TWI719851B - Optical film and display device with touch panel - Google Patents

Abstract

The present invention provides an optical film that can suppress reflections or Newton's rings and suppress glare, and has low total haze and internal haze, and a touch panel with a touch panel that can sufficiently suppress the generation of watermark and glare Display device. The optical film of the present invention has the following constitution: an optical layer having an uneven shape on the surface is laminated on a translucent substrate, and is characterized in that the total haze value is 0% or more and 5% or less, and the internal haze value is 0% Above and less than 5%, set the penetration image clarity measured by an optical comb with a width of 0.125 mm to C (0.125), and set the penetration image measured by an optical comb with a width of 0.25 mm to be clear When the degree is set to C (0.25), the following equations (1) and (2) are satisfied. C（0.25）－C（0.125）≧2% (1) C(0.125)≦64% (2)

Description

Optical film and display device with touch panel

The invention relates to an optical film and a display device with a touch panel.

In liquid crystal display (LCD), cathode ray tube display device (CRT), plasma display (PDP), electroluminescence display (ELD), field emission display (FED) and other image display devices, the image display surface is usually To suppress the reflection of the observer and the observer's background, etc., an anti-glare film with irregularities on the surface or an anti-reflective film with an anti-reflective layer on the outermost surface is provided.

The anti-glare film scatters external light on the concave-convex surface of the anti-glare layer and suppresses the reflection of the observer and the background of the observer. The anti-glare film mainly includes a light-transmitting substrate and an anti-glare layer with uneven surface provided on the light-transmitting substrate.

The anti-glare layer usually contains a binder resin and fine particles that are present in the binder resin and used to form an uneven surface.

However, when such an anti-glare film is disposed on the surface of an image display device, the uneven surface of the anti-glare layer may cause image light to scatter, which may cause so-called glare. In response to this problem, the industry proposes to increase the internal haze of the anti-glare film to suppress glare (for example, refer to Patent Document 1).

In addition, in recent years, there has been continuous development of an ultra-high-definition image display device called 4K2K (3840 horizontal pixels × 2160 vertical pixels) with a horizontal pixel count of 3000 or more. In this ultra-high-definition image display device, as with the above-mentioned image display device, an anti-glare film is provided on the image display surface, but for ultra-high-definition image display devices, the requirements are higher than before Brightness or light transmittance. Here, if the total haze or internal haze of the anti-glare film is increased, it will cause a decrease in brightness or light transmittance. Therefore, for ultra-high-definition image display devices, it is impossible to use the method to increase the internal haze of the anti-glare film. Means as a means for suppressing glare as described above. In addition, if the internal haze of the anti-glare film is increased, the image light may diffuse in the anti-glare film, and part of the image light may become stray light. As a result, the contrast of the dark room may decrease and the image may be blurred. Therefore, at present, as a film incorporated into an ultra-high-definition image display device, a film that can suppress glare and has a low total haze and internal haze is desired.

In addition, in recent years, small mobile devices equipped with touch panels such as smart phones or tablet terminals have rapidly spread. In such small mobile devices, the image display device has a glare problem due to the ultra-high definition of the displayed image. It becomes more pronounced, but on the other hand, higher brightness or light transmittance is required than before.

Previously, there are known display devices with touch panels that are equipped with touch panels on display panels such as liquid crystal displays. In the above-mentioned small mobile devices, a large number of image display devices equipped with touch panels are also used The display device with touch panel. For such a display device with a touch panel, information can be directly input by touching the image display surface with a finger or the like.

When fixing the touch panel on the display panel, in most cases, the display panel and the touch panel are separated from each other. That is, in many cases, the display panel and the touch panel are arranged with an air layer (air gap) interposed therebetween (for example, refer to Patent Document 2).

The image display surface of a display device with a touch panel is not only touched with fingers, but also pressed strongly with fingers. When the image display surface is strongly pressed, there is a problem that the distance between the touch panel and the display panel becomes narrow (the thickness of the air layer becomes thinner) due to the deformation of the touch panel. The light reflected on the surface of the display panel interferes with the light reflected on the surface of the touch panel of the display panel, resulting in Newton's rings, which reduces the visibility of the screen.

In addition, in recent years, the thinning and larger area of display devices with touch panels have been continuously promoted. As the display device with touch panel becomes thinner, the distance between the touch panel and the display panel becomes narrower, and as the display device with touch panel becomes larger, the touch panel becomes It is easy to deform. Therefore, the problem of Newton's ring becomes more significant. Furthermore, the Newton ring generated with the deformation of the touch panel is also specifically referred to as a watermark in the following.

For this kind of watermark problem, for example, Patent Document 3 proposes to fill the gap between the touch panel and the liquid crystal display panel with a resin material and set it as a resin layer, thereby eliminating the reflection at the interface between the touch panel and the liquid crystal display panel. However, when the final product is filled with a resin material, even if a defect is found in the touch panel after the final product is manufactured, it is impossible to replace only the touch panel. In addition, it is difficult to completely fill the gap between the touch panel and the liquid crystal display panel with the resin material, and if it becomes a state containing bubbles, it will become a cause of display image defects.

Here, for a display device in which the display panel and the touch panel are separated from each other, there is known a method of providing a concave-convex surface on the surface of the display panel to diffuse incident light on the concave-convex surface to suppress the generation of Newton's rings (for example, Refer to Patent Document 4). However, in such a display device with a touch panel in which a concave-convex surface is provided on the surface of the display panel, the concave-convex surface may cause image light scattering, which may cause so-called glare.

For this kind of glare problem, similar to the above-mentioned film incorporated into the ultra-high-definition image display device, it is impossible to adopt a method to increase the internal haze of the display panel. In addition, for this kind of glare problem, for example, the following direction has been studied until now: the method of setting the unevenness interval (Sm) of the uneven surface to be less than half of the pixel size, etc., reduces the unevenness interval. However, for ultra-high-definition image display devices, there are cases in which glare cannot be sufficiently suppressed by the conventional method of reducing the interval between unevenness.

[Patent Document 1] JP 2010-102186 A [Patent Document 2] JP 2010-15412 A [Patent Document 3] JP 2004-077887 A [Patent Document 4] JP 2002-189565 A

In view of the foregoing situation, the present invention aims to provide an optical film that can suppress reflections or Newton's rings and glare, and has low total haze and internal haze, and a touch panel with sufficient suppression of watermarks and glare The display device.

The present invention is an optical film, which has the following structure: an optical layer having a concave-convex shape on the surface is laminated on a translucent substrate, and is characterized in that the total haze value is 0% or more and 5% or less, and the internal haze value If the value is 0% or more and 5% or less, set the penetration image clarity measured with a comb with a width of 0.125 mm to C (0.125), and set the penetration image clarity measured with a comb with a width of 0.25 mm When it is set to C (0.25), the following equations (1) and (2) are satisfied. C（0.25）－C（0.125）≧2% (1) C(0.125)≦64% (2)

In addition, another aspect of the present invention is an optical film having a structure in which an optical layer having an uneven surface is laminated on a translucent substrate, and is characterized in that the surface of the optical film is half of the surface height distribution The value width is 200 nm or more, and the average curvature of the surface unevenness is 0.30 mm ^-1 or less.

In the optical film of the present invention, it is preferable that the total haze value of the optical film is 0% or more and 5% or less, and the internal haze value of the optical film is 0% or more and 5% or less. Furthermore, in the optical film of the present invention, it is preferable that the total haze value of the optical film is 0% or more and 1% or less, and the internal haze value of the optical film is substantially 0%. Furthermore, in the optical film of the present invention, it is preferable that the optical layer contains a binder resin and fine particles. Furthermore, it is preferable that the above-mentioned fine particles are inorganic oxide fine particles. It is preferable that the average primary particle diameter of the inorganic oxide microparticles is 1 nm or more and 100 nm or less, and it is also preferable that the inorganic oxide microparticles are inorganic oxide microparticles whose surfaces have been hydrophobized.

In addition, the present invention is a display device with a touch panel, which has a configuration in which the optical film of the present invention and the touch panel are arranged oppositely, and the optical film of the present invention and the above-mentioned touch panel are mutually provided The state of the gap is arranged so that the optical layer of the optical film opposes the touch panel. Hereinafter, the present invention will be described in detail. In addition, in this specification, the so-called "resin" is a concept that also includes monomers, oligomers, etc., as long as it is not specifically mentioned. In addition, in the following, the matters common to the optical film of the present invention and the optical film of another aspect of the present invention will be described only as the optical film of the present invention.

The inventors of the present invention conducted diligent studies and found that by setting the surface of the optical film into a specific concave-convex shape, the generation of glare can be highly suppressed regardless of the internal haze of the optical film, and further, by combining the optical film with The configuration of the touch panel facing the configuration, even if a gap is provided between the optical film and the touch panel, the generation of watermark can be suppressed to a high degree, and a good display image can be obtained, thereby completing the present invention. Furthermore, since the optical film of the present invention can also suppress the generation of Newton's rings such as watermarks to a high degree, it can also be used as an optical layer disposed opposite to the touch panel.

Fig. 1 is a cross-sectional view schematically showing the optical film of the present invention. In the optical film 11 of this invention, it has the structure which laminated|stacked the translucent base material 12 and the optical layer 13 which has a concave-convex shape on the surface.

The total haze value of the optical film 11 of the present invention is 0% or more and 5% or less, and the internal haze value is 0% or more and 5% or less. The total haze value and the internal haze value are measured as the entire optical film. Furthermore, the above-mentioned total haze value and internal haze value can be measured by a haze meter (HM-150, manufactured by Murakami Color Research Institute) by a method based on JIS K7136. Specifically, a haze meter is used to measure the total haze value of the optical film in accordance with JIS K7136. Thereafter, a triacetyl cellulose substrate (manufactured by Fuji Film Co., TD60UL) was attached to the surface of the optical film via a transparent optical adhesive layer. Thereby, the uneven shape of the surface of the optical film is flattened, and the surface of the optical film becomes flat. Then, in this state, using a haze meter (HM-150, manufactured by Murakami Color Research Institute), the haze value was measured in accordance with JIS K7136, thereby obtaining the internal haze value. The internal haze does not consider the unevenness of the surface of the optical film.

The total haze value of the optical film 11 of the present invention is preferably 1% or less, more preferably 0.3% or more and 0.5% or less. The internal haze value is preferably substantially 0%. Here, the so-called "internal haze value is substantially 0%" means the following meaning: it is not limited to the case where the internal haze value is completely 0%, and includes even when the internal haze value exceeds 0%. Within the range of measurement error and the internal haze value can be roughly regarded as the range of 0% (for example, the internal haze value below 0.3%).

When the total haze value of the optical film 11 is 0% or more and 5% or less, and the internal haze value is 0% or more and 5% or less, the surface haze value of the optical film 11 is 0% or more and 5% or less . The surface haze value of the optical film 11 is preferably 0% or more and 1% or less, more preferably 0% or more and 0.3% or less. The surface haze value is caused only by the unevenness of the surface of the optical film 11. By subtracting the internal haze value from the total haze value, the surface haze caused only by the unevenness of the surface of the optical film 11 can be obtained. Degree value.

In the optical film 11 of the present invention, when the penetration image clarity of the optical film 11 measured using a light comb with a width of 0.125 mm is set to C (0.125), the optical film measured with a light comb with a width of 0.25 mm is set to C (0.125). When the clarity of the penetration image of the film 11 is set to C (0.25), the following equations (1) and (2) are satisfied. C（0.25）－C（0.125）≧2% (1) C(0.125)≦64% (2)

Furthermore, the above-mentioned so-called "transmission image clarity" can be measured by a penetration image clarity measuring device based on the penetration method of image clarity of JIS K7374. As such a measuring device, for example, the image clarity measuring device ICM-1T manufactured by SUGA Test Instruments, etc. can be cited. In addition, as shown in FIG. 2, the transmission image clarity measuring device 100 includes a light source 101, a slit 102, a lens 103, a lens 104, an optical comb 105, and a light receiver 106. The lens 103 causes the light source 101 to emit light. And the light passing through the slit 102 becomes parallel light, the parallel light is irradiated to the translucent substrate 12 side of the optical film 11, and the light transmitted from the concave-convex shape 14 of the optical layer 13 of the optical film 11 by the lens 104 Those who gather and receive the light passing through the optical comb 105 by the light receiver 106, based on the amount of light received by the light receiver 106, calculate the transmission image definition C according to the following formula (3). C(n)={(M－m)/(M＋m)}×100(%) (3) Furthermore, in formula (3), C(n) is the clearness (%) of the penetrating image when the width of the optical comb is n (mm), and M is the highest light intensity when the width of the optical comb is n (mm), m It is the minimum amount of light when the width of the comb is n (mm). The optical comb 105 can move along the length of the optical comb 105 and has a light-shielding part and a penetrating part. The width ratio of the light-shielding part and the penetrating part of the optical comb 105 becomes 1:1. Here, in JIS K7374, as the optical comb, five types of optical combs with widths of 0.125 mm, 0.25 mm, 0.5 mm, 1.0 mm, and 2.0 mm are specified.

In the present invention, the optical film must satisfy the above formula (1) and formula (2). The reason is as follows. That is, first, in the optical film, in order to obtain anti-reflective properties or anti-watermarking properties of Newton's rings, a concave-convex shape is formed on the surface of the optical layer. After research, the inventors found that by satisfying the above formula (2) The necessary condition, that is, setting the value of C (0.125) to 64% or less can effectively prevent reflection or watermarking. Furthermore, the anti-reflective property in the present invention refers to those who do not mind the degree of reflection of the observer (observer) and the observer’s background, for example, it means the following: although the observer is found, the outline is not A clear and fuzzy state, and although objects in the background of the observer are also found, their outlines or boundaries become unclear. In this way, only when the outline of the observer is blurred, it becomes a state where the observer does not mind being reflected. On the other hand, there are cases where the concave portion or convex portion of the concave-convex shape condenses and diffuses light to act like a lens (lens effect). It is also believed that if such a lens effect occurs, the transmitted light from the "black matrix that separates the pixels of the liquid crystal display" or "pixels" is randomly enhanced, thereby generating glare. Therefore, the inventors of the present invention conducted further studies, and as a result, it was found that the diffusion of light caused by the uneven shape formed on the surface of the optical layer of the optical film is made to diffuse at a smaller angle, specifically, by Satisfying the requirements of the above formula (1), that is, setting the value of C (0.25)-C (0.125) to 2% or more, can suppress the generation of glare. The reason for this is considered as follows. That is, the clearer the through image is, the smaller the comb is, the more it is affected by the diffusion of the tiny angle and the value decreases. Therefore, it can be said that the smaller the value when using a smaller comb and the larger the value when using a larger comb, the less the wide-angle spread. Therefore, it is believed that by making the second largest comb, that is, C(0.25) more than 2% larger than the value of C(0.125), the diffusion at a small angle can be achieved. Furthermore, it is believed that by setting the diffusion at a small angle, The lens effect becomes extremely small, so it can be extremely effective in preventing glare. In terms of the above, it is considered that the optical film must satisfy the above-mentioned formulas (1) and (2). Furthermore, usually practitioners predict that from the viewpoint of suppressing glare, the difference between the value of C (0.25) and the value of C (0.125) is appropriate. If the difference is large, the glare will be worse. This situation can also be confirmed by, for example, Japanese Patent Laid-Open No. 2010-269504. In the publication, it is stated that from the viewpoint of suppressing glare, the ratio of the penetration image definition using a 0.125 mm optical comb to the penetration image definition using a 2.0 mm optical comb is set to 0.70 or more , And the ratio is preferably set to 0.80 or more and 0.93 or less. That is, in the publication, although the 0.25 mm optical comb is not used, it is described that the ratio is 0.80 or higher compared to 0.70 or higher. Therefore, the following direction is pointed out: the penetration of the 0.125 mm optical comb It is advisable that the difference between the image definition and the through image definition of a 2.0 mm comb is smaller. In contrast to this, contrary to this prediction, in the present invention, in order to suppress glare, the difference between the value of C (0.25) and the value of C (0.125) is set to 2% or more. Therefore, the optical film satisfying the above formula (1) and formula (2) can be said to be beyond the predictable range according to the technical level of the previously known optical film. Furthermore, in the specification of the present case, when it is referred to as an optical laminate, it also means an optical film.

FIG. 3 is a cross-sectional view schematically showing a display device with a touch panel using the optical film 11 of the present invention. As shown in FIG. 3, the display device 30 with a touch panel of the present invention has an optical film 31 and a touch panel 35 opposed to each other. The optical film 31 is laminated on one surface of a light-transmitting substrate 32 with uneven surfaces. Optical layer 33 of shape 34. In the display device 30 with a touch panel of the present invention, the optical film 31 and the touch panel 35 are arranged opposite to each other such that the optical layer 33 (concave and convex shape 34) faces the touch panel 35 in a state where there is a gap between each other. Here, as the touch panel 35, a resistive film type touch panel, an electrostatic capacitive type touch panel, etc. can be cited. In the display device 30 with a touch panel of the present invention, any method can be used, of which the preferred It is an electrostatic capacitive touch panel.

In the display device 30 with a touch panel of the present invention, the total haze value of the optical film 31 is 0% or more and 5% or less, and the internal haze value is 0% or more and 5% or less. The total haze value and the internal haze value are measured as the entire optical film.

In the display device with a touch panel of the present invention, the total haze value of the optical film 31 is preferably 1% or less, more preferably 0.3% or more and 0.5% or less. The internal haze value is preferably substantially 0%. Here, the so-called "internal haze value is substantially 0%" means the following meaning: it is not limited to the case where the internal haze value is completely 0%, and includes even when the internal haze value exceeds 0%. Within the range of measurement error and the internal haze value can be roughly regarded as the range of 0% (for example, the internal haze value below 0.3%).

When the total haze value of the optical film 31 is 0% or more and 5% or less, and the internal haze value is 0% or more and 5% or less, the surface haze value of the optical film 31 is 0% or more and 5% or less . The surface haze value of the optical film 31 is preferably 0% or more and 1% or less, more preferably 0% or more and 0.3% or less. The surface haze value is caused only by the unevenness of the surface of the optical film 31. The surface haze caused only by the unevenness of the surface of the optical film 31 can be obtained by subtracting the internal haze value from the total haze value. Degree value.

For the display device with a touch panel of the present invention, when the penetration image clarity of the optical film 31 measured with a light comb with a width of 0.125 mm is set to C (0.125), it will be measured with a light comb with a width of 0.25 mm When the clarity of the transparent image of the optical film 31 is set to C (0.25), the following formulas (1) and (2) are satisfied. C（0.25）－C（0.125）≧2% (1) C(0.125)≦64% (2)

In the display device with a touch panel of the present invention, the difference between the value of C (0.25) and the value of C (0.125) is preferably 5% or more, more preferably 10% or more. In addition, the difference between the value of C (0.25) and the value of C (0.125) is preferably 30% or less. The value of C(0.125) is preferably 60% or less, and more preferably 50% or less. In addition, the value of C(0.125) is preferably 5% or more, and more preferably 20% or more.

Furthermore, in another form of the optical film of the present invention, the half-value width of the surface height distribution of the surface of the optical film 11 shown in FIG. 1 is 200 nm or more. Here, the reason why the half-value width of the surface height distribution of the optical film is set to 200 nm or more is that if it is in this range, the watermark cannot be observed by human eyes, that is, the watermark can be made invisible. Various theories are considered as the reason, and for example, the theories shown below can be cited. 4 is a schematic diagram showing how light incident into a display device with a touch panel using another form of the optical film 11 of the present invention is reflected. As shown in FIG. 4, the light incident from the side of the touch panel 45 is reflected on the surface of the optical layer 43 (concave-convex shape 44) due to the light reflected from the interface between the optical layer 43 and the gap 46 and penetrates the gap 46 Light generates interference, and the interference color of each position changes according to the thickness of each position of the gap 46 between the touch panel 45 and the surface (concave-convex shape 44) of the optical layer 43. Furthermore, in Fig. 4, the interference occurs in the entire visible wavelength range. The interference color of the light (A) in the thickest part of the gap 46 is red, and the interference color of the light (C) in the thinnest part of the gap 46 It is blue, and the interference color of light (B) is the yellow-green color between light (A) and light (C). Moreover, if such a change of interference color occurs in a tiny area that humans cannot recognize, the interference colors will be mixed, and the human eye cannot recognize the interference fringes (watermark). That is, since the thickness change of the gap 46 corresponds to the height distribution of the uneven shape 44, it is sufficient that the height distribution is formed in an area that is not recognized by the human eye and sufficiently generates interference colors in the entire visible light wavelength range. Here, the difference between the optical distance between the interference color at the lower limit of the visible light wavelength and the interference color at the upper limit of the visible light wavelength is the largest when the optical distance becomes 1 wavelength, because the visible light wavelength is between 380 nm and 780 nm. Range, so the difference in optical distance at this time becomes 400 nm (780 nm-380 nm). Therefore, if the difference in optical distance is 400 nm or more, and the height distribution of the uneven shape 44 therebetween is as uniform as possible, interference colors can be sufficiently generated in the entire visible light wavelength. In addition, since the above-mentioned optical distance is twice the thickness of the gap 46, the thickness of the gap 46 changes as long as it is 200 nm or more. In other words, as long as the surface height of the optical layer 43 having the uneven shape 44 on the surface has a distribution as uniform as possible in the range of 200 nm or more. Therefore, if the half-value width of the surface height distribution on the surface of the optical film 11 is 200 nm or more, the concave-convex shape 44 has a distribution that is as uniform as possible in the above-mentioned surface height range of 200 nm or more. The height distribution of “interference color generated by the ground” can make the watermark invisible. Moreover, at this time, in order to ensure the thickness variation of the gap 46, that is, the surface height distribution of the surface of the optical layer 43 in a small area, it is only necessary to calculate the surface height distribution based on the surface contour after the large gaps are removed in advance. That is, it is sufficient to use a surface profile of "using a long-wavelength cut-off filter". From the viewpoint of making it unrecognizable by the human eye, the wavelength of the long-wavelength cutoff filter is preferably set to 800 μm.

Here, the half-value width of the surface height distribution is expressed as follows: According to the surface profile obtained with a contact surface roughness meter or a non-contact surface roughness meter (such as an interference microscope, a confocal microscope, an atomic force microscope, etc.), The half-value width of the uneven distribution obtained by plotting the Histogram Plot with the horizontal axis as the uneven height (unit: nm) and the vertical axis as the frequency (unit: Counts) (half the height of the height of the peak position distribution) The width of the distribution) (unit: nm). The half-value width of the above-mentioned surface height distribution is preferably 220 nm or more, more preferably 250 nm or more. In addition, the half-value width of the above-mentioned surface height distribution is preferably 500 nm or less. If the half-value width of the surface height distribution exceeds 500 nm, the height of the surface unevenness may be too large, and the glare may deteriorate. The half-value width of the surface height distribution is more preferably 400 nm or less, and still more preferably 300 nm or less. In terms of simplicity, the above-mentioned surface profile is preferably measured using an interference microscope. Examples of such interference microscopes include the "New View" series manufactured by Zygo Corporation.

以與算出上述表面高度分佈時相同之方式獲得之表面輪廓，於其中，若將橫方向設為x方向，將高度方向設為y方向，將橫方向之測定間隔設為d，則x2－x1＝x3－x2＝d，y1、y2、y3視為各點之高度，上式可改寫如下。

藉由根據表面輪廓對各點分別進行如上所述之計算，而計算出各點之曲率，將其等進行平均，藉此可算出表面凹凸之平均曲率。 此時，由於極微小之凹凸無助於透鏡效應，較佳為不包括於曲率之計算中，故而較佳為於求出表面輪廓時，使用短波長截斷濾光器來將極微小之凹凸成分去除。 就該觀點而言，短波長截斷濾光器之波長，較佳設為25 μm。The average curvature of the surface irregularities on the surface of the optical film 11 of the present invention of the above-mentioned another aspect is 0.30 mm ^-1 or less. Concave and convex shapes are formed on the surface of the optical layer for the purpose of preventing watermarks, etc. However, the concavities and convexities of the concave and convex shapes may act like lenses (lens effect). It is also believed that if such a lens effect occurs, the transmitted light from the "black matrix that separates the pixels of the liquid crystal display" or "pixels" is randomly enhanced, thereby generating glare. The inventors conducted research and found that the greater the curvature of the concave-convex shape, the greater the lens effect, and the easier it is to generate glare. Therefore, by setting the average curvature of the surface unevenness of the optical film to 0.30 mm ^-1 or less, even if the uneven shape is formed, glare can be prevented extremely effectively. The average curvature of the surface unevenness is preferably set to 0.25 mm ^-1 or less, more preferably set to 0.20 mm ^-1 or less. In addition, the average curvature of the surface unevenness is preferably 0.05 mm ^-1 or more. If the average curvature is less than 0.05 mm ^-1 , the waterproof seal may be poor. Here, the average curvature of the surface concavities and convexities is obtained as follows. Figure 5 shows the surface profile of the above-mentioned optical film. As shown in Figure 5, when A (x1, y1), B (x2, y2) and C (x3, y3) are assigned to the surface profile of the optical film, the curvature of point B can be It is calculated as the reciprocal of the radius of the circle passing through the three points of point A, point B, and point C, and expressed by the following formula.

The surface profile obtained in the same way as when calculating the above surface height distribution, in which, if the horizontal direction is set to the x direction, the height direction is set to the y direction, and the measurement interval in the horizontal direction is set to d, then x2-x1 =x3-x2=d, y1, y2, and y3 are regarded as the height of each point, and the above formula can be rewritten as follows.

By performing the calculations as described above for each point based on the surface profile, the curvature of each point is calculated, and the average curvature of the surface concavities and convexities can be calculated by averaging the points. At this time, since the extremely small unevenness does not contribute to the lens effect, it is preferably not included in the calculation of curvature. Therefore, it is better to use a short-wavelength cut-off filter to remove the extremely small unevenness when calculating the surface profile. Remove. From this point of view, the wavelength of the short-wavelength cut filter is preferably set to 25 μm.

Furthermore, in general, practitioners predict that, from the viewpoint of suppressing glare, the value of the average interval (Sm) of surface irregularities should be smaller. If the value is larger, glare will deteriorate (for example, refer to Japanese Patent Application Publication No. 2010-191412 Bulletin, etc.). However, the smaller the average interval of the surface unevenness means the larger the average curvature. Therefore, the half-value width of the surface height distribution and the average curvature of the surface concavities and convexities meet the above-mentioned specific numerical value range of the optical film, according to the technical level of the previously known optical film, it can be said that it is beyond the predictable range.

In addition, in a display device with a touch panel using another form of the optical film of the present invention (hereinafter also referred to as another form of the display device with a touch panel of the present invention), another one shown in FIG. 3 The half-value width of the surface height distribution of the surface of the optical film 31 of the present invention of the form of the present invention is 200 nm or more. Here, the half-value width of the surface height distribution is expressed as follows: According to the surface profile obtained with a contact surface roughness meter or a non-contact surface roughness meter (such as an interference microscope, a confocal microscope, an atomic force microscope, etc.), The half-value width of the uneven distribution obtained by plotting the histogram with the horizontal axis as the bump height (unit: nm) and the vertical axis as the frequency (unit: Counts) (the width of the distribution at the half-height position of the height of the peak position distribution) ) (Unit: nm).

In another aspect of the display device with a touch panel of the present invention, the half-value width of the surface height distribution is preferably 220 nm or more, more preferably 250 nm or more. In addition, the half-value width of the above-mentioned surface height distribution is preferably 500 nm or less. If the half-value width of the surface height distribution exceeds 500 nm, the height of the surface unevenness may be too large, and the glare may deteriorate. The half-value width of the surface height distribution is more preferably 400 nm or less, and still more preferably 300 nm or less. In terms of simplicity, the above-mentioned surface profile is preferably measured using an interference microscope. Examples of such interference microscopes include the "New View" series manufactured by Zygo Corporation.

In another aspect of the display device with a touch panel of the present invention, the average curvature of the surface concavities and convexities on the surface of the optical film is 0.30 mm ^-1 or less. The average curvature of the surface irregularities is preferably 0.25 mm ^-1 or less, and more preferably 0.20 mm ^-1 or less. In addition, the average curvature of the surface unevenness is preferably 0.05 mm ^-1 or more. If the average curvature is less than 0.05 mm ^-1 , the waterproof seal may be poor.

Furthermore, in general, practitioners predict that, from the viewpoint of suppressing glare, the value of the average interval (Sm) of surface irregularities should be smaller. If the value is larger, glare will deteriorate (for example, refer to Japanese Patent Application Publication No. 2010-191412 Bulletin, etc.). However, the smaller the average interval of the surface unevenness means the larger the average curvature. Therefore, the half-value width of the surface height distribution and the average curvature of the surface concavities and convexities meet the above-mentioned specific numerical value range of the optical film, according to the technical level of the previously known optical film, it can be said that it is beyond the predictable range.

The optical film of the present invention is laminated on a light-transmitting substrate with an optical layer having a concave-convex shape on the surface. The above-mentioned translucent substrate is not particularly limited as long as it has translucency, and examples include cellulose acylate substrates, cycloolefin polymer substrates, polycarbonate substrates, and acrylate-based substrates. Polymer substrate, polyester substrate, or glass substrate, etc.

As said acylated cellulose base material, a triacetate cellulose base material, a cellulose diacetate base material, etc. are mentioned, for example. Moreover, as said cycloolefin polymer base material, the base material etc. which consist of polymers, such as a norbornene-type monomer and a monocyclic cycloolefin monomer, etc. are mentioned, for example.

In addition, examples of the above-mentioned polycarbonate substrate include aromatic polycarbonate substrates based on bisphenols (bisphenol A, etc.), diethylene glycol bisallyl carbonate (diethylene glycol bisallyl carbonate, etc.). ) And other aliphatic polycarbonate substrates.

In addition, examples of the above-mentioned acrylate-based polymer substrates include polymethyl (meth)acrylate substrates, polyethyl (meth)acrylate substrates, and methyl (meth)acrylate-(meth)acrylate substrates. Butyl acrylate copolymer substrate, etc. In addition, in this specification, (meth)acrylic acid means acrylic acid or methacrylic acid.

Examples of the polyester substrate include at least one of polyethylene terephthalate, polypropylene terephthalate, polybutylene terephthalate, and polyethylene naphthalate. As the base material of the constituent components, etc.

Examples of the glass substrate include glass substrates such as soda lime silica glass, borosilicate glass, and alkali-free glass.

Among them, in terms of excellent retardation and easy adhesion to the polarizing element, the acylated cellulose substrate is preferred, and among the acylated cellulose substrates, the triacetyl cellulose substrate is preferred. (TAC substrate). The triacetyl cellulose substrate is a translucent substrate with an average light transmittance above 50% in the visible light range of 380 to 780 nm. The average light transmittance of the triacetyl cellulose substrate is preferably 70% or more, and more preferably 85% or more. Furthermore, the triacetyl cellulose base material may also be the following: in addition to pure triacetyl cellulose, it becomes cellulose acetate propionate (cellulose acetate propionate), cellulose acetate butyrate (cellulose acetate butyrate), etc. ) Generally, fatty acids that form cellulose and esters are used in combination with ingredients other than acetic acid. In addition, other cellulose lower fatty acid esters such as diacetyl cellulose, or various additives such as plasticizers, ultraviolet absorbers, and slip agents may be added to the triacetyl cellulose as necessary.

In terms of excellent retardation and heat resistance, a cycloolefin polymer substrate is preferred, and in terms of mechanical properties and heat resistance, a polyester substrate is preferred.

The thickness of the light-transmitting substrate is not particularly limited, and it can be 5 μm or more and 1000 μm or less. From the viewpoint of handling properties and the like, the lower limit of the thickness of the light-transmitting substrate is preferably 15 μm or more. More preferably, it is 25 μm or more. From the viewpoint of thinning, the upper limit of the thickness of the translucent substrate is preferably 80 μm or less.

The optical film of the present invention preferably has a mixed region at the interface between the translucent substrate and the optical layer, and the mixed region is the translucent substrate and photopolymerization containing a weight average molecular weight of 1000 or less. Monomers are obtained by mixing resins as monomer units. By having the above-mentioned mixed region, it is possible to suppress interference fringes caused by the reflection at the interface between the above-mentioned translucent base material and the optical layer. The above-mentioned photopolymerizable single system is the same as the "photopolymerizable monomer whose weight average molecular weight of the following binder resin contained in the optical layer as a monomer unit is 1000 or less".

The thickness of the aforementioned mixed region is preferably 0.01 μm or more and 1 μm or less. Since the optical film and the display device with touch panel of the present invention can sufficiently suppress the generation of interference fringes by the following concave-convex surface of the optical layer, even when the thickness of the mixed region is thin as described above, Can suppress interference fringes. Furthermore, the previously known anti-reflection film also suppresses interference fringes by forming the same mixed area as the above-mentioned mixed area, but the thickness of the mixed area formed in the previously known anti-reflection film is 3 μm thick As mentioned above, compared with the mixed area formed in the conventional anti-reflection film, the thickness of the mixed area formed in the present invention can be said to be sufficiently thin. In addition, by forming the above-mentioned mixed region, the adhesion between the light-transmitting base material and the optical layer can be further improved. Furthermore, as described above, since the occurrence of interference fringes can be sufficiently suppressed by the uneven surface of the optical layer, it is not necessary to form such a mixed region in the optical film. Since the occurrence of interference fringes can be suppressed even when the mixed region is not formed in this way, it is difficult to form a mixed region with a substrate such as an acrylic substrate, a cycloolefin polymer substrate, or a polyester substrate. It can also be used as a translucent substrate.

Examples of the above-mentioned optical layer include layers that exhibit functions such as anti-reflection, hard coat, anti-glare, antistatic, or antifouling properties.

When the above-mentioned optical layer is a layer that exhibits hard coat properties in addition to anti-reflective properties, the optical layer preferably has a pencil hardness test (4.9 N load) specified in JIS K5600-5-4 (1999) Hardness above "H".

The surface of the above-mentioned optical layer becomes an uneven surface formed with uneven shapes as described above. In addition, the above-mentioned "surface of the optical layer" means that the surface of the optical layer and the surface on the translucent substrate side (the back surface of the optical layer) is the opposite side.

Moreover, as long as the internal haze value is within the range of 0% or more and 5% or less, the internal haze value will not affect the clarity of the through image, so the clarity of the through image is affected by the unevenness of the surface of the optical film The influence of shape. On the other hand, in the present invention, the surface of the optical film becomes the uneven surface of the optical layer. Therefore, in the present invention, whether the clarity of the transparent image of the optical film satisfies the above-mentioned formulas (1) and (2) is determined by the concave-convex shape of the concave-convex surface of the optical layer. In addition, below, the uneven surface of the optical layer in which the optical film satisfies the above formulas (1) and (2) is referred to as "special uneven surface".

Also, as with the above reasons, as long as the internal haze value is within the range of 0% or more and 5% or less, the internal haze of the optical film will not affect the generation of glare. Therefore, the internal haze is within the above range. In the case of haze, the uneven shape on the surface of the optical film will affect the generation of glare. Hereinafter, the uneven surface of the optical film that satisfies the above-mentioned requirements in the present invention is also referred to as "special uneven surface".

The above-mentioned special uneven surface can be formed by appropriately adjusting the number of unevenness, the size of the unevenness, or the inclination angle of the unevenness, etc. As a method of adjusting these, for example, the use of a photopolymerizable resin containing a hardened adhesive resin A method of forming an uneven surface with a compound and fine particle composition for an optical layer, etc.

In the above-mentioned method of forming an uneven surface, when the photopolymerizable compound is polymerized (crosslinked) to become a binder resin, the photopolymerizable compound shrinks as a whole due to curing and shrinkage of the part where there are no fine particles. In contrast, in the part where the fine particles are present, since the fine particles do not undergo curing shrinkage, only the photopolymerizable compound existing above and below the fine particles undergoes curing shrinkage. Thereby, the film thickness of the optical layer becomes thicker in the part where the fine particles are present than the part where the fine particles are not present, and therefore the surface of the optical layer becomes an uneven surface. Therefore, by appropriately selecting the type or particle size of the fine particles and the type of the photopolymerizable compound, and adjusting the coating film forming conditions, an optical layer with a special uneven surface can be formed.

The above-mentioned optical layer preferably contains a binder resin and fine particles, and is formed by the above-mentioned method.

The above-mentioned binder resin is a polymer (crosslinked product) containing a photopolymerizable compound. In addition to the polymer (crosslinked product) of the photopolymerizable compound, the above-mentioned binder resin may also contain a solvent drying resin or a thermosetting resin. The photopolymerizable compound has at least one photopolymerizable functional group. In addition, in this specification, the "photopolymerizable functional group" refers to a functional group that can undergo polymerization reaction by light irradiation. As such a photopolymerizable functional group, ethylenic double bonds, such as a (meth)acryloyl group, a vinyl group, and an allyl group, are mentioned, for example. Furthermore, the so-called "(meth)acryloyl" includes both the meaning of "acryloyl" and "methacryloyl". In addition, examples of the light irradiated when the photopolymerizable compound is polymerized include visible rays, and free radiation such as ultraviolet rays, X-rays, electron beams, α rays, β rays, and γ rays.

As said photopolymerizable compound, a photopolymerizable monomer, a photopolymerizable oligomer, or a photopolymerizable polymer can be mentioned, for example, These can be adjusted suitably and used. The photopolymerizable compound is preferably a combination of a photopolymerizable monomer and a photopolymerizable oligomer or a photopolymerizable polymer. In addition, when forming the above-mentioned mixed existence region, at least a photopolymerizable monomer is contained as a photopolymerizable compound.

The photopolymerizable monomer is preferably one having a weight average molecular weight of 1,000 or less. When the weight average molecular weight of the above-mentioned photopolymerizable monomer is 1000 or less, the photopolymerizable monomer can be permeated into the translucent substrate together with the solvent that permeates the translucent substrate. Thereby, it is possible to form a mixture of the transparent substrate and the optical layer containing the photopolymerizable monomer in order to relax the refractive index of the transparent substrate and the optical layer in the vicinity of the interface between the transparent substrate and the optical layer. It is a region where the mixture exists as a resin of a monomer unit. In addition, not only one type of such a photopolymerizable monomer can be used, but a plurality of types can also be used.

As the above-mentioned photopolymerizable monomer, a polyfunctional monomer having two (ie, bifunctional) or more photopolymerizable functional groups is preferred. Examples of the above-mentioned bifunctional monomers include trimethylolpropane tri(meth)acrylate, tripropylene glycol di(meth)acrylate, diethylene glycol di(meth)acrylate, and dipropylene glycol. Di(meth)acrylate, neopentylerythritol tri(meth)acrylate, neopentylerythritol tetra(meth)acrylate, dineopentaerythritol hexa(meth)acrylate, 1,6-hexane Glycol di(meth)acrylate, neopentyl glycol di(meth)acrylate, trimethylolpropane tri(meth)acrylate, ditrimethylolpropane tetra(meth)acrylate ( ditrimethylolpropane tetra(meth)acrylate), dineopentaerythritol penta(meth)acrylate, trineopentaerythritol octa(meth)acrylate, tetraneopentaerythritol deca(meth)acrylate, heterotrimer Cyanuric acid tri(meth)acrylate, isocyanuric acid di(meth)acrylate, polyester tri(meth)acrylate, polyester bis(meth)acrylate, bisphenol bis(meth)acrylate Acrylate, diglycerol tetra(meth)acrylate, adamantyl di(meth)acrylate, isobornyl di(meth)acrylate , Dicyclopentane di(meth)acrylate, tricyclodecane di(meth)acrylate, di-trimethylolpropane tetra(meth)acrylate, or use PO, EO, etc. to modify these Qualified ones.

Among them, from the viewpoint of obtaining an optical layer with higher hardness, neopentyl erythritol triacrylate (PETA), dine pentaerythritol hexaacrylate (DPHA), and neopentyl erythritol tetraacrylate (DPHA) are preferred. Esters (PETTA), dineopentaerythritol pentaacrylate (DPPA), etc.

The aforementioned photopolymerizable oligomer has a weight average molecular weight of more than 1,000 and 10,000 or less. The photopolymerizable oligomer is preferably a multifunctional oligomer having two or more functions, and preferably a multifunctional oligomer having three (trifunctional) or more photopolymerizable functional groups. Examples of the above-mentioned multifunctional oligomer include polyester (meth)acrylate, urethane (meth)acrylate, polyester-(meth)acrylate, polyether ( Meth)acrylate, polyol (meth)acrylate, melamine (meth)acrylate, isocyanurate (meth)acrylate, epoxy (meth)acrylate, etc.

The photopolymerizable polymer has a weight average molecular weight of more than 10,000. As the weight average molecular weight, it is preferably more than 10,000 and 80,000 or less, and more preferably more than 10,000 and 40,000 or less. When the weight average molecular weight exceeds 80,000, the coating suitability may decrease due to higher viscosity, and the appearance of the obtained optical film may deteriorate. Examples of the above-mentioned polyfunctional polymer include: (meth)acrylate amine ester, isocyanurate (meth)acrylate, polyester-(meth)acrylate amine ester, epoxy (meth)acrylate, etc. .

The solvent-drying resin-based thermoplastic resin, etc., becomes the resin of the coating film only by drying the solvent "added to adjust the solid content at the time of coating". In the case of adding a solvent-dried resin, it can effectively prevent coating defects on the coating surface of the coating solution when forming the optical layer. The solvent-drying resin is not particularly limited, and generally thermoplastic resins can be used.

Examples of the above-mentioned thermoplastic resins include: styrene resins, (meth)acrylic resins, vinyl acetate resins, vinyl ether resins, halogen-containing resins, alicyclic olefin resins, and polycarbonate resins. , Polyester resin, polyamide resin, cellulose derivative, silicone resin, rubber or elastomer, etc.

The above-mentioned thermoplastic resin is preferably non-crystalline and soluble in an organic solvent (especially a common solvent that can dissolve a plurality of polymers or curable compounds). Especially from the viewpoint of transparency or weather resistance, styrene resins, (meth)acrylic resins, alicyclic olefin resins, polyester resins, cellulose derivatives (cellulose esters, etc.) are preferred. )Wait.

The thermosetting resin is not particularly limited, and examples thereof include phenol resins, urea resins, diallyl phthalate resins, melamine resins, guanamine resins, unsaturated polyester resins, polyurethane resins, Epoxy resin, aminoalkyd resin, melamine-urea co-condensation resin, silicone resin, polysiloxane resin, etc.

The above-mentioned fine particles may be either inorganic fine particles or organic fine particles. Among them, for example _{, silicon dioxide (SiO 2} ) fine particles, alumina fine particles, titanium oxide fine particles, tin oxide fine particles, antimony-doped tin oxide (abbreviation: ATO) are preferred. ) Inorganic oxide particles such as particles and zinc oxide particles. The above-mentioned inorganic oxide fine particles can form aggregates in the optical layer, and a special uneven surface can be formed by the degree of aggregation of the aggregates.

Examples of the above-mentioned organic fine particles include plastic beads. As the plastic beads, specific examples include: polystyrene beads, melamine resin beads, acrylic beads, acrylic-styrene beads, silicone beads, benzoguanamine beads, benzene Guanamine-formaldehyde (benzoguanamine-formaldehyde) condensation beads, polycarbonate beads, polyethylene beads, etc.

The organic fine particles are preferably used to appropriately adjust the resistance of the fine particles to the hardening shrinkage during the hardening and shrinking. When adjusting the resistance to shrinkage, it is better to make a plurality of optical films with "organic particles with different hardnesses produced by changing the degree of three-dimensional crosslinking" in advance, and evaluate the clarity of the optical film's penetration image , Thereby selecting the degree of cross-linking suitable for a special uneven surface.

In the case of using inorganic oxide particles as the above-mentioned fine particles, it is preferable that the inorganic oxide particles have been surface-treated. By performing surface treatment on the above-mentioned inorganic oxide fine particles, the distribution of the fine particles in the optical layer can be better controlled, and the chemical resistance and saponification resistance of the fine particles themselves can also be improved.

As the above-mentioned surface treatment, a hydrophobization treatment to make the surface of the fine particles hydrophobic is preferable. Such a hydrophobization treatment can be obtained by chemically reacting the surface of the fine particles with a surface treatment agent such as silanes or silazanes. Specific surface treatment agents include, for example, dimethyldichlorosilane or polysiloxane oil, hexamethyldisilazane, octylsilane, hexadecylsilane, aminosilane, and methacrylic acid. Silane, octamethylcyclotetrasiloxane, polydimethylsiloxane, etc. When the fine particles are inorganic oxide fine particles, hydroxyl groups are present on the surface of the inorganic oxide fine particles. By performing the hydrophobization treatment as described above, the number of hydroxyl groups present on the surface of the inorganic oxide fine particles becomes The specific surface area measured by the BET method becomes smaller, and the excessive aggregation of fine inorganic oxide particles can be suppressed, and a functional layer with a special uneven surface can be formed.

In the case of using inorganic oxide particles as the above-mentioned fine particles, the inorganic oxide fine particles are preferably amorphous. The reason is that when the inorganic oxide particles are crystalline, the crystal lattice defects contained in the crystal structure of the inorganic oxide particles lead to the increase in the strength of the Lewis acid salt of the inorganic oxide particles, which makes it impossible to control the inorganic oxide particles. There is a risk of excessive agglomeration of oxide particles.

The content of fine particles in the optical layer is not particularly limited, but is preferably 0.1% by mass or more and 5.0% by mass or less. Since the content of fine particles is 0.1% by mass or more, a special uneven surface can be formed more reliably, and since the content of fine particles is 5.0% by mass or less, there is no excessive generation of aggregates, and internal diffusion and/or can be suppressed Large unevenness is generated on the surface of the functional layer, thereby suppressing white turbidity. The lower limit of the content of fine particles is more preferably 0.2% by mass or more, and the upper limit of the content of fine particles is more preferably 3.0% by mass or less.

The above-mentioned fine particles are preferably spherical in a single particle state. Since the single particles of the fine particles are in such a spherical shape, an image with excellent contrast can be obtained when the optical film is arranged on the image display surface of the image display device. Here, the term "spherical" includes, for example, a true spherical shape, an elliptical spherical shape, etc., but does not include the so-called indefinite shape.

In the case of using organic fine particles as the above-mentioned fine particles, the difference in refractive index with the binder resin is reduced by changing the copolymerization ratio of resins with different refractive indexes. For example, in terms of suppressing light diffusion caused by the fine particles , Preferably set to less than 0.01. The average primary particle size of the organic fine particles is preferably less than 8.0 μm, more preferably 5.0 μm or less.

The above-mentioned optical layer is preferably formed by using fine particles that form loose aggregates in the above-mentioned method. The so-called "loose agglomerate" means that the agglomerate of fine particles is not a block, but an agglomerate with a structure including a flexure formed by connecting primary particles and an inner region sandwiched by the flexure. Here, in this specification, the so-called "bending part" also includes the concept of a bending part. Examples of the shape having a bent portion include a V shape, a U shape, an arc shape, a C shape, a spiral shape, and a cage shape. The both ends of the above-mentioned flexion part may be closed, for example, it may be a ring structure with a flexion part.

The above-mentioned buckling part can be formed by connecting primary particles, and is composed of an aggregate of buckled fine particles, and can be formed by a stem formed by connecting the primary particles and a branch formed by connecting the stem from the primary particles. It can also be composed of two branches branched from the stem and connected to the stem. The above-mentioned "cadres" refers to the longest part of the aggregate of fine particles.

The above-mentioned inner area is filled with adhesive resin. It is preferable that the said flexion part exists so that it may sandwich the inner region from the thickness direction of an optical layer.

Agglomerates aggregated into blocks, and when cured, the photopolymerizable compound of the binder resin functions as a single solid during curing and shrinkage (polymerization shrinkage). Therefore, the concave-convex surface of the optical layer corresponds to the shape of the aggregate . In contrast, the aggregate formed by loosely agglomerating fine particles has a flexure and an inner region sandwiched by the flexure, and therefore functions as a solid having a cushioning effect during hardening and shrinking. Therefore, the agglomerate formed by loosely agglomerating fine particles is easily and uniformly squashed during hardening and shrinking. Thereby, compared with the case where the fine particles are aggregated into a block, the shape of the uneven surface is gentler, and it is not easy to locally generate a large uneven shape. When the above-mentioned optical layer is formed of aggregates that are loosely aggregated, the size of the aggregates that are loosely aggregated can also be adjusted by adjusting the film thickness. That is, if the film thickness is thick, the size of the loosely aggregated aggregates tends to become larger. Thereby, the size of the unevenness can be further increased, and the interval between the unevenness can be further enlarged.

In addition, as the fine particles forming loose aggregates, for example, inorganic oxide fine particles having an average primary particle diameter of 1 nm or more and 100 nm or less are preferable. Since the average primary particle size of the fine particles is 1 nm or more, it is easier to form an optical layer with a special uneven surface. In addition, since the average primary particle size is 100 nm or less, the light diffusion caused by the fine particles can be suppressed. Can obtain excellent dark room contrast. The lower limit of the average primary particle size of the fine particles is more preferably 5 nm or more, and the upper limit of the average primary particle size of the fine particles is more preferably 50 nm or less. Furthermore, the average primary particle size of the microparticles is a value measured using image processing software based on images of cross-sectional electron microscopes (preferably TEM, STEM and other penetrating type with a magnification of 50,000 times or more).

When inorganic oxide fine particles are used as the above-mentioned fine particles forming loose aggregates, the unevenness of the uneven surface of the optical layer is preferably formed only of inorganic oxide fine particles. The so-called "concavity and convexity of the uneven surface of the optical layer are formed only by inorganic oxide fine particles" means that the irregularities of the optical layer are formed by fine particles other than inorganic oxide fine particles, except for inorganic oxide fine particles. Situation. The so-called "substantially not included" here means that if it is a fine particle that does not form the uneven surface of the optical layer, or even if the unevenness is formed, it is a small amount that does not affect the anti-reflective property, the optical layer may also include inorganic oxidation Particles other than particles.

Among the above-mentioned inorganic oxide particles, fumed silica is particularly preferred in terms of forming loose aggregates and easily forming special uneven surfaces. The above-mentioned so-called smoked silicon dioxide is an amorphous silicon dioxide with a particle size of 200 nm or less produced by a dry method, which can be obtained by reacting volatile compounds containing silicon in the gas phase. Specifically, for example _{, a silicon compound such as silicon tetrachloride (SiCl 4} ) is hydrolyzed in a flame of oxygen and hydrogen to be produced. As a commercially available product of the above-mentioned fumigated silica, for example, AEROSIL R805 manufactured by Japan Aerosil Co., Ltd. can be cited.

Among the above-mentioned fumigated silicas, there are those exhibiting hydrophilicity and those exhibiting hydrophobicity. Among these, it is preferable to exhibit hydrophobicity from the viewpoint of reducing water absorption and being easily dispersed in the composition for the functional layer. By. The hydrophobic fumigated silica can be obtained by chemically reacting the silanol group present on the surface of the fumigated silica with the above-mentioned surface treatment agent. From the viewpoint of easily obtaining the agglomerates as described above, it is most preferable to treat the silica by fumigating with octylsilane.

The BET specific surface area of the above-mentioned smoked silica is preferably 100 m ² /g or more and 200 m ² /g or less. By setting the BET specific surface area of the smoked silica to be more than 100 m ² /g, the smoked silica will not be over-dispersed, and it is easy to form a moderate agglomerate. The BET specific surface area is set to 200 m ² /g or less, and the fumigated silica is not easy to form too large agglomerates. The lower limit of the BET specific surface area of the smoked silica is more preferably 120 m ² /g, and more preferably 140 m ² /g. The upper limit of the BET specific surface area of the smoked silica is more preferably 180 m ² /g, and still more preferably 165 m ² /g.

Such an optical layer can be formed by the following method, for example. First, the following optical layer composition is applied to the surface of the above-mentioned translucent substrate. Examples of methods for coating the above-mentioned optical layer composition include spin coating, dipping, spraying, swash coating, bar coating, roll coating, gravure coating, and die coating. Well-known coating methods such as nozzle coating method.

The composition for the optical layer contains at least the photopolymerizable compound and the fine particles. In addition, the above-mentioned thermoplastic resin, the above-mentioned thermosetting resin, a solvent, and a polymerization initiator may be added to the composition for an optical layer as needed. Furthermore, in the optical layer composition, it is also possible to add previously known dispersing agents, surfactants, antistatic agents, silane coupling agents, and thickening agents for the purpose of improving the hardness of the optical layer, suppressing curing shrinkage, and controlling the refractive index. Agents, anti-coloring agents, coloring agents (pigments, dyes), defoamers, leveling agents, flame retardants, ultraviolet absorbers, adhering agents, polymerization inhibitors, antioxidants, surface modifiers, slip agents, etc. .

烷、二氧雜環戊烷、四氫呋喃等）、脂肪族烴類（己烷等）、脂環式烴類（環己烷等）、芳香族烴類（甲苯、二甲苯等）、鹵化碳類（二氯甲烷、二氯乙烷等）、酯類（甲酸甲酯、乙酸甲酯、乙酸乙酯、乙酸丙酯、乙酸丁酯、乳酸乙酯等）、賽珞蘇（cellosolve）類（甲基賽珞蘇、乙基賽珞蘇、丁基賽珞蘇等）、乙酸賽珞蘇類、亞碸類（二甲基亞碸等）、醯胺類（二甲基甲醯胺、二甲基乙醯胺等）等，亦可為該等之混合物。The above-mentioned solvent can be used for the following purposes: to easily apply the above-mentioned optical layer composition to adjust the viscosity; or to adjust the evaporation rate or the dispersibility of the fine particles, adjust the degree of aggregation of the fine particles when the optical layer is formed, and easily form special unevenness surface. As such a solvent, for example, alcohol (for example, methanol, ethanol, propanol, isopropanol, n-butanol, sec-butanol, t-butanol, benzyl alcohol, PGME, ethylene glycol), ketones ( Acetone, methyl ethyl ketone (MEK), cyclohexanone, methyl isobutyl ketone, diacetone alcohol, cycloheptanone, diethyl ketone, etc.), ethers (1,4-di

Alkanes, dioxolane, tetrahydrofuran, etc.), aliphatic hydrocarbons (hexane, etc.), alicyclic hydrocarbons (cyclohexane, etc.), aromatic hydrocarbons (toluene, xylene, etc.), halogenated carbons (Dichloromethane, dichloroethane, etc.), esters (methyl formate, methyl acetate, ethyl acetate, propyl acetate, butyl acetate, ethyl lactate, etc.), cellosolve (A Glycerol, ethyl serosol, butyl serosol, etc.), serosol acetate, sulfite (dimethyl sulfoxide, etc.), amines (dimethylformamide, dimethyl sulfoxide, etc.) Acetamide, etc.), etc., may also be a mixture of these.

In addition, as described above, when a mixed region is formed near the interface between the light-transmitting substrate and the optical layer, as the above-mentioned solvent, a solvent containing a transparent base having high permeability to the light-transmitting substrate is used. The material is dissolved or swelled by a penetrating solvent, and as the photopolymerizable compound, one containing at least a photopolymerizable monomer with a weight average molecular weight of 1000 or less is used. By using the above-mentioned penetrating solvent and photopolymerizable monomer, not only the penetrating solvent penetrates into the light-transmitting substrate, the photopolymerizable monomer also penetrates into the light-transmitting substrate, so it can be combined with the light-transmitting substrate. In the vicinity of the interface of the optical layer, a mixed region of "translucent base material and resin containing photopolymerizable monomers as monomer units are mixed" is formed.

烷、二氧雜環戊烷、四氫呋喃等）、賽珞蘇類（甲基賽珞蘇、乙基賽珞蘇、丁基賽珞蘇等）、乙酸賽珞蘇類、亞碸類（二甲基亞碸等）、酚類（苯酚、鄰氯苯酚）等。又，亦可為該等之混合物。於使用三乙醯纖維素基材作為透光性基材之情形時，於該等中，作為滲透性溶劑，例如較佳為選自由甲基異丁基酮、甲基乙基酮、環己酮、乙酸甲酯、乙酸乙酯、乙酸丙酯、乙酸丁酯所組成之群中之至少1種，又，於使用聚酯基材作為透光性基材之情形時，較佳為鄰氯苯酚（ortho chlorophenol）。Examples of the above-mentioned permeable solvent include ketones (acetone, methyl ethyl ketone (MEK), cyclohexanone, methyl isobutyl ketone, diacetone alcohol, cycloheptanone, diethyl ketone), esters (Methyl formate, methyl acetate, ethyl acetate, propyl acetate, butyl acetate, ethyl lactate, etc.), ethers (1,4-two

Alkane, dioxolane, tetrahydrofuran, etc.), serosols (methyl serosol, ethyl serosol, butyl serosol, etc.), serosol acetate, sulfinate (dimethyl serosol, etc.) Sulfite, etc.), phenols (phenol, o-chlorophenol), etc. Moreover, it may be a mixture of these. In the case of using a triacetyl cellulose substrate as a translucent substrate, among these, the penetrating solvent is preferably selected from methyl isobutyl ketone, methyl ethyl ketone, and cyclohexane. At least one of the group consisting of ketone, methyl acetate, ethyl acetate, propyl acetate, and butyl acetate. In addition, when a polyester substrate is used as a translucent substrate, o-chloride is preferred Phenol (ortho chlorophenol).

（thioxanthone）類、苯丙酮類、苯偶醯類、安息香類、醯基氧化膦類。又，較佳為混合光增感劑而使用，作為其具體例，例如可列舉：正丁基胺、三乙基胺、聚正丁基膦等。The above-mentioned polymerization initiator is a component that decomposes by light irradiation, generates radicals, and initiates or proceeds the polymerization (crosslinking) of the photopolymerizable compound. Such a polymerization initiator is not particularly limited as long as it can release a substance that initiates radical polymerization by light irradiation, and those known in the past can be used. Specific examples include, for example, acetophenones and benzophenones. Ketones, Michler's benzoyl benzoate (Michler's benzoyl benzoate), α-amyloxime ester (α-amyloxime), 9-oxysulfur 𠮿

(Thioxanthone), phenylacetone, benzil, benzoin, phosphine oxide. Moreover, it is preferable to mix and use a photosensitizer, and as a specific example, n-butylamine, triethylamine, poly-n-butylphosphine, etc. are mentioned, for example.

類、安息香、安息香甲醚等。As the polymerization initiator, when the binder resin is a resin system having a radically polymerizable unsaturated group, it is preferable to use acetophenones, benzophenones, and 9-oxysulfur singly or in combination.

Class, benzoin, benzoin methyl ether and so on.

The content of the polymerization initiator in the composition for the optical layer is preferably 0.5 parts by mass or more and 10.0 parts by mass or less with respect to 100 parts by mass of the photopolymerizable compound. By setting the content of the polymerization initiator within this range, the hard coat performance can be sufficiently maintained and hardening inhibition can be suppressed.

The content ratio (solid content) of the raw material in the composition for the optical layer is not particularly limited, but it is usually preferably 5% by mass or more and 70% by mass or less, and more preferably 25% by mass or more and 60% by mass or less.

As the above-mentioned leveling agent, for example, silicone oil, fluorine-based surfactant, etc. are preferable in terms of preventing the optical layer from becoming a Benard cell structure. When the solvent-containing resin composition is applied and dried, a difference in surface tension, etc., occurs on the surface and inner surface of the coating film in the coating film, thereby causing a large amount of convection in the coating film. The structure produced by this convection is called the Benard cavitation structure, which causes problems such as orange peel or coating defects in the formed optical layer.

The above-mentioned Benardian flow structure may cause the irregularities on the surface of the optical layer to become too large. If the leveling agent as described above is used, the convection can be prevented, so that not only a defect-free or uneven optical layer can be obtained, but also the uneven shape of the surface of the optical layer can be easily adjusted.

The method for preparing the composition for the optical layer is not particularly limited as long as the components can be uniformly mixed. For example, it can be performed using a known device such as a paint shaker, a bead mill, a kneader, and a stirrer.

After coating the optical layer composition on the surface of the above-mentioned translucent substrate, in order to dry the coated optical layer composition, it is transported to the heated area, and the optical layer composition is made by various known methods. Dry to evaporate the solvent. Here, the aggregation state or distribution state of the particles can be adjusted by selecting the relative evaporation rate of the solvent, the concentration of the solid content, the temperature of the coating solution, the drying temperature, the wind speed of the drying wind, the drying time, the concentration of the solvent environment in the drying area, etc. .

In particular, the method of adjusting the distribution state of fine particles by selecting drying conditions is simple and preferable. For example, by lowering the drying temperature and/or reducing the drying wind speed, the drying speed is slowed down, whereby the fine particles are more likely to agglomerate, so it can be easily formed into a shape with larger unevenness and a wider interval between the unevennesses. The specific drying temperature is preferably 30 to 120°C, and the drying wind speed is preferably 0.2 to 50 m/s. By performing one or more drying treatments that are appropriately adjusted within this range, the distribution of fine particles can be reduced. Adjust to the desired state.

In addition, when the composition for the optical layer is dried, the penetrating solvent that has penetrated into the light-transmitting substrate evaporates, and the photopolymerizable compound remains in the light-transmitting substrate. Thereafter, the coating film-like optical layer composition is irradiated with light such as ultraviolet rays to polymerize (crosslink) the photopolymerizable compound, and the optical layer composition is cured to form an optical layer and form a mixed region.

When ultraviolet rays are used as the light for curing the above-mentioned optical layer composition, ultraviolet rays emitted from ultrahigh pressure mercury lamps, high pressure mercury lamps, low pressure mercury lamps, carbon arcs, xenon arcs, metal halide lamps, etc. can be used. In addition, as the wavelength of ultraviolet rays, a wavelength range of 190 to 380 nm can be used. Specific examples of electron beam sources include: Cockcroft-Walton type, Van de Graaff type, resonance transformer type, insulated core transformer type, or linear type, Various electron beam accelerators such as Dynamitron and high frequency.

Furthermore, by using a photopolymerizable compound and a solvent-drying resin as the material for forming the binder resin, it is also possible to form an optical layer with a special uneven surface. Specifically, for example, an optical layer composition containing a photopolymerizable compound, a solvent drying resin, and fine particles is used, and a coating film of the optical layer composition is formed on a translucent substrate by the same method as described above. The composition for the optical layer is cured in the same manner as described above. When a photopolymerizable compound and a solvent-drying resin are used in combination as the material for forming the above-mentioned binder resin, the viscosity can be increased compared with the case where only the photopolymerizable compound is used, and curing shrinkage (polymerization shrinkage) can be reduced. Therefore, the uneven surface of the optical layer can be formed without following the shape of the particles during drying and curing, thereby forming a special uneven surface. However, since the concave-convex shape of the concave-convex surface of the optical layer is affected by the film thickness of the optical layer, etc., when the optical layer is formed by this method, of course, the film thickness of the optical layer must be adjusted appropriately.

Furthermore, in the present invention, the optical layer may have a single-layer structure or a multilayer structure of two or more layers as long as it satisfies the above-mentioned formulas (1) and (2). In addition, in the present invention, the optical layer As long as it satisfies the half-value width of the above-mentioned surface height distribution and the average curvature of the surface concavities and convexities, it can be a single-layer structure or a multilayer structure of two or more layers. Specifically, the optical layer may have a two-layer structure composed of a base concavo-convex layer whose surface becomes a concavo-convex surface and a surface adjustment layer formed on the base concavo-convex layer. The above-mentioned base concavo-convex layer may be an optical layer. The surface adjustment layer is a layer used to fill the fine unevenness on the surface of the base uneven layer to obtain a smooth uneven surface and/or adjust the interval, size, etc. of the unevenness on the surface of the uneven layer. The surface of the surface adjustment layer becomes an uneven surface, and the uneven surface of the surface adjustment layer becomes a special uneven surface. However, when the optical layer has a multilayer structure, the manufacturing steps may become complicated, and the management of the manufacturing steps may become more difficult than in the case of a single-layer structure. Therefore, the optical layer is preferably a single-layer structure.

From the viewpoint of adjusting the unevenness, the film thickness of the surface adjustment layer is preferably 0.5 μm or more and 20 μm or less. The upper limit of the film thickness of the surface adjustment layer is more preferably 12 μm or less, and still more preferably 8 μm or less. The lower limit of the film thickness of the surface adjustment layer is preferably 3 μm or more.

The optical layer composed of the above-mentioned base concavo-convex layer and the surface adjustment layer can be formed by the following method using the base concavo-convex layer composition and the surface adjustment layer composition as the optical layer composition.

As the composition for the base concavo-convex layer, the same composition as the composition for the optical layer described in the section of the composition for the optical layer can be used. In addition, as the composition for the surface adjustment layer, a composition containing at least the same photopolymerizable compound as the photopolymerizable compound described in the column of the above-mentioned binder resin can be used. In addition to the photopolymerizable compound, the composition for the surface adjustment layer may contain the same leveling agent or solvent as the leveling agent or solvent described in the column of the composition for the optical layer.

When forming the optical layer composed of the above-mentioned base uneven layer and the surface adjustment layer, first, the composition for base uneven layer is coated on the light-transmitting substrate, and the base uneven layer is formed on the light-transmitting substrate The coating film of the thing. Then, after the coating film is dried, the coating film is irradiated with light such as ultraviolet rays to polymerize (crosslink) the photopolymerizable compound to harden the base concavo-convex layer composition to form the base concavo-convex layer. After that, the surface adjustment layer composition is coated on the base uneven layer to form a coating film of the surface adjustment layer composition. Then, after the coating film is dried, the photopolymerizable compound is polymerized (crosslinked) by irradiating the coating film with light such as ultraviolet rays to harden the composition for the surface adjustment layer to form the surface adjustment layer. In this way, even if the fine particles forming loose aggregates are not used, an optical layer with a special uneven surface can be formed. However, since the concave-convex shape of the concave-convex surface of the optical layer is also affected by the drying conditions of the coating film, and the film thickness of the base concave-convex layer and the surface adjustment layer, when the optical layer is formed by this method, of course It is also necessary to appropriately adjust the drying conditions of the coating film and the film thickness of the base uneven layer and the surface adjustment layer.

The above-mentioned optical film preferably has a total light transmittance of 85% or more. If the total light transmittance is 85% or more, when the optical film is mounted on the surface of the image display device, the color reproducibility or visibility can be further improved. The above-mentioned total light transmittance is more preferably 90% or more. The total light transmittance can be measured using a haze meter (manufactured by Murakami Color Technology Research Institute, product number: HM-150) by a method based on JIS K7361.

On the surface of the optical film, the three-dimensional average inclination angle θa _3D of the concavities and convexities constituting the surface is preferably 0.12° or more and 0.5° or less, more preferably 0.15° or more and 0.4° or less. On the surface of the above-mentioned optical film, the average peak interval Smp of the concavities and convexities constituting the surface is preferably 0.05 mm or more and 0.3 mm or less, more preferably 0.10 mm or more and 0.25 mm or less.

On the surface of the optical film, the arithmetic average roughness Ra of the unevenness constituting the surface is preferably 0.01 μm or more and 0.11 μm or less, more preferably 0.035 μm or more and 0.08 μm or less. On the surface of the optical film, the 10-point average roughness Rz of the unevenness constituting the surface is preferably 0.10 μm or more and 0.30 μm or less, more preferably 0.12 μm or more and 0.28 μm or less.

並且，（i,j）之傾斜角度係以tan^-1 （St）算出。 就簡便性而言，上述三維粗糙度曲面較佳為使用干涉顯微鏡進行測定。作為此種干涉顯微鏡，例如可列舉Zygo公司製造之「New View」系列等。 並且，上述三維平均傾斜角θa_3D 係藉由各點之傾斜角度之平均值而算出。 又，本發明中之上述凹凸之平均峰間隔Smp係以如下方式求出。 若將以上述三維粗糙度曲面中高於基準面且由一個區域所包圍之部分作為一個峰時的峰之個數設為Ps，將測定區域整體（基準面）之面積設為A，則Smp係以下述式算出。

又，本發明中之上述凹凸之算術平均粗糙度Ra係將JIS B0601：1994中所記載之作為二維粗糙度參數之Ra擴展成三維者，若於基準面設置正交座標軸X、Y軸，將粗糙度曲面設為Z（x,y），將基準面之大小設為Lx、Ly，則以下述式算出。

A＝Lx×Ly 又，若使用上述Z_i,j ，則上述凹凸之算術平均粗糙度Ra係以下述式算出。

N：總點數The above "θa _3D ", "Smp", "Ra" and "Rz" can be measured by contact surface roughness meter or non-contact surface roughness meter (such as interference microscope, confocal microscope, atomic force microscope, etc.) Calculate the obtained three-dimensional roughness surface. The data of the above-mentioned three-dimensional roughness surface is expressed as follows: on the reference plane (the horizontal direction is set as the x-axis, the vertical direction is set as the y-axis), the interval d is arranged as the height of the grid-like point and the position of the point. Said. That is, if the height of the position of the i-th point in the x-axis direction and the j-th point in the y-axis direction (hereinafter referred to as (i,j)) is set to Z _i,j , it is at any position (i,j) , The slope Sx in the x-axis direction with respect to the x-axis and the slope Sy in the y-axis direction with respect to the y-axis are calculated as follows. _{Sx = (Z i + 1,} j -Z i - 1, j) / 2d Sy = (Z i, j + 1 -Z i, j - 1) / 2d Further, (i, j) with respect to the reference plane The slope St is calculated by the following formula.

In addition, the inclination angle of (i,j) is ^{calculated with tan -1} (St). In terms of simplicity, the above-mentioned three-dimensional roughness curved surface is preferably measured using an interference microscope. Examples of such interference microscopes include the "New View" series manufactured by Zygo Corporation. In addition, the above-mentioned three-dimensional average inclination angle θa _3D is calculated from the average value of the inclination angles of each point. In addition, the average peak interval Smp of the aforementioned concavities and convexities in the present invention is obtained as follows. If the number of peaks when the part of the above-mentioned three-dimensional roughness surface is higher than the reference surface and surrounded by an area as a peak is set to Ps, and the area of the whole measurement area (reference surface) is set to A, then Smp is below The formula is calculated.

In addition, the arithmetic average roughness Ra of the aforementioned concavity and convexity in the present invention is one that expands the Ra as a two-dimensional roughness parameter described in JIS B0601: 1994 into three dimensions. If the orthogonal coordinate axes X and Y are set on the reference plane, Set the roughness surface to Z (x, y), and set the size of the reference surface to Lx, Ly, and calculate it with the following formula.

A=Lx×Ly In addition, if the above-mentioned Zi _{,j is used} , the arithmetic average roughness Ra of the above-mentioned unevenness is calculated by the following formula.

N: total points

The above-mentioned 10-point average roughness Rz in the present invention is a three-dimensional expansion of Rz as a two-dimensional roughness parameter described in JIS B0601: 1994. That is, a large number of straight lines passing through the center of the reference surface are arranged radially in a 360-degree manner on the reference surface to cover the entire area, and the three-dimensional roughness surface obtains a cross-sectional curve cut by each straight line, and obtains 10 of the cross-sectional curve Point average roughness (the sum of the average value of the height from the highest peak to the height of the 5th highest peak in order and the average of the depth of the valley from the deepest valley to the 5th deepest in order). It is calculated by averaging the top 50% of the large number of ten-point average roughness thus obtained.

In addition, as the optical film of the present invention can better prevent reflection and Newton's ring generation, or watermark generation, the optical layer is preferably one with a low refractive index layer laminated on a concave-convex layer having a concave-convex shape on the surface. constitute. Examples of the above-mentioned uneven layer include those formed by the same composition and method as the above-mentioned optical layer containing a binder resin and fine particles. The above-mentioned low refractive index layer is a layer that reduces the reflectance of the optical film when light from the outside (such as fluorescent lamps, natural light, etc.) is reflected on the surface of the optical film. The low refractive index layer is preferably composed of any of the following: 1) resin containing low refractive index particles such as silicon dioxide and magnesium fluoride; 2) fluorine resin containing low refractive index resin; 3) containing Silicon dioxide or magnesium fluoride fluorine resin, 4) Silicon dioxide, magnesium fluoride and other low-refractive-index materials, etc. Regarding resins other than fluorine-based resins, the same resins as the above-mentioned binder resin constituting the optical layer can be used. In addition, the above-mentioned silicon dioxide is preferably hollow silicon dioxide microparticles. Such hollow silicon dioxide microparticles can be produced, for example, by the manufacturing method described in the Examples of Japanese Patent Application Laid-Open No. 2005-099778. The refractive index of the low refractive index layers is preferably 1.45 or less, and particularly preferably 1.42 or less. In addition, the thickness of the low refractive index layer is not limited, and it is usually set appropriately within the range of about 30 nm to 1 μm. In addition, the above-mentioned low refractive index layer can be effective in a single layer, but in order to adjust a lower minimum reflectance or a higher minimum reflectance, two or more low refractive index layers may be appropriately provided. In the case of providing the above-mentioned two or more low-refractive index layers, it is preferable to provide a difference in the refractive index and thickness of each low-refractive index layer.

As the above-mentioned fluorine-based resin, a polymerizable compound containing at least a fluorine atom in the molecule or a polymer thereof can be used. The polymerizable compound is not particularly limited. For example, it is preferably one having a curing reactive group such as a functional group that is cured by free radiation and a thermosetting polar group. Moreover, it may be a compound which has these reactive groups at the same time. With respect to the polymerizable compound, the so-called polymer system does not have the above-mentioned reactive group or the like at all.

As the above-mentioned polymerizable compound having a functional group hardened by free radiation, a fluorine-containing monomer having an ethylenically unsaturated bond can be widely used. More specifically, fluoroolefins (for example, vinyl fluoride, vinylidene fluoride, tetrafluoroethylene, hexafluoropropylene, perfluorobutadiene, perfluoro-2,2-dimethyl-1,3-two Oxolone, etc.). As those with (meth)acrylic acid groups, there are also: 2,2,2-trifluoroethyl (meth)acrylate, 2,2,3,3,3-pentafluoropropyl (meth)acrylate , 2-(perfluorobutyl)ethyl (meth)acrylate, 2-(perfluorohexyl)ethyl (meth)acrylate, 2-(perfluorooctyl)ethyl (meth)acrylate, (meth)acrylate Base) 2-(perfluorodecyl)ethyl acrylate, α-trifluoromethyl methacrylate, α-trifluoroethyl methacrylate and other (meth)acrylate compounds having fluorine atoms in the molecule; The molecule has a fluoroalkyl, fluorocycloalkyl or fluoroalkylene group containing at least 3 fluorine atoms with a carbon number of 1 to 14, and at least 2 (meth)acryloyloxy fluorine-containing polyfunctional (methyl ) Acrylate compounds, etc.

As the above-mentioned thermosetting polar group, a hydrogen bond forming group such as a hydroxyl group, a carboxyl group, an amino group, and an epoxy group is preferred. These not only have excellent adhesion with the coating film, but also have excellent affinity with inorganic ultrafine particles such as silica. Examples of polymerizable compounds having a thermosetting polar group include: 4-fluoroethylene-perfluoroalkyl vinyl ether copolymer; fluoroethylene-hydrocarbon vinyl ether copolymer; epoxy, polyurethane, cellulose, Fluorine-modified products of various resins such as phenol and polyimide. Examples of the above-mentioned polymerizable compound having both a functional group hardened by free radiation and a polar group hardened by heat include: partially and fully fluorinated alkyl, alkenyl, and aryl esters of acrylic acid or methacrylic acid, and complete Or partially fluorinated vinyl ethers, fully or partially fluorinated vinyl esters, fully or partially fluorinated vinyl ketones, etc.

In addition, as the fluorine-based resin, for example, the following can be cited. A polymer containing at least one monomer or monomer mixture of a fluorine-containing (meth)acrylate compound of a polymerizable compound having a free radiation curable group; at least one of the above-mentioned fluorine-containing (meth)acrylate compound Not contained in molecules such as methyl (meth)acrylate, ethyl (meth)acrylate, propyl (meth)acrylate, butyl (meth)acrylate, 2-ethylhexyl (meth)acrylate Copolymers of (meth)acrylate compounds with fluorine atoms; such as vinyl fluoride, vinylidene fluoride, trifluoroethylene, chlorotrifluoroethylene, 3,3,3-trifluoropropylene, 1,1,2-trichloro －3,3,3-Trifluoropropylene, hexafluoropropylene homopolymer or copolymer of fluorine-containing monomer, etc. Polysiloxane-containing vinylidene fluoride copolymers obtained by containing polysiloxane components in these copolymers can also be used. As the polysiloxane component in this case, (poly)dimethylsiloxane, (poly)diethylsiloxane, (poly)diphenylsiloxane, (poly)methylphenyl can be exemplified Silicone, alkyl modified (poly)dimethylsiloxane, azo-containing (poly)dimethylsiloxane, dimethylpolysiloxane, phenylmethylpolysiloxane, alkyl ／Aralkyl modified polysiloxane, fluoropolysiloxane, polyether modified polysiloxane, fatty acid ester modified polysiloxane, methyl hydrogen polysiloxane, polysiloxane containing silanol group, polysiloxane containing alkyl Oxy-based polysiloxane, phenol-containing polysiloxane, methacryl-based modified polysiloxane, acryl-based modified polysiloxane, amine-modified polysiloxane, carboxylic acid-modified polysiloxane , Methanol modified silicone, epoxy modified silicone, mercapto modified silicone, fluorine modified silicone, polyether modified silicone, etc. Among them, those having a dimethylsiloxane structure are preferred.

Furthermore, non-polymers or polymers composed of the compounds shown below can also be used as fluorine-based resins. That is, a compound obtained by reacting a fluorine-containing compound having at least one isocyanate group in the molecule with a compound having at least one functional group that reacts with an isocyanate group such as an amino group, a hydroxyl group, and a carboxyl group in the molecule can be used; Fluorine-containing polyether polyols, fluorine-containing alkyl polyols, fluorine-containing polyester polyols, fluorine-containing epsilon-caprolactone modified polyols and fluorine-containing polyols react with compounds having isocyanate groups. Obtained compounds, etc.

Moreover, each binder resin as described in the said optical layer can also be mixed and used together with the polymerizable compound or polymer which has the said fluorine atom. Furthermore, curing agents for hardening reactive groups, etc., various additives and solvents for improving coatability or imparting antifouling properties can be suitably used.

When forming the above-mentioned low refractive index layer, it is preferable to set the viscosity of the composition for the low refractive index layer to which a low refractive index agent and resin, etc., are added to 0.5-5 mPa·s ( 25℃), preferably within the range of 0.7～3 mPa·s (25℃). It can realize an optical layer with excellent visible light, and can form a uniform and non-uniform coating film, and can form a low refractive index layer with particularly excellent adhesion.

The hardening means of the resin may be the same as that described in the above-mentioned optical layer. In the case of using a heating means for curing treatment, it is preferable to add a thermal polymerization initiator that initiates polymerization of the polymerizable compound by generating, for example, radicals by heating, to the fluorine-based resin composition.

The layer thickness (nm) d _{A of the} low refractive index layer is preferably one that satisfies the following formula (A): d _A =mλ/(4n _A ) (A) (In the above formula, n _A represents the refraction of the low refractive index layer Rate, m represents a positive odd number, preferably 1, λ is the wavelength, preferably a value in the range of 480 to 580 nm).

Furthermore, in the present invention, in terms of reducing reflectance, the low refractive index layer preferably satisfies the following formula (B): 120<n _A d _A <145 (B).

According to the present invention, since the penetration image of the optical film measured by the optical comb with a width of 0.125 mm is set to C (0.125), the penetration image of the optical film measured by the optical comb with a width of 0.25 mm is set to C (0.125). When the clarity is set to C (0.25), the optical film satisfies the above formula (1) and formula (2), so even if the optical film has a low total haze of 0% or more and 5% or less and has 0% or more and 5 The low internal haze below% can also suppress glare, reflection and watermark for the above reasons. Furthermore, according to the present invention, since the half-value width of the surface height distribution of the optical film and the average curvature of the surface concavities and convexities satisfy the above-mentioned specific numerical range, the concavity and convexity of the optical film surface becomes a specific concavity and convexity. Even if the optical film has a low total haze of 0% or more and 5% or less and a low internal haze of 0% or more and 5% or less, for the above reasons, glare can be suppressed and watermark can be controlled.

Here, the total haze value and the internal haze value are the values when the entire optical film is measured. Furthermore, the above-mentioned total haze value and internal haze value can be measured by a haze meter (HM-150, manufactured by Murakami Color Research Institute) by a method based on JIS K7136. Specifically, a haze meter is used to measure the total haze value of the optical film in accordance with JIS K7136. Thereafter, a triacetyl cellulose substrate (manufactured by Fuji Film Co., TD60UL) was attached to the surface of the optical film via a transparent optical adhesive layer. Thereby, the uneven shape of the surface of the optical film is squashed, and the surface of the optical film becomes flat. Then, in this state, using a haze meter (HM-150, manufactured by Murakami Color Research Institute), the haze value was measured in accordance with JIS K7136, thereby obtaining the internal haze value. The internal haze does not consider the unevenness of the surface of the optical film.

In the display device with a touch panel of the present invention, the total haze value of the optical film is preferably 1% or less, more preferably 0.3% or more and 0.5% or less. The internal haze value is preferably substantially 0%. Here, the so-called "internal haze value is substantially 0%" means the following meaning: it is not limited to the case where the internal haze value is completely 0%, and includes even when the internal haze value exceeds 0%. Within the range of measurement error and the internal haze value can be roughly regarded as the range of 0% (for example, the internal haze value below 0.3%).

When the total haze value of the above-mentioned optical film is 0% or more and 5% or less, and the internal haze value is 0% or more and 5% or less, the surface haze value of the optical film becomes 0% or more and 5% or less. The surface haze value of the optical film is preferably 0% or more and 1% or less, more preferably 0% or more and 0.3% or less. The surface haze value is caused only by the unevenness of the surface of the optical film. By subtracting the internal haze value from the total haze value, the surface haze value caused only by the unevenness of the surface of the optical film can be obtained. .

When using inorganic oxide particles with an average primary particle size of 1 nm or more and 100 nm or less (for example, smoked silica) as the above particles to form the optical layer, a lower total haze value (for example, Optical film with a total haze value below 1%) and a lower internal haze value (for example, an internal haze value of substantially 0%). That is, since the total haze and internal haze of the optical film are the ratio of the transmitted light that deviates from the incident light by 2.5° or more due to forward scattering in the transmitted light through the optical film, so long as the deviation from the incident light can be reduced If the ratio of penetrating light is above 2.5°, the total haze value and internal haze become lower. On the other hand, since the inorganic oxide fine particles with an average primary particle size of 100 nm or less do not aggregate into lumps in the optical layer, but form loose aggregates, the light penetrating the optical layer is not easy to diffuse in the optical layer. Therefore, when an optical layer is formed using inorganic oxide fine particles with an average primary particle size of 1 nm or more and 100 nm or less, the generation of transmitted light deviating from the incident light by more than 2.5° can be suppressed, thereby obtaining a total Optical film with lower haze value and internal haze value.

When the uneven surface of the above-mentioned optical layer is formed by only inorganic oxide particles, it is easy to form an uneven surface with gentle and uniform unevenness, that is, an uneven surface with a small curvature, which can obtain anti-reflective properties and water-repellent marks. . Therefore, an optical film with lower total haze value and internal haze value and can further suppress glare can be obtained.

According to the present invention, since the total haze value of the optical film becomes 0% or more and 5% or less, and the internal haze value becomes 0% or more and 5% or less, the decrease in brightness or light transmittance can be suppressed. In addition, since the diffusion of the image light inside the optical film can be suppressed, part of the image light does not become stray light. As a result, there is no risk of lowering the contrast of the dark room and no image blurring. With this, the above optical film can be incorporated into ultra-high-definition small mobile devices, or ultra-high-definition image display devices such as 4K2K (horizontal pixels 3840×vertical pixels 2160) with a horizontal pixel number of 3000 or more Used in.

According to the present invention, since the optical film is provided with the optical layer having the uneven surface, it is possible to suppress the interference of the light reflected at the interface between the translucent substrate and the optical layer and the light reflected on the uneven surface of the optical layer. Thereby, the generation of interference fringes can be suppressed. In addition, when the mixed region is formed, the reflection at the interface between the light-transmitting substrate and the optical layer can be suppressed, so that the generation of interference fringes can be further suppressed.

When the unevenness of the uneven surface of the optical layer is formed by only the inorganic oxide fine particles, it is easy to make the inclination angle of the unevenness of the uneven surface not large. In this way, excessive diffusion of external light will not occur, and therefore the decrease in the contrast of the bright room can be suppressed. In addition, the image light can be prevented from becoming stray light, and therefore, a good dark room contrast can also be obtained. Furthermore, since it has a moderate specular reflection component, when a moving image is displayed, the illuminance or brightness of the image is increased, and a feeling of jumping can be obtained. Thereby, it is possible to obtain a sense of black color that has both excellent contrast and pulsation.

Furthermore, optical films satisfying the above formulas (1) and (2) can also be used to provide methods for improving glare and watermarking.

In addition, an optical film that satisfies the surface height distribution of the above-mentioned optical film with a half-value width of 200 nm or more and an average curvature of surface concavities and convexities of 0.30 mm ^-1 or less can also be used to provide a method for improving glare and watermarking.

The above-mentioned optical film can be incorporated into, for example, a 4K2K (horizontal pixel count of 3840×vertical pixel count of 2160) and an ultra-high-definition image display device with a horizontal pixel count of 3000 or more. Examples of image display devices include: liquid crystal displays (LCD), cathode ray tube display devices (CRT), plasma displays (PDP), electroluminescence displays (ELD), field emission displays (FED), touch panels , Tablet PC, electronic paper, etc.

The above-mentioned image display device is preferably a liquid crystal display with a horizontal pixel count of 3000 or more. The image display device is composed of a backlight unit and a liquid crystal panel with an optical film arranged on the side of the observer more than the backlight unit. As the backlight unit, a well-known backlight unit can be used. As the aforementioned backlight, quantum dot LEDs can also be used.

Since the optical film of the present invention is formed with a specific concave-convex shape, the generation of glare can be sufficiently suppressed, and a high-quality display image can be obtained. In addition, the display device with a touch panel of the present invention has a specific concave-convex shape formed on the surface of the optical film opposite to the touch panel, so that the generation of watermarks and glare can be sufficiently suppressed, and high-quality display images can be obtained. Like. Therefore, the optical film of the present invention can be preferably applied to cathode ray tube display devices (CRT), liquid crystal displays (LCD), plasma displays (PDP), electroluminescence displays (ELD), field emission displays (FED), Electronic paper, tablet PC, etc.

The content of the present invention is illustrated by the following embodiments, but the content of the present invention is not limited to these implementation modes for interpretation. Unless otherwise specified, "parts" and "%" are quality standards.

(Example 1) (Production of optical film) A translucent substrate (cellulose triacetate film, thickness 40 μm, manufactured by Konica Minolta, KC4UAW) was prepared, and the following was coated on one side of the translucent substrate The composition of the optical layer of the shown composition forms a coating film. Then, for the formed coating film, dry air at 50°C was circulated at a flow rate of 0.2 m/s for 30 seconds, and then dry air at 70°C was circulated at a flow rate of 10 m/s for 30 seconds to dry it. This causes the solvent in the coating film to evaporate. After that, using an ultraviolet irradiation device (manufactured by Fusion UV Systems Japan, light source H BULB), under a nitrogen atmosphere (oxygen concentration of 200 ppm or less), ultraviolet rays are irradiated so that the ^{cumulative light quantity becomes 100 mJ/cm 2 to harden the coating film.} This forms an optical layer with a thickness of 5.0 μm (when cured) to produce an optical film.

(Composition for optical layer) Silicon dioxide particles (fumigated silicon dioxide treated with octyl silane, with an average primary particle size of 12 nm, manufactured by Aerosil, Japan) 0.5 parts by mass Neopentyl erythritol tetraacrylate (PETTA) (product name "PETA", manufactured by Daicel-Cytec) Quality 50 copies Amine acrylate (product name "V-4000BA", manufactured by DIC) 50 quality Polymerization initiator (Irgacure 184, manufactured by BASF Japan) 5 Quality Polyether modified polysiloxane (product name "TSF4460", manufactured by Momentive Performance Materials) 0.025 mass copies Toluene 115 mass copies Isopropyl alcohol 45 parts by mass Cyclohexanone 15 parts by mass

(Example 2) The curing condition of the coating film was set to ^{irradiate ultraviolet rays so that the cumulative light amount became 50 mJ/cm 2 to} cure the coating film. Except for this, the uneven layer was formed in the same manner as the optical layer of Example 1 . The composition for a low refractive index layer shown below is applied to the surface of the formed uneven layer to form a coating film. Then, for the formed coating film, 40°C dry air was circulated at a flow rate of 0.2 m/s for 15 seconds, and then 40°C dry air was circulated at a flow rate of 10 m/s for 30 seconds to dry it. This causes the solvent in the coating film to evaporate. After that, using an ultraviolet irradiation device (manufactured by Fusion UV Systems Japan, light source H BULB), under a nitrogen atmosphere (oxygen concentration of 200 ppm or less), ultraviolet rays are irradiated so that the ^{cumulative light quantity becomes 100 mJ/cm 2 to harden the coating film.} Thereby, a low-refractive index layer with a thickness of 0.1 μm (when cured) is formed, and an optical layer having a concavo-convex layer and a low-refractive-index layer laminated on the concavo-convex layer is formed. In this way, the optical film of Example 2 was produced.

(Composition for low refractive index layer) Hollow silica particles (average particle size 60 nm) 125 parts by mass (100% conversion value of solid content) Neopentaerythritol triacrylate (PETA) (product name: PETIA, manufactured by Daicel-Cytec) 20 Quality Fluoropolymer (product name "Opstar JN35", manufactured by JSR company) Quality of 100% (value of solid) 100% Polymerization initiator (Irgacure 127; manufactured by BASF Japan) 7 parts by mass Modified silicone oil (X22164E; manufactured by Shin-Etsu Chemical Industry Co., Ltd.) 5 parts by mass Methyl isobutyl ketone (MIBK) 5300 parts by mass Propylene glycol monomethyl ether acetate (PGMEA) 2200 parts by mass

(Example 3) The blending amount of the silica fine particles in the optical layer composition was 0.8 parts by mass, and the drying conditions of the coating film were set to circulate dry air at 70°C for 15 seconds at a flow rate of 1.0 m/s, and then to 10 The flow rate of m/s allowed dry air at 70° C. to circulate for 30 seconds, except for this, an optical film was produced in the same manner as in Example 1.

(Example 4) Except for setting the thickness of the optical layer at the time of hardening to 4.5 μm, an optical film was produced in the same manner as in Example 1.

(Example 5) Set the drying conditions of the coating film to circulate dry air at 70°C for 15 seconds at a flow rate of 1.0 m/s, and then circulate dry air at 70°C for 30 seconds at a flow rate of 10 m/s to harden the optical layer The thickness was set to 4.5 μm, except for this, an optical film was produced in the same manner as in Example 3.

(Example 6) The composition for the optical layer contains 1.0 part by mass of organic particles (acrylic-styrene copolymer particles, average particle size: 2.0 μm, refractive index: 1.55, manufactured by Sekisui Chemical Industry Co., Ltd.), and the drying conditions of the coating film are set to After circulating dry air at 70°C for 15 seconds at a flow rate of 1.0 m/s, and then circulating dry air at 70°C for 30 seconds at a flow rate of 10 m/s, the optics were fabricated in the same manner as in Example 1, except that membrane.

(Comparative example 1) The blending amount of the silica fine particles in the optical layer composition is 1.0 part by mass, and it contains organic particles (acrylic-styrene copolymer particles, average particle size: 2.0 μm, refractive index: 1.55, Sekisui Chemical Industry Co., Ltd. Manufactured by the company) 3.0 parts by mass. Set the drying conditions of the coating film to circulate dry air at 70°C for 15 seconds at a flow rate of 0.2 m/s, and then circulate dry air at 70°C for 30 seconds at a flow rate of 10 m/s. , Except that the thickness of the optical layer at the time of curing was set to 4.0 μm, an optical film was produced in the same manner as in Example 1.

(Comparative example 2) Except for not blending silicon dioxide fine particles in the composition for the optical layer, an optical film was produced in the same manner as in Example 1.

＜Evaluation of anti-reflective properties＞ The optical films produced in the respective examples and comparative examples were attached to the black acrylic board in such a way that the concave-convex surface becomes the surface through the transparent adhesive. In a bright room environment from a distance of about 2 m away from the eyes, the sample was evaluated with the following criteria to evaluate whether the sample obtained the anti-reflective property of "I don't mind the degree of reflection of the observer and the observer's background". ○: Don't mind entering ×: The reflection is clearly visible

＜Is there a watermark＞ The optical films produced in the respective examples and comparative examples were attached to the black acrylic board in such a way that the concave-convex surface becomes the surface through the transparent adhesive. In addition, tape was attached to both ends of the glass plate with a thickness of 0.7 mm and a size of 10 cm×10 cm. Then, by separating the optical film from the glass plate, the tape-attached surface of the glass plate is arranged to face the optical film. The air gap between the surface of the optical film and the glass plate is 0.1 mm. Then, while pressing the glass plate with a finger, irradiate light from the sodium lamp placed on the glass to investigate whether the watermark is confirmed. The evaluation criteria are as follows. The results are shown in Table 1. ◎: The watermark has not been confirmed. ○: Some watermarks are observed but the level is no problem. ×: The watermark is clearly confirmed.

＜Determination of the clarity of the penetrating image＞ For each optical film obtained in the Examples and Comparative Examples, the clarity of the penetration image was measured in the following manner. The results are shown in Table 1. First, prepare an image clarity measuring device (model: ICM-1T, manufactured by SUGA Test Instruments). Then, the optical films of the Examples and Comparative Examples were set so that the side of the triacetyl cellulose resin film became the light source side of the image clarity measuring device, according to the image clarity of the penetration method of JIS K7374 The measurement method measures the clarity of the penetrating image. As the optical comb, one with a width of 0.125 mm and a width of 0.25 mm is used. Then, obtain the difference between the penetration image definition (C(0.25)) measured by the optical comb with a width of 0.25 mm and the penetration image definition (C(0.125)) measured by the optical comb with a width of 0.125 mm Poor (C (0.25)-C (0.125)). In addition, for reference, an optical comb with a width of 0.5 mm, a width of 1.0 mm, and a width of 2.0 mm was used to measure the clarity of the transmission image of each optical film of the Examples and Comparative Examples in the same manner as described above.

<Glare Evaluation (1)> For each of the optical films obtained in the Examples and Comparative Examples, the surface of the optical film without an optical layer and the glass surface without a matrix of 350 ppi black matrix (glass thickness 0.7 mm) Use adhesives to fit together. For the sample obtained in this way, a white surface light source (Lightbox manufactured by HAKUBA, average brightness 1000 cd/m ² ) is set on the side of the black matrix to simulate glare. Use a CCD camera (KP-M1, C-type mounting adapter, extension tube: PK-11A Nikon, camera lens: 50 mm, F1.4s NIKKOR) to shoot from the optical film side. The distance between the CCD camera and the optical film is set to 250 mm, and the focus of the CCD camera is adjusted by aligning the optical film. Put the image taken by the CCD camera into a personal computer, and use the image processing software (ImagePro Plusver.6.2; manufactured by Media Cybernetics) to analyze in the following way. First, select a 200×160 pixel evaluation part from the image that was put in, and convert it to 16 bit gray scale at the evaluation part. Secondly, select the low-pass filter from the enhanced tab of the filter command, and start the filter under the conditions of 3×3, order 3, and intensity 10. In this way, the components originating from the black matrix pattern are removed. Secondly, choose flattening and perform shadow correction on the condition of dark background and target width 10. Secondly, use the contrast enhancement command to set contrast: 96 and brightness: 48 for contrast enhancement. The obtained image is converted into 8 bit gray scale, and the deviation of the value of each pixel is calculated as the standard deviation value for the 150×110 pixels among them, thereby digitizing the glare. The smaller the glare value after the digitization is, the less glare is. The results are shown in Table 1.

<Glare Evaluation (2)> For each optical film obtained in Examples and Comparative Examples, the glare was evaluated as follows. Set a light box with a brightness of 1500 cd/m ² (white surface light source), a 350 ppi black matrix glass, and an optical film in order to overlap from bottom to top, from the top and the bottom to the left and right at a distance of about 30 cm, Visual evaluation was performed by 15 subjects. Determine whether you mind glare, and evaluate it based on the following criteria. The results are shown in Table 1. ◎: 13 or more people with good answers ○: 10-12 people with good answers △: 7-9 people with good answers ×: 6 people or less with good answers

＜Measurement of total haze, internal haze and surface haze＞ For each optical film obtained in the foregoing Examples and Comparative Examples, the total haze, internal haze, and surface haze were measured as follows. The results are shown in Table 2. First, a haze meter (HM-150, manufactured by Murakami Color Technology Research Institute) was used to measure the total haze value of the optical film in accordance with JIS K7136. After that, a triacetyl cellulose substrate (manufactured by Konica Minolta, KC4UAW) was attached to the surface of the optical layer via a transparent optical adhesive layer. Thereby, the concave-convex shape of the concave-convex surface of the optical layer is squashed, and the surface of the optical film becomes flat. In this state, using a haze meter (HM-150, manufactured by Murakami Color Research Institute), the haze value was measured in accordance with JIS K7136 to obtain the internal haze value. Then, the surface haze value is obtained by subtracting the internal haze value from the total haze value.

<Determination of the three-dimensional average inclination angle of θa _3D> each surface of the optical films of Examples and Comparative Examples for the embodiments obtained in the following manner was measured three-dimensional average inclination angle θa _3D. The results are shown in Table 2. For the surface of each optical film opposite to the surface on which the unevenness was formed, a sample was made by attaching it to a glass plate via a transparent adhesive, using a white interference microscope (New View 7300, manufactured by Zygo), and proceeding under the following conditions Measurement and analysis of the surface shape of the optical film. Furthermore, the measurement and analysis soft system uses MetroPro ver8.3.2. Microscope Application. (Measurement conditions) Objective lens: 50 times Zoom: 1 times Measurement area: 545 μm×545 μm Resolution (interval per 1 point): 0.44 μm (Analysis conditions) Removed: Plane Filter: High Pass FilterType: GaussSpline Low wavelength: 250 μm High wavelength: 3 μm Remove spikes: on Spike Height (xRMS): 2.5 Furthermore, Low wavelength is equivalent to the critical value λc in the roughness parameter. Secondly, use the above analysis software (MetroPro ver8.3.2-Microscope Application) to display "Ra" on the Slope Mag Map screen, and set its value to θa _{3D of the} optical film.

<Measurement of Smp, Ra, Rz> Using the surface shape data obtained when calculating the above-mentioned three-dimensional average inclination angle θa _3D and the same analysis conditions, "Ra" and "SRz" are displayed on the Surface Map screen, and the values of each are displayed. Set as Ra and Rz of optical film. Secondly, display the "Save Data" button on the Surface Map screen to save the 3D surface roughness data after analysis. Then, use Advanced Texture Application to read the above saved data and apply the following analysis conditions. (Analysis conditions) High FFT Filter: off Low FFT Filter: off Remove: Plane Next, display the Peak/Valleys screen, and count the number of peaks according to "Peaks Stats". Among them, in order to exclude insignificant peaks, the peaks whose area is 1/10000 or more of the area of a circle with Low wavelength as the diameter (125 μm×125 μm×π) and whose height is 1/10 or more of Rtm are counted. Furthermore, Rtm can be read from the "Roughness/Waviness Map" screen, which represents the average value of the maximum height of each area when the measurement area is divided into 3×3. Then, using the above method, that is, Smp is calculated based on the following equation. The results are shown in Table 2.

[Table 1] C (0.125) C (0.25) C (0.5) C (1.0) C (2.0) C (0.25)-C (0.125) Anti-reflection Watermark Glare evaluation (1) Glare evaluation (2) Example 1 39.4 55.5 79.8 95.1 99.1 16.1 ○ ◎ 7.4 ◎ Example 2 39.7 58.0 80.5 95.2 99.0 18.3 ○ ◎ 6.5 ◎ Example 3 47.8 56.3 76.4 92.9 98.6 8.5 ○ ◎ 9.0 ○ Example 4 60.5 72.1 87.1 95.9 98.7 11.6 ○ ○ 7.1 ◎ Example 5 56.0 62.3 78.4 92.8 98.1 6.3 ○ ○ 8.7 ○ Example 6 40.8 53.1 72.9 89.2 96.8 12.3 ○ ◎ 9.4 ○ Comparative example 1 57.8 58.5 67.7 82.7 93.5 0.7 ○ ◎ 14.5 X Comparative example 2 97.9 98.3 98.5 98.8 99.1 0.4 X X 5.0 ◎

[Table 2] Total haze Internal haze Surface haze θa3D[°] Smp[mm] Ra[μm] Rz[μm] Example 1 0.3 0.2 0.1 0.26 0.182 0.059 0.19 Example 2 0.3 0.2 0.1 0.28 0.122 0.046 0.16 Example 3 0.3 0.2 0.1 0.30 0.150 0.057 0.19 Example 4 0.3 0.2 0.1 0.18 0.122 0.039 0.12 Example 5 0.3 0.2 0.1 0.28 0.128 0.052 0.18 Example 6 1.5 1.3 0.2 0.30 0.111 0.049 0.19 Comparative example 1 3.2 2.5 0.7 0.52 0.098 0.064 0.27 Comparative example 2 0.2 0.2 0.0 0.10 0.032 0.001 0.02

As shown in Table 1 and Table 2, the optical film of the embodiment has excellent anti-reflective properties, watermarks, and glare (1) and (2). In addition, the total haze, internal haze, and surface haze are excellent The values are low enough. On the other hand, regarding the optical film of Comparative Example 1, the difference between the value of C (0.25) and the value of C (0.125) is small, the uneven shape of the optical layer surface is gentle, and the evaluation of glare is poor. In addition, regarding the optical film of Comparative Example 2, the value of C (0.125) was large, and the difference between the value of C (0.25) and the value of C (0.125) was small, and the evaluation of anti-reflective properties and watermark was poor.

＜Half width of surface height distribution＞ For each optical film obtained in the Examples and Comparative Examples, the surface on the opposite side to the surface on which the optical layer was formed was attached to a glass plate via a transparent adhesive to prepare samples, and a white interference microscope (New View 7300, Zygo company), the surface profile of the optical film is obtained under the following conditions. Furthermore, the measurement and analysis soft system uses MetroPro ver8.3.2. Microscope Application. (Measurement conditions) Objective lens: 10 times Zoom: 1 times Measuring area: 2.71 mm×2.71 mm Resolution (every 1 point interval): 2.18 μm (Analysis conditions) Removed: None Filter: BandPass FilterType: GaussSpline Low wavelength: 800 μm High wavelength: 25 μm Remove spikes: on Spike Height (xRMS): 2.5 Furthermore, Low wavelength is the wavelength of the long-wavelength cut-off filter, and High wavelength is equivalent to the wavelength of the short-wavelength cut-off filter. Secondly, use the aforementioned analysis software (MetroPro ver8.3.2-Microscope Application) to display the Surface Map screen, and display the histogram in such a way that the interval width becomes about 20 nm in the aforementioned screen to obtain the histogram data of the surface height distribution. According to the obtained histogram data, read the width of the distribution at the half-height of the peak position of the distribution height, and set it as the half-value width of the surface height distribution. Furthermore, when calculating the half-value width, an approximate curve obtained by linear interpolation of the values of each level of the obtained histogram data is made, and calculated based on the curve.

＜Average curvature of surface concavity and convexity＞ According to the surface profile obtained in the same way as the above, the curvature is calculated according to the above formula and the average curvature of all the points is calculated according to the above formula for the x direction from each point and the three points before and after it, thereby calculating the average curvature of the surface unevenness .

For the optical film produced in each embodiment and comparative example, the half-value width of the surface height distribution, the average curvature of the surface unevenness, the presence or absence of watermark, glare evaluation (1), (2), total haze, internal haze The results of surface haze, three-dimensional average tilt angle θa3D, "Smp", "Ra" and "Rz" are shown in Table 3.

[table 3] Half width (nm) Average curvature (mm ^-1 ) Watermark Glare (1) Glare (2) Total haze Internal haze Surface haze θa3D (°) Smp (mm) Ra (μm) Rz (μm) Example 1 290 0.146 ◎ 7.4 ◎ 0.3 0.2 0.1 0.26 0.182 0.059 0.19 Example 2 283 0.131 ◎ 6.5 ◎ 0.3 0.2 0.1 0.28 0.122 0.046 0.16 Example 3 315 0.245 ◎ 9.0 ○ 0.3 0.2 0.1 0.30 0.150 0.057 0.19 Example 4 204 0.134 ○ 7.1 ◎ 0.3 0.2 0.1 0.18 0.122 0.039 0.12 Example 5 247 0.207 ○ 8.7 ○ 0.3 0.2 0.1 0.28 0.128 0.052 0.18 Example 6 295 0.251 ◎ 9.4 ○ 1.5 1.3 0.2 0.30 0.111 0.049 0.19 Comparative example 1 268 0.353 ◎ 14.5 X 3.2 2.5 0.7 0.52 0.098 0.064 0.27 Comparative example 2 15 0.013 X 5.0 ◎ 0.2 0.2 0 0.10 0.032 0.001 0.02

As shown in Table 3, regarding the optical films of Examples 1 to 6, the watermark and glare (1) and (2) are excellent in each evaluation, and the values of total haze, internal haze, and surface haze are also sufficiently low . On the other hand, regarding the optical film of Comparative Example 1, the average curvature of the surface unevenness is large, the lens effect caused by the surface unevenness becomes larger, and the evaluation of glare is poor. In addition, regarding the optical film of Comparative Example 2, the half-value width of the surface height distribution was small, and the evaluation of the watermark was poor. [Industrial availability]

Since the optical film of the present invention is composed of the above-mentioned structure, reflection or Newton's ring can be suppressed, and the generation of glare can be sufficiently suppressed, and a high-quality display image can be obtained. In addition, since the display device with a touch panel of the present invention is constituted by the above-mentioned structure, the generation of watermarks and glare can be sufficiently suppressed, and high-quality display images can be obtained. Therefore, the display device with touch panel of the present invention can be preferably applied to cathode ray tube display device (CRT), liquid crystal display (LCD), plasma display (PDP), electroluminescence display (ELD), field emission Display (FED), electronic paper, tablet PC, etc.

11: Optical film 12: Translucent substrate 13: Optical layer 14: Concave and convex shape 100: Penetration image clarity measuring device 101: light source 102: slit 103, 104: lens 105: light comb 106: Receiver 30: Display device with touch panel 31: Optical film 32: Translucent substrate 33: Optical layer 34: bump shape 35: Touch panel 43: optical layer 44: bump shape 45: touch panel 46: Clearance

Fig. 1 is a cross-sectional view schematically showing the optical film of the present invention. [Fig. 2] is a schematic diagram showing how the transmission image clarity of an optical film is measured by a transmission image clarity measuring device. [Fig. 3] is a cross-sectional view schematically showing a display device with a touch panel of the present invention. [Fig. 4] is a schematic diagram showing how incident light is reflected in the second form of the display device with touch panel of the present invention. [Figure 5] is the surface profile of the optical film of the present invention.

Claims (4)

An optical film having the following composition: an optical layer having an uneven shape on the surface is laminated on a translucent substrate, characterized in that the optical layer contains a binder resin and an inorganic material with an average primary particle size of 1nm or more and 100nm or less Oxide fine particles, the total haze value is 0% or more and 5% or less, the internal haze value is 0% or more and 5% or less, and the clearness of the penetration image measured using a comb with a width of 0.125mm is set to C (0.125), when the penetration image clarity measured by a light comb with a width of 0.25mm is set to C(0.25), the following equations (1) and (2) are satisfied, C(0.25)-C(0.125 )≧2% (1) C(0.125)≦64% (2). For example, the optical film of the first item in the scope of the patent application has a total haze value of 0% or more and 1% or less, and the internal haze value is substantially 0%. For example, the optical film of the first item of the scope of patent application, wherein the inorganic oxide fine particles are inorganic oxide fine particles whose surface has been hydrophobized. A display device with a touch panel, which has a configuration in which the optical film of items 1, 2 or 3 of the scope of patent application and the touch panel are arranged oppositely, and the optical film and the touch panel are connected to each other. The state with a gap between each other is arranged so that the optical layer of the optical film faces the touch panel.

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