties such as rough surface adhesion, water resistance, and cold resistance.

習知在黏著劑層設有非黏著劑部分的黏著帶已被使用於各種用途。例如專利文獻1~6記載有塗裝用遮蔽膠帶,說明藉由將非黏著劑部分使用為抓持區便可輕易剝離黏著帶。專利文獻7記載有側端部無塗佈黏著帶,說明藉由利用非黏著劑部分,便可使黏著劑對受黏物輕易地進行再剝離、再黏貼。專利文獻8記載有將收納有蔬菜束之捆束、食品的塑料袋等較輕物予以捆束用的黏著帶,係可輕易利用手指朝與長邊方向正交之方向切斷之捆束用黏著帶,有說明於撕裂黏著帶時,為了由手指勾住非黏著劑部便可輕易施行撕裂作業而設計。另一方面,專利文獻9記載有裝飾用遮蔽膠帶,說明藉由在中央處設置非黏著劑部分,而設置未接觸到黏著劑的筒狀或袋狀空間,便可在其中插入物體。又,專利文獻10記載有將濺鍍靶的靶材與背板材利用焊料接合時,為遮蔽住多餘焊料而使用的遮蔽用黏著帶,有說明將非黏著劑部分使用為脫氣通路。又,專利文獻11記載有電池用黏著帶,有說明為防止從基材發生糊滲出,便在基材的二側端緣部設計非黏著劑部分。 The conventional adhesive tape provided with a non-adhesive part on the adhesive layer has been used for various purposes. For example, Patent Documents 1 to 6 describe masking tapes for coating, explaining that the adhesive tape can be easily peeled off by using the non-adhesive part as a grip area. Patent Document 7 describes a non-coated adhesive tape at the side end, and explains that by using the non-adhesive part, the adhesive can be easily peeled off and reattached to the adherend. Patent Document 8 describes an adhesive tape for bundling light objects such as a bundle containing vegetable bunches and plastic bags for food. It is used for bundling that can be easily cut by fingers in a direction orthogonal to the longitudinal direction. The adhesive tape is designed to easily perform the tearing operation by hooking the non-adhesive part with fingers when tearing the adhesive tape. On the other hand, Patent Document 9 describes a masking tape for decoration, which describes that by providing a non-adhesive part at the center and providing a cylindrical or bag-like space not in contact with the adhesive, objects can be inserted therein. In addition, Patent Document 10 describes a masking adhesive tape used to cover excess solder when the target material of the sputtering target and the backing plate are joined by solder, and it is described that the non-adhesive part is used as a degassing passage. In addition, Patent Document 11 describes an adhesive tape for a battery, and it is described that in order to prevent the oozing of the paste from the base material, a non-adhesive part is designed at the edges of both sides of the base material.

就此種黏著帶所使用的黏著劑,特別提案有溶劑系黏著劑(專利文獻5、6、7、8、11)。但是,溶劑系黏著劑若加厚黏著劑層,則在加熱、乾燥步驟中會產生發泡等,因而必須削薄。此情況,受黏物較難對道路等粗面進行接著。又,若未施加壓接力則黏貼性偏低,因而較難在天花板等高處及鷹架處施工。又,因為對水濕潤地方的黏貼性偏低或低溫下的接著性偏低,因而較難在下雨後或冬季、寒冷地施工。又,習知黏著帶亦必須更加提升剝離作業性。 Regarding the adhesive used in such an adhesive tape, a solvent-based adhesive has been specifically proposed (Patent Documents 5, 6, 7, 8, and 11). However, if the solvent-based adhesive thickens the adhesive layer, foaming occurs during the heating and drying steps, so it must be thinned. In this case, it is difficult for the adherend to adhere to rough surfaces such as roads. In addition, if the crimping force is not applied, the adhesiveness is low, so it is more difficult to construct in the ceiling and other high places and the scaffolding. In addition, because the adhesion to water-moist areas is low or the adhesiveness at low temperatures is low, it is difficult to construct after rain or in winter or cold places. In addition, the conventional adhesive tape must also improve the peeling workability.

[先前技術文獻] [Prior Technical Literature] [專利文獻] [Patent Literature]

專利文獻1:日本專利實公平04-15318號公報 Patent Document 1: Japanese Patent Exhibit No. 04-15318

專利文獻2:日本專利實開昭59-176678號公報 Patent Document 2: Japanese Patent Publication No. 59-176678

專利文獻3:日本專利實開平03-94969號公報 Patent Document 3: Japanese Patent Publication No. 03-94969

專利文獻4:日本專利實開平06-077852號公報 Patent Document 4: Japanese Patent Publication No. 06-077852

專利文獻5:日本專利實開昭59-61880號公報 Patent Document 5: Japanese Patent Publication No. 59-61880

專利文獻6:日本專利特開2014-173038號公報 Patent Document 6: Japanese Patent Laid-Open No. 2014-173038

專利文獻7:日本專利特開2000-309762號公報 Patent Document 7: Japanese Patent Laid-Open No. 2000-309762

專利文獻8:日本專利特開2004-10760號公報 Patent Document 8: Japanese Patent Laid-Open No. 2004-10760

專利文獻9:日本實用新案登錄第3152945號公報 Patent Document 9: Japanese Utility Model Registration No. 3152945

專利文獻10:日本專利特開2003-286568號公報 Patent Document 10: Japanese Patent Laid-Open No. 2003-286568

專利文獻11:日本專利特開2013-064086號公報 Patent Document 11: Japanese Patent Laid-Open No. 2013-064086

本發明目的係於提供一種剝離作業性優異、即便於存 在有不願使受黏物接觸到黏著劑的地方之情況仍可適用,且粗面接著性、耐水性、耐寒性等諸項特性均優異的黏著帶。 The purpose of the present invention is to provide an excellent peeling workability, even in storage Adhesive tape that can still be used in places where you do not want the adherend to come into contact with the adhesive, and has excellent properties such as rough surface adhesion, water resistance, and cold resistance.

本發明者等為達成上述目的經深入鑽研之結果,發現使用固態黏著劑組成物,形成部分性存在非黏著劑部分的較厚特定厚度黏著劑層便屬非常有效,遂完成本發明。 In order to achieve the above object, the inventors of the present invention have conducted intensive research and found that it is very effective to use a solid adhesive composition to form a thicker specific thickness adhesive layer with partial non-adhesive parts, and complete the present invention.

即,本發明的黏著帶係具有在基材至少單面上,設有部分性存在非黏著劑部分的黏著劑層者;其中,該黏著劑層係由固態黏著劑組成物構成,該黏著劑層的厚度係0.03~0.6mm。 That is, the adhesive tape of the present invention is provided with an adhesive layer on at least one side of the substrate with a non-adhesive part partially; wherein the adhesive layer is composed of a solid adhesive composition, and the adhesive The thickness of the layer is 0.03~0.6mm.

本發明的黏著帶係具有使用固態黏著劑組成物,形成部分性存在非黏著劑部分的較厚特定厚度黏著劑層,因而剝離作業性優異、且粗面接著性、耐水性、耐寒性等諸項特性均優異。 The adhesive tape of the present invention has the use of a solid adhesive composition to form an adhesive layer with a thicker specific thickness in which non-adhesive parts are partially present. Therefore, it has excellent peeling workability, rough surface adhesion, water resistance, cold resistance, etc. The characteristics are excellent.

1‧‧‧非黏著劑部分 1‧‧‧Non-adhesive part

2‧‧‧黏著劑部分 2‧‧‧Adhesive part

3‧‧‧黏著帶 3‧‧‧Adhesive tape

3a‧‧‧基材 3a‧‧‧Substrate

3b‧‧‧黏著層 3b‧‧‧Adhesive layer

4‧‧‧夾具 4‧‧‧Fixture

5‧‧‧SUS板 5‧‧‧SUS board

6‧‧‧黏著帶之膠帶捲 6‧‧‧Adhesive tape roll

圖1係本發明的黏著帶一實施形態的示意平面圖。 Fig. 1 is a schematic plan view of an embodiment of the adhesive tape of the present invention.

圖2係本發明的黏著帶一實施形態的示意平面圖。 Fig. 2 is a schematic plan view of an embodiment of the adhesive tape of the present invention.

圖3係本發明的黏著帶一實施形態的示意平面圖。 Fig. 3 is a schematic plan view of an embodiment of the adhesive tape of the present invention.

圖4係本發明的黏著帶一實施形態的示意平面圖。 Fig. 4 is a schematic plan view of an embodiment of the adhesive tape of the present invention.

圖5係參考例的環形初黏性(loop tack)試驗說明示意圖。 Fig. 5 is a schematic diagram illustrating the loop tack test of the reference example.

圖6係實施例與比較例所記載碗狀變形的說明示意圖。 Fig. 6 is an explanatory diagram of the bowl-shaped deformation described in the embodiment and the comparative example.

圖1所示係本發明的黏著帶一實施形態的示意平面圖。本實施形態中,非黏著劑部分1與黏著劑部分2呈斜條紋狀交 互形成。因此,在黏著帶的切斷端面其中一部分與側面均存在有抓持區,因而從哪一部分均可輕易剝離。且,由非黏著劑部分1與黏著劑部分2所構成之圖案,當捲取黏著帶形成膠帶捲時,成為非黏著劑部分與黏著劑部分的膠帶厚度差全部或其中一部分相抵消的圖案,因黏著劑存在而造成的壓力不會在捲取方向上集中於特定地方,因而黏著帶的切面漂亮,膠帶捲的外圍表面較平滑,不易發生捲繞崩潰。該等各情形,容在後述實施例中詳細說明。 Fig. 1 shows a schematic plan view of an embodiment of the adhesive tape of the present invention. In this embodiment, the non-adhesive part 1 and the adhesive part 2 intersect in diagonal stripes. Mutual formation. Therefore, there is a gripping area on part of the cut end surface and the side surface of the adhesive tape, so it can be easily peeled off from any part. Moreover, the pattern formed by the non-adhesive part 1 and the adhesive part 2 becomes a pattern in which all or part of the difference in tape thickness between the non-adhesive part and the adhesive part is offset when the adhesive tape is wound to form a tape roll. The pressure caused by the presence of the adhesive will not be concentrated in a specific place in the winding direction, so the cut surface of the adhesive tape is beautiful, the outer surface of the tape roll is smooth, and the winding collapse is not easy to occur. These various situations are described in detail in the following embodiments.

圖2所示係本發明的黏著帶一實施形態的示意平面圖。本實施形態中,非黏著劑部分1係平行於膠帶寬度方向設置。因此,在黏著帶的側面存在有抓持區,因而可輕易從側面剝離。又,若在非黏著劑部分1的地方切斷,則亦可從切斷端面輕易地剝離。且,由非黏著劑部分1與黏著劑部分2所構成的圖案,係形成在捲取黏著帶形成膠帶捲時,非黏著劑部分與黏著劑部分的膠帶厚度差之全部或其中一部分相抵消的圖案,因為在捲取方向上不會有捲繞壓集中之情形而呈分散狀態,因而黏著帶的切面漂亮,膠帶捲的外圍表面較平滑,不易發生捲繞崩潰。該等各情形,容在後述實施例中詳細說明。又,例如藉由調整非黏著劑部分1的寬度,使膠帶正交的對象物接觸到非黏著劑部分1,並使對象物周圍的構件接觸到黏著劑部分2,亦可使對象物在不會附著到黏著劑之狀態下固定。 Fig. 2 shows a schematic plan view of an embodiment of the adhesive tape of the present invention. In this embodiment, the non-adhesive part 1 is arranged parallel to the width direction of the tape. Therefore, there is a gripping area on the side of the adhesive tape, so it can be easily peeled off from the side. In addition, if it is cut at the non-adhesive part 1, it can be easily peeled from the cut end surface. And, the pattern formed by the non-adhesive part 1 and the adhesive part 2 is formed when the adhesive tape is wound to form a tape roll, and all or part of the difference in tape thickness between the non-adhesive part and the adhesive part is offset. The pattern is in a dispersed state because there is no winding pressure concentration in the winding direction, so the cut surface of the adhesive tape is beautiful, the outer surface of the tape roll is smooth, and the winding collapse is not easy to occur. These various situations are described in detail in the following embodiments. In addition, for example, by adjusting the width of the non-adhesive portion 1 so that the object perpendicular to the tape touches the non-adhesive portion 1, and the surrounding members of the object contact the adhesive portion 2, the object can also be placed in the non-adhesive portion 2. It will be fixed in a state of being attached to the adhesive.

圖3所示係本發明的黏著帶一實施形態的示意平面圖。本實施形態中,沿黏著帶的長度方向在二側端部設置非黏著劑部分1。因此,在黏著帶切斷端面二側端部及側面存在有抓持區,因而不管從何處均可輕易剝離。又,例如當為將對象物簡易固定等而設置時,便可抓住二側端部的非黏著劑部分1而簡單設置。 Fig. 3 shows a schematic plan view of an embodiment of the adhesive tape of the present invention. In this embodiment, the non-adhesive part 1 is provided at both side ends along the length direction of the adhesive tape. Therefore, there are gripping areas on both ends and side surfaces of the cut end surface of the adhesive tape, so it can be easily peeled from anywhere. Moreover, for example, when it is installed for easy fixation of an object, etc., the non-adhesive part 1 of both ends can be grasped, and it can install easily.

圖4所示係本發明的黏著帶一實施形態的示意平面圖。本實施形態中,沿黏著帶的長度方向在中央處設置非黏著劑部分1。因此,在黏著帶切斷端面中央處存在有抓持區,因而可輕易從切斷端面剝離。又,例如使用於例如瓦楞紙箱等捆包箱的密封時,在紙箱開封時若利用切割刀切斷中央處的非黏著劑部分1,則黏著劑不會附著於切割刀上。又,即便利用瓦楞紙箱進行的捆包地方有出現間隙,但內容物仍不會有黏著劑附著。 Fig. 4 shows a schematic plan view of an embodiment of the adhesive tape of the present invention. In this embodiment, the non-adhesive part 1 is provided at the center along the length direction of the adhesive tape. Therefore, there is a grip area at the center of the cut end surface of the adhesive tape, so that it can be easily peeled from the cut end surface. In addition, for example, when used for sealing packing boxes such as corrugated cardboard boxes, if the non-adhesive part 1 at the center is cut by a cutting knife when the carton is opened, the adhesive will not adhere to the cutting knife. In addition, even if there is a gap in the packing place using a corrugated cardboard box, the contents still do not adhere to the adhesive.

以上所說明圖1至4的實施形態中,就從不管縱橫均可輕易剝離等觀點,最好係圖1所示實施形態。惟,本發明的非黏著劑部分1與黏著劑部分2之圖案,並不僅侷限於圖1至4所示實施形態。亦可為例如點陣狀、格子狀、無規狀、經賦予式樣性花紋等其他各種圖案。 In the above-described embodiment of FIGS. 1 to 4, it is preferable to adopt the embodiment shown in FIG. 1 from the viewpoint of easy peeling regardless of the vertical and horizontal directions. However, the patterns of the non-adhesive part 1 and the adhesive part 2 of the present invention are not limited to the embodiments shown in FIGS. 1 to 4. Various other patterns, such as a dot matrix, a grid, a random pattern, and a pattern-given pattern, may be used, for example.

本發明中,黏著劑層的厚度係0.03~0.6mm、較佳係0.04~0.4mm、更佳係0.05~0.4mm、特佳係0.06~0.25mm。如本發明般地加厚黏著劑層,特別就提升針對道路等粗面的黏著力、耐水性、耐寒性等特性觀點,係屬較佳。又,如本發明般加厚黏著劑層,就防止非黏著劑部分1因加壓等外力而造成崩潰情形、以及維持良好剝離作業性的觀點,係屬較佳,又,當有欲使受黏物不要接觸到黏著劑的地方時,就從可確實使之不會接觸的觀點,亦屬較佳。此種厚黏著層係較難利用溶劑系黏著劑組成物形成。 In the present invention, the thickness of the adhesive layer is 0.03 to 0.6 mm, preferably 0.04 to 0.4 mm, more preferably 0.05 to 0.4 mm, particularly preferably 0.06 to 0.25 mm. Thickening the adhesive layer as in the present invention is particularly preferable from the viewpoint of improving the adhesion, water resistance, and cold resistance to rough surfaces such as roads. In addition, thickening the adhesive layer as in the present invention is preferable to prevent the non-adhesive part 1 from collapsing due to external forces such as pressure, and to maintain good peeling workability. When the sticky substance does not come into contact with the adhesive, it is also preferable from the point of view that it can be made sure that it will not touch. Such a thick adhesive layer is difficult to form with a solvent-based adhesive composition.

黏著劑層係由固態黏著劑組成物構成的層。所謂「固態黏著劑組成物」係指實質未含溶劑的黏著劑組成物,所謂「非溶劑系黏著劑組成物」,稱「固態黏著劑組成物」時亦涵蓋熱熔膠黏著劑。固態黏著劑組成物較佳係含有橡膠系黏著劑,特別較佳係含 有例如:天然橡膠、苯乙烯丁二烯橡膠、苯乙烯系嵌段共聚合體等熱可塑性橡膠;合成異戊二烯橡膠、丁基橡膠、聚異丁烯橡膠、丙烯酸橡膠、丁腈橡膠、該等再生橡膠等橡膠成分。又,固態黏著劑組成物較佳係含有例如:碳酸鈣、氧化鋅、氧化鈦等無機填料。無機填料的含有量相對於橡膠成分100質量份,較佳係30~200質量份。又,視需要亦可含有例如:賦黏劑、加工處理油、抗老化劑、紫外線安定劑、硫化劑、著色化劑等公知添加劑。 The adhesive layer is a layer composed of a solid adhesive composition. The so-called "solid adhesive composition" refers to an adhesive composition that does not substantially contain solvent. The so-called "non-solvent adhesive composition" when referred to as "solid adhesive composition" also covers hot melt adhesives. The solid adhesive composition preferably contains a rubber-based adhesive, and particularly preferably contains Examples include: natural rubber, styrene butadiene rubber, styrene block copolymers and other thermoplastic rubbers; synthetic isoprene rubber, butyl rubber, polyisobutylene rubber, acrylic rubber, nitrile rubber, and other recycled materials Rubber components such as rubber. In addition, the solid adhesive composition preferably contains, for example, inorganic fillers such as calcium carbonate, zinc oxide, and titanium oxide. The content of the inorganic filler is preferably 30 to 200 parts by mass relative to 100 parts by mass of the rubber component. In addition, if necessary, known additives such as tackifiers, processing oils, anti-aging agents, ultraviolet stabilizers, vulcanizing agents, and coloring agents may also be contained.

本發明的黏著帶係在基材之至少單面上,設有以上所說明的黏著劑層。基材的種類並無特別的限定。例如:由縲縈、綿、聚酯單獨或混紡形成的紡紗;由聚酯、丙烯酸等長纖維、聚乙烯扁平絲紗等進行織造的織布或編織布;以及聚丙烯、聚乙烯等樹脂薄膜等等。其中,較佳係織布或編織布。基材的厚度較佳係0.05~0.3mm、更佳係0.1~0.2mm。 The adhesive tape of the present invention is attached to at least one side of the substrate, and is provided with the adhesive layer described above. The type of substrate is not particularly limited. For example: spun yarns made of rayon, cotton, polyester alone or blended; woven or woven fabrics woven from polyester, acrylic and other long fibers, polyethylene flat yarns, etc.; and polypropylene, polyethylene and other resins Film and so on. Among them, woven cloth or woven cloth is preferred. The thickness of the substrate is preferably 0.05 to 0.3 mm, more preferably 0.1 to 0.2 mm.

本發明的黏著帶係藉由使用例如軋延輥、熱熔膠塗佈機等塗佈裝置,在基材上依所需圖案塗佈固態黏著劑組成物便可獲得。 The adhesive tape of the present invention can be obtained by coating a solid adhesive composition on a substrate according to a desired pattern by using a coating device such as a calender roll, a hot melt adhesive coater, and the like.

本發明的黏著帶可毫無限制地利用於各種用途,特別係因為剝離作業性優異、且粗面接著性、耐水性、耐寒性等諸項特性亦優異,因而就使用後需剝離的用途(例如:道路、牆壁等粗面塗裝用遮蔽膠帶等等用途)便非常有用。又,亦能有效適用於例如高處、鷹架、寒冷地、水濕潤地方等處的各種工程用暫時固定、臨時固定用膠帶。又,活用黏著劑層有部分性存在非黏著劑部分1的特徵構造,亦可利用於例如:簡易把手、提帶、書本的書背紙、電線暫時固定、裝飾鏈等用途。 The adhesive tape of the present invention can be used for various purposes without limitation, especially because it has excellent peeling workability, and has excellent properties such as rough surface adhesion, water resistance, cold resistance, etc., it is used for applications that need to be peeled off after use ( For example: masking tape for rough coating of roads, walls, etc.) is very useful. In addition, it can also be effectively applied to various construction tapes for temporary fixation and temporary fixation in places such as high places, scaffolds, cold places, and wet places. In addition, the utilizable adhesive layer has a characteristic structure in which the non-adhesive part 1 is partially present, and it can also be used for purposes such as simple handles, carrying straps, book back papers for books, temporary fixing of electric wires, and decorative chains.

[實施例] [Example]

以下,利用實施例針對本發明進行更詳細說明。惟,本發明並不僅侷限於該等實施例。以下敘述中,「份」係指「質量份」。 Hereinafter, the present invention will be described in more detail using examples. However, the present invention is not limited to these embodiments. In the following description, "parts" means "parts by mass".

<黏著劑之評價試驗> <Evaluation Test of Adhesive>

製作以下參考例1~7及比較參考例1~3的黏著帶,並利用以下各方法評價黏著劑。結果如表1與2所示。 The adhesive tapes of the following reference examples 1 to 7 and comparative reference examples 1 to 3 were produced, and the adhesives were evaluated by the following methods. The results are shown in Tables 1 and 2.

[參考例1] [Reference example 1]

在短纖織布(Staple Fiber)的單面(黏著劑層形成面的相對側之面)積層聚乙烯層,更在聚乙烯層上塗佈長鏈烷基系離型材,而獲得厚度0.15mm的基材。另一方面,將天然橡膠100份、碳酸鈣150份、賦黏樹脂(日本ZEON公司製、QUINTONE(註冊商標)R100)100份及加工處理油30份,利用加壓捏和機施行混練而獲得固態黏著劑組成物。將該固態黏著劑組成物利用軋延輥塗佈於基材單面全體,而形成厚度0.04mm的黏著劑層便獲得黏著帶。 Laminate a polyethylene layer on one side of the Staple Fiber (the side opposite to the side where the adhesive layer is formed), and coat the polyethylene layer with a long-chain alkyl-based release profile to obtain a thickness of 0.15mm The substrate. On the other hand, 100 parts of natural rubber, 150 parts of calcium carbonate, 100 parts of tackifying resin (manufactured by ZEON, QUINTONE (registered trademark) R100), and 30 parts of processing oil are kneaded using a pressure kneader. Solid adhesive composition. The solid adhesive composition was coated on the entire single side of the substrate using a rolling roll to form an adhesive layer with a thickness of 0.04 mm to obtain an adhesive tape.

[參考例2] [Reference example 2]

除將黏著劑層的厚度變更為0.06mm之外,其餘均與參考例1同樣地製作黏著帶。 Except that the thickness of the adhesive layer was changed to 0.06 mm, the adhesive tape was produced in the same manner as in Reference Example 1.

[參考例3] [Reference example 3]

除將黏著劑層的厚度變更為0.11mm之外,其餘均與參考例1 同樣地製作黏著帶。 Except that the thickness of the adhesive layer is changed to 0.11mm, the rest are the same as those in Reference Example 1. Make the adhesive tape in the same way.

[參考例4] [Reference example 4]

在短纖織布的單面(黏著劑層形成面的相對側之面)積層聚乙烯層,更在聚乙烯層上塗佈長鏈烷基系離型材,而獲得厚度0.21mm的基材。另一方面,將天然橡膠100份、碳酸鈣120份、賦黏樹脂(日本ZEON公司製、QUINTONE(註冊商標)G115)85份及加工處理油20份,利用加壓捏和機施行混練而獲得固態黏著劑組成物。將該固態黏著劑組成物利用軋延輥塗佈於基材單面全體,而形成厚度0.07mm的黏著劑層便獲得黏著帶。 A polyethylene layer was laminated on one side of the staple fiber woven fabric (the side opposite to the side where the adhesive layer was formed), and a long-chain alkyl-based release profile was coated on the polyethylene layer to obtain a substrate with a thickness of 0.21 mm. On the other hand, 100 parts of natural rubber, 120 parts of calcium carbonate, 85 parts of tackifying resin (manufactured by ZEON Japan, QUINTONE (registered trademark) G115), and 20 parts of processing oil are kneaded with a pressure kneader. Solid adhesive composition. The solid adhesive composition was coated on the entire single side of the substrate with a rolling roll to form an adhesive layer with a thickness of 0.07 mm to obtain an adhesive tape.

[參考例5] [Reference example 5]

除將黏著劑層的厚度變更為0.11mm之外,其餘均與參考例4同樣地製作黏著帶。 Except that the thickness of the adhesive layer was changed to 0.11 mm, the adhesive tape was produced in the same manner as in Reference Example 4.

[參考例6] [Reference example 6]

除將黏著劑層的厚度變更為0.15mm之外,其餘均與參考例4同樣地製作黏著帶。 Except that the thickness of the adhesive layer was changed to 0.15 mm, the adhesive tape was produced in the same manner as in Reference Example 4.

[參考例7] [Reference example 7]

除將黏著劑層的厚度變更為0.23mm之外,其餘均與參考例4同樣地製作黏著帶。 Except that the thickness of the adhesive layer was changed to 0.23 mm, the adhesive tape was produced in the same manner as in Reference Example 4.

[比較參考例1] [Comparative Reference Example 1]

在聚乙烯織布的雙面上積層聚乙烯層,更在單邊的聚乙烯層(形成黏著劑層之一面的相對側之聚乙烯層)上塗佈長鏈烷基系離型材,獲得厚度0.125mm的基材。另一方面,將丙烯酸丁酯20份、丙烯酸-2-乙基己酯77份及丙烯酸3份溶解於溶劑中,使用作為起始劑之2,2'-偶氮雙(異丁腈)進行聚合,便獲得固形份50%的基質聚合物。在該基質聚合物100份中添加異氰酸酯系硬化劑(綜研化學股份有限公司製、商品名L-45)1份並攪拌,便獲得溶劑系黏著劑組成物。將該溶劑系黏著劑組成物利用輥塗機塗佈於基材單面全體,經乾燥,形成厚度0.02mm的黏著劑層,便獲得黏著帶。 Laminate a polyethylene layer on both sides of the polyethylene woven fabric, and coat the long-chain alkyl-based release profile on the polyethylene layer on one side (the polyethylene layer on the opposite side of the side forming the adhesive layer) to obtain a thickness 0.125mm substrate. On the other hand, 20 parts of butyl acrylate, 77 parts of 2-ethylhexyl acrylate, and 3 parts of acrylic acid were dissolved in a solvent, and 2,2'-azobis(isobutyronitrile) was used as a starting agent. After polymerization, a matrix polymer with a solid content of 50% is obtained. One part of an isocyanate-based hardener (manufactured by Soken Chemical Co., Ltd., trade name L-45) was added to 100 parts of the matrix polymer and stirred to obtain a solvent-based adhesive composition. The solvent-based adhesive composition was coated on the entire single side of the substrate with a roll coater, and dried to form an adhesive layer with a thickness of 0.02 mm, thereby obtaining an adhesive tape.

[比較參考例2] [Comparative Reference Example 2]

除將丙烯酸-2-乙基己酯的量變更為79份,並將丙烯酸的量變更為1份之外,其餘均與比較參考例1同樣地製作黏著帶。 Except that the amount of 2-ethylhexyl acrylate was changed to 79 parts, and the amount of acrylic acid was changed to 1 part, the adhesive tape was produced in the same manner as in Comparative Reference Example 1.

[比較參考例3] [Comparative Reference Example 3]

在比較參考例2中,欲將黏著劑層的厚度變更為0.11mm,但因黏著劑組成物出現發泡,導致無法製作適當的黏著帶。 In Comparative Reference Example 2, it was attempted to change the thickness of the adhesive layer to 0.11 mm, but foaming of the adhesive composition made it impossible to produce an appropriate adhesive tape.

[黏著力] [Adhesion]

根據JIS Z 0237(2000),測定寬25mm黏著帶對SUS板的黏著力。 According to JIS Z 0237 (2000), the adhesive force of the adhesive tape with a width of 25 mm to the SUS board was measured.

[對粗面的黏著力] [Adhesion to rough surface]

想像例如道路等粗面,製作將#400研磨紙固定於SUS板上的 試驗板。根據JIS Z 0237(2000),測定寬25mm黏著帶對試驗板研磨紙面的黏著力。 Imagine rough surfaces such as roads and make #400 abrasive paper fixed on a SUS plate Test board. According to JIS Z 0237 (2000), the adhesive force of the adhesive tape with a width of 25 mm to the ground paper surface of the test plate was measured.

[傾斜30°黏性] [Tilt 30° viscosity]

根據JIS Z 0237(2000),利用30°傾斜式滾球黏性試驗測定黏著帶的傾斜30°黏性。 According to JIS Z 0237 (2000), the 30° inclined tackiness of the adhesive tape was measured by the 30° inclined rolling ball tack test.

[環形初黏性] [Annular initial viscosity]

如圖5所示,將寬25mm黏著帶3的基材3a朝內側,並將黏著層3b朝外側,形成圓周100mm的環。利用測定器的夾具4抓持著二端部分,依300mm/分的速度下降至測定器的夾具邊緣、與SUS板5間成為20mm高度為止,然後測定依毫髮不差的相同速度上升至原本位置時的黏著力。該環形初黏性係假設未施加壓接力狀態下的黏著性試驗。 As shown in FIG. 5, the base material 3a of the adhesive tape 3 with a width of 25 mm faces the inside and the adhesive layer 3b faces the outside to form a ring with a circumference of 100 mm. The clamp 4 of the measuring instrument is used to grasp the two end parts, and it descends at a speed of 300mm/min until the edge of the clamp of the measuring instrument reaches a height of 20mm with the SUS plate 5, and then the measurement rises to the original position at the same speed with no difference. Time's adhesion. The initial adhesion of the ring is an adhesion test under the assumption that no crimping force is applied.

[對潤濕粗面的黏著力] [Adhesion to wet rough surface]

想像例如道路等粗面,準備將#280研磨紙固定於SUS板上(研磨面朝上)的試驗板。試驗片在水中浸漬3分鐘後取出,用手甩該試驗板而除去水滴後,根據JIS Z 0237(2000),測定寬25mm黏著帶對試驗板的黏著力。 Imagine a rough surface such as a road, and prepare a test board with #280 abrasive paper fixed to a SUS board (the abrasive surface is facing upward). The test piece was immersed in water for 3 minutes and then taken out. After shaking the test board by hand to remove water droplets, the adhesive force of the adhesive tape with a width of 25 mm to the test board was measured in accordance with JIS Z 0237 (2000).

[低溫環境下的定荷重剝離] [Constant load peeling under low temperature environment]

想像在寒冷地使用,於-20℃環境下施行定荷重剝離測定。使JIS Z 0237(2000)所規定的SUS板,依寬25mm×長50mm的面積接 著試驗膠帶,在膠帶的端部懸吊300g錘。測定1分鐘的剝落距離,或當在1分鐘內便全部剝離時便測定該時間。 Imagine using it in a cold place and performing a constant-load peel test at -20°C. Connect the SUS board specified in JIS Z 0237 (2000) in an area of 25mm in width x 50mm in length Wear the test tape, and hang a 300g hammer on the end of the tape. Measure the peeling distance for 1 minute, or measure the time when all peeling occurs within 1 minute.

[殘留溶劑] [remaining solvent]

黏著劑層中的殘留溶劑係使用島津製作所(股)製氣相色層分析儀,依頂部空間法(加熱條件:80℃、40分)測定揮發檢測到的殘留溶劑量。 The residual solvent in the adhesive layer was measured by a headspace method (heating conditions: 80°C, 40 minutes) using a gas chromatography analyzer manufactured by Shimadzu Corporation.

Figure 106105050-A0101-12-0011-1
Figure 106105050-A0101-12-0011-1

Figure 106105050-A0101-12-0011-2
Figure 106105050-A0101-12-0011-2

<黏著劑之評價結果> <Evaluation Results of Adhesives>

由表1所示之結果得知,參考例1~7之黏著帶由固態黏著劑組成物所構成的黏著劑層,幾乎所有項目均優異。例如因為通常對粗面及下雨後尚未充分乾燥之粗面的黏著力均優異,因而可理解為對通常的道路與潤濕之道路可獲得充分的固定力,且因為傾斜30°黏性與環形初黏性均優異,因而可理解為即便未施加壓接仍可獲得充分的固定力,又因為低溫環境下的定荷重剝離優異,因而可理解為即便冬季仍不易剝離,又因為殘留溶劑少,因而不易發生環境汚染。 From the results shown in Table 1, it can be seen that the adhesive layers of the adhesive tapes of Reference Examples 1-7 are excellent in almost all items. For example, because it usually has excellent adhesion to rough surfaces and rough surfaces that have not been sufficiently dried after rain, it can be understood that sufficient fixing power can be obtained for normal roads and wet roads, and because of the 30° inclination of viscosity and ring shape The initial tack is excellent, so it can be understood that a sufficient fixing force can be obtained even if the crimping is not applied, and because the constant load peeling is excellent in a low temperature environment, it can be understood that it is not easy to peel even in winter, and because there is little residual solvent, Therefore, environmental pollution is unlikely to occur.

另一方面,比較參考例1~2之黏著帶之由溶劑系黏著劑組成物所構成的黏著劑層,幾乎所有項目均遜於參考例1~7。例如黏著力、黏性、定荷重剝離較差的原因之一,可認為係黏著層厚度較參考例1~7薄。另一方面,比較參考例3雖嘗試將黏著劑層厚度設為與參考例3及5相同的0.11mm,但卻因為溶劑系黏著劑組成物出現發泡導致無法製作適當的黏著帶。當如此使用溶劑系黏著劑組成物時,頗難加厚黏著劑層的厚度。 On the other hand, the adhesive layer composed of the solvent-based adhesive composition of the adhesive tapes of Comparative Reference Examples 1 to 2 is inferior to Reference Examples 1 to 7 in almost all items. For example, one of the reasons for the poor adhesion, tackiness and constant-load peeling is that the thickness of the adhesive layer is thinner than that of Reference Examples 1-7. On the other hand, Comparative Reference Example 3 tried to set the thickness of the adhesive layer to 0.11 mm, which is the same as that of Reference Examples 3 and 5. However, the solvent-based adhesive composition was foamed and an appropriate adhesive tape could not be produced. When the solvent-based adhesive composition is used in this way, it is quite difficult to increase the thickness of the adhesive layer.

<剝離作業性的評價試驗> <Evaluation test of peeling workability>

製作以下實施例1~4及比較例1的黏著帶,並依照以下方法評價黏著帶的剝離作業性。結果如表3所示。 The adhesive tapes of the following Examples 1 to 4 and Comparative Example 1 were produced, and the peeling workability of the adhesive tape was evaluated according to the following method. The results are shown in Table 3.

[實施例1] [Example 1]

除利用軋延輥,在基材單面上形成如圖1所示,由非黏著劑部分1與黏著劑部分2呈斜條紋狀交互設置的黏著劑層之外,其餘均 與參考例2同樣地製作膠帶寬25mm的黏著帶。非黏著劑部分1與黏著劑部分2的條紋寬分別設為5mm。 Except for the use of a calender roll to form an adhesive layer on one side of the substrate as shown in Figure 1, the non-adhesive part 1 and the adhesive part 2 are alternately arranged in diagonal stripes, the rest are all In the same manner as in Reference Example 2, an adhesive tape with a tape width of 25 mm was produced. The stripe widths of the non-adhesive part 1 and the adhesive part 2 were each set to 5 mm.

[實施例2] [Example 2]

除利用軋延輥,在基材單面上形成如圖2所示,由非黏著劑部分1平行於膠帶寬度方向設置的黏著劑層之外,其餘均與參考例2同樣地製作膠帶寬25mm的黏著帶。非黏著劑部分1的長度設為5mm,黏著劑部分2的長度設為10mm。 Except for the use of a calender roll to form an adhesive layer on one side of the substrate as shown in Figure 2, the non-adhesive part 1 is parallel to the width of the tape, and the rest is the same as in Reference Example 2. The tape width is 25mm. Adhesive tape. The length of the non-adhesive part 1 is 5 mm, and the length of the adhesive part 2 is 10 mm.

[實施例3] [Example 3]

除利用軋延輥,在基材單面上形成如圖3所示,在二側端部設置非黏著劑部分1的黏著劑層之外,其餘均與參考例2同樣地製作膠帶寬25mm的黏著帶。非黏著劑部分1的寬度分別設為5mm。 Except that the adhesive layer of the non-adhesive part 1 is formed on the single side of the base material as shown in Fig. 3 by the use of a calender roll, the other parts are made in the same manner as in Reference Example 2 with a tape width of 25 mm. Adhesive tape. The width of the non-adhesive part 1 is set to 5 mm, respectively.

[實施例4] [Example 4]

除利用軋延輥,在基材單面上形成如圖4所示,在中央處設置非黏著劑部分1的黏著劑層之外,其餘均與參考例2同樣地製作膠帶寬25mm的黏著帶。非黏著劑部分1的寬度分別設為5mm。 Except that the adhesive layer of the non-adhesive part 1 is provided in the center on one side of the base material using a calender roll, an adhesive tape with a tape width of 25 mm is produced in the same manner as in Reference Example 2. . The width of the non-adhesive part 1 is set to 5 mm, respectively.

[比較例1] [Comparative Example 1]

依照與參考例2同樣地全面塗佈黏著劑,而製作寬25mm的黏著帶。 The adhesive was applied to the entire surface in the same manner as in Reference Example 2, and an adhesive tape with a width of 25 mm was produced.

在沒有凹凸的金屬面上貼附長度100mm的黏著帶,根據在戴上全棉工作手套狀態下剝離時的觸感,依照以下基準評 價。 Stick an adhesive tape with a length of 100mm on a metal surface without unevenness. According to the touch when peeling off with cotton work gloves, the following benchmarks are used to evaluate price.

[◎]:容易剝離。 [◎]: Easy to peel off.

[○]:略容易剝離。 [○]: Slightly easy to peel off.

[×]:不易剝離。 [×]: Not easy to peel off.

Figure 106105050-A0101-12-0014-3
Figure 106105050-A0101-12-0014-3

<剝離作業性之評價結果> <Evaluation result of peeling workability>

由表3所示結果得知,實施例1~4的黏著帶因為非黏著劑部分1成為抓持區,因而剝離作業性佳。具體而言,實施例1的黏著帶(圖1)不管在哪種場所切斷時,均可從抓持區輕易剝離。實施例2的黏著帶(圖2)係依非黏著面位於末端的方式切斷時,可輕易從抓持區剝離。實施例3的黏著帶(圖3)係不管在哪種場所切斷時,均可從抓持區輕易剝離。實施例4的黏著帶(圖4)因為抓持區位於中央處,因而相較於實施例1~3的黏著帶雖呈現稍微難剝離,但相較於比較例1的黏著帶卻顯得格外容易剝離。另一方面,因為比較例1的黏著帶並沒有抓持區,因而不易剝離。 From the results shown in Table 3, it is known that the adhesive tapes of Examples 1 to 4 have good peeling workability because the non-adhesive part 1 serves as the gripping area. Specifically, the adhesive tape of Example 1 (FIG. 1) can be easily peeled off from the gripping area no matter where it is cut. When the adhesive tape of Example 2 (Figure 2) is cut with the non-adhesive surface at the end, it can be easily peeled off from the gripping area. The adhesive tape of Example 3 (Figure 3) can be easily peeled off from the gripping area no matter where it is cut. The adhesive tape of Example 4 (Figure 4) is located at the center of the gripping area. Compared with the adhesive tapes of Examples 1 to 3, although the adhesive tape is slightly difficult to peel off, it is easier than the adhesive tape of Comparative Example 1. Peel off. On the other hand, because the adhesive tape of Comparative Example 1 has no gripping area, it is not easy to peel off.

另外,實施例1~4的黏著帶因為設有非黏著劑部分1,因而相較於參考例3之下,雖黏著力與黏性呈現若干降低,但即便如此卻具有遠較使用溶劑系黏著劑組成物的比較例1優異之黏著力、黏性。 In addition, since the adhesive tapes of Examples 1 to 4 are provided with the non-adhesive part 1, compared with Reference Example 3, although the adhesive force and tackiness are slightly lower, even so, they have far better adhesion than the solvent-based adhesive. Comparative Example 1 of the agent composition has excellent adhesion and tack.

<膠帶捲外觀與經時變化之評價試驗> <Evaluation test of tape roll appearance and changes over time>

針對實施例1~4的黏著帶之膠帶捲外觀與經時變化,依照以下方法施行評價。具體而言,將黏著帶依如圖6的上側所示捲取於紙管上而形成膠帶捲6(寬25mm、捲繞長度25m或300m)、目視觀察膠帶捲6的外圍表面、膠帶端部的切面,依照以下基準施行評價。又,將膠帶捲6的紙管懸吊於軸上,於40℃下放置1週,目視確認有無如圖6中的下側所示捲繞崩潰(碗狀變形)情形,依照以下基準評價。結果如表4所示。 Regarding the appearance and changes with time of the tape roll of the adhesive tapes of Examples 1 to 4, evaluation was performed according to the following methods. Specifically, the adhesive tape is wound on a paper tube as shown in the upper side of Figure 6 to form a tape roll 6 (width 25mm, winding length 25m or 300m), visually observe the outer surface of the tape roll 6 and the tape end The aspect of the evaluation is performed in accordance with the following benchmarks. In addition, the paper tube of the tape roll 6 was hung on the shaft and left at 40°C for 1 week, and visually confirmed whether the roll collapsed (bowl-shaped deformation) as shown on the lower side in Fig. 6 was evaluated according to the following criteria. The results are shown in Table 4.

[◎]:外圍表面及切面均沒有問題,且沒有發生捲繞崩潰。 [◎]: There is no problem with the outer surface and the cut surface, and no winding collapse occurs.

[○]:外圍表面及切面雖略有問題,但沒有發生捲繞崩潰。 [○]: Although there is a slight problem on the outer surface and the cut surface, no winding collapse occurred.

[△]:外圍表面及切面略有問題,且有發生捲繞崩潰。 [△]: There is a slight problem with the peripheral surface and the cut surface, and the winding collapse occurs.

[×]:外圍表面及切面出現大問題,且有發生捲繞崩潰。 [×]: There are major problems with the outer surface and the cut surface, and the winding collapse occurs.

Figure 106105050-A0101-12-0015-4
Figure 106105050-A0101-12-0015-4

<膠帶捲的耐捲繞崩潰評價結果> <Evaluation results of resistance to winding and collapse of tape rolls>

由表4所示結果得知,實施例1的黏著帶(圖1)及實施例2的黏著帶(圖2),係膠帶捲6的外圍表面及切面均無問題,且沒有發生捲繞崩潰。另一方面,實施例3的黏著帶(圖3)及實施例4的黏著帶(圖4),在膠帶捲6捲繞25m時,外圍表面及切面有略出現問題,在膠帶捲6捲繞300m時亦有發生捲繞崩潰。 According to the results shown in Table 4, the adhesive tape of Example 1 (Figure 1) and the adhesive tape of Example 2 (Figure 2) have no problems with the outer surface and cut surface of the tape roll 6, and no winding collapse occurs. . On the other hand, the adhesive tape of Example 3 (Figure 3) and the adhesive tape of Example 4 (Figure 4), when the tape roll 6 is wound for 25m, the outer surface and the cut surface are slightly problematic, and the tape roll 6 is wound Winding collapse also occurred at 300m.

具體而言,實施例3的黏著帶(圖3)及實施例4的黏著帶(圖4),因為在捲取方向上具有由非黏著劑部分1及黏著劑部分2於二端部或中央處呈連續的圖案,若將其捲取形成膠帶捲6,則因二部位1及2的膠帶厚度差相乘,導致在膠帶捲6的外圍表面出現凹凸。另一方面,實施例1的黏著帶(圖1)及實施例2的黏著帶(圖2),因為由非黏著劑部分1及黏著劑部分2所構成之圖案在捲取方向上並非連續,因而若將其捲取形成膠帶捲6,則二部位1及2的膠帶厚度差相抵消,使膠帶捲6的外圍表面呈平滑。 Specifically, the adhesive tape of Example 3 (Figure 3) and the adhesive tape of Example 4 (Figure 4) have a non-adhesive part 1 and an adhesive part 2 at both ends or the center in the winding direction. If it is wound to form a tape roll 6, the tape thickness difference of the two parts 1 and 2 is multiplied, resulting in unevenness on the outer surface of the tape roll 6. On the other hand, the adhesive tape of Example 1 (Figure 1) and the adhesive tape of Example 2 (Figure 2), because the pattern formed by the non-adhesive part 1 and the adhesive part 2 is not continuous in the winding direction, Therefore, if it is wound to form the tape roll 6, the difference in the thickness of the tape at the two locations 1 and 2 will cancel out, and the outer surface of the tape roll 6 will be smooth.

實施例3的黏著帶(圖3)及實施例4的黏著帶(圖4),因為具有在捲取方向上,非黏著劑部分1及黏著劑部分2於二端部或中央處呈連續的圖案,因而若將其捲取300m形成膠帶捲6,則因二部位1及2的膠帶厚度差所造成之黏著力差會產生較大的相乘效應,經在40℃下懸吊1週後便發生捲繞崩潰。另一方面,實施例1的黏著帶(圖1)及實施例2的黏著帶(圖2),因為由非黏著劑部分1及黏著劑部分2所構成圖案在捲取方向上並非連續,因而即便將其捲取300m形成膠帶捲6,二部位1及2的黏著力差異會相抵消,即便在40℃下懸吊1週仍不會發生捲繞崩潰。 The adhesive tape of Example 3 (Figure 3) and the adhesive tape of Example 4 (Figure 4) have the non-adhesive part 1 and the adhesive part 2 continuous at both ends or the center in the winding direction Therefore, if it is rolled 300m to form tape roll 6, the difference in adhesion caused by the difference in tape thickness between the two parts 1 and 2 will have a greater synergistic effect. After being hung at 40°C for 1 week Then the winding collapse occurs. On the other hand, the adhesive tape of Example 1 (Figure 1) and the adhesive tape of Example 2 (Figure 2), because the patterns formed by the non-adhesive part 1 and the adhesive part 2 are not continuous in the winding direction, so Even if it is wound up to 300m to form a tape roll 6, the difference in adhesion between the two parts 1 and 2 will cancel out, and the winding collapse will not occur even if it is suspended at 40°C for 1 week.

(產業上之可利用性) (Industrial availability)

本發明的黏著帶係可毫無限制地使用於各種用途,針對使用後需剝離的用途(例如:道路、牆壁等粗面塗裝用遮蔽膠帶等等用途)非常有用。又,針對各種工程用暫時固定、臨時固定用膠帶亦非常有用。又,亦頗適用於存在有不欲使受黏物接觸到黏著劑之處的情況。 The adhesive tape of the present invention can be used for various purposes without limitation, and is very useful for applications that need to be peeled off after use (for example, masking tape for rough coating of roads, walls, etc.). It is also very useful for temporary fixation and temporary fixation tapes for various constructions. In addition, it is also quite suitable for situations where there is a place where you do not want the adherend to come into contact with the adhesive.

1‧‧‧非黏著劑部分 1‧‧‧Non-adhesive part

2‧‧‧黏著劑部分 2‧‧‧Adhesive part

Claims (5)

一種黏著帶,係在基材之至少單面上,設有部分性存在非黏著劑部分的黏著劑層者,該基材為織布或編織布;其中,該黏著劑層係由包含橡膠系黏著劑之固態黏著劑組成物構成,相對於該橡膠系黏著劑之橡膠成分100質量份,該固態黏著劑組成物含有30~200質量份之無機填料,該黏著劑層的厚度係0.03~0.4mm。 An adhesive tape, which is attached to at least one side of a substrate and is provided with an adhesive layer partially presenting a non-adhesive part. The substrate is a woven or woven cloth; wherein, the adhesive layer is made of rubber The composition of the solid adhesive composition of the adhesive, relative to 100 parts by mass of the rubber component of the rubber-based adhesive, the solid adhesive composition contains 30 to 200 parts by mass of inorganic filler, and the thickness of the adhesive layer is 0.03 to 0.4 mm. 如請求項1之黏著帶,其中,橡膠系黏著劑含有天然橡膠作為橡膠成分。 Such as the adhesive tape of claim 1, wherein the rubber-based adhesive contains natural rubber as a rubber component. 如請求項1之黏著帶,其中,黏著劑層中由非黏著劑部分及黏著劑部分所構成的圖案,係當捲取黏著帶形成膠帶捲時,非黏著劑部分與黏著劑部分的膠帶厚度差之全部或其中一部分相抵消的圖案。 Such as the adhesive tape of claim 1, wherein the pattern formed by the non-adhesive part and the adhesive part in the adhesive layer is the tape thickness of the non-adhesive part and the adhesive part when the adhesive tape is wound to form a tape roll A pattern in which all or part of the difference cancels out. 如請求項3之黏著帶,其中,黏著劑部分與非黏著劑部分係呈斜條紋狀交互地形成。 Such as the adhesive tape of claim 3, wherein the adhesive part and the non-adhesive part are alternately formed in diagonal stripes. 一種黏著帶之製造方法,其係用來製造請求項1所記載之黏著帶的方法,上述方法藉由於基材上塗佈固態黏著劑組成物而形成黏著劑層。 A method for manufacturing an adhesive tape, which is used to manufacture the adhesive tape described in claim 1. The above method forms an adhesive layer by coating a solid adhesive composition on a substrate.
TW106105050A 2016-03-31 2017-02-16 Adhesive tape TWI734747B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2016073114A JP6203894B1 (en) 2016-03-31 2016-03-31 Adhesive tape and method for producing the same
JP2016-073114 2016-03-31

Publications (2)

Publication Number Publication Date
TW201736544A TW201736544A (en) 2017-10-16
TWI734747B true TWI734747B (en) 2021-08-01

Family

ID=59963820

Family Applications (1)

Application Number Title Priority Date Filing Date
TW106105050A TWI734747B (en) 2016-03-31 2017-02-16 Adhesive tape

Country Status (5)

Country Link
JP (1) JP6203894B1 (en)
KR (2) KR20180127164A (en)
CN (1) CN107278222B (en)
TW (1) TWI734747B (en)
WO (1) WO2017168812A1 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6431649B1 (en) * 2017-07-13 2018-11-28 株式会社寺岡製作所 Multilayer masking sheet
KR102193721B1 (en) * 2019-01-21 2020-12-21 주식회사 야스 Cover Film for protecting adhesive sheet using adhesive chuck
CN111500205A (en) * 2019-01-31 2020-08-07 钟友妹 Adhesive tape device easy to tear and preparation method thereof
KR20200107014A (en) 2019-03-05 2020-09-16 삼성디스플레이 주식회사 Display device
JP7086370B2 (en) * 2020-07-17 2022-06-20 株式会社コストジャパン Adhesive tape manufacturing method and adhesive tape

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002173649A (en) * 2000-12-04 2002-06-21 Asahi Rubber Kk Rolled adhesive tape
JP2005272763A (en) * 2004-03-26 2005-10-06 J-Film Corp Pressure sensitive adhesive sheet for pasting

Family Cites Families (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5669635U (en) * 1979-10-30 1981-06-09
JPS57150537U (en) * 1981-03-17 1982-09-21
JPS5961880A (en) 1982-09-30 1984-04-09 日本電気ホームエレクトロニクス株式会社 Field memory reading control circuit
JPS59176678A (en) 1983-03-28 1984-10-06 Toshiba Corp Inspecting device for rotation precision
JPS60122346U (en) * 1984-01-28 1985-08-17 大日本印刷株式会社 adhesive sheet
JPS62118142U (en) * 1986-01-20 1987-07-27
JPS6348381A (en) * 1986-08-14 1988-03-01 Nitto Electric Ind Co Ltd Self-adhesive tape
JPH0268290A (en) * 1988-09-03 1990-03-07 Yukimasa Hori Stay for sail mast
GB8912899D0 (en) 1989-06-05 1989-07-26 Frys Metals Ltd Casting apparatus
JPH0415318A (en) 1990-05-01 1992-01-20 Nissan Motor Co Ltd Flexible joint
EP0455895A3 (en) * 1990-05-11 1992-03-04 Facile Technologies Modified pressure sensitive tape
TW274665B (en) 1992-06-26 1996-04-21 Philips Electronics Nv
JPH07268290A (en) * 1994-03-30 1995-10-17 Natl House Ind Co Ltd Adhesive tape
JPH09104851A (en) * 1995-03-08 1997-04-22 Sekisui Chem Co Ltd Adhesive tape
JP3044590U (en) * 1997-06-19 1997-12-22 関 博文 Adhesive tape
JPH11106729A (en) * 1997-09-30 1999-04-20 Nichiban Co Ltd Hot-melt pressure-sensitive adhesive composition
CA2288817C (en) 1998-03-26 2005-07-26 Nihon Superior Sha Co., Ltd. Lead free solder alloy
JP2000309762A (en) 1999-04-26 2000-11-07 Oji Takku Kk Side-edge-uncoated pressure-sensitive adhesive tape
DE10129522A1 (en) 2001-06-21 2003-01-09 Basf Ag polymer mixture
JP2003049134A (en) * 2001-08-07 2003-02-21 Nitto Denko Hoso System Kk Adhesive tape
JP3085347U (en) * 2001-10-12 2002-04-26 清司 若山 Adhesive tape without glue
JP2003213227A (en) * 2002-01-18 2003-07-30 Nippon Rika Seishi Kk Adhesive tape used by re-moistening for easily openable packing
JP2003286568A (en) 2002-03-28 2003-10-10 Nitto Denko Corp Adhesive tape for masking
JP4276818B2 (en) * 2002-06-07 2009-06-10 株式会社共和 Bonding adhesive tape
JP4943646B2 (en) * 2004-11-19 2012-05-30 大倉工業株式会社 Adhesive sheet for moisture-permeable floor curing
JP2008106242A (en) * 2006-09-25 2008-05-08 Diatex Co Ltd Easy-to-peel adhesive tape and method for producing the same
JP2009046546A (en) * 2007-08-16 2009-03-05 Fusako Ito Easily releasable self-adhesive tape
JP5362302B2 (en) * 2007-09-26 2013-12-11 株式会社寺岡製作所 Cloth adhesive tape
WO2011004662A1 (en) * 2009-07-09 2011-01-13 株式会社ニトムズ Adhesive tape roll
CA2799406A1 (en) 2010-05-14 2011-11-17 Sonavation, Inc. Methods and systems for pointing device using acoustic impediography
JP5782772B2 (en) * 2011-03-25 2015-09-24 株式会社ジェイ・エム・エス Peeling facilitating sticking method and peeling facilitating label
JP6013794B2 (en) * 2012-06-18 2016-10-25 ニチバン株式会社 Self-adhesive adhesive tape for plant invitations
WO2014126158A1 (en) * 2013-02-14 2014-08-21 ニチバン株式会社 Self-adhesive binding tape
JP2014173038A (en) 2013-03-11 2014-09-22 Kamoi Kakoshi Kk Masking tape for multilayer coating and masker using the same
CN203333568U (en) * 2013-06-19 2013-12-11 罗强 Double-faced adhesive sticker
WO2015087405A1 (en) * 2013-12-11 2015-06-18 ニチバン株式会社 Self-adhesion-type adhesive tape
JP3205388U (en) * 2016-05-11 2016-07-21 株式会社寺岡製作所 Adhesive tape laminate

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002173649A (en) * 2000-12-04 2002-06-21 Asahi Rubber Kk Rolled adhesive tape
JP2005272763A (en) * 2004-03-26 2005-10-06 J-Film Corp Pressure sensitive adhesive sheet for pasting

Also Published As

Publication number Publication date
CN107278222A (en) 2017-10-20
JP2017179297A (en) 2017-10-05
KR20200062358A (en) 2020-06-03
JP6203894B1 (en) 2017-09-27
KR102436995B1 (en) 2022-08-26
WO2017168812A1 (en) 2017-10-05
KR20180127164A (en) 2018-11-28
CN107278222B (en) 2020-12-04
TW201736544A (en) 2017-10-16

Similar Documents

Publication Publication Date Title
TWI734747B (en) Adhesive tape
CA2916251C (en) Article comprising pressure-sensitive adhesive stripes
US20160137885A1 (en) Article comprising an adhesive layer comprising first and second pressure-sensitive adhesive stripes
AU2016216573A1 (en) Adhesive composition and masking article for producing precise paint lines
US20190002737A1 (en) Film backings for peel release mounting
TW202405111A (en) Adhesive article
RU2616855C1 (en) Sheet material for reforming sealed packaging
JP7066331B2 (en) Double-sided pressure-sensitive adhesive tape
JP6185790B2 (en) Adhesive composition, adhesive sheet and moisture permeable waterproof adhesive sheet
US20030077439A1 (en) Self-adhesive masking tape for vehicles and vehicle parts
US20190359861A1 (en) Film backings for stretch release mounting
KR102220785B1 (en) Pressure-sensitive adhesive layers with surface-enriched stripes and methods of making
JP4138717B2 (en) Waterproof construction method for a three-sided crossing structure with a waterproof and airtight adhesive sheet having spreadability
US10858209B2 (en) Adhesive tape and its use
US20060035075A1 (en) Hand-tearable adhesive masking tape for vehicles, with low shrinkback tendency
WO2018220555A1 (en) Adhesive seal
KR20130134389A (en) Method for coating the release agent on the surface of the adhesive tape, and the gravure roll used by this method
JP2006241769A (en) Waterproofing execution method by water-proof airtight adhesive sheet having ductility
JP7377534B2 (en) Adhesive tape for preventing three-sided adhesion of sealants